NIOSH POCKET GUIDE TO CHEMICAL HAZARDS

DEPARTMENT OF HEALTH AND HUMAN SERVICES
Centers for Disease Control and Prevention
National Institute for Occupational Safety and Health

September 2005

DHHS (NIOSH) Publication No. 2005-149

DISCLAIMER
Mention of the name of any company or product does not constitute endorsement by the National Institute for Occupational Safety and Health (NIOSH).

ORDERING INFORMATION
For single copies of this publication, or to receive documents or other information about occupational safety and health, contact NIOSH at: NIOSH Publications Dissemination 4676 Columbia Parkway Cincinnati, OH 45226-1998 Telephone: 1-800-35 NIOSH (1-800-356-4674) Fax: 1-513-533-8573 E-mail: pubstaft@cdc.gov NIOSH Web site: http://www.cdc.gov/niosh For sale by: Superintendent of Documents U.S. Government Printing Office P.O. Box 371954 Pittsburgh, PA 15250-7954 Stock number: 017-033-00500-1 Internet: http://bookstore.gpo.gov Toll-free telephone: (866) 512-1800 DC area: (202) 512-1800 Fax: (202) 512-2104 National Technical Information Service, Springfield, VA 22161 Stock number: PB2005-108099 Telephone: (703) 605-6000 Toll-free telephone: (800) 553-6847

COPYING AND REPRINTING
This document is in the public domain and may be freely copied or reprinted.

SAFER • HEALTHIER • PEOPLE™
ii

ELECTRONIC VERSIONS
The Pocket Guide is available in CD-ROM format from NIOSH and is on the NIOSH Web site (http://www.cdc.gov/niosh/npg/npg.html). Further information about these electronic versions, or about copies of this and other NIOSH documents, may be obtained from the office listed below: NIOSH Publications 4676 Columbia Parkway Cincinnati, Ohio 45226-1998 Toll-free telephone: (800) 356-4674 Fax: (513) 533-8573 The Pocket Guide is also made available through commercial vendors in electronic formats. It is currently available in CD-ROM format from the vendors listed below. Please contact them directly to receive more detailed information, including the prices of their products. Canadian Centre for Occupational Health and Safety Hamilton, Ontario, Canada Toll-free telephone: (800) 668-4284 Fax: (905) 572-2206 Industrial Hygiene Services, Inc. St. Louis, Missouri Toll-free telephone: (800) 732-3015 Fax: (314) 993-3193 Emergency Response Specialists, Inc. Birmingham, Alabama Telephone: (205) 324-0100 Praxis Environmental Systems, Inc. Guilford, Connecticut Telephone: (203) 458-7111 Fax: (203) 458-7121 Micromedex, Inc. Englewood, Colorado Toll-free telephone: (800) 525-9083 Fax: (800) 635-6339 Tecsa S.p.A. Italy (portion in Italian) Telephone: +39 2 33910.484 Fax: +39 2 33910.737

COMMENTS & SUGGESTIONS
We encourage and welcome any comments, suggestions, or corrections that you may have regarding the Pocket Guide. You can use the Reader Response Card included with the Pocket Guide, or you can contact us via e-mail or telephone. Thank you for your comments and suggestions. E-mail address: npgcomments@cdc.gov Toll-free telephone: (800) 356-4674

iii

PREFACE
The NIOSH Pocket Guide to Chemical Hazards presents information taken from the NIOSH/OSHA Occupational Health Guidelines for Chemical Hazards, from National Institute for Occupational Safety and Health (NIOSH) criteria documents and Current Intelligence Bulletins, and from recognized references in the fields of industrial hygiene, occupational medicine, toxicology, and analytical chemistry. The information is presented in tabular form to provide a quick, convenient source of information on general industrial hygiene practices. The information in the Pocket Guide includes chemical structures or formulas, identification codes, synonyms, exposure limits, chemical and physical properties, incompatibilities and reactivities, measurement methods, respirator selections, signs and symptoms of exposure, and procedures for emergency treatment. The information assembled in the original 1978 printing of the Pocket Guide was the result of the Standards Completion Program, a joint effort by NIOSH and the Department of Labor to develop supplemental requirements for the approximately 380 workplace environmental exposure standards adopted by the Occupational Safety and Health Administration (OSHA) in 1971. Listed below are changes that were made for this edition of the Pocket Guide: • • This revision of the Pocket Guide includes a new layout for the Chemical Listing section, with information arranged in individual tables for each chemical. Recommendations for particulate respirators have been revised to incorporate “Part 84” terminology; “Part 11” terminology has been removed from the respirator recommendations. See “Recommendations for Respirator Selection” on page xiv for a more thorough explanation of these changes. The Synonym and Trade Name Index has been expanded to include the primary chemical name for each of the 677 chemicals listed in the Pocket Guide. This index is now called the Chemical, Synonym, and Trade Name Index (page 383). Changes were made to some of the ID Numbers and Guide Numbers to reflect changes that the Department of Transportation made in the 2004 Emergency Response Guidebook (http://hazmat.dot.gov/pubs/erg/gydebook.htm). The other major change to this edition of the Pocket Guide is that Appendix E (page 351) has been revised. It now contains OSHA respirator requirements for 28 chemicals or hazardous substances that were identified in the preamble to the OSHA Respiratory Protection Standard (29 CFR 1910.134). Other minor technical changes have also been made since the February 2004 edition. (For the most current information and updates, consult the electronic version on the NIOSH Web site: http://www.cdc.gov/niosh/npg/npg.html.) iv

CONTENTS
Preface .......................................................................................................................... Acknowledgments ........................................................................................................ Introduction ................................................................................................................... NIOSH Recommendations ........................................................................................... How to Use This Pocket Guide ..................................................................................... Table 1 – NIOSH Manual of Analytical Methods ........................................................ Table 2 – Personal Protection and Sanitation Codes .................................................... Table 3 – Symbols, Code Components, and Codes Used for Respirator Selection ..... Table 4 – Selection of N-, R-, or P-Series Particulate Respirators ............................... Table 5 – Abbreviations for Exposure Routes, Symptoms, and Target Organs ........... iv vi vii vii viii xvii xviii xx xxv xxvi

Table 6 – Codes for First Aid Data ............................................................................... xxviii Chemical Listing ........................................................................................................... Appendices .................................................................................................................... Appendix A – NIOSH Potential Occupational Carcinogens ........................................ Appendix B – Thirteen OSHA-Regulated Carcinogens ............................................... Appendix C – Supplementary Exposure Limits ........................................................... Appendix D – Substances with No Established RELs ................................................. Appendix E – OSHA Respirator Requirements for Selected Chemicals ..................... Appendix F – Miscellaneous Notes .............................................................................. Appendix G – Vacated 1989 OSHA PELs ................................................................... Indices ........................................................................................................................... CAS Number Index ...................................................................................................... DOT ID Number Index ................................................................................................. Chemical, Synonym, and Trade Name Index .............................................................. 1 341 342 344 345 350 351 361 362 373 374 379 383

v

ACKNOWLEDGMENTS
The Education and Information Division (EID), National Institute for Occupational Safety and Health (NIOSH), has primary responsibility for the development of the Pocket Guide. There have been many people who have contributed to the preparation and development of this document since it was first published in 1978. I would like to express my appreciation to the following people within EID for their efforts: Vern Anderson for general guidance; Guss Hasbani (Constella Group, Inc.) for computer programming and database development that has been vital to the production of this new edition; Heinz Ahlers, Barb Dames, Charles Geraci, Richard Niemeier, David Votaw, Alan Weinrich, and Ralph Zumwalde for policy review; David Case, Laura Delaney, and Rolland Rogers for reformatting and computerization; Vanessa Becks, Anne Hamilton, and Rodger Tatken for editorial review; Clayton Doak, Eileen Kuempel, Leela Murthy, Henryka Nagy, John Palassis, Faye Rice, and David Votaw for assistance in updating and adding information; Lawrence Foster, Vicki Reuss, Lucy Schoolfield, and Ronald Schuler for data acquisition; Kent Hatfield for consultation on toxicology issues; Charlene Maloney for publication dissemination and general guidance; and Oliver F. Cobb and Associates (Carla Brooks, George Brown, Sherri Diana, and Jesse Romans) for answering requests and mailing thousands of copies of the Pocket Guide. The following people, who constitute the Pocket Guide Editorial Board, have contributed greatly by providing guidance and review of the content and style of this new edition: Steven Ahrenholz (Division of Surveillance, Hazard Evaluations and Field Studies, DSHEFS), Roland BerryAnn (National Personal Protective Technology Laboratory, NPPTL), Joseph Bowman (Division of Applied Research and Technology, DART), Pamela Drake (Spokane Research Laboratory, SRL), Gerald Joy (Pittsburgh Research Laboratory, PRL), Alan Lunsford (DART), Nancy Nilsen (DSHEFS), Paula Fey O’Connor (DART), Carl Ornot (Office of Administrative and Management Services, OAMS), Jay Snyder (NPPTL), Sidney Soderholm (Health Effects Laboratory Division, HELD), David Sylvain (DSHEFS), Ainsley Weston (HELD), and Anthony Zimmer (DART). In addition, the following people also have contributed greatly to the Pocket Guide: Mary Ellen Cassinelli (DART), Donald Dollberg (DART), and Paula Fey O’Connor (DART) for the development of the measurement methods section; Roland BerryAnn (NPPTL), Nancy Bollinger (HELD), Christopher Coffey (Division of Respiratory Disease Studies, DRDS) for the development of respirator recommendations; Laurence Reed (DART) and John Whalen (DART) for policy review; Crystal Ellison (Office of Compensation Analysis and Support, OCAS) for assistance in updating and adding information; and Henry Chan and Howard Ludwig (former Pocket Guide Technical Editors) for general guidance. Also, thanks are due to all of the people who have reviewed and commented on the Pocket Guide during its initial development and subsequent revisions. Michael E. Barsan (Technical Editor) vi

INTRODUCTION
The NIOSH Pocket Guide to Chemical Hazards provides a concise source of general industrial hygiene information for workers, employers, and occupational health professionals. The Pocket Guide presents key information and data in abbreviated tabular form for 677 chemicals or substance groupings commonly found in the work environment (e.g., manganese compounds, tellurium compounds, inorganic tin compounds, etc.). The industrial hygiene information found in the Pocket Guide assists users to recognize and control occupational chemical hazards. The chemicals or substances contained in this revision include all substances for which the National Institute for Occupational Safety and Health (NIOSH) has recommended exposure limits (RELs) and those with permissible exposure limits (PELs) as found in the Occupational Safety and Health Administration (OSHA) Occupational Safety and Health Standards (29 CFR 1910.1000 – 1052). Background In 1974, NIOSH (which is responsible for recommending health and safety standards) joined OSHA (whose jurisdictions include promulgation and enforcement activities) in developing a series of occupational health standards for substances with existing PELs. This joint effort was labeled the Standards Completion Program and involved the cooperative efforts of several contractors and personnel from various divisions within NIOSH and OSHA. The Standards Completion Program developed 380 substance-specific draft standards with supporting documentation that contained technical information and recommendations needed for the promulgation of new occupational health regulations. The Pocket Guide was developed to make the technical information in those draft standards more conveniently available to workers, employers, and occupational health professionals. The Pocket Guide is updated periodically to reflect new data regarding the toxicity of various substances and any changes in exposure standards or recommendations. (For the most current information and updates, consult the electronic version on the NIOSH Web site: http://www.cdc.gov/niosh/npg/npg.html.) Data Collection and Application The data collected for this revision were derived from a variety of sources, including NIOSH policy documents such as criteria documents and Current Intelligence Bulletins (CIBs), and recognized references in the fields of industrial hygiene, occupational medicine, toxicology, and analytical chemistry.

NIOSH RECOMMENDATIONS
Acting under the authority of the Occupational Safety and Health Act of 1970 (29 USC Chapter 15) and the Federal Mine Safety and Health Act of 1977 (30 USC Chapter 22), NIOSH develops and periodically revises recommended exposure limits (RELs) for hazardous substances or conditions in the workplace. NIOSH also recommends appropriate preventive measures to reduce or eliminate the adverse health and safety effects of these vii

hazards. To formulate these recommendations, NIOSH evaluates all known and available medical, biological, engineering, chemical, trade, and other information relevant to the hazard. These recommendations are then published and transmitted to OSHA and the Mine Safety and Health Administration (MSHA) for use in promulgating legal standards. NIOSH recommendations are published in a variety of documents. Criteria documents recommend workplace exposure limits and appropriate preventive measures to reduce or eliminate adverse health effects and accidental injuries. Current Intelligence Bulletins (CIBs) are issued to disseminate new scientific information about occupational hazards. A CIB may draw attention to a formerly unrecognized hazard, report new data on a known hazard, or present information on hazard control. Alerts, Special Hazard Reviews, Occupational Hazard Assessments, and Technical Guidelines support and complement the other standard development activities of the Institute. Their purpose is to assess the safety and health problems associated with a given agent or hazard (e.g., the potential for injury or for carcinogenic, mutagenic, or teratogenic effects) and to recommend appropriate control and surveillance methods. Although these documents are not intended to supplant the more comprehensive criteria documents, they are prepared in order to assist OSHA and MSHA in the formulation of regulations. In addition to these publications, NIOSH periodically presents testimony before various Congressional committees and at OSHA and MSHA rulemaking hearings. Recommendations made through 1992 are available in a single compendium entitled NIOSH Recommendations for Occupational Safety and Health: Compendium of Policy Documents and Statements [DHHS (NIOSH) Publication No. 92-100] (http://www.cdc.gov/niosh/92-100.html). More recent recommendations are available on the NIOSH Web site (http://www.cdc.gov/niosh). Copies of the Compendium may be ordered from the NIOSH Publications office (800-356-4674).

HOW TO USE THIS POCKET GUIDE
The Pocket Guide has been designed to provide chemical-specific data to supplement general industrial hygiene knowledge. Individual tables for each chemical present this data in the Chemical Listing section (page 1). To maximize the amount of data provided in the limited space in these tables, abbreviations and codes have been used extensively. These abbreviations and codes, which have been designed to permit rapid comprehension by the regular user, are discussed for each field in these chemical tables in the following subsections. Chemical Name The chemical name found in the OSHA General Industry Air Contaminants Standard (29 CFR 1910.1000) is listed in the blue box in the top left portion of each chemical table. This name is referred to as the “primary name” in the Chemical, Synonym, and Trade Name Index (page 383). viii

Structure/Formula The chemical structure or formula is listed in the field to the right of the chemical name in each chemical table. Carbon-carbon double bonds (-C=C-) and carbon-carbon triple bonds (-C≡C-) have been indicated where applicable. CAS Number This section lists the Chemical Abstracts Service (CAS) registry number. The CAS number, in the format xxx-xx-x, is unique for each chemical and allows efficient searching on computerized data bases. A page index for all CAS registry numbers listed is included at the back of the Pocket Guide (page 374) to help the user locate a specific substance. RTECS Number This section lists the NIOSH Registry of Toxic Effects of Chemical Substances (RTECS®) number, in the format ABxxxxxxx. RTECS® may be useful for obtaining additional toxicologic information on a specific substance. RTECS® is a compendium of data extracted from the open scientific literature. On December 18, 2001, CDC’s Technology Transfer Office, on behalf of NIOSH, successfully completed negotiating a “PHS Trademark Licensing Agreement” for RTECS®. This nonexclusive licensing agreement provides for the transfer and continued development of the “RTECS® database and its trademark” to MDL Information Systems, Inc. (MDL), a wholly owned subsidiary of Elsevier Science, Inc. Under this agreement, MDL will be responsible for updating, licensing, marketing, and distributing RTECS®. For more information visit the MDL Web site (http://www.mdli.com). The RTECS® entries for chemicals listed in the Pocket Guide can be viewed on the NIOSH Web site (http://www.cdc.gov/niosh/npg/npg.html) or on the CD-ROM version of the Pocket Guide (see page iii for ordering information). IDLH This section lists the immediately dangerous to life or health concentrations (IDLHs). For the June 1994 Edition of the Pocket Guide, NIOSH reviewed and in many cases revised the IDLH values. The criteria utilized to determine the adequacy of the original IDLH values were a combination of those used during the Standards Completion Program and a newer methodology developed by NIOSH. These “interim” criteria formed a tiered approach, preferentially using acute human toxicity data, followed by acute animal inhalation toxicity data, and then by acute animal oral toxicity data to determine a preliminary updated IDLH value. When relevant acute toxicity data were insufficient or unavailable, NIOSH also considered using chronic toxicity data or an analogy to a chemically similar substance. NIOSH then compared these preliminary values with the following criteria to determine the updated IDLH value: 10% of lower explosive limit (LEL); acute animal respiratory irritation data (RD50); other short-term exposure guidelines; and the NIOSH Respirator Selection Logic (DHHS [NIOSH] Publication No. 2005-100; ix

” indicates that an IDLH value has not been determined for that substance. IDLH values that were originally determined in the Standards Completion Program or were subsequently revised are shown in brackets following the “Ca” designations. As a safety margin.gov/niosh/docs/2005-100). and incoordination. in emergency situations. and if other information or criteria should be utilized. NIOSH considered the ability of a worker to escape without loss of life or irreversible health effects along with certain transient effects.gov/niosh/idlh/idlh-1. The IDLH was considered a maximum concentration above which only a highly reliable breathing apparatus providing maximum worker protection should be permitted. in fact.html).cdc. disorientation.. EVERY EFFORT SHOULD BE MADE TO EXIT IMMEDIATELY! The NIOSH Respirator Selection Logic defines IDLH exposure conditions as “conditions that pose an immediate threat to life or health. “N.D.” The purpose of establishing an IDLH exposure concentration is to ensure that the worker can escape from a given contaminated environment in the event of failure of the respiratory protection equipment. In determining IDLH values. Appendix F (page 361) contains an explanation of the “Effective” IDLHs used for four chloronaphthalene compounds. such as severe eye or respiratory irritation. the 30-minute period was NOT meant to imply that workers should stay in the work environment any longer than necessary. The Respirator Selection Logic uses IDLH values as one of several respirator selection criteria.http://www. during entry into an atmosphere that contains a substance at a concentration greater than 2. The Documentation for Immediately Dangerous to Life or Health Concentrations (NTIS Publication Number PB-94-195047) further describes these criteria and provides information sources for both the original and revised IDLH values (http://www. or conditions that pose an immediate threat of severe exposure to contaminants. a self-contained breathing apparatus equipped with a full facepiece and operated in a pressure-demand or other positive-pressure mode) would be selected for firefighting. The purpose for establishing an IDLH value in the Standards Completion Program was to determine the airborne concentration from which a worker could escape without injury or irreversible health effects from an IDLH exposure in the event of the failure of respiratory protection equipment. The notation “Ca” appears in the IDLH field for all substances that NIOSH considers potential occupational carcinogens. exposure to carcinogens. which are likely to have adverse cumulative or delayed effects on health.000 times the NIOSH REL or OSHA PEL. However. NIOSH currently is assessing the various uses of IDLHs. the most protective respirators (e. which could prevent escape. However. x . IDLH values are based on effects that might occur as a consequence of a 30-minute exposure. entry into oxygen-deficient atmospheres. IDLH values are listed in the Pocket Guide for over 380 substances. whether the criteria used to derive the IDLH values are valid. and for entry into IDLH atmospheres.cdc. Under the Respirator Selection Logic. “10%LEL” indicates that the IDLH was based on 10% of the lower explosive limit for safety considerations even though the relevant toxicological data indicated that irreversible health effects or impairment of escape existed only at higher concentrations. such as radioactive materials.g.

Government Printing Office. A short-term exposure limit (STEL) is designated by “ST” preceding the value. *In July 1992. as found in Tables Z-1.S. Z-2. moving them back to PELs xi . that many DOT numbers are not unique for a specific substance. Box 371954. the 11th Circuit Court of Appeals in its decision in AFL-CIO v. this information can be found in the 2004 Emergency Response Guidebook (Office of Hazardous Materials Initiatives and Training [DHM-50]. Research and Special Programs Administration. The Identification (ID) number (xxxx) indicates that the chemical is regulated by DOT.. which contains a brief discussion of potential occupational carcinogens)..O. unless noted otherwise.html). Department of Transportation (DOT) Identification numbers and the corresponding Guide numbers. synonyms. for sale by the U. Superintendent of Documents. The Guide number (yyy) refers to actions to be taken to stabilize an emergency situation. 400 7th Street. Any substance that NIOSH considers to be a potential occupational carcinogen is designated by the notation “Ca” (see Appendix A [page 342]. Washington. unless noted otherwise. the STEL is a 15-minute TWA exposure that should not be exceeded at any time during a workday. U.1000). Department of Transportation. A page index for all DOT ID numbers listed is provided on page 379 to help the user locate a specific substance. 1993* and which are currently enforced by OSHA are listed next. Pittsburgh. and trade names listed in the Pocket Guide is included on page 383. and Z-3 of the OSHA General Industry Air Contaminants Standard (29 CFR 1910. 965 F.S. PA 15250-7954).Conversion Factors This section lists factors for the conversion of ppm (parts of vapor or gas per million parts of contaminated air by volume) to mg/m3 (milligrams of vapor or gas per cubic meter of contaminated air) at 25°C and 1 atmosphere for chemicals with exposure limits expressed in ppm.S. This information is also available on the CD-ROM and Web site versions of the Pocket Guide (http://www. 20590-0001. D. For NIOSH RELs. Synonyms and Trade Names This section contains an alphabetical list of common synonyms and trade names for each chemical. S. that were effective on July 1. P. please note however. A ceiling REL is designated by “C” preceding the value.W. the ceiling value should not be exceeded at any time. A page index for all chemical names. 1992) vacated more protective PELs set by OSHA in 1989 for 212 substances. Their format is xxxx yyy.C.gov/niosh/npg/npg. Exposure Limits The NIOSH recommended exposure limits (RELs) are listed first in this section. “TWA” indicates a time-weighted average concentration for up to a 10-hour workday during a 40-hour workweek. DOT ID and Guide Number This section lists the U.2d 962 (11th Cir. The OSHA permissible exposure limits (PELs). OSHA.cdc.

o-tolidine-. is allowed in any 2 hours during an 8-hour workday. gloves. coke oven emissions. Enforcement of the court decision began on June 30. OSHA ceiling concentrations (designated by “C” preceding the value) must not be exceeded during any part of the workday. For example.1000 which were in effect before 1989. 1993. The “[skin]” designation indicates the potential for dermal absorption. or fibers/cm3 (fibers per cubic centimeter). and Appendix G (page 362) lists the OSHA PELS that were vacated on June 30. mg/m3.established in 1971. 1993 are indicated by the symbol “†” following OSHA in this section and previous values (the PELs that were vacated) are listed in Appendix G (page 362). and tungsten carbide (cemented). cotton dust. carbon black. In addition.g. the various chromium compounds (chromic acid and chromates. Measurement Methods The section provides a source (NIOSH or OSHA) and the corresponding method number for measurement methods which can be used to determine the exposure for the chemical or xii .. if instantaneous monitoring is not feasible. Appendix F (page 361) contains information regarding the OSHA PEL for benzene and IDLH values for four chloronaphthalene compounds. TWA concentrations for OSHA PELs must not be exceeded during any 8-hour workshift of a 40-hour workweek. beryllium. NIAX® Catalyst ESN. ethylene dibromide) that have PEL ceiling values that must not be exceeded except for specified excursions. coal tar pitch volatiles. violations of the “general duty clause” as contained in Section 5(a) (1) of the Occupational Safety and Health Act may be considered when worker exposures exceed the 1989 PELs for the 164 substances that were not previously regulated. A STEL is designated by “ST” preceding the value and is measured over a 15-minute period unless noted otherwise. chromium(II) and chromium(III) compounds. various dyes (benzidine-. a “5-minute maximum peak in any 2 hours” means that a 5-minute exposure above the ceiling value. trichloroethylene. Appendix D (page 350) contains a brief discussion of substances included in the Pocket Guide with no established RELs at this time. but never above the maximum peak. skin exposure should be prevented as necessary through the use of good work practices. Concentrations are given in ppm. and Z-3 of 29 CFR 1910. mppcf (millions of particles per cubic foot of air as determined from counting an impinger sample). asbestos. goggles. there are a number of substances from Table Z-2 (e. Z-2. The appeals court also vacated new PELs for 164 substances that were not previously regulated. and other appropriate equipment. lead. The substances for which OSHA PELs were vacated on June 30. chloroethanes. 1993. Although OSHA is currently enforcing exposure limits in Tables Z-1. the ceiling must be assessed as a 15-minute TWA exposure. and o-dianisidine-based). mineral dusts. The “(total)” designation indicates that the REL or PEL listed is for "total particulate" versus the “(resp)” designation which refers to the “respirable fraction” of the airborne particulate. coveralls. Appendix B (page 344) contains a brief discussion of substances regulated as carcinogens by OSHA. and chromium metal). Appendix C (page 345) contains more detailed discussions of the specific exposure limits for certain low-molecular-weight aldehydes.

...P.... Specific gravity at 68°F* referenced to water at 39.... Molecular weight BP...Boiling point at 1 atmosphere..... % by weight (i.. Chemical and Physical Properties The following abbreviations are used for the chemical and physical properties given for each substance... However..... Vapor pressure at 68°F*..gov/niosh/nmam]) and supplements... closed cup (unless annotated “(oc)” for open cup)....... Note that some methods are only partially evaluated and have been used in very limited sampling situations..cdc.e... eV (electron volts) (Ionization potentials are given as a guideline for the selection of photoionization detector lamps used in some direct-reading instruments... and a question mark (?) indicates that it is unknown..... Physical Description A brief description of the appearance and odor of each substance is provided in the physical description section... °F xiii ... °F IP. the temperature at which the liquid phase gives off enough vapor to flash when exposed to an external ignition source)..) Sp........ Ionization potential. Melting point for solids... Flash point (i. volume 4)].gov/dts/sltc/methods)..... the method may not have been fully optimized to meet the specific sampling situation.... and supplements of the NIOSH Manual of Analytical Methods..... volumes.. 94-113 [http://www.. Notations are made as to whether a substance can be shipped as a liquefied compressed gas or whether it has major use as a pesticide........... g/100 ml) Fl.... Table 1 (page xvii) lists the editions. “NA” indicates that a property is not applicable.. “approx” indicates approximately FRZ......2°F (4°C) RGasD…...... Review the details of the method and consult with the laboratory performing the analysis regarding the applicability of the method and the need for further modifications to the method in order to adjust for the particular conditions.. Freezing point for liquids and gases.... °F Sol.... Relative density of gases referenced to air = 1 (indicates how many times a gas is heavier than air at the same temperature) VP.... The OSHA methods are from the OSHA Web site (http://www... “None available” means that no method is available from NIOSH or OSHA..osha-slc... mm Hg........g. If a different edition of the NIOSH Manual of Analytical Methods is cited. Unless otherwise noted.. MW.. the volume number are noted [e..Gr........ the appropriate edition and. the NIOSH methods are from the 4th edition of the NIOSH Manual of Analytical Methods (DHHS [NIOSH] Publication No.. °F MLT... Solubility in water at 68°F*...... where applicable. II-4 (2nd edition......e...substance......... Each method listed is the recommended method for the analysis of the compound of interest.........

...… Recommends the need for eyewash fountains and/or quick drench facilities. Fl..... g/m3 (when available) *If noted after a specific entry. however......... Lower explosive (flammable) limit in air.106) were used to classify flammable or combustible liquids: Class IA flammable liquid. Class IIIB combustible liquid.. Personal Protection and Sanitation This section presents a summary of recommended practices for each substance... or smoking where chemicals are used) and should be followed if additional controls are needed after using all feasible process........ Recommends whether routine changing of clothing is needed..... These recommendations supplement general work practices (e.. Fl.. or for which NIOSH has previously provided respirator recommendations (e...... drinking... PROVIDE…. Table 2 (page xviii) explains the codes used.....P at or above 200°F. Advises workers when to remove clothing that has accidentally become wet or significantly contaminated......... Fl...... Fl..... Upper explosive (flammable) limit in air.......P at or above 100°F and below 140°F. 186 chemicals listed in xiv .......g......P below 73°F and BP below 100°F.... CHANGE……. before eating). Each category is described as follows: SKIN……….....… Recommends the need for eye protection....P at or above 73°F and below 100°F..P at or above 140°F and below 200°F.. in criteria documents or Current Intelligence Bulletins) for certain chemicals. equipment....g...g....... Class II combustible liquid. WASH SKIN…… Recommends when workers should wash the spilled chemical from the body in addition to normal washing (e.. no eating.......... Minimum explosive concentration..... REMOVE…. The following OSHA criteria (29 CFR 1910. Class IB flammable liquid...... these properties may be reported at other temperatures. Class IIIA combustible liquid...... Fl......UEL.. EYES…………............. % by volume (at room temperature*) LEL..... the flammability/combustibility of a substance is listed at the bottom of the chemical and physical properties section.... % by volume (at room temperature*) MEC..... When available. Fl... Recommendations for Respirator Selection This section provides a condensed table of allowable respirators to be used for those substances for which IDLH values have been determined..... Class IC flammable liquid.…… Recommends the need for personal protective clothing................P below 73°F and BP at or above 100°F.. There are... and task controls...

See Table 4 (page xxv) for information concerning the selection of N-. Individual respirator classes are separated by diagonal lines (/). The symbol “§” is followed by the classes of respirators that are acceptable for emergency or planned entry into unknown concentrations or entry into IDLH conditions. particulate-filter respirators. but now these respirators may be selected regardless of the warning properties.134(d)(3)(iii)]. are listed in Table 3 (page xx).] In 1995. these recommendations will be revised in future editions. The new Part 84 respirators have passed a more demanding certification test than the old respirators (e.html) and will be incorporated into subsequent editions of the Pocket Guide. R-. Among the provisions in the revised standard is the requirement for an end-of-service-life indicator (ESLI) or a change schedule when air-purifying respirators with chemical cartridges or canisters are used for protection against gases and vapors [29 CFR 1910. airpurifying particulate respirators have been updated from previous editions of the Pocket Guide to incorporate Part 84 respirators. mist. The first line in the entry indicates whether the “NIOSH” or the “OSHA” exposure limit is used on which to base the respirator recommendations. pesticide) certified under 30 CFR 11 (also referred to as “Part 11”). The more protective limit between the NIOSH REL or the OSHA PEL is always used. dust and mist. More protective respirators may be worn. Recommendations for non-powered.) In the Pocket Guide. (Updated information on the Pocket Guide can be found on the NIOSH Web site (http://www. In January 1998. air-purifying. or P-series (Part 84) particulate respirators. Codes for the various categories of respirators. Appendix A (page 342) lists the NIOSH carcinogen policy. Each subsequent line lists a maximum use concentration (MUC) followed by the classes of respirators that are acceptable for use up to the MUC. dust.cdc. Part 11 terminology has been removed. OSHA revised its respiratory protection standard (29 CFR 1910. [Appendix F (page 361) contains an explanation of the “Effective” IDLHs used for four chloronaphthalene compounds. and fume. Respirator recommendations in the Pocket Guide have not been revised in this edition to reflect the OSHA requirements for ESLIs or change schedules.gov/niosh/npg/npg.g. (Note: All respirator codes containing “Ccr” or “Ov” are covered by this requirement. the Pocket Guide does not provide respiratory recommendations for those 186 chemicals without IDLH values.the Pocket Guide for which IDLH values have yet to be determined.134). and Assigned Protection Factors (APFs) for these respirators. dust. Respirator recommendations for carcinogens in the Pocket Guide have not been revised to reflect this policy. Since the IDLH value is a critical component for completing the Respirator Selection Logic for a given chemical. As new or revised IDLH values are developed for those and other chemicals.. “NIOSH/OSHA” indicates that the limits are equivalent. NIOSH will provide appropriate respirator recommendations. NIOSH developed a new set of regulations in 42 CFR 84 (also referred to as “Part 84”) for testing and certifying non-powered. “Escape” indicates that the respirators are to be used only xv . air-purifying respirators (without ESLIs) for protection against gases and vapors are recommended only for chemicals with adequate warning properties. spray paint.

The current listing of NIOSH/MSHA certified respirators can be found in the NIOSH Certified Equipment List. which are available on the Respirator Topic Page on the NIOSH Web site (http://www.cdc. Abbreviations are defined in Table 6 (page xxviii). fit-testing. cleaning. fit-checking.cdc. Symptoms. the types of cancer are listed in brackets). and they are not to be used in IDLH conditions. A complete respiratory protection program must be implemented and must fulfill all requirements of 29 CFR 1910. this choice should be made only by a knowledgeable person. For each MUC or condition. All respirators selected must be approved by NIOSH under the provisions of 42 CFR 84. Exposure Routes. medical monitoring. REMEMBER: Air-purifying respirators will not protect users against oxygen-deficient atmospheres. xvi . First Aid This section lists emergency procedures for eye and skin contact. 87-116).134. which is available on the NIOSH Web site (http://www. Information in this section reflects human data unless otherwise noted. maintenance. The third row lists target organs (TO) affected by exposure to the substance (for carcinogens. storage and periodic program evaluation.gov/niosh/npptl/topics/respirators/cel). The second row lists the potential symptoms of exposure (SY) and whether NIOSH considers the substance a potential occupational carcinogen ([carc]).gov/niosh/npptl/topics/respirators).for escape purposes. The only respirators recommended for fire fighting are self-contained breathing apparatuses that have full facepieces and are operated in a pressure-demand or other positive-pressure mode. Selection of a specific respirator within a given class of recommended respirators depends on the particular situation. inhalation. this entry lists only those respirators with the required APF and other use restrictions based on the NIOSH Respirator Selection Logic. and Target Organs The first row for each substance in this section lists the toxicologically important entry routes (ER) and whether contact with the skin or eyes is potentially hazardous. Incompatibilities and Reactivities This section lists important hazardous incompatibilities or reactivities for each substance. A respiratory protection program must include a written standard operating procedure covering regular training. inspection. Additional information on the selection and use of respirators can be found in the NIOSH Respirator Selection Logic (DHHS [NIOSH] Publication No. Abbreviations are defined in Table 5 (page xxvi). and ingestion of the toxic substance. periodic environmental monitoring. 2005-100) and the NIOSH Guide to Industrial Respiratory Protection (DHHS [NIOSH] Publication No.

77-157-A 77-157-B 77-157-C 78-175 79-141 80-125 82-100 84-100 85-117 87-117 89-127 90-121 94-113 96-135 98-119 2003-154 See Measurement Methods section on page xii for more information. The NIOSH Manual of Analytical Methods is available on the NIOSH Web site (http://www. xvii .gov/niosh/nmam).cdc.Table 1 NIOSH Manual of Analytical Methods Edition 2 2 2 2 2 2 2 3 3 3 3 3 4 4 4 4 1 2 3 1 2 3 4 Volume 1 2 3 4 5 6 7 Supplement Publication No.

No recommendation is made specifying the need for removing clothing that becomes wet or contaminated. The worker should immediately wash the skin when it becomes contaminated. Wash skin: When contam Daily N.Table 2 Personal Protection and Sanitation Codes Code Skin: Prevent skin contact Definition Wear appropriate personal protective clothing to prevent skin contact. No recommendation is made specifying the need for washing the substance from the skin (either immediately or at the end of the work shift). No recommendation is made specifying the need for eye protection. etc. Work clothing that becomes wet should be immediately removed due to its flammability hazard (i. Frostbite N. and prior to eating. When wet or contam When wet (flamm) N.R Eyes: Prevent eye contact Frostbite N. No recommendation is made specifying the need for personal protective equipment for the body. smoking..R. Wear appropriate eye protection to prevent eye contact with the liquid that could result in burns or tissue damage from frostbite. for liquids with a flash point <100°F).e. The worker should wash daily at the end of each work shift. Compressed gases may create low temperatures when they expand rapidly. Work clothing that becomes wet or significantly contaminated should be removed and replaced.R. Wear appropriate eye protection to prevent eye contact. Wear appropriate personal protective clothing to prevent the skin from becoming frozen. Remove: xviii . drinking.R. Leaks and uses that allow rapid expansion may cause a frostbite hazard.

No recommendation is made specifying the need for the worker to change clothing after the workshift.Table 2 (Continued) Personal Protection and Sanitation Codes Code Change: Daily Definition Workers whose clothing may have become contaminated should change into uncontaminated clothing before leaving the work premises. Facilities for quickly drenching the body should be provided within the immediate work area for emergency use where there is a possibility of exposure. Provide: Eyewash Quick drench Frostbite wash Other codes: Liq Molt Sol Soln Vap xix . Eyewash fountains should be provided in areas where there is any possibility that workers could be exposed to the substances.] Quick drench facilities and/or eyewash fountains should be provided within the immediate work area for emergency use where there is any possibility of exposure to liquids that are extremely cold or rapidly evaporating. the availability of water from a sink or hose could be considered adequate. this is irrespective of the recommendation involving the wearing of eye protection. [Note: It is intended that these facilities provide a sufficient quantity or flow of water to quickly remove the substance from any body areas likely to be exposed. whereas in others. In certain instances. Liquid Molten Solid Solution containing the contaminant Vapor N. The actual determination of what constitutes an adequate quick drench facility depends on the specific circumstances.R. a deluge shower should be readily available.

or where there is no REL.97% efficient. Code Components. Particulate respirator or filter that is 99. R95.Table 3 Symbols. R99. full-facepiece respirator (gas mask) with a chin-style. at any detectable concentration Emergency or planned entry into unknown concentrations or IDLH conditions Substance reported to cause eye irritation or damage. See Table 4 (page xxv) to select N100. eye protection needed Only nonoxidizable sorbents allowed (not charcoal) End of service life indicator (ESLI) required Assigned protection factor Code Component 95 99 100 Ccr F GmF Papr Sa Scba Ag Cf Hie Ov Pd. and Codes Used for Respirator Selection Symbol ¥ § * £ ¿ † APF Description At concentrations above the NIOSH REL. front. Chemical cartridge respirator Full facepiece Air-purifying. Particulate respirator or filter that is 99% efficient. See Table 4 (page xxv) to select N99. may require eye protection Substance causes eye irritation or damage. or P100.Pp Qm S T XQ Description Particulate respirator or filter that is 95% efficient. or P95. R100. air-purifying respirator Supplied-air respirator Self-contained breathing apparatus Acid gas cartridge or canister Continuous flow mode High-efficiency particulate filter Organic vapor cartridge or canister Pressure-demand or other positive-pressure mode Quarter-mask respirator Chemical cartridge or canister providing protection against the compound of concern Tight-fitting facepiece Except quarter-mask respirator xx . See Table 4 (page xxv) to select N95.or back-mounted canister Powered. or P99.

R95. 10 Any full-facepiece respirator with organic vapor cartridge(s) in combination with an N95. 95XQ 100F 100XQ CcrFAg100 CcrFOv CcrFOv95 CcrFOv100 CcrFS CcrFS100 CcrOv xxi . P100.Table 3 (Continued) Symbols. or P filters. R99. The following filters may also be used: N99. 10 Any air-purifying respirator with an N100. R100. N100. 10 Any air-purifying half-mask respirator equipped with organic vapor cartridge(s). or P filters. P100. See Table 4 (page xxv) for information on selection of N. R. See Table 4 (page xxv) for information on selection of N. R. 10 Any particulate respirator equipped with an N95. 50 Any air-purifying full-facepiece respirator equipped with organic vapor cartridge(s) in combination with an N100. R95. R100. See Table 4 (page xxv) for information on selection of N. R100. and P95 filtering facepieces) except quarter-mask respirators. R95. R100. R99. See Table 4 (page xxv) for information on selection of N. See Table 4 (page xxv) for information on selection of N. See Table 4 (page xxv) for information on selection of N. or P100 filter. R99. or P filters. 50 Any air-purifying full-facepiece respirator equipped with cartridge(s) providing protection against the compound of concern. 50 Any air-purifying. See Table 4 (page xxv) for information on selection of N. or P filters. 50 Any air-purifying full-facepiece respirator equipped with organic vapor cartridge(s). R100. P99. R. and Codes Used for Respirator Selection Code 95F APF Description 10 Any air-purifying full-facepiece respirator equipped with an N95. or P filters. R100. or P filters. R. R. or P100 filter. The following filters may also be used: N99. or P100 filter. R100. R95. R100. or P100 filter. N100. P99. R. R. Code Components. or P filters. or P95 filter. or P95 filter. P100. and P100 filtering facepieces) except quarter-mask respirators. R. The following filters may also be used: N99. or P filters. R100. or P100 filter (including N100. full-facepiece respirator with an N100. 50 Any air-purifying full-facepiece respirator equipped with cartridge(s) providing protection against the compound of concern in combination with an N100. See Table 4 (page xxv) for information on selection of N. N100. P99. or P95 filter (including N95. 50 Any chemical cartridge respirator with a full facepiece and acid gas cartridge(s) in combination with an N100.

R. See Table 4 (page xxv) for information on selection of N. R. The following filters may also be used: N99. and Codes Used for Respirator Selection Code CcrOv95 APF Description 10 Any air-purifying half-mask respirator with organic vapor cartridge(s) in combination with an N95. See Table 4 (page xxv) for information on selection of N.or back-mounted acid gas canister. R99. or P100 filter. 10 Any air-purifying. or P filters.or back-mounted canister providing protection against the compound of concern. P99. Code Components. full facepiece respirator (gas mask) with a chin-style. full-facepiece respirator (gas mask) with a chin-style. or P95 filter. R. 10 Any air-purifying half-mask respirator equipped with cartridge(s) providing protection against the compound of concern. P99. or P100 filter. CcrOv100 CcrOvAg CcrS GmFAg GmFAg100 GmFOv GmFOv95 GmFOv100 GmFOvAg GmFOvAg100 GmFS xxii .or back-mounted organic vapor canister having an N100. P100. or P filters. front.or back-mounted acid gas canister having an N100. or P filters. front. The following filters may also be used: N99. or P95 filter. See Table 4 (page xxv) for information on selection of N. R. See Table 4 (page xxv) for information on selection of N. 10 Any air-purifying half-mask respirator equipped with organic vapor and acid gas cartridge(s). R. See Table 4 (page xxv) for information on selection of N. 50 Any air-purifying. or P filters.or back-mounted organic vapor canister in combination with an N95.or back-mounted organic vapor canister. front. front. R100. or P filters. R100. front. full-facepiece respirator (gas mask) with a chin-style. 10 Any air-purifying half-mask respirator with organic vapor cartridge(s) in combination with an N100. or P100 filter. full-facepiece respirator (gas mask) with a chin-style. N100. R99. 50 Any air-purifying. front. full-facepiece respirator (gas mask) with a chin-style. R100. full facepiece respirator (gas mask) with a chin-style. 50 Any air-purifying. R95. 50 Any air-purifying. See Table 4 (page xxv) for information on selection of N. full-facepiece respirator (gas mask) with a chin-style. or P100 filter. 50 Any air-purifying. or P filters. R100. R100. N100. P100. 50 Any air-purifying. R. R95.Table 3 (Continued) Symbols.or back-mounted organic vapor and acid gas canister. R100. front. front. full-facepiece respirator (gas mask) with a chin-style.or back-mounted organic vapor and acid gas canister having an N100. 50 Any air-purifying.

Any supplied-air respirator operated in a pressure-demand or other positive-pressure mode. See Table 4 (page xxv) for information on selection of N.000 xxiii . R100. full-facepiece respirator (gas mask) with a chin-style. and Codes Used for Respirator Selection Code GmFS100 APF 50 Description Any air-purifying.Pp 5 10 25 1. R. See Table 4 (page xxv) for information on selection of N. Any powered air-purifying respirator with cartridge(s) providing protection against the compound of concern. Any powered air-purifying respirator with an organic vapor cartridge in combination with a high-efficiency particulate filter. R. Code Components. Any powered air-purifying respirator with a tight-fitting facepiece and cartridge(s) providing protection against the compound of concern. PaprAg PaprAgHie PaprHie PaprOv PaprOvAg PaprOvHie PaprS PaprTHie PaprTOv PaprTOvHie 25 25 25 25 25 25 25 50 50 50 PaprTS 50 Qm Sa Sa:Cf Sa:Pd. Any quarter-mask respirator. Any powered air-purifying respirator with organic vapor and acid gas cartridge(s). Any supplied-air respirator. or P100 filter. or P filters. Any powered air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s). or P particulate filters. Any powered air-purifying respirator with a high-efficiency particulate filter. Any powered air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter.or back-mounted canister providing protection against the compound of concern and having an N100. Any supplied-air respirator operated in a continuous-flow mode. front.Table 3 (Continued) Symbols. Any powered air-purifying respirator with acid gas cartridge(s) in combination with a high-efficiency particulate filter. Any powered air-purifying respirator with organic vapor cartridge(s). Any powered air-purifying respirator with a tight-fitting facepiece and organic vapor cartridge(s) in combination with a high-efficiency particulate filter. Any powered air-purifying respirator with acid gas cartridge(s).

SaT:Cf ScbaE ScbaF ScbaF:Pd.000 Description Any supplied-air respirator with a full facepiece. Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive pressure mode. self-contained breathing apparatus. Code Components.Pp:AScba APF 50 2. 10. 50 Any self-contained breathing apparatus with a full facepiece.000 Any supplied-air respirator that has a full-facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.Table 3 (Continued) Symbols. 50 Any supplied-air respirator that has a tight-fitting facepiece and is operated in a continuous-flow mode. Any appropriate escape-type. and Codes Used for Respirator Selection Code SaF SaF:Pd. 10.000 Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode.Pp xxiv .Pp SaF:Pd.

.e. 95%. The choice of facepiece depends on the level of protection needed – that is.Table 4 Selection of N-.g. glycerine) are present.. and P-series filters depends on the presence of oil particles as follows: ● If no oil particles are present in the work environment. use the following guide: N for Not resistant to oil. use a filter of any series (i. The selection of N-. 3. the assigned protection factor (APF) needed. See Table 3 (page xx) for APFs of respirator classes. cutting fluids. R for Resistant to oil. use an ● R. or P-Series Particulate Respirators 1. R-.. If oil particles (e. or P-series). ● If oil particles are present and the filter is to be used for more than one work shift. N-. xxv . lubricants. Higher filter efficiency means lower filter leakage. and see Recommendations for Respirator Selection (page xiv) for more information. Selection of filter efficiency (i. R-. Note: To help you remember the filter series. or 99.e. 2. Note: N-series filters cannot be used if oil particles are present. R-.7%) depends on how much filter leakage can be accepted. P for oil Proof. use only a P-series filter.or P-series filter. 99%.

Symptoms.Table 5 Abbreviations for Exposure Routes. and Target Organs Code abdom abnor abs album anes anor anos anxi arrhy aspir asphy BP breath bron BUN [carc] card chol cirr CNS conc con conf conj constip convuls corn CVS cyan decr depres derm diarr dist Definition Abdominal Abnormal/Abnormalities Skin absorption Albuminuria Anesthesia Anorexia Anosmia (loss of the sense of smell) Code dizz drow dysp emphy eosin epilep epis equi eryt euph fail fasc FEV fib ftg func GI halu head hema hemato hemorr hypox inco incr inebri inflamm Definition Dizziness Drowsiness Dyspnea (breathing difficulty) Emphysema Eosinophilia Epileptiform Epistaxis (nosebleed) Equilibrium Erythema (skin redness) Euphoria Failure Fasciculation Forced expiratory volume Fibrosis Fatigue Function Gastrointestinal Hallucinations Headache Hematuria (blood in the urine) Hematopoietic Hemorrhage Hypoxemia (reduced O2 in the blood) Incoordination Increased Inebriation Inflammation Ingestion Inhalation Injury Insomnia Irregular/Irregularities Irritation Anxiety Arrhythmias Aspiration Asphyxia Blood pressure Breath/breathing Bronchitis Blood urea nitrogen Potential occupational carcinogen Cardiac Cholinesterase Cirrhosis Central nervous system Concentration Skin and/or eye contact Confusion Conjunctivitis Constipation Convulsions Corneal Cardiovascular system Cyanosis Decreased Depressed/Depression Dermatitis Diarrhea Disturbance hyperpig Hyperpigmentation ing inh inj insom irreg irrit xxvi .

Symptoms. exhaustion) Leukocytosis (increased blood leukocytes) Leukopenia (reduced blood leukocytes) Code prot pulm RBC repro resp Definition Proteinuria Pulmonary Red blood cell Reproductive Respiratory/respiration Retrosternal (occurring behind the sternum) Rhinorrhea (discharge of thin nasal mucus) Salivation Sensitization Shortness Sneezing Solid Solution Substernal (occurring beneath the sternum) Sweating Swelling System Tachycardia Tenderness Teratogenic Throbbing Tightness Twitching Unconsciousness Vapor Vesiculation Visual Vomiting Weak/weakness Wheezing restless Restlessness retster rhin salv sens short sneez sol soln subs sweat swell sys tacar tend terato throb tight twitch uncon vap vesic vis vomit weak wheez Liquid Localized Weight loss Malaise (vague feeling of discomfort) Malnutrition Methemoglobinemia Mucous membrane Muscle Narcosis Nausea Necrosis Nephritis Numb/numbness Opacity Palpitations Paralysis Paresthesia Perforation Peripheral neuropathy Periorbital (situated around the eye) Pharyngeal Photophobia (abnormal visual intolerance to light) Pneumonitis Polyneuropathy musc narco nau nec neph numb opac palp para pares perf peri neur periorb phar photo pneu polyneur xxvii .Table 5 (Continued) Abbreviations for Exposure Routes. and Target Organs Code irrity jaun kera lac lar lass leucyt leupen liq local low-wgt mal malnut methemo muc memb Definition Irritability Jaundice Keratitis (inflammation of the cornea) Lacrimation (discharge of tears) Laryngeal Lassitude (weakness.

If irritation. promptly wash (irrigate) the eyes with large amounts of water. get medical attention. get medical attention. If this chemical (or liquids containing this chemical) contacts the skin. gently blot or brush away excess. Get medical attention. Get medical attention immediately. If frostbite has NOT occurred. occasionally lifting the lower and upper lids. If this chemical or liquids containing this chemical penetrate the clothing. If irritation persists after washing. promptly remove the clothing and flush the skin with water. dust it off immediately and then flush the contaminated skin with water. seek medical attention immediately. In order to prevent further tissue damage. swelling. If this chemical penetrates the clothing. Get medical attention immediately. Irr prompt Frostbite Medical attention Skin: Blot/brush away Dust off solid. if tissue is not frozen. If irritation occurs. seek medical attention immediately. lacrimation. If this chemical penetrates the clothing. promptly flush the contaminated skin with soap and water. immediately wash (irrigate) the eyes with large amounts of water. If this chemical or liquids containing this chemical penetrate the clothing. Get medical attention immediately. immediately and thoroughly wash contaminated skin with soap and water. If irritation persists after washing. If this molten chemical contacts the skin. or photophobia persist.Table 6 Codes for First Aid Data Code Eye: Irr immed Definition If this chemical contacts the eyes. If eye tissue is frozen. If this solid chemical contacts the skin. immediately remove the clothing and flush the skin with water. do NOT rub the affected areas or flush them with water. immediately flush the contaminated skin with soap and water. pain. If this chemical contacts the skin. immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes. immediately flush the skin with large amounts of water. get medical attention. occasionally lifting the lower and upper eyelids. do NOT attempt to remove frozen clothing from frostbitten areas. immediately remove the clothing and wash the skin with soap and water. If irritation persists after washing. If frostbite has occurred. If this chemical contacts the eyes. Get medical attention if any discomfort continues. promptly remove the clothing and flush the skin with water. If this chemical contacts the skin. get medical attention as soon as possible. promptly wash the contaminated skin with soap and water. occasionally lifting the lower and upper lids. water flush Frostbite Molten flush immed/ sol-liq soap wash prompt Soap flush immed Soap flush prompt xxviii .

Get medical attention promptly. If this chemical penetrates the clothing. promptly remove the clothing and wash the skin with water. immediately flush the affected area with large amounts of water to remove heat. If irritation persists after washing. If this chemical contacts the skin. If this chemical contacts the skin. If symptoms occur after washing. promptly wash the contaminated skin with soap and water. If this chemical contacts the skin. get medical attention.Table 6 (Continued) Codes for First Aid Data Code Skin (continued): Soap prompt/molten flush immed Definition If this solid chemical or a liquid containing this chemical contacts the skin. get medical attention. If irritation persists after washing. wash the contaminated skin with soap and water. immediately remove the clothing and flush the skin with water promptly. If irritation persists after washing. If this chemical contacts the skin. immediately wash the contaminated skin with soap and water. get medical attention. flush the contaminated skin with water. Soap wash Soap wash immed Soap wash prompt Water flush Water flush immed Water flush prompt Water wash Water wash immed Water wash prompt xxix . Where there is evidence of skin irritation. immediately wash the contaminated skin with water. If this chemical contacts this skin. promptly remove the clothing and wash the skin with soap and water. promptly wash the contaminated skin with water. If this chemical penetrates the clothing. If this chemical penetrates the clothing. flush the contaminated skin with water promptly. wash the skin with soap and water. If this chemical contacts the skin. If this molten chemical contacts the skin or nonimpervious clothing. If this chemical contacts the skin. immediately flush the contaminated skin with water. and get medical attention promptly. wash the contaminated skin with water. immediately remove the clothing. get medical attention immediately. immediately remove the clothing and wash the skin with water. Get medical attention immediately. If this chemical contacts the skin. If this chemical penetrates the clothing. promptly wash the contaminated skin with soap and water. If this chemical contacts the skin. If this chemical penetrates the clothing. If this chemical penetrates the clothing. immediately remove the clothing and flush the skin with water. Get medical attention promptly. get medical attention.

perform artificial respiration. perform artificial respiration. get medical attention immediately. properly trained personnel may assist the affected person by administering 100% oxygen. If breathing has stopped. If breathing has stopped. If a person breathes large amounts of this chemical. move the exposed person to fresh air at once. If this chemical has been swallowed. Get medical attention as soon as possible. Get medical attention as soon as possible. When breathing is difficult. If a person breathes large amounts of this chemical.Table 6 (Continued) Codes for First Aid Data Code Breath: Resp support Definition If a person breathes large amounts of this chemical. 100% O2 Swallow: Medical attention immed xxx . Fresh air Fresh air. Keep the affected person warm and at rest. move the exposed person to fresh air at once. Keep the affected person warm and at rest. Other measures are usually unnecessary. move the exposed person to fresh air at once.

CHEMICAL LISTING 1 .

Pp/SaF:Pd.P: -36°F Remove: When wet (flamm) IP: 10. phenols. fruity odor.Pp/SaF:Pd. black skin.0% Class IA Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. terato effects. phar edema. Often used in an aqueous solution. eye. Methanecarboxylic acid [Note: Can be found in concentrations of 5-8% in vinegar. resp sys. 2789 132 (>80% acid) Synonyms/Trade Names: Acetic acid (aqueous). throat. vinegar-like odor.R.] Exposure Routes. HCN.] Exposure Routes. throat. repro. dental Skin: Water flush immed erosion. alcohols. Sp.22 eV Change: N. bases. 3507 See Appendix A OSHA 68 See Appendix C (Aldehydes) Physical Description: Colorless liquid or gas (above 69°F) with a pungent. skin burns.9% LEL: 4.05 Provide: Eyewash (>5%) VP: 11 mmHg FRZ: 62°F Quick drench (>50%) UEL(200°F): 19.80 mg/m3 DOT: 1089 129 Synonyms/Trade Names: Acetic aldehyde. CNS.P: 103°F GmFOv/ScbaF/SaF Remove: When wet or contam (>10%) §: ScbaF:Pd. Glacial acetic acid (pure compound). Ethanal.Gr: 1. eye. repro sys [in animals: nasal cancer] Swallow: Medical attention immed Acetaldehyde Formula: CAS#: RTECS#: IDLH: CH3COOH 64-19-7 AF1225000 50 ppm Conversion: 1 ppm = 2. Con Eye: Irr immed SY: Irrit eyes. kidneys. Symptoms. skin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 60. ammonia & amines. conj. Skin: Water flush prompt Breath: Resp support delayed pulm edema. Ing. resp sys. teeth Acetic acid 2 . easily undergoes polymerization.46 mg/m3 DOT: 2790 153 (10-80% acid). skin burns. derm. in animals: kidney. 2538. Symptoms.1 NIOSH Skin: Prevent skin contact BP: 69°F ¥: ScbaF:Pd. conj. Sp. hyperkeratosis.66 eV Escape: GmFOv/ScbaE Change: N. Ethyl aldehyde Exposure Limits: Measurement Methods NIOSH REL: Ca OSHA PEL†: TWA 200 ppm (360 mg/m3) (see Table 1): NIOSH 2018.79 Provide: Eyewash VP: 740 mmHg FRZ: -190°F Quick drench UEL: 60% LEL: 4. ketones. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 44. chronic bron Breath: Resp support Swallow: Medical attention immed TO: Eyes. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Con Eye: Irr immed SY: Irrit eyes. [carc] TO: Eyes. skin.Gr: 0. sodium peroxide & nitric acid). skin. nose.A CAS#: RTECS#: IDLH: Formula: 75-07-0 AB1925000 Ca [2000 ppm] CH3CHO Conversion: 1 ppm = 1. lac.R. H2S [Note: Prolonged contact with air may cause formation of peroxides that may explode and burst containers. skin sens. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.1 NIOSH/OSHA Skin: Prevent skin contact (>10%) BP: 244°F 50 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam (>10%) Fl.Pp:AScba IP: 10.Pp:AScba Eyes: Prevent eye contact Sol: Miscible Escape: GmFOv/ScbaE Wash skin: When contam Fl. [Note: Pure compound is a solid below 62°F. Ethanoic acid.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (25 mg/m3) OSHA PEL: TWA 10 ppm (25 mg/m3) 3 NIOSH 1603 ST 15 ppm (37 mg/m ) OSHA ID186SG Physical Description: Colorless liquid or crystals with a sour. cough. CNS depres.0% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers (especially chromic acid. acids. strong caustics [Note: Corrosive to metals. nose.

amines. resp sys CAS#: RTECS#: IDLH: Formula: 67-64-1 AL3150000 2500 ppm [10%LEL] (CH3)2CO Conversion: 1 ppm = 2. Acetic anhydride A Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 102.7% Class II Combustible Liquid Incompatibilities and Reactivities: Water.8% LEL: 2. pungent. Ing. resp sys. corn edema. Acetic oxide.Pp:AScba Remove: When wet (flamm) Fl. mint-like odor. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 102 Physical Description: Colorless liquid with a strong. Skin: Water flush immed Breath: Resp support dysp. Symptoms. Symptoms. Con SY: Conj. dizz. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 58. skin.08 VP: 4 mmHg Quick drench FRZ: -99°F UEL: 10.00 eV Escape: GmFOv/ScbaE Provide: Eyewash Sp. opac.Gr: 0. Reacts with water to form acetic acid. strong oxidizers (especially chromic acid).Pp:AScba Change: N.3% LEL: 2. acids Exposure Routes.P: 0°F Escape: GmFOv/ScbaE Change: N.1 2500 ppm: CcrOv*/PaprOv*/GmFOv/ Eyes: Prevent eye contact BP: 133°F Wash skin: When contam Sol: Miscible Sa*/ScbaF §: ScbaF:Pd. skin burns.5% Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers.1 125 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 282°F 200 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: 12% Remove: When wet or contam Fl. lac. strong caustics [Note: Corrosive to iron. Ethanoic anhydride Exposure Limits: Measurement Methods NIOSH REL: C 5 ppm (20 mg/m3) (see Table 1): 3 NIOSH 3506 OSHA PEL†: TWA 5 ppm (20 mg/m ) OSHA 82. Ketone propane. Con Skin: Soap wash immed SY: Irrit eyes. steel & other metals. CNS Swallow: Medical attention immed Acetone 3 . throat. 2-Propanone Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 250 ppm (590 mg/m3) 3 NIOSH 1300. cough. Ing. skin. nasal.18 mg/m3 DOT: 1715 137 Synonyms/Trade Names: Acetic acid anhydride. derm Breath: Resp support TO: Eyes.P: 120°F ScbaF/SaF §: ScbaF:Pd. head.79 VP: 180 mmHg FRZ: -140°F UEL: 12. photo. sens derm Swallow: Medical attention immed TO: Eyes. alcohols. IP: 10. vinegar-like odor. bron.] Exposure Routes. nose. 2555. CNS depres. 3800 OSHA PEL†: TWA 1000 ppm (2400 mg/m ) OSHA 69 Physical Description: Colorless liquid with a fragrant.Pp/SaF:Pd.38 mg/m3 DOT: 1090 127 Synonyms/Trade Names: Dimethyl ketone. phar irrit. vesic.R. IP: 9.R.CAS#: RTECS#: IDLH: Formula: 108-24-7 AK1925000 200 ppm (CH3CO)2O Conversion: 1 ppm = 4.Pp/SaF:Pd. Acetyl oxide. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.69 eV Sp.Gr: 1.

78 VP: 73 mmHg FRZ: -49°F UEL: 16.P: 165°F 250 ppm: SaF:Pd. CVS.1 200 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 179°F 500 ppm: Sa:Cf/PaprOv/CcrFOv/GmFOv/ Wash skin: When contam Sol: Miscible Remove: When wet (flamm) Fl. liver. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. caustics [Note: Slowly decomposes to acetone & HCN at room temperatures. lass. Skin: Water flush immed Breath: Resp support kidney inj. conf. liver.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 85.48 mg/m3 Formula: CAS#: CH3C(OH)CNCH3 75-86-5 DOT: 1541 155 (stabilized) RTECS#: OD9275000 IDLH: N. nau.Pp:AScba Provide: Eyewash Sp.93 Escape: GmFOv/ScbaE VP: 0. chest pain. 2-Hydroxy-2-methyl-propionitrile.] Exposure Routes. lass. or temperature. rate is accelerated by an increase in pH. Ethyl nitrile.R. pulm edema. convuls. kidneys Acetonitrile 4 . resp sys. Symptoms.8 mmHg Quick drench FRZ: -4°F UEL: 12. vomit.20 eV Escape: GmFOv/ScbaE Provide: Quick drench Sp. head.A Acetone cyanohydrin Conversion: 1 ppm = 3. 2-Methyllactonitrile Exposure Limits: Measurement Methods NIOSH REL: C 1 ppm (4 mg/m3) [15-minute] (see Table 1): NIOSH 2506 OSHA PEL: none Physical Description: Colorless liquid with a faint odor of bitter almond. Abs. Methyl cyanide [Note: Forms cyanide in the body. Synonyms/Trade Names: Cyanohydrin-2-propanone. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. water content.68 mg/m3 DOT: 1648 127 Synonyms/Trade Names: Cyanomethane.P(oc): 42°F ScbaF/SaF §: ScbaF:Pd. [Note: Forms cyanide in the body.D. IP: ? §: ScbaF:Pd.R. CNS.Pp/SaF:Pd. α-Hydroxyisobutyronitrile. kidney damage Swallow: Medical attention immed TO: Resp sys.0% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. convuls.0% LEL: 2. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 41. Ing.Pp/SaF:Pd. throat. skin. Skin: Water flush immed Breath: Resp support in animals: liver. Ing. kidneys. GI tract CAS#: RTECS#: IDLH: Formula: 75-05-8 AL7700000 500 ppm CH3CN Conversion: 1 ppm = 1.1 10 ppm: Sa Eyes: Prevent eye contact BP: 203°F 25 ppm: Sa:Cf Wash skin: When contam Sol: Miscible 50 ppm: ScbaF/SaF Remove: When wet or contam Fl. Con Eye: Irr immed SY: Irrit eyes.0% LEL: 3. CVS. CNS. dizz.Gr(77°F): 0.Pp:AScba Change: N.Pp Change: N. resp sys.] Exposure Limits: Measurement Methods NIOSH REL: TWA 20 ppm (34 mg/m3) (see Table 1): 3 NIOSH 1606 OSHA PEL†: TWA 40 ppm (70 mg/m ) Physical Description: Colorless liquid with an aromatic odor. Abs. 2-Cyano-2-propanol.Gr: 0.2% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Sulfuric acid. stupor. Con Eye: Irr immed SY: Irrit nose. asphy Swallow: Medical attention immed TO: Eyes. asphy. skin. IP: 12. liver.

D.91 Provide: Frostbite wash VP: 44.Pp/SaF:Pd. 2-Fluorenylacetamide Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): See Appendix A None available OSHA PEL: [1910. Symptoms. Ethyne [Note: A compressed gas used in the welding & cutting of metals. [carc] Skin: Soap wash immed TO: Liver. oxygen & other oxidizing agents such as halogens [Note: Forms explosive acetylide compounds with copper. bladder. pancreas. bladder.P: ? See Appendix E (page 351) Change: Daily IP:? Provide: Eyewash Sp. mercury. N-Acetyl-2-aminofluorene. [Note: Commercial Acetylene Criteria Document grade has a garlic-like odor. Symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 26.] Exposure Routes. ethereal odor. kidneys.R. dizz.2 atm FRZ: -119°F (Sublimes) UEL: 100% LEL: 2. Shipped under pressure dissolved in acetone.40 eV Change: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh. silver & brasses (containing more than 66% copper). Abs.1014] See Appendix B Physical Description: Tan.3 ¥: ScbaF:Pd.D.0 Skin: Frostbite BP: Sublimes Not available.Pp:AScba Eyes: Prevent eye contact BP: ? Escape: 100F/ScbaE Wash skin: When contam/Daily Sol: Insoluble Remove: When wet or contam Fl.CAS#: RTECS#: IDLH: Formula: 53-96-3 AB9450000 Ca [N. 2-Acetaminofluorene. pancreas.06 mg/m3 DOT: 1001 116 Synonyms/Trade Names: Ethine. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. resp sys Acetylene 5 . Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 223. 2-AAF. Con (liquid) Skin: Frostbite SY: Head. Fl.Gr: ? VP: ? Quick drench MLT: 381°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. Con SY: Reduced function of liver. FAA.5% Flammable Gas Incompatibilities and Reactivities: Zinc. Ing. kidneys. Eyes: Frostbite Sol: 2% Wash skin: N. skin & pancreas] 2-Acetylaminofluorene A Formula: CAS#: RTECS#: IDLH: 74-86-2 AO9600000 N. bladder. lungs. asphy. liquid: frostbite Breath: Fresh air TO: CNS.P: NA (Gas) Remove: When wet (flamm) IP: 11.] Exposure Limits: Measurement Methods NIOSH REL: C 2500 ppm (2662 mg/m3) (see Table 1): NIOSH OSHA PEL: none Physical Description: Colorless gas with a faint. skin [in animals: tumors of Breath: Resp support Swallow: Medical attention immed the liver.] C15H13NO Conversion: DOT: Synonyms/Trade Names: AAF.R. crystalline powder. 2-FAA. HC≡CH Conversion: 1 ppm = 1. RGasD: 0.

97 VP: 0. Tetrabromoethane. Sp. Ing.Pp:AScba Wash skin: When contam Fl. 1. Symptoms. magnesium. skin. reducing metals such as aluminum. Skin: Water flush prompt Breath: Resp support CNS depres Swallow: Medical attention immed TO: Eyes.07% §: ScbaF:Pd. kidney inj Swallow: Medical attention immed TO: Eyes.] Exposure Routes. nau. Sp.Gr: 2. anor. nose. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.3% Eyes: Prevent eye contact Fl. Aspirin Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): NIOSH 0500 OSHA PEL†: none Physical Description: Odorless. resp sys. Symptoms. skin.7 OSHA Skin: Prevent skin contact BP: 474°F (Decomposes) 8 ppm: Sa/ScbaF Eyes: Prevent eye contact Sol: 0. leucyt. explosion carbonates. CNS Acetylene tetrabromide Formula: CAS#: RTECS#: IDLH: CH3COOC6H4COOH 50-78-2 VO0700000 N.02 mmHg FRZ: 32°F UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Strong caustics.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 345.2 (see Table 2): BP: 284°F (Decomposes) Skin: Prevent skin contact Not available.R. Tetrabromoacetylene. Con Eye: Irr immed SY: Irrit eyes. and zinc Exposure Routes. Conversion: DOT: Synonyms/Trade Names: o-Acetoxybenzoic acid. jaun.D. upper resp sys. liver.A Formula: CAS#: RTECS#: IDLH: CHBr2CHBr2 79-27-6 KI8225000 8 ppm Conversion: 1 ppm = 14. liver. resp sys. incr blood clotting time. hot iron. liver.Pp/SaF:Pd.Gr: 1.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 180. kidneys Acetylsalicyclic acid 6 . moisture hazard if dispersed in air. [Note: Slowly hydrolyzes in moist air to salicyclic & acetic acids. abdom pain.P: NA Escape: GmFOv/ScbaE Remove: When wet or contam IP: ? Change: N.1. head. 2-Acetoxybenzoic acid. Skin: Soap wash Breath: Resp support vomit. Sol(77°F): 0.35 Change: Daily VP: 0 mmHg (approx) Provide: Eyewash MLT: 275°F Quick drench UEL: NA LEL: NA MEC: 40 g/m3 Incompatibilities and Reactivities: Solutions of alkali hydroxides or Combustible Powder. Con Eye: Irr immed SY: Irrit eyes.2. Ing.14 mg/m3 DOT: 2504 159 Synonyms/Trade Names: Symmetrical tetrabromoethane. crystal-line powder. TBE. [Note: A solid below 32°F. strong oxidizers. nau. blood.P: NA Wash skin: When contam IP: NA Remove: N.R.2-Tetrabromoethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 NIOSH 2003 OSHA PEL: TWA 1 ppm (14 mg/m ) Physical Description: Pale-yellow liquid with a pungent odor similar to camphor or iodoform. colorless to white. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. [aspirin] [Note: Develops the vinegar-like odor of acetic acid on contact with moisture.

84 Provide: Eyewash VP: 210 mmHg FRZ: -126°F Quick drench UEL: 31% LEL: 2. alkalis. muc memb. hand sweat.50 eV Remove: When wet or contam Sp. Sp. amines [Note: Polymerizes readily unless inhibited--usually with hydroquinone.Gr: 0. drow.25 mg/m3) (see Table 1): 3 NIOSH 2501 ST 0. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.P: -15°F GmFOv/ScbaF/SaF §: ScbaF:Pd. testes.1 ppm (0.3 mg/m3 [skin] Physical Description: White crystalline. odorless solid. pares. acids. Ing.1 NIOSH/OSHA Skin: Prevent skin contact BP: 127°F 2 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Eyes: Prevent eye contact Sol: 40% Wash skin: When contam Fl.] Exposure Routes. [carc] Swallow: Medical attention immed TO: Eyes. Acrylaldehyde. PNS. ataxia.Pp/SaF:Pd. ammonia. heart Acrolein A Formula: CAS#: RTECS#: IDLH: CH2=CHCONH2 79-06-1 AS3325000 Ca [60 mg/m3] Conversion: DOT: 2074 153P Synonyms/Trade Names: Acrylamide monomer.R. musc weak. Propenamide. skin. repro sys [in animals: tumors of the lungs.Pp:AScba Sol(86°F): 216% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl.CAS#: RTECS#: IDLH: Formula: 107-02-8 AS1050000 2 ppm CH2=CHCHO Conversion: 1 ppm = 2. Acrylic amide.29 mg/m3 DOT: 1092 131P (inhibited) Synonyms/Trade Names: Acraldehyde. Allyl aldehyde.1 (see Table 2): NIOSH BP: 347-572°F (Decomposes) Skin: Prevent skin contact ¥: ScbaF:Pd. numb limbs. Abs.Pp:AScba Remove: When wet (flamm) IP: 10. PV2004 TWA 0.12 Change: Daily VP: 0. Acrylic aldehyde. decr pulm func. Ing. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms.13 eV Escape: GmFOv/ScbaE Change: N. [Note: May polymerize violently upon melting.1 ppm (0.3 ppm (0.Pp/SaF:Pd. Con Eye: Irr immed SY: Irrit eyes.P: 280°F Wash skin: When contam/Daily IP: 9.007 mmHg Provide: Eyewash MLT: 184°F Quick drench UEL: ? LEL: ? Combustible Solid (may also be Incompatibilities and Reactivities: Strong oxidizers dissolved in flammable liquids). skin. Propenal. thyroid & adrenal glands] Acrylamide 7 . Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 56.8 mg/m ) OSHA 52 See Appendix C (Aldehydes) 3 OSHA PEL†: TWA 0. chronic resp disease Swallow: Medical attention immed TO: Eyes.] Exposure Routes. delayed pulm Skin: Water flush immed Breath: Resp support edema.03 mg/m [skin] See Appendix A OSHA PEL†: TWA 0. 2-Propenamide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 OSHA 21. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 71. May form shock-sensitive peroxides over time. absent Skin: Water flush immed Breath: Resp support deep tendon reflex.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers. disagreeable odor. skin. resp sys. Con Eye: Irr immed SY: Irrit eyes.25 mg/m ) Physical Description: Colorless or yellow liquid with a piercing. lass. 2-Propenal Exposure Limits: Measurement Methods NIOSH REL: TWA 0.Gr: 1. repro effects. skin. Symptoms. CNS.

81 Change: N. lung & bowel cancer] Swallow: Medical attention immed Acrylonitrile 8 . skin. sneez. PV2005 OSHA PEL†: none Physical Description: Colorless liquid or solid (below 55°F) with a distinctive. ethylene diamine. AN. LEL: 2. Con Eye: Irr immed SY: Irrit eyes. alkalis. CVS..] First Aid (see Table 6): Exposure Routes. resp sys Acrylic acid Formula: CAS#: RTECS#: IDLH: CH2=CHCN 107-13-1 AT5250000 Ca [85 ppm] Conversion: 1 ppm = 2. Class II Combustible Liquid ethyleneimine. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. skin vesic.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 53. [carc] TO: Eyes.D. vomit.Gr: 1. liver.1 (see Table 2): NIOSH BP: 171°F Skin: Prevent skin contact ¥: ScbaF:Pd. Breath: Resp support scaling derm. head. acrid odor. Symptoms. Aqueous acrylic acid (technical grade is 94%).4% ammonium hydroxide.P: 121°F Wash skin: When contam IP: ? Remove: When wet or contam Sp. Ing.0% bromine. Cyanoethylene. chloro-sulfonic acid. liver. CH2=CHCOOH Conversion: 1 ppm = 2. Ing. skin.Pp/SaF:Pd. acids & alkalis. [Note: Shipped with an inhibitor (e.91 eV Remove: When wet (flamm) See Appendix E (page 351) Sp.95 mg/m3 DOT: 2218 132P (inhibited) Synonyms/Trade Names: Acroleic acid. Class IB Flammable Liquid may polymerize spontaneously or when heated or in presence of strong alkali. 2-Propenoic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (6 mg/m3) [skin] (see Table 1): OSHA 28. amines [Note: Unless inhibited (usually with methylhydroquinone). Con Skin: Water wash immed SY: Irrit eyes.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 72.A CAS#: RTECS#: IDLH: Formula: 79-10-7 AS4375000 N. 2-Propenenitrile. skin sens.1 (see Table 2): BP: 286°F Skin: Prevent skin contact Not available. resp sys. nau.05 Change: N. Attacks copper.1045] TWA 2 ppm C 10 ppm [15-minute] [skin] Physical Description: Colorless to pale-yellow liquid with an unpleasant odor.02% Incompatibilities and Reactivities: Oxidizers. [Note: Odor can only be detected above the PEL. asphy. Ethylenecarboxylic acid. lass. eye. amines.Gr: 0. 2-aminoethanol [Note: Corrosive to many metals. in Skin: Water flush immed Breath: Resp support animals: lung. skin burns. Target Organs (see Table 5): Eye: Irr immed ER: Inh.R. VCN. LEL: 3. Propenenitrile. CNS [brain tumors.R. dizz.P: 30°F Wash skin: When contam IP: 10. skin.] Exposure Routes. kidney inj Swallow: Medical attention immed TO: Eyes. VP: 83 mmHg Provide: Eyewash FRZ: -116°F Quick drench UEL: 17% Incompatibilities and Reactivities: Strong oxidizers.17 mg/m3 DOT: 1093 131P (inhibited) Synonyms/Trade Names: Acrylonitrile monomer. Glacial acrylic acid (98% in aqueous solution). hydroquinone) since it readily polymerizes. Abs. oleum. Symptoms. VP: 3 mmHg Provide: Eyewash FRZ: 55°F Quick drench UEL: 8. Vinyl cyanide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1604 TWA 1 ppm OSHA 37 C 10 ppm [15-minute] [skin] See Appendix A OSHA PEL: [1910.Pp:AScba Sol: 7% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl.g. Abs. kidneys. skin. Sol: Miscible Eyes: Prevent eye contact Fl.

Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Forms cyanide in the body. Swallow: Medical attention immed thyroid & adrenal glands] Formula: C12H8Cl6 DOT: 2761 151 CAS#: 309-00-2 RTECS#: IO2100000 IDLH: Ca [25 mg/m3] 9 .003% Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl.D. Skin: Soap wash immed Breath: Resp support tonic convuls. abdom pain. Con Eye: Irr immed SY: Irrit eyes.P: NA Wash skin: When contam/Daily IP: ? Remove: When wet or contam Sp. myoclonic jerks of limbs. Con Eye: Irr immed SY: Head.00008 mmHg Provide: Eyewash MLT: 219°F Quick drench UEL: NA LEL: NA Noncombustible Solid. [Note: Formerly used as an insecticide.] Adiponitrile A Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 108.Pp/SaF:Pd. nau.CAS#: RTECS#: IDLH: Formula: 111-69-3 AV2625000 N.g.4. Ing. CNS.5. acid catalysts. dysp. Symptoms.0% LEL: 1.60 Change: Daily VP: 0.4a.8-dimethanonaphthalene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 5502 TWA 0.8a-hexahydro-endo-1. liver..Gr: 1. dizz.5% 100 ppm: Sa:Cf Wash skin: When contam Fl. nitrates).. skin [in animals: tumors of the lungs. oily liquid.3.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 364. forming hydrogen cyanide. nau.97 §: ScbaF:Pd. resp sys.Pp/SaF:Pd. Tetramethylene cyanide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 4 ppm (18 mg/m3) OSHA PEL: none NIOSH Physical Description: Water-white.2 NIOSH Skin: Prevent skin contact BP: 563°F 40 ppm: Sa Eyes: Prevent eye contact Sol: 4. vomit. practically odorless. kidneys. active metals. dizz.4. Abs. sulfuric acid) [Note: Decomposes above 194°F. hema. phenol Exposure Routes.43 mg/m3 DOT: 2205 153 Synonyms/Trade Names: 1. [carc] TO: CNS. Nitriles Criteria Document [Note: A solid below 34°F. azotemia. conf.Gr: 0. head. vomit Swallow: Medical attention immed TO: Eyes. perchlorates.4-Dicyanobutane. liver. Abs. resp sys. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.9 (see Table 2): NIOSH BP: Decomposes Skin: Prevent skin contact ¥: ScbaF:Pd.] Exposure Routes. skin. acid oxidizing agents.Pp:AScba VP: 0. strong acids (e. Ing.25 mg/m [skin] Physical Description: Colorless to dark-brown crystalline solid with a mild chemical odor. skin.Pp Change: Daily Sp.10-Hexachloro-1. lass. convuls.25 mg/m [skin] See Appendix A 3 OSHA PEL: TWA 0. clonic.10. Skin: Soap wash immed Breath: Resp support blurred vision. Hexanedinitrile.4-exo-5.002 mmHg Escape: GmFOv/ScbaE FRZ: 34°F UEL: 5.7% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers (e. 1. mal. CVS Aldrin Conversion: Synonyms/Trade Names: HHDN.8. dissolved in flammable liquids. coma. Symptoms. NC(CH2)4CN Conversion: 1 ppm = 4.Pp:AScba Sol: 0.P(oc): 199°F 200 ppm: ScbaF/SaF Remove: When wet or contam IP: ? 250 ppm: SaF:Pd. Octalene.g.2. but may be Incompatibilities and Reactivities: Concentrated mineral acids.

A CAS#: RTECS#: IDLH: Formula: BA5075000 20 ppm CH2=CHCH2OH 107-18-6 Conversion: 1 ppm = 2. muc memb. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 58. magnesium. acids. or peroxides. iron & aluminum chlorides. Con Skin: Soap wash immed SY: Irrit eyes. Con SY: Eye irrit.5% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. or purple liquid with a pungent.R.05 eV §: ScbaF:Pd.63 eV Escape: GmFOv/ScbaE Change: N. Abs. Propenol. skin.1 NIOSH/OSHA Skin: Prevent skin contact BP: 205°F 20 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. oxidizers. Ing. Symptoms. unpleasant odor. amines.9% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers.] First Aid (see Table 6): Exposure Routes.Pp:AScba Remove: When wet (flamm) IP: 9. carbon tetrachloride [Note: Polymerization may be caused by elevated temperatures. nose. 1405 ST 4 ppm (10 mg/m ) [skin] 3 OSHA PEL†: TWA 2 ppm (5 mg/m ) [skin] Physical Description: Colorless liquid with a pungent. Allylic alcohol.4% 50 ppm: ScbaF/SaF Wash skin: When contam Fl. Target Organs (see Table 5): Eye: Irr immed ER: Inh.38 mg/m3 DOT: 1098 131 Synonyms/Trade Names: AA. resp sys Swallow: Medical attention immed Allyl alcohol CAS#: RTECS#: IDLH: Formula: 107-05-1 UC7350000 250 ppm CH2=CHCH2Cl Conversion: 1 ppm = 3. mustard-like odor. skin. pulm edema. pulm edema Skin: Water flush immed Breath: Resp support TO: Eyes. resp sys.Pp/SaF:Pd.1% LEL: 2. kidneys Allyl chloride 10 . Breath: Resp support kidney inj Swallow: Medical attention immed TO: Eyes. irrit upper resp sys. Ing.0% LEL: 2. 1-Chloro-2-propene.5 NIOSH/OSHA Skin: Prevent skin contact BP: 113°F 25 ppm: Sa:Cf* Eyes: Prevent eye contact Sol: 0.85 Provide: Quick drench VP: 17 mmHg FRZ: -200°F UEL: 18. in animals: liver. skin. yellow.94 Escape: GmFOv/ScbaE Provide: Quick drench VP: 295 mmHg MLT: -210°F UEL: 11. 1-Propen-3-ol. skin.P: 70°F GmFOv/ScbaF/SaF §: ScbaF:Pd. Vinyl carbinol Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (5 mg/m3) (see Table 1): 3 NIOSH 1402. Symptoms. zinc First Aid (see Table 6): Exposure Routes.Pp Remove: When wet (flamm) IP: 10. Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 76.Pp:AScba Change: N. Target Organs (see Table 5): Eye: Irr immed ER: Inh. tissue damage. Sp.13 mg/m3 DOT: 1100 131 Synonyms/Trade Names: 3-Chloropropene. brown.R. liver.Gr: 0. acids. Abs.P: -25°F 250 ppm: SaF:Pd. 3-Chloropropylene Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (3 mg/m3) (see Table 1): 3 NIOSH 1000 ST 2 ppm (6 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 1 ppm (3 mg/m ) Physical Description: Colorless. 2-Propenol.Gr: 0.Pp/SaF:Pd.

97 VP: 2 mmHg FRZ: -148°F [forms glass] UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.3-epoxypropane. Symptoms. Symptoms. Fl.3 Skin: N. 2-Propenyl propyl disulfide.Formula: CAS#: RTECS#: IDLH: C6H10O2 106-92-3 RR0875000 50 ppm Conversion: 1 ppm = 4. repro sys Allyl glycidyl ether A Formula: CAS#: RTECS#: IDLH: H2C=CHCH2S2CH2CH2CH3 2179-59-1 JO0350000 N.93 VP: ? FRZ: 5°F UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Oxidizers First Aid (see Table 6): Exposure Routes. repro effects Swallow: Medical attention immed TO: Eyes.P: 135°F Escape: GmFOv/ScbaE Change: N.R. Con Skin: Soap wash immed SY: Irrit eyes. Ing.Gr: 0. blood.P: ? Remove: When wet or contam IP: ? Change: N. resp sys. Ing.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 148. Glycidyl allyl ether.07 mg/m3 DOT: Synonyms/Trade Names: 4. 1-Allyloxy-2.Pp/SaF:Pd. lac Breath: Resp support TO: Eyes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. IP: ? Provide: Eyewash Sp. derm. narco. Breath: Resp support possible hemato.2 50 ppm: CcrOv/PaprOv/ Eyes: Prevent eye contact BP: 309°F Wash skin: When contam Sol: 14% GmFOv/Sa/ScbaF §: ScbaF:Pd. Propyl allyl disulfide Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (12 mg/m3) (see Table 1): 3 OSHA PV2086 ST 3 ppm (18 mg/m ) 3 OSHA PEL†: TWA 2 ppm (12 mg/m ) Physical Description: Pale-yellow liquid with a strong & irritating onion-like odor.Gr(59°F): 0. Onion oil. Eyes: Prevent eye contact Sol: Insoluble Wash skin: N. [Note: The chief volatile component of onion oil.R. Conversion: 1 ppm = 6. Sp. skin.D. nose. pulm edema.67 mg/m3 DOT: 2219 129 Synonyms/Trade Names: AGE.R.Pp:AScba Remove: When wet or contam Fl. Target Organs (see Table 5): Eye: Irr immed ER: Inh.R. [(2-Propenyloxy)methyl] oxirane Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (22 mg/m3) [skin] (see Table 1): 3 NIOSH 2545 ST 10 ppm (44 mg/m ) 3 OSHA PEL†: C 10 ppm (45 mg/m ) Physical Description: Colorless liquid with a pleasant odor. nose. Abs. skin. Con Skin: Water flush prompt SY: Irrit eyes. resp sys. resp sys.5-Dithia-1-octene. resp sys Swallow: Medical attention immed Allyl propyl disulfide 11 . Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 114. BP: ? Not available.

0600 3 OSHA ID109SG. resp sys Breath: Fresh air TO: Eyes. DOT: 1309 170 (powder.0 Change: N. Aluminum trioxide [Note: α-Alumina is the main component of technical grade alumina.] Exposure Routes. Con Skin: Blot/brush away SY: Irrit eyes.P: NA Wash skin: N. Incompatibilities and Reactivities: Strong oxidizers & acids. or methyl chloride. Elemental aluminum Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): NIOSH 7013. Symptoms. acids.Gr: 4. Sp. Exposure Routes.R. may cause explosions. Ing. skin. Emery is an impure crystalline variety of Al2O3. BP: 4221°F Not available. Eyes: N.R. Corundum is natural Al2O3. skin.P: NA Remove: N.70 VP: 0 mmHg (approx) MLT: 1220°F UEL: NA LEL: NA Combustible Solid. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 27. IP: NA Remove: N. 7300. carbon disulfide.R.R.D. Fl. Aluminum metal. Ignition may occur if powders are mixed with halogens. halogenated hydrocarbons [Note: Corrodes in contact with acids & other metals.9 (see Table 2): BP: 5396°F Skin: N. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 101.D. 7303 TWA 5 mg/m3 (resp) 3 OSHA ID121 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Silvery-white. resp sys Aluminum 12 . skin.] form explosive mixtures in air. odorless metal. but dusts may divided iron contacts moisture during crushing & milling operations. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 1396 138 (powder. Aluminum powder. resp sys TO: Eyes. ID198SG TWA 5 mg/m (resp) Physical Description: White. Sp.0 Skin: N. resp sys Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: Al 7429-90-5 BD0330000 N. Sol: Insoluble Wash skin: N. IP: NA Change: N.Gr: 2. oxidizers [Note: Hydrogen gas may be formed when finely Noncombustible solid.R.R.] Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 15 mg/m (total) NIOSH 0500.R. finely divided dust is easily ignited. uncoated). hot chlorinated LEL: NA rubber. Not available. crystalline powder. 7301. Synonyms/Trade Names: Alumina.R. VP: 0 mmHg (approx) MLT: 3632°F UEL: NA Incompatibilities and Reactivities: Chlorine trifluoride.A α-Alumina Conversion: Formula: Al2O3 DOT: CAS#: 1344-28-1 RTECS#: BD1200000 IDLH: N. skin. Conversion: 9260 169 (molten) Synonyms/Trade Names: Aluminium.R. Aluminum oxide. Con Breath: Fresh air SY: Irrit eyes. ductile. Symptoms. Fl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. odorless. coated). malleable.R. Sol: Insoluble Eyes: N.

resp sys. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 mg/m3 NIOSH 7013. resp sys. Eyes: N. Symptoms. Con SY: Irrit skin. pulm fib TO: Skin. as Al) Formula: CAS#: RTECS#: IDLH: N. Target Organs (see Table 5): ER: Inh. Incompatibilities and Reactivities: Varies Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: Not available. Change: N. Properties vary depending upon Skin: N. 7303 OSHA PEL†: none Physical Description: Appearance and odor vary depending upon the specific OSHA ID121 aluminum compound. A Conversion: DOT: 1383 135 (powder.R. the specific aluminum compound. Ing. skin burns TO: Skin. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 NIOSH 7300.R. 7300. Conversion: DOT: 3051 135 (Aluminum alkyls) Synonyms/Trade Names: Synonyms vary depending upon the specific aluminum compound. resp sys First Aid (see Table 6): Eye: Irr immed Skin: Water flush immed Breath: Resp support Swallow: Medical attention immed Aluminum (soluble salts and alkyls. Con SY: Irrit skin.D. Properties vary depending upon Skin: Prevent skin contact the specific aluminum compound. Remove: N. pyrophoric) Synonyms/Trade Names: Synonyms vary depending upon the specific aluminum compound. Eyes: Prevent eye contact Wash skin: When contam Remove: When wet or contam Change: Daily Incompatibilities and Reactivities: Varies Exposure Routes. Target Organs (see Table 5): ER: Inh. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: Not available.R. Wash skin: N. Symptoms. 7303 OSHA PEL†: none Physical Description: Appearance and odor vary depending upon the specific aluminum compound. Ing. resp sys First Aid (see Table 6): Eye: Irr immed Skin: Water flush immed Breath: Resp support Swallow: Medical attention immed 13 . as Al) Formula: CAS#: RTECS#: IDLH: N.Aluminum (pyro powders and welding fumes. 7301.R. 7301.R.D.

or crystals with a characteristic odor. dysp.A Formula: CAS#: RTECS#: IDLH: C6H5C6H4NH2 92-67-1 DU8925000 Ca [N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 169.2 NIOSH Skin: Prevent skin contact BP: 576°F ¥: ScbaF:Pd. but must be preheated before ignition possible.1011] See Appendix B OSHA 93 Physical Description: Colorless crystals with a floral odor.Pp:AScba Eyes: Prevent eye contact Sol: Slight Escape: 100F/ScbaE Wash skin: When contam/Daily Fl.Pp:AScba Wash skin: When contam Sol: >100% Escape: GmFOv100/ScbaE Remove: When wet or contam Fl. Con Eye: Irr immed SY: Head.P: 154°F Change: Daily IP: 8.8 mmHg MLT: 137°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Abs. methemo. nose. Symptoms.Gr: 1. p-Aminodiphenyl. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 94. nau.D. 4-Phenylaniline Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH P&CAM269 (II-4) See Appendix A OSHA PEL: [1910. lass. Ing.] Conversion: DOT: Synonyms/Trade Names: 4-Aminobiphenyl. stupor Swallow: Medical attention immed TO: CNS.Gr: ? VP(77°F): 0. dizz.P: ? Remove: When wet or contam IP: ? See Appendix E (page 351) Change: Daily Sp. Con SY: Irrit eyes. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.5 ppm (2 mg/m3) 3 NIOSH S158 (II-4) OSHA PEL: TWA 0. Symptoms. Abs.00 eV Provide: Quick drench Sp. dizz.Pp/SaF:Pd. ataxia.5 ppm (2 mg/m ) Physical Description: White powder. α-Pyridylamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. [carc] Swallow: Medical attention immed TO: Bladder. [Note: Turns purple on contact with air. high BP. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Incompatibilities and Reactivities: Oxidized by air Exposure Routes. p-Aminobiphenyl. leaflets. head. Skin: Water flush immed Breath: Resp support resp distress. acute hemorrhagic cystitis. skin [bladder cancer] 4-Aminodiphenyl 2-Aminopyridine Conversion: 1 ppm = 3. excitement. convuls. resp sys 14 . drow.16 Provide: Eyewash VP(227°F): 1 mmHg MLT: 127°F Quick drench UEL: ? LEL: ? Combustible Solid. throat.85 mg/m3 Formula: NH2C5H4N DOT: 2671 153 CAS#: 504-29-0 RTECS#: US1575000 IDLH: 5 ppm Synonyms/Trade Names: α-Aminopyridine. Ing. lass.Pp/SaF:Pd. urinary Skin: Soap wash immed Breath: Resp support burning.1 5 ppm: Sa*/ScbaF Eyes: Prevent eye contact BP: 411°F §: ScbaF:Pd.

depres (thyroid func suppression) TO: Eyes. lass.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 17. thyroid [in animals: liver. [herbicide] [Note: Odorless when pure. Ing. Aqueous ammonia [Note: Often used in an aqueous solution.Formula: CAS#: RTECS#: IDLH: C2H4N4 61-82-5 XZ3850000 Ca [N.2 mg/m OSHA PV2006 See Appendix A Physical Description: Colorless to white. skin burns. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. 1005 125 (>50% solution) Synonyms/Trade Names: Anhydrous ammonia. wheez. skin. strong oxidizers Noncombustible Solid. musc spasms.60 (solution) Escape: GmFS/ScbaE Change: N. Ing (solution). dysp. skin.3. pulm Skin: Water flush immed (solution/liquid) Breath: Resp support edema.4-triazole. pink frothy sputum. Symptoms. salts of silver & zinc [Note: Corrosive to copper & galvanized surfaces. halogens. liquid: frostbite Swallow: Medical attention immed (solution) TO: Eyes. crystalline powder. vesic.] Conversion: DOT: Synonyms/Trade Names: Aminotriazole.] Chemical & Physical Properties: Personal Protection/Sanitation Respirator Recommendations (see Tables 3 and 4): MW: 84. 2-Amino-1. skin. salv. VP: 8. thyroid & pituitary gland tumors] Swallow: Medical attention immed Amitrole A Formula: CAS#: RTECS#: IDLH: NH3 7664-41-7 BO0875000 300 ppm DOT: 1005 125 (anhydrous).] Exposure Limits: Measurement Methods NIOSH REL: TWA 25 ppm (18 mg/m3) OSHA PEL†: TWA 50 ppm (35 mg/m3) (see Table 1): 3 NIOSH 3800.0 NIOSH Skin: Prevent skin contact BP: -28°F 250 ppm: CcrS*/Sa* Eyes: Prevent eye contact Sol: 34% Wash skin: When contam (solution) 300 ppm: Sa:Cf*/PaprS*/CcrFS/ Fl. but may be [Note: Corrosive to iron.] Exposure Routes. resp sys Ammonia 15 .Pp/SaF:Pd.Gr: 1. throat. nose. 6016 ST 35 ppm (27 mg/m ) OSHA ID188 Physical Description: Colorless gas with a pungent.18 eV GmFS/ScbaF/SaF §: ScbaF:Pd. Exposure Routes.] Incompatibilities and Reactivities: Strong oxidizers.70 mg/m3 2073 125 (>35-50% solution). Symptoms. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. aluminum & copper.2. 3-Aminotriazole. dysp. skin dryness. Con (solution/liquid) Eye: Irr immed (solution/liquid) SY: Irrit eyes. anor. incr body Skin: Water wash immed Breath: Resp support temperature. suffocating odor. chest pain. 2672 154 (10-35% solution). [Note: Shipped as a liquefied compressed gas. Aqua ammonia. acids. Con Eye: Irr immed SY: Irrit eyes.P: NA Wash skin: Daily IP: ? Remove: When wet or contam Sp. 6015.D.Pp/SaF:Pd.] dissolved in flammable liquids.4-triazole Exposure Limits: Measurement Methods NIOSH REL: Ca OSHA PEL†: none (see Table 1): 3 NIOSH 0500 TWA 0. ataxia.P: NA (Gas) Remove: When wet or contam IP: 10.Pp:AScba RGasD: 0.R. Conversion: 1 ppm = 0.Pp:AScba Sol(77°F): 28% Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl.1 (see Table 2): NIOSH BP: ? Skin: Prevent skin contact ¥: ScbaF:Pd. 3-Amino-1. it should be treated as one.000008 mmHg Provide: Eyewash MLT: 318°F Quick drench UEL: NA LEL: NA Incompatibilities and Reactivities: Light (decomposes).5 atm Provide: Eyewash (>10%) FRZ: -108°F UEL: 28% Quick drench (>10%) LEL: 15% [Note: Although NH3 does not meet the DOT definition of a Flammable Gas (for labeling purposes).14 Change: Daily VP: <0. Easily liquefied under pressure.

1 NIOSH Skin: N.] Exposure Routes.A CAS#: RTECS#: IDLH: Formula: 12125-02-9 BP4550000 N. IP: ? 250 mg/m3: Sa:Cf/PaprHie Change: N.D. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. fire) temperatures. potassium chlorate. resp sys Swallow: Medical attention immed Ammonium sulfamate 16 . Con Skin: Soap wash immed SY: Irrit eyes.R. dysp Breath: Resp support TO: Eyes.5 Skin: Prevent skin contact BP: Sublimes Not available.Gr: 1.Pp:AScba LEL: NA Escape: 100F/ScbaE Noncombustible Solid Incompatibilities and Reactivities: Acids. Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 53. bromine trifluoride [Note: Corrodes most metals at high (i. Ammonium amidosulfonate. resp sys Ammonium chloride fume Formula: CAS#: RTECS#: IDLH: NH4OSO2NH2 7773-06-0 WO6125000 1500 mg/m3 Conversion: DOT: Synonyms/Trade Names: Ammate herbicide. Sol: 200% Wash skin: N. odorless. Monoammonium salt of sulfamic acid. BP: 320°F (Decomposes) 50 mg/m3: Qm Eyes: N. odorless solid. Con Skin: Soap wash prompt SY: Irrit eyes. nose.P: NA 100 mg/m3: 95XQ/Sa Remove: N. hot water [Note: Elevated temperatures cause a highly exothermic reaction with water. resp sys.77 500 mg/m3: SaT:Cf/PaprTHie/100F/ VP: 0 mmHg (approx) ScbaF/SaF MLT: 268°F 1500 mg/m3: Sa:Pd. Symptoms. skin.Gr: 1.] Exposure Routes.R. cough. strong oxidizers.53 Provide: Eyewash VP(321°F): 1 mmHg MLT: 662°F (Sublimes) Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Alkalis & their carbonates. cough. Ammonium muriate fume. throat. [herbicide] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 114. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. dysp.. white particulate dispersed in air.e. Sulfamate Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH S348 (II-5) TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Colorless to white crystalline. Symptoms. AMS. NH4Cl Conversion: DOT: Synonyms/Trade Names: Ammonium chloride.R. Eyes: Prevent eye contact Sol: 37% Wash skin: When contam Fl. Sal ammoniac fume Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (see Table 1): 3 OSHA ID188 ST 20 mg/m OSHA PEL†: none Physical Description: Finely divided.P: NA Remove: When wet or contam IP: NA Change: Daily Sp.R. ammonium nitrate.R. Fl.Pp UEL: NA §: ScbaF:Pd.Pp/SaF:Pd. lead & silver salts. skin. pulm sens Breath: Resp support TO: Eyes.

Ing.5% LEL: 1% Class IC Flammable Liquid Incompatibilities and Reactivities: Nitrates. alkalis & acids Exposure Routes.Pp:AScba Remove: When wet (flamm) Fl.Formula: CAS#: RTECS#: IDLH: CH3COO[CH2]4CH3 628-63-7 AJ9250000 1000 ppm Conversion: 1 ppm = 5. nose.87 VP: 7 mmHg FRZ: -109°F UEL: 7. CNS Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: CH3COOCH(CH3)C3H7 626-38-0 AJ2100000 1000 ppm Conversion: 1 ppm = 5. Con Eye: Irr immed SY: Irrit eyes.88 VP: 4 mmHg FRZ: -95°F UEL: 7.Gr: 0. Con Skin: Water flush prompt SY: Irrit eyes. IP: ? Sp. IP: ? Sp. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. resp sys.P: 89°F Escape: GmFOv/ScbaE Change: N. 1-Pentanol acetate.Gr: 0. Primary amyl acetate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 100 ppm (525 mg/m3) 3 NIOSH 1450. nose. Ing. resp sys.33 mg/m3 DOT: 1104 129 Synonyms/Trade Names: 1-Methylbutyl acetate. Symptoms. alkalis & acids Exposure Routes. skin. Amyl acetic ether. n-Amyl acetate A Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 130.P: 77°F Escape: GmFOv/ScbaE Change: N. Pentyl ester of acetic acid. skin.5% LEL: 1. skin. kidneys.Pp/SaF:Pd. liver. strong oxidizers. sec-Amyl acetate Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 130.1% Class IC Flammable Liquid Incompatibilities and Reactivities: Nitrates.33 mg/m3 DOT: 1104 129 Synonyms/Trade Names: Amyl acetic ester. Skin: Water flush prompt Breath: Resp support possible CNS depres Swallow: Medical attention immed TO: Eyes. CNS 17 . derm.2% Sa*/ScbaF §: ScbaF:Pd.R.2 1000 ppm: CcrOv*/GmFOv/PaprOv*/ Eyes: Prevent eye contact BP: 301°F Wash skin: When contam Sol: 0. narco Breath: Resp support TO: Eyes. possible kidney.Pp/SaF:Pd. strong oxidizers. liver inj. Symptoms. 2-Pentyl ester of acetic acid Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 125 ppm (650 mg/m3) 3 NIOSH 1450. 2549 OSHA PEL: TWA 125 ppm (650 mg/m ) OSHA 7 Physical Description: Colorless liquid with a mild odor. 2-Pentanol acetate. derm. 2549 OSHA PEL: TWA 100 ppm (525 mg/m ) OSHA 7 Physical Description: Colorless liquid with a persistent banana-like odor.R. possible CNS depres. narco.2 1000 ppm: CcrOv*/GmFOv/PaprOv*/ Eyes: Prevent eye contact BP: 249°F Wash skin: When contam Sol: Slight Sa*/ScbaF §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp:AScba Remove: When wet (flamm) Fl.

Ing. kidneys. [carc] Breath: Resp support TO: Blood. bladder & kidneys] o-Anisidine 18 .] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 2514 0. liver. RBC Heinz bodies.P(oc): 244°F Remove: When wet or contam IP: 7. Aniline oil.44 eV Change: Daily Sp. kidneys. Abs. cyan. CVS. [Note: A solid below 41°F. Ing. IP: 7. strong acids. Phenylamine Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 2002. toluene diisocyanate. tacar.1 ¥: ScbaF:Pd. [Note: A solid below 21°F. methemo.02 VP: 0. oily liquid with an amine-like odor.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 123.Gr: 1. 2-Anisidine. cirr. lass. dizz. Con Eye: Irr immed SY: Head.Gr: 1. o-Methoxyaniline [Note: o-Anisidine has been used as a basis for many dyes. resp sys [bladder cancer] Swallow: Medical attention immed Aniline (and homologs) Formula: CAS#: RTECS#: IDLH: NH2C6H4OCH3 90-04-0 BZ5410000 Ca [50 mg/m3] Conversion: DOT: 2431 153 Synonyms/Trade Names: ortho-Aminoanisole. 8317 See Appendix A 3 OSHA PEL†: TWA 5 ppm (19 mg/m ) [skin] OSHA PV2079 Physical Description: Colorless to brown. dizz.5 mg/m [skin] See Appendix A OSHA PEL: TWA 0.70 eV Provide: Quick drench Sp.Pp:AScba Eyes: Prevent eye contact Sol(77°F): 1% Escape: GmFOv/ScbaE Wash skin: When contam Fl.Pp/SaF:Pd.2 NIOSH Skin: Prevent skin contact BP: 437°F ¥: ScbaF:Pd. ataxia.6 mmHg FRZ: 21°F UEL: 11% LEL: 1. liver.Pp:AScba Eyes: Prevent eye contact BP: 363°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: 4% Remove: When wet or contam Fl. alkalis Exposure Routes. cyan. eyes. 2017.81 mg/m3 DOT: 1547 153 Synonyms/Trade Names: Aminobenzene.10 Provide: Eyewash VP: <0.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 93. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. CVS. CNS [in animals: tumors of the Swallow: Medical attention immed thyroid gland.5 mg/m3 [skin] Physical Description: Red or yellow. Abs.A Formula: CAS#: RTECS#: IDLH: C6H5NH2 62-53-3 BW6650000 Ca [100 ppm] Conversion: 1 ppm = 3. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.P: 158°F Change: N.R.Pp/SaF:Pd. oily liquid with an aromatic amine-like odor. [carc] TO: Blood. irrit Skin: Soap wash prompt Breath: Resp support eyes.3% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. Symptoms. Symptoms.1 mmHg FRZ: 41°F Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Con Skin: Soap wash immed SY: Head. dysp on effort. Benzenamine.

Pp:AScba VP(77°F): 0. Conversion: 3141 157 (inorganic liquid compounds. dizz. kidneys.5 mg/m3 [skin] (see Table 1): 3 NIOSH 2514 OSHA PEL: TWA 0. skin. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.o. Abs. p-Methoxyaniline Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Symptoms.5 mg/m3: Sa:Cf/PaprHie Remove: When wet or contam Fl.8 5 mg/m3: 95XQ/Sa Eyes: Prevent eye contact BP: 2975°F Wash skin: When contam Sol: Insoluble 12. cyan.Pp* Provide: Quick drench Sp.P: ? 25 mg/m3: 100F/PaprTHie*/ScbaF/SaF Change: Daily IP: 7.Pp Sp. halogenated acids [Note: Stibine is formed when antimony is exposed to nascent (freshly formed) hydrogen. skin. [*Note: The REL and PEL also apply to other antimony compounds (as Sb).Pp/SaF:Pd. anor. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 121.Gr: 6. dizz. CNS Swallow: Medical attention immed p-Anisidine A Formula: CAS#: RTECS#: IDLH: Sb 7440-36-0 CC4025000 50 mg/m3 (as Sb) DOT: 1549 157 (inorganic compounds. Ing.] P&CAM 261 (II-4) Physical Description: Silver-white.Pp:AScba VP: 0 mmHg (approx) Escape: 100F/ScbaE MLT: 1166°F UEL: NA LEL: NA Noncombustible Solid in bulk form. insom. Skin: Soap wash immed vomit. RBC Heinz bodies Breath: Resp support TO: Blood. head.s.Gr: 1.) Synonyms/Trade Names: Antimony metal. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 4-Anisidine. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 123. n.07 §: ScbaF:Pd. mouth.). nose. lustrous powder.69 §: ScbaF:Pd. 7303. CVS Antimony 19 . Stibium Exposure Limits: Measurement Methods NIOSH REL*: TWA 0. 2871 170 (powder). resp sys. acids. ID125G. lustrous. liver.] Exposure Routes.006 mmHg Escape: 100F/ScbaE MLT: 135°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. n.P: NA 25 mg/m3: 100F/SaT:Cf/PaprTHie/ScbaF/SaF Change: Daily IP: NA 50 mg/m3: Sa:Pd. brittle solid.s.44 eV 50 mg/m3: Sa:Pd. diarr.5 mg/m NIOSH 7301.5 mg/m [skin] Physical Description: Yellow to brown. Ing. Con Eye: Irr immed SY: Irrit eyes.Pp/SaF:Pd. CVS.5 mg/m3: Sa:Cf/PaprHie Remove: When wet or contam Fl. ID206 or a dark-gray. crystalline solid with an amine-like odor. cough.2 5 mg/m3: 95XQ/Sa Eyes: Prevent eye contact BP: 475°F Wash skin: When contam Sol: Moderate 12. Con Skin: Soap wash immed SY: Head. stomach cramps. unable to smell properly Breath: Resp support Swallow: Medical attention immed TO: Eyes. but a moderate explosion hazard in the form of dust when exposed to flame.5 mg/m3 (see Table 1): 3 OSHA PEL*: TWA 0. hard. Incompatibilities and Reactivities: Strong oxidizers. Antimony powder.o.Formula: CAS#: RTECS#: IDLH: NH2C6H4OCH3 104-94-9 BZ5450000 50 mg/m3 Conversion: DOT: 2431 153 Synonyms/Trade Names: para-Aminoanisole. OSHA ID121. Symptoms. nau. throat. scale-like crystals.

A ANTU Conversion: Formula: C10H7NHC(NH2)S DOT: 1651 153 CAS#: 86-88-4 RTECS#: YT9275000 IDLH: 100 mg/m3 Synonyms/Trade Names: α-Naphthyl thiocarbamide. Symptoms. [Note: OSHA considers “Inorganic Arsenic” to mean copper acetoarsenite & all inorganic compounds containing arsenic except ARSINE.P: NA 15 mg/m3: CcrFOv100/GmFOv100/ Change: Daily IP: ? PaprTOvHie/SaT:Cf/ScbaF/SaF Sp. Incompatibilities and Reactivities: Strong oxidizers. BP: Decomposes Wash skin: N. GI disturbances. C 0. odorless powder. [rodenticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N. MW: 202. [carc] TO: Liver. but a slight explosion hazard in the form of dust when exposed to flame.Pp/SaF:Pd.3 mg/m3 (see Table 1): 3 NIOSH S276 (II-5) OSHA PEL: TWA 0. Ing Eye: Irr immed SY: Ulceration of nasal septum. 1-Naphthyl thiourea. as As) Formula: CAS#: As (metal) 7440-38-2 (metal) RTECS#: IDLH: CG0525000 (metal) Ca [5 mg/m3 (as As)] Conversion: DOT: 1558 152 (metal). bromine azide [Note: Hydrogen gas can react with inorganic arsenic to form the highly toxic gas arsine. α-Naphthyl thiourea Exposure Limits: Measurement Methods NIOSH REL: TWA 0. liver Arsenic (inorganic compounds. dysp. lymphatic sys [lung & lymphatic cancer] Swallow: Medical attention immed 20 . Fl.R.Gr: 5. Skin: Soap wash immed Breath: Resp support resp irrit.R. Sol: 0.Pp VP: Low §: ScbaF:Pd.P: NA Remove: When wet or contam IP: NA See Appendix E (page 351) Change: Daily Sp. hyperpig of skin. blood. peri neur.Pp/SaF:Pd.73 (metal) Provide: Eyewash VP: 0 mmHg (approx) MLT: 1135°F (Sublimes) Quick drench UEL: NA LEL: NA Metal: Noncombustible Solid in bulk form. 7303. silver nitrate First Aid (see Table 6): Exposure Routes. kidneys. cyan.1018] TWA 0.002 mg/m [15-minute] 9102. Symptoms. 7301.9 NIOSH Skin: Prevent skin contact BP: Sublimes ¥: ScbaF:Pd.Pp:AScba MLT: 388°F Escape: GmFOv100/ScbaE UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers. Abs. Target Organs (see Table 5): Eye: Irr immed ER: Inh. 1562 152 (dust) Synonyms/Trade Names: Arsenic metal: Arsenia Other synonyms vary depending upon the specific As compound.R.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 7300. 7900 See Appendix A OSHA ID105 OSHA PEL: [1910. liver damage Swallow: Medical attention immed TO: Resp sys.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: GmFAg100/ScbaE Wash skin: When contam/Daily Fl.06% 7.3 mg/m Physical Description: White crystalline or gray.R. brittle. skin. coarse pulm Breath: Resp support rales.] Exposure Routes. odorless solid.5 mg/m3: Sa:Cf/PaprOvHie Remove: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.3 3 mg/m3: CcrOv95/Sa Eyes: N. Ing Skin: Soap wash prompt SY: After ingestion of large doses: vomit.010 mg/m3 Physical Description: Metal: Silver-gray or tin-white.Gr: ? 100 mg/m3: Sa:Pd. derm. Con. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 74. lungs.

19 mg/m DOT: 2188 119 Synonyms/Trade Names: Arsenic hydride. liver [lung & lymphatic cancer] Arsine 3 21 . Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh.9 atm FRZ: -179°F UEL: 78% LEL: 5.89 eV Change: N.0 NIOSH Skin: Frostbite BP: -81°F ¥: ScbaF:Pd. dizz. Exposure Limits: Measurement Methods NIOSH REL: none (see Table 1): 3 OSHA PEL: TWA 0. There is a high potential for the generation of arsine gas when inorganic arsenic is exposed to nascent (freshly formed) hydrogen. repro sys First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: AsH3 7784-42-1 CG6475000 Ca [3 ppm] Conversion: 1 ppm = 3. repro effects. kidney damage. [Note: Shipped as a liquefied compressed gas. garlic-like odor. as As) Formula: CAS#: RTECS#: IDLH: N.] Exposure Routes.1% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers.Arsenic (organic compounds. jaun. mal. A Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific organic arsenic compound.05 ppm (0. Con SY: In animals: irrit skin. chlorine. CNS. liquid: frostbite. Arsenous hydride. Breath: Resp support bronze skin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 78. GI tract. abdom. RGasD: 2. vomit.Pp:AScba Eyes: Frostbite Sol: 20% Escape: GmFS/ScbaE Wash skin: N. kidneys. Symptoms. Hydrogen arsenide Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 6001 C 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: Not available. back pain. possible liver damage TO: Skin. resp distress. liver. possible derm. Ing. kidneys.2 mg/m3) Physical Description: Colorless gas with a mild. Arsenic trihydride. possible GI tract. musc tremor.R.P: NA (Gas) Remove: When wet (flamm) IP: 9.002 mg/m [15-minute] OSHA ID105 See Appendix A OSHA PEL: TWA 0. resp sys. hema. nitric acid [Note: Decomposes above 446°F. Fl. arsenic compound.69 Provide: Frostbite wash VP(70°F): 14. Target Organs (see Table 5): ER: Inh. Symptoms.Pp/SaF:Pd. Recommendations regarding personal Properties vary depending protective clothing vary depending upon upon the specific organic the specific compound. nau.R. convuls. Con (liquid) Skin: Frostbite SY: Head. Arseniuretted hydrogen. [carc] TO: Blood.D. dysp. Incompatibilities and Reactivities: Varies Exposure Routes. diarr. lass. peri neur.5 mg/m NIOSH 5022 Physical Description: Appearance and odor vary depending upon the specific organic arsenic compound.

resp sys. Symptoms. [carc] TO: Resp sys. restricted pulm function. Petroleum asphalt. 2590 171 (white) Synonyms/Trade Names: Actinolite. Con Breath: Fresh air SY: Asbestosis (chronic exposure): dysp. Ing.1001] [1926. Roofing asphalt Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 5042 C 5 mg/m3 [15-minute] See Appendix A OSHA PEL: none Physical Description: Fumes generated during the production or application of asphalt (a dark-brown to black cement-like substance manufactured by the vacuum distillation of crude petroleum oil). finger clubbing. Petroleum bitumen. Symptoms. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Road asphalt. blue (crocidolite). or gray-green (amosite) fibrous. Tremolite asbestos Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 7400. irrit eyes. ID191 See Appendix C OSHA PEL: [1910.P: NA Remove: N. odorless solids. Bitumen (European term). Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Properties vary depending upon Skin: Prevent skin contact ¥: ScbaF:Pd. Tremolite. Actinolite asbestos.R. resp sys [in animals: skin tumors] 22 . Abs. Crocidolite (Riebeckite). [carc] TO: Eyes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: Varies NIOSH Skin: Prevent skin contact BP: Decomposes ¥: ScbaF:Pd. IP: NA Change: Daily See Appendix E (page 351) Sp. brown).D. interstitial fib.1101] See Appendix C Physical Description: White or greenish (chrysotile). 7402 See Appendix A OSHA ID160.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: 100F/ScbaE Wash skin: Daily Fl.Pp/SaF:Pd.D. Con Breath: Resp support SY: Irrit eyes. Anthophyllite.Pp:AScba the specific asphalt formulation or Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Wash skin: Daily mixture.R.] Conversion: DOT: 2212 171 (blue.] Conversion: DOT: 1999 130 (asphalt) Synonyms/Trade Names: Asphalt: Asphaltum. Chrysotile.Pp/SaF:Pd. Change: Daily Asphalt: Combustible Solid Asphalt fumes Formula: Incompatibilities and Reactivities: None reported [Note: Asphalt becomes molten at about 200°F.Gr: ? VP: 0 mmHg (approx) MLT: 1112°F (Decomposes) UEL: NA LEL: NA Noncombustible Solids Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. Amosite (cummingtonite-grunerite). Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Remove: N. Anthophyllite asbestos. eyes [lung cancer] Asbestos CAS#: RTECS#: IDLH: 8052-42-4 CI9900000 Ca [N.] Exposure Routes.A Formula: CAS#: RTECS#: IDLH: Hydrated mineral silicates 1332-21-4 CI6475000 Ca [N.

2 mg/m3 [skin] (see Table 1): 3 NIOSH 5600 OSHA PEL: TWA 0.P: NA Change: Daily IP: ? Provide: Quick drench Sp. nau. crystalline powder. skin.3. Symptoms. resp sys. derm. dysp. Ing. anor. liver inj Swallow: Medical attention immed TO: Eyes. skin. Methyl azinphos Exposure Limits: Measurement Methods NIOSH REL: TWA 0. acids Exposure Routes. Guthion®. diarr.P: NA Remove: When wet or contam IP: NA Change: Daily Sp. CNS. ache eyes.003% Remove: When wet or contam Fl. sweat.Pp/SaF:Pd.3-benzotriazin-3(4H)-ylmethyl phosphorodithioate. [insecticide] Azinphos-methyl Personal Protection/Sanitation Chemical & Physical (see Table 2): Properties: Skin: Prevent skin contact MW: 317. lac. 8315 OSHA PEL†: none Physical Description: Colorless or white. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.3 Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: 0.19 Provide: Eyewash VP: 0.2 mg/m [skin] OSHA PV2087 Physical Description: Colorless crystals or a brown.Gr: 1. sens skin. wheez.D. head.Pp:AScba Escape: GmFOv100/ScbaE First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed 23 . lar spasm. solid. chest tight. Ing. Symptoms.2. vomit.Formula: CAS#: RTECS#: IDLH: C8H14ClN5 1912-24-9 XY5600000 N. Con SY: Miosis. Con Skin: Soap wash immed SY: Irrit eyes. Incompatibilities and Reactivities: Strong acids. blurred vision.0000003 mmHg MLT: 340°F Quick drench UEL: NA LEL: NA Noncombustible Solid.4-diamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 NIOSH 5602.5-triazine-2. salv. toxic) Synonyms/Trade Names: O. salv. liver Atrazine A CAS#: RTECS#: IDLH: Formula: 10 mg/m3 C10H12O3PS2N3 [(CH3O)2P(S)SCH2(N3C7H4O)] 86-50-0 TE1925000 Conversion: DOT: 2783 152 (organophosphorus pesticide. card irreg TO: Resp sys. twitch. Target Organs (see Table 5): ER: Inh. convuls. inco. Eyes: Prevent eye contact Sol: 0. Breath: Resp support hypothermia. para. but may be mixed with flammable liquids.O-Dimethyl-S-4-oxo-1. rhin. strong bases Exposure Routes. [herbicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 215. low BP. cyan.003% Wash skin: When contam Fl.7 Skin: Prevent skin contact BP: Decomposes Not available. Conversion: DOT: 2763 151 (triazine pesticide) Synonyms/Trade Names: 2-Chloro-4-ethylamino-6-isopropylamino-s-triazine. CNS. 6-Chloro-N-ethyl-N'-(1-methylethyl)-1. waxy solid. lass. odorless.44 VP: 8 x 10-9 mmHg MLT: 163°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers.Gr: 1. blood chol Respirator Recommendations (see Tables 3 and 4): NIOSH/OSHA 2 mg/m3: CcrOv95/Sa 5 mg/m3: Sa:Cf/PaprOvHie 10 mg/m3: CcrFOv100/GmFOv100/ PaprTOvHie/SaT:Cf/ScbaF/SaF §: ScbaF:Pd. CVS. Abs.

Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.5 mg/m3: Sa:Cf/PaprHie Remove: When wet or contam IP: ? 25 mg/m3: 100F/SaT:Cf/PaprTHie/ Change: Daily Sp.5 mg/m NIOSH 7056. upper resp sys.4 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 5 mg/m3: 95XQ/Sa Eyes: Prevent eye contact Sol: 9% Wash skin: When contam Fl.Pp MLT: 1094°F §: ScbaF:Pd.) IDLH: 50 mg/m3 (as Ba) Formula: CAS#: RTECS#: IDLH: Ba(NO3)2 10022-31-8 CQ9625000 50 mg/m3 (as Ba) Conversion: DOT: 1446 141 Synonyms/Trade Names: Barium dinitrate. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 261. extrasystoles.Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA Noncombustible Solid. Ing. upper resp sys. aluminum-magnesium alloys. resp sys. hypokalemia Swallow: Medical attention immed TO: Eyes. resp sys.] Exposure Routes. CNS Formula: CAS#: RTECS#: BaCl2 10361-37-2 CQ8750000 DOT: 1564 154 (barium compound. CNS Barium nitrate (as Ba) 24 . skin. odorless solid. Breath: Resp support musc spasm. hypokalemia Swallow: Medical attention immed TO: Eyes.5 mg/m NIOSH 7056 OSHA ID121 [*Note: The REL and PEL also apply to other soluble barium compounds (as Ba) except Barium sulfate. skin burns. Incompatibilities and Reactivities: Acids.Gr: 3. Ing.Gr: 3. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 208. (barium dioxide + zinc) [Note: Contact with combustible material may cause fire. odorless solid. Con Skin: Water flush immed SY: Irrit eyes.] Physical Description: White.B Barium chloride (as Ba) Conversion: Synonyms/Trade Names: Barium dichloride Exposure Limits: Measurement Methods NIOSH REL*: TWA 0.24 ScbaF/SaF VP: Low 50 mg/m3: SaF:Pd. 7303 [*Note: The REL and PEL also apply to other soluble barium compounds (as Ba) OSHA ID121 except Barium sulfate. Breath: Resp support musc spasm.Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Acids. n.2 NIOSH/OSHA Skin: Prevent skin contact BP: 2840°F 5 mg/m3: 95XQ/Sa Eyes: Prevent eye contact Sol: 38% Wash skin: When contam Fl.o. extrasystoles. heart. Barium salt of nitric acid Exposure Limits: Measurement Methods NIOSH REL*: TWA 0. skin burns.P: NA 12. slow pulse. gastroenteritis. gastroenteritis.86 ScbaF/SaF VP: Low 50 mg/m3: SaF:Pd.Pp MLT: 1765°F §: ScbaF:Pd.5 mg/m3 (see Table 1): 3 OSHA PEL*: TWA 0. skin. but will accelerate the burning of combustible materials. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp/SaF:Pd. Symptoms.Pp/SaF:Pd. oxidizers. Barium(II) nitrate (1:2).] Physical Description: White. skin.P: NA 12. slow pulse.s. Symptoms. Con Skin: Water flush immed SY: Irrit eyes.5 mg/m3 (see Table 1): 3 OSHA PEL*: TWA 0.5 mg/m3: Sa:Cf/PaprHie Remove: When wet or contam IP: ? 25 mg/m3: 100F/SaT:Cf/PaprTHie/ Change: Daily Sp. skin. oxidizers Exposure Routes. heart.

Symptoms. 0600 TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: White or yellowish.0004% Wash skin: When contam Fl. benign pneumoconiosis Skin: Soap wash Breath: Resp support (baritosis) Swallow: Medical attention immed TO: Eyes. solid) Synonyms/Trade Names: Methyl 1-(butylcarbamoyl)-2-benzimidazolecarbamate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 NIOSH 0500.D. 0600 OSHA PEL†: TWA 15 mg/m (total) 3 OSHA PV2107 TWA 5 mg/m (resp) Physical Description: White crystalline solid with a faint.R.Gr: ? Provide: Eyewash VP: <0.Formula: CAS#: RTECS#: IDLH: BaSO4 7727-43-7 CR0600000 N. upper resp sys.) Synonyms/Trade Names: Artificial barite.R. Breath: Resp support terato effects Swallow: Medical attention immed TO: Eyes. upper resp sys.25-4.4 Skin: Prevent skin contact BP: Decomposes Not available. Symptoms. possible repro. Con Skin: Soap wash immed SY: Irrit eyes. skin sens. repro sys Benomyl 25 .P: NA Remove: When wet or contam IP: NA Change: Daily Sp. Barite. Conversion: DOT: 1564 154 (barium compound.4 Skin: Prevent skin contact BP: 2912°F (Decomposes) Not available. Ing. aluminum [Note: Aluminum in the presence of heat can cause an explosion. Barytes (natural) Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. resp sys.P: NA Remove: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Sp. Barium salt of sulfuric acid. resp sys Barium sulfate B Formula: CAS#: RTECS#: IDLH: C14H18N4O3 17804-35-2 DD6475000 N. nose. odorless powder. Con Eye: Irr immed SY: Irrit eyes.o. Eyes: Prevent eye contact Sol(64°F): 0.Gr: 4. skin. strong alkalis Exposure Routes. strong acids.s.D.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 290. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Eyes: Prevent eye contact Sol: 0. [fungicide] [Note: Decomposes without melting above 572°F.] Exposure Routes. skin. n. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 233.5 Provide: Eyewash VP: 0 mmHg (approx) MLT: 2876°F Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Phosphorus.00001 mmHg MLT: >572°F (Decomposes) Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Heat.0002% Wash skin: Daily Fl. acrid odor. Conversion: DOT: 2757 151 (carbamate pesticide. IP: NA Change: N.

1 ppm TWA 1 ppm OSHA 12. resp sys.P: 132°F 5 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam IP: 8.19 mg/m3 DOT: 1114 130 Synonyms/Trade Names: Benzol. cough.1 NIOSH Skin: Prevent skin contact BP: 176°F ¥: ScbaF:Pd.88 Provide: Eyewash VP: 75 mmHg FRZ: 42°F Quick drench UEL: 7.B Formula: CAS#: RTECS#: IDLH: C6H6 71-43-2 CY1400000 Ca [500 ppm] Conversion: 1 ppm = 3.Pp:AScba Provide: Eyewash VP(65°F): 1 mmHg Escape: GmFOv/ScbaE FRZ: 5°F Quick drench UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong acids & bases. skin. liver. Symptoms. garlic-like odor. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. anor. alkali metals [Note: Oxidizes on exposure to air.2 NIOSH Skin: Prevent skin contact BP: 336°F 1 ppm: CcrOv/Sa Eyes: Prevent eye contact Sol(77°F): 0.2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. CNS depres. Phenyl hydride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca OSHA PEL: [1910.33 eV Change: N. dizz. lass. kidneys. Abs. CNS. bone marrow depres.07% Escape: GmFOv/ScbaE Wash skin: When contam Fl. staggered Breath: Resp support gait.Pp/SaF:Pd.Gr: 1. resp sys. vomit.24 eV See Appendix E (page 351) Change: N. dizz. wheez.P: 12°F Remove: When wet (flamm) IP: 9. 3800 TWA 0. cyan. [Note: A solid below 42°F. spleen damage Swallow: Medical attention immed TO: Eyes. Con SY: Irrit eyes. nau.R. Ing. derm.R. Phenyl mercaptan. calcium hypochlorite. 1501.Pp:AScba Eyes: Prevent eye contact Sol: 0. 3700. CNS.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Fl. 1005 ST 1 ppm ST 5 ppm See Appendix A See Appendix F Physical Description: Colorless to light-yellow liquid with an aromatic odor. C6H5SH Conversion: 1 ppm = 4. Thiophenol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. Sp.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 78. [Note: A solid below 5°F. head.1028] NIOSH 1500.1 ppm (0.51 mg/m3 DOT: 2337 131 Synonyms/Trade Names: Mercaptobenzene. blood. liver. [carc] Swallow: Medical attention immed TO: Eyes. head.08% 2. skin. skin. Abs. Symptoms. skin. Target Organs (see Table 5): Eye: Irr immed ER: Inh.8% LEL: 1.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 110. nitric acid Exposure Routes.5 mg/m3) [15-minute] OSHA PV2075 OSHA PEL†: none Physical Description: Water-white liquid with an offensive.08 ScbaF/SaF §: ScbaF:Pd. pulm edema. many fluorides & perchlorates.] First Aid (see Table 6): Exposure Routes. Skin: Soap wash immed Breath: Resp support pneu. resp sys. derm. resp sys.D. nau. bone marrow [leukemia] Benzene CAS#: RTECS#: IDLH: Formula: 108-98-5 DC0525000 N. Con Skin: Soap wash immed SY: Irrit eyes.Gr: 0. kidney. dysp. Sp. Ing.Pp/SaF:Pd. spleen Benzenethiol 26 . nose.

Extremely explosion-sensitive to shock.Pp VP: <1 mmHg §: ScbaF:Pd. paper. secondary anemia from hemolysis. kidney & bladder cancer] Swallow: Medical attention immed Benzidine B Formula: CAS#: RTECS#: IDLH: (C6H5CO)2O2 94-36-0 DM8575000 1500 mg/m3 Conversion: DOT: Synonyms/Trade Names: Benzoperoxide.Pp/SaF:Pd. p-Diaminodiphenyl [Note: Benzidine has been used as a basis for many dyes. irreg urination. blood [liver.] Exposure Routes. sens derm Breath: Resp support TO: Eyes. etc.P: ? Remove: When wet or contam IP: ? See Appendix E (page 351) Change: Daily Sp.4'-diamine. 4. [Note: Darkens on exposure to air and light. Con Eye: Irr immed SY: Hema. Con Skin: Soap wash prompt SY: Irrit eyes.P: 176°F 125 mg/m3: Sa:Cf*/PaprHie* Remove: When wet or contam IP: ? 250 mg/m3: 100F/PaprTHie*/ScbaF/SaF Change: Daily Sp.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 184. skin. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Ing.Gr: 1. Symptoms. resp sys Swallow: Medical attention immed Benzoyl peroxide 27 .Formula: CAS#: RTECS#: IDLH: NH2C6H4C6H4NH2 92-87-5 DC9625000 Ca [N. acute cystitis. Incompatibilities and Reactivities: Combustible substances (wood. acute Skin: Soap wash immed Breath: Resp support liver disorders. 4.] Conversion: DOT: 1885 153 Synonyms/Trade Names: Benzidine-based dyes. painful.D.4'-Bianiline.25 Provide: Eyewash VP: Low MLT: 239°F Quick drench UEL: ? LEL: ? Combustible Solid. Dibenzoyl peroxide Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 NIOSH 5009 OSHA PEL: TWA 5 mg/m Physical Description: Colorless to white crystals or a granular powder with a faint. amines.). muc memb.1'-Biphenyl-4. liver. reddish-gray.] Exposure Limits: Measurement Methods NIOSH REL: Ca OSHA PEL: [1910. ethers [Note: Containers may explode when heated.Gr: 1. kidneys. 4. benzaldehyde-like odor. derm. [carc] TO: Bladder.4'-Diaminobiphenyl. 1. Symptoms.Pp:AScba Eyes: Prevent eye contact Sol(54°F): 0.3 NIOSH Skin: Prevent skin contact BP: 752°F ¥: ScbaF:Pd.Pp:AScba MLT: 217°F Escape: 100F/ScbaE UEL: ? LEL: ? Combustible Solid (easily ignited and burns very rapidly).Pp/SaF:Pd. alkalis.4'-Biphenyldiamine.33 1500 mg/m3: SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.1010] (see Table 1): NIOSH 5509 See Appendix A See Appendix B OSHA 65 See Appendix C See Appendix C Physical Description: Grayish-yellow. alcohols.2 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes explosively 50 mg/m3: 95XQ*/Sa* Eyes: Prevent eye contact Sol: <1% Wash skin: When contam Fl.04% Wash skin: When contam/Daily Escape: 100F/ScbaE Fl. acids. Abs. but difficult to burn. skin. heat & friction. Incompatibilities and Reactivities: Red fuming nitric acid Exposure Routes. skin. Ing. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 242. or white crystalline powder.

P: NA Remove: When wet or contam IP: NA Change: Daily Sp. acids. iron. 1567 134 (powder) Synonyms/Trade Names: Beryllium metal: Beryllium Other synonyms vary depending upon the specific beryllium compound.Gr: 1. clubbing of fingers. [carc] TO: Eyes. Con Breath: Fresh air SY: Berylliosis (chronic exposure): anor.85 (metal) Provide: Eyewash VP: 0 mmHg (approx) MLT: 2349°F UEL: NA LEL: NA Metal: Noncombustible Solid in bulk form. pulm insufficiency. Target Organs (see Table 5): Eye: Irr immed ER: Inh.002 mg/m C 0. cough. irrit eyes. molten lithium First Aid (see Table 6): Exposure Routes. magnesium. Incompatibilities and Reactivities: Acids.6 NIOSH/OSHA Skin: Prevent skin contact BP: 354°F 10 ppm: CcrOvAg*/GmFOvAg/ Eyes: Prevent eye contact Sol: 0. skin. irrity.005 mg/m3 0.0 NIOSH Skin: Prevent skin contact BP: 4532°F ¥: ScbaF:Pd. aluminum. aromatic odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 9. lass. resp sys [lung cancer] 28 .1% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers. Sp.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: 100F/ScbaE Wash skin: Daily Fl. OSHA 7 Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 126. low-wgt. CNS Swallow: Medical attention immed Beryllium & beryllium compounds (as Be) Formula: Be (metal) CAS#: 7440-41-7 (metal) RTECS#: DS1750000 (metal) IDLH: Ca [4 mg/m3 (as Be)] Conversion: DOT: 1566 154 (compounds). skin eruption. Ing. skin.10 Provide: Eyewash VP: 1 mmHg FRZ: -38°F Quick drench UEL: ? LEL: 1.Pp:AScba Remove: When wet or contam IP: ? Escape: GmFOvAg/ScbaE Change: N. but a slight explosion hazard in the form of a powder or dust. ID206 OSHA PEL: TWA 0. head. chlorinated hydrocarbons.Gr: 1. tin [Note: Can polymerize when in contact with all common metals except nickel & lead. caustics. 7300. cyan. brittle. 9102 See Appendix A 3 OSHA ID125G. Symptoms. pulm edema Skin: Soap wash immed Breath: Resp support TO: Eyes. derm. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 7102. chest pain.18 mg/m3 Formula: C6H5CH2Cl DOT: 1738 156 CAS#: 100-44-7 RTECS#: XS8925000 IDLH: 10 ppm Synonyms/Trade Names: Chloromethylbenzene. Target Organs (see Table 5): Eye: Irr immed ER: Inh. gray-white solid. nose.Pp/SaF:Pd. Con SY: Irrit eyes. Hydrolyzes in H2O to benzyl alcohol.R.P: 153°F PaprOvAg*/Sa*/ScbaF §: ScbaF:Pd. zinc. resp sys.Pp/SaF:Pd. Symptoms. skin. α-Chlorotoluene Exposure Limits: Measurement Methods NIOSH REL: C 1 ppm (5 mg/m3) [15-minute] (see Table 1): 3 NIOSH 1003 OSHA PEL: TWA 1 ppm (5 mg/m ) Physical Description: Colorless to slightly yellow liquid with a pungent.] First Aid (see Table 6): Exposure Routes.05% Wash skin: When contam Fl.0005 mg/m 7303. copper. oxidizers.B Benzyl chloride Conversion: 1 ppm = 5. 7301. Not to exceed 0. lass.025 mg/m3 [30-minute maximum peak] Physical Description: Metal: A hard.

Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl. doped with Selenium sulfide (as Bi2Te3) Formula: CAS#: RTECS#: IDLH: N. [Note: Doping alters the conductivity of a semiconductor. Wash skin: When contam Remove: When wet or contam Sp. plus some tellurium. Symptoms. garlic breath. moisture. undoped 29 .R. 0600 TWA 5 mg/m (resp) 3 OSHA ID121 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Gray. Bismuth telluride. moisture Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 800. chlorine. Con Skin: Soap wash immed SY: Irrit eyes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin.Gr: 7.g.7 Provide: Eyewash VP: 0 mmHg (approx) MLT: 1063°F Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers (e.8 Skin: Prevent skin contact BP: ? Not available.P: NA Remove: When wet or contam IP: NA Change: N. undoped. crystalline solid that has been enhanced (doped) with a OSHA ID121 small amount of selenium sulfide (SeS). garlic breath Breath: Resp support TO: Eyes. skin.] Chemical & Physical Properties: Respirator Recommendations Personal Protection/Sanitation (see Tables 3 and 4): (see Table 2): Properties are unavailable but Skin: Prevent skin contact should be similar to Bismuth Not available. Eyes: Prevent eye contact telluride.D. Con Eye: Irr immed SY: Irrit eyes. Sp. skin. upper resp sys. Doped tellurobismuthite [Note: Doped with selenium sulfide. 20% stannous telluride. nitric acid (decomposes) Exposure Routes. Doped bismuth telluride. Tellurobismuthite Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. Conversion: DOT: Synonyms/Trade Names: Doped bismuth sesquitelluride.D. Provide: Eyewash Noncombustible Solid Quick drench Incompatibilities and Reactivities: Strong oxidizers. resp sys B Formula: CAS#: RTECS#: IDLH: Bi2Te3 1304-82-1 EB3110000 N. Doped bismuth tritelluride. upper resp sys. Bismuth tritelluride. resp sys Swallow: Medical attention immed Bismuth telluride. Symptoms.R. bromine. Commercial mix may contain 80% Bi2Te3.Bismuth telluride. in animals: Skin: Soap wash immed Breath: Resp support pulm lesions (nonfibrotic) Swallow: Medical attention immed TO: Eyes. or fluorine).. skin. crystalline solid. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.] Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): OSHA PEL†: none NIOSH 0500 Physical Description: Gray. Conversion: DOT: Synonyms/Trade Names: Bismuth sesquitelluride.Gr: ? Change: N.

IP: NA Change: Daily Sp. [herbicide] [Note: Becomes anhydrous at 608°F. Symptoms. Fused borax.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 381.] Exposure Routes. upper resp sys.P: NA Remove: N.4 Skin: N.R. tetra. Borax decahydrate. BP: 2867°F (Decomposes) Not available.R.Gr: 2. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 201.D. Incompatibilities and Reactivities: Zirconium. cough. strong acids.D. skin. Sol: 4% Wash skin: Daily Fl.37 VP: 0 mmHg (approx) MLT: 1366°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Moisture [Note: Forms partial hydrate in moist air. Ing.R. Sol: 6% Wash skin: Daily Fl. cough. skin. dysp Breath: Resp support TO: Eyes. skin. IP: NA Change: Daily Sp.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. resp sys Swallow: Medical attention immed Borates. odorless. Disodium salt of boric acid. odorless powder. resp sys Swallow: Medical attention immed 30 . Eyes: N.B Borates. dysp Breath: Resp support TO: Eyes. skin. Symptoms. derm. Con Skin: Soap wash SY: Irrit eyes.73 VP: 0 mmHg (approx) MLT: 167°F UEL: NA LEL: NA Noncombustible Solid (an inherent fire retardant). BP: 608°F Not available.2 Skin: N. epis. upper resp sys. Conversion: DOT: Synonyms/Trade Names: Anhydrous borax. Con Skin: Soap wash SY: Irrit eyes. [herbicide] [Note: Becomes opaque on exposure to air. Sodium borate decahydrate. tetra. derm. Sodium borate (anhydrous). sodium salts (Decahydrate) Formula: Na2B4O7×10H2O CAS#: 1303-96-4 RTECS#: VZ2275000 IDLH: N. Ing. Borax dehydrated. Sodium tetraborate Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): OSHA PEL†: none NIOSH 0500 OSHA ID125G Physical Description: White to gray. Conversion: DOT: Synonyms/Trade Names: Borax.Gr: 1. metallic salts Exposure Routes. sodium salts (Anhydrous) Formula: Na2B4O7 CAS#: 1330-43-4 RTECS#: ED4588000 IDLH: N. Disodium tetrabromate.P: NA Remove: N.R. Eyes: N. epis. crystalline solid. Sodium tetraborate decahydrate Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): NIOSH 0500 OSHA PEL†: none OSHA ID125G Physical Description: White.

odorless crystals or free-flowing powder. IP: NA Change: Daily Sp.Pp/SaF:Pd. Sodium borate pentahydrate. upper resp sys. resp sys. skin. Ing. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 69. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Borates.R. Symptoms. skin. resp sys Swallow: Medical attention immed B Formula: CAS#: RTECS#: IDLH: B2O3 1303-86-2 ED7900000 2000 mg/m3 Conversion: DOT: Synonyms/Trade Names: Boric anhydride. resp sys Swallow: Medical attention immed Boron oxide 31 . Sol: 3% Wash skin: Daily Fl.D.Gr: 1. white. Symptoms.50 eV 500 mg/m3: 100F/PaprTHie*/ScbaF/SaF Sp. Con Skin: Water flush prompt SY: Irrit eyes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 291. odorless crystals. derm. tetra.6 50 mg/m3: Qm* Eyes: Prevent eye contact BP: 3380°F Wash skin: When contam Sol: 3% 100 mg/m3: 95XQ*/Sa* Remove: When wet or contam Fl. dysp Breath: Resp support TO: Eyes.R. skin.Pp VP: 0 mmHg (approx) §: ScbaF:Pd. conj.P: NA Remove: N. Eyes: N.] Exposure Routes.P: NA 250 mg/m3: Sa:Cf*/PaprHie* Change: N.4 Skin: N.R.46 2000 mg/m3: SaF:Pd.] Exposure Routes.R. epis. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Boric oxide. [herbicide] [Note: Begins to lose water of hydration at 252°F. Con Skin: Soap wash SY: Irrit eyes. IP: 13. cough. BP: ? Not available. sodium salts (Pentahydrate) Formula: Na2B4O7×5H2O CAS#: 12179-04-3 RTECS#: VZ2540000 IDLH: N. Boron trioxide Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (see Table 1): 3 NIOSH 0500 OSHA PEL†: TWA 15 mg/m Physical Description: Colorless. Conversion: DOT: Synonyms/Trade Names: Borax pentahydrate. Ing. skin. cough.Pp:AScba MLT: 842°F Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Water [Note: Reacts slowly with water to form boric acid. semitransparent lumps or hard. skin eryt Breath: Fresh air TO: Eyes.82 VP: 0 mmHg (approx) MLT: 392°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported [Note: See the reactivities & incompatibilities reported for the related substance Borax decahydrate above.Gr: 2. Sodium tetraborate pentahydrate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 mg/m3 NIOSH 0500 OSHA PEL†: none OSHA ID125G Physical Description: Colorless or white.

IP: 15. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 250. resp sys Swallow: Medical attention immed Boron tribromide Formula: CAS#: RTECS#: IDLH: BF3 7637-07-2 ED2275000 25 ppm Conversion: 1 ppm = 2. suffocating odor. eye. skin. kidneys Boron trifluoride 32 . Sol: 106% (in cold H2O) §: ScbaF:Pd.R.R.R. Shipped as a nonliquefied compressed gas.P: NA Remove: When wet or contam IP: 9. Eyes: Prevent eye contact Sol: Decomposes Wash skin: When contam Fl.D. BP: -148°F 25 ppm: Sa:Cf*/ScbaF/SaF Wash skin: N. sodium. in animals: Breath: Resp support pneu.R.77 mg/m3 DOT: 1008 125 Synonyms/Trade Names: Boron fluoride. irritating odor. fuming liquid with a sharp. skin. Con Skin: Water flush immed SY: Irrit eyes.8 10 ppm: Sa* Eyes: N. Symptoms.25 mg/m3 DOT: 2692 157 Synonyms/Trade Names: Boron bromide.R.Pp/SaF:Pd. resp sys.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N.5 Skin: Prevent skin contact BP: 194°F Not available. pulm edema Skin: Water flush immed Breath: Resp support TO: Eyes. water. Symptoms.] Exposure Routes. Tribromoborane Exposure Limits: Measurement Methods NIOSH REL: C 1 ppm (10 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless. wood & rubber. [Note: Forms dense white fumes in moist air. Fl.70 eV Change: N. Conversion: 1 ppm = 10.Gr(65°F): 2. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. kidney damage TO: Eyes.64 Provide: Eyewash VP(57°F): 40 mmHg FRZ: -51°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Moisture. skin burns. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Trifluoroborane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 1 ppm (3 mg/m3) 3 OSHA PEL: C 1 ppm (3 mg/m ) None available Physical Description: Colorless gas with a pungent. epis. skin burns. heat.38 VP: >50 atm FRZ: -196°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Alkali metals. resp sys. resp sys. Con SY: Irrit eyes. hydrogen fluoride & fluoboric acid. potassium. Ing.R. eye. Sp. skin. dysp.50 eV RGasD: 2.B Formula: CAS#: RTECS#: IDLH: BBr3 10294-33-4 ED7400000 N. nose.P: NA Escape: GmFS/ScbaE Change: N.Pp:AScba Remove: N.] First Aid (see Table 6): Exposure Routes. calcium oxide [Note: Hydrolyzes in moist air or hot water to form boric acid. MW: 67. skin. alcohols [Note: Attacks metals. Reacts with water to form boric acid and hydrogen bromide.

open flames Exposure Routes. upper resp sys. Symptoms. abdom pain. wood. skin. readily oxidizable materials. Con Skin: Soap wash immed SY: Irrit eyes.8 NIOSH/OSHA Skin: Prevent skin contact BP: 139°F 2. Symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 261. Ing. ammonia. Con Skin: Soap wash immed SY: Dizz. heat. phosphorus. but accelerates the burning of combustibles. sparks. eye.1 ppm (0. potassium. cotton. in animals: thyroid inj Breath: Resp support TO: Eyes. aluminum. CNS. [herbicide] [Note: Commercially available as a wettable powder or in liquid formulations.55 eV ScbaF/SaF §: ScbaF:Pd.P: NA Remove: When wet or contam IP: 10. measle-like eruptions.). Incompatibilities and Reactivities: Strong acids (decomposes slowly). Incompatibilities and Reactivities: Combustible organics (sawdust.Pp/SaF:Pd.2 Skin: Prevent skin contact BP: Sublimes Not available. skin Formula: Br2 DOT: 1744 154 CAS#: 7726-95-6 RTECS#: EF9100000 IDLH: 3 ppm 33 . epis.] First Aid (see Table 6): Exposure Routes. feeling of oppression. sodium [Note: Corrodes iron.68 mg/m3 DOT: Synonyms/Trade Names: 5-Bromo-3-sec-butyl-6-methyluracil.7 mg/m ) Physical Description: Dark reddish-brown. oxidizers. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 159. stainless steel & copper.Gr: 3. pulm edema. crystalline solid.R. colorless to white. lac. skin. Target Organs (see Table 5): Eye: Irr immed ER: Inh. steel. 5-Bromo-6-methyl-3-(1-methylpropyl)uracil Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (10 mg/m3) (see Table 1): NIOSH 0500 OSHA PEL†: none Physical Description: Odorless. thyroid Swallow: Medical attention immed Bromacil B Bromine Conversion: 1 ppm = 6.Gr: 1.P: NA Remove: When wet or contam IP: ? Change: Daily Sp.1 ppm (0.3 ppm (2 mg/m ) 3 OSHA ID108 OSHA PEL†: TWA 0. etc. straw. skin burns Swallow: Medical attention immed TO: Resp sys.Pp:AScba Change: N. eyes. Breath: Resp support pneu.7 mg/m3) (see Table 1): 3 NIOSH 6011 ST 0.D.5 ppm: Sa:Cf£/PaprS¿£ Eyes: Prevent eye contact Sol: 4% 3 ppm: CcrFS¿/GmFS¿/PaprTS¿£/ Wash skin: When contam Fl. but may be dissolved in flammable liquids. resp sys.55 Provide: Eyewash VP(212°F): 0.0008 mmHg MLT: 317°F (Sublimes) Quick drench UEL: NA LEL: NA Noncombustible Solid. Sp. irritating fumes. fuming liquid with suffocating. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Conversion: 1 ppm = 10. Ing. Eyes: Prevent eye contact Sol(77°F): 0. cough. hydrogen. head. diarr.08% Wash skin: When contam Fl. acetylene.54 mg/m3 Synonyms/Trade Names: Molecular bromine Exposure Limits: Measurement Methods NIOSH REL: TWA 0.12 Escape: GmFS¿/ScbaE Provide: Eyewash VP: 172 mmHg FRZ: 19°F Quick drench UEL: NA LEL: NA Noncombustible Liquid.Formula: CAS#: RTECS#: IDLH: C9H13BrN2O2 314-40-9 YQ9100000 N.

magnesium.Pp IP: 10. sulfur. Formula: CAS#: RTECS#: IDLH: CHBr3 75-25-2 PB5600000 850 ppm Conversion: 1 ppm = 10. Ing. fuming liquid with a pungent odor. water [Note: Reacts with all elements except inert gases.48 eV §: ScbaF:Pd. skin. zinc. cough. CNS depres. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Abs.P: NA Remove: When wet or contam IP: ? Change: N.R.9 Skin: Prevent skin contact BP: 105°F Not available.48 Provide: Eyewash VP: 328 mmHg FRZ: -77°F Quick drench UEL: NA LEL: NA Noncombustible Liquid. kidney inj Swallow: Medical attention immed TO: Eyes. acetone [Note: Gradually decomposes. [Note: A solid below 47°F. liver. 850 ppm: SaF:Pd.Gr: 2.B Bromine pentafluoride Conversion: 1 ppm = 7.5 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 301°F 25 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: 0. skin.] Exposure Routes. Symptoms. strong caustics. Ing.Gr: 2. kidney damage Skin: Soap wash prompt Breath: Resp support TO: Eyes. Symptoms. liver. Incompatibilities and Reactivities: Acids. Sp. skin. Skin: Water flush immed Breath: Resp support pulm edema. selenium.D. Con SY: Irrit eyes.R.89 Escape: GmFOv/ScbaE VP: 5 mmHg FRZ: 47°F UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Lithium.1% Remove: When wet or contam Fl.P: NA ScbaF/SaF Change: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 174. kidneys Swallow: Medical attention immed Bromoform 34 . corn nec.5 ppm (5 mg/m3) [skin] (see Table 1): 3 NIOSH 1003 OSHA PEL: TWA 0. [Note: A colorless gas above 105°F. resp sys. resp sys.15 mg/m3 Synonyms/Trade Names: Bromine fluoride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. sodium. nitrogen & oxygen. calcium. liver. liver.5 ppm (5 mg/m ) [skin] OSHA 7 Physical Description: Colorless to yellow liquid with a chloroform-like odor. kidneys Formula: BrF5 DOT: 1745 144 CAS#: 7789-30-2 RTECS#: EF9350000 IDLH: N.Pp/SaF:Pd. air & light accelerate decomposition. halogens. skin burns.1 ppm (0. resp sys.8 12.] Exposure Routes. dysp.Pp:AScba Sp.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 252. glass. Shipped as a compressed gas. Eyes: Prevent eye contact Sol: Reacts violently Wash skin: When contam Fl. aluminum. acquiring yellow color. Con Eye: Irr immed SY: Irrit eyes. but a very powerful oxidizer. CNS.34 mg/m3 DOT: 2515 159 Synonyms/Trade Names: Methyl tribromide.7 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless to pale-yellow. potassium. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. arsenic. Tribromomethane Exposure Limits: Measurement Methods NIOSH REL: TWA 0. organic materials. resp sys. skin.

Formula: CAS#: RTECS#: IDLH: CH2=CHCH=CH2 106-99-0 EI9275000 Ca [2000 ppm] [10%LEL] Conversion: 1 ppm = 2.65 (Liquid at 24°F) VP: 2.0% LEL: 2.1 (see Table 2): BP: 31°F Skin: Frostbite Not available. A liquid below 31°F. narco.R. Diethyl. Conversion: 1 ppm = 2. Butyl hydride.1051] TWA 1 ppm ST 5 ppm Physical Description: Colorless gas with a mild aromatic or gasoline-like odor. IP: 9. May form explosive peroxides upon exposure to air. Erythrene.1 NIOSH Skin: Frostbite BP: 24°F ¥: ScbaF:Pd. [Note: A liquid below 24°F.Pp:AScba Eyes: Frostbite Sol: Insoluble Escape: GmFS/ScbaE Wash skin: N.0% Flammable Gas Incompatibilities and Reactivities: Phenol. liquid: frostbite TO: CNS First Aid (see Table 6): Eye: Frostbite Skin: Frostbite Breath: Resp support 35 .07 eV Provide: Frostbite wash RGasD: 1. [carc] TO: Eyes.R. Breath: Resp support repro effects. CNS. liquid: frostbite.. Shipped as a liquefied compressed gas.38 mg/m DOT: 1011 115.g. resp sys.Pp/SaF:Pd. Fl.6% perchlorates).Gr: 0.63 eV Remove: When wet (flamm) RGasD: 2. Methylethylmethane [Note: Also see specific listing for Isobutane.P: NA (Gas) Wash skin: N. chlorine dioxide. nitrates and LEL: 1.g. fluorine.3-Butadiene B Formula: CAS#: RTECS#: IDLH: CH3CH2CH2CH3 106-97-8 EJ4200000 N.88 Sp. repro sys [hemato cancer] 1. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh.21 mg/m3 DOT: 1010 116P (inhibited) Synonyms/Trade Names: Biethylene.] Exposure Limits: Measurement Methods NIOSH REL: TWA 800 ppm (1900 mg/m3) (see Table 1): OSHA 56 OSHA PEL†: none Physical Description: Colorless gas with a gasoline-like or natural gas odor. crotonaldehyde [Note: May contain inhibitors (e. chlorine. tributylcatechol) to prevent self-polymerization.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 58.Gr: 0. (nickel carbonyl + oxygen) Flammable Gas n-Butane 3 Exposure Routes. dizz. IP: 10.05 atm FRZ: -217°F UEL: 8. Symptoms. Butadiene.] Exposure Routes. Con (liquid) SY: Drow. asphy.11 Change: N.P: NA (Gas) Remove: When wet (flamm) -105°F (Liquid) See Appendix E (page 351) Change: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 54. Vinylethylene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1024 See Appendix A OSHA 56 OSHA PEL: [1910.R.R. copper. nose. Con (liquid) Skin: Frostbite SY: Irrit eyes. 1075 115 Synonyms/Trade Names: normal-Butane. Bivinyl.4% Incompatibilities and Reactivities: Strong oxidizers (e. terato. Sol: Slight Eyes: Frostbite Fl..D.6 (Liquid at 31°F) Provide: Frostbite wash VP: 2. drow. [Note: Shipped as a liquefied compressed gas. Sp.4 atm FRZ: -164°F UEL: 12. Divinyl. Target Organs (see Table 5): ER: Inh. throat. Symptoms.

Pp/SaF:Pd. inorganic acids. kidneys. Ing. 1004 OSHA PEL†: TWA 200 ppm (590 mg/m ) Physical Description: Colorless liquid with a moderately sharp. lymphoid sys 2-Butoxyethanol 3 36 .1 3000 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 175°F Wash skin: When contam Sol: 28% GmFOv/ScbaF/SaF §: ScbaF:Pd. throat. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. vomit Swallow: Medical attention immed TO: Eyes. liver. skin.1% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. Ethylene glycol monobutyl ether.or acetone-like odor. IP: 9.Gr: 0. strong caustics Exposure Routes.Gr: 0. 84. Jeffersol EB Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (24 mg/m3) [skin] (see Table 1): NIOSH 1403 OSHA PEL†: TWA 50 ppm (240 mg/m3) [skin] OSHA 83 Physical Description: Colorless liquid with a mild. Symptoms.4% LEL(200°F): 1. ether-like odor. skin. hemolysis. Abs. Skin: Soap wash prompt Breath: Resp support head.Pp/SaF:Pd. Butyl oxitol. head. amines. resp sys. 3800 ST 300 ppm (885 mg/m ) 3 OSHA 16.90 §: ScbaF:Pd. vomit. blood.P: 143°F Change: N. CNS Swallow: Medical attention immed 2-Butanone CAS#: RTECS#: IDLH: Formula: 111-76-2 KJ8575000 700 ppm C4H9OCH2CH2OH Conversion: 1 ppm = 4. skin. CNS depres. fragrant.54 eV Provide: Eyewash Sp. Symptoms. dizz.7% LEL(200°F): 1. IP: 10. nose. Con Eye: Irr immed SY: Irrit eyes.R. isocyanates. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 118.00 eV ScbaF/SaF 700 ppm: SaF:Pd. nose. MEK.83 mg/m DOT: 2369 152 Synonyms/Trade Names: Butyl Cellosolve®.4% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. caustics. Methyl ethyl ketone Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (590 mg/m3) (see Table 1): 3 NIOSH 2500.Pp:AScba VP: 0.Pp Provide: Quick drench Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 72. resp sys. derm Breath: Fresh air TO: Eyes. pyridines Exposure Routes. Con Skin: Water wash immed SY: Irrit eyes.P: 16°F Escape: GmFOv/ScbaE Change: N.8 mmHg Escape: GmFOv/ScbaE FRZ: -107°F UEL(275°F): 12. mint. EGBE.B Formula: CAS#: RTECS#: IDLH: CH3COCH2CH3 78-93-3 EL6475000 3000 ppm Conversion: 1 ppm = 2.81 VP: 78 mmHg FRZ: -123°F UEL(200°F): 11. hemato sys. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp:AScba Remove: When wet (flamm) Fl. Dowanol® EB. 2555. CNS. Ing.R. ammonia.2 50 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 339°F 125 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: Miscible 250 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl. Methyl acetone. skin.95 mg/m3 DOT: 1193 127 Synonyms/Trade Names: Ethyl methyl ketone. hema. Ektasolve EB®.

skin. nose. Ektasolve EB® acetate.88 VP: 10 mmHg FRZ: -107°F UEL: 7. fruity odor. alkalis & acids Exposure Routes.Pp:AScba Change: N.Gr: 0. CNS depres. liver.5% 250 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet (flamm) Fl. Ing. CNS Swallow: Medical attention immed n-Butyl acetate 37 .P: 160°F Change: N.88% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes. sweet.3 mmHg Escape: GmFOv/ScbaE FRZ: -82°F UEL(275°F): 8. kidneys. Ing.2 1500 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 258°F 1700 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Wash skin: When contam Sol: 1% Remove: When wet (flamm) Fl. hema. Ethylene glycol monobutyl ether acetate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 ppm (33 mg/m3) OSHA 83 OSHA PEL: none Physical Description: Colorless liquid with a pleasant.Gr: 0. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. throat.Pp Sp. Symptoms.55 mg/m3 DOT: Synonyms/Trade Names: 2-Butoxyethyl acetate. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 116.7% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates.6% LEL: 1. strong oxidizers. Con Skin: Water flush prompt SY: Irrit eyes.Pp:AScba VP: 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 160. Butyl Cellosolve® acetate. hemato sys. blood.D. hemolysis.54% LEL(200°F): 0.Pp/SaF:Pd. drow. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp/SaF:Pd.2 50 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 378°F 125 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 1. Conversion: 1 ppm = 6.94 §: ScbaF:Pd. skin. Con Eye: Irr immed SY: Irrit eyes.P: 72°F GmFOv/ScbaF/SaF §: ScbaF:Pd. upper resp sys. IP: ? ScbaF/SaF 700 ppm: SaF:Pd. CNS. n-Butyl ester of acetic acid. Butyl glycol acetate.00 eV Escape: GmFOv/ScbaE Sp. Butyl ethanoate Exposure Limits: Measurement Methods NIOSH REL: TWA 150 ppm (710 mg/m3) (see Table 1): 3 NIOSH 1450 ST 200 ppm (950 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 150 ppm (710 mg/m ) Physical Description: Colorless liquid with a fruity odor. head.75 mg/m3 DOT: 1123 129 Synonyms/Trade Names: Butyl acetate.R.Formula: CAS#: RTECS#: IDLH: C4H9O(CH2)2OCOCH3 112-07-2 KJ8925000 N. resp sys. IP: 10. EGBEA. narco Breath: Resp support TO: Eyes. Abs. resp sys. Symptoms.R. skin. lymphoid Breath: Resp support Swallow: Medical attention immed sys 2-Butoxyethanol acetate B Formula: CAS#: RTECS#: IDLH: CH3COO[CH2]3CH3 123-86-4 AF7350000 1700 ppm [10%LEL] Conversion: 1 ppm = 4. head. skin. vomit Skin: Soap wash prompt TO: Eyes.

CNS Swallow: Medical attention immed tert-Butyl acetate 38 . Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. sec-Butyl acetate Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 116.Pp:AScba Fl. narco Breath: Resp support TO: Eyes. dryness upper resp sys.Gr: 0. skin.2 1500 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 208°F Wash skin: When contam Sol: Insoluble GmFOv/ScbaF/SaF Remove: When wet (flamm) §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.P: 72°F Change: N.75 mg/m3 DOT: 1123 129 Synonyms/Trade Names: sec-Butyl ester of acetic acid. alkalis & acids Exposure Routes. inflamm eyes.8% GmFOv/ScbaF/SaF Remove: When wet (flamm) §: ScbaF:Pd. strong oxidizers. Ing. skin.86 VP: 10 mmHg FRZ: -100°F UEL: 9.Pp:AScba Fl. skin.Gr: 0. Con SY: Itch. Escape: GmFOv/ScbaE IP: ? Sp. strong oxidizers. Escape: GmFOv/ScbaE IP: 9.91 eV Sp. narco. derm Skin: Water flush prompt Breath: Resp support TO: Resp sys. CNS Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: CH3COOC(CH3)3 540-88-5 AF7400000 1500 ppm [10%LEL] Conversion: 1 ppm = 4. drow.5% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 116. Symptoms.Pp/SaF:Pd. fruity odor. Symptoms. eyes.R.2 1700 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 234°F Wash skin: When contam Sol: 0.7% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates.P: 62°F Change: N. head. alkalis & acids Exposure Routes.8% LEL: 1. irrit upper resp tract. head. Ing. Con Skin: Water flush prompt SY: Irrit eyes. resp sys.B Formula: CAS#: RTECS#: IDLH: CH3COOCH(CH3)CH2CH3 105-46-4 AF7380000 1700 ppm [10%LEL] Conversion: 1 ppm = 4.R.75 mg/m3 DOT: 1123 129 Synonyms/Trade Names: tert-Butyl ester of acetic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (950 mg/m3) (see Table 1): 3 OSHA PEL: TWA 200 ppm (950 mg/m ) NIOSH 1450 OSHA 7 Physical Description: Colorless liquid with a fruity odor. 1-Methylpropyl acetate Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (950 mg/m3) (see Table 1): 3 NIOSH 1450 OSHA PEL: TWA 200 ppm (950 mg/m ) OSHA 7 Physical Description: Colorless liquid with a pleasant.87 VP: ? FRZ: ? UEL: ? LEL: 1.Pp/SaF:Pd.

hydrogen compounds. sunlight [Note: Polymerizes readily on heating. Eyes: Prevent eye contact Sol: 0. characteristic. corn inflamm.] Exposure Routes.5% Class II Combustible Liquid Incompatibilities and Reactivities: Strong acids & alkalis. skin. nose.1 1250 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 243°F 1400 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: 9% Remove: When wet (flamm) Fl. Symptoms. Target Organs (see Table 5): Eye: Irr immed ER: Inh.Gr: 0. Butyl ester of acrylic acid. 1405 OSHA PEL†: TWA 100 ppm (300 mg/m ) OSHA 7 Physical Description: Colorless liquid with a strong. upper resp sys. dizz. lac.03 mg/m3 DOT: 1120 129 Synonyms/Trade Names: 1-Butanol. Con SY: Irrit eyes.Pp:AScba Change: N.P: 103°F Remove: When wet or contam IP: ? Change: N.81 VP: 6 mmHg FRZ: -129°F UEL: 11. mildly alcoholic odor.2 Skin: Prevent skin contact BP: 293°F Not available. Conversion: 1 ppm = 5. derm.Formula: CAS#: RTECS#: IDLH: CH2=CHCOOC4H9 141-32-2 UD3150000 N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 74. n-Butanol.89 Provide: Eyewash VP: 4 mmHg FRZ: -83°F Quick drench UEL: 9. skin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 128. Abs. photo. halogens.Gr: 0. Ing. dysp Breath: Resp support TO: Eyes.R. possible auditory nerve damage. Symptoms. CNS n-Butyl alcohol 39 .4% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. resp sys. head. Ing. throat. Sp.1% Wash skin: When contam Fl. halogens First Aid (see Table 6): Exposure Routes. Butyl-2-propenoate Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (55 mg/m3) (see Table 1): OSHA PV2011 OSHA PEL†: none Physical Description: Clear. strong mineral acids. Abs. fruity odor. drow. heat. hearing Swallow: Medical attention immed loss. oxidizers.R. CNS depres TO: Eyes.P: 84°F ScbaF/SaF §: ScbaF:Pd. 1-Hydroxybutane. may contain an inhibitor to prevent spontaneous polymerization.04 eV Escape: GmFOv/ScbaE Sp. amines.2% LEL: 1.D. Con Skin: Soap wash immed SY: Irrit eyes.Pp/SaF:Pd. IP: 10. blurred Skin: Water flush prompt Breath: Resp support vision. sens derm. alkali metals. resp sys Swallow: Medical attention immed Butyl acrylate B CAS#: RTECS#: IDLH: Formula: EO1400000 1400 ppm [10%LEL] CH3CH2CH2CH2OH 71-36-3 Conversion: 1 ppm = 3.9% LEL: 1.24 mg/m3 DOT: 2348 130P Synonyms/Trade Names: n-Butyl acrylate. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. flame. Butyl alcohol. colorless liquid with a strong. [Note: Highly reactive. n-Propyl carbinol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 50 ppm (150 mg/m3) [skin] 3 NIOSH 1401. skin.

strong hydrochloric acid. IP: 9. skin. throat.Gr: 0. perchloric & permonosulfuric acids Exposure Routes. Butylene hydrate.0% LEL: 2. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. pleasant odor. drow.Pp:AScba Change: N.8% LEL(212°F): 1. Con Skin: Water flush prompt SY: Irrit eyes.79 (Solid) VP(77°F): 42 mmHg FRZ: 78°F UEL: 8. skin. nose. CNS Swallow: Medical attention immed tert-Butyl alcohol 40 .1 1000 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 211°F 2000 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Wash skin: When contam Sol: 16% Remove: When wet (flamm) Fl.Pp/SaF:Pd.Pp/SaF:Pd.1 1600 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 180°F Wash skin: When contam Sol: Miscible GmFOv/ScbaF/SaF §: ScbaF:Pd. organic peroxides. nose. narco Breath: Resp support TO: Eyes. Trimethyl carbinol Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (300 mg/m3) (see Table 1): 3 NIOSH 1400 ST 150 ppm (450 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 100 ppm (300 mg/m ) Physical Description: Colorless solid or liquid (above 77°F) with a camphor-like odor.P: 75°F GmFOv/ScbaF/SaF §: ScbaF:Pd.Gr: 0. 1405 ST 150 ppm (455 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 150 ppm (450 mg/m ) Physical Description: Colorless liquid with a strong.03 mg/m3 DOT: 1120 129 Synonyms/Trade Names: 2-Methyl-2-propanol. 2-Hydroxybutane. resp sys.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. Methyl ethyl carbinol Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (305 mg/m3) (see Table 1): 3 NIOSH 1401.10 eV Escape: GmFOv/ScbaE Sp. oxidizers Exposure Routes. Symptoms.81 VP: 12 mmHg FRZ: -175°F UEL(212°F): 9.4% Combustible Solid Class IB Flammable Liquid Incompatibilities and Reactivities: Strong mineral acids. skin.03 mg/m3 DOT: 1120 129 Synonyms/Trade Names: 2-Butanol.7% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. CNS Swallow: Medical attention immed sec-Butyl alcohol CAS#: RTECS#: IDLH: Formula: 75-65-0 EO1925000 1600 ppm (CH3)3COH Conversion: 1 ppm = 3. resp sys. Ing.P: 52°F Escape: GmFOv/ScbaE Change: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 74. [Note: Often used in aqueous solutions. Con Skin: Water flush prompt SY: Irrit eyes.70 eV Sp. Ing. skin. narco Breath: Resp support TO: Eyes.Pp:AScba Remove: When wet (flamm) Fl. throat. IP: 10.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 74.B Formula: CAS#: RTECS#: IDLH: CH3CH(OH)CH2CH3 78-92-2 EO1750000 2000 ppm Conversion: 1 ppm = 3.

Pp/SaF:Pd. Symptoms. IP: ? Provide: Eyewash Sp. skin. resp sys.7% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. [carc] Swallow: Medical attention immed TO: Eyes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Formula: CAS#: RTECS#: IDLH: CH3CH2CH2CH2NH2 109-73-9 EO2975000 300 ppm Conversion: 1 ppm = 2. ammonia-like odor. hydrazine. moisture. Ing. skin. resp sys.2 NIOSH/OSHA Skin: Prevent skin contact BP: 172°F 50 ppm: CcrS*/Sa* Eyes: Prevent eye contact Sol: Miscible 125 ppm: Sa:Cf*/PaprS* Wash skin: When contam Fl. Sp. burns Breath: Resp support TO: Eyes. [Note: Solidifies at 32-23°F.Pp:AScba FRZ: -58°F Quick drench Escape: GmFS/ScbaE UEL: 9.71 eV Change: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R.99 mg/m3 DOT: 1125 132 Synonyms/Trade Names: 1-Aminobutane. CNS [lung cancer] tert-Butyl chromate 41 . Butylamine Exposure Limits: Measurement Methods NIOSH REL: C 5 ppm (15 mg/m3) [skin] (see Table 1): 3 NIOSH 2012 OSHA PEL: C 5 ppm (15 mg/m ) [skin] Physical Description: Colorless liquid with a fishy.] Exposure Routes. ID215 See Appendix A See Appendix C 3 OSHA PEL: C 0.3 ¥: ScbaF:Pd. acids.Pp:AScba Eyes: Prevent eye contact BP: ? Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: ? Remove: When wet or contam Fl.8% LEL: 1. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 73. Con SY: Irrit eyes. Symptoms. strong acids [Note: May corrode some metals in presence of water. head.P: 10°F 250 ppm: CcrFS/GmFS/PaprTS*/ Remove: When wet (flamm) IP: 8. skin flush. resp sys Swallow: Medical attention immed n-Butylamine B Formula: CAS#: RTECS#: IDLH: [(CH3)3CO]2CrO2 1189-85-1 GB2900000 Ca [15 mg/m3 {as Cr(VI)}] Conversion: DOT: Synonyms/Trade Names: di-tert-Butyl ester of chromic acid Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 7604 TWA 0. alcohols. Ing.Gr: 0. Abs. Abs. skin burns.1 mg CrO3/m [skin] See Appendix C Physical Description: Liquid. nose.P: ? Change: N. eye.R.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 230.Pp/SaF:Pd. combustible materials Exposure Routes.Gr: ? VP: ? Quick drench FRZ: 32-23°F UEL: ? LEL: ? Incompatibilities and Reactivities: Reducing agents. Skin: Soap wash immed Breath: Resp support skin ulcers. Con Skin: Water flush immed SY: Irrit eyes. throat. skin.Pp Provide: Eyewash VP: 82 mmHg §: ScbaF:Pd.74 ScbaF/SaF 300 ppm: SaF:Pd. lung changes. skin.001 mg Cr(VI)/m OSHA ID103. musc weak. drow.

P: 130°F Change: N. Sp.2 56 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 327°F 140 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 2% 250 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Butyl ester of lactic acid. sparks. possible hemato Skin: Soap wash immed Breath: Resp support effects. Butyl lactate Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (25 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Clear. transient odor. skin sens. Symptoms. CNS depres Swallow: Medical attention immed TO: Eyes. blood n-Butyl glycidyl ether Formula: CAS#: RTECS#: IDLH: CH3CH(OH)COOC4H9 138-22-7 OD4025000 N. CNS depres.R.R. open flames First Aid (see Table 6): Exposure Routes.91 Escape: GmFOv/ScbaE VP(77°F): 3 mmHg FRZ: ? UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. resp sys. Eyes: Prevent eye contact Sol: Slight Wash skin: When contam Fl. strong oxidizers.s. Ing.o. nose. skin.15% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong acids & bases.33 mg/m3 DOT: Synonyms/Trade Names: BGE. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): (see Table 2): MW: 146. resp sys. skin.2-Epoxy-3-butoxypropane Exposure Limits: Measurement Methods NIOSH REL: C 5.Gr: 0.Pp/SaF:Pd. head. Con SY: Irrit eyes. Ing. colorless to white liquid with a mild. vomit Skin: Soap wash immed Breath: Resp support TO: Eyes.98 mg/m3 DOT: 1993 128 (combustible liquid.98 Provide: Eyewash VP: 0.Gr: 0.4 mmHg FRZ: -45°F Quick drench UEL: ? LEL: 1. skin. nose.P: 160°F Remove: When wet or contam IP: ? Change: N. narco. skin. CNS Swallow: Medical attention immed n-Butyl lactate 42 .B Formula: CAS#: RTECS#: IDLH: C7H14O2 2426-08-6 TX4200000 250 ppm Conversion: 1 ppm = 5. n. IP: ? ScbaF/SaF §: ScbaF:Pd.D. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 130.6 ppm (30 mg/m3) [15-minute] (see Table 1): 3 NIOSH 1616 OSHA PEL†: TWA 50 ppm (270 mg/m ) OSHA 7 Physical Description: Colorless liquid with an irritating odor. throat. drow. Conversion: 1 ppm = 5. nau.Pp:AScba Sp. Con Eye: Irr immed SY: Irrit eyes. strong caustics Exposure Routes. 1. Symptoms. CNS.2 Skin: Prevent skin contact BP: 370°F Not available. heat.) Synonyms/Trade Names: Butyl ester of 2-hydroxypropanoic acid.

Target Organs (see Table 5): Eye: Irr immed ER: Inh.5 ppm (1. Con Skin: Soap flush immed SY: Irrit eyes.2 Skin: Prevent skin contact BP: 227°F Not available.15 eV §: ScbaF:Pd. liver. or skunk-like odor.R. in Skin: Soap wash prompt Breath: Resp support animals: narco. 2542 OSHA PEL†: TWA 10 ppm (35 mg/m ) Physical Description: Colorless liquid with a strong. cyan. CH3CH2CH(CH3)C6H4OH 89-72-5 Conversion: 1 ppm = 6. n-Butanethiol. mal. Symptoms. sweat. skin. 2-(1-Methylpropyl)phenol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 ppm (30 mg/m3) [skin] OSHA PEL†: none None available Physical Description: Colorless liquid or solid (below 61°F). cabbage-. skin. kidney damage Swallow: Medical attention immed TO: Eyes.06% 25 ppm: CcrFOv/GmFOv/PaprTOv/ScbaF/SaF Remove: When wet (flamm) Fl.Pp/SaF:Pd.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: 0. Ing. lass.Pp:AScba Sp. skin. Abs. vomit. liver. acids First Aid (see Table 6): Exposure Routes. conf. inco.P: 225°F Remove: When wet or contam IP: ? Change: N. Sp.P: 35°F 500 ppm: Sa:Pd. skin.Gr: 0. 1-Butanethiol.CAS#: RTECS#: IDLH: Formula: EK6300000 500 ppm CH3CH2CH2CH2SH 109-79-5 Conversion: 1 ppm = 3. resp sys Swallow: Medical attention immed o-sec-Butylphenol 43 . head.8 mg/m3) [15-minute] (see Table 1): 3 NIOSH 2525. kidneys n-Butyl mercaptan B CAS#: RTECS#: IDLH: Formula: SJ8920000 N.2 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 209°F 12.14 mg/m3 DOT: Synonyms/Trade Names: 2-sec-Butylphenol.Pp* Change: N.69 mg/m3 DOT: 2347 130 Synonyms/Trade Names: Butanethiol. resp sys.Gr: 0. CNS. pulm irrit. musc weak. skin burns Breath: Resp support TO: Eyes. Ing. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.83 Escape: GmFOv/ScbaE VP: 35 mmHg FRZ: -176°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers (such as dry bleaches). 1-Mercaptobutane Exposure Limits: Measurement Methods NIOSH REL: C 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 150.R.89 Provide: Eyewash VP: Low FRZ: 61°F Quick drench UEL: ? LEL: ? Class IIB Combustible Liquid Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 90.D. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Con SY: Irrit eyes. nau. resp sys. IP: 9. garlic-. Symptoms.

IP: 11. CNS.1 80 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 244°F 200 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol(77°F): 3% 400 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) Fl. CNS. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 148. Propyl cyanide. strong acids & bases Exposure Routes.67 eV ScbaF/SaF 1000 ppm: SaF:Pd. abnor Skin: Water flush prompt CVS stress.R. dizz.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.83 mg/m3 DOT: 2411 131 Synonyms/Trade Names: Butanenitrile. skin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 69.65% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers & reducing agents. Symptoms. abdom pain. Symptoms.Pp:AScba Remove: When wet or contam Fl. Con Skin: Soap wash immed SY: Irrit eyes. hemato depres. CNS. nau. Ing. resp sys. liver.B Formula: CAS#: RTECS#: IDLH: (CH3)3CC6H4CH3 98-51-1 XS8400000 100 ppm Conversion: 1 ppm = 6. skin.Pp:AScba VP: 14 mmHg Escape: GmFOv/ScbaE FRZ: -170°F UEL: ? LEL: 1. Breath: Resp support dysp. low BP. suffocating odor. Con SY: Irrit eyes.Pp/SaF:Pd. conf. Ing. resp sys. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. tacar. kidney inj Breath: Resp support TO: Eyes. CH3CH2CH2CN Conversion: 1 ppm = 2. IP: 8.3 100 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 379°F Wash skin: When contam Sol: Insoluble GmFOv/ScbaF/SaF §: ScbaF:Pd.28 eV Sp.7 mmHg FRZ: -62°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes. dry nose.Gr: 0. kidneys Swallow: Medical attention immed p-tert-Butyltoluene CAS#: RTECS#: IDLH: Formula: 109-74-0 ET8750000 N. 1-Cyanopropane. skin. bone marrow. lass. Abs. metallic taste. liver. resp sys.R.86 VP(77°F): 0.D. [Note: Forms cyanide in the body. somewhat like gasoline.P: 62°F Change: N. CVS.81 §: ScbaF:Pd. 1-Methyl-4-tert-butylbenzene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (60 mg/m3) 3 NIOSH 1501 ST 20 ppm (120 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 10 ppm (60 mg/m ) Physical Description: Colorless liquid with a distinct aromatic odor. skin.07 mg/m3 DOT: 2667 152 Synonyms/Trade Names: 4-tert-Butyltoluene. head.Pp Provide: Quick drench Sp. n-Propyl cyanide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 8 ppm (22 mg/m3) NIOSH 1606 (adapt) OSHA PEL: none Physical Description: Colorless liquid with a sharp. throat. Butyronitrile.P: 155°F Escape: GmFOv/ScbaE Change: N. convuls.Gr: 0. CVS n-Butyronitrile 44 . head. vomit Swallow: Medical attention immed TO: Eyes.

elemental sulfur. but will burn in powder form. mild anemia.Pp:AScba Sol: Insoluble Eyes: N.R.005 mg/m [*Note: The REL and PEL apply to all Cadmium compounds (as Cd).] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 128. anos. ID206 OSHA PEL*: [1910.4 (see Table 2): NIOSH BP: Decomposes Skin: N. kidneys.Gr: 8.P: NA Wash skin: Daily IP: NA Remove: N. chest tight. Escape: 100F/ScbaE Fl. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: Ca NIOSH 7048. finely divided particulate dispersed in air. 7303. Cadmium dust (as Cd) C Exposure Routes. subs pain. prostate.15 (crystalline form) Change: Daily See Appendix E (page 351) 6. odorless solid. emphy. vomit. anos. nau. chills. ID125G. prot. yellow-brown. Target Organs (see Table 5): ER: Inh. ID189. emphy. 7300. ID125G.R. dysp.R. head. blood [prostatic & lung cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash Breath: Resp support Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: CdO/Cd 1306-19-0 (CdO) EV1930000 (CdO) Ca [9 mg/m3 (as Cd)] Conversion: DOT: Synonyms/Trade Names: CdO: Cadmium monoxide. blood [prostatic & lung cancer] Cadmium fume (as Cd) 45 . cough. chest tight. 9102 See Appendix A 3 OSHA ID121. ID206 OSHA PEL*: [1910. prot. musc aches.Gr: 8. [carc] TO: Resp sys. Ing SY: Pulm edema. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 112. Escape: 100F/ScbaE Fl. musc aches. Sp.R. Symptoms.] Physical Description: Odorless. 7301.Pp/SaF:Pd. selenium & tellurium form. nau.P: NA Wash skin: Daily IP: NA Remove: N. ¥: ScbaF:Pd.95 (amorphous form) VP: 0 mmHg (approx) MLT: 2599°F UEL: NA LEL: NA Incompatibilities and Reactivities: Not applicable Noncombustible Solid Exposure Routes.65 (metal) Change: Daily VP: 0 mmHg (approx) MLT: 610°F UEL: NA LEL: NA Metal: Noncombustible Solid in bulk Incompatibilities and Reactivities: Strong oxidizers. See Appendix E (page 351) Sp.4 (see Table 2): NIOSH BP: 1409°F Skin: N. 7300. ¥: ScbaF:Pd. vomit. mild anemia. chills.1027] TWA 0. diarr. subs pain. dysp. diarr.1027] TWA 0.] Physical Description: Metal: Silver-white.R.Pp:AScba Sol: Insoluble Eyes: N. Symptoms. kidneys. 7303 See Appendix A 3 OSHA ID121.R. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh Breath: Resp support SY: Pulm edema. cough. head.Formula: CAS#: RTECS#: IDLH: Cd (metal) 7440-43-9 (metal) EU9800000 (metal) Ca [9 mg/m3 (as Cd)] Conversion: DOT: 2570 154 (cadmium compound) Synonyms/Trade Names: Cadmium metal: Cadmium Other synonyms vary depending upon the specific cadmium compound. [carc] TO: Resp sys.005 mg/m [*Note: The REL and PEL apply to all Cadmium compounds (as Cd). [Note: See listing for Cadmium dust for properties of Cd. Cadmium oxide fume Cd: Cadmium Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: Ca NIOSH 7048. ID189. 7301.Pp/SaF:Pd. blue-tinged lustrous.

1 ¥: ScbaF:Pd. as As). Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. peri neur. Not available. Con SY: Irrit eyes. VP: 0 mmHg (approx) MLT: 1517-2442°F (Decomposes) UEL: NA Incompatibilities and Reactivities: Acids.62 VP: 0 mmHg (approx) Quick drench MLT: ? UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported [Note: Produces toxic fumes of arsenic when heated to decomposition. derm. [insecticide/herbicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 398.R. skin. Target Organs (see Table 5): ER: Inh. in animals: liver damage TO: Eyes. 7303 TWA 5 mg/m (resp) 3 OSHA ID121 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: White. LEL: NA mercury & hydrogen.R. Abs.1 (see Table 2): BP: Decomposes Skin: N. resp sys. odorless solid. Conversion: DOT: Synonyms/Trade Names: Calcium salt of carbonic acid [Note: Occurs in nature as as limestone.1018] TWA 0. calcite & oyster shells. aragonite. skin hyperpig. Symptoms. skin.002 mg/m [15-minute] OSHA ID105 See Appendix A 3 OSHA PEL: [1910. resp sys. marble. Fl.R. dolomite. magnesium Noncombustible Solid Calcium carbonate Exposure Routes.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 7020.D. cough TO: Eyes.C Formula: CAS#: RTECS#: IDLH: Ca3(AsO4)2 7778-44-1 CG0830000 Ca [5 mg/m3 (as As)] Conversion: DOT: 1573 151 Synonyms/Trade Names: Calcium salt (2:3) of arsenic acid. Tricalcium arsenate. Con Eye: Irr immed SY: Lass.Gr: 3.95 Change: N.] Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 7900 C 0. Ing. Symptoms. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 100. lymphatic sys [lymphatic & Swallow: Medical attention immed lung cancer] Calcium arsenate (as As) Formula: CAS#: RTECS#: IDLH: CaCO3 1317-65-3 EV9580000 N. fluorine. IP: NA Remove: N.01% Remove: When wet or contam Fl. Tricalcium ortho-arsenate [Note: Also see specific listing for Arsenic (inorganic compounds. alum. Cucumber dust.Gr: 2. palmar planter Skin: Soap wash prompt Breath: Resp support hyperkeratoses.Pp/SaF:Pd. CNS. liver. skin.R.] Exposure Routes.010 mg/m Physical Description: Colorless to white. chalk.001% Eyes: N. GI dist.R. odorless powder or colorless crystals. Sp. ammonium salts.P: NA Wash skin: N.Pp:AScba Eyes: Prevent eye contact BP: Decomposes Escape: 100F/ScbaE Wash skin: When contam/Daily Sol(77°F): 0.P: NA Change: Daily IP: NA Provide: Eyewash Sp. resp sys First Aid (see Table 6): Eye: Irr immed Skin: Soap wash Breath: Fresh air 46 .7-2. Sol: 0. [carc].

24 Provide: Eyewash VP: 0 mmHg (approx) MLT: 1076°F (Decomposes) (Loses H2O) Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Maleic anhydride. resp sys Calcium hydroxide 47 .Gr: 2. vomit. rapid breath. [fertilizer] [Note: Commercial grades may contain calcium carbide. gray. bron. Antabuse-like effects Swallow: Medical attention immed TO: Eyes. Lime nitrogen. Con Skin: Soap flush immed SY: Irrit eyes. Symptoms. Skin: Soap flush immed Breath: Resp support nau. Breath: Resp support cough. Nitrogen lime [Note: Cyanamide is also a synonym for Hydrogen cyanamide.1% calcium carbide) Synonyms/Trade Names: Calcium carbimide.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 80. nitropropane [Note: Attacks some metals.29 Change: Daily VP: 0 mmHg (approx) Provide: Eyewash MLT: 2444°F Quick drench UEL: NA Incompatibilities and Reactivities: Water LEL: NA [Note: May polymerize in water or alkaline solutions to dicyanamide. Con Eye: Irr immed SY: Irrit eyes. low BP.Formula: CAS#: RTECS#: IDLH: CaCN2 156-62-7 GS6000000 N.P: NA Wash skin: When contam IP: NA Remove: When wet or contam Sp. nitromethane. sens.P: NA Remove: When wet or contam IP: NA Change: Daily Sp. skin burns. Sol: Insoluble Eyes: Prevent eye contact Fl. Target Organs (see Table 5): Eye: Irr immed ER: Inh. skin.] if it contains calcium carbide. pneu Swallow: Medical attention immed TO: Eyes. Slaked lime Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 NIOSH 7020 OSHA PEL: TWA 15 mg/m3 (total) OSHA ID121 TWA 5 mg/m3 (resp) Physical Description: White. resp sys. skin. head. Ing. or black crystals or powder. odorless powder. Eyes: Prevent eye contact Sol(32°F): 0.] First Aid (see Table 6): Exposure Routes. nitroparaffins. Ing. Cyanamide. Noncombustible Solid. vasomotor sys Calcium cyanamide C Formula: CAS#: RTECS#: IDLH: Ca(OH)2 1305-62-0 EW2800000 N. skin. [Note: Readily absorbs CO2 from the air to form calcium carbonate.D. eye. Exposure Routes. phosphorus. NH2CN. Conversion: DOT: 1403 138 (with >0. cough. skin vesic.Gr: 2. skin burns. upper resp sys.D. resp sys. skin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 74.5 mg/m3 NIOSH 0500 OSHA PEL†: none Physical Description: Colorless. but a fire risk Decomposes in water to form acetylene & ammonia. Conversion: DOT: Synonyms/Trade Names: Calcium hydrate. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms.1 (see Table 2): BP: Sublimes Skin: Prevent skin contact Not available.1 Skin: Prevent skin contact BP: Decomposes Not available. dizz. nitroethane. Hydrated lime. Caustic lime.2% Wash skin: When contam/Daily Fl.

Con Skin: Soap wash SY: Irrit eyes. resp sys Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: CaSiO3 1344-95-2 VV9150000 N. Symptoms. Unslaked lime Exposure Limits: Measurement Methods NIOSH REL: TWA 2 mg/m3 (see Table 1): 3 NIOSH 7020.01% Wash skin: N. [Note: The commercial product is prepared from diatomaceous earth & lime. but will support combustion by liberation of oxygen. Sol: 0. IP: NA Change: N. Symptoms. skin. Con SY: Irrit eyes. free-flowing powder. Sp. fluorine. Calcium monosilicate. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. derm Skin: Water flush immed Breath: Resp support TO: Eyes. ulcer.Pp/SaF:Pd.Pp:AScba MLT: 4662°F Escape: 100F/ScbaE Quick drench UEL: NA LEL: NA Noncombustible Solid. perf nasal septum. Fl. Burnt lime. Calcium salt of silicic acid. Incompatibilities and Reactivities: Water (liberates heat). upper resp tract. Eyes: N. Calcium oxide Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 56. Calcium metasilicate.34 ScbaF/SaF Provide: Eyewash VP: 0 mmHg (approx) §: ScbaF:Pd. pneu.P: NA Remove: N.9 VP: 0 mmHg (approx) MLT: 2804°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported [Note: After prolonged contact with water.1 NIOSH Skin: Prevent skin contact BP: 5162°F 10 mg/m3: Qm Eyes: Prevent eye contact Sol: Reacts Wash skin: When contam/Daily 20 mg/m3: 95XQ/Sa Fl.C Formula: CAS#: RTECS#: IDLH: CaO 1305-78-8 EW3100000 25 mg/m3 Conversion: DOT: 1910 157 Synonyms/Trade Names: Burned lime.R. Ing.R. skin. skin.R.P: NA Remove: When wet or contam IP: NA 25 mg/m3: Sa:Cf/PaprHie/100F/ Change: Daily Sp.] First Aid (see Table 6): Exposure Routes. Pebble lime. ethanol [Note: Reacts with water to form calcium hydroxide.Gr: 2. Lime. Quick lime. Wollastonite (mineral) Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 7020 TWA 5 mg/m (resp) 3 OSHA ID121 OSHA PEL: TWA 15 mg/m (total) TWA 5 mg/m3 (resp) Physical Description: White or cream-colored.] Exposure Routes.D.2 Skin: N.Gr: 3. Target Organs (see Table 5): Eye: Irr immed ER: Inh. skin. solution reverts to soluble calcium salts & amorphous silica.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 116. odorless lumps or granular powder. BP: ? Not available. Conversion: DOT: Synonyms/Trade Names: Calcium hydrosilicate.R.R. upper resp sys Breath: Fresh air TO: Eyes. 7303 OSHA PEL: TWA 5 mg/m OSHA ID121 Physical Description: White or gray. resp sys Calcium silicate 48 .

Abs.Gr: 2. aluminum.6% Combustible Solid Incompatibilities and Reactivities: Strong oxidizers (especially chromic anhydride & potassium permanganate) Exposure Routes.99 §: ScbaF:Pd. [Note: May have blue.. resp sys. resp sys Calcium sulfate C CAS#: RTECS#: IDLH: Formula: 76-22-2 EX1225000 200 mg/m3 C10H16O Conversion: DOT: 2717 133 Synonyms/Trade Names: 2-Camphonone. water [Note: Hygroscopic (i.D.1 Skin: N. Anhydrous sulfate of lime. Sp.96 VP: 0 mmHg (approx) MLT: 2840°F (Decomposes) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Diazomethane. epis Breath: Fresh air TO: Eyes. skin.76 eV 200 mg/m3: SaF:Pd. Laurel camphor. conj. nau.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. head. Breath: Resp support excitement. Ing.3% Wash skin: N. crystalline solid. Symptoms.R.R.R. muc memb. diarr. Conversion: DOT: Synonyms/Trade Names: Anhydrous calcium sulfate. Con Skin: Soap wash immed SY: Irrit eyes.Pp Sp. Sol: 0. Reacts with water to form Gypsum & Plaster of Paris.5% LEL: 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Con Skin: Soap wash SY: Irrit eyes.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 152.] Exposure Routes. gray.3 50 mg/m3: Sa:Cf£/PaprOvHie£ Eyes: Prevent eye contact BP: 399°F Wash skin: When contam Sol: Insoluble 100 mg/m3: CcrFOv100/GmFOv100/ Remove: When wet or contam Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 136. skin. 2553 OSHA PEL: TWA 2 mg/m OSHA 7 Physical Description: Colorless or white crystals with a penetrating.P: NA Remove: N. Eyes: N. or reddish tinge. Synthetic camphor Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 mg/m3 3 NIOSH 1301. skin.Pp/SaF:Pd. Anhydrous gypsum.P: 150°F PaprTOvHie£/ScbaF/SaF Change: Daily IP: 8. BP: Decomposes Not available. dizz. Gum camphor. IP: NA Change: N. upper resp sys. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. rhinitis.e. absorbs moisture from the air). white powder or colorless.Gr: 0. aromatic odor. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Odorless.R.2 mmHg Escape: GmFOv100/ScbaE MLT: 345°F UEL: 3. Calcium salt of sulfuric acid [Note: Gypsum is the dihydrate form & Plaster of Paris is the hemihydrate form.Pp:AScba VP: 0. phosphorus. CNS Camphor (synthetic) 49 . Fl. Symptoms. skin.Formula: CAS#: RTECS#: IDLH: CaSO4 7778-18-9 WS6920000 N. epilep convuls Swallow: Medical attention immed TO: Eyes. vomit.

liver.Gr: 1. asthma. kidneys Caprolactam Formula: CAS#: RTECS#: IDLH: C10H9Cl14NO2S 2425-06-1 GW4900000 Ca [N. but may be Incompatibilities and Reactivities: Acids. [fungicide] [Note: Available commercially as a wettable powder or in liquid form. kidneys.P: NA Wash skin: When contam/Daily IP: NA Remove: When wet or contam Sp. CNS. Ing. Breath: Resp support vomit.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 113. Skin: Water wash immed Breath: Resp support dizz. diarr.01 Change: Daily VP: 0.Pp:AScba Sol: 0. kidney inj.63 mg/m3 DOT: Synonyms/Trade Names: Aminocaproic lactam.1 (see Table 2): NIOSH BP: Decomposes Skin: Prevent skin contact ¥: ScbaF:Pd.C CAS#: RTECS#: IDLH: Formula: 105-60-2 CM3675000 N. derm.000008 mmHg Provide: Eyewash MLT: 321°F (Decomposes) Quick drench UEL: NA LEL: NA Noncombustible Solid. conf.4% Incompatibilities and Reactivities: Strong oxidizers.22 ppm (1 mg/m ) 3 ST 0. strong oxidizers dissolved in flammable liquids. Symptoms. liver.2-dicarboximide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca OSHA PEL†: none NIOSH 0500 TWA 0. 2-Oxohexamethyleneimine Exposure Limits: Measurement Methods NIOSH REL: Dust: TWA 1 mg/m3 (see Table 1): 3 OSHA PV2012 ST 3 mg/m 3 Vapor: TWA 0. Symptoms. CVS [in animals: tumors at Swallow: Medical attention immed many sites] Captafol 50 . eyes. crystalline solid with a slight. resp sys. resp sys. derm. epsilon-Caprolactam. in animals: terato effects. head. resp sys. First Aid (see Table 6): Exposure Routes.] Conversion: DOT: Synonyms/Trade Names: Captofol. CNS. Combustible Solid (acetic acid + dinitrogen trioxide) Exposure Routes. abdom cramps.Pp/SaF:Pd.P: 282°F Wash skin: When contam IP: ? Remove: When wet or contam Sp.Gr: ? Change: Daily VP: 0. [carc] TO: Eyes.2 (see Table 2): BP: 515°F Skin: Prevent skin contact Not available.1 mg/m3 [skin] See Appendix A Physical Description: White. Con Eye: Irr immed SY: Irrit skin. skin sens. C2H11NO Conversion: 1 ppm = 4. skin. Con Skin: Soap wash immed SY: Irrit eyes.66 ppm (3 mg/m ) OSHA PEL†: none Physical Description: White. characteristic pungent odor. vomit. skin.00000008 mmHg MLT: 156°F UEL: 8. Abs. bron. epis. resp sys.0001% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. nau. skin.1. [Note: Significant vapor concentrations would be expected only at elevated temperatures. Hexahydro-2H-azepin-2-one.2-Tetrachloroethyl)thio)-4-cyclohexene-1.0% LEL: 1.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 349.D.D. diarr. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. N-((1. skin sens. Ing. Difolatan®. kidney inj Swallow: Medical attention immed TO: Eyes. Sol: 53% Eyes: Prevent eye contact Fl. high BP.2. irrity. wheez. conj. liver. CVS. crystalline solid or flakes with an unpleasant odor. liver. acid vapors. Target Organs (see Table 5): Eye: Irr immed ER: Inh.

diarr.2 50 mg/m3: Sa* Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: 0. repro sys Carbaryl 51 .Gr: 1. Breath: Resp support vomit. [pesticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 201.P: NA §: ScbaF:Pd.6 ¥: ScbaF:Pd. Sevin® Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): NIOSH 5006. rhin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 300. 5601 OSHA PEL: TWA 5 mg/m3 OSHA 63 Physical Description: White or gray. sweat. liver.Gr: 1. but may be dissolved in flammable liquids. skin Breath: Resp support sens. Ing. Abs. GI tract. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. blurred vision. 1-Naphthyl N-Methyl-carbamate. Incompatibilities and Reactivities: Strong oxidizers. Incompatibilities and Reactivities: Strong alkaline materials (e. resp sys. 9202. convuls.Pp:AScba Change: Daily IP: ? Escape: GmFOv100/ScbaE Sp..00004 mmHg MLT: 293°F UEL: NA LEL: NA Noncombustible Solid. CNS.2-dicarboximide Exposure Limits: Measurement Methods NIOSH REL: Ca OSHA PEL†: none (see Table 1): 3 NIOSH 5601. tremor. N-Trichloromethylmercapto-4-cyclohexene-1. may be dissolved in flammable liquids. tear.] Exposure Routes. vomit.74 VP: 0 mmHg (approx) Quick drench MLT: 352°F (Decomposes) UEL: ? LEL: ? Combustible Solid. salv. upper resp sys. CVS.Pp/SaF:Pd.CAS#: RTECS#: IDLH: Formula: 133-06-2 GW5075000 Ca [N. skin. Ing. kidneys [in animals: duodenal tumors] Captan C Formula: CAS#: RTECS#: IDLH: CH3NHCOOC10H7 63-25-2 EC5950000 100 mg/m3 Conversion: DOT: 2757 151 Synonyms/Trade Names: α-Naphthyl N-methyl-carbamate.0003% Remove: When wet or contam Fl. crystalline powder. dysp. cyan. Abs. skin.D. [carc] Swallow: Medical attention immed TO: Eyes. possible repro effects Swallow: Medical attention immed TO: Resp sys. white. irrit skin. Symptoms. odorless solid. derm.23 VP(77°F): <0.Pp:AScba Eyes: Prevent eye contact BP: Decomposes Escape: GmFOv/ScbaE Wash skin: When contam/Daily Sol(77°F): 0. nau. [fungicide] [Note: Commercial product is a yellow powder with a pungent odor. hydrated lime) [Note: Corrosive to metals. Con Skin: Soap wash prompt SY: Miosis. strongly alkaline pesticides First Aid (see Table 6): Exposure Routes.g. Symptoms. Target Organs (see Table 5): Eye: Irr immed ER: Inh. blood chol. 9205 TWA 5 mg/m See Appendix A Physical Description: Odorless. abdom cramps.P: ? Change: Daily IP: NA Provide: Eyewash Sp. skin. diarr.01% 100 mg/m3: Sa:Cf*/ScbaF/SaF Remove: When wet or contam Fl. Con Skin: Soap wash immed SY: Irrit eyes. blurred vision.] C9H8Cl3NO2S Conversion: DOT: Synonyms/Trade Names: Captane.Pp/SaF:Pd.

Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Furadan® Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Incompatibilities and Reactivities: Strong oxidizers such as chlorates.D. crystalline solid. Furacarb®. Breath: Fresh air head.Gr: 1.C Formula: CAS#: RTECS#: IDLH: C12H15NO3 1563-66-2 FB9450000 N. abdom cramps.R.18 Change: Daily VP(77°F): 0. diarr.3-Dihydro-2.1 mg/m3 (see Table 1): NIOSH 5601 OSHA PEL†: none Physical Description: Odorless. in presence of polycyclic aromatic hydrocarbons: [carc] TO: Resp sys. peroxides. Con Skin: Soap flush immed SY: Miosis. [insecticide] [Note: May be dissolved in a liquid carrier. IP: NA 175 mg/m3: 100F/PaprTHie/ScbaF/SaF Sp..1 mg PAHs/m See Appendix A See Appendix C OSHA PEL: TWA 3. Abs.8-2.5 mg/m3 Physical Description: Black. salv.Pp:AScba MLT: Sublimes Escape: 100F/ScbaE UEL: NA LEL: NA In presence of polycyclic aromatic hydrocarbons: NIOSH Combustible Solid that ¥: ScbaF:Pd. Furnace black.Gr: 1.P: NA Wash skin: When contam IP: NA Remove: When wet or contam Sp.Pp/SaF:Pd. inco.3 (see Table 2): BP: ? Skin: Prevent skin contact Not available.1 1750 mg/m3: Sa:Pd. convuls Swallow: Medical attention immed TO: CNS. bromates & nitrates First Aid (see Table 6): Exposure Routes.P: NA 87.g. Conversion: DOT: 2757 151 Synonyms/Trade Names: 2. Noncombustible Solid permanganates) Exposure Routes. vomit. Sol(77°F): 0. eyes [lymphatic cancer (in presence of PAHs)] Carbon black 52 . irrit eyes. chlorates.000003 mmHg Provide: Eyewash MLT: 304°F Quick drench UEL: NA Incompatibilities and Reactivities: Alkaline substances.0 17. lass.Pp:AScba may contain flammable Escape: 100F/ScbaE hydrocarbons. Channel black.R.2-dimethyl-7-benzofuranyl methylcarbamate.R. acid. Ing.5 mg/m3: Sa:Cf/PaprHie Change: N. Fl. nau. white or grayish.Pp VP: 0 mmHg (approx) §: ScbaF:Pd. perchlorates. Symptoms. blurred vision. musc twitch. odorless solid. Con Breath: Fresh air SY: Cough. nitrates. Symptoms. sweat. PNS. LEL: NA strong oxidizers (e.Pp/SaF:Pd.5 mg/m3: Qm Eyes: Prevent eye contact BP: Sublimes Wash skin: Daily Sol: Insoluble 35 mg/m3: 95XQ/Sa Remove: N.5 mg/m3 (see Table 1): NIOSH 5000 Carbon black in presence of polycyclic aromatic hydrocarbons (PAHs): OSHA ID196 Ca 3 TWA 0. blood chol Carbofuran Formula: CAS#: RTECS#: IDLH: C 1333-86-4 FF5800000 1750 mg/m3 Conversion: DOT: Synonyms/Trade Names: Acetylene black. Thermal black Exposure Limits: Measurement Methods NIOSH REL: TWA 3. Lamp black. Target Organs (see Table 5): Eye: Irr prompt ER: Inh. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 221.07% Eyes: Prevent eye contact Fl. MW: 12.

2% Eyes: Frostbite §: ScbaF:Pd.P: NA Wash skin: N. mal.0 (see Table 2): NIOSH/OSHA BP: Sublimes Skin: Frostbite 40. amines Class IB Flammable Liquid [Note: Vapors may be ignited by contact with an ordinary light bulb. skin. ScbaF/SaF 500 ppm: Sa:Pd. Ing.3% Wash skin: When contam 50 ppm: CcrFOv/GmFOv/PaprTOv/ Fl. frostbite (liq.Pp/SaF:Pd. repro effects Swallow: Medical attention immed TO: CNS. lass. ocular changes. restless.3% such as sodium. liver. Escape: ScbaE IP: 13.Formula: CAS#: RTECS#: IDLH: CO2 124-38-9 FF6400000 40. such as UEL: NA magnesium.08 eV Change: N. potassium & zinc. Exposure Limits: Measurement Methods NIOSH REL: TWA 5000 ppm (9000 mg/m3) (see Table 1): 3 NIOSH 6603 ST 30.R.77 eV Remove: N. poor sleep. Symptoms. Symptoms. low-wgt. azides. incr heart rate. kidneys.R. Abs.Pp:AScba VP: 297 mmHg Escape: GmFOv/ScbaE FRZ: -169°F UEL: 50. chemically-active metals LEL: 1. derm. Breath: Resp support polyneur.] Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH MW: 76. gastritis. First Aid (see Table 6): Exposure Routes. coronary heart disease. dry ice) TO: Resp sys. BP. card Breath: Resp support output. skin burns. Dry ice [Note: Normal constituent of air (about 300 ppm)]. RGasD: 1. Target Organs (see Table 5): Eye: Irr immed ER: Inh. CVS.80 mg/m3 DOT: 1013 120. eye.R. pares.11 mg/m3 Synonyms/Trade Names: Carbon bisulfide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 ppm (3 mg/m3) 3 NIOSH 1600. titanium.R. 2187 120 (liquid) Synonyms/Trade Names: Carbonic acid gas. Forms carbonic Nonflammable Gas acid in water. Parkinson-like syndrome. CVS Carbon dioxide C Carbon disulfide Conversion: 1 ppm = 3.26 §: ScbaF:Pd. asphy. eyes.5 atm Provide: Frostbite wash MLT: -109°F (Sublimes) Incompatibilities and Reactivities: Dusts of various metals. rust. repro sys Formula: CS2 DOT: 1131 131 CAS#: 75-15-0 RTECS#: FF6650000 IDLH: 500 ppm 53 . chromium & manganese are LEL: NA ignitable and explosive when suspended in carbon dioxide.000 ppm (54.000 ppm: Sa/ScbaF Sol(77°F): 0. Solid form is utilized as dry ice. [Note: Shipped as a liquefied compressed gas. 3800 ST 10 ppm (30 mg/m ) [skin] OSHA PEL†: TWA 20 ppm C 30 ppm 100 ppm (30-minute maximum peak) Physical Description: Colorless to faint-yellow liquid with a sweet ether-like odor. anor. zirconium. halogens.000 mg/m ) 3 OSHA ID172 OSHA PEL†: TWA 5000 ppm (9000 mg/m ) Physical Description: Colorless. kidney. convuls. Con Skin: Soap wash immed SY: Dizz.53 Change: N.Pp Sp. sweat.Pp/SaF:Pd.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 44.Gr: 1. dizz.1 Skin: Prevent skin contact 10 ppm: CcrOv/Sa BP: 116°F Eyes: Prevent eye contact 25 ppm: Sa:Cf/PaprOv Sol: 0.Pp:AScba Fl. PNS. dysp. Target Organs (see Table 5): Eye: Frostbite ER: Inh.] First Aid (see Table 6): Exposure Routes. psychosis. aluminum. odorless gas. head. liver inj.000 ppm Conversion: 1 ppm = 1. [Note: Reagent grades are foul smelling.P: -22°F Remove: When wet (flamm) IP: 10. VP: 56. coma. Con (liquid/solid) Skin: Frostbite SY: Head. anxi.0% Incompatibilities and Reactivities: Strong oxidizers. 1845 120 (dry ice).

resp sys. blood. Conversion: 1 ppm = 13. Breath: Resp support in animals: corn damage Swallow: Medical attention immed TO: Eyes. Tetrabromomethane Exposure Limits: Measurement Methods NIOSH REL: TWA 0. skin. skin.R. bromine trifluoride.57 mg/m3 DOT: 2516 151 Synonyms/Trade Names: Carbon bromide. halu.15 mg/m3 DOT: 1016 119.R. lung.C Formula: CAS#: RTECS#: IDLH: CO 630-08-0 FG3500000 1200 ppm Conversion: 1 ppm = 1. Sol: 2% 1200 ppm: GmFS†/ScbaF/SaF Remove: When wet (flamm) Fl. lungs.97 VP: >35 atm MLT: -337°F UEL: 74% LEL: 12. Symptoms. Con Skin: Soap wash prompt SY: Irrit eyes. resp sys. Symptoms.Gr: 3.R. Methane tetrabromide. liver.Pp:AScba Change: N. Ing. BP: 374°F Not available. IP: 10.31 eV Change: Daily Sp. lass.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Frostbite MW: 28.1 ppm (1. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 331. chlorine trifluoride.D. tachypnea. Eyes: Prevent eye contact Sol: 0.02% Wash skin: Daily Fl. depres S-T segment Skin: Frostbite Breath: Resp support of electrocardiogram. lac.01 eV Escape: GmFS†/ScbaE Provide: Frostbite wash RGasD: 0. nau. Con (liquid) Eye: Frostbite SY: Head. [Note: Shipped as a nonliquefied or liquefied compressed gas.P: NA Remove: N. liver.4 mg/m3) (see Table 1): 3 None available ST 0. dizz.3 ppm (4 mg/m ) OSHA PEL†: none Physical Description: Colorless to yellow-brown crystals with a slight odor. Flue gas. conf. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. ID210 OSHA PEL†: TWA 50 ppm (55 mg/m ) Physical Description: Colorless. lithium Exposure Routes. odorless gas. syncope TO: CVS.5% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.R. cyan. 9202 168 (cryogenic liquid) Synonyms/Trade Names: Carbon oxide. kidney inj.0 350 ppm: Sa Eyes: Frostbite BP: -313°F 875 ppm: Sa:Cf Wash skin: N.7 Skin: N.Pp/SaF:Pd. lithium Exposure Routes. hexacyclohexyldilead. IP: 14. kidneys Carbon tetrabromide 54 .42 Provide: Eyewash VP(205°F): 40 mmHg MLT: 194°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers. Monoxide Exposure Limits: Measurement Methods NIOSH REL: TWA 35 ppm (40 mg/m3) (see Table 1): 3 NIOSH 6604 C 200 ppm (229 mg/m ) 3 OSHA ID209.P: NA (Gas) §: ScbaF:Pd. angina. CNS Carbon monoxide Formula: CAS#: RTECS#: IDLH: CBr4 558-13-4 FG4725000 N.

resp sys. aluminum [Note: Forms highly Noncombustible Liquid toxic phosgene gas when exposed to flames or welding arcs.Gr: 1. [Note: Shipped as a liquefied compressed gas. musc fib. skin. eye. resp sys. Halon® 104. chronic exposure: GI pain. Ing. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. kidney inj. eyes. bone Carbonyl fluoride 55 .D.Pp/SaF:Pd.6 mg/m ) [60-minute] OSHA 7 See Appendix A OSHA PEL†: TWA 10 ppm C 25 ppm 200 ppm (5-minute maximum peak in any 4 hours) Physical Description: Colorless liquid with a characteristic ether-like odor. VP: 55. kidneys.0 (see Table 2): BP: -118°F Skin: Frostbite Not available. Symptoms. Con Eye: Irr immed SY: Irrit eyes. skin burns.59 Change: N. moisture. dysp. IP: 13. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 153. nau. skeletal fluorosis. Carbon tet.4 atm Provide: Frostbite wash FRZ: -173°F Incompatibilities and Reactivities: Heat. lac. Tetrachloromethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 1003 ST 2 ppm (12.29 Change: N. Symptoms. Conversion: 1 ppm = 2. lungs. UEL: NA hexafluoroisopropylideneamino-lithium LEL: NA [Note: Reacts with water to form hydrogen fluoride & carbon dioxide.P: NA Wash skin: When contam IP: 11.05% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. Freon® 10. skin. dizz.R.R. liver.] Nonflammable Gas First Aid (see Table 6): Exposure Routes.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 66. CNS depres.] Exposure Routes. fluorine.02 eV Remove: N. Carbon oxyfluoride. skin [in animals: liver cancer] Carbon tetrachloride C Formula: CAS#: RTECS#: IDLH: COF2 353-50-4 FG6125000 N.Formula: CAS#: RTECS#: IDLH: CCl4 56-23-5 FG4900000 Ca [200 ppm] Conversion: 1 ppm = 6.47 eV Remove: When wet or contam Sp.70 mg/m3 DOT: 2417 125 Synonyms/Trade Names: Carbon difluoride oxide. Skin: Soap wash immed Breath: Resp support inco. muc memb. VP: 91 mmHg Provide: Eyewash FRZ: -9°F Quick drench UEL: NA Incompatibilities and Reactivities: Chemically-active metals such as LEL: NA sodium.29 mg/m3 DOT: 1846 151 Synonyms/Trade Names: Carbon chloride. Abs.R. liquid: frostbite TO: Eyes. Target Organs (see Table 5): Eye: Frostbite ER: Inh. Fluoroformyl fluoride. potassium & magnesium. vomit. Breath: Resp support pulm edema. liver.Pp:AScba Sol: 0. Carbon fluoride oxide. Con Skin: Frostbite SY: Irrit eyes.R. drow. cough. skin. Carbonyl difluoride. RGasD: 2. [carc] Swallow: Medical attention immed TO: CNS.8 (see Table 2): NIOSH BP: 170°F Skin: Prevent skin contact ¥: ScbaF:Pd. Fluorophosgene Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (5 mg/m3) (see Table 1): 3 None available ST 5 ppm (15 mg/m ) OSHA PEL†: none Physical Description: Colorless gas with a pungent and very irritating odor. Sol: Reacts Eyes: Frostbite Fl.P: NA Wash skin: N.

derm.R. nitric acid First Aid (see Table 6): Exposure Routes. sodium nitrate. Abs. Ing. Sp. 0600. skin. [Note: The principal fiber cell wall material of vegetable tissues (wood. Eyes: Prevent eye contact Sol: 44% Wash skin: When contam Fl.2-Benzenediol. 7404 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Odorless. burns eyes. IP: NA Change: N. 2-Hydroxyphenol. Eyes: N. Target Organs (see Table 5): Eye: Irr immed ER: Inh. muc memb Breath: Fresh air TO: Eyes. kidneys Catechol Formula: CAS#: RTECS#: IDLH: (C6H10O5)n 9004-34-6 FJ5691460 N.R. skin. lac. 1. Con Skin: Water wash immed SY: Irrit eyes. grass. skin sens.000 Skin: N. skin.R.Gr: 1.R.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 160.C Formula: CAS#: RTECS#: IDLH: C6H4(OH)2 120-80-9 UX1050000 N. Fl.D. fluorine. cotton.P: NA Remove: N.P: 261°F Remove: When wet or contam IP: ? Change: Daily Sp. etc.R. strong oxidizers Exposure Routes.50 mg/m3 DOT: Synonyms/Trade Names: 1. skin. o-Dihydroxybenzene. bromine pentafluoride. flax. Conversion: DOT: Synonyms/Trade Names: Hydroxycellulose. o-Benzenediol. resp sys.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 110. kidney inj Swallow: Medical attention immed TO: Eyes.D.34 Provide: Eyewash VP(244°F): 10 mmHg MLT: 221°F UEL: ? LEL: 1.). Con Skin: Soap wash SY: Irrit eyes. incr BP.000-560. Conversion: 1 ppm = 4. BP: Decomposes Not available. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Pyrocellulose Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500. Symptoms. CNS. resp sys.61 VP: 0 mmHg (approx) MLT: 500-518°F (Decomposes) UEL: NA LEL: NA Combustible Solid Incompatibilities and Reactivities: Water.27-1. Pyrocatechol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 ppm (20 mg/m3) [skin] OSHA PV2014 OSHA PEL†: none Physical Description: Colorless. white substance.1 Skin: Prevent skin contact BP: 474°F Not available. Symptoms.Gr: 1.4% Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. Breath: Resp support convuls. Sol: Insoluble Wash skin: N. [Note: Discolors to brown in air & light. crystalline solid with a faint odor. resp sys Cellulose 56 .2-Dihydroxybenzene.

anuria. vomit.7-methanoindane Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 5510 TWA 0. 1.4. Symptoms. Ing. Con Skin: Soap wash immed SY: Blurred vision. Symptoms.9 Skin: Prevent skin contact BP: ? Not available.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 149. Sn. irrity.7. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 409. liver. ataxia. 2681 154 (solution) Synonyms/Trade Names: Cesium hydrate. kidney Breath: Resp support Swallow: Medical attention immed damage. eye. convuls.P: NA Remove: When wet or contam IP: ? Change: Daily Sp.6 Provide: Eyewash VP: 0.Formula: CAS#: RTECS#: IDLH: CsOH 21351-79-1 FK9800000 N. tremor.4. skin burns Breath: Resp support TO: Eyes. absorbs moisture from the air).Gr(77°F): 1. Incompatibilities and Reactivities: Strong oxidizers.2. [Note: Hygroscopic (i.e. Chlordano. oxygen [Note: CsOH is a strong base.5 mg/m [skin] OSHA 67 See Appendix A OSHA PEL: TWA 0. cough. Target Organs (see Table 5): Eye: Irr immed ER: Inh. skin.Gr: 3.6. Pb. metals (e. eyes. Abs. CO2. Conversion: DOT: 2682 157.. conf.. [carc] TO: CNS. in animals: lung.8. delirium. diarr. skin.5.68 Provide: Eyewash VP: 0 mmHg (approx) MLT: 522°F Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Water. Eyes: Prevent eye contact Sol(59°F): 395% Wash skin: When contam Fl.] Exposure Routes.00001 mmHg FRZ: 217-228°F Quick drench UEL: NA LEL: NA Noncombustible Liquid. kidneys [in animals: liver cancer] Chlordane 57 . Zn).7. Con Skin: Water flush immed SY: Irrit eyes.Pp:AScba Eyes: Prevent eye contact Sol: 0. but may be utilized in flammable solutions. Al. nau. crystalline solid. acids. causing the generation of considerable heat in contact with water or moisture. resp sys Swallow: Medical attention immed Cesium hydroxide C Formula: CAS#: RTECS#: IDLH: C10H6Cl8 57-74-9 PB9800000 Ca [100 mg/m3] Conversion: DOT: 2996 151 Synonyms/Trade Names: Chlordan. Cesium hydroxide dimer Exposure Limits: Measurement Methods NIOSH REL: TWA 2 mg/m3 (see Table 1): OSHA PEL†: none None available Physical Description: Colorless or yellowish. upper resp sys. lungs. Ing.8 NIOSH Skin: Prevent skin contact BP: Decomposes ¥: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. alkaline reagents First Aid (see Table 6): Exposure Routes. abdom pain.0001% Escape: GmFOv100/ScbaE Wash skin: When contam Fl.P: NA Remove: When wet or contam IP: NA Change: Daily Sp. liver.Pp/SaF:Pd. chlorine-like odor.g.D. viscous liquid with a pungent.5 mg/m3 [skin] Physical Description: Amber-colored.7a-tetrahydro-4.8-Octachloro-3a.

Toxaphene Exposure Limits: Measurement Methods NIOSH REL: Ca [skin] (see Table 1): NIOSH 5039 See Appendix A 3 OSHA PEL†: TWA 0. [carc] Breath: Resp support TO: CNS. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact Properties vary depending 5 mg/m3: Sa/ScbaF upon the specific compound. piney. dry.5 mg/m3 (see Table 1): NIOSH 5025 OSHA PEL: TWA 0. Symptoms. Target Organs (see Table 5): Eye: Irr immed ER: Inh. ranging from monochlorodiphenyl oxide [(C6H4Cl)O(C6H5)] to decachlorodiphenyl oxide [(C6Cl5)O(C6Cl5)]. Con Skin: Soap wash prompt SY: Nau.5 mg/m3 Physical Description: Appearance and odor vary depending upon the specific compound. conf. Con SY: Acne-form derm.4 mmHg Quick drench MLT: 149-194°F UEL: NA LEL: NA Noncombustible Solid.Pp:AScba Remove: When wet or contam Escape: GmFOvAg100/ScbaE Change: Daily Chlorinated diphenyl oxide Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. waxy solid with a mild.0003% Remove: When wet or contam Fl.Gr: 1.] First Aid (see Table 6): Exposure Routes. liver damage TO: Skin. Symptoms. Incompatibilities and Reactivities: Strong oxidizers [Note: Slightly corrosive to metals under moist conditions.Pp/SaF:Pd. Abs. but may be dissolved in flammable liquids. agitation. Target Organs (see Table 5): ER: Inh. uncon. Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Ing. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 413.5 mg/m [skin] Physical Description: Amber. Ing. liver First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed 58 .and camphorlike odor. chlorine. red skin. convuls. tremor.P: NA Change: Daily IP: ? Provide: Eyewash Sp.Pp/SaF:Pd. Octachlorocamphene. Eyes: Prevent eye contact Wash skin: When contam §: ScbaF:Pd.C Formula: CAS#: RTECS#: IDLH: C10H10Cl8 8001-35-2 XW5250000 Ca [200 mg/m3] Conversion: DOT: 2761 151 Synonyms/Trade Names: Chlorocamphene. skin [in animals: liver cancer] Swallow: Medical attention immed Chlorinated camphene CAS#: RTECS#: IDLH: Formula: 5 mg/m3 C12H10-nClnO Conversion: DOT: Synonyms/Trade Names: Synonyms depend on the degree of chlorination of diphenyl oxide [(C6H5)2O]. Polychlorocamphene.65 VP(77°F): 0.Pp:AScba Eyes: Prevent eye contact BP: Decomposes Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: 0.8 ¥: ScbaF:Pd.

Chlorine peroxide Exposure Limits: Measurement Methods NIOSH REL: TWA 0. frozen) Synonyms/Trade Names: Chlorine oxide.5 ppm: Sa:Cf£/PaprS£ Wash skin: When contam (liquid) Fl. Con Skin: Soap wash immed (liquid) SY: Irrit eyes.3 mg/m ) Physical Description: Yellow to red gas or a red-brown liquid (below 52°F) with an unpleasant odor similar to chlorine and nitric acid. Symptoms.3 ppm (0. turpentine. mercury.1 ppm (0. Incompatibilities and Reactivities: Reacts explosively or forms explosive compounds with many common substances such as acetylene.Chlorine Conversion: 1 ppm = 2. pulm edema. dizz.Pp/SaF:Pd. syncope. choking. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed (liquid) ER: Inh. subs pain.36 eV §: ScbaF:Pd. Combustible Liquid Incompatibilities and Reactivities: Organic materials. IP: 11.7% 10 ppm: Sa:Cf*/PaprS*/CcrFS/GmFS/ Wash skin: N. skin.45 mg/m3) [15-minute] (see Table 1): 3 NIOSH 6011 OSHA PEL†: C 1 ppm (3 mg/m ) OSHA ID101. hypox.90 mg/m3 Synonyms/Trade Names: Molecular chlorine Exposure Limits: Measurement Methods NIOSH REL: C 0. rhin. Skin: Frostbite vomit.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 70. cough.9 mg/m ) 3 OSHA PEL†: TWA 0. carbon monoxide [Note: Unstable in light. ether. Breath: Resp support chronic bron Swallow: Medical attention immed (liquid) TO: Eyes. mouth. ID126SGX Physical Description: Greenish-yellow gas with a pungent. irritating odor. RGasD: 2. wheez.Pp/SaF:Pd. sulfur.33 Escape: GmFS¿/ScbaE Provide: Eyewash (liquid) Sp.Pp:AScba Change: N.P: NA (Gas) ? (Liquid) 5 ppm: CcrFS/GmFS/ScbaF/SaF Remove: When wet (flamm) IP: 10. heat. ammonia.3% 2. fuel gas. RGasD: 2. Con Eye: Frostbite SY: Burning of eyes. Exposure Routes. cough. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Gr: 1. ID202 ST 0.5 NIOSH/OSHA Skin: Prevent skin contact (liquid) BP: 52°F 1 ppm: CcrS/Sa Eyes: Prevent eye contact (liquid) Sol(77°F): 0. nau.76 mg/m3 DOT: 9191 143 (hydrate.48 eV ScbaF/SaF §: ScbaF:Pd.] Exposure Routes. resp sys Chlorine dioxide 59 .6 (Liquid at 32°F) VP: >1 atm Quick drench (liquid) FRZ: -74°F UEL: ? LEL: ? Flammable Gas. Fl. A powerful oxidizer.8 atm FRZ: -150°F UEL: NA LEL: NA Nonflammable Gas.R. bron. resp sys Formula: Cl2 DOT: 1017 124 CAS#: 7782-50-5 RTECS#: FO2100000 IDLH: 10 ppm C Formula: CAS#: RTECS#: IDLH: ClO2 10049-04-4 FO3000000 5 ppm Conversion: 1 ppm = 2. phosphorus. pneu. potassium hydroxide. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 67. but a strong oxidizer. nose.R. derm.1 ppm (0.5 ppm (1. pulm edema. throat.47 Escape: GmFS/ScbaE Provide: Frostbite wash VP: 6. lac.3 mg/m3) (see Table 1): 3 OSHA ID126SGX. Ing (liquid). hydrogen & finely divided metals.9 NIOSH Skin: Frostbite BP: -29°F 5 ppm: CcrS*/Sa* Eyes: Frostbite Sol: 0. liquid: frostbite Breath: Resp support TO: Eyes. nose. head.Pp:AScba Change: N. Symptoms.R.R.P: NA Remove: N. [Note: Shipped as a liquefied compressed gas.

Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Con Eye: Irr immed SY: Irrit skin. [Note: Shipped as a liquefied compressed gas. 2-Chloroethanal Exposure Limits: Measurement Methods NIOSH REL: C 1 ppm (3 mg/m3) (see Table 1): 3 NIOSH 2015 OSHA PEL: C 1 ppm (3 mg/m ) OSHA 76 Physical Description: Colorless liquid with an acrid. corn ulcer.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 78. in animals: Skin: Water flush immed Breath: Resp support lac. metals (corrosive) [Note: Reacts with water to form chlorine & hydrofluoric acid. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.R. acids. penetrating odor.C Formula: CAS#: RTECS#: IDLH: ClF3 7790-91-2 FO2800000 20 ppm Conversion: 1 ppm = 3. Chlorotrifluoride Exposure Limits: Measurement Methods NIOSH REL: C 0. Con Eye: Irr immed SY: Eye. skin.78 mg/m3 DOT: 1749 124 Synonyms/Trade Names: Chlorine fluoride. muc memb. skin burns (liq or high vap conc). sand.21 contam (liquid) Escape: GmFS/ScbaE Sp. but contact Incompatibilities and Reactivities: Oxidizers.] SPONTANEOUS ignition.4 mg/m3) (see Table 1): 3 OSHA PEL: C 0. water.R. resp sys sens Swallow: Medical attention immed TO: Eyes.1 ppm (0.77 (Liquid at 53°F) Change: N.Pp/SaF:Pd.Pp IP: 13. pulm Skin: Water flush immed Breath: Resp support edema. Symptoms.Pp:AScba RGasD: 3. combustible with organic materials may result in materials.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 92. suffocating odor. eyes.5 ppm: Sa:Cf£ Sol: Reacts Eyes: Prevent eye contact 5 ppm: ScbaF/SaF Fl. Exposure Routes.Gr: 1.1 ppm (0. acids Exposure Routes.19 (40% solution) Escape: GmFOv/ScbaE VP: 100 mmHg Quick drench FRZ: -3°F (40% solution) UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers.Gr: 1. VP: 1. eyes. resp sys Chlorine trifluoride Formula: CAS#: RTECS#: IDLH: ClCH2CHO 107-20-0 AB2450000 45 ppm Conversion: 1 ppm = 3. Ing.P: 190°F (40% solution) Change: N. [Note: Typically found as a 40% aqueous solution.Pp:AScba Provide: Eyewash Sp. eye damage.21 mg/m3 DOT: 2232 153 Synonyms/Trade Names: Chloroacetaldehyde (40% aqueous solution). Ing (liquid). Abs.5 10 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 186°F 25 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: Miscible 45 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl. IP: 10. 2-Chloroacetaldehyde. pulm edema Swallow: Medical attention immed (liquid) TO: Skin.61 eV ScbaF/SaF §: ScbaF:Pd. resp irrit. skin burns.Pp/SaF:Pd.00 eV Remove: When wet or §: ScbaF:Pd. skin.P: NA Wash skin: When contam (liquid) 20 ppm: SaF:Pd.5 (see Table 2): NIOSH/OSHA BP: 53°F Skin: Prevent skin contact 2.4 mg/m ) None available Physical Description: Colorless gas or a greenish-yellow liquid (below 53°F) with a somewhat sweet. glass. Symptoms.4 atm Provide: Eyewash (liquid) FRZ: -105°F Quick drench (liquid) UEL: NA LEL: NA Nonflammable Gas Noncombustible Liquid. resp sys Chloroacetaldehyde 60 .

bases. Tear gas Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Abs.9 Skin: Prevent skin contact BP: 223°F Not available. resp sys Swallow: Medical attention immed Chloroacetyl chloride 61 . cough. skin.32 Escape: GmFS100/ScbaE VP: 0. resp sys.05 ppm) Physical Description: Colorless to gray crystalline solid with a sharp.Gr: 1. Monochloroacetyl chloride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.P: 244°F 15 mg/m3: CcrFOv100/GmFS100/ScbaF/SaF Change: Daily IP: 9. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 112.44 eV §: ScbaF:Pd. lac Breath: Resp support TO: Eyes.005 mmHg MLT: 134°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Water. Target Organs (see Table 5): Eye: Irr immed ER: Inh. steam. strong oxidizers [Note: Slowly corrodes metals. irritating odor.32 mg/m3 DOT: 1697 153 Synonyms/Trade Names: 2-Chloroacetophenone.3 mg/m (0.2 mg/m3) OSHA PEL†: none None available Physical Description: Colorless to yellowish liquid with a strong.3 mg/m3 (0. Ing.42 Provide: Eyewash VP: 19 mmHg FRZ: -7°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Water.30 eV Change: N. wheez. dysp. alcohols. pungent odor. Eyes: Prevent eye contact Sol: Decomposes Wash skin: When contam Fl.05 ppm (0. skin.P: NA Remove: When wet or contam IP: 10. Con Skin: Soap wash immed SY: Irrit eyes. Symptoms.05 ppm) 3 NIOSH P&CAM291 (II-5) OSHA PEL: TWA 0. amines [Note: Decomposes in water to form chloroacetic acid & hydrogen chloride gas. resp sys. Con Skin: Water flush immed SY: Irrit eyes.62 mg/m3 DOT: 1752 156 Synonyms/Trade Names: Chloroacetic acid chloride.6 3 mg/m3: CcrOv95/Sa Eyes: Prevent eye contact BP: 472°F Wash skin: When contam Sol: Insoluble 7.] First Aid (see Table 6): Exposure Routes.D. Phenacyl chloride. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Chloromethyl phenyl ketone. Symptoms.CAS#: RTECS#: IDLH: Formula: 532-27-4 AM6300000 15 mg/m3 C6H5COCH2Cl Conversion: 1 ppm = 6. skin burns. Ing. Mace®. skin. metals (corrosive). Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 154.5 mg/m3: Sa:Cf£/PaprOvHie£ Remove: When wet or contam Fl. skin. Phenyl chloromethyl ketone. Chloroacetic chloride.R.Pp:AScba Provide: Eyewash Sp.] Exposure Routes. ClCH2COCl Conversion: 1 ppm = 4.Gr: 1. resp sys Swallow: Medical attention immed α-Chloroacetophenone C CAS#: RTECS#: IDLH: Formula: 79-04-9 AO6475000 N.Pp/SaF:Pd. pulm edema Breath: Resp support TO: Eyes. eye. Sp.

CS. Chlorobenzene Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact MW: 112. drow. resp sys 62 .61 mg/m3 DOT: 1134 130 Synonyms/Trade Names: Benzene chloride.05 ppm (0.6% LEL: 1.Gr: 1. burn eyes. Monochlorobenzene. irrit Skin: Soap wash immed Breath: Resp support throat.Pp/SaF:Pd.05% GmFOv/ScbaF/SaF Remove: When wet (flamm) §: ScbaF:Pd.07 eV Sp. Abs. lac.11 VP: 9 mmHg FRZ: -50°F UEL: 9. Ing. in animals: Skin: Soap wash prompt Breath: Resp support liver. Symptoms. CNS depres. CNS.Pp:AScba Fl. Chlorobenzol. OCBM Exposure Limits: Measurement Methods NIOSH REL: C 0. nose. inco. MCB. skin.Pp/SaF:Pd. Con Eye: Irr immed SY: Pain. Con Eye: Irr immed SY: Irrit eyes. eryt. eryt eyelids.P: 82°F Change: N. conj. vesic skin Swallow: Medical attention immed TO: Eyes. blepharospasm.6 1000 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 270°F Wash skin: When contam Sol: 0. kidney inj Swallow: Medical attention immed TO: Eyes. Ing.71 mg/m3 DOT: 2810 153 Synonyms/Trade Names: 2-Chlorobenzalmalonitrile.4 mg/m ) NIOSH P&CAM304 (II-5) Physical Description: White crystalline solid with a pepper-like odor.3% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Escape: GmFOv/ScbaE IP: 9. skin.Pp:AScba Sol: Insoluble Remove: When wet or contam Escape: GmFS100/ScbaE Fl.C CAS#: RTECS#: IDLH: Formula: 108-90-7 CZ0175000 1000 ppm C6H5Cl Conversion: 1 ppm = 4.Gr: ? VP: 0.R.05 ppm (0. lung. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 188. liver o-Chlorobenzylidene malononitrile ClC H CH=C(CN) 6 4 2 Formula: CAS#: 2698-41-1 RTECS#: OO3675000 IDLH: 2 mg/m3 Conversion: 1 ppm = 7. Phenyl chloride Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL: TWA 75 ppm (350 mg/m ) NIOSH 1003 OSHA 7 Physical Description: Colorless liquid with an almond-like odor.P: ? Change: Daily IP: ? Sp. chest tight. Symptoms.4 mg/m3) [skin] (see Table 1): 3 OSHA PEL†: TWA 0.00003 mmHg MLT: 203-205°F UEL: ? LEL: ? MEC: 25 g/m3 Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.6 2 mg/m3: Sa:Cf£/GmFS100/ScbaF/SaF Eyes: Prevent eye contact BP: 590-599°F Wash skin: When contam/Daily §: ScbaF:Pd. cough. skin. resp sys. head. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.

Refrigerant 22 Measurement Methods Exposure Limits: NIOSH REL: TWA 1000 ppm (3500 mg/m3) (see Table 1): NIOSH 1018 ST 1250 ppm (4375 mg/m3) OSHA PEL†: none Physical Description: Colorless gas with a faint.Gr: 1. Monochlorodifluoromethane.Pp:AScba Remove: When wet or contam Fl.54 mg/m DOT: 1018 126 Synonyms/Trade Names: Difluorochloromethane. Freon® 22. card Skin: Frostbite Breath: Resp support arrhy.R.CAS#: RTECS#: IDLH: Formula: 74-97-5 PA5250000 2000 ppm CH2BrCl Conversion: 1 ppm = 5. IP: 10. conf. Conversion: 1 ppm = 3. Ing. heart palp.R. Fluorocarbon 1011.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 86. Con SY: Irrit eyes. [Note: Shipped as a liquefied compressed gas. zinc) Exposure Routes. asphy.. Methyl chlorobromide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 200 ppm (1050 mg/m3) 3 NIOSH 1003 OSHA PEL: TWA 200 ppm (1050 mg/m ) Physical Description: Colorless to pale-yellow liquid with a chloroform-like odor.g. CNS Swallow: Medical attention immed Chlorobromomethane C Formula: CAS#: RTECS#: IDLH: CHClF2 75-45-6 PA6390000 N. Sol(77°F): 0. Fluorocarbon-22. throat. VP: 9. pulm edema Skin: Soap wash prompt Breath: Resp support TO: Eyes.R.P: NA Escape: GmFOv/ScbaE Change: N. RGasD: 3. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Halon® 1011.11 Change: N. drow. Symptoms.93 VP: 115 mmHg FRZ: -124°F UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Chemically-active metals such as calcium.4 2000 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 155°F Wash skin: When contam Sol: Insoluble GmFOv/ScbaF/SaF §: ScbaF:Pd. Symptoms. CNS. ringing in ears. potassium.3% Eyes: Frostbite Fl. CBM. sodium.P: NA Wash skin: N. skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. kidneys. sweetish odor.Pp/SaF:Pd. resp sys.45 eV Remove: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 129. Con (liquid) Eye: Frostbite SY: Irrit resp sys. dizz. and magnesium Exposure Routes. CB.77 eV Sp. alkaline earth metals (e. spleen inj. spleen Chlorodifluoromethane 3 63 . conf. kidneys. [Note: May be used as a fire extinguishing agent. liver. liver. IP: 12. powdered aluminum.D. liver.R. liquid: frostbite TO: Resp sys. Genetron® 22. skin. kidney. zinc.5 (see Table 2): BP: -41°F Skin: Frostbite Not available.29 mg/m3 DOT: 1887 160 Synonyms/Trade Names: Bromochloromethane.4 atm Provide: Frostbite wash FRZ: -231°F UEL: NA LEL: NA Incompatibilities and Reactivities: Alkalis. CVS. CNS depres. Nonflammable Gas powdered aluminum.

Gr(77°F): 1. Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. repro effects.Gr(77°F): 1.] Physical Description: Colorless to pale-yellow. and chlorinated dibenzo-p-dioxins. polychlorinated dibenzofurans & chlorinated dibenzo-p-dioxins.] Physical Description: Colorless to light-colored. Ing.001 mg/m OSHA PV2089 See Appendix A [*Note: The REL also applies to other PCBs. Abs. Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: GmFOv100/ScbaE Wash skin: When contam Fl. leukemia] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed 64 . repro effects. viscous liquid with a mild. Symptoms. leukemia] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: Ca C6H3Cl2C6H2Cl3 (approx) 11097-69-1 TQ1360000 [5 mg/m3] Conversion: DOT: 2315 171 Synonyms/Trade Names: Aroclor® 1254. Abs. liver. chloracne. Con SY: Irrit eyes. hydrocarbon odor.Pp/SaF:Pd. eyes. liver damage. PCB. but exposure in a fire results in the formation of a black soot containing PCBs. PCB.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. polychlorinated dibenzofurans. liver. Con SY: Irrit eyes.38 Provide: Eyewash VP: 0.C CAS#: RTECS#: IDLH: Formula: TQ1356000 Ca [5 mg/m3] C6H4ClC6H3Cl2 (approx) 53469-21-9 Conversion: DOT: 2315 171 Synonyms/Trade Names: Aroclor® 1242. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 258 (approx) NIOSH Skin: Prevent skin contact BP: 617-691°F ¥: ScbaF:Pd. repro sys [in animals: tumors of the pituitary gland & liver.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: GmFOv100/ScbaE Wash skin: When contam Fl. chloracne.001 mmHg FRZ: -2°F Quick drench UEL: NA LEL: NA Chlorodiphenyl (42% chlorine) Nonflammable Liquid. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 326 (approx) NIOSH Skin: Prevent skin contact BP: 689-734°F ¥: ScbaF:Pd. eyes.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. Target Organs (see Table 5): ER: Inh.Pp/SaF:Pd. liver damage. Symptoms. [carc] TO: Skin. Target Organs (see Table 5): ER: Inh. [carc] TO: Skin. but exposure in a fire results in the formation of a black soot containing PCBs.5 mg/m3 [skin] (see Table 1): NIOSH 5503 TWA 0. Polychlorinated biphenyl Exposure Limits: Measurement Methods NIOSH REL*: Ca OSHA PEL: TWA 0. hydrocarbon odor. repro sys [in animals: tumors of the pituitary gland & liver. Polychlorinated biphenyl Exposure Limits: Measurement Methods NIOSH REL*: Ca OSHA PEL: TWA 1 mg/m3 [skin] (see Table 1): 3 NIOSH 5503 TWA 0. viscous liquid or solid (below 50°F) with a mild.00006 mmHg FRZ: 50°F Quick drench UEL: NA LEL: NA Chlorodiphenyl (54% chlorine) Nonflammable Liquid.001 mg/m3 OSHA PV2088 See Appendix A [*Note: The REL also applies to other PCBs.39 Provide: Eyewash VP: 0. Ing.

] First Aid (see Table 6): Exposure Routes. [carc] TO: Eyes. skin. skin.] First Aid (see Table 6): Exposure Routes.Pp:AScba Eyes: Prevent eye contact BP: 143°F Escape: GmFOv/ScbaE Wash skin: When contam Sol(77°F): 0.Formula: CAS#: RTECS#: IDLH: CHCl3 67-66-3 FS9100000 Ca [500 ppm] Conversion: 1 ppm = 4. pulm congestion. Dichloromethyl ether. Ing. CNS [in animals: liver & kidney cancer] Swallow: Medical attention immed Chloroform C CAS#: RTECS#: IDLH: Formula: 542-88-1 KN1575000 Ca [N.0 NIOSH Skin: Prevent skin contact BP: 223°F ¥: ScbaF:Pd.Pp/SaF:Pd. kidneys. resp sys. resp sys [lung cancer] bis-Chloromethyl ether 65 . Target Organs (see Table 5): Eye: Irr immed ER: Inh. Abs. Con Skin: Soap wash immed SY: Irrit eyes. strong oxidizers [Note: When heated to decomposition. bronchial secretions. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 115.78 mg/m ) [60-minute] See Appendix A 3 OSHA PEL†: C 50 ppm (240 mg/m ) Physical Description: Colorless liquid with a pleasant odor.32 Provide: Eyewash VP(72°F): 30 mmHg FRZ: -43°F Quick drench UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Acids.48 VP: 160 mmHg Quick drench FRZ: -82°F UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Strong caustics.88 mg/m3 DOT: 1888 151 Synonyms/Trade Names: Methane trichloride. mental dullness.] (CH2Cl)2O Conversion: DOT: 2249 131 Synonyms/Trade Names: BCME. blood-stained Swallow: Medical attention immed sputum.R.Gr: 1. decr pulm function. nec. sodium & potassium. Trichloromethane Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 1003 ST 2 ppm (9. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 119. [carc] TO: Liver.1008] (see Table 1): OSHA 10 See Appendix A See Appendix B Physical Description: Colorless liquid with a suffocating odor.42 eV Provide: Eyewash Sp. conf.P: <66°F Remove: When wet (flamm) IP: ? See Appendix E (page 351) Change: Daily Sp. eyes.5% Remove: When wet or contam Fl. IP: 11. wheez.Pp:AScba Eyes: Prevent eye contact Sol: Reacts Escape: GmFOv/ScbaE Wash skin: When contam/Daily Fl. Symptoms. edema. dysp. Breath: Resp support enlarged liver. Chloromethyl ether. Abs.Gr: 1. cough. water [Note: Reacts with water to form hydrochloric acid & formaldehyde. Oxybis(chloromethane) Exposure Limits: Measurement Methods NIOSH REL: Ca OSHA PEL: [1910. nau.P: NA Change: N.4 ¥: ScbaF:Pd. lass. chemically-active metals such as aluminum or magnesium powder.D. skin. head. bis-CME. Con Skin: Soap wash prompt SY: Irrit eyes. corn Breath: Resp support damage. Dichlorodimethyl ether. Symptoms. dizz. Target Organs (see Table 5): Eye: Irr immed ER: Inh. forms phosgene gas. anes. Ing. muc memb. heart. skin.Pp/SaF:Pd.

pulm congestion. CMME. Dimethylchloroether.Pp/SaF:Pd.06 mg/m Synonyms/Trade Names: Korax®. Symptoms. eyes Swallow: Medical attention immed Formula: CAS#: CH3CH2CHClNO2 600-25-9 DOT: RTECS#: TX5075000 IDLH: 100 ppm 66 .25 eV Provide: Eyewash Sp. [carc] TO: Eyes.5% 100 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl. pneu. Lanstan® Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (10 mg/m3) (see Table 1): NIOSH S211 (II-5) OSHA PEL†: TWA 20 ppm (100 mg/m3) Physical Description: Colorless liquid with an unpleasant odor.D. Ing. Breath: Resp support skin burns. nec.21 Escape: GmFOv/ScbaE VP(77°F): 6 mmHg FRZ: ? UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.R.] First Aid (see Table 6): Exposure Routes. Abs. Chloromethoxymethane.90 eV ScbaF/SaF §: ScbaF:Pd. liver. skin. resp sys [in animals: skin & lung cancer] Chloromethyl methyl ether 1-Chloro-1-nitropropane 3 Conversion: 1 ppm = 5. pulm congestion.P(oc): 32°F See Appendix E (page 351) Change: Daily IP: 10.P(oc): 144°F Change: N.C CAS#: RTECS#: IDLH: Formula: 107-30-2 KN6650000 Ca [N. kidney. heart damage Breath: Resp support TO: Resp sys. pulm edema. IP: 9. Con Skin: Soap wash SY: In animals: irrit eyes. liver. skin. kidneys. Symptoms.] CH3OCH2Cl Conversion: DOT: 1239 131 Synonyms/Trade Names: Chlorodimethyl ether.6 20 ppm: Sa* Eyes: Prevent eye contact BP: 289°F 50 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 0.06 VP(70°F): 192 mmHg Quick drench FRZ: -154°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Water [Note: Reacts with water to form hydrochloric acid & formaldehyde. muc memb. Target Organs (see Table 5): Eye: Irr immed ER: Inh. cough. wheez.Pp:AScba Eyes: Prevent eye contact BP: 138°F Escape: GmFOv/ScbaE Wash skin: When contam/Daily Sol: Reacts Remove: When wet (flamm) Fl. Ing. [fungicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 123. acids First Aid (see Table 6): Exposure Routes. bronchial secretions.Pp/SaF:Pd. low-wgt.Gr: 1. Methylchloromethyl ether Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH P&CAM220 (II-1) See Appendix A OSHA 10 OSHA PEL: [1910. pulm edema. blood stainedSwallow: Medical attention immed sputum.Pp:AScba Sp.Gr: 1. Target Organs (see Table 5): Eye: Irr immed ER: Inh.1006] See Appendix B Physical Description: Colorless liquid with an irritating odor. CVS. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 80.5 ¥: ScbaF:Pd. Con Skin: Soap wash immed SY: Irrit eyes.

P: NA Escape: GmFOv/ScbaE Change: N. Fl. vomit Skin: Soap wash immed Breath: Resp support TO: Eyes. lac.32 mg/m3 DOT: 1020 126 Synonyms/Trade Names: Fluorocarbon-115.D. card arrhy. RGasD: 5. resp sys Swallow: Medical attention immed Chloropicrin 67 .2% GmFOv/ScbaF/SaF §: ScbaF:Pd. Ing. cough. Symptoms. Conversion: 1 ppm = 6. potassium.P: NA Remove: N.96 eV Change: N. CNS. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. narco.R. CVS Chloropentafluoroethane C Formula: CAS#: RTECS#: IDLH: CCl3NO2 76-06-2 PB6300000 2 ppm Conversion: 1 ppm = 6. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.5 Skin: Frostbite BP: -38°F Not available.] Exposure Routes. Con (liquid) Eye: Frostbite SY: Dysp.Pp:AScba Remove: When wet or contam Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 154. [pesticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 164. skin. Monochloropentafluoroethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1000 ppm (6320 mg/m3) OSHA PEL†: none None available Physical Description: Colorless gas with a slight. pulm edema.7 mg/m ) None available Physical Description: Colorless to faint-yellow.s.1 ppm (0. aluminum powder.Formula: CAS#: RTECS#: IDLH: CClF2CF3 76-15-3 KH7877500 N. liquid: frostbite..R. oily liquid with an intensely irritating odor. IP: 12. zinc) Exposure Routes. Genetron® 115. derm TO: Skin.7 mg/m3) (see Table 1): 3 OSHA PEL: TWA 0.55 Provide: Frostbite wash VP(70°F): 7. Halocarbon 115. n. skin. resp sys. Freon® 115.Pp/SaF:Pd.006% Wash skin: N. IP: ? Provide: Eyewash Sp.) Synonyms/Trade Names: Nitrochloroform. heart palp.Gr: 1.66 VP: 18 mmHg Quick drench FRZ: -93°F UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: The material may explode when heated under confinement.g. Eyes: Frostbite Sol(77°F): 0. nau. Con SY: Irrit eyes. inco.72 mg/m3 DOT: 1580 154. Trichloronitromethane Exposure Limits: Measurement Methods NIOSH REL: TWA 0.R. dizz. 1583 154 (mixture. nau. ethereal odor. sodium.R. Skin: Frostbite Breath: Resp support asphy.o. [Note: Shipped as a liquefied compressed gas.4 2 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 234°F Wash skin: When contam Sol: 0. Nitrotrichloromethane. alkaline earth metals (e. vomit.1 ppm (0.9 atm FRZ: -223°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Alkalis.

resp sys.79 eV Provide: Eyewash Sp. Ing. derm. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 138. liver. Sp. enlarged liver. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 88. jaun Breath: Resp support TO: Eyes. alopecia. skin.3% LEL: 1.R. repro sys [lung & skin cancer] β-Chloroprene Formula: CAS#: RTECS#: IDLH: ClC6H4CH=CH2 2039-87-4 WL4160000 N. resp sys.Gr: 0. skin. CNS. PNS Swallow: Medical attention immed o-Chlorostyrene 3 68 . Conversion: 1 ppm = 5.6 Skin: Prevent skin contact BP: 372°F Not available.] First Aid (see Table 6): Exposure Routes.C Formula: CAS#: RTECS#: IDLH: CH2=CClCH=CH2 126-99-8 EI9625000 Ca [300 ppm] Conversion: 1 ppm = 3. acidosis. anxi.9% Class IB Flammable Liquid Incompatibilities and Reactivities: Peroxides & other oxidizers [Note: Polymerizes at room temperature unless inhibited with antioxidants. kidneys. Target Organs (see Table 5): Eye: Irr immed ER: Inh. repro Breath: Resp support effects.P: -4°F Change: N. [carc] Swallow: Medical attention immed TO: Eyes. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Con Skin: Soap wash immed SY: Irrit eyes. Symptoms.D.10 VP(77°F): 0. ether-like odor.62 mg/m3 DOT: 1991 131P (inhibited) Synonyms/Trade Names: 2-Chloro-1.5 ¥: ScbaF:Pd. irrity. Symptoms.3-butadiene.Gr: 1. Ing.R. prot. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl. Abs. Chloroprene Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 1002 C 1 ppm (3. ortho-Chlorostyrene.67 mg/m DOT: Synonyms/Trade Names: 2-Chlorostyrene.6 mg/m ) [15-minute] OSHA 112 See Appendix A 3 OSHA PEL†: TWA 25 ppm (90 mg/m ) [skin] Physical Description: Colorless liquid with a pungent.P: 138°F Remove: When wet or contam IP: ? Change: N.Pp:AScba Eyes: Prevent eye contact BP: 139°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: Slight Remove: When wet (flamm) Fl.96 VP: 188 mmHg Quick drench FRZ: -153°F UEL: 11. skin. Chlorobutadiene. Con Skin: Soap wash SY: In animals: irrit eyes. IP: 8. 1-Chloro-2-ethenylbenzene Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (285 mg/m3) (see Table 1): 3 ST 75 ppm (428 mg/m ) None available OSHA PEL†: none Physical Description: Colorless liquid. skin.96 mmHg FRZ: -82°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. hema.Pp/SaF:Pd.

magnesium [Note: Emits oxides of nitrogen and chloride ion when heated to decomposition. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 230. Abs. resp sys. anes.] Exposure Routes. Con SY: No adverse effects noted in ingestion studies with animals. skin Swallow: Medical attention immed 2-Chloro-6-trichloromethyl pyridine 69 .2. Skin: Soap wash immed Breath: Resp support TO: Eyes.9 Skin: Prevent skin contact BP: ? Not available. Sp.Gr: ? VP(73°F): 0.6 Skin: Prevent skin contact BP: 320°F Not available. drow. skin. sweet odor. kidneys o-Chlorotoluene C Formula: CAS#: RTECS#: IDLH: ClC5H3NCCl3 1929-82-4 US7525000 N. Conversion: DOT: Synonyms/Trade Names: 2-Chloro-6-(trichloro-methyl)pyridine.003 mmHg MLT: 145°F UEL: ? LEL: ? Combustible Solid [Explosive] Incompatibilities and Reactivities: Aluminum. Conversion: 1 ppm = 5. liver.08 Provide: Eyewash VP(77°F): 4 mmHg FRZ: -31°F UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Acids. Con SY: Irrit eyes. Abs. inco. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 126. 2-Chloro-1-methylbenzene. CNS. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.6-Tetrachloro-2-picoline Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 None available ST 20 mg/m (total) 3 TWA 5 mg/m (resp) OSHA PEL: TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp) Physical Description: Colorless or white.009% Wash skin: When contam Fl.P: ? Remove: When wet or contam IP: ? Change: Daily Sp. N-serve®.D. oxidizers. Symptoms. Ing. muc memb. o-Tolyl chloride Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (250 mg/m3) (see Table 1): 3 ST 75 ppm (375 mg/m ) None available OSHA PEL†: none Physical Description: Colorless liquid with an aromatic odor.18 mg/m3 DOT: 2238 129 Synonyms/Trade Names: 1-Chloro-2-methylbenzene. alkalis. Ing. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. reducing materials. Nitrapyrin. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl. Symptoms. cough. Skin: Soap wash immed Breath: Resp support liver. 2. water Exposure Routes.P: 96°F Remove: When wet (flamm) IP: 8.Gr: 1.D. crystalline solid with a mild. Eyes: Prevent eye contact Sol(77°F): 0.Formula: CAS#: RTECS#: IDLH: ClC6H4CH3 95-49-8 XS9000000 N. skin.83 eV Change: N. 2-Chlorotoluene. kidney inj Swallow: Medical attention immed TO: Eyes.2. derm.

W4001 See Appendix A See Appendix C 3 OSHA PEL (as CrO3): C 0. Con SY: Irrit resp sys. wood. Chromium(VI) oxide (1:3).] Chemical & Physical Properties: Personal Protection/Sanitation Respirator Recommendations (see Tables 3 and 4): MW: 100. [pesticide] [Note: Commercial formulations may be combined with combustible liquids. PNS. diarr TO: Resp sys.). Dursban® Exposure Limits: Measurement Methods NIOSH REL: TWA 0. or other CrO3: Noncombustible Solid. skin. nau. 7605 TWA 0. 1463 141 (acid.1 mg/m See Appendix C Physical Description: CrO3: Dark-red. CNS. chromium(VI) compounds) such as zinc chromate vary depending upon the specific compound. sens derm.e. etc.6-trichloro-2-pyridyl phosphorothioate.70 (CrO3) Change: Daily Provide: Eyewash VP: Very low MLT: 387°F (Decomposes) Quick drench UEL: NA LEL: NA Incompatibilities and Reactivities: Combustible.Gr: 2. [Note: Often used in an aqueous solution (H2CrO4). caustics. Sol: 0.P: ? Wash skin: When contam IP: ? Remove: When wet or contam Sp.6 (see Table 2): BP: 320°F (Decomposes) Skin: Prevent skin contact Not available. Ing.6 mg/m [skin] Physical Description: Colorless to white. blurred vision. Symptoms. amines LEL: ? [Note: Corrosive to copper & brass. kidneys.001 mg/m3 OSHA ID103. Symptoms. liver. salv.] Combustible Solid Chlorpyrifos Exposure Routes. accelerate the burning of combustible corrosive to metals materials. eyes. leucyt. nasal septum perf. organic. conj.5. skin [lung cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap flush immed Breath: Resp support Swallow: Medical attention immed 70 . Chromic acid and chromates Exposure Routes. Target Organs (see Table 5): ER: Inh. abdom cramps.Pp:AScba Sol: 63% Eyes: Prevent eye contact Escape: 100F/ScbaE Fl.40 (Liquid at 110°F) Change: Daily VP: 0.. solid) Synonyms/Trade Names: Chromic acid (CrO3): Chromic anhydride. plastics. eye inj. bluish lips.P: NA Wash skin: When contam IP: NA Remove: When wet or contam Sp. Chromium trioxide. plasma chol First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed RTECS#: IDLH: Ca [15 mg/m3 Formula: CAS#: CrO3 (acid) 1333-82-0 (CrO3) GB6650000 (CrO3) {as Cr(VI)}] Conversion: DOT: 1755 154 (acid solution). vomit.0002% Eyes: Prevent eye contact Fl. resp sys. C9H11Cl3NO3PS 2921-88-2 Conversion: DOT: 2783 152 Synonyms/Trade Names: Chlorpyrifos-ethyl. liver. odorless flakes or powder. Target Organs (see Table 5): ER: Inh.Gr: 1. lar spasms. eosin. miosis.C CAS#: RTECS#: IDLH: Formula: TF6300000 N. 7604. skin ulcer. Ing. ID215.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 350.2 mg/m3 (see Table 1): OSHA PEL†: none 3 NIOSH 5600 OSHA 62 ST 0. Con SY: Wheez. Exposure Limits: Measurement Methods NIOSH REL (as Cr): Ca (see Table 1): NIOSH 7600. Chromic oxide. Abs. [carc] TO: Blood. O.0 (see Table 2): NIOSH BP: 482°F (Decomposes) Skin: Prevent skin contact ¥: ScbaF:Pd. Synonyms of chromates (i. aluminum. crystalline solid with a mild.Pp/SaF:Pd. leupen. kidney damage.O-Diethyl O-3. but will readily oxidizable materials (paper. sulfur. mercaptan-like odor.D.00002 mmHg MLT: 108°F UEL: ? Incompatibilities and Reactivities: Strong acids.

5 mg/m3: Sa:Cf*/PaprHie* Change: N.Pp/SaF:Pd. 7301.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes.5 mg/m3 (see Table 1): NIOSH 7024. 7301.5 mg/m OSHA ID121.5 mg/m See Appendix C Physical Description: Appearance and odor vary depending upon the specific compound. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Properties vary depending Skin: Prevent skin contact 2.R. Remove: When wet or contam 12. [Note: Chromium(II) compounds include soluble chromous salts. 25 mg/m3: 100F/PaprTHie*/ScbaF/SaF 250 mg/m3: SaF:Pd.5 mg/m3: Qm* Eyes: Prevent eye contact upon the specific Wash skin: When contam 5 mg/m3: 95XQ*/Sa* compound. Con Skin: Water flush prompt SY: Irrit eyes.R. ID125G See Appendix C Physical Description: Appearance and odor vary depending upon the specific compound. Symptoms. 25 mg/m3: 100F/PaprTHie*/ScbaF/SaF §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 9102 See Appendix C 3 OSHA ID121.Pp/SaF:Pd.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Pp §: ScbaF:Pd. ID125G OSHA PEL: TWA 0. 7303. Con Skin: Water flush prompt SY: Irrit eyes.5 mg/m3: Sa:Cf*/PaprHie* Change: N. Ing. skin Swallow: Medical attention immed C Chromium(III) compounds (as Cr) Formula: CAS#: RTECS#: IDLH: 25 mg/m3 [as Cr(III)] Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific Chromium(III) compound.5 mg/m3 NIOSH 7024. 7300.5 mg/m3: Qm* upon the specific compound. [Note: Chromium(III) compounds include soluble chromic salts. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.] Exposure Limits: Measurement Methods NIOSH REL: TWA 0.Chromium(II) compounds (as Cr) Formula: CAS#: RTECS#: IDLH: 250 mg/m3 [as Cr(II)] Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific Chromium(II) compound. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact Properties vary depending 2. skin Swallow: Medical attention immed 71 . sens derm Breath: Resp support TO: Eyes. Symptoms. 9102 See Appendix C 3 OSHA PEL: TWA 0. 7300. Eyes: Prevent eye contact Wash skin: When contam 5 mg/m3: 95XQ*/Sa* Remove: When wet or contam 12.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes. 7303. sens derm Breath: Resp support TO: Eyes. Ing.

VP: 20 mmHg Provide: Eyewash FRZ: -142°F Quick drench UEL: NA Incompatibilities and Reactivities: Water. 7301. skin. Chromium oxychloride.P: NA Wash skin: When contam IP: 12. Chromium dioxychloride. skin.R.Chromium metal C Conversion: Synonyms/Trade Names: Chrome. Dichlorodioxochromium Exposure Limits: Measurement Methods NIOSH REL: Ca OSHA PEL: none (see Table 1): 3 0.R. skin.0 (see Table 2): NIOSH BP: 4788°F Skin: N. but a chromic chloride. eye. See Appendix C Physical Description: Deep-red liquid with a musty.D.5 mg/m3: Sa:Cf*/PaprHie* Sp.] Conversion: DOT: 1758 137 Synonyms/Trade Names: Chlorochromic anhydride. acrid odor. skin burns [carc] TO: Eyes. lung fib (histologic) Breath: Resp support TO: Eyes.5 mg/m3: Qm* Sol: Insoluble Eyes: N. Chromyl chloride Exposure Routes.Pp:AScba LEL: NA Escape: 100F/ScbaE Noncombustible Solid in bulk form. hard. 2. Chromic oxychloride.R. resp sys Swallow: Medical attention immed Formula: Cr DOT: CAS#: 7440-47-3 RTECS#: GB4200000 IDLH: 250 mg/m3 (as Cr) Formula: CAS#: RTECS#: IDLH: Cr(OCl)2 14977-61-8 GB5775000 Ca [N. brittle. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Symptoms.Pp/SaF:Pd. skin. Chromium dioxide dichloride. ID125G See Appendix C [*Note: The PEL also applies to insoluble chromium salts.001 mg Cr(VI)/m None available See Appendix A.R. Noncombustible Liquid. 9102 OSHA ID121. Fl. combustible substances. peroxide). Corrodes common metals. odorless solid. Chromium chloride oxide. [Note: Fumes in moist air.R. upper resp sys.Pp/SaF:Pd. halides. resp sys [lung cancer] First Aid (see Table 6): Eye: Irr immed Skin: Water flush immed Breath: Resp support Swallow: Medical attention immed 72 . Ing. 25 mg/m3: 100F/PaprTHie*/ VP: 0 mmHg (approx) ScbaF/SaF MLT: 3452°F 250 mg/m3: SaF:Pd. Chromium Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Gr: 7. Con SY: Irrit eyes. Abs.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 154. 12. Chromium dichloride dioxide.9 (see Table 2): NIOSH BP: 243°F Skin: Prevent skin contact ¥: ScbaF:Pd.14 Change: N. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 52.R. Ing. forms chromic acid. 5 mg/m3: 95XQ*/Sa* IP: NA Remove: N.P: NA Wash skin: N. turpentine [Note: Reacts violently in water. 7300. Con Skin: Soap wash SY: Irrit eyes.Pp:AScba Sol: Reacts Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. but finely divided dust burns Incompatibilities and Reactivities: Strong oxidizers (such as hydrogen rapidly if heated in a flame.Pp UEL: NA §: ScbaF:Pd.60 eV Remove: When wet or contam Sp.91 Change: N. Target Organs (see Table 5): ER: Inh.5 mg/m3 NIOSH 7024. lustrous. hydrochloric acid & chlorine.] Physical Description: Blue-white to steel-gray.] powerful oxidizer. Symptoms. LEL: NA phosphorus. alkalis Exposure Routes. burning.Gr(77°F): 1. See Appendix C 3 OSHA PEL*: TWA 1 mg/m 7303.

Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 192. Combustible Solid.R. throat.R.R. Bituminous coal dust. emphy TO: Resp sys First Aid (see Table 6): Breath: Fresh air 73 . resp sys Clopidol C Coal dust Formula: CAS#: RTECS#: GF8281000 IDLH: N. crystalline solid. Incompatibilities and Reactivities: None reported Exposure Routes. Fl. Lignite coal dust Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 NIOSH 0600.Gr: ? VP: ? MLT: >608°F UEL: NA LEL: NA Noncombustible Solid. Incompatibilities and Reactivities: None reported Exposure Routes.R. Sp. specific coal type. Symptoms. ≥ 5% SiO2] See Appendix C (Mineral Dusts) Physical Description: Dark-brown to black solid dispersed in air. Change: N. C7H7Cl2NO Conversion: DOT: Synonyms/Trade Names: Coyden®.R. Not available. 3. Target Organs (see Table 5): ER: Inh SY: Chronic bron.R. Wash skin: N. Eyes: N.4 mg/m [respirable. skin. Con Skin: Soap wash SY: Irrit eyes. 0600 ST 20 mg/m (total) 3 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) TWA 5 mg/m3 (resp) Physical Description: White to light-brown.5-Dichloro-2. Sol: Insoluble Wash skin: N. cough Breath: Fresh air TO: Eyes. Eyes: N.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Conversion: DOT: 1361 133 Synonyms/Trade Names: Anthracite coal dust. but dust may explode in cloud form.6-dimethyl-4-pyridinol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500.R. slightly explosive Remove: N.1 Skin: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): Properties vary depending upon the Skin: N. IP: ? Change: N. skin. nose.D.P: NA Remove: N.D. <5% SiO2] 3 TWA (10 mg/m )/(%SiO2 + 2) [respirable.CAS#: RTECS#: IDLH: Formula: 2971-90-6 UU7711500 N. decr pulm func. BP: ? Not available. when exposed to flame. 7500 OSHA PEL†: TWA 2.R.R. Symptoms.

pyrene. Con SY: Derm.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. Symptoms. Dicobalt carbonyl. kidney & skin cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: C8Co2O8 10210-68-1 GG0300000 N. kidneys [lung. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Properties vary depending upon Skin: Prevent skin contact ¥: ScbaF:Pd. Escape: GmFOv100/ScbaE Wash skin: Daily Combustible Solids Remove: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 341.87 VP: 0. anthracene & benzo(a)pyrene). bladder. skin. Incompatibilities and Reactivities: Air [Note: Decomposes on exposure to air or heat. Octacarbonyldicobalt Exposure Limits: Measurement Methods NIOSH REL: TWA 0. [carc] TO: Resp sys.D. chrysene.7 mmHg MLT: 124°F UEL: NA LEL: NA Noncombustible Solid. [Note: The pure substance is white. coal tar pitch.Pp:AScba Eyes: Prevent eye contact the specific compound. resp sys. in animals: liver.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 OSHA 58 TWA 0. crystalline solid. Ing. Cobalt octacarbonyl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. phenanthrene. but flammable carbon monoxide is emitted during decomposition. skin. skin. and creosote to be coal tar products.9 Skin: Prevent skin contact BP: 126°F (Decomposes) Not available.2 mg/m3 (benzene-soluble fraction) [1910. blood.Pp/SaF:Pd. acridine. kidney inj. stable in atmosphere of hydrogen & carbon monoxide. CNS Cobalt carbonyl (as Co) 74 . Breath: Resp support dysp.] Exposure Routes.Gr: 1.1 mg/m (cyclohexane-extractable fraction) See Appendix A See Appendix C OSHA PEL: TWA 0.C CAS#: RTECS#: IDLH: 65996-93-2 GF8655000 Ca [80 mg/m3] Conversion: DOT: 2713 153 (acridine) Synonyms/Trade Names: Synonyms vary depending upon the specific compound (e. Con Skin: Soap wash SY: Irrit eyes.1002] See Appendix C Physical Description: Black or dark-brown amorphous residue. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.1 mg/m3 (see Table 1): OSHA PEL†: none None available Physical Description: Orange to dark-brown. wheez. Conversion: DOT: Synonyms/Trade Names: di-mu-Carbonylhexacarbonyldicobalt.. muc memb. Abs. pulm edema Swallow: Medical attention immed TO: Eyes. Symptoms. Change: Daily Coal tar pitch volatiles Formula: Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. cough.g.R. bron. [Note: NIOSH considers coal tar. Cobalt tetracarbonyl dimer. Target Organs (see Table 5): ER: Inh. Dicobalt Octacarbonyl. decr pulm func.

dysp.93 VP: >1 atm FRZ: -15°F UEL: ? LEL: ? Flammable Gas Incompatibilities and Reactivities: Air [Note: Unstable gas that decomposes rapidly in air at room temperature to cobalt carbonyl & hydrogen.Gr: 8. Eyes: Prevent eye contact Sol: 0.0 Skin: Prevent skin contact BP: ? Not available. resp sys Cobalt hydrocarbonyl (as Co) C Formula: CAS#: RTECS#: IDLH: Co 7440-48-4 GF8750000 20 mg/m3 (as Co) Conversion: DOT: Synonyms/Trade Names: Cobalt metal dust. 7300.1 mg/m3 (see Table 1): OSHA PEL†: none None available Physical Description: Gas with an offensive odor. dysp. Cobalt metal fume Exposure Limits: Measurement Methods NIOSH REL: TWA 0.P: NA (Gas) Remove: When wet or contam IP: ? Change: Daily RGasD: 5. silver-gray to black solid.] First Aid (see Table 6): Exposure Routes. Con Eye: Irr immed SY: Cough. Tetracarbonylhydridocobalt.05% Wash skin: When contam Fl.R.25 mg/m3: Qm Eyes: N. Conversion: DOT: Synonyms/Trade Names: Hydrocobalt tetracarbonyl. ID125G.92 20 mg/m3: SaF:Pd.Pp:AScba MLT: 2719°F Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid in bulk form. resp hypersensitivity. resp sys Cobalt metal dust and fume (as Co) 75 . decr pulm func. cough.05 mg/m3 (see Table 1): 3 OSHA PEL†: TWA 0.P: NA 1. Tetracarbonylhydrocobalt Exposure Limits: Measurement Methods NIOSH REL: TWA 0.25 mg/m3: Sa:Cf*/PaprHie* Change: Daily IP: NA 2. ammonium nitrate Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 172.9 0.5 mg/m3: 100F/ScbaF/SaF Sp. pulm edema Breath: Resp support TO: Eyes. diffuse Skin: Soap wash Breath: Resp support nodular fib. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 58.D. Target Organs (see Table 5): Eye: Irr immed ER: Inh. derm. 9102 OSHA ID121. BP: 5612°F Wash skin: When contam Sol: Insoluble 0.Pp VP: 0 mmHg (approx) §: ScbaF:Pd.1 mg/m NIOSH 7027.Pp/SaF:Pd. wheez. Symptoms. skin. Symptoms. Ing. Incompatibilities and Reactivities: Strong oxidizers.5 mg/m3: 95XQ*/Sa* Remove: When wet or contam Fl. ID213 Physical Description: Odorless. but finely divided dust will burn at high temperatures. low-wgt. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. asthma Swallow: Medical attention immed TO: Skin. 7301. 7303. Con Skin: Soap wash SY: In animals: irrit resp sys.Formula: CAS#: RTECS#: IDLH: HCo(CO)4 16842-03-8 GG0900000 N. decr pulm func.

metallic taste. odorless solid. as Cu) 76 . pharynx.D. Skin: Soap wash prompt Breath: Resp support in animals: lung. Incompatibilities and Reactivities: Oxidizers. Escape: GmFOv100/ScbaE Wash skin: Daily Remove: N. skin. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 63. derm. alkalis. resp sys. [*Note: The REL and PEL also apply to other copper compounds (as Cu) except 7303.Pp VP: 0 mmHg (approx) §: ScbaF:Pd. lung.94 100 mg/m3: SaF:Pd. ID125G copper fume.Coke oven emissions Formula: CAS#: RTECS#: GH0346000 IDLH: Ca [N. [Note: See Appendix C for more information. 9102 OSHA ID121. cough.] C Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific constituent. 7301. 7300. Change: Daily See Appendix E (page 351) Incompatibilities and Reactivities: None reported Exposure Routes. Symptoms. Ing. kidneys (incr risk with Wilson's disease) Swallow: Medical attention immed Copper (dusts and mists. sodium azide. Con SY: Irrit eyes. liver.R. but powdered form may ignite. Con SY: Irrit eyes. Target Organs (see Table 5): Eye: Irr immed ER: Inh. liver. wheez.2 mg/m (benzene-soluble fraction) See Appendix A See Appendix C OSHA PEL: [1910.P: NA 25 mg/m3: Sa:Cf*/PaprHie* Change: Daily IP: NA 50 mg/m3: 100F/PaprTHie*/ScbaF/SaF Sp. resp sys.150 mg/m3 (benzene-soluble fraction) Physical Description: Emissions released during the carbonization of bituminous coal for the production of coke.Pp/SaF:Pd. [carc] TO: Skin. nasal septum perf.1029] TWA 0.Pp/SaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Properties vary depending upon Skin: Prevent skin contact ¥: ScbaF:Pd.Pp:AScba MLT: 1981°F Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid in bulk form. Symptoms.Gr: 8. acetylene First Aid (see Table 6): Exposure Routes. urinary sys [skin. lustrous.Pp:AScba Eyes: Prevent eye contact the constituent.5 5 mg/m3: Qm* Eyes: Prevent eye contact BP: 4703°F Wash skin: When contam 10 mg/m3: 95XQ*/Sa* Sol: Insoluble Remove: When wet or contam Fl. anemia TO: Eyes. nose. kidney damage. Copper metal fumes Exposure Limits: Measurement Methods NIOSH REL*: TWA 1 mg/m3 (see Table 1): OSHA PEL*: TWA 1 mg/m3 NIOSH 7029. malleable. dysp. kidney & bladder cancer] First Aid (see Table 6): Eye: Irr immed Breath: Resp support Formula: CAS#: RTECS#: IDLH: Cu 7440-50-8 GL5325000 100 mg/m3 (as Cu) Conversion: DOT: Synonyms/Trade Names: Copper metal dusts. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 OSHA 58 TWA 0. Target Organs (see Table 5): ER: Inh.] Physical Description: Reddish. resp sys.

R. IP: NA 5 mg/m3: 100F/SaT:Cf/PaprTHie/ Change: N. hair TO: Eyes. Fl.1043] See Appendix C Physical Description: Colorless. IP: NA 5 mg/m3: Sa:Cf/PaprHie Change: N. ID206 Physical Description: Finely divided black particulate dispersed in air. Fl. ID125G. upper resp symptoms after initial exposure TO: CVS. BP: Decomposes 1 mg/m3: Qm Eyes: N. Symptoms.R.P: NA 2 mg/m3: 95XQ/Sa Remove: N. resp sys (incr risk with Wilson's disease) Copper fume (as Cu) C Cotton dust (raw) Formula: CAS#: RTECS#: GN2275000 IDLH: 100 mg/m3 Conversion: DOT: 1365 133 (cotton) Synonyms/Trade Names: Raw cotton dust Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA <0. skin. Sp. lass. decr FEV. 7303 OSHA ID121. upper resp sys. Copper(II) oxide fume.5 NIOSH/OSHA Skin: N. zirconium [Note: See Copper (dusts and mists) for properties of Copper metal.R.Pp/SaF:Pd.R. bron. 7300.1 mg/m NIOSH 7029.R.Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA CuO: Noncombustible Solid Incompatibilities and Reactivities: CuO: Acetylene.Pp:AScba LEL: NA Escape: 100F/ScbaE See Appendix E (page 351) Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.200 mg/m3 OSHA [1910. cough. chills. dry throat.Pp/SaF:Pd. discoloration skin. metallic or sweet taste.4 (CuO) ScbaF/SaF VP: 0 mmHg (approx) 100 mg/m3: SaF:Pd.R. musc ache. Sol: Insoluble Wash skin: N.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 79.R. BP: Decomposes 1 mg/m3: 95XQ/Sa Eyes: N.Formula: CAS#: RTECS#: IDLH: CuO/Cu 1317-38-0 (CuO) GL7900000 (CuO) 100 mg/m3 (as Cu) Conversion: DOT: Synonyms/Trade Names: Cu: Copper fume CuO: Black copper oxide fume. fever. Sol: Insoluble Wash skin: N. mal. Cupric oxide fume [Note: Also see specific listing for Copper (dusts and mists).R.] Exposure Limits: Measurement Methods NIOSH REL: TWA 0.1043] See Appendix C OSHA PEL: [Z-1-A & 1910. wheez.1 mg/m3 (see Table 1): 3 OSHA PEL: TWA 0. [Note: Exposure may occur in copper & brass plants and during the welding of copper alloys. Con Breath: Resp support SY: Irrit eyes. 7301. resp sys 77 .P: NA 2. odorless solid.R. Symptoms.R.5 mg/m3: Sa:Cf/PaprHie Remove: N. Copper monoxide fume.Pp MLT: 1879°F (Decomposes) §: ScbaF:Pd.Gr: ? 10 mg/m3: 100F/SaT:Cf/PaprTHie/ VP: 0 mmHg (approx) ScbaF/SaF MLT: Decomposes 100 mg/m3: Sa:Pd.Pp UEL: NA §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. cough. Sp. nau.Gr: 6. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: ? NIOSH Skin: N. dysp. fever. metal fume fever: chills.] Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Breath: Fresh air ER: Inh SY: Byssinosis: chest tight.

Pp FRZ: 54°F Quick drench §: ScbaF:Pd. liver. pancreas. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. kidney damage. 3-Hydroxytoluene. skin. Ing. [Note: A solid below 54°F. CNS effects: conf. derm. skin burns. convuls Swallow: Medical attention immed TO: Eyes.Pp:AScba UEL: ? Escape: GmFOv100/ScbaE LEL(300°F): 1.70 ScbaF/SaF VP: 0. 2-(2. skin. CNS. kidneys Crag® herbicide Formula: CAS#: RTECS#: IDLH: CH3C6H4OH 108-39-4 GO6125000 250 ppm Conversion: 1 ppm = 4.Pp:AScba MLT: 473°F (Decomposes) Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers. liver.14 mmHg ScbaF/SaF 250 ppm: SaF:Pd. kidney. liver. weak pulse. Abs. CNS. in animals: CNS Skin: Water wash prompt Breath: Resp support effects.5 ppm: Sa:Cf/PaprOvHie Wash skin: When contam Fl. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Con Eye: Irr immed SY: Irrit eyes. kidneys.Pp/SaF:Pd. muc memb.P: 187°F 115 ppm: CcrFOv100/GmFOv100/ Remove: When wet or contam IP: 8.2 NIOSH Skin: Prevent skin contact BP: 397°F 23 ppm: CcrOv95/Sa Eyes: Prevent eye contact Sol: 2% 57.43 mg/m3 DOT: 2076 153 Synonyms/Trade Names: meta-Cresol.4-Dichlorophenoxy)ethyl sodium sulfate.3 ppm (10 mg/m3) 3 NIOSH 2546 OSHA PEL: TWA 5 ppm (22 mg/m ) [skin] OSHA 32 Physical Description: Colorless to yellowish liquid with a sweet. 3-Methyl phenol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2. Swallow: Medical attention immed lung.P: NA 250 mg/m3: Sa:Cf/PaprHie Change: Daily IP: ? 500 mg/m3: 100F/PaprTHie*/SaT:Cf*/ Sp. resp sys. 3-Cresol. Symptoms. CVS m-Cresol 78 .Pp/SaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 108. liver. Ing. odorless solid.Gr: 1. irreg rapid resp. pancreas damage TO: Eyes.1 mmHg §: ScbaF:Pd. 1-Hydroxy-3-methylbenzene. m-Cresylic acid. Sesone Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH S356 (II-5) TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Colorless to white crystalline. tarry odor. dysp.Gr: 1. resp Skin: Soap wash immed Breath: Resp support fail. skin.1 50 mg/m3: Qm Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol(77°F): 26% 100 mg/m3: 95XQ/Sa Remove: When wet or contam Fl. acids Exposure Routes.98 eV Change: Daily Sp. acids Exposure Routes.C CAS#: RTECS#: IDLH: Formula: KK4900000 500 mg/m3 C6H3Cl2OCH2CH2OSO3Na 136-78-7 Conversion: DOT: Synonyms/Trade Names: Crag® herbicide No.1% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. Symptoms.03 PaprTOvHie*/SaT:Cf*/ Provide: Eyewash VP(77°F): 0. 1. depres. Con Eye: Irr immed SY: Irrit eyes. [herbicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 309. skin. eye.

weak pulse. resp fail. Target Organs (see Table 5): Eye: Irr immed ER: Inh. 1-Hydroxy-2-methylbenzene. Ing. Target Organs (see Table 5): ER: Inh. resp sys.43 mg/m3 DOT: 2076 153 Synonyms/Trade Names: ortho-Cresol. o-Cresylic acid. acids Class IIIA Combustible Liquid o-Cresol C Exposure Routes.11 mmHg ScbaF/SaF 250 ppm: SaF:Pd. 4-Methyl phenol Exposure Limits: Measurement Methods NIOSH REL: TWA 2. liver. irreg rapid resp.97 eV Change: Daily Sp. kidneys. skin.5 ppm: Sa:Cf/PaprOvHie Fl.2 (see Table 2): NIOSH BP: 376°F Skin: Prevent skin contact 23 ppm: CcrOv95/Sa Sol: 2% Eyes: Prevent eye contact 57. derm. muc memb. CNS.Pp MLT: 88°F Quick drench §: ScbaF:Pd. tarry odor. pancreas damage TO: Eyes. lung.Pp/SaF:Pd. skin burns.4% Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. Symptoms. Swallow: Medical attention immed kidney.2 NIOSH Skin: Prevent skin contact BP: 396°F 23 ppm: CcrOv95/Sa Eyes: Prevent eye contact Sol: 2% 57. tarry odor.04 PaprTOvHie*/SaT:Cf*/ Provide: Eyewash VP(77°F): 0.Pp MLT: 95°F Quick drench §: ScbaF:Pd.3 ppm (10 mg/m3) 3 NIOSH 2546 OSHA PEL: TWA 5 ppm (22 mg/m ) [skin] OSHA 32 Physical Description: White crystals with a sweet.Gr: 1. skin burns. CNS. resp fail. pancreas. skin. depres. kidney. 2-Hydroxytoluene. Symptoms. liver. derm. resp sys. pancreas. Con SY: Irrit eyes. Abs. [Note: A liquid above 88°F.29 mmHg Provide: Eyewash ScbaF/SaF 250 ppm: SaF:Pd. eye.43 mg/m DOT: 2076 153 Synonyms/Trade Names: para-Cresol. 1-Hydroxy-4-methylbenzene. irreg rapid resp. muc memb. depres. 4-Hydroxytoluene. kidneys. CVS First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed CAS#: RTECS#: IDLH: Formula: 106-44-5 GO6475000 250 ppm CH3C6H4OH Conversion: 1 ppm = 4.Pp:AScba UEL: ? Escape: GmFOv100/ScbaE LEL(300°F): 1.Gr: 1. Breath: Resp support dysp. CNS effects: conf.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 108. CVS p-Cresol 3 79 . dysp. Con Skin: Soap wash immed SY: Irrit eyes. liver. CNS effects: conf. eye. Abs. weak pulse. Ing. [Note: A liquid above 95°F. skin.Pp:AScba UEL: ? Escape: GmFOv100/ScbaE LEL(300°F): 1. skin.Pp/SaF:Pd. 2-Methyl phenol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2.CAS#: RTECS#: IDLH: Formula: 95-48-7 GO6300000 250 ppm CH3C6H4OH Conversion: 1 ppm = 4.3 ppm (10 mg/m3) (see Table 1): 3 NIOSH 2546 OSHA PEL: TWA 5 ppm (22 mg/m ) [skin] OSHA 32 Physical Description: Crystalline solid with a sweet.1% Combustible Solid Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. lung. pancreas damage TO: Eyes. p-Cresylic acid.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 108. liver. 2-Cresol.P: 178°F Wash skin: When contam 115 ppm: CcrFOv100/GmFOv100/ IP: 8. 4-Cresol.5 ppm: Sa:Cf/PaprOvHie Wash skin: When contam Fl.P: 187°F 115 ppm: CcrFOv100/GmFOv100/ Remove: When wet or contam IP: 8.93 eV Remove: When wet or contam Sp. acids First Aid (see Table 6): Exposure Routes.05 Change: Daily PaprTOvHie*/SaT:Cf*/ VP(77°F): 0.

in animals: dysp. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.P: 45°F Remove: When wet (flamm) IP: 9. nau. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin.73 eV GmFOv/ScbaF/SaF §: ScbaF:Pd.1% Class IB Flammable Liquid Incompatibilities and Reactivities: Caustics.] Exposure Routes. Sp.5% LEL: 2. [pesticide] [Note: Commercial product is a yellow oil. resp sys. pulm edema. Symptoms.Pp:AScba Change: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 291. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin. β-Methyl acrolein. wheez.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 70.87 mg/m3 CAS#: Formula: CH3CH=CHCHO 4170-30-3 DOT: 1143 131P (inhibited) RTECS#: GP9499000 IDLH: 50 ppm C Synonyms/Trade Names: 2-Butenal.] Exposure Routes.1 NIOSH/OSHA Skin: Prevent skin contact BP: 219°F 20 ppm: CcrOv*/Sa* Eyes: Prevent eye contact Sol: 18% 50 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Wash skin: When contam Fl. lac. dysp.D. Propylene aldehyde Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 ppm (6 mg/m3) NIOSH 3516 See Appendix C (Aldehydes) 3 OSHA 81 OSHA PEL: TWA 2 ppm (6 mg/m ) Physical Description: Water-white liquid with a suffocating odor. amines [Note: Polymerization may occur at elevated temperatures.87 Escape: GmFOv/ScbaE Provide: Eyewash VP: 19 mmHg FRZ: -101°F Quick drench UEL: 15. [Note: Turns pale-yellow on contact with air. Abs. C12H19ClNO3P Conversion: DOT: Synonyms/Trade Names: 4-t-Butyl-2-chlorophenylmethyl methylphosphoramidate. ammonia. Ing. blurred vision. resp sys. strong oxidizers. blood chol Crufomate 80 .Crotonaldehyde Conversion: 1 ppm = 2. such as in fire conditions.P: ? Remove: When wet or contam IP: ? Change: Daily Sp. Con SY: Irrit eyes. Dowco® 132.R. nitric acid.Gr: 1. resp sys Swallow: Medical attention immed CAS#: RTECS#: IDLH: Formula: 299-86-5 TB3850000 N.Gr: 0. Breath: Resp support sweat.7 Skin: Prevent skin contact BP: Decomposes Not available. resp sys. abdom cramps. anor Swallow: Medical attention immed TO: Eyes.16 VP(243°F): 0. diarr. skin. Con Skin: Soap wash immed SY: Irrit eyes.01 mmHg MLT: 140°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strongly alkaline & strongly acidic media [Note: Unstable over long periods in aqueous preparations or above 140°F. Ing.Pp/SaF:Pd. Ruelene® Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 NIOSH 0500 ST 20 mg/m OSHA PV2015 OSHA PEL†: none Physical Description: White. irrit skin Skin: Water flush immed Breath: Resp support TO: Eyes. crystalline solid in pure form.

CNS Swallow: Medical attention immed Cumene C CAS#: RTECS#: IDLH: Formula: 420-04-2 GS5950000 N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. IP: 8. or alkalis.28 Provide: Eyewash VP: ? MLT: 113°F Quick drench UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Above 104°F: Moisture. Symptoms.] Exposure Routes. skin. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 120. NH2CN Conversion: DOT: Synonyms/Trade Names: Amidocyanogen. resp sys.Gr: 1. lac. Abs.9% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers. coma Breath: Resp support TO: Eyes.P: 286°F Remove: When wet or contam IP: 10. Carbodiimide. Breath: Resp support twitch.1 Skin: Prevent skin contact BP: 500°F (Decomposes) Not available. acids.Pp:AScba Change: N.5% LEL: 0. sulfur acid [Note: Forms cumene hydroperoxide upon long exposure to air.92 mg/m3 DOT: 1918 130 Synonyms/Trade Names: Cumol. Eyes: Prevent eye contact Sol(59°F): 78% Wash skin: When contam Fl. Abs. skin burns. resp sys. Carbimide. Isopropyl benzene. CNS Cyanamide 81 . Con Skin: Water flush immed SY: Irrit eyes. Ing.] Exposure Limits: Measurement Methods NIOSH REL: TWA 2 mg/m3 (see Table 1): NIOSH 0500 OSHA PEL†: none Physical Description: Crystalline solid. Ing.86 VP: 8 mmHg FRZ: -141°F UEL: 6.Gr: 0. skin. derm. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 42.] Exposure Routes.Formula: CAS#: RTECS#: IDLH: C6H5CH(CH3)2 98-82-8 GR8575000 900 ppm [10%LEL] Conversion: 1 ppm = 4. 2-Phenyl propane Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (245 mg/m3) [skin] (see Table 1): 3 NIOSH 1501 OSHA PEL: TWA 50 ppm (245 mg/m ) [skin] Physical Description: Colorless liquid with a sharp. miosis. eye. salv. Cyanogen nitride.D. nitric acid. 1.P: 96°F GmFOv/ScbaF/SaF §: ScbaF:Pd. resp sys. muc memb. Antabuse-like effects Swallow: Medical attention immed TO: Eyes. Hydrogen cyanamide [Note: Cyanamide is also a synonym for Calcium cyanamide. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin. aromatic odor.R. skin.2-phenylene diamine salts [Note: Polymerization may occur on evaporation of aqueous solutions. narco. penetrating. Con Skin: Water flush prompt SY: Irrit eyes. Symptoms.2 500 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 306°F 900 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Wash skin: When contam Sol: Insoluble Remove: When wet (flamm) Fl.65 eV Change: Daily Sp. head.75 eV Escape: GmFOv/ScbaE Sp.Pp/SaF:Pd.

Gr: 0. Dicyanogen. May be stabilized to prevent polymerization. almond-like odor. Skin: Water wash immed (liquid) Breath: Resp support head. conf. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. resp sys.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 52. Chlorocyanide. Dicyan. upper resp sys. water. Fl. convuls. strong oxidizers (e.95 (Liquid at -6°F) VP(70°F): 5.] Exposure Routes.6 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless gas or liquid (below 55°F) with an irritating odor. [Note: Shipped as a liquefied compressed gas.R.Gr: 1. acids.] Exposure Routes. tachypnea.0 Skin: Frostbite BP: -6°F Not available. irreg heartbeat. Ethanedinitrile. RGasD: 2. A solid below 20°F. Eyes: Prevent eye contact (liquid) Sol: 7% Wash skin: When contam (liquid) Fl. dichlorine oxide. liquid: frostbite TO: Eyes. Symptoms.5 Skin: Prevent skin contact (liquid) BP: 55°F Not available.C Formula: CAS#: RTECS#: IDLH: NCCN 460-19-5 GT1925000 N. CNS.R. dizz. irrit skin (liquid) Swallow: Medical attention immed (liquid) TO: Eyes.P: NA Remove: When wet or contam (liquid) IP: 12. loss of appetite.6% Flammable Gas Incompatibilities and Reactivities: Acids. skin. Conversion: 1 ppm = 2. lac. nose. alkalis.P: NA (Gas) Remove: When wet (flamm) IP: 13. dizz. resp sys. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Ing (liquid). CVS Cyanogen Formula: CAS#: RTECS#: IDLH: ClCN 506-77-4 GT2275000 N.R. Eyes: Prevent eye contact/Frostbite Sol: 1% Wash skin: N.52 mg/m3 DOT: 1589 125 (inhibited) Synonyms/Trade Names: Chlorcyan. Forms cyanide in the body. CVS Cyanogen chloride 82 . hypernea..22 (Liquid at 32°F) VP: 1010 mmHg Quick drench (liquid) FRZ: 20°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Water. ammonia. delayed pulm edema. vomit.D.82 Provide: Frostbite wash Sp. upper resp sys.1 atm FRZ: -18°F UEL: 32% LEL: 6. Chlorine cyanide. Chlorocyanogen Exposure Limits: Measurement Methods NIOSH REL: C 0. Conversion: 1 ppm = 2. Forms cyanide in the body. Oxalonitrile Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (20 mg/m3) (see Table 1): OSHA PV2104 OSHA PEL†: none Physical Description: Colorless gas with a pungent.49 eV Change: N. alcohols [Note: Can react very slowly with water to form hydrogen cyanide. cough. Symptoms.57 eV Change: N. or ammonia. Con Eye: Frostbite SY: Irrit eyes. Con (liquid) Eye: Irr immed SY: Irrit eyes.D. fluorine) [Note: Slowly hydrolyzed in water to form hydrogen cyanide. head. nau. cherry red lips. low-wgt. Abs (liquid).] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 61. oxalic acid. [Note: Shipped as a liquefied gas. Skin: Frostbite Breath: Resp support bradycardia.g.16 Provide: Eyewash (liquid) Sp. RGasD: 1.13 mg/m3 DOT: 1026 119 Synonyms/Trade Names: Carbon nitride.3 ppm (0. lass. CNS.

88 eV Sp. Ing. Symptoms. skin. head. CNS Swallow: Medical attention immed Cyclohexane C CAS#: RTECS#: IDLH: Formula: 1569-69-3 GV7525000 N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. Hexamethylene.Pp:AScba Remove: When wet (flamm) Fl. cough.5 ppm (2. dysp Swallow: Medical attention immed TO: Eyes. drow. CNS Cyclohexanethiol 83 .Formula: CAS#: RTECS#: IDLH: C6H12 110-82-7 GU6300000 1300 ppm [10%LEL] Conversion: 1 ppm = 3. narco.2 1300 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 177°F Wash skin: When contam Sol: Insoluble GmFOv/ScbaF/SaF §: ScbaF:Pd.P: 0°F Escape: GmFOv/ScbaE Change: N. offensive odor.P: 110°F Change: N.D.Gr: 0. skin.Gr: 0. Cyclohexylthiol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. lass. laryngitis. strong acids. IP: 9.4 mg/m3) [15-minute] OSHA PEL: none None available Physical Description: Colorless liquid with a strong. resp sys. chloroform-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 116. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Hexanaphthene Exposure Limits: Measurement Methods NIOSH REL: TWA 300 ppm (1050 mg/m3) (see Table 1): 3 NIOSH 1500 OSHA PEL: TWA 300 ppm (1050 mg/m ) OSHA 7 Physical Description: Colorless liquid with a sweet.98 Escape: GmFOv/ScbaE VP: 10 mmHg Quick drench FRZ: -181°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Oxidizers. wheez. skin. nau.Pp:AScba Provide: Eyewash Sp.Pp/SaF:Pd. C6H11SH Conversion: 1 ppm = 4.Pp/SaF:Pd. Con Eye: Irr immed SY: Irrit eyes. IP: ? ScbaF/SaF §: ScbaF:Pd.R. skin. Skin: Soap flush immed Breath: Resp support convuls.2 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 316°F 12.44 mg/m3 DOT: 1145 128 Synonyms/Trade Names: Benzene hexahydride. Con Skin: Water flush prompt SY: Irrit eyes. alkali metals Exposure Routes. resp sys. [Note: A solid below 44°F. vomit. dizz.3% Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 84. coma Breath: Resp support TO: Eyes. Abs.78 VP: 78 mmHg FRZ: 44°F UEL: 8% LEL: 1. Hexahydrobenzene. reducing agents.75 mg/m3 DOT: 3054 129 Synonyms/Trade Names: Cyclohexylmercaptan. Symptoms. resp sys. derm. resp sys.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl. Ing.

kidney damage Swallow: Medical attention immed TO: Eyes. 2555 OSHA PEL†: TWA 50 ppm (200 mg/m ) OSHA 1 Physical Description: Water-white to pale-yellow liquid with a peppermint. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. in Breath: Resp support animals: liver. Cyclohexyl alcohol.2 625 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 312°F 700 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: 15% Remove: When wet or contam Fl. n.Pp/SaF:Pd. Con Skin: Water wash prompt SY: Irrit eyes. Abs.P: 146°F ScbaF/SaF §: ScbaF:Pd.2 400 ppm: CcrOv*/PaprOv*/GmFOv/ Eyes: Prevent eye contact BP: 322°F Wash skin: When contam Sol: 4% Sa*/ScbaF §: ScbaF:Pd. resp sys Swallow: Medical attention immed Cyclohexanol CAS#: RTECS#: IDLH: Formula: 108-94-1 GW1050000 700 ppm C6H10O Conversion: 1 ppm = 4. nitric acid Exposure Routes.Pp:AScba Remove: When wet or contam Fl.s. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 98. liver. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. resp sys.R. Cyclohexyl ketone. throat. Ing. Hexahydrophenol. CNS.P: 154°F Escape: GmFOv/ScbaE Change: Daily IP: 10. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 100.14 eV Escape: GmFOv/ScbaE Sp. narco.C CAS#: RTECS#: IDLH: Formula: 108-93-0 GV7875000 400 ppm C6H11OH Conversion: 1 ppm = 4. Hexalin.00 eV Sp. IP: 9.95 VP: 5 mmHg FRZ: -49°F UEL: 9.1% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers. Hydroxycyclohexane Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (200 mg/m3) [skin] (see Table 1): 3 NIOSH 1402. skin. skin. Hydralin. narco Breath: Resp support TO: Eyes.4% LEL(212°F): 1.o.10 mg/m3 DOT: 1993 128 (combustible liquid. kidneys Cyclohexanone 84 . Abs. Con Skin: Water flush prompt SY: Irrit eyes. muc memb.Pp:AScba Change: N. Pimelic ketone Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 25 ppm (100 mg/m3) [skin] 3 NIOSH 1300.Gr: 0. derm. Symptoms. coma. 1405 OSHA PEL†: TWA 50 ppm (200 mg/m ) Physical Description: Sticky solid or colorless to light-yellow liquid (above 77°F) with OSHA 7 a camphor-like odor. skin. nose.) Synonyms/Trade Names: Anol.Pp/SaF:Pd.02 mg/m3 DOT: 1915 127 Synonyms/Trade Names: Anone.96 VP: 1 mmHg MLT: 77°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers (such as hydrogen peroxide & nitric acid) Exposure Routes. head. Symptoms. Ing. skin.Gr: 0.or acetone-like odor.

Pp/SaF:Pd.81 VP: 67 mmHg FRZ: -154°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Forms explosive peroxides with oxygen upon storage. Ing. resp sys.37 eV Change: N.5% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers. Symptoms. Escape: GmFOv/ScbaE IP: 8.4% LEL: 1. eye. resp sys. Con Skin: Soap wash prompt SY: Irrit eyes. skin burns. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. acid chlorides.P: 11°F Change: N. skin. OSHA PV2016 Cyclohexylamine Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 99. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. drow. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. CNS Swallow: Medical attention immed Cyclohexene C Formula: CAS#: RTECS#: IDLH: C6H11NH2 108-91-8 GX0700000 N. acid anhydrides. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 82.Formula: CAS#: RTECS#: IDLH: C6H10 110-83-8 GW2500000 2000 ppm Conversion: 1 ppm = 3.R. fishy. resp sys. Sp.87 Provide: Eyewash VP: 11 mmHg FRZ: 0°F Quick drench UEL: 9. cough. skin Breath: Resp support sens.D. lead [Note: Corrosive to copper.2 Skin: Prevent skin contact BP: 274°F Not available. Con Skin: Water flush immed SY: Irrit eyes. Aminohexahydrobenzene. dizz. Hexahydrobenzenamine Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (40 mg/m3) (see Table 1): NIOSH 2010 OSHA PEL†: none Physical Description: Colorless or yellow liquid with a strong. drow Breath: Resp support TO: Eyes. skin.95 eV Sp.R. Conversion: 1 ppm = 4. nau.] Exposure Routes. CNS 85 . Symptoms. pulm edema. organic compounds.Gr: 0. Ing.36 mg/m3 DOT: 2256 130 Synonyms/Trade Names: Benzene tetrahydride. amine-like odor.] Exposure Routes.Gr: 0.Pp:AScba Fl. Hexahydroaniline. acids. Abs.P: 88°F Remove: When wet (flamm) IP: 8. Tetrahydrobenzene Exposure Limits: Measurement Methods NIOSH REL: TWA 300 ppm (1015 mg/m3) (see Table 1): 3 NIOSH 1500 OSHA PEL: TWA 300 ppm (1015 mg/m ) OSHA 7 Physical Description: Colorless liquid with a sweet odor.06 mg/m3 DOT: 2357 132 Synonyms/Trade Names: Aminocyclohexane. muc memb. vomit Swallow: Medical attention immed TO: Eyes. aluminum. skin. skin.2 2000 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 181°F Wash skin: When contam Sol: Insoluble GmFOv/ScbaF/SaF Remove: When wet (flamm) §: ScbaF:Pd. resp sys. zinc & galvanized steel. diarr.

irrity.Gr: 1. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 66.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 222. nose Breath: Resp support TO: Eyes. RDX. vomit. Hexahydro-1. sulfuric acid [Note: Polymerizes to dicyclopentadiene upon standing. convuls Swallow: Medical attention immed TO: Eyes. Con Eye: Irr immed SY: Irrit eyes.3-Cyclopentadiene Exposure Limits: Measurement Methods NIOSH REL: TWA 75 ppm (200 mg/m3) (see Table 1): 3 NIOSH 2523 OSHA PEL: TWA 75 ppm (200 mg/m ) Physical Description: Colorless liquid with an irritating.Pp:AScba Remove: When wet (flamm) IP: 8. head.3. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam/Daily Fl. Ing. skin.80 VP: 400 mmHg FRZ: -121°F UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. dizz. Ing. Abs.0004 mmHg MLT: 401°F Quick drench UEL: ? LEL: ? Combustible Solid [EXPLOSIVE!] Incompatibilities and Reactivities: Strong oxidizers. 1. terpene-like odor. skin.82 Provide: Eyewash VP(230°F): 0.5 mg/m3 (see Table 1): 3 NIOSH 0500 ST 3 mg/m [skin] OSHA PEL†: none Physical Description: White.P(oc): 77°F Sa/ScbaF §: ScbaF:Pd.2 Skin: Prevent skin contact BP: ? Not available. Skin: Soap flush immed Breath: Resp support insom.D. fuming nitric acid.56 eV Escape: GmFOv/ScbaE Change: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Trimethylenetrinitramine.5-trinitro-s-triazine.P: Explodes Remove: When wet or contam IP: ? Change: Daily Sp. Con Skin: Soap wash prompt SY: Irrit eyes.Gr: 0. crystalline powder. tremor.3. Conversion: DOT: Synonyms/Trade Names: Cyclotrimethylenetrinitramine. Symptoms. resp sys Swallow: Medical attention immed Cyclopentadiene 86 .5-Trinitro-1. heat [Note: Detonates on contact with mercury fulminate.] Exposure Routes.70 mg/m3 DOT: Synonyms/Trade Names: 1. [Note: A powerful high explosive.5-triazacyclohexane Exposure Limits: Measurement Methods NIOSH REL: TWA 1.] Exposure Routes.3. Sp. lass.1 NIOSH/OSHA Skin: Prevent skin contact BP: 107°F 750 ppm: CcrOv/GmFOv/PaprOv/ Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl. combustible materials. nau.C Formula: CAS#: RTECS#: IDLH: C3H6N6O6 121-82-4 XY9450000 N.Pp/SaF:Pd. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. CNS Cyclonite Formula: CAS#: RTECS#: IDLH: C5H6 542-92-7 GY1000000 750 ppm Conversion: 1 ppm = 2.

skin. Breath: Resp support stupor. cracking skin Swallow: Medical attention immed TO: Eyes. in animals: liver.P: NA 16 mg/m3: CcrFOv100/GmFOv100/ Change: Daily IP: NA PaprTOvHie/SaT:Cf/ScbaF/SaF Sp. skin. C CAS#: RTECS#: IDLH: 80 mg/m3 Formula: 13121-70-5 WH8750000 [25 mg/m3 (as Sn)] (C6H11)3SnOH Conversion: DOT: Synonyms/Trade Names: TCHH. kidneys Cyhexatin 87 . Con Skin: Soap wash SY: Irrit eyes. Ing. nearly odorless.g. resp sys. CNS Formula: C5H10 DOT: 1146 128 CAS#: 287-92-3 RTECS#: GY2390000 IDLH: N.Gr: ? 80 mg/m3: SaF:Pd.32 mg/m [0. Target Organs (see Table 5): Eye: Irr immed ER: Inh.1% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers (e. throat. kidney damage Swallow: Medical attention immed TO: Eyes. Tricyclohexylstannium hydroxide. abdom Skin: Soap wash immed Breath: Resp support pain. liver. Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl.7% LEL: 1. head. dizz. cough. Tricyclohexylhydroxystannane. crystalline powder.75 VP(88°F): 400 mmHg FRZ: -137°F UEL: 8.87 mg/m3 Synonyms/Trade Names: Pentamethylene Exposure Limits: Measurement Methods NIOSH REL: TWA 600 ppm (1720 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with a mild. vomit. Tricyclohexyltin hydroxide Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 3 OSHA PEL†: TWA 0. Con SY: Irrit eyes. vomit. resp sys. Abs. ultraviolet light First Aid (see Table 6): Exposure Routes.1 mg/m (as Sn)] NIOSH 5504 Physical Description: Colorless to white. Ing.52 eV Change: N. dry. skin burns.D. euph. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Symptoms.Pp VP: 0 mmHg (approx) §: ScbaF:Pd.Pp/SaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 70.R. skin..2 mg/m3: CcrOv95/Sa BP: 442°F (Decomposes) Eyes: N.P: -35°F Remove: When wet (flamm) IP: 10. nau. sweet odor.2 Skin: Prevent skin contact BP: 121°F Not available. dizz. sore throat.Cyclopentane Conversion: 1 ppm = 2. nose. fluorine) Exposure Routes.Pp:AScba MLT: 383°F Escape: GmFOv100/ScbaE UEL: NA LEL: NA Incompatibilities and Reactivities: Strong oxidizers. bromine. inco.R. skin.Gr: 0. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact MW: 385. Wash skin: When contam 8 mg/m3: Sa:Cf/PaprOvHie Sol: Insoluble Remove: When wet or contam Fl. resp sys. Symptoms.2 3. chlorine. Tricyclohexylhydroxytin. pruritus. Sp.

pares tongue. 1. [carc] TO: Eyes. Con Eye: Irr immed SY: Lass.5 NIOSH Skin: Prevent skin contact BP: 230°F (Decomposes) ¥: ScbaF:Pd. PNS [in animals: liver.D CAS#: RTECS#: IDLH: Formula: 94-75-7 AG6825000 100 mg/m3 Cl2C6H3OCH2COOH Conversion: DOT: 2765 152 Synonyms/Trade Names: Dichlorophenoxyacetic acid. odorless powder. CNS. vomit.0000002 mmHg MLT: 227°F Quick drench UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. lung Swallow: Medical attention immed & lymphatic tumors] DDT 88 . skin.Pp:AScba Change: Daily Sp. stupor.4-D Formula: CAS#: RTECS#: IDLH: (C6H4Cl)2CHCCl3 50-29-3 KJ3325000 Ca [500 mg/m3] Conversion: DOT: 2761 151 Synonyms/Trade Names: p.P: 162-171°F Remove: When wet or contam IP: ? Change: Daily Sp. dizz.2-bis(p-chlorophenyl)ethane Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH S274 (II-3) TWA 0. mal. hyporeflexia. [herbicide] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 221. [pesticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 354. convuls. aromatic odor.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Fl. in Skin: Soap wash prompt Breath: Resp support animals: liver. but may be dissolved in flammable liquids.Gr: 1. alkalis Exposure Routes. face.0 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 100 mg/m3: CcrOv95/GmFOv100/ Eyes: Prevent eye contact Sol: 0.P: NA PaprOvHie/Sa/ScbaF Remove: When wet or contam IP: ? §: ScbaF:Pd. kidney inj Swallow: Medical attention immed TO: Skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.p'-DDT. skin.05% Wash skin: When contam Fl.1-Trichloro-2.1. derm. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.99 Provide: Eyewash VP: 0. lips.Gr: 0.Pp/SaF:Pd. Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. kidneys 2.Pp/SaF:Pd. head. Con Skin: Soap wash prompt SY: Irrit eyes. paresis hands. Abs. convuls. anxi. kidneys. liver.4 mmHg MLT: 280°F UEL: NA LEL: NA Noncombustible Solid. Dichlorodiphenyltrichloroethane. Ing.5 mg/m See Appendix A 3 OSHA PEL: TWA 1 mg/m [skin] Physical Description: Colorless crystals or off-white powder with a slight. Abs. Breath: Resp support conf. CNS. liver. Ing. 2. tremor. crystalline. Symptoms. musc twitch.57 Escape: GmFOv100/ScbaE VP(320°F): 0. lass.4-Dichlorophenoxyacetic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (see Table 1): 3 NIOSH 5001 OSHA PEL: TWA 10 mg/m Physical Description: White to yellow.

5 mg/m3: Sa:Cf Remove: When wet or contam IP: 9. kidneys Decaborane D Formula: CAS#: RTECS#: IDLH: CH3(CH2)9SH 143-10-2 N.P: 176°F 7. nau.Pp/SaF:Pd. conf. lass. lass. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Conversion: 1 ppm = 7. water. Con SY: Irrit eyes. local musc spasm. liver.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 174.Pp:AScba Provide: Eyewash VP: 0.R. vomit. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.3 mg/m3 (0. dizz. n-Decylmercaptan. Con Eye: Irr immed SY: Dizz.05 ppm) [skin] (see Table 1): 3 None available ST 0.9 mg/m (0. CNS 1-Decanethiol 89 .6 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Colorless liquid with a strong odor. strong acids & bases. Abs. head.2 mmHg Escape: GmFOv100/ScbaE MLT: 211°F Quick drench UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Oxidizers. nitric acid Exposure Routes.Gr: 0. head. inco.D.5 ppm (3. chocolate-like odor. Ing. IP: ? ScbaF/SaF §: ScbaF:Pd. resp sys. Symptoms.Gr: 0.3 mg/m (0. resp sys. Symptoms.84 Escape: GmFOv/ScbaE VP: ? FRZ: -15°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers. nau.Pp/SaF:Pd. Skin: Soap wash immed Breath: Resp support convuls. drow. Decomposes slowly in hot water. convuls Swallow: Medical attention immed TO: Eyes. in animals: dysp.88 eV 15 mg/m3: SaT:Cf/ScbaF/SaF Change: Daily Sp.Formula: CAS#: RTECS#: IDLH: B10H14 17702-41-9 HD1400000 15 mg/m3 Conversion: 1 ppm = 5. Ing.15 ppm) 3 OSHA PEL†: TWA 0. liver.05 ppm) [skin] Physical Description: Colorless to white crystalline solid with an intense. bitter.Pp:AScba Sp.P: 209°F Change: N.] Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 122.4 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 465°F 12.13 mg/m3 DOT: 1228 131 Synonyms/Trade Names: Decylmercaptan.94 §: ScbaF:Pd.00 mg/m3 DOT: 1868 134 Synonyms/Trade Names: Decaboron tetradecahydride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. halogenated compounds (especially carbon tetrachloride) [Note: May ignite SPONTANEOUSLY on exposure to air. Abs.2 NIOSH/OSHA Skin: Prevent skin contact BP: 415°F 3 mg/m3: Sa Eyes: Prevent eye contact Sol: Slight Wash skin: When contam/Daily Fl. tremor. skin. Skin: Soap wash Breath: Resp support lass. drow. 1-Mercaptodecane Exposure Limits: Measurement Methods NIOSH REL: C 0. skin. kidney damage Swallow: Medical attention immed TO: CNS. alkali metals.

R. Symptoms.Pp:AScba IP: ? Escape: GmFOv/ScbaE Sp. convuls. diarr. in animals: narco.9% LEL: 1. chest tight. blood chol Demeton CAS#: RTECS#: IDLH: Formula: SA9100000 1800 ppm [10%LEL] CH3COCH2C(CH3)2OH 123-42-2 Conversion: 1 ppm = 4. Target Organs (see Table 5): Eye: Irr immed ER: Inh. corn damage. Skin: Water flush prompt Breath: Resp support liver damage Swallow: Medical attention immed TO: Eyes. 1405 OSHA PEL: TWA 50 ppm (240 mg/m ) OSHA 7 Physical Description: Colorless liquid with a faint. vomit. water First Aid (see Table 6): Exposure Routes. 4-Hydroxy-4-methyl-2-pentanone. 2-Methyl-2-pentanol-4-one Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 50 ppm (240 mg/m3) 3 NIOSH 1402.Pp Provide: Eyewash Sp. ataxia. head. lass.Pp/SaF:Pd. wheez.8% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.94 VP: 1 mmHg FRZ: -47°F UEL: 6. Symptoms. alkalis. Systox® Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Con Skin: Soap wash immed SY: Irrit eyes.Gr: 1. skin. para. card irreg Swallow: Medical attention immed TO: Eyes. oily liquid with a sulfur-like odor. dizz.75 mg/m3 DOT: 1148 129 Synonyms/Trade Names: Diacetone. strong alkalis Exposure Routes. CVS.Pp:AScba VP: 0.P: 113°F 5 mg/m3: SaT:Cf/ScbaF/SaF Change: Daily IP: ? 10 mg/m3: Sa:Pd. resp sys. anor. §: ScbaF:Pd.Gr: 0. abdom cramps.D Formula: CAS#: RTECS#: IDLH: (C2H5O)2PSOC2H4SC2H5 8065-48-3 TF3150000 10 mg/m3 Conversion: DOT: Synonyms/Trade Names: O-O-Diethyl-O(and S)-2-(ethylthio)ethyl phosphorothioate mixture.12 §: ScbaF:Pd. nau. Ing. Ing. nose. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 258. conf. local sweat.3 1 mg/m3: Sa Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: 0.1 mg/m [skin] Physical Description: Amber. Con Eye: Irr immed SY: Irrit eyes. CNS. throat.Pp/SaF:Pd. lar Breath: Resp support spasm. musc fasc. skin. skin. Abs. CNS. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.2 1250 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 334°F 1800 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: Miscible Remove: When wet or contam Fl. minty odor. cyan. miosis.P: 125°F ScbaF/SaF Change: N. Diacetone alcohol Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 116. salv. resp sys. liver 90 . ache eyes. rhin.0003 mmHg Escape: GmFOv100/ScbaE Quick drench FRZ: <-13°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. low BP.01% 2.5 mg/m3: Sa:Cf Remove: When wet or contam Fl.1 mg/m3 [skin] (see Table 1): 3 NIOSH 5514 OSHA PEL: TWA 0. skin. coma.

Ing.) Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): Minimize occupational exposure (especially skin exposures) None available See Appendix A OSHA PEL: none Physical Description: Colorless solid (needles). [Note: Used as a basis for many dyes.Gr: ? Change: Daily VP: ? Provide: Eyewash MLT: 153°F Quick drench UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.P: 403°F Wash skin: When contam/Daily IP: ? Remove: When wet or contam Sp.3 (see Table 2): NIOSH BP: ? Skin: Prevent skin contact ¥: ScbaF:Pd.D. liver [in animals: bladder.Pp/SaF:Pd. 3.Pp:AScba Sol: Insoluble Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl.] Conversion: DOT: Synonyms/Trade Names: Dianisidine. liver. repro sys [in animals: thyroid. liver changes. Con SY: Irrit skin. thyroid. Symptoms. terato effects.Pp:AScba Sol: ? Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl. liver. [carc] Skin: Soap wash immed TO: Skin. 4-Methoxy-1. 4-Methoxy-m-phenylene-diamine (Synonyms of salts vary depending upon the specific compound.Formula: CAS#: RTECS#: IDLH: (NH2)2C6H3OCH3 615-05-4 BZ8580500 Ca [N.Gr: ? Change: Daily VP: ? Provide: Eyewash MLT: 279°F Quick drench UEL: ? LEL: ? Incompatibilities and Reactivities: Oxidizers Combustible Solid First Aid (see Table 6): Exposure Routes. liver.4-diaminoanisole sulfate) is a component of hair & fur dye formulations. Symptoms. skin & Breath: Resp support Swallow: Medical attention immed lymphatic sys tumors] 2.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 244. Abs.] Conversion: DOT: Synonyms/Trade Names: 1. thyroid.4-Diaminoanisole (and its salts) D Formula: CAS#: RTECS#: IDLH: (NH2C6H3OCH3)2 119-90-4 DD0875000 Ca [N. Abs.3-Diamino-4-methoxybenzene. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Ing. [Note: The primary use (including its salts such as 2.D. Target Organs (see Table 5): Eye: Irr immed ER: Inh.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 138. in animals: kidney.P: ? Wash skin: When contam/Daily IP: ? Remove: When wet or contam Sp.3'-Dimethoxybenzidine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 5013 See Appendix A OSHA 71 See Appendix C OSHA PEL: See Appendix C Physical Description: Colorless crystals that turn a violet color on standing. liver. [carc] Skin: Soap wash immed Breath: Resp support TO: Skin. Con Eye: Irr immed SY: In animals: irrit skin. thyroid. liver damage. kidneys.Pp/SaF:Pd.3-benzene-diamine.2 (see Table 2): NIOSH BP: ? Skin: Prevent skin contact ¥: ScbaF:Pd. stomach & Swallow: Medical attention immed mammary gland tumors] o-Dianisidine 91 . thyroid.3'-Dianisidine. spleen changes. 3.

IP: 9. Sol: Reacts Escape: GmFOv/ScbaE Remove: When wet (flamm) Fl. drying agents such as calcium arsenate [Note: May explode violently on heating. liquid: frostbite TO: Eyes. fever. resp sys. blurred vision. salv. Eyes: Prevent eye contact Sol: 0. O.O-Diethyl-O-2-isopropyl-4-methyl-6-pyrimidinyl-phosphorothioate.1 mg/m3 [skin] NIOSH 5600 OSHA PEL†: none OSHA 62 Physical Description: Colorless liquid with a faint ester-like odor.P: 180°F Remove: When wet or contam IP: ? Change: Daily Sp. cough.D CAS#: RTECS#: IDLH: Formula: 333-41-5 TF3325000 N. dizz. Skin: Soap wash immed Breath: Resp support dysp.45 VP: >1 atm FRZ: -229°F UEL: ? LEL: ? Flammable Gas [EXPLOSIVE!] Incompatibilities and Reactivities: Alkali metals. Diazide®.4 Skin: Prevent skin contact BP: Decomposes Not available. pneu. exposure to sunlight. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp:AScba Wash skin: N. short breath. CVS. lass.2 ppm (0.Pp/SaF:Pd. blood chol Diazinon® Formula: CAS#: RTECS#: IDLH: CH2N2 334-88-3 PA7000000 2 ppm Conversion: 1 ppm = 1. resp sys Diazomethane 92 . [Note: Shipped as a liquefied compressed gas. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. C12H21N2O3PS Conversion: DOT: 2783 152 Synonyms/Trade Names: Basudin®. Skin: Frostbite Breath: Resp support chest pain. head.P: NA (Gas) Change: N.0001 mmHg FRZ: ? Quick drench UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong acids & alkalis. miosis. Ing. asthma. nau. CNS.] Exposure Routes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Frostbite MW: 42. conf.Gr: 1. lass.12 Provide: Eyewash VP: 0. copper-containing compounds [Note: Hydrolyzes slowly in water & dilute acid. abdom cramps. Abs.004% Wash skin: When contam Fl.1 2 ppm: Sa*/ScbaF Eyes: Frostbite BP: -9°F §: ScbaF:Pd.R.4 mg/m ) Physical Description: Yellow gas with a musty odor. Con Eye: Irr immed SY: Irrit eyes.] Exposure Routes. Spectracide® Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.R.00 eV Provide: Frostbite wash RGasD: 1. [insecticide] [Note: Technical grade is pale to dark brown.72 mg/m3 DOT: Synonyms/Trade Names: Azimethylene. convuls. Azomethylene.2 ppm (0.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 304. Symptoms. water. flush skin. or contact with rough edges such as ground glass.D. Con (liquid) Eye: Frostbite SY: Irrit eyes.4 mg/m3) (see Table 1): 3 NIOSH 2515 OSHA PEL: TWA 0. Diazirine Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Symptoms. vomit Swallow: Medical attention immed TO: Eyes. pulm edema.

[pesticide] [Note: A solid below 43°F. skin.5 ppm: Sa:Cf Wash skin: N.13 mg/m3 DOT: 1911 119 Synonyms/Trade Names: Boroethane.Pp/SaF:Pd.97 §: ScbaF:Pd. Ing. [Note: Usually shipped in pressurized cylinders diluted with hydrogen.1 ppm (0. pulm edema.1 mg/m ) Physical Description: Colorless gas with a repulsive. vomit. nau.R. chills. Fl. IP: 11. lithium. nitrogen. pulm edema.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 27. skin. aluminum.] Conversion: 1 ppm = 9. drow.8% Flammable Gas Incompatibilities and Reactivities: Water. head.7 NIOSH/OSHA Skin: N. lungs.R. dizz.] Exposure Routes. liver. sweet odor. Symptoms.D. nonproductive cough. throat. kidney damage. repro sys.001 ppm Physical Description: Dense yellow or amber liquid with a pungent odor at high concentrations. CNS. Con Eye: Irr immed SY: Irrit eyes. kidneys.Formula: CAS#: RTECS#: IDLH: B2H6 19287-45-7 HQ9275000 15 ppm Conversion: 1 ppm = 1. Diboron hexahydride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.R. liver.P(oc): 170°F Wash skin: When contam/Daily IP: ? Remove: When wet or contam See Appendix E (page 351) Sp.38 eV 15 ppm: Sa:Pd. [carc] Swallow: Medical attention immed TO: Eyes.1044] TWA 0. Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh SY: Chest tight.P: NA (Gas) 5 ppm: SaT:Cf/ScbaF/SaF Remove: N.4 (see Table 2): NIOSH BP: 384°F Skin: Prevent skin contact ¥: ScbaF:Pd. CNS.Pp:AScba Sol: 0. tremor.1 ppm (0.Pp Change: N.8 mmHg Provide: Eyewash FRZ: 43°F Quick drench UEL: ? LEL: ? Incompatibilities and Reactivities: Chemically-active metals such as Class IIIA Combustible Liquid aluminum. precordial pain. resp sys. short breath.Pp/SaF:Pd.R. sterility. Reacts with water to form hydrogen & boric acid. oxidized surfaces. BP: -135°F 1 ppm: Sa Eyes: N. DBCP.2-Dibromo-3-chloropropane 93 . fever.1% Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 236.] Exposure Routes.Pp:AScba VP(62°F): 39. in animals: liver. magnesium & tin alloys [Note: Corrosive to metals. nose. acids [Note: Will ignite spontaneously in moist air at room temperature. stomach.1 mg/m3) 3 NIOSH 6006 OSHA PEL: TWA 0. Skin: Soap wash immed Breath: Resp support kidney inj. spleen. RGasD: 0. or helium.Gr: 2. hemorr TO: Resp sys. pharynx. adrenal & mammary glands] 1. nau.R. argon. liver. lass.05 Change: Daily VP: 0.3-dibromopropane. Abs. Boron hydride. Symptoms.5 atm Escape: GmFS/ScbaE FRZ: -265°F UEL: 88% LEL: 0. musc fasc. digestive sys [in animals: cancer of the nasal cavity. Dibromochloropropane Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): See Appendix A None available OSHA PEL: [1910. Sol: Reacts 2. halogenated compounds. tongue.67 mg/m3 DOT: 2872 159 Synonyms/Trade Names: 1-Chloro-2. kidneys Diborane D Formula: CAS#: RTECS#: IDLH: CH2BrCHBrCH2Cl 96-12-8 TX8750000 Ca [N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.

05 VP: 0.D CAS#: RTECS#: IDLH: Formula: 102-81-8 KK3850000 N.4% Wash skin: When contam Fl. 2-Dibutylaminoethanol.01 mmHg MLT: 158°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes. low-wgt Breath: Resp support TO: Eyes.6-di-tert-butyl phenol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 NIOSH P&CAM226 (II-1) OSHA PEL†: none OSHA PV2108 Physical Description: White to pale-yellow. Abs.N-Dibutylethanolamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 ppm (14 mg/m3) [skin] NIOSH 2007 OSHA PEL†: none Physical Description: Colorless liquid with a faint. Dibutylated hydroxytoluene.P: 195°F Remove: When wet or contam IP: ? Change: N.D. Eyes: Prevent eye contact Sol: 0.00004% Wash skin: When contam Fl.09 mg/m3 DOT: 2873 153 Synonyms/Trade Names: Dibutylaminoethanol. Symptoms. resp sys Swallow: Medical attention immed 2-N-Dibutylaminoethanol Formula: CAS#: RTECS#: IDLH: [C(CH3)3]2CH3C6H2OH 128-37-0 GO7875000 N.86 Provide: Eyewash VP: 0. Ing. nose. corn nec. Eyes: Prevent eye contact Sol: 0. skin.Gr: 1. skin. Sp. Symptoms.4 Skin: Prevent skin contact BP: 509°F Not available.6-Di-tert-butyl-p-cresol 94 . Ing. 4-Methyl-2. in animals: decr growth rate. 2-Di-N-butylaminoethanol. Conversion: DOT: Synonyms/Trade Names: BHT.R. skin Swallow: Medical attention immed 2. derm.3 Skin: Prevent skin contact BP: 446°F Not available.P: 261°F Remove: When wet or contam IP: ? Change: Daily Sp. [food preservative] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 220. Con Skin: Soap flush immed SY: In animals: irrit eyes. Butylated hydroxytoluene. skin. Con SY: Irrit eyes. incr liver weight Skin: Soap wash Breath: Fresh air TO: Eyes. skin. amine-like odor. (C4H9)2NCH2CH2OH Conversion: 1 ppm = 7. N. 2-Di-N-butylaminoethyl alcohol. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 173.D.1 mmHg FRZ: ? Quick drench UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers First Aid (see Table 6): Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Target Organs (see Table 5): Eye: Irr immed ER: Inh. phenolic odor.Gr: 0. crystalline solid with a slight.

resp sys. Dibutyl-1. odorless liquid. 125 mg/m3: Sa:Cf£/PaprHie£ Sol(77°F): 0. head Breath: Resp support TO: Eyes.R.Pp/SaF:Pd. GI tract Swallow: Medical attention immed 95 .57 mg/m3 DOT: Synonyms/Trade Names: DBP. Fl. strong oxidizers. resp sys Swallow: Medical attention immed Dibutyl phosphate D Formula: CAS#: RTECS#: IDLH: C6H4(COOC4H9)2 84-74-2 TI0875000 4000 mg/m3 Conversion: 1 ppm = 11. Con Skin: Soap wash prompt SY: Irrit eyes.R.05 §: ScbaF:Pd.P: 315°F 250 mg/m3: 100F/ScbaF/SaF Change: N. Ing.60 mg/m3 DOT: Synonyms/Trade Names: Dibutyl acid o-phosphate.Pp:AScba Change: N. Con Skin: Wash regularly SY: Irrit eyes. IP: ? 4000 mg/m3: SaF:Pd.Gr: 1.2 10 ppm: Sa Eyes: Prevent eye contact BP: 212°F (Decomposes) 25 ppm: Sa:Cf Wash skin: When contam Sol: Insoluble 30 ppm: SaT:Cf/ScbaF/SaF Remove: When wet or contam Fl. Di-n-butyl phthalate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 3 NIOSH 5020 OSHA PEL: TWA 5 mg/m Physical Description: Colorless to faint-yellow.06 VP: 1 mmHg (approx) FRZ: ? UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.5% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Nitrates. alkalis & acids. resp sys. skin.00007 mmHg Escape: 100F/ScbaE FRZ: -31°F UEL: ? LEL(456°F): 0. aromatic odor.P: ? §: ScbaF:Pd. IP: ? Escape: GmFOv100/ScbaE Provide: Quick drench Sp. liquid chlorine Exposure Routes.Gr: 1. OSHA 104 Dibutyl phthalate Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N. MW: 278. skin.Pp:AScba VP: 0.Pp Sp. Symptoms. stomach Breath: Resp support TO: Eyes.Pp/SaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 210.CAS#: RTECS#: IDLH: Formula: TB9605000 30 ppm (C4H9O)2(OH)PO 107-66-4 Conversion: 1 ppm = 8.001% Remove: N.3 50 mg/m3: 95F Eyes: Prevent eye contact BP: 644°F Wash skin: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Ing. upper resp sys. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. Symptoms. Dibutyl phosphoric acid Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (5 mg/m3) (see Table 1): 3 NIOSH 5017 ST 2 ppm (10 mg/m ) 3 OSHA PEL†: TWA 1 ppm (5 mg/m ) Physical Description: Pale-amber.R. Di-n-butyl hydrogen phosphate. oily liquid with a slight.R.2-benzene-dicarboxylate.

o-Dichlorobenzol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 50 ppm (300 mg/m3) 3 NIOSH 1003 OSHA PEL: C 50 ppm (300 mg/m ) Physical Description: Colorless to pale-yellow liquid with a pleasant.0 200 ppm: CcrFOv/PaprOv£/ Eyes: Prevent eye contact BP: 357°F Wash skin: When contam Sol: 0.06 eV Sp. acid fumes Exposure Routes. chlorides. brain inj. heat. liver. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. shock Exposure Routes.] Conversion: 1 ppm = 3.Pp/SaF:Pd. intense jaw pain. Symptoms.30 VP: 1 mmHg FRZ: 1°F UEL: 9. DCA is not produced commercially. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.P: 151°F Change: N. Escape: GmFOv/ScbaE IP: 9. cranial Skin: Soap flush immed Breath: Resp support nerve palsy.88 mg/m3 DOT: Synonyms/Trade Names: DCA. skin blisters Breath: Resp support TO: Eyes. skin.Pp:AScba Fl. Sp.R.R.9 NIOSH Skin: Prevent skin contact BP: 90°F (Explodes) ¥: ScbaF:Pd. Ing. Abs.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 94.Gr: 1. aluminum. in animals: kidney. Ing. Con Skin: Soap wash prompt SY: Irrit eyes. ortho-Dichlorobenzene.D.D Formula: CAS#: RTECS#: IDLH: C2Cl2 7572-29-4 AP1080000 Ca [N. acids.Pp:AScba Eyes: Prevent eye contact Sol: ? Escape: GmFOv/ScbaE Wash skin: When contam Fl. sweetish odor.26 Provide: Eyewash VP: ? FRZ: -58 to -87°F Quick drench UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Oxidizers.Gr: 1.4 mg/m ) None available See Appendix A OSHA PEL†: none Physical Description: Volatile oil with a disagreeable.P: ? Remove: When wet (flamm) IP: ? Change: N.01% ScbaF/SaF Remove: When wet or contam §: ScbaF:Pd. aromatic odor.] Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 C 0. Abs.01 mg/m DOT: 1591 152 Synonyms/Trade Names: o-DCB. nau. kidney damage. liver.2-Dichlorobenzene. nose. Dichloroethyne [Note: DCA is a possible decomposition product of trichloroethylene or trichloroethane. [Note: A gas above 90°F. resp sys. Symptoms. [carc] Swallow: Medical attention immed TO: CNS [in animals: kidney tumors] Dichloroacetylene Formula: CAS#: RTECS#: IDLH: C6H4Cl2 95-50-1 CZ4500000 200 ppm Conversion: 1 ppm = 6.2% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. OSHA 7 [herbicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 147. liver. vomit.2% LEL: 2. 1. kidneys Swallow: Medical attention immed o-Dichlorobenzene 3 96 . loss of appetite.1 ppm (0.Pp/SaF:Pd. low-wgt. Con SY: Head.

25 Provide: Eyewash VP: 1. Dichlorocide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1003 See Appendix A 3 OSHA 7 OSHA PEL†: TWA 75 ppm (450 mg/m ) Physical Description: Colorless or white crystalline solid with a mothball-like odor. Ing. liver.Gr: 1.0 NIOSH Skin: Prevent skin contact BP: 345°F ¥: ScbaF:Pd. cirr. swell periorb. [carc] TO: Bladder.1 ¥: ScbaF:Pd. head. anor. 3.Formula: CAS#: RTECS#: IDLH: C6H4Cl2 106-46-7 CZ4550000 Ca [150 ppm] Conversion: 1 ppm = 6.4'-biphenyldiamine.Pp/SaF:Pd. 1. derm. Dichlorobenzidine base.1007] See Appendix B Physical Description: Gray to purple. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 253. low-wgt. Incompatibilities and Reactivities: Strong oxidizers (such as chlorine or permanganate) Exposure Routes. resp sys. o. Breath: Resp support dysuria. crystalline solid. Target Organs (see Table 5): Eye: Irr immed ER: Inh.Pp/SaF:Pd. dizz.P: ? See Appendix E (page 351) Change: Daily IP: ? Provide: Eyewash Sp.4'-diamine. 3. Con Skin: Soap wash immed SY: Skin sens.3'-dichlorobiphenyl. nau. 3. Abs.D. skin [in animals: liver & kidney cancer] p-Dichlorobenzene D 3.3'-Dichlorobiphenyl-4.5% Combustible Solid. GI tract [in animals: liver & bladder cancer] Swallow: Medical attention immed 97 . [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 147. caustic burns.] Conversion: DOT: Synonyms/Trade Names: 4.3'-Dichloro-4.P: 150°F Remove: When wet or contam IP: 8. Ing.Pp:AScba Eyes: Prevent eye contact Sol: 0. Symptoms. profuse rhinitis.4'-diaminobiphenyl Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 5509 See Appendix A OSHA 65 OSHA PEL: [1910. frequent urination.3 mmHg MLT: 128°F Quick drench UEL: ? LEL: 2. Symptoms. Abs. lung.01 mg/m3 DOT: Synonyms/Trade Names: p-DCB. eyes. para-Dichlorobenzene. upper resp infection. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. kidneys. head. but may take some effort to ignite. hema.3'-Dichloro-4. jaun. Con Skin: Soap wash SY: Eye irrit. Breath: Resp support vomit.008% Escape: GmFOv/ScbaE Wash skin: When contam/Daily Fl.4-Dichlorobenzene.o'-Dichlorobenzidine.3'-Dichlorobenzidine (and its salts) NH ClC H C H ClNH 2 6 3 6 3 2 Formula: CAS#: 91-94-1 RTECS#: DD0525000 IDLH: Ca [N.07% Remove: When wet or contam Fl. GI upset.4'-Diamino-3. [carc] Swallow: Medical attention immed TO: Liver. skin.Pp:AScba Eyes: Prevent eye contact BP: 788°F Escape: 100F/ScbaE Wash skin: When contam/Daily Sol(59°F): 0.98 eV Change: Daily Sp.Gr: ? VP: ? Quick drench MLT: 271°F UEL: ? LEL: ? Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. in animals: liver. kidney inj.

zinc & magnesium First Aid (see Table 6): Exposure Routes.95 mg/m3 DOT: 1028 126 Synonyms/Trade Names: Difluorodichloromethane. IP: 11.Pp/SaF:Pd. muc memb. Ing. powdered aluminum. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 197.Gr: 1. Genetron® 12.P: NA Escape: GmFOv/ScbaE Change: N. Refrigerant 12 Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1000 ppm (4950 mg/m3) 3 NIOSH 1018 OSHA PEL: TWA 1000 ppm (4950 mg/m ) Physical Description: Colorless gas with an ether-like odor at extremely high concentrations.Pp:AScba Remove: N. uncon. [Note: Shipped as a liquefied compressed gas. Con Skin: Soap wash prompt SY: Irrit eyes.2 mg/m3 (see Table 1): 3 None available ST 0.7 atm FRZ: -252°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Chemically-active metals such as sodium. Halane Exposure Limits: Measurement Methods NIOSH REL: TWA 0. resp sys Swallow: Medical attention immed Formula: C5H6Cl2N2O2 DOT: CAS#: 118-52-5 RTECS#: MU0700000 IDLH: 5 mg/m3 98 . easily oxidized materials such as ammonia salts & sulfides Exposure Routes. strong acids.5-dimethylhydantoin Conversion: Synonyms/Trade Names: Dactin.2% Wash skin: When contam Fl. card arrest.Pp/SaF:Pd. card arrhy. Con (liquid) Skin: Frostbite SY: Dizz.9 10.03% §: ScbaF:Pd.R. Propellant 12.5 Escape: GmFS100/ScbaE Provide: Eyewash VP: ? MLT: 270°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Water. tremor. resp sys Breath: Resp support TO: Eyes. asphy. Sol(77°F): 0. Freon® 12.0 NIOSH/OSHA Skin: Prevent skin contact BP: ? 2 mg/m3: Sa Eyes: Prevent eye contact Sol: 0.2 mg/m Physical Description: White powder with a chlorine-like odor.2 VP: 5.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.75 eV Provide: Frostbite wash RGasD: 4.Pp:AScba Change: Daily Sp.000 ppm Conversion: 1 ppm = 4.D Formula: CAS#: RTECS#: IDLH: CCl2F2 75-71-8 PA8200000 15. Symptoms. calcium.3-Dichloro-5. Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Frostbite MW: 120.000 ppm: Sa Eyes: Frostbite BP: -22°F 15. Target Organs (see Table 5): Eye: Frostbite ER: Inh.P: 346°F 5 mg/m3: Sa:Cf/ScbaF/SaF Remove: When wet or contam IP: ? §: ScbaF:Pd. Halon® 122. potassium.R. liquid: frostbite Breath: Resp support TO: CVS. PNS Dichlorodifluoromethane 1. Fluorocarbon 12.000 ppm: Sa:Cf/ScbaF/SaF Wash skin: N. DDH. Symptoms.4 mg/m 3 OSHA PEL†: TWA 0.

6% 2500 ppm: Sa:Cf Wash skin: When contam Fl.P: 36-39°F Remove: When wet (flamm) Escape: GmFOv/ScbaE IP: 9. Con SY: Irrit eyes.1-Ethylidene dichloride Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (400 mg/m3) (see Table 1): NIOSH 1003 See Appendix C (Chloroethanes) 3 OSHA 7 OSHA PEL: TWA 100 ppm (400 mg/m ) Physical Description: Colorless.1-Dichloroethane D Formula: CAS#: RTECS#: IDLH: ClCH=CHCl 540-59-0 KV9360000 1000 ppm Conversion: 1 ppm = 3. Ing.05 mg/m3 DOT: 2362 130 Synonyms/Trade Names: Asymmetrical dichloroethane. strong caustics Exposure Routes.4% Wash skin: When contam GmFOv/ScbaF/SaF §: ScbaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 99. Symptoms. CNS depres TO: Eyes.6% hydroxide. Symptoms. kidney. CNS depres.2-Dichloroethylene Exposure Routes. 1. Con Skin: Soap flush prompt SY: Irrit skin.Pp/SaF:Pd.8% Incompatibilities and Reactivities: Strong oxidizers. CNS First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed 99 .Pp/SaF:Pd. Sp. sym-Dichloroethylene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 200 ppm (790 mg/m3) 3 NIOSH 1003 OSHA PEL: TWA 200 ppm (790 mg/m ) OSHA 7 Physical Description: Colorless liquid (usually a mixture of the cis & trans isomers) with a slightly acrid. copper [Note: Usually contains inhibitors to prevent polymerization.Formula: CAS#: RTECS#: IDLH: CHCl2CH3 75-34-3 KI0175000 3000 ppm Conversion: 1 ppm = 4. potassium LEL: 5. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R.Gr(77°F): 1. Ethylidene chloride.4% LEL: 5. chloroform-like odor.27 VP: 180-265 mmHg FRZ: -57 to -115°F UEL: 12. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 97.06 eV §: ScbaF:Pd.Pp:AScba Change: N.P: 2°F 3000 ppm: ScbaF/SaF Remove: When wet (flamm) IP: 11. Target Organs (see Table 5): ER: Inh.R.97 mg/m3 DOT: 1150 130P Synonyms/Trade Names: Acetylene dichloride. oily liquid with a chloroform-like odor. lungs. kidneys. liver.18 Escape: GmFOv/ScbaE VP: 182 mmHg FRZ: -143°F UEL: 11. CNS Swallow: Medical attention immed 1. resp sys. trans-Acetylene dichloride.Pp:AScba Fl. lung damage Breath: Resp support TO: Skin. Sp. strong alkalis.4% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. liver. cis-Acetylene dichloride. resp sys.0 NIOSH/OSHA Skin: Prevent skin contact BP: 135°F 1000 ppm: Sa Eyes: Prevent eye contact Sol: 0. Ing.0 Skin: Prevent skin contact 2000 ppm: Sa:Cf£/PaprOv£/CcrFOv/ BP: 118-140°F Eyes: Prevent eye contact Sol: 0.Gr: 1.65 eV Change: N.] Class IB Flammable Liquid 1.

39 eV Change: N.Pp/SaF:Pd. Freon® 21. Refrigerant 21 Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (40 mg/m3) NIOSH 2516 OSHA PEL†: TWA 1000 ppm (4200 mg/m3) Physical Description: Colorless gas with a slight.22 VP: 0. resp sys. acid. Ing. LEL: NA potassium. §: ScbaF:Pd. 2. zinc & magnesium. Con Eye: Irr immed SY: Irrit nose. Symptoms.P: NA Remove: N.Pp IP: 12.R.R.Pp:AScba RGasD: 3. ether-like odor.2'-Dichloroethyl ether Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 1004 TWA 5 ppm (30 mg/m ) 3 OSHA 7 ST 10 ppm (60 mg/m ) [skin] See Appendix A 3 OSHA PEL†: TWA 15 ppm (90 mg/m ) [skin] Physical Description: Colorless liquid with a chlorinated solvent-like odor.85 mg/m3 DOT: 1916 152 Synonyms/Trade Names: bis(2-Chloroethyl)ether. Fluorodichloromethane.0 ¥: ScbaF:Pd. [carc] Swallow: Medical attention immed TO: Eyes. 500 ppm: ScbaF/SaF Fl.] Exposure Routes. lac.D CAS#: RTECS#: IDLH: Formula: 111-44-4 KN0875000 Ca [100 ppm] (ClCH2CH2)2O Conversion: 1 ppm = 5.Gr: 1. 5000 ppm: Sa:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 143.57 Provide: Frostbite wash Escape: GmFOv/ScbaE VP(70°F): 1. Target Organs (see Table 5): ER: Inh. CVS First Aid (see Table 6): Eye: Frostbite Skin: Frostbite Breath: Resp support 100 .2'-Dichlorodiethyl ether. resp sys. Con (liquid) SY: Asphy. Shipped as a liquefied compressed gas. Abs. nau.7% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Decomposes in presence of moisture to form hydrochloric acid.Pp:AScba Eyes: Prevent eye contact BP: 352°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: 1% Remove: When wet or contam Fl.7% Wash skin: N.6 atm FRZ: -211°F UEL: NA Incompatibilities and Reactivities: Chemically-active metals such as sodium.R. Halon® 112.] Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH MW: 102.7 mmHg Quick drench FRZ: -58°F UEL: ? LEL: 2.P: 131°F Change: N. liver [in animals: liver tumors] Dichloroethyl ether CAS#: RTECS#: IDLH: Formula: 75-43-4 PA8400000 5000 ppm CHCl2F Conversion: 1 ppm = 4. acid fumes Nonflammable Gas Dichloromonofluoromethane 3 Exposure Routes. IP: ? Provide: Eyewash Sp. liquid: frostbite TO: Resp sys. throat. calcium. powdered aluminum. [Note: A liquid below 48°F. card arrhy.21 mg/m DOT: 1029 126 Synonyms/Trade Names: Dichlorofluoromethane. cough. vomit.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms. card arrest. 2. in animals: Skin: Soap wash Breath: Resp support pulm edema. liver damage. Genetron® 21.9 Skin: Frostbite 100 ppm: Sa BP: 48°F Eyes: Frostbite 250 ppm: Sa:Cf Sol(86°F): 0.R.

] Exposure Routes. hemorr Swallow: Medical attention immed TO: Eyes.3% oxidizers [Note: Epichlorohydrin may be added as a stabilizer. Ing. kidneys [in animals: cancer of the bladder.3-Dichloropropene Exposure Routes. VP: 28 mmHg Provide: Eyewash FRZ: -119°F Quick drench UEL: 14.Gr: 1.3-Dichloropropylene. Target Organs (see Table 5): ER: Inh. LEL: 5. lac. in animals. head.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 111. skin burns. 1.Pp:AScba Remove: When wet or contam Fl.89 mg/m3 Synonyms/Trade Names: Dichloronitroethane Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (10 mg/m3) (see Table 1): 3 NIOSH 1601 OSHA PEL†: C 10 ppm (60 mg/m ) OSHA 7 Physical Description: Colorless liquid with an unpleasant odor. skin. Symptoms. [fumigant] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 143. lung & forestomach] First Aid (see Table 6): Eye: Irr immed Skin: Soap flush immed Breath: Resp support Swallow: Medical attention immed 101 . dizz. resp sys.] Conversion: 1 ppm = 4.5% Incompatibilities and Reactivities: Aluminum. pulm Skin: Soap wash immed Breath: Resp support edema.] Class IC Flammable Liquid 1.3% §: ScbaF:Pd. liver.1.P: 77°F Wash skin: When contam IP: ? Remove: When wet (flamm) Sp. skin. resp sys. skin.Gr: 1. liver. [carc] TO: Eyes. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.0 (see Table 2): NIOSH BP: 226°F Skin: Prevent skin contact ¥: ScbaF:Pd. halogens.54 mg/m3 DOT: 2047 129 Synonyms/Trade Names: 3-Chloroallyl chloride. magnesium.Pp/SaF:Pd.Pp/SaF:Pd. [insecticide] [Note: Exists as mixture of cis. 1. chloroform-like odor. heart. liver. Abs. kidneys. CVS Formula: CH3CCl2NO2 DOT: 2650 153 CAS#: 594-72-9 RTECS#: KI0500000 IDLH: 25 ppm D Formula: CAS#: RTECS#: IDLH: ClHC=CHCH2Cl 542-75-6 UC8310000 Ca [N.R. kidney damage.& trans-isomers.D. CNS. liver.1-Dichloro-1-nitroethane Conversion: 1 ppm = 5.9 20 ppm: Sa Eyes: Prevent eye contact BP: 255°F 25 ppm: Sa:Cf/ScbaF/SaF Wash skin: When contam Sol: 0. Con SY: Irrit eyes.43 VP: 15 mmHg FRZ: ? UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Corrosive to iron in presence of moisture.P: 136°F Escape: GmFOv/ScbaE Change: N. Con Eye: Irr immed SY: In animals: irrit eyes. eye. kidney damage. IP: ? Sp.R. sweet. DCP. irritating. Symptoms. Telone® Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 None available TWA 1 ppm (5 mg/m ) [skin] See Appendix A OSHA PEL†: none Physical Description: Colorless to straw-colored liquid with a sharp. liver.21 Change: N. Ing.2% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. resp sys.3-Dichloro-1-propene.Pp:AScba Sol: 0. skin.

CNS depres Swallow: Medical attention immed TO: Eyes.000 ppm: Sa:Cf/ScbaF/SaF Wash skin: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh. Con Eye: Irr immed SY: Irrit eyes.2-Dichlorotetrafluoroethane. Symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 143. is often used.P: NA §: ScbaF:Pd. Symptoms. CNS Formula: CAS#: RTECS#: IDLH: CClF2CClF2 76-14-2 KI1101000 15. Reacts slowly in water to form hydrochloric & pyruvic acids.0 Skin: Prevent skin contact BP: 374°F Not available.40 Provide: Eyewash VP: ? FRZ: 46°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Metals [Note: Very corrosive to aluminum & copper alloys.20 eV Escape: GmFOv/ScbaE Change: N. card arrhy. IP: 12.9 atm FRZ: -137°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Chemically-active metals such as sodium. a white powder. [Note: A liquid below 38°F. resp sys.R. upper resp sys. 2. powdered aluminum. D Synonyms/Trade Names: Dalapon. Fl. lass. calcium. GI tract.85 mg/m3 Formula: CH3CCl2COOH DOT: CAS#: 75-99-0 RTECS#: UF0690000 IDLH: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 170.2. potassium. Genetron® 114.2-Dichloropropanoic acid. slowing of pulse.Pp/SaF:Pd. ether-like odor at high concentrations. Shipped as a liquefied compressed gas.R. Refrigerant 114 Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1000 ppm (7000 mg/m3) 3 NIOSH 1018 OSHA PEL: TWA 1000 ppm (7000 mg/m ) Physical Description: Colorless gas with a faint. The sodium salt. card arrest.01% 15.000 ppm: Sa Eyes: Frostbite Sol: 0.Gr: 1. Ing. diarr.R.P: NA Remove: When wet or contam IP: ? Change: N. α. CVS Dichlorotetrafluoroethane 102 .000 ppm Conversion: 1 ppm = 6. skin.α-Dichloropropionic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (6 mg/m3) (see Table 1): OSHA PV2017 OSHA PEL†: none Physical Description: Colorless liquid with an acrid odor. acids. Sp. [herbicide] [Note: A white to tan powder below 46°F. RGasD: 5. skin burns. vomit.Pp:AScba Remove: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.9 NIOSH/OSHA Skin: Frostbite BP: 38°F 10. Halon® 242. asphy.99 mg/m3 DOT: 1958 126 Synonyms/Trade Names: 1.D. skin.2-Dichloropropionic acid Conversion: 1 ppm = 5.R.] Exposure Routes. Freon® 114.93 Provide: Frostbite wash VP(70°F): 1. Eyes: Prevent eye contact Sol: 50% Wash skin: When contam Fl. loss of Skin: Water wash immed Breath: Resp support appetite. zinc & magnesium. liquid: frostbite Skin: Frostbite Breath: Resp support TO: Resp sys. Con (liquid) SY: Irrit resp sys. acid fumes Exposure Routes.

tremor. musc twitch. mal Swallow: Medical attention immed TO: CNS. 2. salv. head. lar Breath: Resp support spasm.70 mg/m3 DOT: Synonyms/Trade Names: Bidrin®.] Exposure Routes.25 mg/m3 [skin] (see Table 1): NIOSH 5600 OSHA PEL†: none Physical Description: Yellow-brown liquid with a mild. blood chol Dichlorvos D Formula: CAS#: RTECS#: IDLH: C8H16NO5P 141-66-2 TC3850000 N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 221.Gr(59°F): 1. ache eyes. Abs. anxi. Abs. rhinitis. Skin: Water wash immed Breath: Resp support vomit. inco. CNS.2-Dichlorovinyl dimethyl phosphate Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 [skin] (see Table 1): 3 NIOSH P&CAM295 (II-5) OSHA PEL: TWA 1 mg/m [skin] OSHA 62 Physical Description: Colorless to amber liquid with a mild. ester odor. Symptoms. abdom cramps. dizz. sweat. Carbicron®. 2-Dimethyl-cis-2-dimethylcarbamoyl-1-methylvinylphosphate Exposure Limits: Measurement Methods NIOSH REL: TWA 0. nau. wheez. musc fasc.R. dizz.Pp Sp. brass & stainless steel.5% 25 mg/m3: Sa:Cf Remove: When wet or contam Fl. IP: ? 100 mg/m3: Sa:Pd. convuls. nau. blood chol Dicrotophos 103 . vomit.P: >175°F 50 mg/m3: SaT:Cf/ScbaF/SaF Change: N. Symptoms. cyan.0 10 mg/m3: Sa Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: 0. Con Skin: Soap wash immed SY: Irrit eyes. rhin. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Ing. card irreg TO: Eyes.D.P: >200°F Remove: When wet or contam IP: ? Change: Daily Sp. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 237. diarr. Con Eye: Irr immed SY: Head.2 Skin: Prevent skin contact BP: 752°F Not available.] First Aid (see Table 6): Exposure Routes.Formula: CAS#: RTECS#: IDLH: (CH3O)2P(O)OCH=CCl2 62-73-7 TC0350000 100 mg/m3 Conversion: 1 ppm = 9. Swallow: Medical attention immed ataxia. salv. chest tight.01 mmHg Escape: GmFOv100/ScbaE FRZ: ? UEL: ? LEL: ? Class III Combustible Liquid Incompatibilities and Reactivities: Strong acids. resp sys. CVS. para. Target Organs (see Table 5): Eye: Irr immed ER: Inh. skin. anor. miosis.22 Provide: Quick drench VP: 0.Pp:AScba VP: 0. lac.Pp/SaF:Pd. chemical odor.42 §: ScbaF:Pd. [Note: Insecticide that may be absorbed on a dry carrier. low BP.04 mg/m3 DOT: 2783 152 Synonyms/Trade Names: DDVP. strong alkalis [Note: Corrosive to iron & mild steel. diarr. lass. sweat. anor. skin. Ing.Gr(77°F): 1. mild steel.0001 mmHg FRZ: ? UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Metals [Note: Corrosive to cast iron. Conversion: 1 ppm = 9. restless.

Conversion: 1 ppm = 5. inco. Iron dicyclopentadienyl Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): OSHA ID125G TWA 5 mg/m3 (resp) 3 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Orange. Symptoms.D. Eyes: N. [Note: A liquid above 90°F. skin. skin Skin: Soap flush immed Breath: Resp support blisters. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R.3% Incompatibilities and Reactivities: Oxidizers LEL: 0.7. BP: 480°F Not available.02% Eyes: Prevent eye contact Fl. Con SY: Irrit eyes. 3a.4 mmHg Provide: Eyewash FRZ: 90°F Quick drench UEL: 6. in animals: liver.7a-Tetrahydro-4. head.41 mg/m3 DOT: 2048 130 Synonyms/Trade Names: Bicyclopentadiene.Gr: ? VP: ? MLT: 343°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Ammonium perchlorate. Sol: Insoluble Wash skin: N. Must be inhibited and maintained under an inert Combustible Solid atmosphere to prevent polymerization. crystalline solid with a disagreeable. nose.98 (Liquid at 95°F) Change: Daily VP: 1. resp sys.R. cough.R. DCPD. resp sys. resp sys.7-methanoindene [Note: Exists in two stereoisomeric forms. Symptoms.1 Skin: N. Fl. in animals: kidney.P(oc): 90°F Wash skin: When contam IP: ? Remove: When wet or contam Sp. mercury(II) nitrate Exposure Routes.D. Ing. Con Skin: Soap wash SY: Possible irrit eyes.] Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (30 mg/m3) (see Table 1): OSHA PV2098 OSHA PEL†: none Physical Description: Colorless. CNS. kidneys Dicyclopentadiene CAS#: RTECS#: IDLH: Formula: 102-54-5 LK0700000 N. IP: 6. Ing.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 132. crystalline solid with a camphor-like odor.D Formula: CAS#: RTECS#: IDLH: C10H12 77-73-6 PC1050000 N. skin. skin. Sol: 0. sneez.4.] Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 186. camphor-like odor.R. RBC. throat. lung damage Swallow: Medical attention immed TO: Eyes. skin.88 eV Change: Daily Sp.2 (see Table 2): BP: 342°F Skin: Prevent skin contact Not available. repro sys Dicyclopentadienyl iron 104 .P: ? Remove: N.Gr: 0. Breath: Resp support testicular changes Swallow: Medical attention immed TO: Eyes.8% [Note: Depolymerizes at boiling point and forms two molecules of Class IC Flammable Liquid cyclopentadiene.3-Dicyclopentadiene dimer. (C5H5)2Fe Conversion: DOT: Synonyms/Trade Names: bis(Cyclopentadienyl)iron. tetranitromethane. 1. blood. Ferrocene. liver. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.

75 VP(77°F): 8 x 10-7 mmHg Quick drench MLT: 349°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers.4-endo. kidney damage TO: CNS. Symptoms.5.8. Remove: N. exhaust component.10-Hexachloro-6. [carc]. skin [in animals: lung. dizz. thyroid & adrenal Swallow: Medical attention immed gland tumors] Formula: C12H8Cl6O DOT: 2761 151 CAS#: 60-57-1 RTECS#: IO1750000 IDLH: Ca [50 mg/m3] D Diesel exhaust Formula: CAS#: RTECS#: HZ1755000 IDLH: Ca [N.Pp/SaF:Pd.Pp:AScba Eyes: N.Pp:AScba Eyes: Prevent eye contact BP: Decomposes Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: 0.R.] Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific diesel exhaust component. liver.Pp/SaF:Pd.4. nau. mal.7.R.R.2. ¥: ScbaF:Pd. Incompatibilities and Reactivities: Varies Exposure Routes. in animals: liver. clonic. Ing. the specific component diesel Escape: GmFOv100/ScbaE Wash skin: N.25 mg/m [skin] Physical Description: Colorless to light-tan crystals with a mild. phenols First Aid (see Table 6): Exposure Routes.3. vomit. active metals such as sodium. chemical odor.R.P: NA Change: Daily IP: ? Provide: Eyewash Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Properties vary depending upon Skin: N. Con Skin: Soap wash immed SY: Head. myoclonic limb jerks.Dieldrin Conversion: Synonyms/Trade Names: HEOD. coma. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 380. Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 2560.02% Remove: When wet or contam Fl. Target Organs (see Table 5): ER: Inh.10. Abs. strong acids. kidneys.6.9 ¥: ScbaF:Pd. Breath: Resp support tonic convuls. 5040 See Appendix A OSHA PEL: none Physical Description: Appearance and odor vary depending upon the specific diesel exhaust component. [carc] TO: Eyes.8-dimethanonaphthalene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH S283 (II-3) TWA 0.exo-5.25 mg/m [skin] See Appendix A 3 OSHA PEL: TWA 0. Con SY: Eye irrit.4a.D.8a-octahydro-1.R. 1.Gr: 1. Target Organs (see Table 5): Eye: Irr immed ER: Inh.4. pulm func changes. Change: N. liver. resp sys [in animals: lung tumors] First Aid (see Table 6): Breath: Resp support 105 . Symptoms. sweat.7-epoxy-1.

5%) Sp.P: 279°F Remove: When wet or contam IP: ? Change: Daily Sp.1 200 ppm: Sa:Cf£/PaprS£/CcrFS/GmFS/ Eyes: Prevent eye contact BP: 132°F Wash skin: When contam Sol: Miscible ScbaF/SaF §: ScbaF:Pd.99 mg/m DOT: 1154 132 Synonyms/Trade Names: Diethamine.. white liquid (above 82°F) with a OSHA PV2018 mild.Gr: 1. Ing. ammonia-like odor. skin.10 Provide: Eyewash VP: <0. resp sys. CVS Diethylamine 3 106 . cough. skin.N-Diethylamine. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 73. Di(2-hydroxyethyl)amine. Skin: Water flush immed Breath: Resp support lac. and galvanized iron.01 mmHg MLT: 82°F Quick drench UEL: 9.8% LEL: 1.30 mg/m3 DOT: Synonyms/Trade Names: DEA. skin. nose. in animals. 2.2'-Iminodiethanol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 3 ppm (15 mg/m3) NIOSH 3509 OSHA PEL†: none Physical Description: Colorless crystals or a syrupy.01 eV Provide: Eyewash (>0. Corrosive to copper. corn nec. Con Skin: Water flush immed SY: Irrit eyes.2'-Dihydroxydiethyamine. Hygroscopic (i. N-Ethylethanamine Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (30 mg/m3) (see Table 1): NIOSH 2010 ST 25 ppm (75 mg/m3) OSHA 41 OSHA PEL†: TWA 25 ppm (75 mg/m3) Physical Description: Colorless liquid with a fishy.Pp/SaF:Pd. sneez Swallow: Medical attention immed TO: Eyes. eye burns. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 105. (HOCH2CH2)2NH 111-42-2 Conversion: 1 ppm = 4. resp sys Diethanolamine CAS#: RTECS#: IDLH: Formula: 109-89-7 HZ8750000 200 ppm (C2H5)2NH Conversion: 1 ppm = 2. absorbs moisture from the air).D.71 VP: 192 mmHg Quick drench (liquid) FRZ: -58°F UEL: 10.Pp:AScba Remove: When wet (flamm) Fl. Symptoms.R. halides [Note: Reacts with CO2 in the air. bis(2-Hydroxyethyl)amine. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. zinc.e. myocardial Breath: Resp support degeneration Swallow: Medical attention immed TO: Eyes. 2. N.Gr: 0. strong acids. Ing. cellulose nitrate Exposure Routes.] Exposure Routes.6% Class IIIB Combustible Liquid Combustible Solid Incompatibilities and Reactivities: Oxidizers. strong acids. skin. skin burns.1% LEL: 1. Abs. Diolamine.D CAS#: RTECS#: IDLH: Formula: KL2975000 N. IP: 8.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. Con Eye: Irr immed SY: Irrit eyes.P: -15°F Escape: GmFS/ScbaE Change: N. ammonia-like odor. acid anhydrides. throat. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.2 Skin: Prevent skin contact BP: 516°F (Decomposes) Not available. resp sys. Symptoms. Eyes: Prevent eye contact Sol: 95% Wash skin: When contam Fl.

2-Diethylaminoethyl alcohol. Sp.96 Provide: Eyewash VP: 0. [Note: Hygroscopic (i. upper resp sys. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. (NH2CH2CH2)2NH 111-40-0 Conversion: 1 ppm = 4.Gr: 0. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. nau. vomit Breath: Resp support TO: Eyes. Symptoms.P: 208°F Remove: When wet or contam IP: ? Change: N. pulm sens Swallow: Medical attention immed TO: Eyes.2-ethanediamine. skin. skin. resp sys.D.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 103. Ing.7% LEL: 6. N. skin nec. cough. 2-Hydroxytriethylamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (50 mg/m3) [skin] 3 NIOSH 2007 OSHA PEL: TWA 10 ppm (50 mg/m ) [skin] Physical Description: Colorless liquid with a nauseating.e.Pp:AScba Remove: When wet or contam Fl. Diethyl-(2-hydroxyethyl)amine. Abs. muc memb.89 VP: 1 mmHg Quick drench FRZ: -94°F UEL: 11. skin. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 117.Gr: 0. brass & zinc. IP: ? Provide: Eyewash (>5%) Sp. Con Skin: Water flush immed SY: Irrit eyes. absorbs moisture from the air).R. ammonia-like odor. cellulose nitrate [Note: May form explosive complexes with silver.. cobalt.2 Skin: Prevent skin contact BP: 405°F Not available. Abs. skin.] Exposure Routes. Corrosive to aluminum.22 mg/m3 DOT: 2079 154 Synonyms/Trade Names: N-(2-Aminoethyl)-1. bis(2-Aminoethyl)amine. resp sys Diethylenetriamine 107 .2'-Diaminodiethylamine Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (4 mg/m3) [skin] (see Table 1): NIOSH 2540 OSHA PEL†: none OSHA 60 Physical Description: Colorless to yellow liquid with a strong.7% LEL: 2% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers. strong acids. or chromium compounds. derm. strong acids Exposure Routes. copper. skin sens.4 mmHg FRZ: -38°F Quick drench UEL: 6. dysp. 2. resp sys Swallow: Medical attention immed 2-Diethylaminoethanol D CAS#: RTECS#: IDLH: Formula: IE1225000 N.2 100 ppm: CcrOv*/GmFOv/PaprOv*/ Eyes: Prevent eye contact BP: 325°F Wash skin: When contam Sol: Miscible Sa*/ScbaF §: ScbaF:Pd. Skin: Water flush immed Breath: Resp support eye.7% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. Ing. DETA.P: 126°F Escape: GmFOv/ScbaE Change: N.N-Diethylethanolamine. Con Eye: Irr immed SY: Irrit eyes.CAS#: RTECS#: IDLH: Formula: 100-37-8 KK5075000 100 ppm (C2H5)2NCH2CH2OH Conversion: 1 ppm = 4.Pp/SaF:Pd. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. ammonia-like odor.R.79 mg/m3 DOT: 2686 132 Synonyms/Trade Names: Diethylaminoethanol.

Dimethylacetone. resp sys Swallow: Medical attention immed Diethyl ketone Formula: CAS#: RTECS#: IDLH: C6H4(COOC2H5)2 84-66-2 TI1050000 N.R.Gr: 0.P(oc): 55°F Remove: When wet (flamm) IP: 9. ignition is difficult.12 VP(77°F): 0.P(oc): 322°F Remove: N. Metacetone. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 86. strong acids.81 VP(77°F): 35 mmHg FRZ: -44°F UEL: 6.1% Wash skin: N. Eyes: N. Breath: Resp support Swallow: Medical attention immed in animals: repro effects TO: Eyes. alkalis. water First Aid (see Table 6): Exposure Routes. skin.4% LEL: 1. Incompatibilities and Reactivities: Strong oxidizers. oily liquid with a very slight. lass. vestibular dysfunc. Symptoms.R. nose. BP: 215°F Not available. spasms in arms & legs. however. Ing.R. dizz. resp sys. skin. Ethyl ketone. cough.6% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers.R. Diethyl ester of phthalic acid.R. Symptoms. muc memb.D.Gr: 1. Sol(77°F): 0. skin. Con Skin: Soap wash SY: Irrit eyes. lac. Eyes: Prevent eye contact Sol: 5% Wash skin: Daily Fl. resp sys. Propione Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (705 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with an acetone-like odor. Con Skin: Wash regularly SY: Irrit eyes. Conversion: DOT: Synonyms/Trade Names: DEP.D. 3-Pentanone. repro sys Diethyl phthalate 108 . pain.R. Sp. Sp.D Formula: CAS#: RTECS#: IDLH: CH3CH2COCH2CH3 96-22-0 SA8050000 N.53 mg/m3 DOT: 1156 127 Synonyms/Trade Names: DEK. (hydrogen peroxide + nitric acid) Exposure Routes.3 Skin: N. Fl. numb. Conversion: 1 ppm = 3.32 eV Change: N. sneez Breath: Resp support TO: Eyes. CNS. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.2 Skin: N. PNS. skin. BP: 563°F Not available.R. Ethyl phthalate Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): OSHA PEL†: none OSHA 104 Physical Description: Colorless to water-white.7% Class IIIB Combustible Liquid. nitric acid. permanganates. head.002 mmHg FRZ: -41°F UEL: ? LEL(368°F): 0. aromatic odor. IP: ? Change: N. Ing. [pesticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 222. Target Organs (see Table 5): Eye: Irr immed ER: Inh. possible polyneur. nau. mineral acids. throat.

repro sys [in animals: skin tumors] Diglycidyl ether 3 109 .Gr: 1. Sp. Halon® 1202 Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (860 mg/m3) (see Table 1): 3 NIOSH 1012 OSHA PEL: TWA 100 ppm (860 mg/m ) OSHA 7 Physical Description: Colorless. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 130. in animals: hemato sys. zinc & magnesium Nonflammable Gas Exposure Routes. Noncombustible Liquid potassium.09 mmHg Quick drench FRZ: ? UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Abs. 2-Epoxypropyl ether. Ing.5 mg/m3) None available See Appendix A 3 OSHA PEL†: C 0. powdered aluminum. skin. resp sys.Formula: CAS#: RTECS#: IDLH: CBr2F2 75-61-6 PA7525000 2000 ppm Conversion: 1 ppm = 8. liver Swallow: Medical attention immed Difluorodibromomethane D Formula: CAS#: RTECS#: IDLH: C6H10O3 2238-07-5 KN2350000 Ca [10 ppm] Conversion: 1 ppm = 5. Di(2.Pp/SaF:Pd.2 ¥: ScbaF:Pd. skin burns. liver damage Breath: Resp support TO: Resp sys.8 Skin: Prevent skin contact 1000 ppm: Sa BP: 76°F Eyes: Prevent eye contact 2000 ppm: Sa:Cf/ScbaF/SaF Sol: Insoluble Wash skin: N. heavy liquid or gas (above 76°F) with a characteristic odor.Gr(59°F): 2.3-epoxypropyl) ether. CNS. Con Skin: Water flush immed SY: In animals: irrit resp sys. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 209. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. repro effects. §: ScbaF:Pd. irritating odor.12 VP(77°F): 0.P: 147°F Change: Daily IP: ? Provide: Eyewash Sp.Pp:AScba Eyes: Prevent eye contact BP: 500°F Escape: GmFOv/ScbaE Wash skin: When contam/Daily Sol: ? Remove: When wet or contam Fl.8 mg/m ) Physical Description: Colorless liquid with a strong.07 eV Change: N.P: NA Remove: When wet or contam Escape: GmFOv/ScbaE IP: 11. Skin: Soap wash immed Breath: Resp support lung. kidney damage. Symptoms. liver.1 ppm (0.5 ppm (2.R. [carc] Swallow: Medical attention immed TO: Eyes. DGE. CNS symptoms. calcium.58 mg/m3 DOT: 1941 171 Synonyms/Trade Names: Dibromodifluoromethane. Symptoms. Freon® 12B2. resp sys.Pp:AScba Fl.33 mg/m DOT: Synonyms/Trade Names: Diallyl ether dioxide.3-Epoxypropyl) ether Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): TWA 0.R. skin.Pp/SaF:Pd. bis(2. Con Eye: Irr immed SY: Irrit eyes. Ing.29 VP: 620 mmHg FRZ: -231°F UEL: NA LEL: NA Incompatibilities and Reactivities: Chemically-active metals such as sodium.

D CAS#: RTECS#: IDLH: Formula: MJ5775000 500 ppm [(CH3)2CHCH2]2CO 108-83-8 Conversion: 1 ppm = 5.Pp:AScba Change: N.6-Dimethyl-4-heptanone. BP: 334°F Wash skin: When contam Sol: 0. resp sys. CNS. 2. IP: 9. resp sys.73 eV Escape: GmFOv/ScbaE Provide: Eyewash (>5%) Sp. kidney damage TO: Eyes. Con Skin: Water wash immed SY: Irrit eyes. Target Organs (see Table 5): ER: Inh. Abs. liver.14 mg/m3 DOT: 1158 132 Synonyms/Trade Names: DIPA.05% Remove: When wet or contam Fl. skin.72 VP: 70 mmHg FRZ: -141°F UEL: 7.Gr: 0.P: 20°F ScbaF/SaF §: ScbaF:Pd. skin. vis dist Breath: Resp support TO: Eyes.8% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.R. skin. Diisobutyl ketone Personal Protection/Sanitation Chemical & Physical (see Table 2): Properties: Skin: Prevent skin contact MW: 142. nose. derm.1% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. Symptoms. vomit. liver. nau. resp sys Swallow: Medical attention immed Diisopropylamine 110 .2 125 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact (>5%) BP: 183°F 200 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: Miscible Remove: When wet (flamm) Fl.1% LEL: 1.Pp/SaF:Pd.P: 120°F Change: N.Gr: 0. kidneys Respirator Recommendations (see Tables 3 and 4): NIOSH 500 ppm: Sa:Cf£/PaprOv£/CcrFOv/ GmFOv/ScbaF/SaF §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. dizz.81 VP: 2 mmHg FRZ: -43°F UEL(200°F): 7.R. Isovalerone. sweet odor. N-(1-Methylethyl)-2-propanamine Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (20 mg/m3) [skin] (see Table 1): 3 OSHA PEL: TWA 5 ppm (20 mg/m ) [skin] NIOSH S141 (II-4) Physical Description: Colorless liquid with an ammonia. Ing.04 eV Sp. sym-Diisopropyl acetone.3 Eyes: N.1% LEL(200°F): 0. skin. IP: 7. Valerone Exposure Limits: Measurement Methods NIOSH REL: TWA 25 ppm (150 mg/m3) (see Table 1): 3 NIOSH 1300. throat. Con SY: Irrit eyes.82 mg/m3 DOT: 1157 128 Synonyms/Trade Names: DIBK. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 101. Symptoms. 2555 OSHA PEL†: TWA 50 ppm (290 mg/m ) OSHA 7 Physical Description: Colorless liquid with a mild. head.Pp:AScba Escape: GmFOv/ScbaE First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: [(CH3)2CH]2NH 108-18-9 IM4025000 200 ppm Conversion: 1 ppm = 4. Ing.or fish-like odor.R.Pp/SaF:Pd. head. strong acids Exposure Routes.

5% LEL(212°F): 1. liver. DMAC Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (35 mg/m3) [skin] (see Table 1): 3 NIOSH 2004 OSHA PEL: TWA 10 ppm (35 mg/m ) [skin] Physical Description: Colorless liquid with a weak.1 250 ppm: Sa:Cf£ BP: 44°F Frostbite 500 ppm: ScbaF/SaF Eyes: Prevent eye contact (liquid) Sol(140°F): 24% §: ScbaF:Pd.8% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 87. brass. Symptoms. liquid: frostbite TO: Eyes.56 mg/m3 DOT: Synonyms/Trade Names: N.R.56 Change: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. oxidizers Exposure Routes. liver damage. maleic anhydride. other halogenated compounds when in contact with iron. Con Eye: Irr immed SY: Irrit skin.P(oc): 158°F §: ScbaF:Pd. conj. Ing.Pp/SaF:Pd.P: NA (Gas) 20°F (Liquid) Frostbite Escape: GmFS/ScbaE Wash skin: When contam (liquid) IP: 8.8% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Carbon tetrachloride.Pp:AScba Change: N. depres. zinc Exposure Routes.94 VP: 2 mmHg FRZ: -4°F UEL(320°F): 11. Shipped as a liquefied compressed gas. sneez. Skin: Water flush immed (liquid)/Frostbite Breath: Resp support derm.Gr: 0. dysp. CNS Breath: Resp support Swallow: Medical attention immed Dimethyl acetamide D CAS#: RTECS#: IDLH: Formula: 124-40-3 IP8750000 500 ppm (CH3)2NH Conversion: 1 ppm = 1.81 eV Escape: GmFOv/ScbaE Provide: Quick drench Sp. mercury. pulm edema.Pp/SaF:Pd. jaun. chlorine. Symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact (liquid) MW: 45. drow.4% Frostbite wash LEL: 2.24 eV Remove: When wet (flamm) RGasD: 1. cough.Pp:AScba Fl. [Note: A liquid below 44°F.7 atm FRZ: -134°F Quick drench (liquid) UEL: 14. skin.or fish-like odor. Con (liquid) Eye: Irr immed (liquid)/Frostbite SY: Irrit nose.Formula: CAS#: RTECS#: IDLH: CH3CON(CH3)2 127-19-5 AB7700000 300 ppm Conversion: 1 ppm = 3. delusions Skin: Water flush immed TO: Skin. resp sys Dimethylamine 111 . throat. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.67 (Liquid at 44°F) Provide: Eyewash (liquid) VP: 1. fluorides. ammonia. acraldehyde. Sp.Gr: 0. IP: 8. aluminum.R.1 100 ppm: Sa Eyes: Prevent eye contact BP: 329°F 250 ppm: Sa:Cf Wash skin: When contam Sol: Miscible 300 ppm: ScbaF/SaF Remove: When wet or contam Fl.or fish-like odor.85 mg/m3 DOT: 1032 118 (anhydrous). Abs.N-Dimethyl acetamide. 1160 132 (solution) Synonyms/Trade Names: Dimethylamine (anhydrous). N-Methylmethanamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (18 mg/m3) 3 NIOSH 2010 OSHA PEL: TWA 10 ppm (18 mg/m ) OSHA 34 Physical Description: Colorless gas with an ammonia. halu. copper.

along with dimethylaminopropionitrile (95%). kidneys.3 ¥: ScbaF:Pd.] Exposure Limits: Measurement Methods NIOSH REL: See Appendix C (NIAX® Catalyst ESN) (see Table 1): OSHA PEL: See Appendix C (NIAX® Catalyst ESN) None available Physical Description: Liquid. C8H20N2O Conversion: DOT: Synonyms/Trade Names: NIAX® A99. IP: ? Provide: Eyewash Sp.2'-Oxybis(N. cough. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 225. [carc] Breath: Resp support TO: Skin.] Conversion: DOT: Synonyms/Trade Names: Butter yellow. p-Dimethylaminoazobenzene. bladder [in animals: liver & bladder tumors] Swallow: Medical attention immed 4-Dimethylaminoazobenzene CAS#: RTECS#: IDLH: Formula: 3033-62-3 KR9460000 N. PNS Swallow: Medical attention immed bis(2-(Dimethylamino)ethyl)ether 112 .Gr: ? VP: ? Quick drench FRZ: ? UEL: ? LEL: ? Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. dysuria. Symptoms. Target Organs (see Table 5): Eye: Irr immed ER: Inh. DAB.) Quick drench MLT: 237°F UEL: ? LEL: ? Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes.Pp/SaF:Pd. Abs. frequent urination. leaf-shaped crystals. Abs.0000003 mmHg (est. wheez.3 ¥: ScbaF:Pd. resp sys.D.D.1015] See Appendix B Physical Description: Yellow. in animals: irrit eyes.Gr: ? VP: 0. NIAX® Catalyst A1.D Formula: CAS#: RTECS#: IDLH: C6H5NNC6H4N(CH3)2 60-11-7 BX7350000 Ca [N. contact derm.Pp/SaF:Pd. liver. neurological disorders.Pp:AScba Eyes: Prevent eye contact BP: Sublimes Escape: 100F/ScbaE Wash skin: When contam/Daily Sol: 0. Target Organs (see Table 5): Eye: Irr immed ER: Inh.N-dimethyl ethylamine) [Note: A component (5%) of NIAX® Catalyst ESN. skin Breath: Resp support TO: Eyes. Methyl yellow Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH P&CAM284 (II-4) See Appendix A OSHA PEL: [1910. kidney dist. skin. Ing. bronchial secretions. 2. hema. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 160. N. bloody sputum. Symptoms. Con Skin: Water flush immed SY: Possible urinary dist. Con Skin: Soap wash immed SY: Enlarged liver.001% Remove: When wet or contam Fl.P: ? See Appendix E (page 351) Change: Daily IP: ? Provide: Eyewash Sp. dysp.R. urinary tract. Ing.Pp:AScba Eyes: Prevent eye contact BP: 372°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: ? Remove: When wet or contam Fl. liver.N-Dimethyl-4-aminoazobenzene.P: ? Change: N.

ataxia.14 eV Provide: Quick drench Sp.2 50 ppm: Sa Eyes: Prevent eye contact BP: 378°F 100 ppm: Sa:Cf/ScbaF/SaF Wash skin: When contam Sol: 2% §: ScbaF:Pd. urinary tract Dimethylaminopropionitrile D Formula: CAS#: RTECS#: IDLH: C6H5N(CH3)2 121-69-7 BX4725000 100 ppm Conversion: 1 ppm = 4. skin. CVS Swallow: Medical attention immed N. [Note: A solid below 36°F. lass.D. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Gr(86°F): 0.CAS#: RTECS#: IDLH: Formula: UG1575000 N. neurological disorders.Pp:AScba Eyes: Prevent eye contact BP: 342°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: Miscible Remove: When wet or contam Fl.] First Aid (see Table 6): Exposure Routes. methemo Breath: Resp support TO: Blood. along with bis(2-(dimethylamino)ethyl) ether (5%). strong acids.P: 142°F Escape: GmFOv/ScbaE Change: N.N-Dimethylbenzeneamine.N-Dimethylaniline 3 113 . dizz.Pp/SaF:Pd. Abs. Con SY: Irrit eyes.N-Dimethylphenylamine [Note: Also known as Dimethylaniline which is a correct synonym for Xylidine. N. Con Skin: Soap wash immed SY: Anoxia symptoms: cyan. urinary dist. oily liquid with an amine-like odor.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 121. IP: 7.2 ¥: ScbaF:Pd. Symptoms. lass.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix C (NIAX® Catalyst ESN) OSHA PEL: See Appendix C (NIAX® Catalyst ESN) None available Physical Description: Colorless liquid.Pp/SaF:Pd.P: 147°F Change: N. skin. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 98. CNS. Target Organs (see Table 5): Eye: Irr immed ER: Inh.96 mg/m DOT: 2253 153 Synonyms/Trade Names: N. (CH3)2NCH2CH2CN 1738-25-6 Conversion: DOT: Synonyms/Trade Names: 3-(Dimethylamino)propionitrile.R.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 ppm (25 mg/m3) NIOSH 2002 ST 10 ppm (50 mg/m3) [skin] OSHA PV2064 OSHA PEL†: TWA 5 ppm (25 mg/m3) [skin] Physical Description: Pale yellow.Pp:AScba Remove: When wet or contam Fl. Symptoms.R. decr nerve conduction in Breath: Resp support Swallow: Medical attention immed lower legs TO: Eyes. Ing. vomit.86 VP(135°F): 10 mmHg Quick drench FRZ: -48°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers [Note: Emits toxic oxides of nitrogen and cyanide fumes when heated to decomposition. musc weak. N. pins & needles Skin: Water flush immed in hands & feet. nau. IP: ? Provide: Eyewash Sp. liver.96 VP: 1 mmHg FRZ: 36°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.N-Dimethylamino-3-propionitrile [Note: A component (95%) of NIAX® Catalyst ESN. kidneys. Abs.Gr: 0. benzoyl peroxide Exposure Routes. Ing.

abdom cramp. resp sys.96 200 mg/m3: Sa:Pd.2dichlorethyl phosphate Formula: CAS#: (CH3O)2P(O)OCHBrCBrCl2 300-76-5 RTECS#: TB9450000 IDLH: 200 mg/m3 Conversion: DOT: Synonyms/Trade Names: Dibrom®.Pp VP: 0. wheez.8 30 mg/m3: 95XQ/Sa Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: Insoluble 75 mg/m3: Sa:Cf/PaprHie Remove: When wet or contam Fl. card irreg TO: Eyes. nau.Pp/SaF:Pd.2-Dibromo-2. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 380. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin. Abs. vomit.] Exposure Routes. Ing. blood chol 114 .D. salv. nose. larnygitis. ataxia. resp sys. miosis. Ing.D CAS#: RTECS#: IDLH: Formula: 79-44-7 FD4200000 Ca [N. Dimethylcarbamic chloride. nau.Gr: 1. sunlight.2-dichloroethyl dimethyl phosphate. dizz. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH MW: 107.17 Provide: Eyewash VP: ? Quick drench FRZ: -27°F UEL: ? Incompatibilities and Reactivities: Acids. skin burns. chest tight.P: NA 150 mg/m3: 100F/SaT:Cf/PaprTHie/ Change: Daily IP: ? ScbaF/SaF Provide: Eyewash Sp. Con Skin: Soap wash immed SY: Irrit eyes.Pp:AScba BP: 329°F Eyes: Prevent eye contact Escape: GmFOv/ScbaE Sol: Reacts Wash skin: When contam Fl. Hydrolyzed in presence of water. water LEL: ? [Note: Rapidly hydrolyzes in water to dimethylamine.P: 155°F Remove: When wet or contam IP: ? Change: N.R. N. vomit.Gr(77°F): 1. DMCC Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): See Appendix A None available OSHA PEL: none Physical Description: Clear. lass. eye.] (CH3)2NCOCl Conversion: DOT: 2262 156 Synonyms/Trade Names: Chloroformic acid dimethylamide.6 Skin: Prevent skin contact ¥: ScbaF:Pd. carbon dioxide. and Class IIIA Combustible Liquid hydrogen chloride. head. Sp.0002 mmHg §: ScbaF:Pd. resp sys. Swallow: Medical attention immed twitch. Con Eye: Irr immed SY: Irrit eyes. liver inj. CNS. [carc] Breath: Resp support Swallow: Medical attention immed TO: Eyes. acids. cyan. wheez. convuls. water [Note: Corrosive to metals.N-Dimethylcarbamoyl chloride. Abs. lar Breath: Resp support spasm. diarr. lac. colorless liquid. CVS. dysp. throat.] Exposure Routes. low BP. para. liver [in animals: nasal cancer] Dimethyl carbamoyl chloride Dimethyl-1. skin. anor. skin.Pp/SaF:Pd. Naled Exposure Limits: Measurement Methods NIOSH REL: TWA 3 mg/m3 [skin] (see Table 1): OSHA PEL†: TWA 3 mg/m3 None available Physical Description: Colorless to white solid or straw-colored liquid (above 80°F) with a slightly pungent odor.Pp:AScba MLT: 80°F Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers. 1. Symptoms. Skin: Water flush immed cough. head.2-dibromo-2. skin. Symptoms.

blood. GI tract. skin. DMH.Pp:AScba Eyes: Prevent eye contact BP: 147°F Escape: GmFS/ScbaE Wash skin: When contam Sol: Miscible Remove: When wet (flamm) Fl.06 ppm (0. Abs.12 eV §: ScbaF:Pd.Formula: CAS#: RTECS#: IDLH: HCON(CH3)2 68-12-2 LQ2100000 500 ppm Conversion: 1 ppm = 2. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 60. [carc] TO: CNS.15 mg/m ) [2-hr] See Appendix A 3 OSHA PEL: TWA 0. inorganic nitrates Exposure Routes. IP: 8.95 Escape: GmFOv/ScbaE VP: 3 mmHg FRZ: -78°F UEL: 15. UDMH. other halogenated compounds when in contact with iron. enlarged Skin: Water flush prompt Breath: Resp support liver. anoxia.or fish-like odor.1-Dimethylhydrazine 115 . liver. DMF Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (30 mg/m3) [skin] (see Table 1): 3 NIOSH 2004 OSHA PEL: TWA 10 ppm (30 mg/m ) [skin] OSHA 66 Physical Description: Colorless to pale-yellow liquid with a faint.Gr: 0. derm. vomit. halogens.5 ppm (1 mg/m ) [skin] Physical Description: Colorless liquid with an ammonia.2% LEL(212°F): 2. Ing.99 mg/m3 DOT: 2265 129 Synonyms/Trade Names: Dimethyl formamide. chest pain. CVS Dimethylformamide D Formula: CAS#: RTECS#: IDLH: (CH3)2NNH2 57-14-7 MV2450000 Ca [15 ppm] Conversion: 1 ppm = 2. Breath: Resp support convuls. nau. resp sys. nau.P: 136°F 500 ppm: SaT:Cf*/ScbaF/SaF Remove: When wet or contam IP: 9. liver.N-Dimethylformamide. dysp. kidneys.R. amine-like odor. skin. eyes. liver damage. skin [in animals: tumors Swallow: Medical attention immed of the lungs. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. resp sys. N.46 mg/m3 DOT: 1163 131 Synonyms/Trade Names: Dimazine. Symptoms.Pp/SaF:Pd. Unsymmetrical dimethylhydrazine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 3515 C 0.Pp/SaF:Pd. Target Organs (see Table 5): Eye: Irr immed ER: Inh.2% Class II Combustible Liquid Incompatibilities and Reactivities: Carbon tetrachloride.1 NIOSH Skin: Prevent skin contact BP: 307°F 100 ppm: Sa* Eyes: Prevent eye contact Sol: Miscible 250 ppm: Sa:Cf* Wash skin: When contam Fl. choking. Ing. liver inj. hydrogen peroxide [Note: May ignite SPONTANEOUSLY in contact with oxidizers. Con Eye: Irr immed SY: Irrit eyes.P: 5°F Change: N. liver. in animals: kidney.1 ¥: ScbaF:Pd.79 VP: 103 mmHg Quick drench FRZ: -72°F UEL: 95% LEL: 2% Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers. colic. alkyl aluminums. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 73.] First Aid (see Table 6): Exposure Routes. face flush. Sp. resp sys.R.Gr: 0. metallic mercury. Abs. drow. Symptoms. Con Skin: Water flush immed SY: Irrit eyes. skin. high BP.05 eV Provide: Eyewash Sp. heart damage Swallow: Medical attention immed TO: Eyes. strong oxidizers. blood vessels & intestines] 1.Pp:AScba Change: N. fuming nitric acid.

R. skin. hema. strong oxidizers.Pp:AScba FRZ: 42°F Escape: 100F/ScbaE UEL: ? LEL(358°F): 0. aromatic odor.2-benzenedicarboxylic acid. vomit.R. BP: 543°F 50 mg/m3: 95F Eyes: Prevent eye contact Sol: 0. chest pain. productive cough. Con Eye: Irr immed SY: Irrit eyes. prot.1 mmHg FRZ: -25°F Quick drench UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. conj. Sp. nose.1 NIOSH Skin: Prevent skin contact BP: 370°F (Decomposes) ¥: ScbaF:Pd. delirium.4% Wash skin: N.R. skin burns.01 mmHg §: ScbaF:Pd.Pp VP: 0. however. liver. Fl.R.5 mg/m ) [skin] See Appendix A 3 OSHA PEL†: TWA 1 ppm (5 mg/m ) [skin] Physical Description: Colorless. Symptoms. Ing.Pp/SaF:Pd. Methyl sulfate Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 2524 TWA 0.Gr: 1.33 Provide: Eyewash VP: 0. cyan. dizz. Symptoms. kidneys.2 NIOSH/OSHA Skin: N. dysphonia.] Exposure Routes. Sp.16 mg/m3 DOT: 1595 156 Synonyms/Trade Names: Dimethyl ester of sulfuric acid. Con Eye: Irr prompt SY: Irrit eyes.P: 182°F Remove: When wet or contam IP: ? Change: N. ignition is difficult. periorb edema. Incompatibilities and Reactivities: Nitrates. CNS [in animals: nasal & lung cancer] Dimethyl sulfate 116 . oily liquid with a faint.Gr: 1. [carc] TO: Eyes. Ing. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 126. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.1 ppm (0. dysphagia.9% Class IIIB Combustible Liquid.Pp:AScba Eyes: Prevent eye contact Sol(64°F): 3% Escape: GmFS/ScbaE Wash skin: When contam Fl. analgesia.Pp/SaF:Pd.R. onion-like odor.19 2000 mg/m3: SaF:Pd. stomach pain Skin: Wash regularly TO: Eyes. [Note: A solid below 42°F. oily liquid with a slight. resp sys.D Formula: CAS#: RTECS#: IDLH: C6H4(COOCH3)2 131-11-3 TI1575000 2000 mg/m3 Conversion: DOT: Synonyms/Trade Names: Dimethyl ester of 1. head. Skin: Water flush immed Breath: Resp support aphonia.64 eV 250 mg/m3: 100F/ScbaF/SaF Change: N. ammonia solutions [Note: Decomposes in water to sulfuric acid. DMP Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 OSHA 104 OSHA PEL: TWA 5 mg/m Physical Description: Colorless. fever. photo. upper resp sys. resp sys. GI tract Breath: Resp support Swallow: Medical attention immed Dimethylphthalate Formula: CAS#: RTECS#: IDLH: (CH3)2SO4 77-78-1 WS8225000 Ca [7 ppm] Conversion: 1 ppm = 5.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 194. Swallow: Medical attention immed dysuria. alkalis & acids Exposure Routes. dysp. diarr. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. eye. Dimethylsulfate.P: 295°F 125 mg/m3: Sa:Cf£/PaprHie£ Remove: N. IP: 9. corrosive to metals. Abs.

5-Dinitro-o-toluamide. Conversion: DOT: Synonyms/Trade Names: 3.3-Dinitrobenzene Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 [skin] (see Table 1): 3 NIOSH S214 (II-4) OSHA PEL: TWA 1 mg/m [skin] Physical Description: Pale-white or yellow solid. in animals: methemo. Skin: Soap wash immed Breath: Resp support dry throat.P: 302°F 25 mg/m3: Sa:Cf/PaprHie Change: Daily IP: 10. anemia. liver damage Swallow: Medical attention immed TO: Eyes. liver. Con Skin: Soap wash immed SY: Contact eczema.1 5 mg/m3: Qm Eyes: Prevent eye contact BP: 572°F Wash skin: When contam Sol: 0. bad taste.Formula: CAS#: RTECS#: IDLH: (NO2)2C6H2(CH3)CONH2 148-01-6 XS4200000 N. skin.Gr: 1. vis dist. Zoalene Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): NIOSH 0500 OSHA PEL†: none Physical Description: Yellowish. CVS. 2-Methyl-3. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 168.58 ScbaF/SaF VP: ? §: ScbaF:Pd. central scotomas.02% 10 mg/m3: 95XQ/Sa Remove: When wet or contam Fl. Symptoms. Target Organs (see Table 5): Eye: Irr immed ER: Inh. eyes. metals such as tin & zinc [Note: Prolonged exposure to fire and heat may result in an explosion due to SPONTANEOUS decomposition. cyan. crystalline solid. liver changes Breath: Resp support TO: Skin.5-dinitrobenzamide.D. Ing. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 225.2 Skin: Prevent skin contact BP: ? Not available.Pp/SaF:Pd. Ing. 1. Con SY: Anoxia. CNS m-Dinitrobenzene 117 . Eyes: Prevent eye contact Sol: Slight Wash skin: When contam Fl. blood.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. yellowing hair.] First Aid (see Table 6): Exposure Routes.Gr: ? VP: ? MLT: 351°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. burning mouth. Symptoms.43 eV 50 mg/m3: 100F/SaT:Cf/PaprTHie/ Provide: Quick drench Sp.Pp:AScba MLT: 192°F Escape: 100F/ScbaE UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. blood Swallow: Medical attention immed Dinitolmide D Formula: CAS#: RTECS#: IDLH: C6H4(NO2)2 99-65-0 CZ7350000 50 mg/m3 Conversion: DOT: 1597 152 Synonyms/Trade Names: meta-Dinitrobenzene. liver. thirst. skin. caustics. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Abs.

Pp/SaF:Pd. yellowing hair. anemia.] First Aid (see Table 6): Exposure Routes. Target Organs (see Table 5): Eye: Irr immed ER: Inh. caustics. Symptoms. bad taste. bad taste. liver damage Swallow: Medical attention immed TO: Eyes.05% 10 mg/m3: 95XQ/Sa Remove: When wet or contam Fl. skin. skin. Abs. eyes.57 ScbaF/SaF VP: ? §: ScbaF:Pd. anemia.50 eV 50 mg/m3: 100F/SaT:Cf/PaprTHie/ Provide: Quick drench Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 168.] First Aid (see Table 6): Exposure Routes. caustics. burning mouth. liver.2-Dinitrobenzene Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 [skin] (see Table 1): 3 NIOSH S214 (II-4) OSHA PEL: TWA 1 mg/m [skin] Physical Description: Pale-white or yellow solid. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 168. metals such as tin & zinc [Note: Prolonged exposure to fire and heat may result in an explosion due to SPONTANEOUS decomposition. CNS o-Dinitrobenzene Formula: CAS#: RTECS#: IDLH: C6H4(NO2)2 100-25-4 CZ7525000 50 mg/m3 Conversion: DOT: 1597 152 Synonyms/Trade Names: para-Dinitrobenzene. Symptoms. central scotomas. burning mouth.D Formula: CAS#: RTECS#: IDLH: C6H4(NO2)2 528-29-0 CZ7450000 50 mg/m3 Conversion: DOT: 1597 152 Synonyms/Trade Names: ortho-Dinitrobenzene.P: ? 25 mg/m3: Sa:Cf/PaprHie Change: Daily IP: 10.P: 302°F 25 mg/m3: Sa:Cf/PaprHie Change: Daily IP: 10.1 5 mg/m3: Qm Eyes: Prevent eye contact BP: 606°F Wash skin: When contam Sol: 0. vis dist. 1. Skin: Soap wash immed Breath: Resp support dry throat. thirst.4-Dinitrobenzene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 mg/m3 [skin] 3 NIOSH S214 (II-4) OSHA PEL: TWA 1 mg/m [skin] Physical Description: Pale-white or yellow solid. eyes. CVS. yellowing hair. liver. Ing. 1.71 eV 50 mg/m3: 100F/SaT:Cf/PaprTHie/ Provide: Quick drench Sp. thirst. Ing. skin. Con SY: Anoxia. CNS p-Dinitrobenzene 118 . blood.01% Remove: When wet or contam Fl. vis dist. Con SY: Anoxia.Gr: 1.Pp:AScba MLT: 244°F Escape: 100F/ScbaE UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers.63 ScbaF/SaF VP: ? §: ScbaF:Pd. skin. dry Skin: Soap wash immed Breath: Resp support throat.Pp:AScba MLT: 343°F Escape: 100F/ScbaE UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. blood. Abs. cyan.Pp/SaF:Pd.Gr: 1. CVS.1 5 mg/m3: Qm Eyes: Prevent eye contact BP: 570°F Wash skin: When contam 10 mg/m3: 95XQ/Sa Sol: 0. metals such as tin & zinc [Note: Prolonged exposure to fire and heat may result in an explosion due to SPONTANEOUS decomposition. cyan. central scotomas. liver damage Swallow: Medical attention immed TO: Eyes.

anemia.32 Provide: Quick drench VP: 1 mmHg MLT: 158°F UEL: ? LEL: ? Combustible Solid. but difficult to ignite. short breath.6-Dinitro-2-methyl phenol. 3.01% Eyes: Prevent eye contact Fl. Abs. lass. repro sys [in animals: liver. Breath: Resp support excess thirst. DNC. Ing. caustics. 2038 152 (solid) Synonyms/Trade Names: Dinitrotoluol.1 (see Table 2): NIOSH/OSHA BP: 594°F Skin: Prevent skin contact 2 mg/m3: 95F Sol: 0.00005 mmHg Escape: 100F/ScbaE MLT: 190°F UEL: NA LEL: NA MEC: 30 g/m3 Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. hyperpnea. Symptoms. Incompatibilities and Reactivities: Strong oxidizers. odorless solid. [carc] Breath: Resp support TO: Blood.] First Aid (see Table 6): Exposure Routes. head.5 mg/m [skin] Physical Description: Orange-yellow crystalline solid with a characteristic odor. liver. endocrine sys Dinitro-o-cresol D Formula: CAS#: RTECS#: IDLH: CH3C6H3(NO2)2 25321-14-6 XT1300000 Ca [50 mg/m3] Conversion: DOT: 1600 152 (molten). cyan. coma Swallow: Medical attention immed TO: CVS. metals such as tin & zinc [Note: Commercial grades will decompose at 482°F. cough.Formula: CAS#: RTECS#: IDLH: CH3C6H2OH(NO2)2 534-52-1 GO9625000 5 mg/m3 Conversion: DOT: 1598 153 Synonyms/Trade Names: 4.Pp/SaF:Pd. jaun. Methyldinitrobenzene [Note: Various isomers of DNT exist.P: NA Wash skin: When contam/Daily 5 mg/m3: 100F/Sa:Cf£/PaprHie£/ IP: ? Remove: When wet or contam ScbaF/SaF Sp.2 mg/m [skin] Physical Description: Yellow.Gr: 1. Symptoms.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam/Daily Escape: GmFOv100/ScbaE Fl. Con Skin: Soap wash immed SY: Sense of well being. fever.5 mg/m [skin] See Appendix A 3 OSHA PEL: TWA 1. Ing. [insecticide] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 198. DNOC Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.2 NIOSH Skin: Prevent skin contact BP: 572°F ¥: ScbaF:Pd.Pp/SaF:Pd.2 mg/m3 [skin] 3 NIOSH S166 (II-5) OSHA PEL: TWA 0.5-Dinitro-2-hydroxytoluene. DNT. CVS. repro effects. Abs. Con Skin: Soap wash immed SY: Anoxia.Pp:AScba VP: 0. skin & kidney tumors] Swallow: Medical attention immed Dinitrotoluene 119 .Gr: 1.6-Dinitro-o-cresol. [Note: Often shipped molten. 4. tacar. Target Organs (see Table 5): Eye: Irr immed ER: Inh.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 182. with self-sustaining decomposition at 536°F.] Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 OSHA 44 TWA 1.1 (estimated) Change: Daily §: ScbaF:Pd.P: 404°F Remove: When wet or contam IP: ? Change: Daily Sp. profuse sweat.

nose. vomit.3% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Nitrates.5 NIOSH Skin: N. DOP. repro sys. Ing. Fl. terato effects. muc memb.Pp:AScba Eyes: Prevent eye contact Sol: Miscible Escape: GmFOv/ScbaE Wash skin: When contam Fl. acids & alkalis First Aid (see Table 6): Exposure Routes. [carc] Swallow: Medical attention immed TO: Eyes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 390. IP: ? Change: N.R.03 Provide: Eyewash VP: 29 mmHg FRZ: 53°F Quick drench UEL: 22% LEL: 2. resp sys. Con Skin: Water wash prompt SY: Irrit eyes. kidneys [in animals: lung.0% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers.13 eV Change: N. Target Organs (see Table 5): Eye: Irr immed ER: Inh. liver. Target Organs (see Table 5): Eye: Irr immed ER: Inh.P: 55°F Remove: When wet (flamm) IP: 9. Symptoms. p-Dioxane. CNS.1 NIOSH Skin: Prevent skin contact BP: 214°F ¥: ScbaF:Pd. GI tract [in animals: liver tumors] Di-sec octyl phthalate Formula: CAS#: RTECS#: IDLH: C4H8O2 123-91-1 JG8225000 Ca [500 ppm] Conversion: 1 ppm = 3.99 VP: <0. Ing. nau. Di(2-ethylhexyl)phthalate. decaborane.P(oc): 420°F Remove: N. triethynyl aluminum First Aid (see Table 6): Exposure Routes.R.Gr: 0. [carc] Swallow: Medical attention immed TO: Eyes. liver & nasal cavity tumors] Dioxane 120 .Pp:AScba Eyes: N. ether-like odor.R.00003% Escape: 100F/ScbaE Wash skin: N. Dioxan. 1. Diethylene ether. strong oxidizers. Symptoms.01 mmHg FRZ: -58°F UEL: ? LEL(474°F): 0.6 mg/m ) [30-minute] OSHA 7 See Appendix A 3 OSHA PEL†: TWA 100 ppm (360 mg/m ) [skin] Physical Description: Colorless liquid or solid (below 53°F) with a mild. Sol(75°F): 0.60 mg/m3 DOT: 1165 127 Synonyms/Trade Names: Diethylene dioxide.Pp/SaF:Pd.Pp/SaF:Pd. oily liquid with a slight odor.4-Dioxane Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 1602 C 1 ppm (3. Sp. liver damage. resp sys. Breath: Resp support kidney failure. Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 88.Gr: 1. Octyl phthalate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 5020 TWA 5 mg/m 3 ST 10 mg/m See Appendix A OSHA PEL†: TWA 5 mg/m3 Physical Description: Colorless. skin.R. Con Breath: Resp support SY: Irrit eyes.R. drow. bis-(2-Ethylhexyl)phthalate. liver.R. throat.D Formula: CAS#: RTECS#: IDLH: C24H38O4 117-81-7 TI0350000 Ca [5000 mg/m3] Conversion: DOT: Synonyms/Trade Names: DEHP. skin. in animals: liver damage. head. Abs. BP: 727°F ¥: ScbaF:Pd.

resp sys. liver damage Skin: Water flush immed Breath: Resp support TO: Eyes. heat Exposure Routes. lass. Symptoms. resp sys. Con SY: Irrit eyes. or dark-amber liquid. Ing.8% LEL(232°F): 0.Pp/SaF:Pd. Phenyl benzene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 mg/m3 (0. rhin. CNS Swallow: Medical attention immed Diphenyl 121 . tan. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. numb limbs. p-Dioxane-2.2 10 mg/m3: CcrOv95/Sa Eyes: Prevent eye contact BP: 489°F Wash skin: When contam Sol: Insoluble 25 mg/m3: Sa:Cf*/PaprOvHie* Remove: When wet or contam Fl. nau. head. salv.3-p-Dioxanethiol-S. Skin: Soap flush immed Breath: Resp support vomit.6 Skin: Prevent skin contact BP: ? Not available.2 ppm) 3 NIOSH 2530 OSHA PEL: TWA 1 mg/m (0.Gr: 1.D.2 mg/m3 [skin] OSHA PEL†: none None available Physical Description: Viscous. iron or tin surfaces.S-bis(O. lass. head. [insecticide] [Note: Technical product is a mixture of cis. chest tight. Con SY: Irrit eyes. liver. diarr.31 mg/m3 DOT: Synonyms/Trade Names: Biphenyl. drow Swallow: Medical attention immed TO: Eyes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 456.& trans-isomers.Pp VP: 0. skin. dizz. Symptoms. throat.P: NA Remove: When wet or contam IP: ? Change: N. CVS. abdom cramps. Ing. 2.26 Provide: Eyewash VP: ? FRZ: -4°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Alkalis. conf. brown. miosis. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.6% Combustible Solid Incompatibilities and Reactivities: Oxidizers Exposure Routes. Sp.04 100 mg/m3: SaF:Pd. Dioxane phosphate.95 eV PaprTOvHie*/ScbaF/SaF Provide: Eyewash (molt) Sp.Formula: CAS#: RTECS#: IDLH: C4H6O2[SPS(OC2H5)2]2 78-34-2 TE3350000 N.Gr(79°F): 1. musc fasc. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.2 ppm) OSHA PV2022 Physical Description: Colorless to pale-yellow solid with a pleasant. blood chol Dioxathion D Formula: CAS#: RTECS#: IDLH: C6H5C6H5 92-52-4 DU8050000 100 mg/m3 Conversion: 1 ppm = 6. CNS.P: 235°F 50 mg/m3: CcrFOv100/GmFOv100/ Change: Daily IP: 7.3-diyl ethyl phosphorodithioate. Abs. nau. skin.R. [fungicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 154. characteristic odor. Navadel® Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Abs.005 mmHg §: ScbaF:Pd. Conversion: DOT: Synonyms/Trade Names: Delnav®.O-diethyl phosphoro-dithioate).Pp:AScba Quick drench (molt) MLT: 156°F Escape: GmFOv100/ScbaE UEL(311°F): 5.

blood. dizz. skin.06 mg/m DOT: Synonyms/Trade Names: Dipropylene glycol monomethyl ether. Ing. resp sys. skin.40 eV Change: Daily Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N. (C6H5)2NH Conversion: DOT: Synonyms/Trade Names: Anilinobenzene. incr BP. Abs. CVS. bladder Breath: Resp support Swallow: Medical attention immed inj.Gr: 0. repro sys Diphenylamine CAS#: RTECS#: IDLH: Formula: 34590-94-8 JM1575000 600 ppm CH3OC3H6OC3H6OH Conversion: 1 ppm = 6. Symptoms. sneez. hypertension. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Phenylaniline.Pp/SaF:Pd.5 mmHg FRZ: -112°F UEL: 3. bladder. N-Phenylbenzenamine [Note: The carcinogen 4-Aminodiphenyl may be present as an impurity in the commercial product. amber. muc memb. tacar. in animals: terato effects TO: Eyes. eczema. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R.0% LEL(392°F): 1. Abs. Dowanol® 50B Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (600 mg/m3) (see Table 1): 3 NIOSH 2554. Con Skin: Water wash prompt SY: Irrit eyes.R. cough. IP: ? Sp. ether-like odor.D. MW: 148.2 Skin: Prevent skin contact BP: 576°F Not available. lass. floral odor. Ing. throat.Pp:AScba Wash skin: N. N-Phenylaniline. S69 (II-2) ST 150 ppm (900 mg/m ) [skin] OSHA PEL†: TWA 100 ppm (600 mg/m3) [skin] Physical Description: Colorless liquid with a mild. prot. or brown crystalline solid with a pleasant. trichloromelamine Exposure Routes.R.2 600 ppm: Sa/ScbaF Eyes: N.Gr: 1.R.03% Wash skin: Daily Fl.1% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. methemo. BP: 408°F §: ScbaF:Pd. CNS Swallow: Medical attention immed Dipropylene glycol methyl ether 3 122 .P: 180°F Change: N. hexachloromelamine. [fungicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 169. head Breath: Resp support TO: Eyes. Eyes: Prevent eye contact Sol: 0.D CAS#: RTECS#: IDLH: Formula: 122-39-4 JJ7800000 N. explosive if a cloud of dust is exposed to a source of ignition.95 VP: 0. DPA. heart rate. tan. 78 OSHA PEL†: none Physical Description: Colorless. hema. resp sys.P: 307°F Remove: When wet or contam IP: 7.R. nose.16 VP(227°F): 1 mmHg MLT: 127°F UEL: ? LEL: ? Combustible Solid. Sol: Miscible Escape: GmFOv100/ScbaE Remove: N. Con Skin: Soap wash prompt SY: Irrit eyes. Fl. Symptoms. Incompatibilities and Reactivities: Oxidizers.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 OSHA 22.

Abs. chest pain. convuls. muc memb. CNS. vomit. skin.P: 120°F Remove: When wet or contam IP: 9. narco Swallow: Medical attention immed TO: Eyes.1'-Ethylene-2. Ing. Conversion: DOT: 2781 151 (solid). kidneys. cough. DPK. rhin. resp sys. tremor.67 mg/m3 DOT: 2710 128 Synonyms/Trade Names: Butyrone. liver inj. 1. but does not readily Incompatibilities and Reactivities: Alkalis. [herbicide] [Note: Commercial product may be found in a liquid concentrate or a solution. skin. decr breath.CAS#: RTECS#: IDLH: Formula: 123-19-3 MJ5600000 N. 2782 131 (liquid) Synonyms/Trade Names: Diquat dibromide. Symptoms. Ing. liver Dipropyl ketone D Formula: CAS#: RTECS#: IDLH: C12H12N2Br2 85-00-7 JM5690000 N. (CH3CH2CH2)2CO Conversion: 1 ppm = 4. dysp. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.D.D. kidney. skin. skin burns.10 eV Change: N.22-1. liver. nau. CNS depres. Propyl ketone Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (235 mg/m3) (see Table 1): OSHA 7 OSHA PEL†: none Physical Description: Colorless liquid with a pleasant odor.R. drow. Heptan-4-one. Symptoms.82 VP: 5 mmHg FRZ: -27°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes.27 Change: Daily VP: <0. diarr. dizz. Diquat (Diquat dibromide) Exposure Routes.P: ? Wash skin: When contam IP: ? Remove: When wet or contam Sp. Con Skin: Soap wash SY: Irrit eyes. basic solutions [Note: Concentrated diquat solutions corrode aluminum. delayed healing of wounds TO: Eyes.2 Skin: Prevent skin contact BP: 291°F Not available. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 114.2'-bipyridyllium dibromide [Note: Diquat is a cation (C12H12N2++. Sol: 70% Eyes: Prevent eye contact Fl. Various diquat salts are commercially available.1 (see Table 2): BP: Decomposes Skin: Prevent skin contact Not available. CNS First Aid (see Table 6): Eye: Irr immed Skin: Water flush immed Breath: Resp support Swallow: Medical attention immed 123 . Sp.Gr: 0.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 344. Con SY: Irrit eyes.Gr: 1. UV light. in Breath: Resp support animals: liver inj.] ignite and burns with difficulty.1'-Ethylene-2.00001 mmHg Provide: Quick drench MLT: 635°F UEL: ? LEL: ? Combustible Solid.2-bipyridyllium ion). epis. Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl. mal. Target Organs (see Table 5): ER: Inh. resp sys. skin.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. 4-Heptanone. pulm edema. 1.5 mg/m3 OSHA PEL†: none None available Physical Description: Dibromide salt: Yellow crystals.

musc fasc. diarr.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. Skin: Soap flush immed Breath: Resp support lass.O-Diethyl S-2-(ethylthio)-ethyl phosphorodithioate.] OSHA PEL†: none Physical Description: White. PNS. dizz. Symptoms. resp sys. but will not ignite easily. CVS. Incompatibilities and Reactivities: Alkalis Exposure Routes. metallic taste. chest tight.14 Provide: Eyewash VP: 0.D. Conversion: DOT: 2783 152 Synonyms/Trade Names: O. peri neur. [fungicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 296. Tetraethylthiuram disulfide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 mg/m3 None available [Precautions should be taken to avoid concurrent exposure to ethylene dibromide. rhin. head. skin. nau. blood chol Disulfoton 124 . Con Eye: Irr immed SY: Irrit eyes. or light-gray powder with a slight odor.0002 mmHg FRZ: >-13°F Quick drench UEL: ? LEL: ? Combustible Liquid. dizz. sulfur odor. resp sys. skin. Ro-Sulfiram®. skin. card irreg. Symptoms. Swallow: Medical attention immed eye. yellowish. Thiodemeton Exposure Limits: Measurement Methods NIOSH REL: TWA 0. skin burns TO: Eyes. [insecticide] [Note: Technical product is a brown liquid. Ing.Gr: 1. abdom cramps.4 Skin: Prevent skin contact BP: ? Not available.P: >180°F Remove: When wet or contam IP: ? Change: Daily Sp. Conversion: DOT: Synonyms/Trade Names: Antabuse®. miosis. CNS. tremor. vomit. dysp. Con Eye: Irr immed SY: Irrit eyes. Eyes: Prevent eye contact Sol: 0. TETD.D. liver damage Swallow: Medical attention immed TO: Eyes.30 VP: ? MLT: 158°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. Di-Syston®. salv.1 mg/m3 [skin] (see Table 1): NIOSH 5600 OSHA PEL†: none Physical Description: Oily. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.D Formula: CAS#: RTECS#: IDLH: [(C2H5)2NCS]2S2 97-77-8 JO1225000 N. bis(Diethylthiocarbamoyl) disulfide. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. resp sys.6 Skin: Prevent skin contact BP: ? Not available. Skin: Soap wash immed Breath: Resp support head.Gr: 1. CNS.003% Wash skin: When contam Fl. Ing. restless. Eyes: Prevent eye contact Sol(73°F): 0. skin.02% Wash skin: When contam Fl. colorless to yellow liquid with a characteristic. lass. sens derm. liver Disulfiram Formula: CAS#: RTECS#: IDLH: C8H19O2PS3 298-04-4 TD9275000 N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 274. Abs. blurred vision.

000000002 mmHg MLT: 316°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong acids Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. crystalline solid. in animals: anemia. resp sys.Gr: ? VP: 0. Con Skin: Water flush immed SY: Irrit eyes.Formula: CAS#: RTECS#: IDLH: C6H3Cl2NHCON(CH3)2 330-54-1 YS8925000 N. throat. Eyes: Prevent eye contact Sol: 0.1 Skin: Prevent skin contact BP: 356°F (Decomposes) Not available. skin.D. resp sys. skin burns.1-dimethylurea. Ing. Eyes: Prevent eye contact Sol: 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. straw-colored liquid. odorless. CNS Swallow: Medical attention immed Divinyl benzene 125 .2% LEL: 1.P(oc): 169°F Remove: When wet or contam IP: ? Change: N.D. DVB. but m-isomer predominates. Conversion: 1 ppm = 5.004% Wash skin: Daily Fl. Usually contains an inhibitor to prevent polymerization.93 Provide: Eyewash VP: 0. blood Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: C6H4(HC=CH2)2 1321-74-0 (mixed isomers) CZ9370000 N. [herbicide] Diuron D Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 233. methemo Breath: Resp support TO: Eyes. IP:? Change: Daily Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 130. Vinylstyrene [Note: Commercial product contains all 3 isomers. Conversion: DOT: Synonyms/Trade Names: 3-(3. Symptoms. Direx®. Con SY: Irrit eyes. resp sys.33 mg/m3 DOT: 2049 130 Synonyms/Trade Names: Diethyl benzene.P: NA Remove: N.005% Wash skin: When contam Fl. Karmex® Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (see Table 1): NIOSH 5601 OSHA PEL†: none OSHA PV2097 Physical Description: White. skin.R. Sp.4-Dichlorophenyl)-1.Gr: 0. Symptoms.R.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (50 mg/m3) OSHA 89 OSHA PEL†: none Physical Description: Pale. skin. skin.7 mmHg FRZ: -88°F Quick drench UEL: 6. Ing.1% Class IIIA Combustible Liquid Incompatibilities and Reactivities: None reported Exposure Routes. in animals: CNS depres Skin: Soap flush immed Breath: Resp support TO: Eyes.2 Skin: Prevent skin contact BP: 392°F Not available. nose.

Con SY: Irrit eyes. reducing agents. Impure corundum. alkali metals. chemical properties.E CAS#: RTECS#: IDLH: Formula: 112-55-0 JR3155000 N. resp sys. n-Lauryl mercaptan.5 ppm (4.Gr: 0. white. nau. Ing.1 mg/m3) [15-minute] OSHA PEL: none None available Physical Description: Colorless. cough.P(oc): 190°F Change: N. skunk-like odor. Not available. resp sys. blood 1-Dodecanethiol Formula: CAS#: RTECS#: IDLH: Al2O3 1302-74-5 (corundum) GN2310000 (corundum) N. resp sys TO: Eyes. Lauryl mercaptan.4 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 441-478°F 12.R. Ing. Emery Incompatibilities and Reactivities: Exposure Routes.R. conf. Natural aluminum oxide [Note: Emery is an impure variety of Al2O3 which may contain small impurities of iron. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: Skin: N. [Note: A solid below 15°F.28 mg/m3 DOT: 1228 131 Synonyms/Trade Names: Dodecyl mercaptan. IP: ? ScbaF/SaF §: ScbaF:Pd. Target Organs (see Table 5): ER: Inh. See α-Alumina for physical & Eyes: N. skin. CH3(CH2)11SH Conversion: 1 ppm = 8. dizz.Pp:AScba Provide: Eyewash Sp.R. Symptoms.R. strong bases. water-white. Corundum. Aluminum trioxide. resp sys First Aid (see Table 6): Eye: Irr immed Breath: Fresh air Swallow: Medical attention immed 126 .] Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): OSHA PEL†: TWA 15 mg/m3 (total) NIOSH 0500. steam Exposure Routes. skin. Remove: N. Change: N.R.85 Escape: GmFOv/ScbaE VP(77°F): 3 mmHg FRZ: 15°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers & acids. Con SY: Irrit eyes. skin.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin sens Swallow: Medical attention immed TO: Eyes. Wash skin: N. 1-Dodecyl mercaptan. 1-Mercaptododecane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. crystalline powder. or pale-yellow.D.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl. 0600 3 TWA 5 mg/m (resp) Physical Description: Odorless. Conversion: DOT: Synonyms/Trade Names: Aluminum oxide. Symptoms. skin. dysp. magnesium & silica Corundum is natural Al2O3.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 202. lass. CNS. Skin: Soap wash immed Breath: Resp support abdom pain.D. cyan.Pp/SaF:Pd. oily liquid with a mild. n-Dodecyl mercaptan. water.

drow. head.1 mg/m3 [skin] OSHA PEL†: none OSHA PV2023 Physical Description: Brown crystals with a slight. agitation. nau.10-Hexachloro-1.6.4-endo. [insecticide] Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 380. Target Organs (see Table 5): ER: Inh.4. aggressiveness. vomit. Exposure Routes.9 Skin: Prevent skin contact 1 mg/m3: CcrOv95/Sa BP: Decomposes Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam 2 mg/m3: Sa:Cf/PaprOvHie/ Fl. Ing.70 Provide: Eyewash §: ScbaF:Pd.Pp:AScba VP: Low Escape: GmFOv100/ScbaE Quick drench MLT: 392°F (Decomposes) UEL: NA LEL: NA Noncombustible Solid. tremor.7.2.74 Change: Daily VP(77°F): 0. 6.6.P: NA Wash skin: When contam IP: ? Remove: When wet or contam Sp. repro sys Endosulfan E Endrin Conversion: Synonyms/Trade Names: Hexadrin®. anor.4a. Endosulphan. Sol: 0. dizz. Breath: Resp support convuls. stupor.7. kidneys. Incompatibilities and Reactivities: Strong oxidizers.P: NA Remove: When wet or contam CcrFOv100/GmFOv100/ IP: ? Change: Daily ScbaF/SaF Sp.1 mg/m [skin] NIOSH 5519 Physical Description: Colorless to tan.10.5.7-epoxy-1.Pp/SaF:Pd.8a-octahydro-1.CAS#: RTECS#: IDLH: Formula: 115-29-7 RB9275000 N.9a-hexachloro-6. conf.9-methano-2.5. Abs. Thiodan® Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Gr: 1. but [Note: Corrosive to iron. nau. abdom discomfort. conf.9.4. decomposes in presence of alkalis and acids to form sulfur dioxide. chemical odor.00001% Eyes: Prevent eye contact Fl. 1. Con SY: Epilep convuls.1 mg/m3 [skin] (see Table 1): 3 OSHA PEL: TWA 0.8.] flammable liquids. strong acids. decr testis weight Swallow: Medical attention immed TO: Skin. crystalline solid with a mild.4. flushing. water LEL: NA Noncombustible Solid. Con Skin: Soap flush immed SY: Irrit skin. Symptoms. [insecticide] [Note: Technical product is a tan. isomer mixture.9. Ing. in animals: kidney. acids.Gr: 1. Symptoms. liver. liver inj. waxy.D. Abs. in animals: liver damage TO: CNS. Hydrolyzes slowly on contact with water or may be dissolved in flammable liquids.8. liver First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed Formula: C12H8Cl6O DOT: 2761 151 CAS#: 72-20-8 RTECS#: IO1575000 IDLH: 2 mg/m3 127 .00001 mmHg Provide: Eyewash MLT: 223°F Quick drench UEL: NA Incompatibilities and Reactivities: Alkalis.9 (see Table 2): BP: Decomposes Skin: Prevent skin contact Not available.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 406.5a.10-Hexachloro-6.] Exposure Routes. CNS. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. C9H6Cl6O3S Conversion: DOT: 2761 151 Synonyms/Trade Names: Benzoepin. parathion but may be dissolved in [Note: May emit hydrogen chloride & phosgene when heated or burned. lass.3. dry mouth. insom.8-dimethanonaphthalene Exposure Limits: Measurement Methods NIOSH REL: TWA 0. sulfur dioxide odor. head.3-benzo-dioxathiepin-3-oxide.endo-5.

skin with deep pain.8% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. analgesia.Gr: 1. Ethrane® Exposure Limits: Measurement Methods NIOSH REL*: C 2 ppm (15. Eyes: Prevent eye contact Sol: Low Wash skin: N. aluminum.5 NIOSH Skin: Prevent skin contact BP: 242°F ¥: ScbaF:Pd.] OSHA 29. convuls.5 Skin: N.60 eV Change: N. CNS Swallow: Medical attention immed Enflurane Epichlorohydrin Conversion: 1 ppm = 3. sweet odor.1.Gr(77°F): 1. resp depres Breath: Resp support TO: Eyes. Ing.R. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. 2-Chloro-1. particularly when hot.] Exposure Routes.2-trifluoroethyl difluoromethyl ether.2-trifluoroethane. 2-Chloropropylene oxide. Sp.78 mg/m3 Formula: CAS#: C3H5OCl 106-89-8 DOT: 2023 131P RTECS#: TX4900000 IDLH: Ca [75 ppm] Synonyms/Trade Names: 1-Chloro-2. [carc] TO: Eyes. zinc.1 mg/m3) [60-minute] (see Table 1): [*Note: REL for exposure to waste anesthetic gas. Abs.1. anes. kidneys. colorless liquid with a mild.E CAS#: RTECS#: IDLH: Formula: KN6800000 N.Pp:AScba Eyes: Prevent eye contact Sol: 7% Escape: GmFOvAg/ScbaE Wash skin: When contam Fl.R. strong acids. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 92. skin.R. Symptoms. nau. resp distress. Fl.0% LEL: 3. Skin: Soap wash immed Breath: Resp support cough. resp sys.P: 93°F Remove: When wet (flamm) IP: 10. certain salts. cyan. Target Organs (see Table 5): Eye: Irr immed ER: Inh.R.55 mg/m3 DOT: Synonyms/Trade Names: 2-Chloro-1-(difluoromethoxy)-1. Con Skin: Soap wash SY: Irrit eyes. BP: 134°F Not available. liver. vomit. 103 OSHA PEL: none Physical Description: Clear. CHF2OCF2CHClF 13838-16-9 Conversion: 1 ppm = 7. IP: ? Change: N. repro sys [in animals: nasal cancer] Swallow: Medical attention immed 128 . chloroform-like odor. γ-Chloropropylene oxide Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 1010 See Appendix A 3 OSHA 7 OSHA PEL†: TWA 5 ppm (19 mg/m ) [skin] Physical Description: Colorless liquid with a slightly irritating.P: NA Remove: N.Pp/SaF:Pd. abdom pain. caustics.52 VP: 175 mmHg FRZ: ? UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. CNS depres.18 Provide: Eyewash VP: 13 mmHg FRZ: -54°F Quick drench UEL: 21. Sp.3-epoxypropane. [inhalation anesthetic] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 184. water [Note: May polymerize in presence of strong acids and bases. Symptoms. repro effects. Ing. Con Eye: Irr immed SY: Irrit eyes.R.D.

Pp/SaF:Pd. and rubber.5 mg/m [skin] Physical Description: Yellow solid with an aromatic odor. iron [Note: May attack copper. resp sys.P: NA Remove: When wet or contam Escape: GmFOv100/ScbaE IP: ? Change: Daily Sp.96 eV Provide: Eyewash Sp. ammonia-like odor. anor. blood chol First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: NH2CH2CH2OH 141-43-5 KJ5775000 30 ppm Conversion: 1 ppm = 2. viscous liquid or solid (below 51°F) with an unpleasant. brass. lac.] Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 323.3 Skin: Prevent skin contact 5 mg/m3: Sa/ScbaF BP: ? Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam §: ScbaF:Pd.0% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.02 VP: 0. skin.4 mmHg FRZ: 51°F UEL: 23. O-Ethyl O-(4-nitrophenyl) phenylphosphonothioate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Abs.0003 mmHg Quick drench MLT: 97°F UEL: NA LEL: NA Incompatibilities and Reactivities: Strong oxidizers Noncombustible Solid EPN E Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Ing. Symptoms. cyan. lar spasm. CVS. chest tight. drow Breath: Resp support TO: Eyes. skin. head. rhin. CNS. convuls.Pp:AScba Fl. card irreg TO: Eyes. Con Skin: Water flush prompt SY: Irrit eyes. skin. 2-Hydroxyethylamine. Target Organs (see Table 5): ER: Inh. abdom cramps. salv. β-Aminoethyl alcohol.P: 186°F Change: Daily IP: 8. strong acids. resp sys. low BP. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 61. wheez. Monoethanolamine Exposure Limits: Measurement Methods NIOSH REL: TWA 3 ppm (8 mg/m3) (see Table 1): NIOSH 2007 ST 6 ppm (15 mg/m3) OSHA PEL†: TWA 3 ppm (6 mg/m3) Physical Description: Colorless.27 Provide: Eyewash VP(212°F): 0.CAS#: RTECS#: IDLH: Formula: 2104-64-5 TB1925000 5 mg/m3 C14H14O4NSP Conversion: DOT: Synonyms/Trade Names: Ethyl p-nitrophenyl benzenethionophosphonate. para.5% LEL(284°F): 3. Symptoms.Gr(77°F): 1.Pp/SaF:Pd. resp sys. Ethylolamine. Ing.5 mg/m3 [skin] 3 NIOSH 5012 OSHA PEL: TWA 0. skin. Con SY: Irrit eyes.1 30 ppm: CcrS*/GmFS/PaprS*/Sa*/ScbaF Eyes: Prevent eye contact BP: 339°F §: ScbaF:Pd. miosis. [pesticide] [Note: A brown liquid above 97°F. nau.Pp:AScba Wash skin: When contam Sol: Miscible Escape: GmFS/ScbaE Remove: When wet or contam Fl.50 mg/m DOT: 2491 153 Synonyms/Trade Names: 2-Aminoethanol. CNS Swallow: Medical attention immed Ethanolamine 3 129 .] Exposure Routes.Gr: 1. diarr.

[insecticide] [Note: A solid below 10°F. vomit. CVS.5 ppm (1.P: 110°F 500 ppm: Sa:Pd. liver. card irreg. 79 Physical Description: Colorless liquid with a sweet. salv. resp sys. CNS. The technical product has a very disagreeable odor. diarr. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.7% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.22 Provide: Eyewash VP: 0.P: 349°F Remove: When wet or contam IP: ? Change: Daily Sp. hemato sys Swallow: Medical attention immed 2-Ethoxyethanol 130 .Gr: 0. EGEE. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. abdom cramps. Ing. Skin: Water flush prompt Breath: Resp support lung damage. IP: ? §: ScbaF:Pd. skin. repro.0001% Wash skin: When contam Fl.8 mg/m3) [skin] (see Table 1): 3 OSHA PEL: TWA 200 ppm (740 mg/m ) [skin] NIOSH 1403 OSHA 53. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 90. Skin: Soap wash immed lass. alkalis Exposure Routes. resp sys. Abs. blurred vision. rhin. resp sys. odorless liquid.5 ppm: Sa:Cf* Wash skin: When contam Sol: Miscible 25 ppm: ScbaF/SaF Remove: When wet or contam Fl.O'.69 mg/m3 DOT: 1171 127 Synonyms/Trade Names: Cellosolve®. Ing. nau. skin. kidney. head. kidneys. Con SY: In animals: irrit eyes. blood chol Ethion Formula: CAS#: RTECS#: IDLH: C2H5OCH2CH2OH 110-80-5 KK8050000 500 ppm Conversion: 1 ppm = 3.S'-methylene di(phosphorodithioate) Exposure Limits: Measurement Methods NIOSH REL: 0. Conversion: DOT: Synonyms/Trade Names: O. dysp Breath: Resp support Swallow: Medical attention immed TO: Eyes. Symptoms.O.1 5 ppm: Sa* Eyes: Prevent eye contact BP: 275°F 12. liver.Pp* Change: N. Ethylene glycol monoethyl ether Exposure Limits: Measurement Methods NIOSH REL: TWA 0.Pp:AScba Sp. terato effects TO: Eyes. musc fasc.R. ether-like odor. Con Eye: Irr immed SY: Irrit eyes.E Formula: CAS#: RTECS#: IDLH: [(C2H5O)2P(S)S]2CH2 563-12-2 TE4550000 N.D.93 Escape: GmFOv/ScbaE VP: 4 mmHg FRZ: -130°F UEL(200°F): 15.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 384.5 Skin: Prevent skin contact BP: >302°F (Decomposes) Not available.0000015 mmHg FRZ: 10°F Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Acids. pleasant. Eyes: Prevent eye contact Sol: 0. miosis. dizz. Symptoms.Gr: 1. blood.Pp/SaF:Pd. repro sys.6% LEL(200°F): 1. chest tight. Abs. blood changes.O'-Tetraethyl S.4 mg/m3 [skin] (see Table 1): NIOSH 5600 OSHA PEL†: none Physical Description: Colorless to amber-colored.

strong oxidizers.Pp:AScba VP: 2 mmHg Escape: GmFOv/ScbaE FRZ: -79°F UEL: ? LEL: 1.1 2000 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 171°F Wash skin: When contam Sol(77°F): 10% GmFOv/ScbaF/SaF §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Ing. IP: ? ScbaF/SaF 500 ppm: Sa:Pd.P: 124°F Change: N. nose. in animals: Breath: Resp support repro. Ing. throat.90 VP: 73 mmHg FRZ: -117°F UEL: 11.7% Class II Combustible Liquid Incompatibilities and Reactivities: Nitrates.98 §: ScbaF:Pd.Pp* Sp. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. strong oxidizers. kidney damage. terato effects Swallow: Medical attention immed TO: Eyes. EGEEA. resp sys. fruity odor. nose. Acetic ether. vomit.R. alkalis & acids Exposure Routes.Pp/SaF:Pd. Symptoms.5 ppm (2. alkalis & acids Exposure Routes. derm Breath: Resp support TO: Eyes. Ethyl ethanoate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 400 ppm (1400 mg/m3) 3 NIOSH 1457 OSHA PEL: TWA 400 ppm (1400 mg/m ) OSHA 7 Physical Description: Colorless liquid with an ether-like. repro sys.Gr: 0. Ethyl ester of acetic acid.R. Abs.5 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 23% 25 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl.Formula: CAS#: RTECS#: IDLH: CH3COOCH2CH2OC2H5 111-15-9 KK8225000 500 ppm Conversion: 1 ppm = 5.41 mg/m3 DOT: 1172 129 Synonyms/Trade Names: Cellosolve® acetate.01 eV Sp. skin.Gr: 0. narco. Ethylene glycol monoethyl ether acetate.P: 24°F Escape: GmFOv/ScbaE Change: N.7 mg/m3) [skin] 3 NIOSH 1450 OSHA PEL: TWA 100 ppm (540 mg/m ) [skin] OSHA 53 Physical Description: Colorless liquid with a mild odor.5% LEL: 2.60 mg/m3 DOT: 1173 129 Synonyms/Trade Names: Acetic ester.Pp:AScba Remove: When wet (flamm) Fl.Pp/SaF:Pd. GI tract. resp sys Swallow: Medical attention immed 131 . Symptoms.0% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates. skin. Con Skin: Water flush prompt SY: Irrit eyes. 2-Ethoxyethyl acetate E Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 132. hemato sys Formula: CAS#: RTECS#: IDLH: CH3COOC2H5 141-78-6 AH5425000 2000 ppm [10%LEL] Conversion: 1 ppm = 3. Con Skin: Water flush prompt SY: Irrit eyes. para.2 5 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 313°F 12. Ethyl acetate Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 88. Glycol monoethyl ether acetate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. IP: 10.

09 mg/m3 DOT: 1917 129P (inhibited) Synonyms/Trade Names: Ethyl acrylate (inhibited). blood.Pp:AScba Eyes: Prevent eye contact BP: 211°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: 2% Remove: When wet (flamm) Fl. resp sys. vinous odor.4% Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers.Pp/SaF:Pd. chlorosulfonic acid [Note: Polymerizes readily unless an inhibitor such as hydroquinone is added. polymerizers. strong alkalis.79 VP: 44 mmHg FRZ: -173°F UEL: 19% LEL: 3. Cologne spirit. Symptoms.1 ¥: ScbaF:Pd. resp sys. liver. drow. liver Breath: Fresh air damage. peroxides. skin.Pp:AScba Wash skin: When contam Sol: Miscible Escape: ScbaE Remove: When wet (flamm) Fl.] Exposure Routes. terato effects Swallow: Medical attention immed TO: Eyes.47 eV Sp. head. cough. [carc] TO: Eyes. IP: 10.30 eV Provide: Eyewash Sp.P: 55°F Change: N.R. IP: 10.89 mg/m3 DOT: 1170 127 Synonyms/Trade Names: Alcohol. anemia.R.E Formula: CAS#: RTECS#: IDLH: CH2=CHCOOC2H5 140-88-5 AT0700000 Ca [300 ppm] Conversion: 1 ppm = 4. Ethyl ester of acrylic acid.92 VP: 29 mmHg Quick drench FRZ: -96°F UEL: 14% LEL: 1. Con Skin: Water flush immed SY: Irrit eyes. Ethyl propenoate Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 1450 See Appendix A 3 OSHA PEL†: TWA 25 ppm (100 mg/m ) [skin] OSHA 92 Physical Description: Colorless liquid with an acrid odor. skin.Pp/SaF:Pd. skin.P: 48°F Change: N. platinum.Gr: 0. moisture.1 3300 ppm: Sa/ScbaF Eyes: Prevent eye contact BP: 173°F §: ScbaF:Pd. ethereal. potassium dioxide. acetyl chloride.Gr: 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. bromine pentafluoride. skin. nose. resp sys [in animals: tumors of the forestomach] Breath: Resp support Swallow: Medical attention immed Ethyl acrylate Formula: CAS#: RTECS#: IDLH: CH3CH2OH 64-17-5 KQ6300000 3300 ppm [10%LEL] Conversion: 1 ppm = 1. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 100. EtOH. colorless liquid with a weak. narco. Symptoms. CNS. acetyl bromide. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. lass. Ing. Ing. repro sys 132 . Grain alcohol Exposure Limits: Measurement Methods NIOSH REL: TWA 1000 ppm (1900 mg/m3) (see Table 1): 3 NIOSH 1400 OSHA PEL: TWA 1000 ppm (1900 mg/m ) OSHA 100 Physical Description: Clear.3% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. Ethanol. Ethyl alcohol Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 46. sodium Exposure Routes. Abs. repro. Con Skin: Water flush prompt SY: Irrit eyes.

Escape: GmFOv/ScbaE IP: 8.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact (liquid) MW: 45. tin & zinc in presence of moisture. skin. derm Breath: Resp support TO: Eyes. 1002 OSHA PEL†: TWA 100 ppm (435 mg/m3) Physical Description: Colorless liquid with an aromatic odor. hypochlorites Exposure Routes.69 (Liquid) Quick drench (liquid) VP: 874 mmHg FRZ: -114°F UEL: 14. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed (liquid) ER: Inh. cellulose nitrate. skin. derm. Ethylamine (anhydrous).85 mg/m3 DOT: 1036 118 Synonyms/Trade Names: Aminoethane. IP: 8.Pp:AScba Change: N.61 Sp. copper. skin. [Note: Shipped as a liquefied compressed gas. skin.Gr: 0.2 800 ppm: CcrOv*/GmFOv/PaprOv*/ Eyes: Prevent eye contact BP: 277°F Wash skin: When contam Sol: 0. Ing.0% LEL: 3.5% Flammable Gas Incompatibilities and Reactivities: Strong acids. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 106.P: 55°F Change: N. skin burns.Pp Remove: When wet or contam (liquid) Fl.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Ing (liquid).Pp/SaF:Pd. narco.Pp/SaF:Pd.Formula: CAS#: RTECS#: IDLH: CH3CH2NH2 75-04-7 KH2100000 600 ppm Conversion: 1 ppm = 1.7% LEL: 0.87 VP: 7 mmHg FRZ: -139°F UEL: 6. Phenylethane Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (435 mg/m3) (see Table 1): 3 NIOSH 1501 ST 125 ppm (545 mg/m ) OSHA 7.R. head. Symptoms.01% Sa*/ScbaF Remove: When wet (flamm) §: ScbaF:Pd.Gr: 0.Pp:AScba Fl. Con (liquid) Skin: Water flush immed (liquid) SY: Irrit eyes. Monoethylamine Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (18 mg/m3) (see Table 1): 3 NIOSH S144 (II-3) OSHA PEL: TWA 10 ppm (18 mg/m ) OSHA 36 Physical Description: Colorless gas or water-white liquid (below 62°F) with an ammonia-like odor.P: 1°F §: ScbaF:Pd. muc memb. resp sys. Symptoms. resp sys.76 eV Sp.86 eV Escape: GmFS/ScbaE Provide: Eyewash (liquid) RGasD: 1. coma Breath: Resp support TO: Eyes. Abs (liquid).34 mg/m DOT: 1175 130 Synonyms/Trade Names: Ethylbenzol. strong oxidizers. Con Skin: Water flush prompt SY: Irrit eyes.R. resp sys Swallow: Medical attention immed (liquid) Ethylamine E Formula: CAS#: RTECS#: IDLH: CH3CH2C6H5 100-41-4 DA0700000 800 ppm [10%LEL] Conversion: 1 ppm = 4. chlorine.1 250 ppm: Sa:Cf£/PaprS£ Eyes: Prevent eye contact (liquid) BP: 62°F 500 ppm: CcrFS/GmFS/ScbaF/SaF Wash skin: When contam (liquid) Sol: Miscible 600 ppm: SaF:Pd. CNS Swallow: Medical attention immed Ethyl benzene 3 133 . Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.

46 mg/m3 DOT: 1891 131 Synonyms/Trade Names: Bromoethane. kidneys. Monobromoethane Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 200 ppm (890 mg/m ) NIOSH 1011 OSHA 7 Physical Description: Colorless to yellow liquid with an ether-like odor. 2553 OSHA PEL: TWA 50 ppm (230 mg/m ) OSHA 7 Physical Description: Colorless liquid with a powerful. IP: 9. pulm edema. resp sys.R. CVS. Ing. calcium.02 eV Escape: GmFOv/ScbaE Sp.0 2000 ppm: Sa/ScbaF Eyes: Prevent eye contact BP: 101°F §: ScbaF:Pd.Gr: 1. resp sys.46 VP: 375 mmHg FRZ: -182°F UEL: 8. head. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 114. [Note: A gas above 101°F. card arrest Swallow: Medical attention immed TO: Eyes.R. resp sys. CNS depres. powdered aluminum. IP: 10.82 VP: 4 mmHg FRZ: -38°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Oxidizers. Skin: Soap flush prompt Breath: Resp support kidney disease.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Chemically-active metals such as sodium. liver. potassium.Pp:AScba Wash skin: When contam Sol: 0. coma.Pp:AScba Change: N. muc memb. Symptoms.Pp/SaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact MW: 109. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Symptoms. narco. zinc & magnesium Exposure Routes. CNS Swallow: Medical attention immed Ethyl butyl ketone 134 . skin. skin. CNS Ethyl bromide Formula: CAS#: RTECS#: IDLH: CH3CH2CO[CH2]3CH3 106-35-4 MJ5250000 1000 ppm Conversion: 1 ppm = 4.67 mg/m3 DOT: 1224 127 Synonyms/Trade Names: Butyl ethyl ketone.Gr: 0.Pp/SaF:Pd. derm Breath: Resp support TO: Eyes. Ing.2 500 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 298°F 1000 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Wash skin: When contam Sol: 1% Remove: When wet or contam Fl. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. perchloric acid Exposure Routes. card arrhy.9% Escape: GmFOv/ScbaE Remove: When wet (flamm) Fl.E CAS#: RTECS#: IDLH: Formula: 74-96-4 KH6475000 2000 ppm CH3CH2Br Conversion: 1 ppm = 4.P: <4°F Change: N.P(oc): 115°F GmFOv/ScbaF/SaF §: ScbaF:Pd.0% LEL: 6. fruity odor. Con Skin: Water flush SY: Irrit eyes. skin. acetaldehyde.29 eV Sp. Con Eye: Irr immed SY: Irrit eyes. skin. liver. 3-Heptanone Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (230 mg/m3) (see Table 1): 3 NIOSH 1301.

Gr: 1. Symptoms. water or steam First Aid (see Table 6): Exposure Routes. ether-like odor. card arrest.5 7 ppm: Sa*/ScbaF Eyes: Prevent eye contact BP: 262°F §: ScbaF:Pd.R. powdered aluminum. dizz.20 VP: 5 mmHg Quick drench FRZ: -90°F UEL: 15. Sol: 0. abdom cramps.92 (Liquid at 32°F) VP: 1000 mmHg FRZ: -218°F UEL: 15. kidneys.9% LEL: 4. ether-like odor. vis dist. kidneys. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 80. Ing. liver. -58°F (Liquid) IP: 10. Ing (liquid). NIOSH 2519 See Appendix C (Chloroethanes) 3 OSHA PEL: TWA 1000 ppm (2600 mg/m ) Physical Description: Colorless gas or liquid (below 54°F) with a pungent. eyes Ethylene chlorohydrin 3 135 .4% LEL: 3. resp sys. Breath: Resp support kidney damage Swallow: Medical attention immed (liquid) TO: Liver.Pp:AScba Wash skin: When contam Sol: Miscible Escape: GmFOv/ScbaE Remove: When wet or contam Fl. 2-Chloroethyl alcohol. low BP. Con Skin: Water flush prompt (liquid) SY: Inco. liver. Ethylene chlorhydrin Exposure Limits: Measurement Methods NIOSH REL: C 1 ppm (3 mg/m3) [skin] (see Table 1): NIOSH 2513 OSHA PEL†: TWA 5 ppm (16 mg/m3) [skin] OSHA 7 Physical Description: Colorless liquid with a faint. collapse. CNS. calcium.23 Sp. Hydrochloric ether.5 3800 ppm: Sa*/ScbaF Eyes: Prevent eye contact (liquid) BP: 54°F §: ScbaF:Pd. [Note: Shipped as a liquefied compressed gas.R.] Exposure Routes. Symptoms.29 mg/m DOT: 1135 131 Synonyms/Trade Names: 2-Chloroethanol. CVS. inco.8% Flammable Gas Incompatibilities and Reactivities: Chemically-active metals such as sodium.97 eV RGasD: 2.9% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. liver. Monochloroethane. head. potassium. Breath: Resp support delirium. coma. zinc & magnesium.Pp/SaF:Pd. Abs. vomit. card arrhy.P: 140°F Change: N. Abs (liquid). CNS Ethyl chloride E Formula: CAS#: RTECS#: IDLH: CH2ClCH2OH 107-07-3 KK0875000 7 ppm Conversion: 1 ppm = 3.P: NA (Gas) Change: N. oxidizers.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact (liquid) MW: 64. inebri. thirst. numb. strong caustics.Pp:AScba Wash skin: N. Target Organs (see Table 5): Eye: Irr immed ER: Inh. nau.90 eV Provide: Eyewash Sp.6% Escape: GmFOv/ScbaE Remove: When wet (flamm) Fl.CAS#: RTECS#: IDLH: Formula: 75-00-3 KH7525000 3800 ppm [10%LEL] CH3CH2Cl Conversion: 1 ppm = 2.Pp/SaF:Pd.Gr: 0. Con Skin: Water flush immed SY: Irrit muc memb. Muriatic ether Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Handle with caution in the workplace. water or steam [Note: Reacts with water to form hydrochloric acid. shock. IP: 10.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed (liquid) ER: Inh.64 mg/m3 DOT: 1037 115 Synonyms/Trade Names: Chloroethane. kidney damage Swallow: Medical attention immed TO: Resp sys. CVS.

1.045 ppm OSHA 2 C 0. Ethylene bromide.69 mg/m DOT: 1605 154 Synonyms/Trade Names: 1. §: ScbaF:Pd. [fumigant] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 187. skin.Pp/SaF:Pd. liver.45 eV Remove: When wet or contam Sp. Con Skin: Water flush immed SY: Irrit nose. derm with vesic.E Formula: CAS#: RTECS#: IDLH: NH2CH2CH2NH2 107-15-3 KH8575000 1000 ppm Conversion: 1 ppm = 2. Noncombustible Liquid strong oxidizers First Aid (see Table 6): Exposure Routes. Ing.60 eV Change: N. calcium.] First Aid (see Table 6): Exposure Routes.P: NA Wash skin: When contam IP: 9. heart.13 ppm [15-minute] See Appendix A OSHA PEL: TWA 20 ppm C 30 ppm 50 ppm [5-minute maximum peak] Physical Description: Colorless liquid or solid (below 50°F) with a sweet odor.Pp:AScba Sol: 0. asthma. [fungicide] OSHA 60 [Note: A solid below 47°F.2-Dibromoethane.Pp IP: 8. skin. repro sys [in animals: skin & lung tumors] Ethylene dibromide 3 136 . potassium.5% & other chlorinated organic compounds.91 Provide: Eyewash (>5%) Escape: GmFS/ScbaE VP: 11 mmHg Quick drench FRZ: 47°F UEL(212°F): 12% Incompatibilities and Reactivities: Strong acids & oxidizers.Pp:AScba Sp. spleen. resp sys.2-Ethanediamine. kidneys Swallow: Medical attention immed Ethylenediamine CAS#: RTECS#: IDLH: Formula: 106-93-4 KH9275000 Ca [100 ppm] BrCH2CH2Br Conversion: 1 ppm = 7.46 mg/m3 DOT: 1604 132 Synonyms/Trade Names: 1. Abs. liquid ammonia. sens derm. kidney damage Breath: Resp support TO: Skin. Symptoms. repro effects. Breath: Resp support kidney damage.2-Diaminoethane. resp sys.Pp/SaF:Pd.R. Ethylenediamine (anhydrous) Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (25 mg/m3) (see Table 1): 3 NIOSH 2540 OSHA PEL: TWA 10 ppm (25 mg/m ) Physical Description: Colorless.Gr: 0. Con Skin: Soap wash immed SY: Irrit eyes.P: 93°F Remove: When wet (flamm) ScbaF/SaF 1000 ppm: SaF:Pd.1 Skin: Prevent skin contact 250 ppm: Sa:Cf£/PaprS£ BP: 241°F Eyes: Prevent eye contact 500 ppm: CcrFS/GmFS/PaprTS£/ Sol: Miscible Wash skin: When contam/Daily Fl.9 (see Table 2): NIOSH BP: 268°F Skin: Prevent skin contact ¥: ScbaF:Pd. liver.] Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 60. hot aluminum & magnesium. carbon disulfide Class IC Flammable Liquid [Note: Corrosive to metals.R. Glycol dibromide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1008 TWA 0. resp sys. kidneys. Abs. Target Organs (see Table 5): Eye: Irr immed ER: Inh.Gr: 2. Symptoms. liver. VP: 12 mmHg Provide: Eyewash FRZ: 50°F Quick drench UEL: NA Incompatibilities and Reactivities: Chemically-active metals such as LEL: NA sodium. resp sys. [carc] Swallow: Medical attention immed TO: Eyes.17 Change: N. Ing. viscous liquid with an ammonia-like odor. Target Organs (see Table 5): Eye: Irr immed ER: Inh. carbon tetrachloride LEL(212°F): 2.4% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. liver.

liver. Monoethylene glycol Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): OSHA PEL†: none NIOSH 5523 OSHA PV2024 Physical Description: Clear.3% potassium permanganate. [carc] Swallow: Medical attention immed TO: Eyes.CAS#: RTECS#: IDLH: Formula: 107-06-2 KI0525000 Ca [50 ppm] ClCH2CH2Cl Conversion: 1 ppm = 4. nau. colorless. corn opac.P: 56°F Wash skin: When contam IP: 11. Breath: Resp support kidney.9% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. nau. syrupy. chloroform-like odor. chromium trioxide. chemicallyLEL: 6. CNS depres. throat.Gr: 1. liver. Target Organs (see Table 5): ER: Inh. Ethylene chloride. Glycol alcohol. skin sens TO: Eyes. skin.2-Dichloroethane.] Class IIIB Combustible Liquid Ethylene glycol Exposure Routes. CVS damage. becomes acidic & darkens in color. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. CVS [in animals: forestomach. sodium & potassium. CNS. CNS depres. nose. Ing.24 Change: N. Con Skin: Soap wash prompt SY: Irrit eyes. vomit. [Note: Decomposes slowly.05 eV Remove: When wet (flamm) Sp. Sol: Miscible Eyes: Prevent eye contact Fl.1 (see Table 2): BP: 388°F Skin: Prevent skin contact Not available.05 mg/m3 DOT: 1184 131 Synonyms/Trade Names: 1.0 (see Table 2): NIOSH BP: 182°F Skin: Prevent skin contact ¥: ScbaF:Pd. Ing. CNS First Aid (see Table 6): Eye: Irr immed Skin: Water wash immed Breath: Resp support Swallow: Medical attention immed 137 .] Exposure Routes. stupor. VP: 64 mmHg Provide: Eyewash FRZ: -32°F Quick drench UEL: 16% Incompatibilities and Reactivities: Strong oxidizers & caustics. kidneys. skin.2% active metals such as magnesium or aluminum powder. Symptoms. absorbs moisture from the air). abdom pain. Abs. Con SY: Irrit eyes. sodium peroxide LEL: 3. Class IB Flammable Liquid liquid ammonia [Note: Decomposes to vinyl chloride & HCl above 1112°F. Glycol.P: 232°F Wash skin: When contam IP: ? Remove: When wet or contam Sp. skin. dizz.e. vomit. mammary gland & circulatory sys cancer] Ethylene dichloride E CAS#: RTECS#: IDLH: Formula: 107-21-1 KW2975000 N.Pp/SaF:Pd.D. convuls. See Appendix C (Chloroethanes) OSHA PEL†: TWA 50 ppm C 100 ppm 200 ppm [5-minute maximum peak in any 3 hours] Physical Description: Colorless liquid with a pleasant.R. derm. UEL: 15. odorless liquid.2-Ethanediol.. [antifreeze] [Note: A solid below 9°F. resp sys. 1. Symptoms. Glycol dichloride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 1003 TWA 1 ppm (4 mg/m ) 3 OSHA 3 ST 2 ppm (8 mg/m ) See Appendix A. HOCH2CH2OH Conversion: DOT: Synonyms/Trade Names: 1.Gr: 1.Pp:AScba Sol: 0.2% [Note: Hygroscopic (i.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 99.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 62.06 mmHg FRZ: 9°F Incompatibilities and Reactivities: Strong oxidizers.11 Change: Daily VP: 0.2-Dihydroxyethane. lass.

76 mg/m DOT: 1185 131P (inhibited) Synonyms/Trade Names: Aminoethylene. CNS depres.05 mmHg Escape: GmFOv100/ScbaE FRZ: -8°F UEL: ? LEL: ? Explosive Liquid Incompatibilities and Reactivities: Acids.Pp/SaF:Pd. Dimethyleneimine. Symptoms. liver. dizz. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. head.Pp/SaF:Pd. Skin: Soap wash immed Breath: Resp support kidney damage.2 ppm (1 mg/m ) [skin] OSHA 43 Physical Description: Colorless to yellow. 1. throat.2-Ethanediol dinitrate. nau.P: 419°F 5 mg/m3: SaT:Cf*/ScbaF/SaF Change: Daily IP: ? 75 mg/m3: SaF:Pd.83 Change: Daily VP: 160 mmHg Provide: Eyewash FRZ: -97°F Quick drench UEL: 54. [carc] Swallow: Medical attention immed TO: Eyes. pulm edema. vomit. abdom pain. silver solder).8% Incompatibilities and Reactivities: Polymerizes explosively in presence of LEL: 3.g. Aziridine. vomit. dizz. liver. in animals: Swallow: Medical attention immed anemia. Con Skin: Soap wash immed SY: Throb head. odorless liquid.5 mg/m3: Sa:Cf* Remove: When wet (flamm) Fl.Pp:AScba VP: 0. CVS. skin.1 mg/m3 [skin] 3 NIOSH 2507 OSHA PEL†: C 0. angina.P: 12°F Wash skin: When contam/Daily IP: 9.22 mg/m3 DOT: Synonyms/Trade Names: EGDN. flush. hypotension. Con Eye: Irr immed SY: Irrit eyes. resp sys. delirium. methemo. [Note: Usually contains inhibitors to prevent polymerization.49 §: ScbaF:Pd. blood.Pp:AScba Sol: Miscible Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. nau. oily. Symptoms. kidney damage TO: Skin. Ethylenimine. skin sens.] Exposure Routes. Ing.3% acids [Note: Explosive silver derivatives may be formed with silver alloys Class IB Flammable Liquid (e. Target Organs (see Table 5): Eye: Irr immed ER: Inh. nose. Breath: Resp support palp. skin. Azirane. eye burns. alkalis First Aid (see Table 6): Exposure Routes. liver. kidneys [in animals: lung & liver tumors] Ethyleneimine 3 138 .E Formula: CAS#: RTECS#: IDLH: O2NOCH2CH2ONO2 628-96-6 KW5600000 75 mg/m3 Conversion: 1 ppm = 6.. Abs.20 eV Remove: When wet or contam See Appendix E (page 351) Sp. irrit skin.Pp Provide: Quick drench Sp. Nitroglycol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: ST 0. Ing.Gr: 1. Ethylene nitrate.1 1 mg/m3: Sa* Eyes: Prevent eye contact BP: 387°F Wash skin: When contam Sol: Insoluble 2. [Note: An explosive ingredient (60-80%) in dynamite along with nitroglycerine (40-20%).] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 43.1012] See Appendix B Physical Description: Colorless liquid with an ammonia-like odor. kidneys Ethylene glycol dinitrate CAS#: RTECS#: IDLH: Formula: 151-56-4 KX5075000 Ca [100 ppm] C2H5N Conversion: 1 ppm = 1. Dimethylenimine. Abs. Glycol dinitrate. Ethylimine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 3514 See Appendix A OSHA PEL: [1910.Gr: 0. Ethylene dinitrate. liver.1 (see Table 2): NIOSH BP: 133°F Skin: Prevent skin contact ¥: ScbaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 152.

EKG abnor. repro sys [in animals: liver.D. inco. Oxirane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 1614. Ing. skin. Target Organs (see Table 5): Eye: Irr immed ER: Inh.1 ppm (0. (liquid).Gr: 0. immed (liquid) leukemia] Ethylene oxide E Formula: CAS#: RTECS#: IDLH: C3H6N2S 96-45-7 NI9625000 Ca [N. terato effects. N. liver. [carc] Skin: Soap wash immed TO: Eyes.49 Sp. alkalis & oxidizers. goiter. repro sys [peritoneal cancer.18 mg/m ) 3 OSHA 30. IP: 10. drow. nose.P: 486°F Wash skin: When contam/Daily IP: 8. amine odor. resp sys. Con Eye: Irr immed SY: Irrit eyes. skin burns (liq or high vap conc). kidney damage TO: Eyes. crystalline solid with a faint. Con SY: Irrit eyes.P: NA (Gas) Wash skin: When contam (liquid) Escape: GmFS†/ScbaE Remove: When wet (flamm) -20°F (Liquid) Change: N. ETU.Pp:AScba Sol(86°F): 2% Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl.2 (see Table 2): NIOSH BP: 446-595°F Skin: Prevent skin contact ¥: ScbaF:Pd.56 eV See Appendix E (page 351) Provide: Quick drench (liquid) RGasD: 1. lass. Skin: Water flush immed Breath: Resp support pulm edema. 1. kidneys. repro effects. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 44. OSHA 95 See Appendix A Physical Description: White to pale-green.1 (see Table 2): NIOSH BP: 51°F Skin: Prevent skin contact (liquid) 5 ppm: GmFS†/ScbaF/SaF Sol: Miscible Eyes: Prevent eye contact (liquid) §: ScbaF:Pd.N-Ethylenethiourea. aluminum & tin. Swallow: Medical attention liquid: frostbite. vomit. 49. Ing.2-Epoxy ethane. thyroid & lymphatic sys Breath: Resp support Swallow: Medical attention immed tumors] Ethylene thiourea 139 .3-Ethylene-2-thiourea. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. peculiar taste.0% chlorides of iron.R.82 (Liquid at 50°F) VP: 1. liver.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 102. [carc]. skin.Gr: ? Change: Daily VP: 16 mmHg MLT: 392°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Acrolein Exposure Routes.15 eV Remove: When wet or contam Sp. LEL: 3. dysp. skin.CAS#: RTECS#: IDLH: Formula: 75-21-8 KX2450000 Ca [800 ppm] C2H4O Conversion: 1 ppm = 1. 2-Imidazolidine-2-thione Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca OSHA PEL: none NIOSH 5011 Use encapsulated form. water Flammable Gas First Aid (see Table 6): Exposure Routes. in animals: convuls. blood.Pp/SaF:Pd.Pp:AScba Fl. 3800 TWA <0.Pp/SaF:Pd.] Conversion: DOT: Synonyms/Trade Names: 1. oxides of iron & aluminum.1047] TWA 1 ppm 5 ppm [15-minute Excursion] Physical Description: Colorless gas or liquid (below 51°F) with an ether-like odor. cyan. 50 C 5 ppm (9 mg/m ) [10-min/day] See Appendix A OSHA PEL: [1910. eye. in animals: thickening of the skin.80 mg/m3 DOT: 1040 119P Synonyms/Trade Names: Dimethylene oxide. [Note: Used as an accelerator in the curing of polychloroprene & other elastomers. diarr. Symptoms. thyroid. CNS. Symptoms.46 atm FRZ: -171°F UEL: 100% Incompatibilities and Reactivities: Strong acids. nau. throat. head.

Sol: 8% Sa*/ScbaF §: ScbaF:Pd.R. Symptoms. Symptoms. Ing. excited.] Exposure Routes. resp sys. sulfur compounds [Note: Tends to form explosive peroxides under influence of air and light. sweetish odor.Pp/SaF:Pd.Pp/SaF:Pd. IP: 9. head. Ethyl methanoate Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (300 mg/m3) (see Table 1): 3 NIOSH 1452 OSHA PEL: TWA 100 ppm (300 mg/m ) OSHA 7 Physical Description: Colorless liquid with a fruity odor. in animals: narco Breath: Resp support TO: Eyes. Con Skin: Water flush immed SY: Irrit eyes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 74. CNS Ethyl ether Formula: CAS#: RTECS#: IDLH: CH3CH2OCHO 109-94-4 LQ8400000 1500 ppm Conversion: 1 ppm = 3.1 1500 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Eyes: Prevent eye contact BP: 130°F Wash skin: When contam Sol(64°F): 9% GmFOv/ScbaF/SaF §: ScbaF:Pd.1 1900 ppm: CcrOv*/GmFOv/PaprOv*/ Eyes: Prevent eye contact BP: 94°F Wash skin: N.Pp:AScba Remove: When wet (flamm) Fl.R.03 mg/m3 DOT: 1155 127 Synonyms/Trade Names: Diethyl ether. strong oxidizers.53 eV Sp. alkalis & acids [Note: Decomposes slowly in water to form ethyl alcohol and formic acid.P: -49°F Escape: GmFOv/ScbaE Change: N. upper resp sys. Con Eye: Irr immed SY: Irrit eyes. Ether.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact MW: 74. CNS Swallow: Medical attention immed Ethyl formate 140 . Ethyl oxide.R. IP: 10.Gr: 0.] Exposure Routes. Solvent ether Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 400 ppm (1200 mg/m ) NIOSH 1610 OSHA 7 Physical Description: Colorless liquid with a pungent.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates.E Formula: CAS#: RTECS#: IDLH: C2H5OC2H5 60-29-7 KI5775000 1900 ppm [10%LEL] Conversion: 1 ppm = 3. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Skin: Water wash prompt Breath: Resp support narco. nau.71 VP: 440 mmHg FRZ: -177°F UEL: 36.P: -4°F Escape: GmFOv/ScbaE Change: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.0% LEL: 2. resp sys. Diethyl oxide. vomit Swallow: Medical attention immed TO: Eyes.Gr: 0. halogens.Pp:AScba Remove: When wet (flamm) Fl.61 eV Sp. sulfur. dizz.0% LEL: 1. drow. Ing. [Note: A gas above 94°F. skin.9% Class IA Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers.03 mg/m3 DOT: 1190 129 Synonyms/Trade Names: Ethyl ester of formic acid. skin. upper resp sys.92 VP: 200 mmHg FRZ: -113°F UEL: 16.

Symptoms.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: 0. Ethyl sulfhydrate. Sp.P: -55°F Change: N. kidneys. Con Eye: Irr immed SY: Irrit muc memb.Formula: CAS#: RTECS#: IDLH: C9H12 16219-75-3 RB9450000 N. 5-Ethylidenebicyclo(2.P(oc): 101°F Remove: When wet or contam IP: ? Change: N.Pp:AScba VP: 442 mmHg Escape: GmFOv/ScbaE FRZ: -228°F UEL: 18.8% Class IA Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Reacts violently with calcium hypochlorite. cyan. Abs. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms. throat.] First Aid (see Table 6): Exposure Routes. Breath: Resp support Swallow: Medical attention immed kidney.] Exposure Routes. Mercaptoethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. skunk-like odor. Target Organs (see Table 5): Eye: Irr immed ER: Inh. narco Swallow: Medical attention immed TO: Eyes.Pp Sp.R. lass.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 62. IP: 9. ENB may be stabilized with tert-butyl catechol. liver. nau. 5-Ethylidene-2-norbornene [Note: Due to its reactivity. skin.92 mg/m3 DOT: Synonyms/Trade Names: ENB. Ing. Ing. head.D. [Note: A gas above 95°F. taste changes.Pp/SaF:Pd. in animals: inco.R. bone marrow effects TO: Eyes. resp sys.2.3 mg/m3) [15-minute] 3 NIOSH 2542 OSHA PEL†: C 10 ppm (25 mg/m ) Physical Description: Colorless liquid with a strong.5 ppm (1. vomit.2 Skin: Prevent skin contact BP: 298°F Not available. urogenital system. liver.54 mg/m DOT: 2363 129 Synonyms/Trade Names: Ethanethiol. liver. chemical pneu (aspir liquid).1 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 95°F 12. dysp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 120. bone marrow Ethylidene norbornene E CAS#: RTECS#: IDLH: Formula: 75-08-1 KI9625000 500 ppm CH3CH2SH Conversion: 1 ppm = 2. resp sys.1)hept-2-ene. in animals: liver.84 §: ScbaF:Pd. nau. olfactory.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 5 ppm (25 mg/m3) OSHA PEL†: none None available Physical Description: Colorless to white liquid with a turpentine-like odor. Conversion: 1 ppm = 4.90 VP: 4 mmHg FRZ: -112°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Oxygen [Note: ENB should be stored in a nitrogen atmosphere since it reacts with oxygen.Gr: 0. Skin: Soap wash immed Breath: Resp support kidney damage. nose.Gr: 0. head. skin. kidneys.0% LEL: 2. urogenital inj. CNS. blood Ethyl mercaptan 3 141 . Con Skin: Soap wash immed SY: Irrit eyes.7% 25 ppm: CcrFOv/GmFOv/SaT:Cf/PaprTOv/ Remove: When wet (flamm) Fl. cough.29 eV ScbaF/SaF 500 ppm: Sa:Pd. Eyes: Prevent eye contact Sol: ? Wash skin: Daily Fl.

pulm edema. kidney damage. strong oxidizers Exposure Routes.Pp:AScba Sp.] Exposure Routes. Ing. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. in animals: lac. kidneys. Symptoms. nose. Con SY: Irrit eyes. blue-gray Skin: Water flush prompt Breath: Resp support vision. dysp. resp sys.Pp:AScba Change: N.R. Symptoms.2 50 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 281°F 100 ppm: Sa:Cf*/PaprOv*/CcrFOv/ Wash skin: When contam Sol: Miscible Remove: When wet (flamm) Fl.N-Ethylmorpholine E Conversion: 1 ppm = 4.Pp/SaF:Pd.R. colored haloes Swallow: Medical attention immed TO: Eyes.52 mg/m3 DOT: 1292 129 Synonyms/Trade Names: Ethyl orthosilicate. IP: 9.Pp Change: N.Pp/SaF:Pd. vis dist: corn edema.90 VP: 6 mmHg Quick drench FRZ: -81°F UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Strong acids.3 100 ppm: Sa* Eyes: Prevent eye contact BP: 336°F 250 ppm: Sa:Cf* Wash skin: When contam Sol: Reacts 500 ppm: ScbaF/SaF Remove: When wet (flamm) Fl. liver. Tetraethyl silicate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (85 mg/m3) 3 NIOSH S264 (II-3) OSHA PEL†: TWA 100 ppm (850 mg/m ) Physical Description: Colorless liquid with a sharp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 115.Gr: 0. skin Ethyl silicate 142 . Tetraethoxysilane.93 Escape: GmFOv/ScbaE VP: 1 mmHg FRZ: -117°F UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. Con Eye: Irr immed SY: Irrit eyes. resp sys Formula: C4H8ONCH2CH3 DOT: CAS#: 100-74-3 RTECS#: QE4025000 IDLH: 100 ppm Formula: CAS#: RTECS#: IDLH: (C2H5)4SiO4 78-10-4 VV9450000 700 ppm Conversion: 1 ppm = 8. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 208.Gr: 0. IP: ? Escape: GmFOv/ScbaE Provide: Eyewash (>15%) Sp. Abs.P: 99°F 700 ppm: SaF:Pd. throat.77 eV §: ScbaF:Pd. liver. tremor. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Skin: Soap wash prompt Breath: Resp support narco. water [Note: Reacts with water to form a silicone adhesive (a milky-white mass).71 mg/m3 Synonyms/Trade Names: 4-Ethylmorpholine Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (23 mg/m3) [skin] (see Table 1): 3 NIOSH S146 (II-3) OSHA PEL†: TWA 20 ppm (94 mg/m ) [skin] Physical Description: Colorless liquid with an ammonia-like odor. blood. alcohol-like odor.P(oc): 90°F GmFOv/ScbaF/SaF §: ScbaF:Pd. anemia Swallow: Medical attention immed TO: Eyes. Ing. nose. Tetraethyl orthosilicate. Ethyl silicate (condensed).

Gr: 1.CAS#: RTECS#: IDLH: Formula: 22224-92-6 TB3675000 N. blurred vision. Breath: Resp support rhin. Symptoms. Eyes: Prevent eye contact Sol: 0. head.1 mg/m3 OSHA PEL†: none None available Physical Description: Brown liquid or yellow oil.03% Wash skin: When contam/Daily Fl. Con SY: Nau. blood chol Fenamiphos F Formula: CAS#: RTECS#: IDLH: C11H17O4PS2 115-90-2 TF3850000 N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. salv.4 Skin: Prevent skin contact BP: ? Not available. blood chol Fensulfothion 143 . CVS. blurred vision. Eyes: Prevent eye contact Sol(77°F): 0. miosis. Symptoms.P: ? Remove: When wet or contam IP: ? Change: Daily Sp. musc fasc. rhin. CVS. Sp. diarr. resp sys.00005 mmHg MLT: 121°F UEL: ? LEL: ? Incompatibilities and Reactivities: None reported [Note: May hydrolyze under alkaline conditions. card irreg. Abs. diarr. chest tight. dizz. nau. Ing. O. Phenamiphos Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. abdom cramps. head.Gr: 1. vomit. dysp Swallow: Medical attention immed TO: Resp sys. C13H22NO3PS Conversion: DOT: Synonyms/Trade Names: Ethyl 3-methyl-4-(methylthio)phenyl-(1-methylethyl)phosphoramidate.] Exposure Routes. CNS. dizz.R. musc fasc. card irreg. miosis.1 mg/m3 [skin] NIOSH 5600 OSHA PEL†: none Physical Description: Off-white to tan.4 Skin: Prevent skin contact BP: ? Not available.D. Con Skin: Soap flush immed SY: Irrit skin.D. Target Organs (see Table 5): Eye: Irr immed ER: Inh.O-Diethyl O-(p-methylsulfinyl)phenyl)phosphorothioate. vomit. lass. Conversion: DOT: Synonyms/Trade Names: Dasanit®. Nemacur®. [pesticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 308.14 Provide: Quick drench VP: 0. dys Swallow: Medical attention immed TO: Skin. abdom cramps.20 Provide: Eyewash VP: ? FRZ: ? Quick drench UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Alkalis First Aid (see Table 6): Exposure Routes. Skin: Soap flush immed Breath: Resp support chest tight.P: ? Remove: When wet or contam IP: ? Change: N.2% Wash skin: When contam Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 303. Terracur P® Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Ing. salv. CNS. [insecticide] [Note: Found commercially as a granular ingredient (5-15%) or in an emulsifiable concentrate (400 g/l). Abs. lass. waxy solid.

CVS.P: ? 250 mg/m3: Sa:Cf*/PaprHie* Change: Daily IP: 7.Gr: ? ScbaF/SaF VP: 0 mmHg (approx) 800 mg/m3: SaF:Pd. GI tract Swallow: Medical attention immed Ferbam 144 . garlic-like odor. C10H15O3PS Conversion: DOT: Synonyms/Trade Names: Baytex. Ferric dimethyl dithiocarbamate Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (see Table 1): 3 OSHA PEL†: TWA 15 mg/m NIOSH 0500 Physical Description: Dark brown to black. salv. lass.006% Wash skin: When contam Fl. Con Eye: Irr immed SY: Nau. odorless solid. diarr.Gr: 1. resp tract. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. O. vomit.Pp/SaF:Pd.0003 mmHg FRZ: 43°F UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes. musc fasc.Pp:AScba UEL: ? Escape: 100F/ScbaE LEL: ? 3 MEC: 55 g/m Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. resp sys. blurred vision. Ing. CNS.Pp MLT: >356°F (Decomposes) §: ScbaF:Pd. head. plasma chol Fenthion Formula: CAS#: RTECS#: IDLH: [(CH3)2NCS2]3Fe 14484-64-1 NO8750000 800 mg/m3 Conversion: DOT: Synonyms/Trade Names: tris(Dimethyldithiocarbamato)iron. Eyes: Prevent eye contact Sol: 0.25 VP: 0. Symptoms.5 50 mg/m3: Qm Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam 100 mg/m3: 95XQ*/Sa* Sol: 0.O-Dimethyl O-3-methyl-4-methylthiophenyl phosphorothioate Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): OSHA PEL†: none None available Physical Description: Colorless to brown liquid with a slight.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. [fungicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 416.3 Skin: Prevent skin contact BP: ? Not available. derm. Con Skin: Soap wash prompt SY: Irrit eyes. Ing. skin.01% Remove: When wet or contam Fl. miosis. GI dist Breath: Resp support TO: Eyes. moisture Exposure Routes. Symptoms. dizz. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. dysp Swallow: Medical attention immed TO: Resp sys. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 278. card irregularities.72 eV 500 mg/m3: 100F/SaT:Cf*/PaprTHie*/ Sp.D. Entex. abdom cramps. chest Skin: Soap flush immed Breath: Resp support tight. Abs. rhin.F CAS#: RTECS#: IDLH: Formula: 55-38-9 TF9625000 N.

R. Symptoms. Glass wool [Note: Usually produced from borosilicate & low alkali silicate glasses. Fiberglass. 50X REL: 100F/PaprTHie/ScbaF/SaF IP: NA Change: Daily 1000X REL: SaF:Pd. BP: ? 5 mg/m3: Qm* Eyes: N. Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.Pp:AScba LEL: NA Escape: 100F/ScbaE 3 MEC: 1. Target Organs (see Table 5): ER: Inh. resp sys.Pp/SaF:Pd. Con Breath: Resp support SY: Irrit eyes.8 NIOSH/OSHA Skin: N.P: NA 10 mg/m3: 95XQ*/Sa* Remove: N.R. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. dysp TO: Eyes. in animals: bron. nose. ID125G ST 3 mg/m [*Note: The REL also applies to Vanadium metal and Vanadium carbide. skin. resp sys First Aid (see Table 6): Eye: Irr immed Breath: Fresh air 145 .Gr: ? 50 mg/m3: 100F/SaT:Cf*/PaprTHie*/ VP: 0 mmHg (approx) ScbaF/SaF MLT: 2696-2768°F 500 mg/m3: SaF:Pd. glass filaments >3 µm in diameter or glass “wool” with diameters down to 0.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 106.R.Pp:AScba VP: 0 mmHg (approx) Escape: 100F/ScbaE MLT: ? UEL: NA LEL: NA Incompatibilities and Reactivities: None reported Noncombustible Fibers Exposure Routes. skin.R. Fl. pneu TO: Eyes. [Note: Ferrovanadium metal is an alloy usually containing 50-80% vanadium.R. Conversion: DOT: Synonyms/Trade Names: Fiber glas®.Pp Sp.5 µm in diameter & ≤ 10 µm in length) (see Table 1): NIOSH 7400 TWA 5 mg/m3 (total) OSHA PEL: TWA 15 mg/m3 (total) 3 TWA 5 mg/m (resp) Physical Description: Typically. but dust may be an explosion hazard.5 §: ScbaF:Pd. resp sys Formula: FeV DOT: CAS#: 12604-58-9 RTECS#: LK2900000 IDLH: 500 mg/m3 F Fibrous glass dust Formula: CAS#: RTECS#: LK3651000 IDLH: N. odorless particulate dispersed in air.05 µm & >1 µm in length. Glass fibers.] Exposure Limits: Measurement Methods NIOSH REL: TWA 3 fibers/cm3 (fibers ≤ 3. Sol: Insoluble Wash skin: N.Pp/SaF:Pd. IP: NA 25 mg/m3: Sa:Cf*/PaprHie* Change: N.3 g/m Metal: Noncombustible Solid.D. Sp.Gr: 2.] 3 OSHA PEL†: TWA 1 mg/m Physical Description: Dark. throat.R. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH MW: NA Skin: Prevent skin contact 5X REL: Qm BP: NA Eyes: Prevent eye contact 10X REL: 95XQ/Sa Sol: Insoluble Wash skin: Daily 25X REL: Sa:Cf/PaprHie Fl.P: NA Remove: N.Ferrovanadium dust Conversion: Synonyms/Trade Names: Ferrovanadium Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: TWA 1 mg/m3 3 OSHA ID121. Con SY: Irrit eyes.Pp UEL: NA §: ScbaF:Pd.

Ing. tremor.2 mg/m3) (see Table 1): 3 OSHA PEL: TWA 0. Trichlorofluoromethane.Fluorine F Conversion: 1 ppm = 1. powdered aluminum. Refrigerant 11. nearly odorless liquid or gas (above 75°F). resp sys. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 137. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact (liquid) MW: 38.Pp/SaF:Pd.74 Change: N. Con Skin: Water flush immed SY: Inco.P: NA Wash skin: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. CVS Swallow: Medical attention immed Fluorotrichloromethane 3 146 .70 eV §: ScbaF:Pd. organic compounds [Note: Reacts violently with all combustible materials.55 mg/m3 Synonyms/Trade Names: Fluorine-19 Exposure Limits: Measurement Methods NIOSH REL: TWA 0. resp sys.31 Escape: GmFS¿/ScbaE VP: >1 atm Quick drench (liquid) FRZ: -363°F UEL: NA LEL: NA Nonflammable Gas.1 ppm (0.47 (Liquid at 75°F) Provide: Eyewash VP: 690 mmHg Quick drench FRZ: -168°F UEL: NA LEL: NA Incompatibilities and Reactivities: Chemically-active metals such as Noncombustible Liquid sodium. skin. skin burns. in animals: liver. Con Skin: Water flush immed SY: Irrit eyes. Trichloromonofluoromethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 1000 ppm (5600 mg/m3) NIOSH 1006 OSHA PEL†: TWA 1000 ppm (5600 mg/m3) Physical Description: Colorless to water-white. Symptoms. nose.1% Eyes: Prevent eye contact §: ScbaF:Pd.Gr: 1.1 ppm (0. Target Organs (see Table 5): Eye: Irr immed ER: Inh.5 ppm: Sa:Cf* Wash skin: When contam (liquid) Sol: Reacts 5 ppm: ScbaF/SaF Remove: When wet or contam (liquid) Fl. lar spasm. Monofluorotrichloromethane. oxidizers. kidneys Formula: CAS#: RTECS#: F2 7782-41-4 LM6475000 DOT: 1045 124.Pp:AScba Provide: Eyewash (liquid) RGasD: 1. kidney damage TO: Eyes. potassium. but an extremely strong oxidizer. Reacts with H2O to form hydrofluoric acid. irritating odor. asphy.] Exposure Routes. calcium.Pp/SaF:Pd. except the metal containers in which it is shipped.P: NA 25 ppm: SaF:Pd. zinc.77 eV Remove: When wet or contam RGasD: 4. liver. card arrhy.R. liquid: frostbite Breath: Resp support TO: Skin. magnesium & lithium Nonflammable Gas shavings.R. pulm edema. IP: 15.0 1 ppm: Sa* Eyes: Prevent eye contact (liquid) BP: -307°F 2. nitric acid. card arrest. Breath: Resp support eye. Escape: GmFOv/ScbaE IP: 11. 9192 167 (cryogenic liquid) IDLH: 25 ppm CAS#: RTECS#: IDLH: Formula: 75-69-4 PB6125000 2000 ppm CCl3F Conversion: 1 ppm = 5.62 mg/m DOT: Synonyms/Trade Names: Freon® 11. Sp. Incompatibilities and Reactivities: Water.Pp:AScba Fl. derm.Pp Change: N. Symptoms.4 (see Table 2): NIOSH/OSHA BP: 75°F Skin: Prevent skin contact 2000 ppm: Sa/ScbaF Sol(75°F): 0. granular barium First Aid (see Table 6): Exposure Routes.2 mg/m ) None available Physical Description: Pale-yellow to greenish gas with a pungent. resp sys. wheez.

diarr. dysp Swallow: Medical attention immed TO: Resp sys.0002 mmHg FRZ: ? Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: None reported Exposure Routes. salv.3 mg/m3) [60-minute] (see Table 1): [*Note: REL for exposure to waste anesthetic gas.Gr: 1.P: ? Remove: N. convuls. Sp.D.2-Trifluoroethyl vinyl ether Exposure Limits: Measurement Methods NIOSH REL*: C 2 ppm (10. CNS Swallow: Medical attention immed Fluoroxene F Formula: CAS#: RTECS#: IDLH: C10H15OPS2 944-22-9 TA5950000 N. blurred vision.1 Skin: N. blood chol 147 . CNS.P: >201°F Remove: When wet or contam IP: ? Change: Daily Sp. card irreg.] None available OSHA PEL: none Physical Description: Liquid. IP: ? Change: N. Fl.07 mg/m3 DOT: Synonyms/Trade Names: Dyfonate®.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 126.R. Ing.R. Eyes: Prevent eye contact Sol: 0. CNS depres. Conversion: 1 ppm = 10. vomit. Fonophos Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.2.2-Trifluoroethoxyethene. abdom cramps. Conversion: 1 ppm = 5.15 Provide: Eyewash VP(77°F): 0. Symptoms. rhin. O-Ethyl-S-phenyl ethylphosphorothioate. Con SY: Nau. Symptoms. Ing. Abs.3 Skin: Prevent skin contact BP: ? Not available. 2.1 mg/m3 [skin] NIOSH 5600 OSHA PEL†: none OSHA PV2027 Physical Description: Light-yellow liquid with an aromatic odor.16 mg/m3 DOT: Synonyms/Trade Names: 2. head. Dyphonate. BP: 109°F Not available. Con Skin: Soap wash SY: Irrit eyes. [insecticide] Fonofos Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 246. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Gr: 1. Eyes: Prevent eye contact Sol: ? Wash skin: N. [inhalation anesthetic] [Note: A gas above 109°F.2. analgesia. dizz. Target Organs (see Table 5): Eye: Irr immed ER: Inh. miosis.R. Skin: Soap flush immed Breath: Resp support chest tight.R. musc fasc. anes. CVS.14 VP: 286 mmHg FRZ: ? UEL: ? LEL: ? Combustible Liquid [Potentially EXPLOSIVE!] Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes.D. lass. resp depres Breath: Resp support TO: Eyes.001% Wash skin: When contam Fl.Formula: CAS#: RTECS#: IDLH: CF3CH2OCH=CH2 406-90-6 KO4250000 N.

2541. 3800 TWA 0. suffocating odor.Pp:AScba Sol: Miscible Eyes: Prevent eye contact Escape: GmFS/ScbaE Fl. LEL: 7.75 ppm (see Table 1): NIOSH 2016. Symptoms. wheez. IP: 10. 2541. Symptoms. alkalis & acids.Pp:AScba BP: 214°F Eyes: Prevent eye contact Escape: GmFS/ScbaE Sol: Miscible Wash skin: When contam Fl.R.Pp/SaF:Pd.04 Change: N.R. resp sys [nasal cancer] Swallow: Medical attention immed 148 . derm. cough. resp sys [nasal cancer] Formaldehyde Formalin (as formaldehyde) Formula: CAS#: RTECS#: IDLH: Ca [20 ppm] Conversion: DOT: 1198 132. nose. 2209 132 Synonyms/Trade Names: Formaldehyde solution [Note: Formalin is an aqueous solution that is 37% formaldehyde by weight. urea [Note: Pure formaldehyde has a tendency to polymerize.016 ppm ST 2 ppm OSHA ID205.1048] TWA 0. throat.Pp/SaF:Pd. phenols.88 eV Remove: N.R. 52 C 0. anhydrides First Aid (see Table 6): Exposure Routes.08 Provide: Eyewash VP: 1 mmHg Quick drench FRZ: ? UEL: 73% LEL: 7% Incompatibilities and Reactivities: Strong oxidizers. 3500. wheez. cough. [Note: Often used in an aqueous solution (see specific listing for Formalin). alkalis & acids. 52 C 0. Target Organs (see Table 5): Eye: Irr immed ER: Inh.75 ppm ST 2 ppm Physical Description: Nearly colorless gas with a pungent. [carc] Breath: Resp support TO: Eyes. isocyanates.P: NA (Gas) Wash skin: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Sp. 3500. 3800 TWA 0. resp sys.R.] Flammable Gas Exposure Routes.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 30.0% Reacts with HCl to form bis-Chloromethyl ether. See Appendix E (page 351) RGasD: 1. inhibited solutions usually contain 6-12% methyl alcohol. oxides. Ing.R.016 ppm OSHA ID205. throat. VP: >1 atm FRZ: -134°F Incompatibilities and Reactivities: Strong oxidizers.P: 185°F Remove: When wet or contam See Appendix E (page 351) IP: ? Change: N. lac. Also see specific listings for Formaldehyde and Methyl alcohol. Methyl aldehyde. skin. [carc] TO: Eyes. UEL: 73% phenols. Methylene oxide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 2016. Class IIIA Combustible Liquid urea. caustics. nose. ¥: ScbaF:Pd.1048] TWA 0.1 ppm [15-minute] See Appendix A Physical Description: Colorless liquid with a pungent odor.F Formula: CAS#: RTECS#: IDLH: HCHO 50-00-0 LP8925000 Ca [20 ppm] Conversion: 1 ppm = 1.] Exposure Limits: Measurement Methods NIOSH REL: Ca OSHA PEL: [1910.0 (see Table 2): NIOSH BP: -6°F Skin: N. Con Breath: Resp support SY: Irrit eyes.Gr(77°F): 1. Con Skin: Water flush prompt SY: Irrit eyes.23 mg/m3 DOT: Synonyms/Trade Names: Methanal.1 ppm [15-minute] See Appendix A OSHA PEL: [1910. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH MW: Varies Skin: Prevent skin contact ¥: ScbaF:Pd. resp sys. lac.

lac.P(oc): 310°F Remove: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 45. cough.D. Sp. concentrated sulfuric acid [Note: Corrosive to metals. absorbs moisture from the air).Gr: 1. nau. [Note: A solid below 37°F. Sp. Hydrogen carboxylic acid.R.85 mg/m3 DOT: Synonyms/Trade Names: Carbamaldehyde. drow. penetrating odor. skin Skin: Water wash Breath: Resp support eruptions.05 eV SaF:Pd. throat. nau Swallow: Medical attention immed TO: Eyes. lead [Note: Hygroscopic (i. iodine. Fl. Ing. derm.1 mmHg FRZ: 37°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers. strong caustics. in animals: repro effects Swallow: Medical attention immed TO: Eyes.Formula: CAS#: RTECS#: IDLH: HCONH2 75-12-7 LQ0525000 N.13 VP(86°F): 0.. acidosis. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Eyes: Prevent eye contact Sol: Miscible Wash skin: N. skin.] Exposure Routes.R. Con Eye: Irr immed SY: Irrit eyes. copper. pyridine. sulfur trioxide. muc memb. resp sys Formic acid 149 . lass. skin burns. Con Eye: Irr immed SY: Irrit eyes. IP: 10.0 NIOSH/OSHA Skin: Prevent skin contact BP: 224°F (90% solution) 30 ppm: Sa*/ScbaF Eyes: Prevent eye contact Sol: Miscible §: ScbaF:Pd.20 eV Change: N.] Exposure Routes. BP: 411°F (Decomposes) Not available. [Note: Often used in an aqueous solution.R. Methanoic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (9 mg/m3) (see Table 1): 3 OSHA PEL: TWA 5 ppm (9 mg/m ) NIOSH 2011 OSHA ID186SG Physical Description: Colorless liquid with a pungent.R. skin. resp sys.88 mg/m3 DOT: 1779 153 Synonyms/Trade Names: Formic acid (85-95% in aqueous solution).22 (90% solution) Provide: Eyewash VP: 35 mmHg FRZ: 20°F (90% solution) Quick drench UEL: 57% (90% solution) LEL: 18% (90% solution) Class II Combustible Liquid (90% solution) Incompatibilities and Reactivities: Strong oxidizers.Gr: 1.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 46. Skin: Water flush immed Breath: Resp support dysp. Methanamide Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (15 mg/m3) [skin] (see Table 1): OSHA PEL†: none None available Physical Description: Colorless.R. Ing.Pp:AScba Escape: GmFOv100/ScbaE Change: N. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. repro sys Formamide F Formula: CAS#: RTECS#: IDLH: HCOOH 64-18-6 LQ4900000 30 ppm Conversion: 1 ppm = 1.1 Skin: N. rhin.P(oc): 122°F (90% solution) Remove: When wet or contam IP: 11.e. skin. Conversion: 1 ppm = 1. skin. CNS.Pp/ Wash skin: When contam Fl. brass. Symptoms. oily liquid.

2-Hydroxymethylfuran Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (40 mg/m3) [skin] 3 NIOSH 2505 ST 15 ppm (60 mg/m ) 3 OSHA PEL†: TWA 50 ppm (200 mg/m ) Physical Description: Colorless to amber liquid with a faint.Pp:AScba Change: N.13 VP(77°F): 0. Symptoms.93 mg/m3 DOT: 1199 132P Synonyms/Trade Names: Fural. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. IP: ? Provide: Quick drench Sp.1 50 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 323°F 100 ppm: Sa:Cf*/CcrFOv/PaprOv*/ Wash skin: When contam Sol: 8% Remove: When wet or contam Fl.21 eV Escape: GmFOv/ScbaE Sp.P: 149°F Escape: GmFOv/ScbaE Change: N.6 mmHg FRZ: 6°F UEL: 16. Ing. Abs. vomit. [Note: Darkens in light and air. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. strong alkalis [Note: May polymerize on contact with strong acids or strong alkalis.R. muc memb.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 98. skin. IP: 9. body Breath: Resp support temperature depres. upper resp sys. nau.P: 140°F GmFOv/ScbaF/SaF §: ScbaF:Pd. derm Breath: Resp support TO: Eyes. 2-Furancarboxaldehyde.3% LEL: 2. [Note: Darkens on exposure to light.Pp/SaF:Pd.] Exposure Routes.1 75 ppm: CcrOv*/GmFOv/PaprOv*/ Eyes: Prevent eye contact BP: 338°F Wash skin: When contam Sol: Miscible Sa*/ScbaF §: ScbaF:Pd. resp sys Swallow: Medical attention immed Furfural Formula: CAS#: RTECS#: IDLH: C5H6O2 98-00-0 LU9100000 75 ppm Conversion: 1 ppm = 4. oxidizers.1% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong acids.01 mg/m3 DOT: 2874 153 Synonyms/Trade Names: 2-Furylmethanol. burning odor. Symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact MW: 96. Con Skin: Water flush immed SY: Irrit eyes. diarr. 2-Furfuraldehyde Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 5 ppm (20 mg/m ) [skin] NIOSH 2529 OSHA 72 Physical Description: Colorless to amber liquid with an almond-like odor. skin. CNS Furfuryl alcohol 150 .3% LEL: 1. resp sys. Furfuraldehyde.F Formula: CAS#: RTECS#: IDLH: C5H4O2 98-01-1 LT7000000 100 ppm Conversion: 1 ppm = 3.Gr: 1.Pp/SaF:Pd. resp. head. dizz. Abs.Pp:AScba Remove: When wet or contam Fl.Gr: 1. Ing. Con Skin: Water flush prompt SY: Irrit eyes.8% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers & acids [Note: Contact with organic acids may lead to polymerization. skin.16 VP: 2 mmHg FRZ: -34°F UEL: 19. derm Swallow: Medical attention immed TO: Eyes. diuresis.] Exposure Routes.R.

Eyes: N. vomit. slurred speech. Ing.R. convuls.D. head. Symptoms. liver. head. Sol: Insoluble Wash skin: N. blurred vision.R. Natural gasoline. BP: -127°F Not available. Germanium hydride.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: GmFOv/ScbaE Wash skin: When contam Fl. RGasD: 2. kidney damage. chemical pneu (aspir liquid). dysp. [Note: Shipped as a compressed gas.6 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless gas with a pungent odor. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Motor spirits.] Exposure Limits: Measurement Methods NIOSH REL: TWA 0. blood Germanium tetrahydride 3 151 . lass. Incompatibilities and Reactivities: Bromine Exposure Routes.Gasoline Formula: CAS#: 8006-61-9 RTECS#: LX3300000 IDLH: Ca [N. Petrol [Note: A complex mixture of volatile hydrocarbons (paraffins. nitric acid & perchlorates First Aid (see Table 6): Exposure Routes.D.P: NA (Gas) Remove: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 110 (approx) NIOSH Skin: Prevent skin contact BP: 102°F ¥: ScbaF:Pd.] Conversion: 1 ppm = 4. kidneys [in animals: liver & kidney cancer] G Formula: CAS#: RTECS#: IDLH: GeH4 7782-65-2 LY4900000 N.5 mg/m3 (approx) DOT: 1203 128 Synonyms/Trade Names: Motor fuel. Breath: Resp support dizz. dizz. fainting.72-0. muc memb. CNS. IP: 11. kidneys. Abs. Con Skin: Soap flush immed SY: Irrit eyes.2 ppm (0. resp sys. hemolytic effects TO: CNS. Symptoms.] Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): OSHA PV2028 See Appendix A OSHA PEL†: none Physical Description: Clear liquid with a characteristic odor. Fl.Gr(60°F): 0.13 mg/m DOT: 2192 119 Synonyms/Trade Names: Germane. skin. kidney inj. skin.4% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers such as peroxides.6 Skin: N.P: -45°F Remove: When wet (flamm) IP: ? Change: N. nau. conf.R.R.76 Provide: Eyewash VP: 38-300 mmHg FRZ: ? Quick drench UEL: 7. Germanomethane. cycloparaffins & aromatics).R.R. Sp. [carc] TO: Eyes. Conversion: 1 ppm = 3.34 eV Change: N.65 VP: >1 atm FRZ: -267°F UEL: ? LEL: ? Flammable Gas (may ignite SPONTANEOUSLY in air). Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh SY: Mal.6% LEL: 1. Swallow: Medical attention immed possible liver. Monogermane [Note: Used chiefly for the production of high purity germanium for use in semiconductors. derm.Pp/SaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 76.

10 Provide: Eyewash VP: 17 mmHg FRZ: 7°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Strong oxidizers.R. absorbs moisture from the air). BP: 554°F (Decomposes) Not available.P: 320°F Remove: N. Symptoms.R.D. 0600 3 TWA 5 mg/m (resp) Physical Description: Clear.003 mmHg MLT: 64°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers (e. syrupy liquid or solid (below 64°F). derm. 1. skin. vomit.P: NA Remove: When wet or contam IP: ? Change: N. potassium permanganate) [Note: Hygroscopic (i. resp sys.R. OCH(CH2)3CHO 111-30-8 Conversion: 1 ppm = 4. amines.R.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 92. Target Organs (see Table 5): Eye: Irr immed ER: Inh. skin. odorless. potassium chlorate. resp sys Swallow: Medical attention immed Glutaraldehyde CAS#: RTECS#: IDLH: Formula: 56-81-5 MA8050000 N.8 mg/m3) (see Table 1): NIOSH 2532 See Appendix C (Aldehydes) OSHA 64 OSHA PEL†: none Physical Description: Colorless liquid with a pungent odor.2 ppm (0. cough. Sp.e.G CAS#: RTECS#: IDLH: Formula: MA2450000 N. Eyes: N. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. Sp. asthma.26 VP(122°F): 0. resp sys.1 Skin: N. nau. Symptoms. [Note: The solid form melts above 64°F but the liquid form freezes at a much lower temperature.. vomit Skin: Water flush immed Breath: Resp support TO: Eyes. Con SY: Irrit eyes. Con Skin: Water wash SY: Irrit eyes.1 Skin: Prevent skin contact BP: 212°F Not available.R. activated glutaraldehyde) react with alcohol. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 100. IP: ? Change: N. chromium trioxide. Glycyl alcohol.5-Pentanedial Exposure Limits: Measurement Methods NIOSH REL: C 0.e.Gr: 1.Gr: 1. Ing. sens skin. Abs. colorless.g.3-Propanetriol. 1. Sol: Miscible Wash skin: N. hydrazines & proteins. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.09 mg/m3 DOT: Synonyms/Trade Names: Glutaric dialdehyde. HOCH2CH(OH)CH2OH Conversion: DOT: Synonyms/Trade Names: Glycerin (anhydrous).R.. ketones. skin. resp sys. strong bases [Note: Alkaline solutions of glutaraldehyde (i. Trihydroxypropane Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 15 mg/m (total) NIOSH 0500. kidney inj Breath: Fresh air TO: Eyes. head. nau. Glycerol.] First Aid (see Table 6): Exposure Routes.D.2.] Exposure Routes. kidneys Glycerin (mist) 152 . skin. Fl..

lass. throat. Hydroxymethyl ethylene oxide. 2-Hydroxymethyl oxiran. head. abdom pain. Glycide.34 mg/m3 DOT: Synonyms/Trade Names: Cyanomethanol. Formaldehyde cyanohydrin. nose. Epoxypropyl alcohol. CVS Glycolonitrile 153 .1 20 ppm: Sa Eyes: Prevent eye contact BP: 361°F (Decomposes) 50 ppm: Sa:Cf Wash skin: When contam Sol: Soluble 100 ppm: ScbaF/SaF Remove: When wet or contam Fl.D. IP: ? Sp. skin. Breath: Resp support dysp. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. odorless. Glycidol Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 74.Pp/SaF:Pd.Gr: 1. convuls. resp sys. oily liquid.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 57. Con Skin: Water wash prompt SY: Irrit eyes.10 Escape: GmFOv/ScbaE VP(145°F): 1 mmHg Quick drench FRZ: <-98°F UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Traces of alkalis (promote violent polymerization) Exposure Routes. nau. dizz. Symptoms. narco Breath: Resp support TO: Eyes.P: 162°F Change: N. Symptoms. conf.9 mmHg FRZ: -49°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. Abs.1 150 ppm: Sa*/ScbaF Eyes: Prevent eye contact BP: 320°F (Decomposes) §: ScbaF:Pd. [Note: Forms cyanide in the body.Formula: CAS#: RTECS#: IDLH: C3H6O2 556-52-5 UB4375000 150 ppm Conversion: 1 ppm = 3. Hydroxyacetonitrile Exposure Limits: Measurement Methods NIOSH REL: C 2 ppm (5 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Colorless. skin.Pp Change: Daily IP: ? §: ScbaF:Pd. Glycolic nitrile.Pp/SaF:Pd. skin.12 VP(77°F): 0. Glyconitrile. Con Skin: Water wash immed SY: Irrit eyes.P: ? 250 ppm: SaF:Pd. CNS. resp sys. Ing.Pp:AScba Provide: Eyewash Sp. vomit Swallow: Medical attention immed TO: Eyes. resp sys.03 mg/m3 DOT: Synonyms/Trade Names: 2. CNS Swallow: Medical attention immed G CAS#: RTECS#: IDLH: Formula: 107-16-4 AM0350000 N.R.Pp:AScba Wash skin: When contam Sol: Miscible Escape: GmFOv/ScbaE Remove: When wet or contam Fl. 3-Hydroxypropylene oxide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 25 ppm (75 mg/m3) 3 NIOSH 1608 OSHA PEL†: TWA 50 ppm (150 mg/m ) OSHA 7 Physical Description: Colorless liquid. HOCH2CN Conversion: 1 ppm = 2.Gr(66°F): 1. nitrates Exposure Routes. skin. Ing. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.3-Epoxy-1-propanol.

greasy feeling. BP: Sublimes Wash skin: N.R.R. asthma. upper resp sys.25 ScbaF/SaF VP: 0 mmHg (approx) 1250 mg/m3: SaF:Pd. Sol: Insoluble 25 mg/m3: 95XQ/Sa Remove: N.P: NA 62. rhinitis. chronic obstructive pulm disease.0-2.] Exposure Limits: Measurement Methods NIOSH REL: TWA 2. skin.Pp/SaF:Pd. Con Breath: Fresh air SY: Cough.] Exposure Limits: Measurement Methods NIOSH REL: TWA 4 mg/m3 (see Table 1): 3 OSHA PEL: TWA 10 mg/m NIOSH 0500 Physical Description: Mixture of grain and all the other substances associated with its cultivation & harvesting.5 mg/m3 (resp) (see Table 1): NIOSH 0500. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: N. derm. Fl. conj. specific component of the grain Wash skin: N.R. wheat.0 12. Plumbago. chlorine trifluoride & potassium peroxide Exposure Routes.Gr: 2.R. wheez. dysp. Not available.5 mg/m3: Qm Eyes: N. Symptoms. pesticides & microorganisms.R. Target Organs (see Table 5): ER: Inh. and includes fertilizers. IP: NA 125 mg/m3: 100F/PaprTHie/SaT:Cf/ Sp. barley) Formula: CAS#: RTECS#: MD7900000 IDLH: N. Change: Daily Incompatibilities and Reactivities: None reported Exposure Routes. dysp. Properties depend upon the Eyes: N. Remove: N. Con SY: Irrit eyes.Grain dust (oat. grain fever TO: Eyes. skin. lung fib TO: Resp sys. Mineral carbon.Pp MLT: 6602°F (Sublimes) §: ScbaF:Pd. decr pulm func. Stove black [Note: Also see specific listing for Graphite (synthetic).R. odorless solid. black sputum. bron. dust. resp sys First Aid (see Table 6): Eye: Irr immed Breath: Fresh air Formula: CAS#: RTECS#: IDLH: C 7782-42-5 MD9659600 1250 mg/m3 Conversion: DOT: Synonyms/Trade Names: Black lead.D. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: Skin: N.R. MW: 12. CVS Graphite (natural) 154 .R. 0600 OSHA PEL†: TWA 15 mppcf Physical Description: Steel gray to black. cough.Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA Combustible Solid Incompatibilities and Reactivities: Very strong oxidizers such as fluorine.R. G Conversion: DOT: Synonyms/Trade Names: None [Note: Grain dust consists of 60-75% organic materials (cereal grains) & 25-40% inorganic materials (soil). Silver graphite. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.5 mg/m3: PaprHie/Sa:Cf Change: N.

32 Change: N. CVS Graphite (synthetic) G CAS#: RTECS#: IDLH: Formula: 13397-24-5 MG2360000 N. Artificial graphite [Note: Also see specific listing for Graphite (natural).R.R. Symptoms. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 172.D. Sol(77°F): 0.2% Eyes: N. Fl. BP: Sublimes Not available. Not available. greasy feeling.P: NA Remove: N.R. upper resp sys. Eyes: N.R.Gr: 2. VP: 0 mmHg (approx) MLT: 262-325°F (Loses H2O) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Aluminum (at high temperatures). odorless solid. Mineral white [Note: Gypsum is the dihydrate form of calcium sulfate.Gr: 1. Conversion: DOT: Synonyms/Trade Names: Acheson graphite. Con Breath: Fresh air SY: Cough. muc memb.R.D. 0600 3 TWA 5 mg/m (resp) Physical Description: Steel gray to black.2 (see Table 2): BP: ? Skin: N.Formula: CAS#: RTECS#: IDLH: C 7440-44-0 (synthetic) FF5250100 (synthetic) N. diazomethane First Aid (see Table 6): Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.P: NA Wash skin: N. IP: NA Change: N.0 Skin: N. skin. lung fib TO: Resp sys. Con SY: Irrit eyes.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 12. Gypsum stone.8 VP: 0 mmHg (approx) MLT: 6602°F (Sublimes) UEL: NA LEL: NA Combustible Solid Incompatibilities and Reactivities: Very strong oxidizers such as fluorine.R.R. cough. chlorine trifluoride & potassium peroxide Exposure Routes. dysp. Target Organs (see Table 5): Eye: Irr immed ER: Inh.R. sneez. Fl. resp sys Gypsum 155 . rhin Breath: Fresh air TO: Eyes. skin. black sputum. CaSO4×2H2O Conversion: DOT: Synonyms/Trade Names: Calcium(II) sulfate dihydrate. IP: NA Remove: N. Symptoms. Sp. crystalline solid. odorless.] Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 15 mg/m (total) NIOSH 0500. Sol: Insoluble Wash skin: N. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) TWA 5 mg/m3 (resp) Physical Description: White or nearly white.R. decr pulm func. Hydrated calcium sulfate.5-1. Plaster of Paris is the hemihydrate form.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500. Sp.

H

Formula: CAS#: RTECS#: IDLH: Hf 7440-58-6 MG4600000 50 mg/m3 (as Hf) Conversion: DOT: 1326 170 (powder, wet); 2545 135 (powder, dry) Synonyms/Trade Names: Celtium, Elemental hafnium, Hafnium metal Exposure Limits: Measurement Methods NIOSH REL*: TWA 0.5 mg/m3 (see Table 1): 3 NIOSH S194 (II-5) OSHA PEL*: TWA 0.5 mg/m OSHA ID121 [*Note: The REL and PEL also apply to other hafnium compounds (as Hf).] Physical Description: Highly lustrous, ductile, grayish solid. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Table 2): (see Tables 3 and 4): MW: 178.5 Skin: Prevent skin contact NIOSH/OSHA BP: 8316°F Eyes: Prevent eye contact 2.5 mg/m3: Qm Sol: Insoluble Wash skin: When contam/Daily Fl.P: NA 5 mg/m3: 95XQ/Sa Remove: When wet or contam IP: NA 12.5 mg/m3: Sa:Cf*/PaprHie* Change: Daily Sp.Gr: 13.31 25 mg/m3: 100F/SaT:Cf*/PaprTHie*/ Provide: Eyewash VP: 0 mmHg (approx) ScbaF/SaF MLT: 4041°F 50 mg/m3: SaF:Pd,Pp Quick drench UEL: NA §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba LEL: NA Escape: 100F/ScbaE Explosive in powder form (either dry or with <25% water); finely divided powder can be ignited by static electricity or even SPONTANEOUSLY. Incompatibilities and Reactivities: Strong oxidizers, chlorine Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash prompt SY: In animals: irrit eyes, skin, muc memb; liver damage Breath: Resp support TO: Eyes, skin, muc memb, liver Swallow: Medical attention immed

Hafnium

Formula: CAS#: RTECS#: IDLH: CF3CHBrCl 151-67-7 KH6550000 N.D. Conversion: 1 ppm = 8.07 mg/m DOT: Synonyms/Trade Names: 1-Bromo-1-chloro-2,2,2-trifluoroethane; 2-Bromo-2-chloro-1,1,1-trifluoroethane; 1,1,1-Trifluoro-2-bromo-2-chloroethane; 2,2,2-Trifluoro-1-bromo-1-chloroethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: C 2 ppm (16.2 mg/m3) [60-minute] OSHA 29 [*Note: REL for exposure to waste anesthetic gas.] OSHA PEL: none Physical Description: Clear, colorless liquid with a sweetish, pleasant odor. [inhalation anesthetic] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 197.4 Skin: Prevent skin contact BP: 122°F Not available. Eyes: Prevent eye contact Sol: 0.3% Wash skin: When contam Fl.P: NA Remove: When wet or contam IP: ? Change: N.R. Sp.Gr: 1.87 Provide: Eyewash VP: 243 mmHg FRZ: -180°F UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: May attack rubber & some plastics; sensitive to light. [Note: Light causes decomposition. May be stabilized with 0.01% thymol.] First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Abs, Ing, Con SY: Irrit eyes, skin, resp sys; conf, drow, dizz, nau, analgesia, anes; card Skin: Soap wash prompt Breath: Resp support arrhy; liver, kidney damage; decr audio-visual performance; in animals: Swallow: Medical attention immed repro effects TO: Eyes, skin, resp sys, CVS, CNS, liver, kidneys, repro sys

Halothane

3

156

Formula: CAS#: RTECS#: IDLH: C10H5Cl7 76-44-8 PC0700000 Ca [35 mg/m3] Conversion: DOT: 2761 151 (organochlorine pesticide, solid) Synonyms/Trade Names: 1,4,5,6,7,8,8-Heptachloro-3a,4,7,7a-tetrahydro-4,7-methanoindene Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH S287 (II-5) TWA 0.5 mg/m [skin] OSHA PV2029 See Appendix A 3 OSHA PEL: TWA 0.5 mg/m [skin] Physical Description: White to light-tan crystals with a camphor-like odor. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 373.4 ¥: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Eyes: Prevent eye contact BP: 293°F (Decomposes) Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: 0.0006% Remove: When wet or contam Fl.P: NA Change: Daily IP: ? Provide: Eyewash Sp.Gr: 1.66 VP(77°F): 0.0003 mmHg Quick drench MLT: 203°F UEL: NA LEL: NA Noncombustible Solid, but may be dissolved in flammable liquids. Incompatibilities and Reactivities: Iron, rust Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Soap wash immed SY: In animals: tremor, convuls; liver damage; [carc] Breath: Resp support TO: CNS,liver [in animals: liver cancer] Swallow: Medical attention immed

Heptachlor

H

Formula: CH3[CH2]5CH3 Conversion: 1 ppm = 4.10 mg/m DOT: 1206 128 Synonyms/Trade Names: Heptane, normal-Heptane Exposure Limits: NIOSH REL: TWA 85 ppm (350 mg/m3) C 440 ppm (1800 mg/m3) [15-minute] OSHA PEL†: TWA 500 ppm (2000 mg/m3) Physical Description: Colorless liquid with a gasoline-like odor. Personal Protection/Sanitation Chemical & Physical (see Table 2): Properties: Skin: Prevent skin contact MW: 100.2 Eyes: Prevent eye contact BP: 209°F Wash skin: When contam Sol: 0.0003% Remove: When wet (flamm) Fl.P: 25°F Change: N.R. IP: 9.90 eV Sp.Gr: 0.68 VP(72°F): 40 mmHg FRZ: -131°F UEL: 6.7% LEL: 1.05% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): ER: Inh, Ing, Con SY: Dizz, stupor, inco; loss of appetite, nau; derm; chemical pneu (aspir liquid); uncon TO: Skin, resp sys, CNS

n-Heptane

CAS#: 142-82-5

RTECS#: MI7700000

IDLH: 750 ppm

3

Measurement Methods (see Table 1): NIOSH 1500 OSHA 7 Respirator Recommendations (see Tables 3 and 4): NIOSH 750 ppm: CcrOv/GmFOv/PaprOv/ Sa/ScbaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Escape: GmFOv/ScbaE

First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed

157

H

CAS#: RTECS#: IDLH: Formula: 1639-09-4 MJ1400000 N.D. CH3[CH2]6SH Conversion: 1 ppm = 5.41 mg/m3 DOT: 1228 131 Synonyms/Trade Names: Heptyl mercaptan, n-Heptyl mercaptan Exposure Limits: Measurement Methods NIOSH REL: C 0.5 ppm (2.7 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Colorless liquid with a strong odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 132.3 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 351°F 12.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl.P: 115°F Change: N.R. IP: ? ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Sp.Gr: 0.84 Escape: GmFOv/ScbaE VP: ? FRZ: -46°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Oxidizers, reducing agents, strong acids & bases, alkali metals Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing, Con Eye: Irr immed SY: Irrit eyes, skin, nose, throat; lass, cyan, incr respiration, nau, Skin: Soap wash Breath: Resp support drow, head, vomit Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, blood

1-Heptanethiol

Formula: CAS#: RTECS#: IDLH: Cl2C=CClCCl=CCl2 87-68-3 EJ07000 Ca [N.D.] Conversion: 1 ppm = 10.66 mg/m3 DOT: 2279 151 Synonyms/Trade Names: HCBD; Hexachloro-1,3-butadiene; 1,3-Hexachlorobutadiene; Perchlorobutadiene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 2543 TWA 0.02 ppm (0.24 mg/m ) [skin] See Appendix A OSHA PEL†: none Physical Description: Clear, colorless liquid with a mild, turpentine-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 260.7 ¥: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Eyes: Prevent eye contact BP: 419°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: Insoluble Remove: When wet or contam Fl.P: ? Change: N.R. IP: ? Provide: Eyewash Sp.Gr: 1.55 VP: 0.2 mmHg Quick drench FRZ: -6°F UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Soap wash immed SY: In animals: irrit eyes, skin, resp sys; kidney damage; [carc] Breath: Resp support TO: Eyes, skin, resp sys, kidneys [in animals: kidney tumors] Swallow: Medical attention immed

Hexachlorobutadiene

158

Formula: CAS#: RTECS#: IDLH: C5Cl6 77-47-4 GY1225000 N.D. Conversion: 1 ppm = 11.16 mg/m3 DOT: 2646 151 Synonyms/Trade Names: HCCPD; Hexachloro-1,3-cyclopentadiene; 1,2,3,4,5,5-Hexachloro-1,3-cyclopentadiene; Perchlorocyclopentadiene Exposure Limits: Measurement Methods NIOSH REL: TWA 0.01 ppm (0.1 mg/m3) (see Table 1): NIOSH 2518 OSHA PEL†: none Physical Description: Pale-yellow to amber-colored liquid with a pungent, unpleasant odor. [Note: A solid below 16°F.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 272.8 Skin: Prevent skin contact BP: 462°F Not available. Eyes: Prevent eye contact Sol(77°F): 0.0002% (Reacts) Wash skin: When contam Fl.P: NA Remove: When wet or contam IP: ? Change: N.R. Sp.Gr: 1.71 Provide: Eyewash VP(77°F): 0.08 mmHg FRZ: 16°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Water, light [Note: Reacts slowly with water to form hydrochloric acid; will corrode iron & most metals in presence of moisture. Explosive hydrogen gas may collect in enclosed spaces in the presence of moisture.] First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Abs, Ing, Con SY: Irrit eyes, skin, resp sys; eye, skin burns; lac; sneez, cough, dysp, Skin: Soap flush immed Breath: Resp support salv, pulm edema; nau, vomit, diarr; in animals: liver, kidney inj Swallow: Medical attention immed TO: Eyes, skin, resp sys, liver, kidneys

Hexachlorocyclopentadiene

H

Formula: CAS#: RTECS#: IDLH: Cl3CCCl3 67-72-1 KI4025000 Ca [300 ppm] Conversion: 1 ppm = 9.68 mg/m DOT: Synonyms/Trade Names: Carbon hexachloride, Ethane hexachloride, Perchloroethane Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 1003 TWA 1 ppm (10 mg/m ) [skin] OSHA 7 See Appendix A See Appendix C (Chloroethanes) OSHA PEL: TWA 1 ppm (10 mg/m3) [skin] Physical Description: Colorless crystals with a camphor-like odor. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH MW: 236.7 Skin: Prevent skin contact ¥: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba BP: Sublimes Eyes: Prevent eye contact Escape: GmFOv/ScbaE Sol(72°F): 0.005% Wash skin: When contam/Daily Fl.P: NA Remove: When wet or contam IP: 11.22 eV Change: Daily Sp.Gr: 2.09 Provide: Eyewash VP: 0.2 mmHg Quick drench MLT: 368°F (Sublimes) UEL: NA Incompatibilities and Reactivities: Alkalis; metals such as zinc, cadmium, LEL: NA aluminum, hot iron & mercury Noncombustible Solid

Hexachloroethane

3

Exposure Routes, Symptoms, Target Organs (see Table 5): ER: Inh, Abs, Ing, Con SY: Irrit eyes, skin, muc memb; in animals: kidney damage; [carc] TO: Eyes, skin, resp sys, kidneys [in animals: liver cancer]

First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed

159

Hexachloronaphthalene

H

Conversion: Synonyms/Trade Names: Halowax® 1014 Exposure Limits: Measurement Methods NIOSH REL: TWA 0.2 mg/m3 [skin] (see Table 1): 3 NIOSH S100 (II-2) OSHA PEL: TWA 0.2 mg/m [skin] Physical Description: White to light-yellow solid with an aromatic odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 334.9 2 mg/m3: Sa*/ScbaF Eyes: Prevent eye contact BP: 650-730°F Wash skin: When contam/Daily Sol: Insoluble §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet or contam Fl.P: NA Escape: GmFOv/ScbaE Change: Daily IP: ? Sp.Gr: 1.78 VP: <1 mmHg MLT: 279°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Soap wash prompt SY: Acne-form derm, nau, conf, jaun, coma Breath: Resp support TO: Skin, liver Swallow: Medical attention immed

Formula: C10H2Cl6 DOT:

CAS#: 1335-87-1

RTECS#: QJ7350000

IDLH: 2 mg/m3

Formula: CAS#: RTECS#: IDLH: CH3[CH2]15SH 2917-26-2 N.D. Conversion: 1 ppm = 10.59 mg/m3 DOT: 1228 131 (liquid) Synonyms/Trade Names: Cetyl mercaptan, Hexadecanethiol-1, n-Hexadecanethiol, Hexadecyl mercaptan Exposure Limits: Measurement Methods NIOSH REL: C 0.5 ppm (5.3 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Colorless liquid or solid (below 64-68°F) with a strong odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 258.5 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: ? 12.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl.P: 215°F Change: Daily IP: ? ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Sp.Gr: 0.85 Escape: GmFOv/ScbaE VP: 0.1 mmHg FRZ: 64-68°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers, strong acids & bases, alkali metals, reducing agents Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con SY: Irrit eyes, skin, resp sys; head, dizz, lass, cyan, nau, convuls Skin: Soap wash immed Breath: Resp support TO: Eyes, skin, resp sys, CNS, blood Swallow: Medical attention immed

1-Hexadecanethiol

160

CAS#: RTECS#: IDLH: Formula: 684-16-2 UC2450000 N.D. (CF3)2CO Conversion: 1 ppm = 6.79 mg/m3 DOT: 2420 125 Synonyms/Trade Names: Hexafluoro-2-propanone; 1,1,1,3,3,3-Hexafluoro-2-propanone; HFA; Perfluoroacetone Exposure Limits: Measurement Methods NIOSH REL: TWA 0.1 ppm (0.7 mg/m3) [skin] (see Table 1): OSHA PEL†: none None available Physical Description: Colorless gas with a musty odor. [Note: Shipped as a liquefied compressed gas.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 166.0 (see Table 2): BP: -18°F Skin: Prevent skin contact/Frostbite Not available. Sol: Reacts Eyes: Prevent eye contact/Frostbite Fl.P: NA Wash skin: N.R. IP: 11.81 eV Remove: N.R. RGasD: 5.76 Change: N.R. VP: 5.8 atm Provide: Frostbite wash FRZ: -188°F UEL: NA LEL: NA Nonflammable Gas, but highly reactive Incompatibilities and Reactivities: Water, acids [Note: Hygroscopic (i.e., absorbs moisture from the air); reacts with with water & other substances, moisture to form a highly acidic sesquihydrate.] releasing heat. Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Con Eye: Frostbite SY: Irrit eyes, skin, muc memb, resp sys; pulm edema; liquid: Skin: Frostbite Breath: Resp support frostbite; in animals: terato, repro effects; kidney inj TO: Eyes, skin, resp sys, kidneys, repro sys

Hexafluoroacetone

H

Formula: CAS#: RTECS#: IDLH: OCN[CH2]6NCO 822-06-0 MO1740000 N.D. Conversion: 1 ppm = 6.88 mg/m DOT: 2281 156 Synonyms/Trade Names: 1,6-Diisocyanatohexane; HDI; Hexamethylene-1,6-diisocyanate; 1,6-Hexamethylene diisocyanate; HMDI Exposure Limits: Measurement Methods NIOSH REL: TWA 0.005 ppm (0.035 mg/m3) (see Table 1): NIOSH 5521, 5522, 5525 C 0.020 ppm (0.140 mg/m3) [10-minute] OSHA 42 OSHA PEL: none Physical Description: Clear, colorless to slightly yellow liquid with a sharp, pungent odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 168.2 0.05 ppm: Sa* Eyes: Prevent eye contact BP: 415°F 0.125 ppm: Sa:Cf* Wash skin: When contam Sol: Low (Reacts) 0.25 ppm: ScbaF/SaF Remove: When wet or contam Fl.P: 284°F 1 ppm: SaF:Pd,Pp Change: N.R. IP:? §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Provide: Eyewash Sp.Gr(77°F): 1.04 Escape: GmFOv/ScbaE VP(77°F): 0.5 mmHg Quick drench FRZ: -89°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Water, alcohols, strong bases, amines, carboxylic acids, organotin catalysts [Note: Reacts slowly with water to form carbon dioxide. Avoid heating above 392°F (polymerizes).] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing, Con Eye: Irr immed SY: Irrit eyes, skin, resp sys; cough, dysp, bron, wheez, pulm Skin: Soap flush immed Breath: Resp support edema, asthma; corn damage, skin blisters Swallow: Medical attention immed TO: Eyes, skin, resp sys

Hexamethylene diisocyanate
3

161

H

CAS#: RTECS#: IDLH: Formula: 680-31-9 TD0875000 Ca [N.D.] [(CH3)2N]3PO Conversion: DOT: Synonyms/Trade Names: Hexamethylphosphoric triamide, Hexamethylphosphorotriamide, HMPA, Tris(dimethylamino)phosphine oxide Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): See Appendix A None available OSHA PEL: none Physical Description: Clear, colorless liquid with an aromatic or mild, amine-like odor. [Note: A solid below 43°F.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 179.2 NIOSH Skin: Prevent skin contact BP: 451°F ¥: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Eyes: Prevent eye contact Sol: Miscible Escape: GmFOv/ScbaE Wash skin: When contam Fl.P: 220°F Remove: When wet or contam IP: ? Change: N.R. Sp.Gr: 1.03 Provide: Eyewash VP: 0.03 mmHg FRZ: 43°F Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers, strong acids, chemically-active metals (e.g., potassium, sodium, magnesium, zinc) Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Water flush immed SY: Irrit eyes, skin, resp sys; dysp; abdom pain; [carc] TO: Eyes, skin, resp sys, CNS, GI tract [in animals: cancer of the Breath: Resp support Swallow: Medical attention immed nasal cavity]

Hexamethyl phosphoramide

Formula: CAS#: RTECS#: IDLH: CH3[CH2]4CH3 110-54-3 MN9275000 1100 ppm [10%LEL] Conversion: 1 ppm = 3.53 mg/m DOT: 1208 128 Synonyms/Trade Names: Hexane, Hexyl hydride, normal-Hexane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 50 ppm (180 mg/m3) 3 NIOSH 1500, 3800 OSHA PEL†: TWA 500 ppm (1800 mg/m ) OSHA 7 Physical Description: Colorless liquid with a gasoline-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 86.2 500 ppm: Sa* Eyes: Prevent eye contact BP: 156°F 1100 ppm: Sa:Cf*/ScbaF/SaF Wash skin: When contam Sol: 0.002% §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet (flamm) Fl.P: -7°F Escape: GmFOv/ScbaE Change: N.R. IP: 10.18 eV Sp.Gr: 0.66 VP: 124 mmHg FRZ: -219°F UEL: 7.5% LEL: 1.1% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash immed SY: Irrit eyes, nose; nau, head; peri neur: numb extremities, Breath: Resp support musc weak; derm; dizz; chemical pneu (aspir liquid) Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, PNS

n-Hexane

3

162

Formula: CAS#: RTECS#: IDLH: C6H14 N.D. Conversion: 1 ppm = 3.53 mg/m3 DOT: 1208 128 Synonyms/Trade Names: Diethylmethylmethane; Diisopropyl; 2,2-Dimethylbutane; 2,3-Dimethylbutane; Isohexane; 2-Methylpentane; 3-Methylpentane [Note: Also see specific listing for n-Hexane.] Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (350 mg/m3) (see Table 1): 3 None available C 510 ppm (1800 mg/m ) [15-minute] OSHA PEL†: none Physical Description: Clear liquids with mild, gasoline-like odors. [Note: Includes all the isomers of hexane except n-hexane.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 86.2 1000 ppm: Sa* Eyes: Prevent eye contact BP: 122-145°F 2500 ppm: Sa:Cf* Wash skin: When contam Sol: Insoluble 5000 ppm: SaT:Cf*/ScbaF/SaF Remove: When wet (flamm) Fl.P: -54 to 19°F §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Change: N.R. IP: ? Escape: GmFOv/ScbaE Sp.Gr: 0.65-0.66 VP: ? FRZ: -245 to -148°F UEL: ? LEL: ? Class IB Flammable Liquids Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash immed SY: Irrit eyes, skin, resp sys; head, dizz; nau; chemical pneu Breath: Resp support (aspir liquid); derm Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS

Hexane isomers (excluding n-Hexane)

H

CAS#: RTECS#: IDLH: Formula: 111-31-9 MO4550000 N.D. CH3[CH2]5SH Conversion: 1 ppm = 4.83 mg/m DOT: 1228 131 Synonyms/Trade Names: 1-Hexanethiol, Hexyl mercaptan, n-Hexyl mercaptan, n-Hexylthiol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0.5 ppm (2.7 mg/m3) [15-minute] OSHA PEL: none None available Physical Description: Colorless liquid with an unpleasant odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 118.2 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 304°F 12.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) Fl.P: 68°F Change: N.R. IP: ? ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Sp.Gr: 0.84 Escape: GmFOv/ScbaE VP: ? FRZ: -113°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers, reducing agents, strong acids & bases, alkali metals Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con SY: Irrit eyes, skin, nose, throat; lass, cyan, incr respiration, nau, Skin: Soap wash immed Breath: Resp support drow, head, vomit Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, blood

n-Hexanethiol

3

163

Formula: CAS#: RTECS#: IDLH: CH3CO[CH2]3CH3 591-78-6 MP1400000 1600 ppm Conversion: 1 ppm = 4.10 mg/m3 DOT: Synonyms/Trade Names: Butyl methyl ketone, MBK, Methyl butyl ketone, Methyl n-butyl ketone Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (4 mg/m3) (see Table 1): 3 NIOSH 1300, 2555 OSHA PEL†: TWA 100 ppm (410 mg/m ) OSHA PV2031 Physical Description: Colorless liquid with an acetone-like odor.

2-Hexanone

H

Personal Protection/Sanitation Chemical & Physical (see Table 2): Properties: Skin: Prevent skin contact MW: 100.2 Eyes: Prevent eye contact BP: 262°F Wash skin: When contam Sol: 2% Remove: When wet (flamm) Fl.P: 77°F Change: N.R. IP: 9.34 eV Sp.Gr: 0.81 VP: 11 mmHg FRZ: -71°F UEL: 8% LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): ER: Inh, Abs, Ing, Con SY: Irrit eyes, nose; peri neur: lass, pares; derm; head, drow TO: Eyes, skin, resp sys, CNS, PNS

Respirator Recommendations (see Tables 3 and 4): NIOSH 10 ppm: Sa 25 ppm: Sa:Cf 50 ppm: SaT:Cf/ScbaF/SaF 1600 ppm: SaF:Pd,Pp §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Escape: GmFOv/ScbaE

First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed

Formula: CAS#: RTECS#: IDLH: CH3COCH2CH(CH3)2 108-10-1 SA9275000 500 ppm Conversion: 1 ppm = 4.10 mg/m3 DOT: 1245 127 Synonyms/Trade Names: Isobutyl methyl ketone, Methyl isobutyl ketone, 4-Methyl 2-pentanone, MIBK Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (205 mg/m3) (see Table 1): 3 NIOSH 1300, 2555 ST 75 ppm (300 mg/m ) 3 OSHA 1004 OSHA PEL†: TWA 100 ppm (410 mg/m ) Physical Description: Colorless liquid with a pleasant odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 100.2 500 ppm: CcrOv*/GmFOv/PaprTOv*/ Eyes: Prevent eye contact BP: 242°F Wash skin: When contam Sol: 2% Sa*/ScbaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet (flamm) Fl.P: 64°F Escape: GmFOv/ScbaE Change: N.R. IP: 9.30 eV Sp.Gr: 0.80 VP: 16 mmHg FRZ: -120°F UEL(200°F): 8.0% LEL(200°F): 1.2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers, potassium tert-butoxide Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing, Con Eye: Irr immed SY: Irrit eyes, skin, muc memb; head, narco, coma; derm; in Skin: Water flush prompt Breath: Resp support animals: liver, kidney damage Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, liver, kidneys

Hexone

164

Gr: 0. 2-Methylpentane-2. pleasant. head. CNS depres.P: 209°F Remove: When wet or contam IP: ? Change: N. strong oxidizers. dizz. Ing.4-pentanediol. Ing. skin.R. throat.Gr: 0. head.e. Conversion: 1 ppm = 4. nau. Escape: GmFOv/ScbaE IP: ? Sp.4-Dihydroxy-2-methylpentane. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 118. Sp. Con Eye: Irr immed SY: Irrit eyes.4-pentanediol.4-diol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 25 ppm (125 mg/m3) OSHA PV2101 OSHA PEL†: none Physical Description: Colorless liquid with a mild. Methylisoamyl acetate Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (300 mg/m3) (see Table 1): 3 NIOSH 1450 OSHA PEL: TWA 50 ppm (300 mg/m ) OSHA 7 Physical Description: Colorless liquid with a mild. sweetish odor. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl.] Exposure Routes. resp sys.2 Skin: Prevent skin contact BP: 388°F Not available. CNS Swallow: Medical attention immed sec-Hexyl acetate H Formula: CAS#: RTECS#: IDLH: (CH3)2COHCH2CHOHCH3 107-41-5 SA0810000 N.Pp/SaF:Pd.05 mmHg FRZ: -58°F (Sets to glass) UEL(est): 7. strong acids [Note: Hygroscopic (i.P: 113°F Change: N.. absorbs moisture from the air).92 Provide: Eyewash VP: 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 144.83 mg/m3 DOT: Synonyms/Trade Names: 2. fruity odor. resp sys.4% LEL(calc): 1. skin.2 500 ppm: CcrOv*/GmFOv/PaprOv*/ Eyes: Prevent eye contact BP: 297°F Wash skin: When contam Sol: 0. Con Skin: Water flush prompt SY: Irrit eyes. skin.3-Dimethylbutyl acetate.86 VP: 3 mmHg FRZ: -83°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Nitrates. Symptoms.08% Sa*/ScbaF Remove: When wet or contam §: ScbaF:Pd. skin. skin sens Swallow: Medical attention immed TO: Eyes.D. nose.Pp:AScba Fl.Formula: CAS#: RTECS#: IDLH: C8H16O2 108-84-9 SA7525000 500 ppm Conversion: 1 ppm = 5. 2-Methyl-2. Skin: Water wash immed Breath: Resp support derm.R. inco. alkalis & acids Exposure Routes.3% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. CNS Hexylene glycol 165 . Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. resp sys.90 mg/m3 DOT: 1233 130 Synonyms/Trade Names: 1. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. in animals: narco Breath: Resp support TO: Eyes. 4-Methyl-2. Symptoms.

R. [carc] TO: Eyes. oily.] First Aid (see Table 6): Exposure Routes. skin. Hydrazine (anhydrous). Con SY: Irrit eyes. hemato sys Swallow: Medical attention immed Hydrogenated terphenyls 3 166 . blood vessels & intestine] Hydrazine Formula: CAS#: RTECS#: IDLH: (C6Hn)3 61788-32-7 WZ6535000 N. [Note: A solid below 36°F.] Exposure Routes.009 (40% hydrogenated) VP: ? FRZ: ? UEL: ? LEL: ? Class IIIB Combustible Liquids Incompatibilities and Reactivities: None reported [Note: When heated. 2029 132 (>64% solution) Synonyms/Trade Names: Diamine. wood & cloth. skin burns. resp sys.03 ppm (0. liver. pale-yellow liquids with a faint odor. fuming. resp sys. hydrogen peroxide. dizz.Pp/SaF:Pd. oily liquid with an ammonia-like odor.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 32.003-1. in animals: bron.1 NIOSH Skin: Prevent skin contact BP: 236°F ¥: ScbaF:Pd.3 mg/m ) [skin] Physical Description: Colorless. nitric acid.93 eV Change: N. 3293 152 (≤ 37% solution).D. pulm edema. Hydrazine base Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 3503 C 0.04 mg/m ) [2-hour] OSHA 20. Abs.9% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers. Swallow: Medical attention immed convuls. resp sys. kidneys [in animals: tumors of the lungs.Gr(77°F): 1. kidneys. liver. Sp. skin.5 ppm (5 mg/m3) OSHA PEL†: none None available Physical Description: Clear. Conversion: 1 ppm = 12. Hydrogenated triphenyls [Note: Complex mixture of terphenyl isomers that are partially hydrogenated. CNS. irritating vapors will be released.P: 99°F Remove: When wet (flamm) IP: 8. nose.01 Provide: Eyewash VP: 10 mmHg FRZ: 36°F Quick drench UEL: 98% LEL: 2. Hydrogenated phenylbiphenyls.P: 315°F (40% hydrogenated) Remove: When wet or contam IP: ? Change: Daily Sp.H Formula: CAS#: RTECS#: IDLH: H2NNH2 302-01-2 MU7175000 Ca [50 ppm] DOT: 2029 132 (anhydrous). Conversion: 1 ppm = 1. Ing.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. temporary blindness. derm. Skin: Water flush immed Breath: Resp support eye. liver. Symptoms. kidney damage.Pp:AScba Eyes: Prevent eye contact Sol: Miscible Escape: ScbaE Wash skin: When contam Fl.31 mg/m3 2030 153 (37-64% solution). kidney. acids [Note: Can ignite SPONTANEOUSLY on contact with oxidizers or porous materials such as earth. metallic oxides. skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 108 See Appendix A 3 OSHA PEL†: TWA 1 ppm (1. Symptoms. liver. Ing. Con Skin: Soap wash immed SY: Irrit eyes. Target Organs (see Table 5): Eye: Irr immed ER: Inh. skin. throat. liver. nau.19 mg/m (40% hydrogenated) DOT: Synonyms/Trade Names: Hydrogenated diphenylbenzenes. [plasticizer/heat-transfer media] Personal Protection/Sanitation Respirator Chemical & Physical Properties: Recommendations (see Table 2): MW: 298 (40% hydrogenated) (see Tables 3 and 4): Skin: Prevent skin contact BP: 644°F (40% hydrogenated) Eyes: Prevent eye contact Sol: Insoluble Not available. hemato damage Breath: Resp support TO: Eyes. Wash skin: When contam Fl.Gr: 1.

Formula: CAS#: RTECS#: IDLH: HBr 10035-10-6 MW3850000 30 ppm Conversion: 1 ppm = 3.31 mg/m3 DOT: 1048 125 (anhydrous); 1788 154 (solution) Synonyms/Trade Names: Anhydrous hydrogen bromide; Aqueous hydrogen bromide (i.e., Hydrobromic acid) Exposure Limits: Measurement Methods NIOSH REL: C 3 ppm (10 mg/m3) (see Table 1): 3 NIOSH 7903 OSHA PEL†: TWA 3 ppm (10 mg/m ) OSHA ID165SG Physical Description: Colorless gas with a sharp, irritating odor. [Note: Shipped as a liquefied compressed gas. Often used in an aqueous solution.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact (solution)/Frostbite MW: 80.9 30 ppm: Sa:Cf£/PaprAg£/GmFAg/ Eyes: Prevent eye contact (solution)/Frostbite BP: -88°F Wash skin: When contam (solution) Sol: 49% ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet or contam (solution) Fl.P: NA Escape: GmFAg/ScbaE Change: N.R. IP: 11.62 eV Provide: Eyewash (liquid) RGasD: 2.81 VP: 20 atm Quick drench (solution) FRZ: -124°F Frostbite wash UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Strong oxidizers, strong caustics, moisture, copper, brass, zinc [Note: Hydrobromic acid is highly corrosive to most metals.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing (solution), Con Eye: Irr immed (solution)/Frostbite SY: Irrit eyes, skin, nose, throat; solution: eye, skin burns; liquid: Skin: Water flush immed (solution)/Frostbite Breath: Resp support frostbite Swallow: Medical attention immed (solution) TO: Eyes, skin, resp sys

Hydrogen bromide

H

Formula: CAS#: RTECS#: IDLH: HCl 7647-01-0 MW4025000 50 ppm Conversion: 1 ppm = 1.49 mg/m3 DOT: 1050 125 (anhydrous); 1789 157 (solution) Synonyms/Trade Names: Anhydrous hydrogen chloride; Aqueous hydrogen chloride (i.e., Hydrochloric acid, Muriatic acid) [Note: Often used in an aqueous solution.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 5 ppm (7 mg/m3) 3 NIOSH 7903 OSHA PEL: C 5 ppm (7 mg/m ) OSHA ID174SG Physical Description: Colorless to slightly yellow gas with a pungent, irritating odor. [Note: Shipped as a liquefied compressed gas.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: Skin: Prevent skin contact (solution)/Frostbite NIOSH/OSHA MW: 36.5 50 ppm: CcrS*/GmFS/PaprS*/ Eyes: Prevent eye contact/Frostbite BP: -121°F Wash skin: When contam (solution) Sol(86°F): 67% Sa*/ScbaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet or contam (solution) Fl.P: NA Escape: GmFAg/ScbaE Change: N.R. IP: 12.74 eV Provide: Eyewash (solution) RGasD: 1.27 VP: 40.5 atm Quick drench (solution) FRZ: -174°F Frostbite wash UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Hydroxides, amines, alkalis, copper, brass, zinc [Note: Hydrochloric acid is highly corrosive to most metals.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed (solution)/Frostbite ER: Inh, Ing (solution), Con SY: Irrit nose, throat, larynx; cough, choking; derm; solution: eye, Skin: Water flush immed (solution)/Frostbite Breath: Resp support skin burns; liquid: frostbite; in animals: lar spasm; pulm edema Swallow: Medical attention immed (solution) TO: Eyes, skin, resp sys

Hydrogen chloride

167

H

Formula: CAS#: RTECS#: IDLH: HCN 74-90-8 MW6825000 50 ppm DOT: 1051 117 (>20% solution); 1051 117 (anhydrous); Conversion: 1 ppm = 1.10 mg/m3 1613 154 (20% solution) Synonyms/Trade Names: Formonitrile, Hydrocyanic acid, Prussic acid Exposure Limits: Measurement Methods NIOSH REL: ST 4.7 ppm (5 mg/m3) [skin] (see Table 1): 3 OSHA PEL†: TWA 10 ppm (11 mg/m ) [skin] NIOSH 6010, 6017 Physical Description: Colorless or pale-blue liquid or gas (above 78°F) with a bitter, almond-like odor. [Note: Often used as a 96% solution in water.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 27.0 NIOSH Skin: Prevent skin contact BP: 78°F (96%) 47 ppm: Sa Eyes: Prevent eye contact Sol: Miscible 50 ppm: Sa:Cf/ScbaF/SaF Wash skin: When contam Fl.P: 0°F (96%) §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet (flamm) IP: 13.60 eV Escape: GmFS/ScbaE Change: N.R. Sp.Gr: 0.69 Provide: Eyewash VP: 630 mmHg FRZ: 7°F (96%) Quick drench UEL: 40.0% LEL: 5.6% Class IA Flammable Liquid Flammable Gas Incompatibilities and Reactivities: Amines, oxidizers, acids, sodium hydroxide, calcium hydroxide, sodium carbonate, caustics, ammonia [Note: Can polymerize at 122-140°F.] First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Abs, Ing, Con SY: Asphy; lass, head, conf; nau, vomit; incr rate and depth of respiration Skin: Water flush immed Breath: Resp support or respiration slow and gasping; thyroid, blood changes Swallow: Medical attention immed TO: CNS, CVS, thyroid, blood

Hydrogen cyanide

Formula: CAS#: RTECS#: IDLH: HF 7664-39-3 MW7875000 30 ppm Conversion: 1 ppm = 0.82 mg/m DOT: 1052 125 (anhydrous); 1790 157 (solution) Synonyms/Trade Names: Anhydrous hydrogen fluoride; Aqueous hydrogen fluoride (i.e., Hydrofluoric acid); HF-A Exposure Limits: Measurement Methods NIOSH REL: TWA 3 ppm (2.5 mg/m3) (see Table 1): 3 NIOSH 3800, 7902, 7903, C 6 ppm (5 mg/m ) [15-minute] OSHA PEL†: TWA 3 ppm 7906 OSHA ID110 Physical Description: Colorless gas or fuming liquid (below 67°F) with a strong, irritating odor. [Note: Shipped in cylinders.] Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 20.0 Skin: Prevent skin contact (liquid) 30 ppm: CcrS*/PaprS*/GmFS/ BP: 67°F Eyes: Prevent eye contact (liquid) Sol: Miscible Wash skin: When contam (liquid) Sa*/ScbaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Fl.P: NA Remove: When wet or contam (liquid) Escape: GmFS/ScbaE IP: 15.98 eV Change: N.R. RGasD: 1.86 Provide: Eyewash (liquid) Sp.Gr: 1.00 (Liquid at 67°F) Quick drench (liquid) VP: 783 mmHg FRZ: -118°F UEL: NA Incompatibilities and Reactivities: Metals, water or steam LEL: NA [Note: Corrosive to metals. Will attack glass and concrete.] Nonflammable Gas

Hydrogen fluoride

3

Exposure Routes, Symptoms, Target Organs (see Table 5): ER: Inh, Abs (liquid), Ing (solution), Con SY: Irrit eyes, skin, nose, throat; pulm edema; eye, skin burns; rhinitis; bron; bone changes TO: Eyes, skin, resp sys, bones

First Aid (see Table 6): Eye: Irr immed (solution/liquid) Skin: Water flush immed (solution/liquid) Breath: Resp support Swallow: Medical attention immed (solution)

168

Formula: CAS#: RTECS#: IDLH: H2O2 7722-84-1 MX0900000 75 ppm DOT: 2984 140 (8-20% solution); 2014 140 (20-60% solution); Conversion: 1 ppm = 1.39 mg/m3 2015 143 (>60% solution) Synonyms/Trade Names: High-strength hydrogen peroxide, Hydrogen dioxide, Hydrogen peroxide (aqueous), Hydroperoxide, Peroxide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 ppm (1.4 mg/m3) 3 OSHA ID126SG OSHA PEL: TWA 1 ppm (1.4 mg/m ) Physical Description: Colorless liquid with a slightly sharp odor. [Note: The pure compound is a crystalline solid below 12°F. Often used in an aqueous solution.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 34.0 NIOSH/OSHA Skin: Prevent skin contact BP: 286°F 10 ppm: Sa* Eyes: Prevent eye contact Sol: Miscible 25 ppm: Sa:Cf* Wash skin: When contam Fl.P: NA 50 ppm: ScbaF/SaF Remove: When wet or contam IP: 10.54 eV 75 ppm: SaF:Pd,Pp Change: N.R. Sp.Gr: 1.39 §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Provide: Eyewash VP(86°F): 5 mmHg Escape: GmFS/ScbaE FRZ: 12°F Quick drench UEL: NA LEL: NA Noncombustible Liquid, but a powerful oxidizer. Incompatibilities and Reactivities: Oxidizable materials, iron, copper, brass, bronze, chromium, zinc, lead, silver, manganese [Note: Contact with combustible material may result in SPONTANEOUS combustion.] First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Ing, Con Skin: Water flush immed SY: Irrit eyes, nose, throat; corn ulcer; eryt, vesic skin; bleaching hair Breath: Resp support TO: Eyes, skin, resp sys Swallow: Medical attention immed

Hydrogen peroxide

H

CAS#: RTECS#: IDLH: Formula: 7783-07-5 MX1050000 1 ppm H2Se Conversion: 1 ppm = 3.31 mg/m DOT: 2202 117 (anhydrous) Synonyms/Trade Names: Selenium dihydride, Selenium hydride Exposure Limits: Measurement Methods NIOSH REL: TWA 0.05 ppm (0.2 mg/m3) (see Table 1): OSHA PEL: TWA 0.05 ppm (0.2 mg/m3) None available Physical Description: Colorless gas with an odor resembling decayed horseradish. [Note: Shipped as a liquefied compressed gas.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Frostbite MW: 81.0 0.5 ppm: Sa Eyes: Frostbite BP: -42°F 1 ppm: Sa:Cf*/ScbaF/SaF Wash skin: N.R. Sol(73°F): 0.9% §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet (flamm) Fl.P: NA (Gas) Escape: GmFS¿/ScbaE Change: N.R. IP: 9.88 eV Provide: Frostbite wash RGasD: 2.80 VP(70°F): 9.5 atm FRZ: -87°F UEL: ? LEL: ? Flammable Gas Incompatibilities and Reactivities: Strong oxidizers, acids, water, halogenated hydrocarbons First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Frostbite ER: Inh, Con Skin: Frostbite SY: Irrit eyes, nose, throat; nau, vomit, diarr; metallic taste, garlic Breath: Resp support breath; dizz, lass; liquid: frostbite; in animals: pneu; liver damage TO: Eyes, resp sys, liver

Hydrogen selenide

3

169

H

CAS#: RTECS#: IDLH: Formula: 7783-06-4 MX1225000 100 ppm H2S Conversion: 1 ppm = 1.40 mg/m3 DOT: 1053 117 Synonyms/Trade Names: Hydrosulfuric acid, Sewer gas, Sulfuretted hydrogen Exposure Limits: Measurement Methods NIOSH REL: C 10 ppm (15 mg/m3) [10-minute] (see Table 1): NIOSH 6013 OSHA PEL†: C 20 ppm OSHA ID141 50 ppm [10-minute maximum peak] Physical Description: Colorless gas with a strong odor of rotten eggs. [Note: Sense of smell becomes rapidly fatigued & can NOT be relied upon to warn of the continuous presence of H2S. Shipped as a liquefied compressed gas.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Frostbite MW: 34.1 100 ppm: PaprS/GmFS/Sa*/ScbaF Eyes: Frostbite BP: -77°F §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Wash skin: N.R. Sol: 0.4% Escape: GmFS/ScbaE Remove: When wet (flamm) Fl.P: NA (Gas) Change: N.R. IP: 10.46 eV Provide: Frostbite wash RGasD: 1.19 VP: 17.6 atm FRZ: -122°F UEL: 44.0% LEL: 4.0% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers, strong nitric acid, metals First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Frostbite ER: Inh, Con Skin: Frostbite SY: Irrit eyes, resp sys; apnea, coma, convuls; conj, eye pain, lac, photo, corn vesic; dizz, head, lass, irrity, insom; GI dist; liquid: frostbite Breath: Resp support TO: Eyes, resp sys, CNS

Hydrogen sulfide

Formula: CAS#: RTECS#: IDLH: C6H4(OH)2 123-31-9 MX3500000 50 mg/m3 Conversion: DOT: 2662 153 Synonyms/Trade Names: p-Benzenediol; 1,4-Benzenediol; Dihydroxybenzene; 1,4-Dihydroxybenzene; Quinol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 2 mg/m3 [15-minute] 3 NIOSH 5004 OSHA PEL: TWA 2 mg/m OSHA PV2094 Physical Description: Light-tan, light-gray, or colorless crystals. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 110.1 NIOSH/OSHA Skin: Prevent skin contact BP: 545°F 50 mg/m3: PaprHie£/100F/SaT:Cf£/ Eyes: Prevent eye contact Sol: 7% Wash skin: When contam Fl.P: 329°F (Molten) ScbaF/SaF Remove: When wet or contam IP: 7.95 eV §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Change: Daily Sp.Gr: 1.33 Escape: 100F/ScbaE Provide: Eyewash (>7%) VP: 0.00001 mmHg MLT: 338°F UEL: ? LEL: ? Combustible Solid; dust cloud may explode if ignited in an enclosed area. Incompatibilities and Reactivities: Strong oxidizers, alkalis First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Ing, Con Skin: Water flush SY: Irrit eyes; conj; kera; CNS excitement; colored urine, nau, dizz, suffocation, rapid breath; musc twitch, delirium; collapse; skin irrit, sens, derm Breath: Resp support Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS

Hydroquinone

170

2-Hydroxypropyl acrylate
Conversion: 1 ppm = 5.33 mg/m3

Formula: CH2=CHCOOCH2CHOHCH3 DOT:

CAS#: 999-61-1

RTECS#: AT1925000

IDLH: N.D.

Synonyms/Trade Names: HPA, β-Hydroxypropyl acrylate, Propylene glycol monoacrylate Exposure Limits: Measurement Methods NIOSH REL: TWA 0.5 ppm (3 mg/m3) [skin] (see Table 1): OSHA PEL†: none None available Physical Description: Clear to light-yellow liquid wiith a sweetish, solvent odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 130.2 Skin: Prevent skin contact BP: 376°F Not available. Eyes: Prevent eye contact Sol: ? Wash skin: When contam Fl.P: 149°F Remove: When wet or contam IP: ? Change: N.R. Sp.Gr: 1.05 Provide: Eyewash VP: ? FRZ: ? Quick drench UEL: ? LEL: 1.8% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Water [Note: Can become unstable at high temperatures & pressures or may react with water with some release of energy, but not violently.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Soap flush immed SY: Irrit eyes, skin, resp sys; eye, skin burns; cough, dysp Breath: Resp support TO: Eyes, skin, resp sys Swallow: Medical attention immed

I

Indene

Conversion: 1 ppm = 4.75 mg/m3 Synonyms/Trade Names: Indonaphthene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (45 mg/m3) OSHA PEL†: none None available Physical Description: Colorless liquid. [Note: A solid below 29°F.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 116.2 Skin: Prevent skin contact BP: 359°F Not available. Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl.P: 173°F Remove: When wet or contam IP: 8.81 eV Change: N.R. Sp.Gr: 0.997 VP: ? FRZ: 29°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: None reported [Note: Polymerizes & oxidizes on standing. It has exploded during nitration with (H2SO4 + HNO3).] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing, Con Eye: Irr immed SY: In animals: irrit eyes, skin, muc memb; derm, skin sens; Skin: Soap wash Breath: Resp support chemical pneu (aspir liquid); liver, kidney, spleen inj Swallow: Medical attention immed TO: Eyes, skin, resp sys, liver, kidneys, spleen

Formula: C9H8 DOT:

CAS#: 95-13-6

RTECS#: NK8225000

IDLH: N.D.

171

Indium

I

Conversion: Synonyms/Trade Names: Indium metal Exposure Limits: Measurement Methods NIOSH REL*: TWA 0.1 mg/m3 (see Table 1): [*Note: The REL also applies to other indium compounds (as In).] NIOSH 7303, P&CAM173 (II-5) OSHA ID121 OSHA PEL†: none Physical Description: Ductile, shiny, silver-white metal that is softer than lead. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 114.8 Skin: N.R. BP: 3767°F Not available. Eyes: N.R. Sol: Insoluble Wash skin: N.R. Fl.P: NA Remove: N.R. IP: NA Change: N.R. Sp.Gr: 7.31 VP: 0 mmHg (approx) MLT: 314°F UEL: NA LEL: NA Noncombustible Solid in bulk form, but may ignite in powdered or dust form. Incompatibilities and Reactivities: (Dinitrogen tetraoxide + acetonitrile), mercury(II) bromide (at 662°F), sulfur (mixtures ignite when heated) [Note: oxidizes readily at higher temperatures.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing, Con Eye: Irr immed SY: Irrit eyes, skin, resp sys; possible liver, kidney, heart, blood Skin: Soap wash Breath: Resp support effects; pulm edema Swallow: Medical attention immed TO: Eyes, skin, resp sys, liver, kidneys, heart, blood

Formula: In DOT:

CAS#: 7440-74-6

RTECS#: NL1050000

IDLH: N.D.

Formula: CAS#: RTECS#: IDLH: I2 7553-56-2 NN1575000 2 ppm Conversion: 1 ppm = 10.38 mg/m3 DOT: Synonyms/Trade Names: Iodine crystals, Molecular iodine Exposure Limits: Measurement Methods NIOSH REL: C 0.1 ppm (1 mg/m3) (see Table 1): 3 NIOSH 6005 OSHA PEL: C 0.1 ppm (1 mg/m ) OSHA ID212 Physical Description: Violet solid with a sharp, characteristic odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 253.8 1 ppm: Sa* Eyes: Prevent eye contact BP: 365°F 2 ppm: Sa:Cf*/ScbaF/SaF Wash skin: When contam Sol: 0.01% §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet or contam Fl.P: NA Escape: GmFAg100/ScbaE Change: Daily IP: 9.31 eV Provide: Eyewash (>7%) Sp.Gr: 4.93 VP(77°F): 0.3 mmHg Quick drench (>7%) MLT: 236°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Ammonia, acetylene, acetaldehyde, powdered aluminum, active metals, liquid chlorine Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con SY: Irrit eyes, skin, nose; lac; head; chest tight; skin burns, rash; Skin: Soap wash immed Breath: Resp support cutaneous hypersensitivity Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, CVS

Iodine

172

Iodoform

Conversion: 1 ppm = 16.10 mg/m3 Synonyms/Trade Names: Triiodomethane Exposure Limits: Measurement Methods NIOSH REL: TWA 0.6 ppm (10 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Yellow to greenish-yellow powder or crystalline solid with a pungent, disagreeable odor. [antiseptic for external use] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 393.7 Skin: Prevent skin contact BP: 410°F (Decomposes) Not available. Eyes: Prevent eye contact Sol: 0.01% Wash skin: When contam Fl.P: NA Remove: When wet or contam IP: ? Change: Daily Sp.Gr: 4.01 VP: ? MLT: 246°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers, lithium, metallic salts (e.g., mercuric oxide, silver nitrate), strong bases, calomel, tannin Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con SY: Irrit eyes, skin; lass, dizz, nau, inco, CNS depres; dysp; liver, Skin: Soap wash immed Breath: Resp support kidney, heart damage; vis dist Swallow: Medical attention immed TO: Eyes, skin, resp sys, liver, kidneys, heart

Formula: CHI3 DOT:

CAS#: 75-47-8

RTECS#: PB7000000

IDLH: N.D.

I

RTECS#: CAS#: IDLH: NO7400000 1309-37-1 2500 mg/m3 (as Fe) NO7525000 (fume) Conversion: DOT: 1376 135 (spent) Synonyms/Trade Names: Ferric oxide, Iron(III) oxide Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 NIOSH 7300, 7301, 7303, 9102 OSHA PEL: TWA 10 mg/m OSHA ID121, ID125G Physical Description: Reddish-brown solid. [Note: Exposure to fume may occur during the arc-welding of iron.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: N.R. MW: 159.7 50 mg/m3: 95XQ/Sa Eyes: N.R. BP: ? Wash skin: N.R. Sol: Insoluble 125 mg/m3: Sa:Cf/PaprHie Remove: N.R. Fl.P: NA 250 mg/m3: 100F/SaT:Cf/PaprTHie/ Change: N.R. IP: NA ScbaF/SaF Sp.Gr: 5.24 2500 mg/m3: Sa:Pd,Pp VP: 0 mmHg (approx) §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba MLT: 2664°F Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Calcium hypochlorite Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh SY: Benign pneumoconiosis with X-ray shadows indistinguishable from fibrotic pneumoconiosis (siderosis) TO: Resp sys

Iron oxide dust and fume (as Fe)

Formula: Fe2O3

173

I

Formula: CAS#: RTECS#: IDLH: Fe(CO)5 13463-40-6 NO4900000 N.D. Conversion: 1 ppm = 2.28 mg/m3 (as Fe) DOT: 1994 131 Synonyms/Trade Names: Iron carbonyl, Pentacarbonyl iron Exposure Limits: Measurement Methods NIOSH REL: TWA 0.1 ppm (0.23 mg/m3) (see Table 1): 3 None available ST 0.2 ppm (0.45 mg/m ) OSHA PEL†: none Physical Description: Colorless to yellow to dark-red, oily liquid. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 195.9 Skin: Prevent skin contact BP(749 mmHg): 217°F Not available. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.P: 5°F Remove: When wet (flamm) IP: ? Change: N.R. Sp.Gr: 1.46-1.52 Provide: Quick drench VP(87°F): 40 mmHg FRZ: -6°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers, nitrogen oxide, (zinc + cobalt halides) [Note: Pyrophoric (i.e., ignites spontaneously in air). Decomposed by light or air, releasing carbon monoxide.] First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Soap flush immed SY: Irrit eyes, muc memb, resp sys; head, dizz, nau, vomit; fever, cyan, Breath: Resp support cough, dysp; liver, kidney, lung inj; degenerative changes in CNS Swallow: Medical attention immed TO: Eyes, resp sys, CNS, liver, kidneys

Iron pentacarbonyl (as Fe)

Iron salts (soluble, as Fe)

Formula:

CAS#:

RTECS#:

IDLH: N.D.

Conversion: DOT: Synonyms/Trade Names: FeSO4: Ferrous sulfate, Iron(II) sulfate; FeCl2: Ferrous chloride, Iron(II) chloride; Fe(NO3)3: Ferric nitrate, Iron(III) nitrate; Fe(SO4)3: Ferric sulfate, Iron(III) sulfate; FeCl3: Ferric chloride, Iron (III) chloride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 mg/m3 NIOSH 7300, 7301, 7303, 9102 OSHA PEL†: none Physical Description: Appearance and odor vary depending upon the specific OSHA ID121, ID125G soluble iron salt. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): Properties vary depending upon the Skin: Prevent skin contact Not available. specific soluble iron salt. Eyes: Prevent eye contact Wash skin: Daily Noncombustible Solids Remove: N.R. Change: Daily

Incompatibilities and Reactivities: Varies Exposure Routes, Symptoms, Target Organs (see Table 5): ER: Inh, Ing, Con SY: Irrit eyes, skin, muc memb; abdom pain, diarr, vomit; possible liver damage TO: Eyes, skin, resp sys, liver, GI tract First Aid (see Table 6): Eye: Irr immed Skin: Soap wash Breath: Resp support Swallow: Medical attention immed

174

Formula: CAS#: RTECS#: IDLH: CH3COOCH2CH2CH(CH3)2 123-92-2 NS9800000 1000 ppm Conversion: 1 ppm = 5.33 mg/m3 DOT: 1104 129 Synonyms/Trade Names: Banana oil, Isopentyl acetate, 3-Methyl-1-butanol acetate, 3-Methylbutyl ester of acetic acid, 3-Methylbutyl ethanoate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 100 ppm (525 mg/m3) 3 NIOSH 1450 OSHA PEL: TWA 100 ppm (525 mg/m ) OSHA 7 Physical Description: Colorless liquid with a banana-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 130.2 NIOSH/OSHA Skin: Prevent skin contact BP: 288°F 1000 ppm: CcrOv/PaprOv/GmFOv/ Eyes: Prevent eye contact Sol: 0.3% Wash skin: When contam Fl.P: 77°F Sa/ScbaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet (flamm) IP: ? Escape: GmFOv/ScbaE Change: N.R. Sp.Gr: 0.87 VP: 4 mmHg FRZ: -109°F UEL: 7.5% LEL(212°F): 1.0% Class IC Flammable Liquid Incompatibilities and Reactivities: Nitrates; strong oxidizers, alkalis & acids Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Water flush prompt SY: Irrit eyes, skin, nose, throat; derm; in animals: narco Breath: Resp support TO: Eyes, skin, resp sys, CNS Swallow: Medical attention immed

Isoamyl acetate

I

Formula: CAS#: RTECS#: IDLH: (CH3)2CHCH2CH2OH 123-51-3 EL5425000 500 ppm Conversion: 1 ppm = 3.61 mg/m3 DOT: 1105 129 Synonyms/Trade Names: Fermentation amyl alcohol, Fusel oil, Isobutyl carbinol, Isopentyl alcohol, 3-Methyl-1-butanol, Primary isoamyl alcohol Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (360 mg/m3) (see Table 1): 3 NIOSH 1402, 1405 ST 125 ppm (450 mg/m ) 3 OSHA PEL†: TWA 100 ppm (360 mg/m ) Physical Description: Colorless liquid with a disagreeable odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 88.2 500 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 270°F Wash skin: When contam Sol(57°F): 2% PaprOv£/ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet or contam Fl.P: 109°F Escape: GmFOv/ScbaE Change: N.R. IP: ? Sp.Gr(57°F): 0.81 VP: 28 mmHg FRZ: -179°F UEL(212°F): 9.0% LEL: 1.2% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Water flush prompt SY: Irrit eyes, skin, nose, throat; head, dizz; cough, dysp, nau, Breath: Resp support vomit, diarr; skin cracking; in animals: narco Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS

Isoamyl alcohol (primary)

175

RGasD: 2. head.Pp/SaF:Pd. dysp.4% LEL: 1. A liquid below 11°F.2 500 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 234°F Wash skin: When contam Sol: ? PaprOv£/ScbaF/SaF §: ScbaF:Pd. nau. Con Skin: Water flush prompt SY: Irrit eyes. narco. 1969 115 Synonyms/Trade Names: 2-Methylpropane [Note: Also see specific listing for n-Butane. Breath: Resp support vomit.g. in animals: narco Swallow: Medical attention immed TO: Eyes.D. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh.P(oc): 95°F Escape: GmFOv/ScbaE Change: N. chlorine. liquid: frostbite Breath: Resp support TO: CNS Isobutane 176 . skin.6% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers (e. nitrates & perchlorates). diarr. Secondary isoamyl alcohol Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (360 mg/m3) (see Table 1): 3 NIOSH 1402 ST 125 ppm (450 mg/m ) 3 OSHA PEL†: TWA 100 ppm (360 mg/m ) Physical Description: Colorless liquid with a disagreeable odor. Symptoms. Eyes: Frostbite Sol: Slight Wash skin: N.R. skin cracking. skin.82 VP: 1 mmHg FRZ: ? UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes..61 mg/m3 DOT: 1105 129 Synonyms/Trade Names: 3-Methyl-2-butanol.38 mg/m3 DOT: 1075 115.P: NA (Gas) Remove: When wet (flamm) IP: 10. [Note: Shipped as a liquefied compressed gas. IP: ? Sp. fluorine. Symptoms. asphy. Con (liquid) Skin: Frostbite SY: Drow. CNS Isoamyl alcohol (secondary) Formula: CAS#: RTECS#: IDLH: CH3CH(CH3)2 75-28-5 TZ4300000 N.1 Skin: Frostbite BP: 11°F Not available. Conversion: 1 ppm = 2.1 atm FRZ: -255°F UEL: 8. resp sys.74 eV Change: N. nose.Gr: 0.R. (nickel carbonyl + oxygen) Exposure Routes. Fl.Pp:AScba Remove: When wet (flamm) Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 58.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 800 ppm (1900 mg/m3) OSHA PEL†: none None available Physical Description: Colorless gas with a gasoline-like or natural gas odor. throat. Ing. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 88.R.06 Provide: Frostbite wash VP(70°F): 3. dizz. cough.I Formula: CAS#: RTECS#: IDLH: (CH3)2CHCH(OH)CH3 6032-29-7 SA4900000 500 ppm Conversion: 1 ppm = 3. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.

resp sys.03 mg/m3 DOT: 1212 129 Synonyms/Trade Names: IBA. floral odor.5% LEL: 1. IP: 10. Ing.R. strong oxidizers. Symptoms.80 Escape: GmFOv/ScbaE VP: 9 mmHg FRZ: -162°F UEL(202°F): 10. 2-Methylpropyl acetate. skin cracking. Isopropylcarbinol. Con SY: Irrit eyes. head. musty odor. head.Pp/SaF:Pd.12 eV ScbaF/SaF §: ScbaF:Pd. Isobutanol. Symptoms. Con SY: Irrit eyes. in animals: narco Skin: Water flush prompt Breath: Resp support TO: Eyes. β-Methylpropyl ethanoate Exposure Limits: Measurement Methods NIOSH REL: TWA 150 ppm (700 mg/m3) (see Table 1): 3 NIOSH 1450 OSHA PEL: TWA 150 ppm (700 mg/m ) OSHA 7 Physical Description: Colorless liquid with a fruity. Target Organs (see Table 5): Eye: Irr immed ER: Inh.R. Escape: GmFOv/ScbaE IP: 9. throat. CNS Swallow: Medical attention immed I Formula: CAS#: RTECS#: IDLH: (CH3)2CHCH2OH 78-83-1 NP9625000 1600 ppm Conversion: 1 ppm = 3.97 eV Sp. upper resp sys. skin.P: 64°F Change: N.Pp:AScba Sp. skin. anes.75 mg/m3 DOT: 1213 129 Synonyms/Trade Names: Isobutyl ester of acetic acid. oily liquid with a sweet. drow. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Isobutyl acetate Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 116.Gr: 0.6% PaprOv£/ScbaF/SaF Remove: When wet (flamm) §: ScbaF:Pd.Formula: CAS#: RTECS#: IDLH: CH3COOCH2CH(CH3)2 110-19-0 AI4025000 1300 ppm [10%LEL] Conversion: 1 ppm = 4. resp sys.6% LEL(123°F): 1.3% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates. 1405 OSHA 7 Physical Description: Colorless.2 1300 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 243°F Wash skin: When contam Sol(77°F): 0. 2-Methyl-1-propanol Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (150 mg/m3) (see Table 1): 3 OSHA PEL†: TWA 100 ppm (300 mg/m ) NIOSH 1401.1 500 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 227°F 1250 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 10% 1600 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet (flamm) Fl. skin.7% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers First Aid (see Table 6): Exposure Routes.Gr: 0.Pp:AScba Fl.87 VP: 13 mmHg FRZ: -145°F UEL: 10. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 74. skin. alkalis & acids First Aid (see Table 6): Exposure Routes.P: 82°F Change: N. drow. 2-Methylpropyl ester of acetic acid. CNS Swallow: Medical attention immed Isobutyl alcohol 177 . Ing.Pp/SaF:Pd. in animals: narco Skin: Water flush prompt Breath: Resp support TO: Eyes.

nose.I CAS#: RTECS#: IDLH: Formula: 78-82-0 TZ4900000 N.] Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (270 mg/m3) [skin] (see Table 1): OSHA PV2033 OSHA PEL†: none Physical Description: Clear. strong acids & bases Exposure Routes. abdom pain. Oxooctyl alcohol [Note: A mixture of closely related isomeric. Skin: Soap flush immed Breath: Resp support dysp.33 mg/m3 DOT: Synonyms/Trade Names: Isooctanol. convuls.P: 47°F Change: N. Con Skin: Soap wash immed SY: Irrit eyes. colorless liquid.83 Provide: Eyewash VP: 0. skin. resp sys. throat. reducing agents.3 Skin: Prevent skin contact BP: 367°F Not available. resp sys Swallow: Medical attention immed Isooctyl alcohol 178 . Symptoms. Ing.): 5.Gr: 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. head. lass.): 0. (CH3)2CHCN Conversion: 1 ppm = 2. Symptoms.Gr: 0. dizz. skin.Pp:AScba VP(130°F): 100 mmHg Quick drench Escape: GmFOv/ScbaE FRZ: -97°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers. skin burns Breath: Resp support TO: Eyes. primary alcohols with branched chains such as 2-Ethylhexanol.D. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam/Daily Fl.83 mg/m3 DOT: 2284 131 Synonyms/Trade Names: Isopropyl cyanide. Abs. C7H15CH2OH Conversion: 1 ppm = 5. Abs. Sp.7% LEL(calc. skin. CH3(CH2)3CH(CH2CH3)CH2OH. CNS. IP: ? ScbaF/SaF 1000 ppm: SaF:Pd.Pp Provide: Eyewash Sp.R. throat.76 §: ScbaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 69.D.9% Class IIIA Combustible Liquid Incompatibilities and Reactivities: None reported Exposure Routes. skin. 2-Methylpropanenitrile. nose. Ing.4 mmHg FRZ: <-105°F UEL(est. conf. CVS Isobutyronitrile CAS#: RTECS#: IDLH: Formula: 26952-21-6 NS7700000 N. vomit Swallow: Medical attention immed TO: Eyes. nau. 2-Methylpropionitrile Exposure Limits: Measurement Methods NIOSH REL: TWA 8 ppm (22 mg/m3) (see Table 1): NIOSH 1606 (adapt) OSHA PEL: none Physical Description: Colorless liquid with an almond-like odor.R.Pp/SaF:Pd. [Note: Forms cyanide in the body.1 80 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 219°F 200 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Slight 400 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) Fl. eye. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 130.P(oc): 180°F Remove: When wet or contam IP: ? Change: N. Con SY: Irrit eyes.

amides. liver damage Swallow: Medical attention immed TO: Eyes.07 eV SaT:Cf*/ScbaF/SaF §: ScbaF:Pd. kidneys I Formula: CAS#: RTECS#: IDLH: C12H18N2O2 4098-71-9 NQ9370000 N. Isophorone Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 138.5.s. alcohols.09 mg/m3 DOT: 2290 156 Synonyms/Trade Names: IPDI. Breath: Resp support derm. Ing. pulm edema. 2556 OSHA PEL†: TWA 25 ppm (140 mg/m ) OSHA 7 Physical Description: Colorless to white liquid with a peppermint-like odor. cough.Gr: 0. mercaptans. head. resp sys. dizz.R. skin. amines Exposure Routes.P: 311°F 1 ppm: SaF:Pd.005 ppm (0.3 mmHg FRZ: 17°F UEL: 3. Con Eye: Irr immed SY: Irrit eyes. lass.P: 184°F Change: N.045 mg/m3) [skin] (see Table 1): 3 NIOSH 5525 ST 0.D. phenols. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.8% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers.Gr: 1.] Exposure Routes. liver. CNS. urethanes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 222. resp sys Isophorone diisocyanate 179 .125 ppm: Sa:Cf* Wash skin: When contam Sol: Decomposes 0.92 Escape: GmFOv/ScbaE VP: 0. Symptoms. resp sys.8% LEL: 0.5-Trimethyl-2-cyclo-hexen-1-one Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 4 ppm (23 mg/m3) 3 NIOSH 2508.o.25 ppm: ScbaF/SaF Remove: When wet or contam Fl. dysp. possible resp sens. bron.5. nau.5-Trimethyl-2-cyclohexenone.05 ppm: Sa* Eyes: Prevent eye contact BP: ? 0. 3-Isocyanatomethyl-3.Pp/SaF:Pd. n.65 mg/m3 DOT: 1993 128 (combustible liquid.2 40 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 419°F 100 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 1% 200 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl.02 ppm (0. 3. nose. mal.0003 mmHg FRZ: -76°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Water. ureas [Note: Reacts with water to form carbon dioxide.5-trimethylcyclohexyl-isocyanate.Pp:AScba Provide: Eyewash Sp. sore Skin: Water flush immed Breath: Resp support throat. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. amines. IP: 9. in animals: kidney. Conversion: 1 ppm = 9. skin. Ing.Pp/SaF:Pd. wheez.CAS#: RTECS#: IDLH: Formula: 78-59-1 GW7700000 200 ppm C9H14O Conversion: 1 ppm = 5. Con Skin: Soap wash prompt SY: Irrit eyes. narco.Pp Change: Daily IP: ? §: ScbaF:Pd. skin. Symptoms. asthma Swallow: Medical attention immed TO: Eyes.) Synonyms/Trade Names: Isoacetophorone.5.3 0. Isophorone diamine diisocyanate Exposure Limits: Measurement Methods NIOSH REL: TWA 0. 3. throat.180 mg/m ) OSHA PV2034 OSHA PEL†: none Physical Description: Colorless to slightly yellow liquid with a pungent odor. chest tight.Pp:AScba Provide: Quick drench Sp. Abs.06 Escape: GmFOv/ScbaE VP: 0. strong alkalis.

D. in animals: narco Breath: Resp support TO: Eyes. β-Hydroxyethyl isopropyl ether.2 Skin: Prevent skin contact BP: 283°F Not available. Con Skin: Water flush prompt SY: Irrit eyes. skin.2 1800 ppm: Sa:Cf£/ScbaF/SaF Eyes: Prevent eye contact BP: 194°F §: ScbaF:Pd. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. Abs.90 VP: 3 mmHg FRZ: ? UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes. nose.2-Isopropoxyethanol Conversion: CAS#: Formula: (CH3)2CHOCH2CH2OH 109-59-1 DOT: RTECS#: KL5075000 IDLH: N. 2-Propyl acetate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 NIOSH 1454. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 104. resp sys. Ing.R.Gr: 0. skin.87 VP: 42 mmHg FRZ: -92°F UEL: 8% LEL(100°F): 1. blood Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: CH3COOCH(CH3)2 108-21-4 AI4930000 1800 ppm Conversion: 1 ppm = 4. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.95 eV Sp. Ing. skin. CNS Swallow: Medical attention immed 180 . 1-Methylethyl ester of acetic acid. I Synonyms/Trade Names: Ethylene glycol isopropyl ether.Pp/SaF:Pd. hema. Sp.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates. derm. Isopropyl Cellosolve®. resp sys.Gr: 0. Symptoms.18 mg/m3 DOT: 1220 129 Synonyms/Trade Names: Isopropyl ester of acetic acid. alkalis & acids Exposure Routes. skin. strong oxidizers. Symptoms.P: 36°F Change: N. 1460 OSHA PEL†: TWA 250 ppm (950 mg/m ) OSHA 7 Physical Description: Colorless liquid with a fruity odor.Pp:AScba Wash skin: When contam Sol: 3% Escape: GmFOv/ScbaE Remove: When wet (flamm) Fl.R. Isopropyl acetate Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact MW: 102.P(oc): 92°F Remove: When wet (flamm) IP: ? Change: N. anemia. ethereal odor. pulm edema Breath: Resp support TO: Eyes. Isopropyl glycol Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with a mild. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Con Skin: Water wash immed SY: In animals: irrit eyes. IP: 9.

sec-Propylamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 NIOSH S147 (II-3) OSHA PEL†: TWA 5 ppm (12 mg/m ) Physical Description: Colorless liquid with an ammonia-like odor. drow. 2-Propylamine. derm Skin: Water flush immed Breath: Resp support TO: Eyes. Rubbing alcohol Exposure Limits: Measurement Methods NIOSH REL: TWA 400 ppm (980 mg/m3) (see Table 1): 3 NIOSH 1400 ST 500 ppm (1225 mg/m ) 3 OSHA 109 OSHA PEL†: TWA 400 ppm (980 mg/m ) Physical Description: Colorless liquid with the odor of rubbing alcohol.R. IP: 10.7% LEL: 2. IP: 8. skin. strong oxidizers. skin.Pp/SaF:Pd.1 125 ppm: Sa:Cf£/PaprS£ Eyes: Prevent eye contact BP: 91°F 250 ppm: CcrFS/GmFS/PaprTS£/ Wash skin: When contam Sol: Miscible Remove: When wet (flamm) Fl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Gr: 0.42 mg/m3 DOT: 1221 132 Synonyms/Trade Names: 2-Aminopropane.79 VP: 33 mmHg FRZ: -127°F UEL(200°F): 12. epoxides First Aid (see Table 6): Exposure Routes. Ing. ethylene oxide.Pp Change: N. Symptoms.72 eV §: ScbaF:Pd. resp sys Isopropyl alcohol I Formula: CAS#: RTECS#: IDLH: (CH3)2CHNH2 75-31-0 NT8400000 750 ppm Conversion: 1 ppm = 2. Isopropanol. dry cracking skin. chlorine. Target Organs (see Table 5): Eye: Irr immed ER: Inh. vis dist. ketones. aldehydes. resp sys Swallow: Medical attention immed Isopropylamine 181 .10 eV Sp. skin burns.R. [Note: A gas above 91°F. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 60.Gr: 0.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: Prevent skin contact MW: 59. acids. 2-Propanol.Pp:AScba Remove: When wet (flamm) Fl.0% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers.P: 53°F Escape: GmFOv/ScbaE Change: N.P(oc): -35°F ScbaF/SaF 750 ppm: SaF:Pd.Pp/SaF:Pd.Pp:AScba Provide: Eyewash Sp. acetaldehyde.CAS#: RTECS#: IDLH: Formula: 67-63-0 NT8050000 2000 ppm [10%LEL] (CH3)2CHOH Conversion: 1 ppm = 2. dizz. sec-Propyl alcohol. isocyanates Exposure Routes.46 mg/m3 DOT: 1219 129 Synonyms/Trade Names: Dimethyl carbinol. Abs. Monoisopropylamine. pulm edema. throat. Breath: Resp support in animals: narco Swallow: Medical attention immed TO: Eyes. Symptoms. Ing.69 Escape: GmFS/ScbaE VP: 460 mmHg Quick drench FRZ: -150°F UEL: ? LEL: ? Class IA Flammable Liquid Incompatibilities and Reactivities: Strong acids. IPA. throat. Con SY: Irrit eyes. skin.1 2000 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 181°F Wash skin: When contam Sol: Miscible PaprOv£/ScbaF/SaF §: ScbaF:Pd. eye. nose. Con Skin: Water flush SY: Irrit eyes. head. nose.

2 Skin: Prevent skin contact BP: 397°F Not available.73 VP: 119 mmHg FRZ: -76°F UEL: 7. acids [Note: Unstable peroxides may form on long contact with air. dizz.93 Provide: Quick drench VP(77°F): 0. lass. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 135. head. derm. Eyes: Prevent eye contact Sol: ? Wash skin: When contam Fl.53 mg/m3 DOT: Synonyms/Trade Names: N-IPA. cyan. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. aromatic odor. Skin: Soap wash prompt Breath: Resp support tacar. Conversion: 1 ppm = 5. resp sys. narco Swallow: Medical attention immed TO: Eyes. ataxia. Isopropylaniline. uncon.18 mg/m3 DOT: 1159 127 Synonyms/Trade Names: Diisopropyl ether. nose. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. dizz.R.2% Sa*/ScbaF Remove: When wet (flamm) §: ScbaF:Pd.R. skin.] Exposure Routes.P: -18°F Change: N. Symptoms.Gr: 0. 2-Isopropoxy propane Exposure Limits: Measurement Methods NIOSH REL: TWA 500 ppm (2100 mg/m3) (see Table 1): 3 NIOSH 1618 OSHA PEL: TWA 500 ppm (2100 mg/m ) OSHA 7 Physical Description: Colorless liquid with a sharp. skin.20 eV Sp.Pp:AScba Fl. ether-like odor. CVS. blood.P(oc): 190°F Remove: When wet or contam IP: ? Change: N.Gr(60°F): 0. Isopropyl ether Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 102. CNS 182 . skin. skin.4% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. in animals: Breath: Resp support drow. resp discomfort. liver.Pp/SaF:Pd. yellowish liquid with a sweet. Ing. resp sys.I Formula: CAS#: RTECS#: IDLH: C6H5NHCH(CH3)2 768-52-5 BY4190000 N. Abs. Diisopropyl oxide. sweet. Sp. N-(1-Methylethyl)-benzenamine.03 mmHg FRZ: -58°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: None reported Exposure Routes. kidneys N-Isopropylaniline Formula: CAS#: RTECS#: IDLH: (CH3)2CHOCH(CH3)2 108-20-3 TZ5425000 1400 ppm [10%LEL] Conversion: 1 ppm = 4.2 1400 ppm: CcrOv*/PaprOv*/GmFOv/ Eyes: Prevent eye contact BP: 154°F Wash skin: When contam Sol: 0. N-Phenylisopropylamine Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (10 mg/m3) [skin] (see Table 1): OSHA 78 OSHA PEL†: none Physical Description: Clear. dysp on effort. Escape: GmFOv/ScbaE IP: 9.D. methemo Swallow: Medical attention immed TO: Eyes. Symptoms.9% LEL: 1. Con SY: Irrit eyes. Ing. Con Skin: Soap wash prompt SY: Irrit eyes.

Sol: Insoluble Wash skin: N.R.R. IGE. skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin. Skin: Soap wash immed Breath: Resp support repro effects Swallow: Medical attention immed TO: Eyes.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500. Eyes: N. repro sys K Kaolin Formula: CAS#: 1332-58-7 RTECS#: GF1670500 IDLH: N. possible hemato. Porcelain clay [Note: Main constituent of Kaolin is Kaolinite (Al2Si2O5(OH)4). Symptoms. upper resp sys. resp sys.Gr: 1. Isopropoxymethyl oxirane Exposure Limits: Measurement Methods NIOSH REL: C 50 ppm (240 mg/m3) [15-minute] (see Table 1): 3 NIOSH 1620 OSHA PEL†: TWA 50 ppm (240 mg/m ) OSHA 7 Physical Description: Colorless liquid.] Exposure Routes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: varies Skin: N.P: NA Remove: N. Sp.Formula: CAS#: RTECS#: IDLH: C6H12O2 4016-14-2 TZ3500000 400 ppm Conversion: 1 ppm = 4.P: 92°F Change: N.Gr: 0. Ing. skin sens.Pp:AScba Wash skin: When contam Sol: 19% Escape: GmFOv/ScbaE Remove: When wet (flamm) Fl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Fl. Symptoms.2-Epoxy-3-isopropoxypropane. stomach granuloma TO: Resp sys.92 VP(77°F): 9 mmHg FRZ: ? UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. IP: ? Sp. strong caustics [Note: May form explosive peroxides upon exposure to air or light.75 mg/m3 DOT: Synonyms/Trade Names: 1.2 400 ppm: Sa:Cf£/ScbaF Eyes: Prevent eye contact BP: 279°F §: ScbaF:Pd. 0600 TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) TWA 5 mg/m3 (resp) Physical Description: White to yellowish or grayish powder. [Note: When moistened. Con SY: Irrit eyes. Conversion: DOT: Synonyms/Trade Names: China clay. darkens & develops a clay-like odor.R.6 VP: 0 mmHg (approx) MLT: ? UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. Con Breath: Fresh air SY: Chronic pulm fib. Hydrite.Pp/SaF:Pd.R. blood. Isopropyl glycidyl ether Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 116. BP: ? Not available. Hydrated aluminum silicate. IP: NA Change: N.D.R.8-2. stomach 183 . Clay.R.

Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 170 (approx) 1000 mg/m3: CcrOv/Sa Eyes: Prevent eye contact BP: 347-617°F Wash skin: When contam Sol: Insoluble 2500 mg/m3: Sa:Cf/PaprOv Remove: When wet or contam Fl. CNS.7% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers First Aid (see Table 6): Exposure Routes. skin. low sperm count.Gr: 0. lass.7-methanoindeneone Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 5508 TWA 0.Gr: ? Change: Daily VP(77°F): 3 x 10-7 mmHg Provide: Eyewash MLT: 662°F (Sublimes) Quick drench UEL: NA LEL: NA Incompatibilities and Reactivities: Acids.3. 16% mononuclear aromatics. Ing.81 §: ScbaF:Pd. skin. resp sys. Target Organs (see Table 5): Eye: Irr immed ER: Inh. [insecticide] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 490. acid fumes Noncombustible Solid Kepone Exposure Routes.R. diarr.K CAS#: RTECS#: IDLH: Formula: 143-50-0 PC8575000 Ca [N. liver. Decachlorooctahydro-kepone-2-one.4-metheno-2H-cyclobuta(cd)-pentalen-2-one. IP: ? PaprTOv/ScbaF/SaF Provide: Quick drench Sp. skin eryt. 12% dicycloparaffins. [carc] TO: Eyes. kidney damage. liver. Conversion: DOT: 1223 128 Synonyms/Trade Names: Fuel Oil No.001 mg/m See Appendix A OSHA PEL: none Physical Description: Tan to white. drow. ataxia. crystalline. Target Organs (see Table 5): ER: Inh. throat. burning sensation in chest. which typically is 25% normal paraffins. Ing.Pp/SaF:Pd. Decachlorotetrahydro-4. conf. resp sys.D.P: 100-162°F 5000 mg/m3: CcrFOv/GmFOv/ Change: N. chest pain.D.] C10Cl10O Conversion: DOT: Synonyms/Trade Names: Chlordecone. vis dist. 11% branched paraffins. 30% monocycloparaffins. odorless solid. CNS 184 . testicular atrophy. nose. Range oil [Note: A refined petroleum solvent (predominantly C9-C16). Skin: Soap flush immed Breath: Resp support restless. 1% tricycloparaffins. chemical pneu (aspir liquid) Swallow: Medical attention immed TO: Eyes.6 (see Table 2): NIOSH BP: Sublimes Skin: Prevent skin contact ¥: ScbaF:Pd. head. inco. 1. Symptoms.P: NA Wash skin: When contam/Daily IP: ? Remove: When wet or contam Sp. nau.Pp:AScba Sol(212°F): 0. oily liquid with a strong. Con SY: Irrit eyes. vomit. Symptoms.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 100 mg/m3 NIOSH 1550 OSHA PEL: none Physical Description: Colorless to yellowish.Pp/SaF:Pd. kidneys. tremor. anxi. Con SY: Head. derm. skin. repro sys [in animal: liver cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed Kerosene Formula: CAS#: 8008-20-6 RTECS#: OA5500000 IDLH: N.5% Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl. and 5% dinuclear aromatics.Pp:AScba VP(100°F): 5 mmHg Escape: GmFOv/ScbaE FRZ: -50°F UEL: 5% LEL: 0. characteristic odor. Decachlorooctahydro-1. Abs.

Pp:AScba Escape: 100F/ScbaE See Appendix E (page 351) Incompatibilities and Reactivities: Strong oxidizers. Symptoms. 5 ppm: Sa*/ScbaF BP: -69°F Eyes: N. insom.Pp §: ScbaF:Pd.9 mg/m ) Physical Description: Colorless gas with a penetrating odor. 7301. alcohols. Lead RTECS#: OF7525000 IDLH: 100 mg/m3 (as Pb) Measurement Methods (see Table 1): NIOSH 7082. 9105 OSHA ID121. 7702.] Physical Description: A heavy. colic. nose. para wrist.see Appendix C.P: NA (Gas) Remove: N.45 VP: >1 atm FRZ: -238°F UEL: ? Incompatibilities and Reactivities: Water. soft.5 mg/m3: 100XQ/Sa 1. 7300. IP: 9. Con Skin: Soap flush prompt SY: Lass.050 mg/m3 See Appendix C [*Note: The REL and PEL also apply to other lead compounds (as Pb) -.9 mg/m3) (see Table 1): 3 NIOSH S92 (II-2) ST 1. kidney disease. Con SY: Irrit eyes.CAS#: RTECS#: IDLH: Formula: 463-51-4 OA7700000 5 ppm CH2=CO Conversion: 1 ppm = 1. 7700. 7105. hypotension TO: Eyes. Symptoms.P: NA Remove: When wet or contam IP: NA Change: Daily Sp.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh.72 mg/m3 DOT: Synonyms/Trade Names: Carbomethene. Swallow: Medical attention immed encephalopathy. tremor.R. resp sys. Ing.R. kidneys.25 mg/m3: Sa:Cf/PaprHie 2. 7303. hydrogen peroxide. ID206 Respirator Recommendations (see Tables 3 and 4): NIOSH/OSHA 0. Target Organs (see Table 5): Eye: Irr immed ER: Inh. acids First Aid (see Table 6): Exposure Routes. blood. gingival lead line.Gr: 11.R. throat. §: ScbaF:Pd.5 ppm (3 mg/m ) 3 OSHA PEL†: TWA 0. anemia. low-wgt.61 eV Change: N. GI tract.] Flammable Gas Exposure Routes.2 Skin: Prevent skin contact BP: 3164°F Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl. 9102. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 42. constip. 7701.R.5 ppm (0. Ethenone. Keto-ethylene Exposure Limits: Measurement Methods NIOSH REL: TWA 0. CNS. skin.050 mg/m3 See Appendix C OSHA PEL*: [1910. resp sys Ketene L Formula: CAS#: Pb 7439-92-1 Conversion: DOT: Synonyms/Trade Names: Lead metal.Pp:AScba Sol: Reacts Wash skin: N. gingival tissue 185 . Escape: GmFOv/ScbaE Fl.5 mg/m3: 100F/SaT:Cf/PaprTHie/ ScbaF/SaF 50 mg/m3: Sa:Pd.5 ppm (0. malnut.Pp/SaF:Pd. ankles. anor. Personal Protection/Sanitation Chemical & Physical Properties: (see Table 2): MW: 207.34 VP: 0 mmHg (approx) MLT: 621°F UEL: NA LEL: NA Noncombustible Solid in bulk form. ductile. gray solid. Reacts with water to form acetic acid.Pp 3 100 mg/m : SaF:Pd.R. Plumbum Exposure Limits: NIOSH REL*: TWA 0. RGasD: 1. pulm edema TO: Eyes.1025] TWA 0.0 Skin: N. abdom Breath: Resp support pain. facial pallor. ID125G. ammonia LEL: ? [Note: Readily polymerizes. irrit eyes. skin.

00001 mmHg 50 mg/m3: SaF:Pd. lac Breath: Fresh air TO: Eyes. skin. CNS.L Formula: CAS#: RTECS#: IDLH: CaCO3 1317-65-3 N. rhin. musc spasm. Conversion: DOT: Synonyms/Trade Names: Calcium carbonate. blood. nau. HCH. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 100. Natural calcium carbonate [Note: Calcite & aragonite are commercially important natural calcium carbonates.9 VP: 0 mmHg (approx) MLT: 1517-2442°F (Decomposes) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Fluorine. ammonium salts Exposure Routes. Con Eye: Irr immed SY: Irrit eyes.5.R. liver.1 Skin: N.D.4.85 PaprTOvHie*/ScbaF/SaF Provide: Quick drench VP: 0.Pp:AScba UEL: NA Escape: GmFOv100/ScbaE LEL: NA Noncombustible Solid.001% Wash skin: N. nose. Symptoms.5 mg/m3 [skin] 3 NIOSH 5502 OSHA PEL: TWA 0.2. skin. cough. magnesium. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Odorless. skin. Sol: 0. clonic convuls. kidney damage Swallow: Medical attention immed TO: Eyes. in animals: liver. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Sol: 0.8 NIOSH/OSHA Skin: Prevent skin contact BP: 614°F 5 mg/m3: CcrOv95/Sa Eyes: N.R.R. Sp. musty odor. aplastic anemia. Incompatibilities and Reactivities: Corrosive to metals Exposure Routes. Abs. Skin: Soap wash prompt Breath: Resp support cyan. resp sys Limestone Formula: CAS#: RTECS#: IDLH: C6H6Cl6 58-89-9 GV4900000 50 mg/m3 Conversion: DOT: 2761 151 Synonyms/Trade Names: BHC. γ-Hexachlorocyclohexane.Pp/SaF:Pd. [pesticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 290.R.5 mg/m3: Sa:Cf*/PaprOvHie* Remove: When wet or contam IP: ? 25 mg/m3: CcrFOv100/GmFOv100/ Change: Daily Sp. head. BP: Decomposes Not available. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. crystalline powder with a slight. muc memb. alum.6-Hexachlorocyclohexane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Fl. IP: NA Change: N. white to tan powder.P: NA 12. gamma isomer of 1.Gr: 2.R.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500.Pp MLT: 235°F §: ScbaF:Pd.7-2.5 mg/m [skin] Physical Description: White to yellow. resp sys.Gr: 1. Symptoms. Eyes: N. Ing. skin. kidneys Lindane 186 .P: NA Remove: N. resp difficulty.R. acids.001% Wash skin: When contam Fl.3. sneez. Con Skin: Soap wash SY: Irrit eyes. throat. but may be dissolved in flammable liquids.

Shipped as a liquefied compressed gas.R. or oxidizers.025 mg/m3 (see Table 1): 3 OSHA ID121 OSHA PEL: TWA 0.1% (Propane) 1. Liquefied hydrocarbon gas. Con SY: Irrit eyes. butanes & butylenes. Personal Protection/Sanitation Chemical & Physical Properties: Respirator Recommendations (see Table 2): MW: 7. water [Note: May ignite SPONTANEOUSLY in air and may reignite after fire is extinguished.Pp/SaF:Pd. mouth.95 (see Tables 3 and 4): Skin: Prevent skin contact BP: Decomposes NIOSH/OSHA Eyes: Prevent eye contact 0. off-white to gray. LPG [Note: A fuel mixture of propane. [Note: A foul-smelling odorant is usually added.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 42-58 NIOSH/OSHA Skin: Frostbite BP: >-44°F 2000 ppm: Sa/ScbaF Eyes: Frostbite Sol: Insoluble §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 2805 138 (fused.9% (Butane) Flammable Gas Incompatibilities and Reactivities: Strong oxidizers.R. translucent. propylene. drow.Pp/SaF:Pd.P: NA (Gas) Escape: ScbaE Remove: When wet (flamm) IP: 10.00 Provide: Frostbite wash VP: >1 atm FRZ: ? UEL: 9. solid) Synonyms/Trade Names: Lithium monohydride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Incompatibilities and Reactivities: Strong oxidizers.78 §: ScbaF:Pd. Fl. Symptoms. resp sys.72-2. musc twitches.P: NA 0. skin burns. asphy.5% (Butane) LEL: 2.5% (Propane) 8.5 mg/m3: Sa:Cf*/100F/PaprHie*/ IP: NA (DO NOT WASH) ScbaF/SaF Remove: When wet or contam Sp. CNS L. halogenated hydrocarbons. odorless gas when pure. heat. CNS Lithium hydride L Formula: CAS#: RTECS#: IDLH: C3H8/C3H6/C4H10/C4H8 68476-85-7 SE7545000 2000 ppm [10%LEL] 3 Conversion: 1 ppm = 1.25 mg/m3: 100XQ/Sa Sol: Reacts Wash skin: Brush Fl.Pp:AScba Change: Daily VP: 0 mmHg (approx) Escape: 100F/ScbaE Provide: Eyewash MLT: 1256°F UEL: NA Quick drench (>0. skin. 187 . eye.Pp:AScba Wash skin: N.5 mg/m3 Conversion: DOT: 1414 138. chlorine dioxide Exposure Routes.] Exposure Routes.37 mg/m DOT: 1075 115 Synonyms/Trade Names: Bottled gas.P.025 mg/m Physical Description: Odorless.Gr: 0.G. Con (liquid) Skin: Water flush immed (liquid) SY: Dizz. liquid: frostbite Breath: Resp support TO: Resp sys. noncorrosive. Ing. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed (liquid) ER: Inh. esophagus burns (if Skin: Brush (DO NOT WASH) Breath: Resp support ingested). Compressed petroleum gas.45-2. Reacts with water to form hydrogen & lithium hydroxide. blurred vision Swallow: Medical attention immed TO: Eyes.95 eV Change: N. skin. crystalline mass or white powder.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1000 ppm (1800 mg/m3) 3 NIOSH S93 (II-2) OSHA PEL: TWA 1000 ppm (1800 mg/m ) Physical Description: Colorless. nau.5 mg/m3) LEL: NA Combustible Solid that can form airborne dust clouds which may explode on contact with flame. Liquefied petroleum gas. mental conf. RGasD: 1. acids.Formula: CAS#: RTECS#: IDLH: LiH 7580-67-8 OJ6300000 0. Symptoms.

[Note: Exposure may occur when magnesium is burned. chest pain. 7303 OSHA PEL†: TWA 15 mg/m OSHA ID121 Physical Description: Finely divided white particulate dispersed in air. BP: 6512°F Wash skin: N.P: NA 750 mg/m3: 100F/PaprTHie*/ScbaF/SaF Change: N. Conversion: DOT: Synonyms/Trade Names: Carbonate magnesium. resp sys.01% Wash skin: N. Fl. MW: 40. resp sys Magnesite Magnesium oxide fume Conversion: Synonyms/Trade Names: Magnesia fume Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 NIOSH 7300.R. IP: NA §: ScbaF:Pd. Sol(86°F): 0.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 84.58 Escape: 100F/ScbaE VP: 0 mmHg (approx) MLT: 5072°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Chlorine trifluoride.R. flu-like fever TO: Eyes. skin. formaldehyde Exposure Routes.Pp/SaF:Pd.R.R. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: White. or welded upon. Symptoms.M Formula: CAS#: RTECS#: IDLH: MgCO3 546-93-0 OM2470000 N.R. Sol: 0.3 150 mg/m3: 95XQ/Sa Eyes: N.P: NA Remove: N. odorless. Magnesium(II) carbonate [Note: Magnesite is a naturally-occurring form of magnesium carbonate.3 Skin: N.009% 375 mg/m3: Sa:Cf/PaprHie Remove: N.R. metal fume fever: cough. Eyes: N.Gr: 2. Con SY: Irrit eyes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Skin: N. nose. Symptoms. Target Organs (see Table 5): Breath: Resp support ER: Inh.R. Con Breath: Fresh air SY: Irrit eyes. IP: NA Change: N. Sp.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500.R. cough TO: Eyes. phosphorus pentachloride First Aid (see Table 6): Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin. resp sys Formula: MgO DOT: CAS#: 1309-48-4 RTECS#: OM3850000 IDLH: 750 mg/m3 188 . Hydromagnesite.R. thermally cut. Magnesium carbonate. BP: Decomposes Not available. crystalline powder.Gr: 3. 7301.D. Fl.Pp:AScba Sp.96 VP: 0 mmHg (approx) MLT: 662°F (Decomposes) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Acids.

CNS. Maleic acid anhydride.R.Pp:AScba VP: 0. bronchial asthma. double vision. blurred vision. liver. [Note: Reacts slowly with water (hydrolyzes) to form maleic acid. and amines above 150°F difficult to ignite. conj.01 mg/m3 DOT: 2215 156 Synonyms/Trade Names: cis-Butenedioic anhydride. VP: 0.4 Skin: Prevent skin contact 100 mg/m3: CcrOv95/Sa BP: 140°F (Decomposes) Eyes: Prevent eye contact Sol: 0.Gr: 1. blood chol. ataxia. or pellets with an irritating. 2. alkalis. water. salv. chest tight.2 mmHg Provide: Eyewash MLT: 127°F UEL: 7. upper resp sys.4% Incompatibilities and Reactivities: Strong oxidizers. Abs. Ing. resp sys First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed 189 . Target Organs (see Table 5): ER: Inh. GI tract First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed M Formula: CAS#: RTECS#: IDLH: C4H2O3 108-31-6 ON3675000 10 mg/m3 Conversion: 1 ppm = 4. Symptoms. diarr. rhin.Gr: 1. Ing.O-dimethyl-phosphorodithioate.Pp/SaF:Pd. white lumps. resp sys.00004 mmHg Escape: GmFOv100/ScbaE FRZ: 37°F UEL: ? LEL: ? Incompatibilities and Reactivities: Strong oxidizers. anor. vomit. photo. wheez. lar spasm TO: Eyes.02% Wash skin: When contam 250 mg/m3: Sa:Cf*/CcrFOv100/ Fl. nau.25 ppm) (see Table 1): 3 NIOSH 3512 OSHA PEL: TWA 1 mg/m (0.] Maleic anhydride Exposure Routes. Con SY: Irrit eyes.Pp/SaF:Pd.P: 218°F Wash skin: When contam §: ScbaF:Pd. skin.25 ppm) OSHA 25. abdom cramps.48 Change: N. Symptoms. miosis. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 98. skin. aching eyes. alkaline pesticides [Note: Corrosive to metals. head. lac. dizz. Malathion Exposure Routes.P(oc): >325°F Remove: When wet or contam GmFOv100/PaprOvHie*/ IP: ? Change: Daily ScbaF/SaF Sp. Class IIIB Combustible Liquid.Formula: CAS#: RTECS#: IDLH: C10H19O6PS2 121-75-5 WM8400000 250 mg/m3 Conversion: DOT: 2783 152 Synonyms/Trade Names: S-[1. 86 Physical Description: Colorless needles.5-Furanedione.1% LEL: 1.] Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH MW: 330.1 (see Table 2): NIOSH/OSHA BP: 396°F Skin: Prevent skin contact 10 mg/m3: Sa:Cf£/ScbaF/SaF Sol: Reacts Eyes: Prevent eye contact Fl. skin. Target Organs (see Table 5): ER: Inh. Con SY: Irrit nose. magnesium. Diethyl (dimethoxyphosphinothioylthio) succinate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 [skin] 3 NIOSH 5600 OSHA PEL†: TWA 15 mg/m [skin] Physical Description: Deep-brown to yellow liquid with a garlic-like odor. [insecticide] OSHA 62 [Note: A solid below 37°F.90 eV Remove: When wet or contam Escape: GmFOv100/ScbaE Sp. Toxilic anhydride Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (0. Combustible Solid. derm TO: Eyes. conf. metals. but may be caustics.2-bis(ethoxycarbonyl) ethyl]O. CVS.21 §: ScbaF:Pd. choking odor.Pp:AScba IP: 9.] but may be difficult to ignite.

Pp Provide: Eyewash Sp. Propanedial. lass. or in contact with strong bases at lower temperatures.Gr: ? VP: ? Quick drench MLT: 161°F UEL: ? LEL: ? Incompatibilities and Reactivities: Proteins [Note: Pure compound is stable under neutral conditions. Dicyanomethane. but not under acidic conditions.Gr: 1. skin.] CHOCH2CHO Conversion: DOT: Synonyms/Trade Names: Malonic aldehyde.Pp:AScba VP: ? Escape: GmFOv/ScbaE Quick drench MLT: 90°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong bases [Note: May polymerize violently on prolonged heating at 265°F. 1.] Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): See Appendix A None available See Appendix C (Aldehydes) OSHA PEL: none Physical Description: Solid (needles). nau.70 mg/m DOT: 2647 153 Synonyms/Trade Names: Cyanoacetonitrile. Con SY: Irrit eyes. CNS. NCCH2CN Conversion: 1 ppm = 2. resp sys. dizz.Pp:AScba Eyes: Prevent eye contact BP: ? Escape: GmFOv/ScbaE Wash skin: When contam/Daily Sol: ? Remove: When wet or contam Fl. head.M CAS#: RTECS#: IDLH: Formula: 542-78-9 TX6475000 Ca [N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.P: ? Change: Daily IP: ? Provide: Eyewash Sp. CNS [in animals: thyroid gland tumors] Breath: Resp support Swallow: Medical attention immed Malonaldehyde CAS#: RTECS#: IDLH: Formula: 109-77-3 OO3150000 N. Forms cyanide in the body.Pp/SaF:Pd. throat. [Note: Melts above 90°F. skin.P(oc): 266°F 400 mg/m3: ScbaF/SaF Change: Daily IP: 12. [carc] TO: Eyes. resp sys. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 72. resp sys.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 66.D.] Exposure Routes.19 §: ScbaF:Pd. skin. vomit Swallow: Medical attention immed TO: Eyes. convuls.88 eV 667 mg/m3: SaF:Pd. nose. Abs. Abs. skin. Malonodialdehyde. Skin: Water wash immed Breath: Resp support dysp. Malonic dinitrile Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 3 ppm (8 mg/m3) NIOSH Nitriles Criteria Document OSHA PEL: none Physical Description: White powder or colorless crystals. conf.] Exposure Routes. Symptoms. Con Skin: Water flush immed SY: Irrit eyes. CVS Malononitrile 3 190 . CNS depres. abdom pain. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Ing.D.1 80 mg/m3: Sa Eyes: Prevent eye contact BP: 426°F Wash skin: When contam Sol: 13% 200 mg/m3: Sa:Cf Remove: When wet or contam Fl.Pp/SaF:Pd. Ing.1 ¥: ScbaF:Pd.3-Propanedial [Note: Pure Malonaldehyde is unstable and may be used as its sodium salt.

Exposure Limits: Measurement NIOSH REL*: TWA 1 mg/m3 Methods 3 (see Table 1): ST 3 mg/m [*Note: Also see specific listings for Manganese cyclopentadienyl tricarbonyl.Pp/SaF:Pd. resp sys. pulm edema.Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA Incompatibilities and Reactivities: Oxidizers Metal: Combustible Solid [Note: Will react with water or steam to produce hydrogen. lass. Abs. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 54. Skin: Soap wash Breath: Resp support kidney changes. Sol: Slight Eyes: Prevent eye contact Fl.R. vomit.D. 50 mg/m3: 100F/SaT:Cf/PaprTHie/ Sp.Pp MLT: 2271°F §: ScbaF:Pd.1 mg/m3 [skin] (see Table 1): 3 OSHA PEL†: C 5 mg/m None available Physical Description: Yellow. insom. metal fume fever: dry throat. Fl.R. convuls. [Note: An antiknock additive for gasoline. rales. chest tight. 7301. 9102 OSHA PEL*: C 5 mg/m3 OSHA ID121.Gr: 7. CNS. kidneys 191 . Target Organs (see Table 5): Breath: Resp support ER: Inh. flu-like fever.] Physical Description: A lustrous.] First Aid (see Table 6): Exposure Routes. Ing. Cyclopentadienyl tricarbonyl manganese. CNS. MCT Exposure Limits: Measurement Methods NIOSH REL: TWA 0. 10 mg/m3: 95XQ/Sa Sol: Insoluble Eyes: N. Ing Swallow: Medical attention immed SY: Parkinson's. 25 mg/m3: Sa:Cf/PaprHie IP: NA Remove: N. asthenia. mal. Methyl NIOSH 7300. crystalline solid with a characteristic odor. mental conf. and Manganese tetroxide.P: ? Wash skin: When contam IP: ? Remove: When wet or contam Sp. ScbaF/SaF VP: 0 mmHg (approx) 500 mg/m3: Sa:Pd. kidneys M Manganese cyclopentadienyl tricarbonyl (as Mn) Formula: C5H5Mn(CO)3 CAS#: 12079-65-1 RTECS#: OO9720000 IDLH: N. Symptoms. brittle.R. May be found in an oil & gaseous solution. Conversion: DOT: Synonyms/Trade Names: Cyclopentadienylmanganese tricarbonyl. decr resistance to infection Swallow: Medical attention immed TO: Skin.Manganese compounds and fume Formula: Mn (metal) (as Mn) CAS#: 7439-96-5 (metal) RTECS#: OO9275000 (metal) IDLH: 500 mg/m3 (as Mn) Conversion: DOT: Synonyms/Trade Names: Manganese metal: Colloidal manganese. dysp. kidney damage TO: Resp sys. low-back pain.P: NA Wash skin: N. CNS. Manganese-55 Synonyms of other compounds vary depending upon the specific manganese compound. cough. blood. resp sys.20 (metal) Change: N.1 (see Table 2): BP: Sublimes Skin: Prevent skin contact Not available.R. Symptoms. ID125G [*Note: Also see specific listings for Manganese cyclopentadienyl tricarbonyl and Methyl cyclopentadienyl manganese tricarbonyl.9 (see Table 2): NIOSH BP: 3564°F Skin: N.Gr: ? Change: Daily VP: ? MLT: 167°F (Sublimes) UEL: ? LEL: ? Incompatibilities and Reactivities: Oxygen Combustible Solid Exposure Routes.R. cyclopentadienyl manganese tricarbonyl. silvery solid.] 7303.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 204. Con Eye: Irr immed SY: In animals: irrit skin.

Sol: 0. pneu Swallow: Medical attention immed TO: Resp sys. mental conf. Eyes: N. resp sys Marble 192 . ammonium salts First Aid (see Table 6): Exposure Routes. low-back pain.Gr: 4. Symptoms. acids. magnesium. ID125G Manganese tetroxide (as Mn) M Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 228. BP: Decomposes Not available. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 100.7-2. Manganomanganic oxide.001% Wash skin: N.R. 7301.R. IP: NA Change: Daily Sp.R. upper resp sys. Sp.1 Skin: N. CNS. IP: NA Change: N. skin. Skin: Soap wash Breath: Resp support lass.9 VP: 0 mmHg (approx) MLT: 1517-2442°F (Decomposes) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Fluorine.R. Con Eye: Irr immed SY: Asthenia. Fl. cough. Eyes: N. rhin. Natural calcium carbonate [Note: Marble is a metamorphic form of calcium carbonate. lac Breath: Fresh air TO: Eyes.P: NA Remove: N.88 VP: 0 mmHg (approx) MLT: 2847°F UEL: NA LEL: NA Incompatibilities and Reactivities: Soluble in hydrochloric acid (liberates chlorine gas) Exposure Routes. alum. kidneys Formula: CAS#: RTECS#: IDLH: CaCO3 1317-65-3 EV9580000 N. vomit.D. white powder.8 Skin: N. Fl.P: NA Remove: N. sneez. Conversion: DOT: Synonyms/Trade Names: Calcium carbonate. blood. Con Skin: Soap wash SY: Irrit eyes. skin. mal.Formula: CAS#: RTECS#: IDLH: Mn3O4 1317-35-7 OP0895000 N. OSHA PEL†: C 5 mg/m 9102 Physical Description: Brownish-black powder.R. Ing. Symptoms. muc memb. Sol: Insoluble Wash skin: N.R.Gr: 2.] OSHA ID121. BP: ? Not available. Target Organs (see Table 5): Eye: Irr immed ER: Inh. kidney damage. 7303. Conversion: DOT: Synonyms/Trade Names: Manganese oxide. [Note: Fumes are generated whenever manganese oxides are heated strongly in air. Trimanganese tetraoxide. insom.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500.R. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.R. Trimanganese tetroxide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 NIOSH 7300.R. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Odorless.D.

0012 mmHg §: ScbaF:Pd. anor.Gr: 13. skin burns.05 mg/m3 [skin] OSHA PEL†: C 0. Quicksilver Synonyms of “other” Hg compounds vary depending upon the specific compound. ammonia. constip. tremor.1 mg/m [skin] Physical Description: Metal: Silver-white.01 mg/m3 (see Table 1): OSHA PEL†: TWA 0. Exposure Limits: Measurement Methods NIOSH REL: Hg Vapor: TWA 0.Pp/SaF:Pd. Skin: Soap wash prompt irrity. heavy. Con SY: Irrit eyes. diarr.25 mg/m3: Sa:Cf/PaprS†(canister) Remove: When wet or contam Fl.5 mg/m : CcrS†/Sa Wash skin: When contam Sol: Insoluble 1. bron. Con Skin: Soap wash immed SY: Pares. odorless liquid. skin. Abs. hearing dist. dizz. kidney inj.P: NA 2. vomit. dysarthria. copper 10 mg/m3: Sa:Pd. lithium. chest pain. calcium (amalgam formation).R. BP: 674°F 0.Pp Provide: Eyewash §: ScbaF:Pd. PNS. indecision. Abs. Target Organs (see Table 5): Eye: Irr immed ER: Inh. kidneys Mercury compounds [except (organo) alkyls] (as Hg) Formula: Hg (metal) M Mercury (organo) alkyl compounds (as Hg) Formula: CAS#: RTECS#: IDLH: 2 mg/m3 (as Hg) Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific (organo) alkyl mercury compound.25 mg/m3: Sa:Cf alkyl mercury compound. skin.5 mg/m3: CcrFS†/GmFS†/SaT:Cf/ Change: Daily IP: ? PaprTS(canister)/ScbaF/SaF Sp. cough.Pp:AScba Escape: ScbaE Quick drench Incompatibilities and Reactivities: Strong oxidizers such as chlorine First Aid (see Table 6): Exposure Routes. head. pneu.01 mg/m3 3 3 None available C 0. 5 mg/m3: CcrFS†/GmFS†/SaT:Cf/ chlorine dioxide. kidneys 193 .Pp:AScba Escape: GmFS/ScbaE First Aid (see Table 6): Exposure Routes. resp sys. spasticity. CNS.5 mg/m3: Sa:Cf/PaprS†(canister) Incompatibilities and Reactivities: Acetylene. emotional Swallow: Medical attention immed dist. Remove: When wet or contam 0. lass. vision.1 mg/m3: Sa upon the specific (organo) Eyes: Prevent eye contact Wash skin: When contam 0. skin. salv.Pp:AScba FRZ: -38°F Escape: GmFS/ScbaE UEL: NA Other mercury compounds: LEL: NA NIOSH/OSHA Metal: Noncombustible Liquid 1 mg/m3: CcrS†/Sa 2.5 mg/m3: SaT:Cf/ScbaF/SaF Change: Daily 2 mg/m3: Sa:Pd.] Personal Protection/Sanitation Respirator Recommendations (see Tables Chemical & Physical (see Table 2): Properties: Mercury vapor: 3 and 4): Skin: Prevent skin contact MW: 200. insom. nau.6 (metal) 10 mg/m3: Sa:Pd. possible terato effects TO: Eyes.Pp §: ScbaF:Pd. Symptoms. Exposure Limits: Measurement Methods NIOSH REL: TWA 0. prot Breath: Resp support Swallow: Medical attention immed TO: Eyes. [Note: “Other” Hg compounds include all inorganic & aryl Hg compounds except (organo) alkyls. low-wgt. Ing.CAS#: RTECS#: IDLH: 7439-97-6 OV4550000 10 mg/m3 (as Hg) (metal) (metal) Conversion: DOT: 2809 172 (metal) Synonyms/Trade Names: Mercury metal: Colloidal mercury. jerking Breath: Resp support limbs. Symptoms.Pp/SaF:Pd.1 mg/m3 (see Table 1): 3 NIOSH 6009 OSHA ID140 Other: C 0. stomatitis. salv. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Metallic mercury.Pp VP: 0. dysp.04 mg/m ST 0. GI dist. rubidium. CNS. lac.03 mg/m [skin] Physical Description: Appearance and odor vary depending upon the specific (organo) alkyl mercury compound. PaprTS(canister)/ScbaF/SaF sodium carbide. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Properties vary depending Skin: Prevent skin contact 0. azides.6 NIOSH 3 Eyes: N. Ing. ataxia.Pp/SaF:Pd.

skin.02 (Liquid) Provide: Eyewash VP: 0. Symptoms.2 250 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 266°F 500 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: 3% Remove: When wet (flamm) Fl. skin.2% LEL: 1. resp sys.Pp:AScba Provide: Quick drench Sp. skin. Methyl isobutenyl ketone. Symptoms. in animals: liver. liver. Eyes: Prevent eye contact Sol(77°F): 9% Wash skin: When contam Fl. Methacrylic acid (inhibited).] Exposure Routes. narco. eye.Gr: 1. kidneys Mesityl oxide Methacrylic acid Conversion: 1 ppm = 3. Con Eye: Irr immed SY: Irrit eyes. acids Exposure Routes. IP: 9. CNS.08 eV §: ScbaF:Pd.86 Escape: GmFOv/ScbaE VP: 9 mmHg FRZ: -52°F UEL: 7. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 98. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 2553 OSHA PEL†: TWA 25 ppm (100 mg/m ) OSHA 7 Physical Description: Oily. 2-Methylpropenoic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 20 ppm (70 mg/m3) [skin] (see Table 1): OSHA PV2005 OSHA PEL†: none Physical Description: Colorless liquid or solid (below 61°F) with an acrid.Pp/SaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 86. coma. Ing.R.D. skin. muc memb.52 mg/m3 Formula: CAS#: CH2=C(CH3)COOH 79-41-4 DOT: 2531 153P (inhibited) RTECS#: OZ2975000 IDLH: N.P(oc): 171°F Remove: When wet or contam IP: ? Change: Daily Sp. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Synonyms/Trade Names: Methacrylic acid (glacial). repulsive odor. Ing.or honey-like odor.M Formula: CAS#: RTECS#: IDLH: (CH3)2C=CHCOCH3 141-79-7 SB4200000 1400 ppm [10%LEL] Conversion: 1 ppm = 4. 2-Methylacrylic acid. Con Skin: Water flush immed SY: Irrit eyes.7 mmHg FRZ: 61°F Quick drench UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers.Pp Change: N. elevated temperatures. Abs.1 Skin: Prevent skin contact BP: 325°F Not available. Isopropylideneacetone. 4-Methyl-3-penten-2-one Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (40 mg/m3) 3 NIOSH 1301.Gr(59°F): 0. hydrochloric acid [Note: Typically contains 100 ppm of the monomethyl ether of hydroquinone to prevent polymerization. α-Methacrylic acid.02 mg/m3 DOT: 1229 129 Synonyms/Trade Names: Isobutenyl methyl ketone. skin burns Breath: Resp support TO: Eyes.P: 87°F ScbaF/SaF 1400 ppm: SaF:Pd. colorless to light-yellow liquid with a peppermint. resp sys Swallow: Medical attention immed 194 . CNS effects Swallow: Medical attention immed TO: Eyes.4% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers. muc memb. Skin: Water flush immed Breath: Resp support kidney damage.

1. kidneys. Incompatibilities and Reactivities: Strong bases Exposure Routes. but difficult to burn. kidney.Gr: 1. Ing Breath: Fresh air SY: In animals: fasc. musc twitch. 2.Gr(75°F): 1. solid. nau. CVS.2 Skin: Prevent skin contact BP: ? Not available. salv. Incompatibilities and Reactivities: Oxidizers First Aid (see Table 6): Exposure Routes. [insecticide] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 345. toxic) Synonyms/Trade Names: Lannate®.1-Trichloro-2.1-trichloroethane. Con Eye: Irr immed SY: Irrit eyes. Symptoms. trembling. Methyl N-((methylamino)carbonyl)oxy)ethanimidothioate.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. Skin: Water flush immed Breath: Resp support vomit.p'-Dimethoxydiphenyltrichloroethane. DMDT.5 mg/m3 NIOSH 5601 OSHA PEL†: none Physical Description: White.P: ? Remove: When wet or contam IP: ? Change: Daily Sp. but may be dissolved in flammable liquids. Symptoms. crystalline solid with a slight.2-bis(p-Methoxyphenyl)-1. liver. liver. fruity odor. 1.2-bis-(p-methoxyphenyl)ethane Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH S371 (II-4) See Appendix A OSHA PEL†: TWA 15 mg/m3 OSHA PV2038 Physical Description: Colorless to light-yellow crystals with a slight.41 VP: Very low MLT: 171°F UEL: ? LEL: ? Combustible Solid. CNS. blurred vision. kidneys [in animals: liver & ovarian cancer] Methoxychlor 195 . Target Organs (see Table 5): Skin: Soap wash ER: Inh. liver. dysp.Pp:AScba Eyes: N.R. solid. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 162.29 Provide: Quick drench VP(77°F): 0.00005 mmHg MLT: 172°F UEL: NA LEL: NA Noncombustible Solid. resp sys.1. Methoxy-DDT. convuls.7 NIOSH Skin: Prevent skin contact BP: Decomposes ¥: ScbaF:Pd.D.00001% Wash skin: When contam/Daily Escape: GmFOv100/ScbaE Fl. kidney damage Swallow: Medical attention immed TO: Eyes. toxic) Synonyms/Trade Names: p. abdom cramps. S-Methyl-N-(methylcarbamoyloxy)thioacetimidate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2. Conversion: DOT: 2757 151 (carbamate pesticide. liver damage.Formula: CAS#: RTECS#: IDLH: CH3C(SCH3)NOC(O)NHCH3 16752-77-5 AK2975000 N. lass. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Sol: 0.Pp/SaF:Pd. Ing. miosis. Eyes: Prevent eye contact Sol(77°F): 6% Wash skin: When contam Fl. sulfur-like odor. [carc] Swallow: Medical attention immed TO: CNS. blood chol Methomyl M Formula: CAS#: RTECS#: IDLH: (C6H4OCH3)2CHCCl3 72-43-5 KJ3675000 Ca [5000 mg/m3] Conversion: DOT: 2761 151 (organochlorine pesticide.

Con Eye: Irr immed SY: Irrit eyes.Gr(77°F): 1. terato effects Swallow: Medical attention immed TO: Eyes. waxy solid with an odor of caramel & phenol.55 Provide: Eyewash VP: <0. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. analgesia.5 mg/m3) [60-minute] (see Table 1): [*Note: REL for exposure to waste anesthetic gas. convuls.2-Dichloro-1. CNS 4-Methoxyphenol 196 .0 Skin: N. in animals: repro. Ing.42 VP: 23 mmHg FRZ: -31°F UEL: ? LEL(176°F): 7% Combustible Liquid Incompatibilities and Reactivities: None reported Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 124. Ing. p-Methoxyphenol. Symptoms.D. acid anhydrides Exposure Routes. CNS depres. skin. Abs. BP: 220°F Not available.50 eV Change: Daily Sp.2-Dichloro-1. CNS.] None available OSHA PEL: none Physical Description: Colorless liquid with a fruity odor. Methoxyfluorane. eye. [inhalation anesthetic] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 165.01 mmHg MLT: 135°F Quick drench UEL: ? LEL: ? Combustible Solid.P: ? Remove: When wet or contam IP: ? Change: N. liver.M Formula: CAS#: RTECS#: IDLH: CHCl2CF2OCH3 76-38-0 KN7820000 N. strong bases. acid chlorides. Fl.P(oc): 270°F Remove: When wet or contam IP: 7. Incompatibilities and Reactivities: Strong oxidizers.D. kidneys. Mequinol. kidney inj. resp sys. a dust cloud can probably explode if ignited by a spark or flame. liver. Methoflurane. nose. anes. resp Breath: Resp support depres. Sp. Monomethyl ether hydroquinone Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): OSHA PEL†: none None available Physical Description: Colorless to white.R. Con Skin: Soap wash SY: Irrit eyes. Eyes: Prevent eye contact Sol: Slight Wash skin: N.R. skin burns.1-difluoroethyl methyl ether. under certain conditions.R. Skin: Soap flush immed Breath: Resp support CNS depres Swallow: Medical attention immed TO: Eyes. skin. Eyes: Prevent eye contact Sol(77°F): 4% Wash skin: When contam Fl. 2. repro sys Methoxyflurane CAS#: RTECS#: IDLH: Formula: 150-76-5 SL7700000 N. throat.75 mg/m3 DOT: Synonyms/Trade Names: 2.Gr: 1. CH3OC6H4OH Conversion: DOT: Synonyms/Trade Names: Hydroquinone monomethyl ether. p-Hydroxyanisole. Penthrane Exposure Limits: Measurement Methods NIOSH REL*: C 2 ppm (13. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Conversion: 1 ppm = 6.1-difluoro-1-methoxyethane.2 Skin: Prevent skin contact BP: 469°F Not available. Symptoms. upper resp sys.

Con (liquid) SY: Irrit resp sys. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. RGasD: 1.93 VP: 173 mmHg FRZ: -145°F UEL: 16% LEL: 3.1 NIOSH/OSHA Skin: Frostbite BP: -10°F 1700 ppm: Sa/ScbaF Eyes: Frostbite Sol: Insoluble §: ScbaF:Pd.36 eV Change: N.6 atmospheres of pressure.R.P: NA (Gas) Escape: GmFOv/ScbaE Remove: When wet (flamm) IP: 10.03 mg/m3 DOT: 1231 129 Synonyms/Trade Names: Methyl ester of acetic acid.] Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh. skin. in animals: narco Swallow: Medical attention immed TO: Eyes. resp sys.Gr: 0. strong oxidizers. anes.64 mg/m3 DOT: Synonyms/Trade Names: Allylene.1 2000 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 135°F 3100 ppm: Sa:Cf*/CcrFOv/GmFOv/ Wash skin: When contam Sol: 25% Remove: When wet (flamm) Fl. optic nerve atrophy. Symptoms. copper alloys [Note: Can decompose explosively at 4.Pp/SaF:Pd.] Exposure Routes.7% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers (such as chlorine). alkalis & acids. skin. water [Note: Reacts slowly with water to form acetic acid & methanol. CNS Methyl acetate M Formula: CAS#: RTECS#: IDLH: CH3C≡CH 74-99-7 UK4250000 1700 ppm [10%LEL] Conversion: 1 ppm = 1. [Note: A fuel that is shipped as a liquefied compressed gas. Skin: Water flush prompt Breath: Resp support chest tight.5 to 5. Fl. fruity odor. Ing. liquid: frostbite Skin: Frostbite Breath: Resp support TO: Resp sys. throat.R. Propine. CNS Methyl acetylene 197 . Symptoms. IP: 10.41 Provide: Frostbite wash VP: 5. nose.Pp/SaF:Pd. 1-Propyne Exposure Limits: Measurement Methods NIOSH REL: TWA 1000 ppm (1650 mg/m3) (see Table 1): 3 NIOSH S84 (II-5) OSHA PEL: TWA 1000 ppm (1650 mg/m ) Physical Description: Colorless gas with a sweet odor. head.27 eV Escape: GmFOv/ScbaE Sp.P: 14°F PaprOv*/ScbaF/SaF §: ScbaF:Pd.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 40. Methyl ethanoate Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (610 mg/m3) (see Table 1): 3 NIOSH 1458 ST 250 ppm (760 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 200 ppm (610 mg/m ) Physical Description: Colorless liquid with a fragrant. Con Eye: Irr immed SY: Irrit eyes.1% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates.Formula: CAS#: RTECS#: IDLH: CH3COOCH3 79-20-9 AI9100000 3100 ppm [10%LEL] Conversion: 1 ppm = 3. tremor.Pp:AScba Change: N.2 atm FRZ: -153°F UEL: ? LEL: 1. Propyne. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 74.R.Pp:AScba Wash skin: N. hyperexcitability. drow.

Methyl acetylene-propadiene mixture

Formula: CH3≡CH/CH2=C=CH2

CAS#: 59355-75-8

RTECS#: UK4920000

IDLH: 3400 ppm [10%LEL]

M

Conversion: 1 ppm = 1.64 mg/m3 DOT: 1060 116P (stabilized) Synonyms/Trade Names: MAPP gas, Methyl acetylene-allene mixture, Propadiene-methyl acetylene, Methyl acetylene-propadiene mixture (stabilized), Propyne-allene mixture, Propyne-propadiene mixture Exposure Limits: Measurement Methods NIOSH REL: TWA 1000 ppm (1800 mg/m3) (see Table 1): 3 NIOSH S85 (II-6) ST 1250 ppm (2250 mg/m ) 3 OSHA PEL†: TWA 1000 ppm (1800 mg/m ) OSHA 7 Physical Description: Colorless gas with a strong, characteristic, foul odor. [Note: A fuel that is shipped as a liquefied compressed gas.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Frostbite MW: 40.1 3400 ppm: Sa/ScbaF Eyes: Frostbite BP: -36 to -4°F §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Wash skin: N.R. Sol: Insoluble Escape: GmFS/ScbaE Remove: When wet (flamm) Fl.P: NA (Gas) Change: N.R. IP: ? Provide: Frostbite wash RGasD: 1.48 VP: >1 atm FRZ: -213°F UEL: 10.8% LEL: 3.4% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers, copper alloys [Note: Forms explosive compounds at high pressure in contact with alloys containing more than 67% copper.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh, Con (liquid) Skin: Frostbite SY: Irrit resp sys; excitement, conf, anes; liquid: frostbite Breath: Resp support TO: Resp sys, CNS

Formula: CAS#: RTECS#: IDLH: CH2=CHCOOCH3 96-33-3 AT2800000 250 ppm Conversion: 1 ppm = 3.52 mg/m DOT: 1919 129P (inhibited) Synonyms/Trade Names: Methoxycarbonylethylene, Methyl ester of acrylic acid, Methyl propenoate Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (35 mg/m3) [skin] (see Table 1): NIOSH 1459, 2552 OSHA PEL: TWA 10 ppm (35 mg/m3) [skin] OSHA 92 Physical Description: Colorless liquid with an acrid odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 86.1 100 ppm: Sa* Eyes: Prevent eye contact BP: 176°F 250 ppm: Sa:Cf*/ScbaF/SaF Wash skin: When contam Sol: 6% §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet (flamm) Fl.P: 27°F Escape: GmFOv/ScbaE Change: N.R. IP: 9.90 eV Provide: Quick drench Sp.Gr: 0.96 VP: 65 mmHg FRZ: -106°F UEL: 25% LEL: 2.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates, oxidizers such as peroxides, strong alkalis [Note: Polymerizes easily; usually contains an inhibitor such as hydroquinone.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Water flush immed SY: Irrit eyes, skin, upper resp sys Breath: Resp support TO: Eyes, skin, resp sys Swallow: Medical attention immed

Methyl acrylate

3

198

CAS#: RTECS#: IDLH: Formula: UD1400000 N.D. CH2=C(CH3)CN 126-98-7 Conversion: 1 ppm = 2.74 mg/m3 DOT: 3079 131P (inhibited) Synonyms/Trade Names: 2-Cyanopropene-1, 2-Cyano-1-propene, Isoprene cyanide, Isopropenylnitrile, Methacrylonitrile, α-Methylacrylonitrile, 2-Methylpropenenitrile Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (3 mg/m3) [skin] (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with an odor like bitter almonds. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 67.1 Skin: Prevent skin contact BP: 195°F Not available. Eyes: Prevent eye contact Sol: 3% Wash skin: When contam Fl.P: 34°F Remove: When wet (flamm) IP: ? Change: N.R. Sp.Gr: 0.80 VP(77°F): 71 mmHg FRZ: -32°F UEL: 6.8% LEL: 2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong acids, strong oxidizers, alkali, light [Note: Polymerization may occur due to elevated temperature, visible light, or contact with a concentrated alkali.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Ing, Con Eye: Irr immed SY: Irrit eyes, skin; lac; in animals: convuls, loss of motor control in Skin: Soap wash immed Breath: Resp support hind limbs Swallow: Medical attention immed TO: Eyes, skin, CNS

Methylacrylonitrile

M

Formula: CAS#: RTECS#: IDLH: CH3OCH2OCH3 109-87-5 PA8750000 2200 ppm [10%LEL] Conversion: 1 ppm = 3.11 mg/m3 DOT: 1234 127 Synonyms/Trade Names: Dimethoxymethane, Formal, Formaldehyde dimethylacetal, Methoxymethyl methyl ether, Methylene dimethyl ether Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1000 ppm (3100 mg/m3) 3 NIOSH 1611 OSHA PEL: TWA 1000 ppm (3100 mg/m ) Physical Description: Colorless liquid with a chloroform-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 76.1 2200 ppm: Sa/ScbaF Eyes: Prevent eye contact BP: 111°F §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Wash skin: When contam Sol: 33% Escape: GmFOv/ScbaE Remove: When wet (flamm) Fl.P(oc): -26°F Change: N.R. IP: 10.00 eV Sp.Gr: 0.86 VP: 330 mmHg FRZ: -157°F UEL: 13.8% LEL: 2.2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers, acids Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Water flush prompt SY: Irrit eyes, skin, upper resp sys; anes Breath: Resp support TO: Eyes, skin, resp sys, CNS Swallow: Medical attention immed

Methylal

199

M

CAS#: RTECS#: IDLH: Formula: 67-56-1 PC1400000 6000 ppm CH3OH Conversion: 1 ppm = 1.31 mg/m3 DOT: 1230 131 Synonyms/Trade Names: Carbinol, Columbian spirits, Methanol, Pyroligneous spirit, Wood alcohol, Wood naphtha, Wood spirit Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (260 mg/m3) (see Table 1): 3 NIOSH 2000, 3800 ST 250 ppm (325 mg/m ) [skin] 3 OSHA PEL†: TWA 200 ppm (260 mg/m ) OSHA 91 Physical Description: Colorless liquid with a characteristic pungent odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 32.1 NIOSH/OSHA Skin: Prevent skin contact BP: 147°F 2000 ppm: Sa Eyes: Prevent eye contact Sol: Miscible 5000 ppm: Sa:Cf Wash skin: When contam Fl.P: 52°F 6000 ppm: SaT:Cf/ScbaF/SaF Remove: When wet (flamm) IP: 10.84 eV §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Change: N.R. Sp.Gr: 0.79 Escape: ScbaE VP: 96 mmHg FRZ: -144°F UEL: 36% LEL: 6.0% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con SY: Irrit eyes, skin, upper resp sys; head, drow, dizz, nau, vomit; Skin: Water flush prompt Breath: Resp support vis dist, optic nerve damage (blindness); derm Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, GI tract

Methyl alcohol

Formula: CAS#: RTECS#: IDLH: CH3NH2 74-89-5 PF6300000 100 ppm Conversion: 1 ppm = 1.27 mg/m3 DOT: 1061 118 (anhydrous); 1235 132 (aqueous) Synonyms/Trade Names: Aminomethane, Methylamine (anhydrous), Methylamine (aqueous), Monomethylamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 ppm (12 mg/m3) 3 OSHA 40 OSHA PEL: TWA 10 ppm (12 mg/m ) Physical Description: Colorless gas with a fish- or ammonia-like odor. [Note: A liquid below 21°F. Shipped as a liquefied compressed gas.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact (solution) MW: 31.1 100 ppm: CcrFS/GmFS/PaprS£/ BP: 21°F Frostbite Eyes: Prevent eye contact (solution) Sol: Soluble ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Fl.P: NA (Gas) Frostbite Escape: GmFS/ScbaE Wash skin: When contam (solution) 14°F (Liquid) Remove: When wet (flamm) IP: 8.97 eV Change: N.R. RGasD: 1.08 Provide: Frostbite wash Sp.Gr: 0.70 (Liquid at 13°F) VP: 3.0 atm FRZ: -136°F UEL: 20.7% LEL: 4.9% Flammable Gas Incompatibilities and Reactivities: Mercury, strong oxidizers, nitromethane [Note: Corrosive to copper & zinc alloys, aluminum & galvanized surfaces.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed (solution)/Frostbite ER: Inh, Abs (solution), Ing (solution), Con (solution/liquid) Skin: Water flush immed (solution)/Frostbite SY: Irrit eyes, skin, resp sys; cough; skin, muc memb burns; Breath: Resp support derm; conj; liquid: frostbite Swallow: Medical attention immed (solution) TO: Eyes, skin, resp sys

Methylamine

200

Formula: CAS#: RTECS#: IDLH: CH3CO[CH2]4CH3 110-43-0 MJ5075000 800 ppm Conversion: 1 ppm = 4.67 mg/m3 DOT: 1110 127 Synonyms/Trade Names: Amyl methyl ketone, n-Amyl methyl ketone, 2-Heptanone Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (465 mg/m3) (see Table 1): 3 NIOSH 1301, 2553 OSHA PEL: TWA 100 ppm (465 mg/m ) Physical Description: Colorless to white liquid with a banana-like, fruity odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 114.2 800 ppm: CcrOv*/PaprOv*/GmFOv/ Eyes: Prevent eye contact BP: 305°F Wash skin: When contam Sol: 0.4% Sa*/ScbaF Remove: When wet or contam §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Fl.P: 102°F Change: N.R. Escape: GmFOv/ScbaE IP: 9.33 eV Sp.Gr: 0.81 VP: 3 mmHg FRZ: -32°F UEL(250°F): 7.9% LEL(151°F): 1.1% Class II Combustible Liquid Incompatibilities and Reactivities: Strong acids, alkalis & oxidizers [Note: Will attack some forms of plastic.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash SY: Irrit eyes, skin, muc memb; head; narco, coma; derm Breath: Fresh air TO: Eyes, skin, resp sys, CNS, PNS Swallow: Medical attention immed

Methyl (n-amyl) ketone

M

Formula: CAS#: RTECS#: IDLH: CH3Br 74-83-9 PA4900000 Ca [250 ppm] Conversion: 1 ppm = 3.89 mg/m3 DOT: 1062 123 Synonyms/Trade Names: Bromomethane, Monobromomethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 2520 See Appendix A 3 OSHA PV2040 OSHA PEL†: C 20 ppm (80 mg/m ) [skin] Physical Description: Colorless gas with a chloroform-like odor at high concentrations. [Note: A liquid below 38°F. Shipped as a liquefied compressed gas.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 95.0 (see Table 2): NIOSH BP: 38°F Skin: Prevent skin contact (liquid) ¥: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Sol: 2% Eyes: Prevent eye contact (liquid) Escape: GmFOv/ScbaE Fl.P: NA (Gas) Wash skin: When contam (liquid) IP: 10.54 eV Remove: When wet (flamm) RGasD: 3.36 Change: N.R. Sp.Gr: 1.73 (Liquid at 32°F) Provide: Quick drench (liquid) VP: 1.9 atm FRZ: -137°F UEL: 16.0% LEL: 10% Flammable Gas, but only in Incompatibilities and Reactivities: Aluminum, magnesium, strong oxidizers presence of a high energy ignition [Note: Attacks aluminum to form aluminum trimethyl, which is source. SPONTANEOUSLY flammable.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs (liquid), Con (liquid) Eye: Irr immed (liquid) SY: Irrit eyes, skin, resp sys; musc weak, inco, vis dist, dizz; nau, vomit, head; Skin: Water flush immed (liquid) Breath: Resp support mal; hand tremor; convuls; dysp; skin vesic; liquid: frostbite; [carc] TO: Eyes, skin, resp sys, CNS [in animals: lung, kidney & forestomach tumors]

Methyl bromide

201

CAS#: RTECS#: IDLH: Formula: KL5775000 200 ppm CH3OCH2CH2OH 109-86-4 Conversion: 1 ppm = 3.11 mg/m3 DOT: 1188 127 Synonyms/Trade Names: EGME, Ethylene glycol monomethyl ether, Glycol monomethyl ether, 2-Methoxyethanol Exposure Limits: Measurement Methods NIOSH REL: TWA 0.1 ppm (0.3 mg/m3) [skin] (see Table 1): 3 NIOSH 1403 OSHA PEL: TWA 25 ppm (80 mg/m ) [skin] OSHA 53, 79 Physical Description: Colorless liquid with a mild, ether-like odor.

Methyl Cellosolve®

M

Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 76.1 1 ppm: Sa* Eyes: Prevent eye contact BP: 256°F 2.5 ppm: Sa:Cf* Wash skin: When contam Sol: Miscible 5 ppm: ScbaF/SaF Remove: When wet or contam Fl.P: 102°F 100 ppm: Sa:Pd,Pp* Change: N.R. IP: 9.60 eV 200 ppm: SaF:Pd,Pp Provide: Quick drench Sp.Gr: 0.96 §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba VP: 6 mmHg Escape: GmFOv/ScbaE FRZ: -121°F UEL: 14% LEL: 1.8% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers, caustics Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Ing, Con Eye: Irr immed SY: Irrit eyes, nose, throat; head, drow, lass; ataxia, tremor; Skin: Water flush prompt Breath: Resp support anemic pallor; in animals: repro, terato effects TO: Eyes, resp sys, CNS, blood, kidneys, repro sys, hemato sys Swallow: Medical attention immed

Formula: CAS#: RTECS#: IDLH: CH3COOCH2CH2OCH3 110-49-6 KL5950000 200 ppm Conversion: 1 ppm = 4.83 mg/m3 DOT: 1189 129 Synonyms/Trade Names: EGMEA, Ethylene glycol monomethyl ether acetate, Glycol monomethyl ether acetate, 2-Methoxyethyl acetate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.1 ppm (0.5 mg/m3 [skin] 3 NIOSH 1451 OSHA PEL: TWA 25 ppm (120 mg/m ) [skin] OSHA 53, 79 Physical Description: Colorless liquid with a mild, ether-like odor.

Methyl Cellosolve® acetate

Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 118.1 1 ppm: Sa* Eyes: Prevent eye contact BP: 293°F 2.5 ppm: Sa:Cf* Wash skin: When contam Sol: Miscible 5 ppm: ScbaF/SaF Remove: When wet or contam Fl.P: 120°F 100 ppm: Sa:Pd,Pp* Change: N.R. IP: ? 200 ppm: SaF:Pd,Pp Sp.Gr: 1.01 §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba VP: 2 mmHg Escape: GmFOv/ScbaE FRZ: -85°F UEL: 8.2% LEL: 1.7% Class II Combustible Liquid Incompatibilities and Reactivities: Nitrates; strong oxidizers, alkalis & acids Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Ing, Con Eye: Irr immed SY: Irrit eyes, nose, throat; kidney, brain damage; in animals: narco; Skin: Water flush prompt Breath: Resp support repro, terato effects Swallow: Medical attention immed TO: Eyes, resp sys, kidneys, brain, CNS, PNS, repro sys, hemato sys

202

CAS#: RTECS#: IDLH: Formula: 74-87-3 PA6300000 Ca [2000 ppm] CH3Cl Conversion: 1 ppm = 2.07 mg/m3 DOT: 1063 115 Synonyms/Trade Names: Chloromethane, Monochloromethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1001 See Appendix A OSHA PEL†: TWA 100 ppm C 200 ppm 300 ppm (5-minute maximum peak in any 3 hours) Physical Description: Colorless gas with a faint, sweet odor which is not noticeable at dangerous concentrations. [Note: Shipped as a liquefied compressed gas.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 50.5 NIOSH Skin: Frostbite BP: -12°F ¥: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Eyes: Frostbite Sol: 0.5% Escape: ScbaE Wash skin: N.R. Fl.P: NA (Gas) Remove: When wet (flamm) IP: 11.28 eV Change: N.R. RGasD: 1.78 Provide: Frostbite wash VP: 5.0 atm FRZ: -144°F UEL: 17.4% LEL: 8.1% Flammable Gas Incompatibilities and Reactivities: Chemically-active metals such as potassium, powdered aluminum, zinc, and magnesium; water [Note: Reacts with water (hydrolyzes) to form hydrochloric acid.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Con (liquid) Eye: Frostbite SY: Dizz, nau, vomit; vis dist, stagger, slurred speech, convuls, coma; Skin: Frostbite Breath: Resp support liver, kidney damage; liquid: frostbite; repro, terato effects; [carc] TO: CNS, liver, kidneys, repro sys [in animals: lung, kidney & forestomach tumors]

Methyl chloride

M

Formula: CAS#: RTECS#: IDLH: CH3CCl3 71-55-6 KJ2975000 700 ppm Conversion: 1 ppm = 5.46 mg/m DOT: 2831 160 Synonyms/Trade Names: Chlorothene; 1,1,1-Trichloroethane; 1,1,1-Trichloroethane (stabilized) Exposure Limits: Measurement Methods NIOSH REL: C 350 ppm (1900 mg/m3) [15-minute] (see Table 1): NIOSH 1003 See Appendix C (Chloroethanes) 3 OSHA PEL†: TWA 350 ppm (1900 mg/m ) Physical Description: Colorless liquid with a mild, chloroform-like odor. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 133.4 (see Table 2): NIOSH/OSHA BP: 165°F Skin: Prevent skin contact 700 ppm: Sa*/ScbaF Sol: 0.4% Eyes: Prevent eye contact §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Fl.P: ? Wash skin: When contam Escape: GmFOv/ScbaE IP: 11.00 eV Remove: When wet or contam Sp.Gr: 1.34 Change: N.R. VP: 100 mmHg FRZ: -23°F Incompatibilities and Reactivities: Strong caustics; strong oxidizers; UEL: 12.5% chemically-active metals such as zinc, aluminum, magnesium powders, LEL: 7.5% sodium & potassium; water Combustible Liquid, but burns with [Note: Reacts slowly with water to form hydrochloric acid.] difficulty.

Methyl chloroform

3

Exposure Routes, Symptoms, Target Organs (see Table 5): ER: Inh, Ing, Con SY: Irrit eyes, skin; head, lass, CNS depres, poor equi; derm; card arrhy; liver damage TO: Eyes, skin, CNS, CVS, liver

First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed

203

Methyl-2-cyanoacrylate
Conversion: 1 ppm = 4.54 mg/m3

Formula: CH2=C(CN)COOCH3 DOT:

CAS#: 137-05-3

RTECS#: AS7000000

IDLH: N.D.

M

Synonyms/Trade Names: Mecrylate, Methyl cyanoacrylate, Methyl α-cyanoacrylate, Methyl ester of 2-cyanoacrylic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (8 mg/m3) (see Table 1): 3 OSHA 55 ST 4 ppm (16 mg/m ) OSHA PEL†: none Physical Description: Colorless liquid with a characteristic odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 111.1 Skin: Prevent skin contact BP: ? Not available. Eyes: Prevent eye contact Sol: 30% Wash skin: Daily Fl.P: 174°F Remove: N.R. IP: ? Change: N.R. Sp.Gr(81°F): 1.10 Provide: Eyewash VP(77°F): 0.2 mmHg FRZ: ? UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Moisture [Note: Contact with moisture causes rapid polymerization.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Water wash SY: Irrit eyes, skin, nose; blurred vision, lac; rhinitis Breath: Resp support TO: Eyes, skin, resp sys Swallow: Medical attention immed

Formula: CAS#: RTECS#: IDLH: CH3C6H11 108-87-2 GV6125000 1200 ppm [LEL] Conversion: 1 ppm = 4.02 mg/m3 DOT: 2296 128 Synonyms/Trade Names: Cyclohexylmethane, Hexahydrotoluene Exposure Limits: Measurement Methods NIOSH REL: TWA 400 ppm (1600 mg/m3) (see Table 1): 3 OSHA PEL†: TWA 500 ppm (2000 mg/m ) NIOSH 1500 OSHA 7 Physical Description: Colorless liquid with a faint, benzene-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 98.2 1200 ppm: Sa/ScbaF Eyes: Prevent eye contact BP: 214°F §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Wash skin: When contam Sol: Insoluble Escape: GmFOv/ScbaE Remove: When wet (flamm) Fl.P: 25°F Change: N.R. IP: 9.85 eV Sp.Gr: 0.77 VP: 37 mmHg FRZ: -196°F UEL: 6.7% LEL: 1.2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash prompt SY: Irrit eyes, skin, nose, throat; dizz, drow; in animals: narco Breath: Resp support TO: Eyes, skin, resp sys, CNS Swallow: Medical attention immed

Methylcyclohexane

204

CAS#: RTECS#: IDLH: Formula: 25639-42-3 GW0175000 500 ppm CH3C6H10OH Conversion: 1 ppm = 4.67 mg/m3 DOT: 2617 129 Synonyms/Trade Names: Hexahydrocresol, Hexahydromethylphenol Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (235 mg/m3) (see Table 1): 3 NIOSH 1404 OSHA PEL†: TWA 100 ppm (470 mg/m ) Physical Description: Straw-colored liquid with a weak odor like coconut oil. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 114.2 500 ppm: Sa*/ScbaF Eyes: Prevent eye contact BP: 311-356°F §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Wash skin: When contam Sol: 4% Escape: GmFOv/ScbaE Remove: When wet or contam Fl.P: 149-158°F Change: N.R. IP: 9.80 eV Sp.Gr: 0.92 VP(86°F): 2 mmHg FRZ: -58°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Ing, Con Eye: Irr immed SY: Irrit eyes, skin, upper resp sys; head; in animals: narco; liver, Skin: Soap wash prompt Breath: Resp support kidney damage Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, kidneys, liver

Methylcyclohexanol

M

Formula: CAS#: RTECS#: IDLH: CH3C6H9O 583-60-8 GW1750000 600 ppm Conversion: 1 ppm = 4.59 mg/m3 DOT: 2297 128 Synonyms/Trade Names: 2-Methylcyclohexanone Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (230 mg/m3) [skin] (see Table 1): 3 NIOSH 2521 ST 75 ppm (345 mg/m ) 3 OSHA PEL†: TWA 100 ppm (460 mg/m ) [skin] Physical Description: Colorless liquid with a weak, peppermint-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 112.2 500 ppm: Sa* Eyes: Prevent eye contact BP: 325°F 600 ppm: Sa:Cf*/ScbaF/SaF Wash skin: When contam Sol: Insoluble §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet or contam Fl.P: 118°F Escape: GmFOv/ScbaE Change: N.R. IP: ? Sp.Gr: 0.93 VP: 1 mmHg FRZ: 7°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Soap wash prompt SY: In animals: irrit eyes, muc memb; narco; derm Breath: Resp support TO: Skin, resp sys, liver, kidneys, CNS Swallow: Medical attention immed

o-Methylcyclohexanone

205

Methyl cyclopentadienyl manganese tricarbonyl (as Mn)

Formula: CAS#: CH3C5H4Mn(CO)3 12108-13-3

RTECS#: OP1450000

IDLH: N.D.

M

Conversion: DOT: Synonyms/Trade Names: CI-2, Combustion Improver-2, Manganese tricarbonylmethylcyclopentadienyl, 2-Methylcyclopentadienyl manganese tricarbonyl, MMT Exposure Limits: Measurement Methods NIOSH REL: TWA 0.2 mg/m3 [skin] (see Table 1): 3 OSHA PEL†: C 5 mg/m None available Physical Description: Yellow to dark-orange liquid with a faint, pleasant odor. [Note: A solid below 36°F.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 218.1 Skin: Prevent skin contact BP: 449°F Not available. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.P: 230°F Remove: When wet or contam IP: ? Change: N.R. Sp.Gr: 1.39 VP(212°F): 7 mmHg FRZ: 36°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Light (decomposes) Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Ing, Con Eye: Irr immed SY: Irrit eyes; dizz, nau, head; in animals: tremor, severe clonic Skin: Soap wash immed Breath: Resp support spasms, lass, slow respiration; liver, kidney inj Swallow: Medical attention immed TO: Eyes, CNS, liver, kidneys

Formula: CAS#: RTECS#: IDLH: C6H15O3PS2 8022-00-2 TG1760000 N.D. Conversion: DOT: Synonyms/Trade Names: Demeton methyl; O,O-Dimethyl 2-ethylmercaptoethyl thiophosphate; Metasystox®; Methyl mercaptophos; Methyl systox® Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.5 mg/m3 [skin] OSHA PEL†: none None available Physical Description: Oily, colorless to pale-yellow liquid with an unpleasant odor. [insecticide] [Note: Technical grade consists of 2 isomers: thiono & thiolo.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 230.3 Skin: Prevent skin contact BP: Decomposes Not available. Eyes: Prevent eye contact Sol: 0.03-0.3% Wash skin: When contam Fl.P: ? Remove: When wet or contam IP: ? Change: Daily Sp.Gr: 1.20 Provide: Eyewash VP: 0.0004 mmHg FRZ: ? Quick drench UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers, alkalis, water Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Soap wash immed SY: Irrit eyes, skin; ache eyes, rhin; nau, head, dizz, vomit Breath: Resp support TO: Eyes, skin, resp sys, CNS, CVS, blood chol Swallow: Medical attention immed

Methyl demeton

206

resp sys. organotin catalysts [Note: May slowly polymerize if heated above 122°F. colorless to light-yellow liquid. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 262. chest tight.R.44 VP(77°F): 0. magnesium. kidney irrit. [carc] Breath: Resp support TO: Liver. lung & bladder tumors] Swallow: Medical attention immed M Methylene bis(4-cyclohexylisocyanate) CH [(C H )NCO] 2 6 10 2 Formula: CAS#: 5124-30-1 RTECS#: NQ9250000 IDLH: N. IP: ? §: ScbaF:Pd.D. 4. 71 TWA 0. Ing. Target Organs (see Table 5): Eye: Irr immed ER: Inh.00001 mmHg Quick drench MLT: 230°F UEL: ? LEL: ? Incompatibilities and Reactivities: Chemically-active metals (e. ethanol. zinc) First Aid (see Table 6): Exposure Routes. Con Eye: Irr immed SY: Irrit eyes.1 ppm: Sa* Eyes: Prevent eye contact BP: ? 0.Pp Change: N.4'-diisocyanate. Saturated MDI Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. pulm edema. Abs.Gr(77°F): 1.3'-Dichloro-4. MOCA Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 OSHA 24.Pp/SaF:Pd.Gr: 1. bis(4-Isocyanatocyclohexyl)methane. kidneys [in animals: liver. cyan.Pp:AScba Eyes: Prevent eye contact BP: ? Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: Slight Remove: When wet or contam Fl. Con Skin: Soap flush immed SY: Hema. bases. skin. dry throat.01 ppm (0. sodium.g. amine-like odor. 4. amines.Pp:AScba Provide: Quick drench Sp.4'-Methylenebis(2-chlorobenzenamine).2 ¥: ScbaF:Pd. 3. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 267. resp sens.11 mg/m3) NIOSH 5525 OSHA PEL†: none OSHA PV2092 Physical Description: Clear. wheez. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Reduced MDI. blood. DMDI.4.4'-Methylenebis(o-chloro aniline).] Exposure Routes.003 mg/m [skin] See Appendix A OSHA PEL†: none Physical Description: Tan-colored pellets or flakes with a faint.P: ? Change: Daily IP: ? Provide: Eyewash Sp. HMDI. acids. skin blisters Swallow: Medical attention immed TO: Eyes. alcohols. Symptoms. Skin: Water flush immed Breath: Resp support cough.4'-Methylenebis(2-chloroaniline) CH (C H ClNH ) 101-14-4 2 6 4 2 2 Formula: CAS#: RTECS#: CY1050000 IDLH: Ca [N.P: >395°F 1 ppm: SaF:Pd.07 Escape: GmFOv/ScbaE VP(77°F): 0. Ing. skin. Hydrogenated MDI.. MBOCA. skin.5 ppm: ScbaF/SaF Remove: When wet or contam Fl. Symptoms. potassium.001 mmHg FRZ: <14°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Water.25 ppm: Sa:Cf* Wash skin: When contam Sol: Reacts 0.4 0. dysp.D. methemo. resp sys 207 .Pp/SaF:Pd. nau.4'-diaminodiphenylmethane.] Conversion: DOT: Synonyms/Trade Names: DACPM.73 mg/m3 DOT: Synonyms/Trade Names: Dicyclohexylmethane 4. Conversion: 1 ppm = 10.

Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms.2 mg/m (0. numb. skin. [carc] Skin: Soap wash prompt TO: Eyes. drow. Symptoms.Pp/SaF:Pd. cough. [Note: A liquid above 99°F.R.2 mg/m (0. chemically-active metals such as aluminum. dysp.Gr: 1. 3800 See Appendix A OSHA 59.5 mg/m3: Sa* Eyes: Prevent eye contact Sol: 0.47 mg/m3 DOT: 1593 160 Synonyms/Trade Names: Dichloromethane. resp sys Methylene bisphenyl isocyanate Formula: CAS#: RTECS#: IDLH: CH2Cl2 75-09-2 PA8050000 Ca [2300 ppm] Conversion: 1 ppm = 3. IP: 11. dizz.005 ppm) 3 NIOSH 5521.Pp:AScba Eyes: Prevent eye contact BP: 104°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: 2% Remove: When wet or contam Fl. Methylene dichloride Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 1005. magnesium powders. liver.3 NIOSH Skin: Prevent skin contact BP: 597°F 0. MDI. concentrated nitric acid Exposure Routes. CNS [in animals: lung. Methylene di-p-phenylene ester of isocyanic acid Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Abs.23 (Solid at 77°F) 75 mg/m3: SaF:Pd.P: 390°F 1. potassium & sodium.33 VP: 350 mmHg Quick drench FRZ: -139°F UEL: 23% LEL: 13% Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. resp sens.Pp/SaF:Pd.M Formula: CAS#: RTECS#: IDLH: CH2(C6H4NCO)2 101-68-8 NQ9350000 75 mg/m3 Conversion: 1 ppm = 10. Ing. nose.020 ppm) [10-minute] 3 OSHA 18 OSHA PEL: C 0.Pp §: ScbaF:Pd.4'-Diphenylmethane diisocyanate.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 84. asthma Swallow: Medical attention immed TO: Eyes. 80 OSHA PEL: [1910. lass.P: ? See Appendix E (page 351) Change: N. pulm secretions. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.05 mg/m3 (0.000005 mmHg Escape: GmFOv100/ScbaE MLT: 99°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong alkalis. caustics. CVS. skin.9 ¥: ScbaF:Pd.24 mg/m3 DOT: Synonyms/Trade Names: 4. Con Eye: Irr immed SY: Irrit eyes. 5525 C 0. Skin: Soap wash immed Breath: Resp support chest pain. salivary & mammary Breath: Resp support Swallow: Medical attention immed gland tumors] Methylene chloride 208 . odorless flakes. [Note: A gas above 104°F. acids. 5522.1052] TWA 25 ppm ST 125 ppm Physical Description: Colorless liquid with a chloroform-like odor.25 mg/m3: Sa:Cf* Remove: When wet or contam IP: ? 2. Con Eye: Irr immed SY: Irrit eyes.2% Wash skin: When contam Fl.32 eV Provide: Eyewash Sp. Ing.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 250.Gr: 1. Methylene bis(4-phenyl isocyanate). nau.Pp:AScba 1.] Exposure Routes. throat.02 ppm) Physical Description: White to light-yellow.5 mg/m3: ScbaF/SaF Change: Daily Sp. tingle limbs. alcohol [Note: Polymerizes at 450°F.19 (Liquid at 122°F) VP(77°F): 0.

2 ppm (1.] Conversion: DOT: Synonyms/Trade Names: 4.P: 374°F Wash skin: When contam/Daily IP: 10. resp sys. MDA Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 5029 See Appendix A OSHA PEL: [1910. [carc] TO: Eyes. kidney damage TO: Eyes. Ethyl methyl ketone peroxide. liver. Pure MEKP is shock sensitive. MEKP. Symptoms. Conversion: 1 ppm = 7. jaun. Sp. flames. Breath: Resp support blurred vision. blisters.4'-Diphenylmethanediamine.Gr(59°F): 1.4'-Methylenedianiline Exposure Routes. skin. [Note: Explosive decomposition occurs at 230°F.D. heat. Con Skin: Water wash immed SY: Irrit eyes. cyclohexane peroxide.0000002 mmHg Provide: Eyewash MLT: 198°F Quick drench UEL: ? LEL: ? Incompatibilities and Reactivities: Strong oxidizers Combustible Solid 4. Target Organs (see Table 5): ER: Inh. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. myocardial damage. abdom pain.010 ppm ST 0. Abs. Ing. nose.D. sunlight.Pp/SaF:Pd.2 Skin: Prevent skin contact BP: 244°F (Decomposes) Not available. in animals: heart. Commercial product is diluted with 40% dimethyl phthalate. diarr. in animals: liver. hepatitis. pulm edema. dysp. Swallow: Medical attention immed derm. Methyl ethyl ketone hydroperoxide Exposure Limits: Measurement Methods NIOSH REL: C 0.4'-Diaminodiphenylmethane.Gr: 1. Eyes: Prevent eye contact Sol: Soluble Wash skin: When contam Fl. spleen [in animals: bladder cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed M Formula: CAS#: RTECS#: IDLH: C8H16O4 1338-23-4 EL9450000 N.Pp:AScba Sol: 0. spleen damage. liver.P(oc): 125-200°F (60% MEKP) Remove: When wet or contam IP: ? Change: N. crystalline solid with a faint. para. kidneys Methyl ethyl ketone peroxide 3 209 .1050] TWA 0.21 mg/m DOT: Synonyms/Trade Names: 2-Butanone peroxide. Symptoms. amine-like odor. MEK peroxide. Dianilinomethane.Formula: CAS#: RTECS#: IDLH: CH2(C6H4NH2)2 101-77-9 BY5425000 Ca [N.1% Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl. 4. skin.R.12 Provide: Eyewash VP: ? FRZ: ? Quick drench UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Organic materials. liver.70 eV Remove: When wet or contam See Appendix E (page 351) Sp. or diallyl phthalate to reduce sensitivity to shock.3 (see Table 2): NIOSH BP: 748°F Skin: Prevent skin contact ¥: ScbaF:Pd. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 198. Ing.100 ppm Physical Description: Pale-brown. CVS. Con SY: Irrit eyes. throat.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 176.5 mg/m3) (see Table 1): NIOSH 3508 OSHA PEL†: none OSHA 77 Physical Description: Colorless liquid with a characteristic odor. vomit. cough.] Exposure Routes. scars skin.06 (Liquid at 212°F) Change: Daily VP(77°F): 0. para'-Diaminodiphenyl-methane. trace contaminants [Note: A strong oxidizing agent.

82 eV Escape: GmFOv/ScbaE Sp. CNS depres. coma. IP: ? Sp. Ing. skin. Con Skin: Water flush SY: Irrit eyes. IP: 10. 3-Methyl-5-heptanone Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 25 ppm (130 mg/m3) 3 NIOSH 1301. narco Swallow: Medical attention immed TO: Eyes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.P: 138°F Escape: GmFOv/ScbaE Change: N. CNS Swallow: Medical attention immed 5-Methyl-3-heptanone 3 210 . Con Skin: Soap wash immed SY: Irrit eyes. chest tight.98 VP: 476 mmHg FRZ: -148°F UEL: 23% LEL: 4. resp sys.24 mg/m DOT: 2271 127 Synonyms/Trade Names: Amyl ethyl ketone. resp sys. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 128.5% Class IA Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Reacts slowly with water to form methanol & formic acid.Gr: 0. Abs.Pp:AScba Remove: When wet or contam Fl.M Formula: CAS#: RTECS#: IDLH: HCOOCH3 107-31-3 LQ8925000 4500 ppm Conversion: 1 ppm = 2.1 1000 ppm: Sa* Eyes: Prevent eye contact BP: 89°F 2500 ppm: Sa:Cf* Wash skin: When contam Sol: 30% 4500 ppm: ScbaF/SaF Remove: When wet (flamm) Fl.Pp:AScba Change: N. derm Breath: Resp support TO: Eyes.2 100 ppm: CcrOv*/PaprOv*/GmFOv/ Eyes: Prevent eye contact BP: 315°F Wash skin: When contam Sol: Insoluble Sa*/ScbaF §: ScbaF:Pd.46 mg/m3 DOT: 1243 129 Synonyms/Trade Names: Methyl ester of formic acid.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 60. head.Pp/SaF:Pd. skin.Gr: 0. muc memb. vis dist. CNS Methyl formate Formula: CAS#: RTECS#: IDLH: C2H5COCH2CH(CH3)CH2CH3 541-85-5 MJ7350000 100 ppm Conversion: 1 ppm = 5. Methyl methanoate Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (250 mg/m3) (see Table 1): 3 NIOSH S291 (II-5) ST 150 ppm (375 mg/m ) 3 OSHA PV2041 OSHA PEL†: TWA 100 ppm (250 mg/m ) Physical Description: Colorless liquid with a pleasant odor.R. 2553 OSHA PEL: TWA 25 ppm (130 mg/m ) Physical Description: Colorless liquid with a pungent odor. in Breath: Resp support animals: pulm edema. Symptoms.] Exposure Routes. Ing.P: -2°F §: ScbaF:Pd.82 VP: 2 mmHg FRZ: -70°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. dysp. Ethyl amyl ketone. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. Symptoms. nose. narco. [Note: A gas above 89°F.Pp/SaF:Pd.

hydrogen peroxide First Aid (see Table 6): Exposure Routes.Pp:AScba Eyes: Prevent eye contact Sol: 1% Escape: GmFOv/ScbaE Wash skin: When contam Fl.Pp/SaF:Pd. resp sys.Pp:AScba Sol: Miscible Eyes: Prevent eye contact Escape: ScbaE Fl.35 mg/m ) [skin] Physical Description: Fuming. derm.9 NIOSH Skin: Prevent skin contact BP: 109°F ¥: ScbaF:Pd.Formula: CAS#: RTECS#: IDLH: CH3NHNH2 60-34-4 MV5600000 Ca [20 ppm] Conversion: 1 ppm = 1. blood vessel & intestine tumors] Methyl hydrazine M CAS#: RTECS#: IDLH: Formula: 74-88-4 PA9450000 Ca [100 ppm] CH3I Conversion: 1 ppm = 5. CNS. copper.2 ppm (0. Sp. [carc] TO: Eyes. blood.Gr(77°F): 0. Con Eye: Irr immed SY: Irrit eyes.00 eV Remove: When wet (flamm) Sp. kidney & forestomach tumors] Methyl iodide 3 211 . LEL: 2.28 Provide: Eyewash VP: 400 mmHg FRZ: -88°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Decomposes at 518°F. tremor. porous materials such as earth. resp sys. nau. Ing.04 ppm (0. Abs. Swallow: Medical attention immed liver.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 141. Con Skin: Water flush immed SY: Irrit eyes. Monoiodomethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1014 TWA 2 ppm (10 mg/m3) [skin] See Appendix A 3 OSHA PEL: TWA 5 ppm (28 mg/m ) [skin] Physical Description: Colorless liquid with a pungent. skin. ataxia. [Note: Turns yellow. skin. skin. Target Organs (see Table 5): Eye: Irr immed ER: Inh.80 mg/m DOT: 2644 151 Synonyms/Trade Names: Iodomethane.R. asbestos. convuls. Breath: Resp support cyan.Pp/SaF:Pd. drow.P: 17°F Wash skin: When contam IP: 8. resp sys. Monomethylhydrazine Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 3510 C 0. Class IB Flammable Liquid strong oxidizers such as fluorine & chlorine. Abs.54 eV Change: N. Symptoms. ether-like odor.87 Change: N. CNS [in animals: lung.P: NA Remove: When wet or contam IP: 9.08 mg/m ) [2-hr] See Appendix A 3 OSHA PEL: C 0. nitric acid.R. colorless liquid with an ammonia-like odor.5% lead. VP: 38 mmHg Provide: Eyewash FRZ: -62°F Quick drench UEL: 92% Incompatibilities and Reactivities: Oxides of iron. Symptoms. CVS [in animals: lung. anoxia. vomit. vomit.] Exposure Routes. ataxia. skin. [carc] Swallow: Medical attention immed TO: Eyes. liver.Gr: 2. slurred Skin: Soap flush immed Breath: Resp support speech. copper alloys. resp sys. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 46. manganese. Ing. red. or brown on exposure to light & moisture. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.89 mg/m3 DOT: 1244 131 Synonyms/Trade Names: MMH. diarr. wood & cloth. dizz.1 (see Table 2): NIOSH BP: 190°F Skin: Prevent skin contact ¥: ScbaF:Pd.

4-Methyl-2-pentanol.P: 106°F Escape: GmFOv/ScbaE Change: N. kidney damage Swallow: Medical attention immed TO: Eyes. resp sys. in Breath: Resp support animals: liver.Gr: 0.Pp:AScba VP: 5 mmHg Escape: GmFOv/ScbaE FRZ: -101°F UEL(200°F): 8.81 §: ScbaF:Pd. Ing. IP: ? Sp. drow.2 250 ppm: Sa* Eyes: Prevent eye contact BP: 271°F 400 ppm: Sa:Cf*/ScbaF/SaF Wash skin: When contam Sol: 2% §: ScbaF:Pd. MIBC Exposure Limits: Measurement Methods NIOSH REL: TWA 25 ppm (100 mg/m3) (see Table 1): 3 NIOSH 1402.5% 2500 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet (flamm) Fl. Con Skin: Soap flush prompt SY: Irrit eyes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 114.81 VP: 3 mmHg FRZ: -130°F UEL: 5. kidneys Methyl isoamyl ketone Formula: CAS#: RTECS#: IDLH: (CH3)2CHCH2CH(OH)CH3 108-11-2 SA7350000 400 ppm Conversion: 1 ppm = 4. 2-Methyl-5-hexanone.D. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 102. Symptoms. derm. narco. muc memb.67 mg/m3 DOT: 2302 127 Synonyms/Trade Names: Isoamyl methyl ketone.M Formula: CAS#: RTECS#: IDLH: CH3COCH2CH2CH(CH3)2 110-12-3 MP3850000 N.284 eV SaT:Cf*/ScbaF/SaF 5000 ppm: SaF:Pd. Ing.R. skin. Methyl amyl alcohol.P: 97°F Change: N. derm. head. skin.Pp/SaF:Pd.Gr: 0. liver. skin.5% LEL: 1. Conversion: 1 ppm = 4.0% Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Symptoms. head. Con Skin: Water flush prompt SY: Irrit eyes. 1405 ST 40 ppm (165 mg/m ) [skin] 3 OSHA 7 OSHA PEL†: TWA 25 ppm (100 mg/m ) [skin] Physical Description: Colorless liquid with a mild odor.18 mg/m3 DOT: 2053 129 Synonyms/Trade Names: Isobutylmethylcarbinol. MIAK Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 50 ppm (240 mg/m3) 3 OSHA PV2042 OSHA PEL†: TWA 100 ppm (475 mg/m ) Physical Description: Colorless. coma. 5-Methyl-2-hexanone. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp/SaF:Pd.2 500 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 291°F 1250 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp:AScba Remove: When wet or contam Fl. IP: 9. CNS. in animals: narco Breath: Resp support TO: Eyes.Pp Sp.2% LEL(200°F): 1. Isopentyl methyl ketone. CNS Swallow: Medical attention immed Methyl isobutyl carbinol 212 .0% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes.R. clear liquid with a pleasant. fruity odor. Abs. skin.

CAS#: RTECS#: IDLH: Formula: 624-83-9 NQ9450000 3 ppm CH3NCO Conversion: 1 ppm = 2.34 mg/m3 DOT: 2480 155 Synonyms/Trade Names: Methyl ester of isocyanic acid, MIC Exposure Limits: Measurement Methods NIOSH REL: TWA 0.02 ppm (0.05 mg/m3) [skin] (see Table 1): 3 OSHA 54 OSHA PEL: TWA 0.02 ppm (0.05 mg/m ) [skin] Physical Description: Colorless liquid with a sharp, pungent odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 57.1 0.2 ppm: Sa* Eyes: Prevent eye contact BP: 102-104°F 0.5 ppm: Sa:Cf* Wash skin: When contam Sol(59°F): 10% 1 ppm: ScbaF/SaF Remove: When wet (flamm) Fl.P: 19°F 3 ppm: SaF:Pd,Pp Change: N.R. IP: 10.67 eV §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Provide: Eyewash Sp.Gr: 0.96 Escape: GmFOv/ScbaE VP: 348 mmHg Quick drench FRZ: -49°F UEL: 26% LEL: 5.3% Class IB Flammable Liquid Incompatibilities and Reactivities: Water, oxidizers, acids, alkalis, amines, iron, tin, copper [Note: Usually contains inhibitors to prevent polymerization.] First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Water flush immed SY: Irrit eyes, skin, nose, throat; resp sens, cough, pulm secretions, Breath: Resp support chest pain, dysp; asthma; eye, skin damage; in animals: pulm edema Swallow: Medical attention immed TO: Eyes, skin, resp sys

Methyl isocyanate

M

Formula: CAS#: RTECS#: IDLH: CH3COCH(CH3)2 563-80-4 EL9100000 N.D. Conversion: 1 ppm = 3.53 mg/m3 DOT: 2397 127 Synonyms/Trade Names: 2-Acetyl propane, Isopropyl methyl ketone, 3-Methyl-2-butanone, 3-Methyl butan-2-one, MIPK Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (705 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with an acetone-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 86.2 Skin: Prevent skin contact BP: 199°F Not available. Eyes: Prevent eye contact Sol: Very slight Wash skin: When contam Fl.P: ? Remove: When wet or contam IP: 9.32 eV Change: N.R. Sp.Gr: 0.81 VP: 42 mmHg FRZ: -134°F UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash immed SY: Irrit eyes, skin, muc memb, resp sys; cough Breath: Resp support TO: Eyes, skin, resp sys Swallow: Medical attention immed

Methyl isopropyl ketone

213

M

CAS#: RTECS#: IDLH: Formula: 74-93-1 PB4375000 150 ppm CH3SH Conversion: 1 ppm = 1.97 mg/m3 DOT: 1064 117 Synonyms/Trade Names: Mercaptomethane, Methanethiol, Methyl sulfhydrate Exposure Limits: Measurement Methods NIOSH REL: C 0.5 ppm (1 mg/m3) [15-minute] (see Table 1): 3 NIOSH 2542 OSHA PEL†: C 10 ppm (20 mg/m ) OSHA 26 Physical Description: Colorless gas with a disagreeable odor like garlic or rotten cabbage. [Note: A liquid below 43°F. Shipped as a liquefied compressed gas.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact (liquid) MW: 48.1 5 ppm: CcrOv/Sa BP: 43°F Frostbite 12.5 ppm: Sa:Cf/PaprOv Eyes: Prevent eye contact (liquid) Sol: 2% 25 ppm: CcrFOv/GmFOv/PaprTOv/ Fl.P: NA (Gas) Frostbite Wash skin: N.R. SaT:Cf/ScbaF/SaF (oc) 0°F (Liquid) 150 ppm: Sa:Pd,Pp Remove: When wet (flamm) IP: 9.44 eV §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Change: N.R. RGasD: 1.66 Escape: GmFOv/ScbaE Provide: Eyewash (liquid) Sp.Gr: 0.90 (Liquid at 32°F) VP: 1.7 atm Quick drench (liquid) FRZ: -186°F Frostbite wash UEL: 21.8% LEL: 3.9% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers, bleaches, copper, aluminum, nickel-copper alloys First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed (liquid)/Frostbite ER: Inh, Con (liquid) Skin: Water flush immed (liquid)/Frostbite SY: Irrit eyes, skin, resp sys; narco; cyan; convuls; liquid: frostbite Breath: Resp support TO: Eyes, skin, resp sys, CNS, blood

Methyl mercaptan

Formula: CAS#: RTECS#: IDLH: CH2=C(CH3)COOCH3 80-62-6 OZ5075000 1000 ppm Conversion: 1 ppm = 4.09 mg/m3 DOT: 1247 129P (inhibited) Synonyms/Trade Names: Methacrylate monomer, Methyl ester of methacrylic acid, Methyl-2-methyl-2-propenoate Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (410 mg/m3) (see Table 1): 3 NIOSH 2537 OSHA PEL: TWA 100 ppm (410 mg/m ) OSHA 94 Physical Description: Colorless liquid with an acrid, fruity odor.

Methyl methacrylate

Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 100.1 1000 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 214°F Wash skin: When contam Sol: 1.5% PaprOv£/ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Remove: When wet (flamm) Fl.P(oc): 50°F Escape: GmFOv/ScbaE Change: N.R. IP: 9.70 eV Sp.Gr: 0.94 VP: 29 mmHg FRZ: -54°F UEL: 8.2% LEL: 1.7% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates, oxidizers, peroxides, strong alkalis, moisture [Note: May polymerize if subjected to heat, oxidizers, or ultraviolet light. Usually contains an inhibitor such as hydroquinone.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Water flush prompt SY: Irrit eyes, skin, nose, throat; derm Breath: Resp support TO: Eyes, skin, resp sys Swallow: Medical attention immed

214

Formula: CAS#: RTECS#: IDLH: (CH3O)2P(S)OC6H4NO2 298-00-0 TG0175000 N.D. Conversion: DOT: 2783 152 (solid); 3018 152 (liquid) Synonyms/Trade Names: Azophos®; O,O-Dimethyl-O-p-nitrophenylphosphorothioate; Parathion methyl Exposure Limits: Measurement Methods NIOSH REL: TWA 0.2 mg/m3 [skin] (see Table 1): NIOSH 5600 OSHA PEL†: none Physical Description: White to tan, crystalline solid or powder with a pungent, garlic- OSHA PV2112 like odor. [pesticide] [Note: The commercial product in xylene is a tan liquid.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 263.2 NIOSH Skin: Prevent skin contact BP: 289°F 2 mg/m3: CcrOv95/Sa Eyes: Prevent eye contact Sol(77°F): 0.006% Wash skin: When contam/Daily Fl.P: ? 5 mg/m3: Sa:Cf/PaprOvHie Remove: When wet or contam IP: ? 10 mg/m3: CcrFOv100/GmFOv100/ Change: Daily Sp.Gr: 1.36 PaprTOvHie/SaT:Cf/ Provide: Eyewash VP: 0.00001 mmHg ScbaF/SaF MLT: 99°F 200 mg/m3: SaF:Pd,Pp Quick drench UEL: ? §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba LEL: ? Escape: GmFOv100/ScbaE Combustible Solid Incompatibilities and Reactivities: Strong oxidizers, water [Note: Explosive risk when heated above 122°F.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Ing, Con Eye: Irr immed SY: Irrit eyes, skin; nau, vomit, abdom cramps, diarr, salv; head, dizz, Skin: Soap wash immed lass; rhin, chest tight; blurred vision, miosis; card irreg; musc fasc; dysp Breath: Resp support Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, CVS, blood chol

Methyl parathion

M

Formula: CAS#: RTECS#: IDLH: (CH3O)4Si 681-84-5 VV9800000 N.D. Conversion: 1 ppm = 6.23 mg/m3 DOT: 2606 155 Synonyms/Trade Names: Methyl orthosilicate, Tetramethoxysilane, Tetramethyl ester of silicic acid, Tetramethyl silicate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 ppm (6 mg/m3) OSHA PEL†: none None available Physical Description: Clear, colorless liquid. [Note: A solid below 28°F.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 152.3 Skin: Prevent skin contact BP: 250°F Not available. Eyes: Prevent eye contact Sol: Soluble Wash skin: Daily Fl.P: 205°F Remove: When wet or contam IP: ? Change: N.R. Sp.Gr: 1.02 Provide: Eyewash VP(77°F): 12 mmHg FRZ: 28°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers; hexafluorides of rhenium, molybdenum & tungsten Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con SY: Irrit eyes, corn damage (following even short-term exposure Skin: Soap wash Breath: Resp support to the vapor); lung, kidney inj; pulm edema Swallow: Medical attention immed TO: Eyes, resp sys, kidneys

Methyl silicate

215

M

Formula: CAS#: RTECS#: IDLH: C6H5C(CH3)=CH2 98-83-9 WL5075300 700 ppm Conversion: 1 ppm = 4.83 mg/m3 DOT: Synonyms/Trade Names: AMS, Isopropenyl benzene, 1-Methyl-1-phenylethylene, 2-Phenyl propylene Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (240 mg/m3) (see Table 1): 3 NIOSH 1501 ST 100 ppm (485 mg/m ) 3 OSHA 7 OSHA PEL†: C 100 ppm (480 mg/m ) Physical Description: Colorless liquid with a characteristic odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 118.2 500 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 330°F 700 ppm: Sa:Cf*/CcrFOv/GmFOv/ Wash skin: When contam Sol: Insoluble Remove: When wet or contam Fl.P: 129°F PaprOv*/ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Change: N.R. IP: 8.35 eV Escape: GmFOv/ScbaE Sp.Gr: 0.91 VP: 2 mmHg FRZ: -10°F UEL: 6.1% LEL: 1.9% Class II Combustible Liquid Incompatibilities and Reactivities: Oxidizers, peroxides, halogens, catalysts for vinyl or ionic polymers; aluminum, iron chloride, copper [Note: Usually contains an inhibitor such as tert-butyl catechol.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Water flush prompt SY: Irrit eyes, skin, nose, throat; drow; derm Breath: Resp support TO: Eyes, skin, resp sys, CNS Swallow: Medical attention immed

α-Methyl styrene

Formula: CAS#: RTECS#: IDLH: C8H14N4OS 21087-64-9 XZ2990000 N.D. Conversion: DOT: Synonyms/Trade Names: 4-Amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5(4H)-one Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): OSHA PV2044 OSHA PEL†: none Physical Description: Colorless, crystalline solid. [herbicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 214.3 Skin: Prevent skin contact BP: ? Not available. Eyes: Prevent eye contact Sol: 0.1% Wash skin: When contam/Daily Fl.P: NA Remove: When wet or contam IP: ? Change: Daily Sp.Gr: 1.31 VP: 0.0000004 mmHg MLT: 257°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash SY: In animals: CNS depres; thyroid, liver enzyme changes Breath: Fresh air TO: CNS, thyroid, liver Swallow: Medical attention immed

Metribuzin

216

Mica (containing less than 1% quartz)

Formula:

CAS#: 12001-26-2

RTECS#: VV8760000

IDLH: 1500 mg/m3

Conversion: DOT: Synonyms/Trade Names: Biotite, Lepidolite, Margarite, Muscovite, Phlogopite, Roscoelite, Zimmwaldite Exposure Limits: Measurement Methods NIOSH REL: TWA 3 mg/m3 (resp) (see Table 1): NIOSH 0600 OSHA PEL†: TWA 20 mppcf Physical Description: Colorless, odorless flakes or sheets of hydrous silicates. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: N.R. MW: 797 (approx) 15 mg/m3: Qm Eyes: N.R. BP: ? Wash skin: N.R. Sol: Insoluble 30 mg/m3: 95XQ/Sa Remove: N.R. Fl.P: NA 75 mg/m3: Sa:Cf/PaprHie Change: N.R. IP: NA 150 mg/m3: 100F/SaT:Cf/PaprTHie/ Sp.Gr: 2.6-3.2 ScbaF/SaF VP: 0 mmHg (approx) 1500 mg/m3: Sa:Pd,Pp MLT: ? §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Con Breath: Fresh air SY: Irrit eyes; pneumoconiosis, cough, dysp; lass; low-wgt TO: Resp sys

M

Mineral wool fiber

Formula:

CAS#:

RTECS#: PY8070000

IDLH: N.D.

Conversion: DOT: Synonyms/Trade Names: Manmade mineral fibers, Rock wool, Slag wool, Synthetic vitreous fibers [Note: Produced by blowing steam or air through molten rock (rock wool) or various furnace slags that are by-products of metal smelting or refining processes (slag wool).] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 3 fibers/cm3 (fibers ≤ 3.5 µm diameter & ≥ 10 µm in length) 3 NIOSH 0500, 7400 TWA 5 mg/m (total) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Typically, a mineral “wool” with diameters >0.5 µm & >1.5 µm in length. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: varies 5X REL: Qm Eyes: Prevent eye contact BP: NA 10X REL: 95XQ/Sa Wash skin: Daily Sol: Insoluble 25X REL: Sa:Cf/PaprHie Remove: N.R. Fl.P: NA 50X REL: 100F/PaprTHie/ScbaF/SaF Change: Daily IP: NA 1000X REL: SaF:Pd,Pp Sp.Gr: ? §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba VP: 0 mmHg (approx) Escape: 100F/ScbaE MLT: ? UEL: NA LEL: NA Noncombustible Fibers Incompatibilities and Reactivities: None reported Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Con Breath: Fresh air SY: Irrit eyes, skin, resp sys; dysp TO: Eyes, skin, resp sys

217

Molybdenum

M

Conversion: Synonyms/Trade Names: Molybdenum metal Exposure Limits: Measurement Methods NIOSH REL*: See Appendix D (see Table 1): 3 OSHA PEL*†: TWA 15 mg/m NIOSH 7300, 7301, 7303, 9102 [*Note: The PEL also applies to other insoluble molybdenum OSHA ID121, ID125G compounds (as Mo).] Physical Description: Dark gray or black powder with a metallic luster. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 95.9 OSHA Skin: N.R. BP: 8717°F 75 mg/m3: Qm Eyes: N.R. Sol: Insoluble Wash skin: N.R. Fl.P: NA 150 mg/m3: 95XQ/Sa Remove: N.R. IP: NA 375 mg/m3: Sa:Cf/PaprHie Change: N.R. Sp.Gr: 10.28 750 mg/m3: 100F/SaT:Cf/PaprTHie/ VP: 0 mmHg (approx) ScbaF/SaF MLT: 4752°F 5000 mg/m3: Sa:Pd,Pp UEL: NA §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba LEL: NA Escape: 100F/ScbaE Combustible Solid in form of dust or powder. Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing, Con Eye: Irr immed SY: In animals: irrit eyes, nose, throat; anor, diarr, low-wgt; Breath: Resp support Swallow: Medical attention immed listlessness; liver, kidney damage TO: Eyes, resp sys, liver, kidneys

Formula: Mo DOT:

CAS#: 7439-98-7

RTECS#: QA4680000

IDLH: 5000 mg/m3 (as Mo)

Molybdenum (soluble compounds, as Mo)

Formula:

CAS#:

RTECS#:

IDLH: 1000 mg/m3 (as Mo)

Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific soluble molybdenum compound. Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL: TWA 5 mg/m NIOSH 7300, 7301, 7303, 9102 Physical Description: Appearance and odor vary depending upon the specific OSHA ID121, ID125G soluble molybdenum compound. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: OSHA Properties vary depending upon Skin: Prevent skin contact 25 mg/m3: Qm* the specific soluble molybdenum Eyes: Prevent eye contact Wash skin: When contam 50 mg/m3: 95XQ*/Sa* compound. Remove: When wet or contam 125 mg/m3: Sa:Cf*/PaprHie* Change: N.R. 250 mg/m3: 100F/SaT:Cf*/PaprTHie*/ ScbaF/SaF 1000 mg/m3: SaF:Pd,Pp §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con SY: In animals: irrit eyes, nose, throat; anor; inco; dysp; anemia Skin: Water flush Breath: Resp support TO: Eyes, resp sys, kidneys, blood Swallow: Medical attention immed

218

CAS#: RTECS#: IDLH: Formula: 6923-22-4 TC4375000 N.D. C7H14NO5P Conversion: DOT: 2783 152 (organophosphorus pesticide, solid) Synonyms/Trade Names: Azodrin®, 3-Hydroxy-N-methylcrotonamide dimethylphosphate, Monocron Exposure Limits: Measurement Methods NIOSH REL: TWA 0.25 mg/m3 (see Table 1): NIOSH 5600 OSHA PEL†: none OSHA PV2045 Physical Description: Colorless to reddish-brown solid with a mild, ester odor. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 223.2 Skin: Prevent skin contact BP: 257°F Not available. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl.P: >200°F Remove: When wet or contam IP: ? Change: Daily Sp.Gr: ? VP: 0.000007 mmHg MLT: 129°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Metals, low molecular weight alcohols & glycols [Note: Corrosive to black iron, drum steel, stainless steel 304 & brass. Should be stored at 70-80°F.] First Aid (see Table 6): Exposure Routes, Symptoms, Target Organs (see Table 5): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Water flush immed SY: Irrit eyes, miosis, blurred vision; dizz, convuls; dysp; salv, abdom cramps, nau, diarr, vomit; in animals: possible terato effects Breath: Resp support Swallow: Medical attention immed TO: Eyes, resp sys, CNS, CVS, blood chol, repro sys

Monocrotophos

M

Formula: CAS#: RTECS#: IDLH: C6H5NHCH3 100-61-8 BY4550000 100 ppm Conversion: 1 ppm = 4.38 mg/m3 DOT: 2294 153 Synonyms/Trade Names: MA, (Methylamino)benzene, N-Methyl aniline, Methylphenylamine, N-Phenylmethylamine Exposure Limits: Measurement Methods NIOSH REL: TWA 0.5 ppm (2 mg/m3) [skin] (see Table 1): 3 NIOSH 3511 OSHA PEL†: TWA 2 ppm (9 mg/m ) [skin] Physical Description: Yellow to light-brown liquid with a weak, ammonia-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 107.2 5 ppm: Sa Eyes: Prevent eye contact BP: 384°F 12.5 ppm: Sa:Cf Wash skin: When contam Sol: Insoluble 25 ppm: SaT:Cf/ScbaF/SaF Remove: When wet or contam Fl.P: 175°F 100 ppm: SaF:Pd,Pp Change: N.R. IP: 7.32 eV §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Sp.Gr: 0.99 Escape: GmFS/ScbaE VP: 0.3 mmHg FRZ: -71°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong acids, strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con SY: Lass, dizz, head; dysp, cyan; methemo; pulm edema; liver, Skin: Soap wash immed Breath: Resp support kidney damage Swallow: Medical attention immed TO: Resp sys, liver, kidneys, blood, CNS

Monomethyl aniline

219

N

CAS#: RTECS#: IDLH: Formula: 110-91-8 QD6475000 1400 ppm [10%LEL] C4H9ON Conversion: 1 ppm = 3.56 mg/m3 DOT: 2054 132 Synonyms/Trade Names: Diethylene imidoxide; Diethylene oximide; Tetrahydro-1,4-oxazine; Tetrahydro-p-oxazine Exposure Limits: Measurement Methods NIOSH REL: TWA 20 ppm (70 mg/m3) [skin] (see Table 1): 3 NIOSH S150 (II-3) ST 30 ppm (105 mg/m ) 3 OSHA PEL†: TWA 20 ppm (70 mg/m ) [skin] Physical Description: Colorless liquid with a weak, ammonia- or fish-like odor. [Note: A solid below 23°F.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 87.1 500 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 264°F 1000 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: Miscible Remove: When wet (flamm) Fl.P(oc): 98°F ScbaF/SaF 1400 ppm: SaF:Pd,Pp Change: N.R. IP: 8.88 eV §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Provide: Eyewash (>15%) Sp.Gr: 1.007 Escape: GmFOv/ScbaE VP: 6 mmHg Quick drench (>25%) FRZ: 23°F UEL: 11.2% LEL: 1.4% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong acids, strong oxidizers, metals, nitro compounds [Note: Corrosive to metals.] Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Abs, Ing, Con Eye: Irr immed SY: Irrit eyes, skin, nose, resp sys; vis dist; cough; in animals: Skin: Water flush immed Breath: Resp support liver, kidney damage Swallow: Medical attention immed TO: Eyes, skin, resp sys, liver, kidneys

Morpholine

Naphtha (coal tar)
3

Formula:

CAS#: 8030-30-6

RTECS#: DE3030000

IDLH: 1000 ppm [10%LEL]

Conversion: 1 ppm = 4.50 mg/m (approx) DOT: Synonyms/Trade Names: Crude solvent coal tar naphtha, High solvent naphtha, Naphtha Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (400 mg/m3) (see Table 1): NIOSH 1550 OSHA PEL: TWA 100 ppm (400 mg/m3) Physical Description: Reddish-brown, mobile liquid with an aromatic odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 110 (approx) 1000 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 320-428°F Wash skin: When contam Sol: Insoluble PaprOv£/ScbaF/SaF Remove: When wet or contam §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Fl.P: 100-109°F Change: N.R. Escape: GmFOv/ScbaE IP: ? Sp.Gr: 0.89-0.97 VP: <5 mmHg FRZ: ? UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): ER: Inh, Ing, Con Eye: Irr immed SY: Irrit eyes, skin, nose; dizz, drow; derm; in animals: liver, Skin: Soap wash prompt Breath: Resp support kidney damage Swallow: Medical attention immed TO: Eyes, skin, resp sys, CNS, liver, kidneys

220

Formula: CAS#: RTECS#: IDLH: C10H8 91-20-3 QJ0525000 250 ppm Conversion: 1 ppm = 5.24 mg/m3 DOT: 1334 133 (crude or refined); 2304 133 (molten) Synonyms/Trade Names: Naphthalin, Tar camphor, White tar Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (50 mg/m3) (see Table 1): 3 NIOSH 1501 ST 15 ppm (75 mg/m ) 3 OSHA 35 OSHA PEL†: TWA 10 ppm (50 mg/m ) Physical Description: Colorless to brown solid with an odor of mothballs. [Note: Shipped as a molten solid.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 128.2 NIOSH/OSHA Skin: Prevent skin contact BP: 424°F 100 ppm: CcrOv95*/Sa* Eyes: Prevent eye contact Sol: 0.003% 250 ppm: Sa:Cf*/CcrFOv100/ Wash skin: When contam Fl.P: 174°F Remove: When wet or contam IP: 8.12 eV PaprOvHie*/ Change: Daily Sp.Gr: 1.15 ScbaF/SaF §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba VP: 0.08 mmHg Escape: GmFOv100/ScbaE MLT: 176°F UEL: 5.9% LEL: 0.9% Combustible Solid, but will take some effort to ignite. Incompatibilities and Reactivities: Strong oxidizers, chromic anhydride Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Abs, Ing, Con Skin: Molten flush immed/sol-liq soap wash SY: Irrit eyes; head, conf, excitement, mal; nau, vomit, abdom prompt pain; irrit bladder; profuse sweat; jaun; hema, renal shutdown; Breath: Resp support derm, optical neuritis, corn damage TO: Eyes, skin, blood, liver, kidneys, CNS Swallow: Medical attention immed

Naphthalene

N

Formula: CAS#: RTECS#: IDLH: C10H6(NCO)2 3173-72-6 NQ9600000 N.D. Conversion: 1 ppm = 8.60 mg/m DOT: Synonyms/Trade Names: 1,5-Diisocyanatonaphthalene; 1,5-Naphthalene diisocyanate; 1,5-Naphthalene ester of isocyanic acid; NDI Exposure Limits: Measurement Methods NIOSH REL: TWA 0.040 mg/m3 (0.005 ppm) (see Table 1): NIOSH 5525 C 0.170 mg/m3 (0.020 ppm) [10-minute] OSHA PV2046 OSHA PEL: none Physical Description: White to light-yellow, crystalline flakes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 210.2 0.05 ppm: Sa* Eyes: Prevent eye contact BP: 505°F 0.125 ppm: Sa:Cf* Wash skin: When contam Sol: ? 0.25 ppm: ScbaF/SaF Remove: When wet or contam Fl.P(oc): 311°F 1 ppm: SaF:Pd,Pp Change: Daily IP: ? §: ScbaF:Pd,Pp/SaF:Pd,Pp:AScba Sp.Gr: ? Escape: GmFOv/ScbaE VP(75°F): 0.003 mmHg MLT: 261°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes, Symptoms, Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh, Ing, Con Skin: Soap wash immed SY: Irrit eyes, nose, throat; resp sens, cough, pulm secretions, Breath: Resp support chest pain, dysp; asthma Swallow: Medical attention immed TO: Eyes, resp sys

Naphthalene diisocyanate
3

221

ataxia. hemorrhagic cystitis.P: 315°F See Appendix E (page 351) Change: Daily IP: 9. hema.Gr(208°F): 1. [Note: Darkens in air to a reddish-purple color.D. hema.2 ¥: ScbaF:Pd.Pp/SaF:Pd. Symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 143. methemo. [carc] Swallow: Medical attention immed TO: Bladder. aromatic odor. [Note: Darkens in air to a reddish-purple color. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp:AScba Eyes: Prevent eye contact BP: 573°F Escape: 100F/ScbaE Wash skin: When contam/Daily Sol: 0. methemo.Pp:AScba Eyes: Prevent eye contact BP: 583°F Escape: 100F/ScbaE Wash skin: When contam/Daily Sol: Miscible in hot water Remove: When wet or contam Fl. Con Eye: Irr immed SY: Derm.002% Remove: When wet or contam Fl. [carc] Swallow: Medical attention immed TO: Bladder. skin [bladder cancer] β-Naphthylamine 222 .30 eV Provide: Eyewash Sp. Abs.06 VP(226°F): 1 mmHg Quick drench MLT: 232°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. Abs.Pp/SaF:Pd. hemorrhagic cystitis.1004] See Appendix B OSHA 93 Physical Description: Colorless crystals with an ammonia-like odor.] Conversion: DOT: 1650 153 Synonyms/Trade Names: 2-Aminonaphthalene. Con Eye: Irr immed SY: Derm. ataxia.] Conversion: DOT: 2077 153 Synonyms/Trade Names: 1-Aminonaphthalene. 2-Naphthylamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 5518 See Appendix A OSHA 93 OSHA PEL: [1910. Ing. dysp.Gr: 1.71 eV Provide: Eyewash Sp.N Formula: CAS#: RTECS#: IDLH: C10H7NH2 134-32-7 QM1400000 Ca [N. Skin: Soap wash immed Breath: Resp support dysuria. white to red crystals with a faint. 1-Naphthylamine Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 5518 See Appendix A OSHA PEL: [1910.12 VP(220°F): 1 mmHg Quick drench MLT: 122°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Oxidizes in air Exposure Routes.D. dysp.2 ¥: ScbaF:Pd. Ing.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 143.1009] See Appendix B Physical Description: Odorless. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. skin [bladder cancer] α-Naphthylamine Formula: CAS#: RTECS#: IDLH: C10H7NH2 91-59-8 QM2100000 Ca [N. Symptoms. Skin: Soap wash immed Breath: Resp support dysuria.P: 315°F See Appendix E (page 351) Change: Daily IP: 7.

nau. musc weak.P: ? Change: Daily IP: ? Provide: Eyewash Sp.Pp:AScba Eyes: Prevent eye contact BP: ? Escape: GmFOv/ScbaE Wash skin: When contam Sol: ? Remove: When wet or contam Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 170. skin.Pp/SaF:Pd.32 VP: 315 mmHg Quick drench FRZ: -13°F UEL: ? LEL: 2% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitric acid.R. bromine.Pp/SaF:Pd. [Note: A gas above 110°F. Abs. lass.007 mg/m3) Physical Description: Colorless to yellow liquid with a musty odor. substernal pain.7 ¥: ScbaF:Pd. chlorine & other oxidizers. hyperpnea.001 ppm (0. pins & Breath: Resp support needles in hands & feet. terato effects TO: Lungs. vomit. neurological disorders. decr nerve Swallow: Medical attention immed conduction in lower legs TO: Eyes. PNS N Formula: CAS#: RTECS#: IDLH: Ni(CO)4 13463-39-3 QR6300000 Ca [2 ppm] Conversion: 1 ppm = 6. Con Skin: Soap wash immed SY: Head.Gr(63°F): 1. Tetracarbonyl nickel Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 6007 TWA 0.007 mg/m ) See Appendix A OSHA PEL: TWA 0. Abs.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: mixture ¥: ScbaF:Pd.05% Remove: When wet (flamm) Fl. Ing. dizz. vomit. nau.Pp:AScba Eyes: Prevent eye contact BP: 110°F Escape: GmFS/ScbaE Wash skin: When contam Sol: 0. Symptoms.D.P: <-4°F Change: N. [Note: Used in the past as a catalyst in the manufacture of flexible polyurethane foams. cough. skin. Symptoms. urinary dist. leucyt. delirium. lass. urinary tract. [carc].Gr: ? VP: ? Quick drench FRZ: ? UEL: ? LEL: ? Incompatibilities and Reactivities: Oxidizers First Aid (see Table 6): Exposure Routes. in animals: Breath: Resp support Swallow: Medical attention immed repro. Con Skin: Soap flush immed SY: Irrit eyes. paranasal sinus. Conversion: DOT: Synonyms/Trade Names: None [Note: A mixture of 95% dimethylaminopropionitrile & 5% bis(2-dimethylamino)ethyl ether. pneu. flammable materials First Aid (see Table 6): Exposure Routes. Ing. epigastric pain. CNS.001 ppm (0. Target Organs (see Table 5): Eye: Irr immed ER: Inh.28 eV Provide: Eyewash Sp. IP: 8. repro sys [lung & nasal cancer] Nickel carbonyl 223 . convuls. cyan. Target Organs (see Table 5): Eye: Irr immed ER: Inh.98 mg/m3 DOT: 1259 131 Synonyms/Trade Names: Nickel tetracarbonyl.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix C OSHA PEL: See Appendix C None available Physical Description: A liquid mixture.Niax® Catalyst ESN Formula: CAS#: 62765-93-9 RTECS#: QR3900000 IDLH: N.

sulfur. card arrhy.Pp/SaF:Pd.5 mg/m [skin] Physical Description: Pale-yellow to dark-brown liquid with a fish-like odor when warm. Nickel catalyst Synonyms of other nickel compounds vary depending upon the specific compound. sponge catalyst may ignite wood & other combustibles. dysp. diarr.015 mg/m OSHA ID121.7 (see Table 2): NIOSH BP: 5139°F Skin: Prevent skin contact ¥: ScbaF:Pd.P: 203°F §: ScbaF:Pd. Abs. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 162. 9102 TWA 0. 7301. repro sys Nicotine 224 .7% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. nickel nitrate SPONTANEOUSLY in air. N Exposure Routes. convuls.R.2 NIOSH/OSHA Skin: Prevent skin contact BP: 482°F (Decomposes) 5 mg/m3: Sa/ScbaF Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. vis dist. odorless solid. nickel Incompatibilities and Reactivities: Strong acids.0% LEL: 0. allergic asthma. vomit. Sp. 7303.P: NA Wash skin: When contam/Daily IP: NA Remove: When wet or contam Sp. strong acids Exposure Routes. pneu. head. Ing. Target Organs (see Table 5): ER: Inh.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Gr: 1. Escape: 100F/ScbaE Fl. Con Eye: Irr immed SY: Nau. salv. inco. ID125G See Appendix A OSHA PEL*†: TWA 1 mg/m3 [*Note: The REL and PEL do not apply to Nickel carbonyl.Pp:AScba Sol: Insoluble Eyes: N.] Physical Description: Metal: Lustrous. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: Ca 3 NIOSH 7300. GI tract. selenium. Symptoms. in animals: terato effects Swallow: Medical attention immed TO: CNS.5 mg/m3 [skin] 3 NIOSH 2544. [carc] TO: Nasal cavities.90 (Metal) Change: Daily VP: 0 mmHg (approx) MLT: 2831°F UEL: NA LEL: NA Metal: Combustible Solid.01 Provide: Eyewash VP: 0.Pp:AScba Remove: When wet or contam IP: 8. 2551 OSHA PEL: TWA 0. skin [lung and nasal cancer] First Aid (see Table 6): Skin: Water flush immed Breath: Resp support Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: C5H4NC4H7NCH3 54-11-5 QS5250000 5 mg/m3 Conversion: DOT: 1654 151 Synonyms/Trade Names: 3-(1-Methyl-2-pyrrolidyl)pyridine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Nickel metal and other compounds (as Ni) Formula: Ni (metal) CAS#: 7440-02-0 (metal) RTECS#: IDLH: Ca QR5950000 (metal) [10 mg/m3 (as Ni)] Conversion: DOT: Synonyms/Trade Names: Nickel metal: Elemental nickel. silvery. Skin: Water flush immed Breath: Resp support lass. Symptoms. lungs. conf. Ing.01 eV Escape: GmFOv/ScbaE Change: N. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 58. CVS.R. lungs.Gr: 8. Con SY: Sens derm. abdom pain.08 mmHg FRZ: -110°F Quick drench UEL: 4. hearing. dizz.

chlorinated hydrocarbons.58 mg/m3 DOT: 2032 157 (fuming). teeth Nitric acid N Formula: CAS#: RTECS#: IDLH: NO 10102-43-9 QX0525000 100 ppm Conversion: 1 ppm = 1. resp sys.Gr(77°F): 1.R.5) FRZ: -44°F Quick drench (pH<2.0 NIOSH/OSHA Skin: N. RGasD: 1. delayed pulm edema. Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh SY: Irrit eyes. Symptoms. skin. [Note: Shipped as a nonliquefied compressed gas.] Exposure Routes.27 eV Escape: GmFS¿/ScbaE Change: N.R.23 mg/m3 DOT: 1660 124 Synonyms/Trade Names: Mononitrogen monoxide. Rapidly converted in air to nitrogen dioxide.2 atm FRZ: -263°F UEL: NA LEL: NA Nonflammable Gas.5) UEL: NA LEL: NA Noncombustible Liquid. throat. or red.50 Change: N.R.P: NA Wash skin: When contam ScbaF/SaF §: ScbaF:Pd.R. methemo TO: Eyes. Corrosive to metals. Fuming nitric acid is concentrated nitric acid that contains dissolved nitrogen dioxide. [Note: Reacts with water to produce heat. Symptoms. CNS Nitric oxide 225 . carbon disulfide [Note: Reacts with water to form nitric acid. metallic increases the flammability of powders.Pp:AScba Remove: N. pneu.P: NA GmFS¿/Sa*/ScbaF §: ScbaF:Pd. but will accelerate the burning of combustible materials. ozone. uncon.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 63.R. wet skin. Red fuming nitric acid (RFNA).] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 30. 2031 157 (other than red fuming) Synonyms/Trade Names: Aqua fortis. Hydrogen nitrate. blood. Fl. NH3. skin. alcohols combustible materials. dental erosion Swallow: Medical attention immed TO: Eyes. resp sys.0 (see Table 2): NIOSH/OSHA BP: 181°F Skin: Prevent skin contact 25 ppm: Sa:Cf*/CcrFS¿/GmFS¿/ Sol: Miscible Eyes: Prevent eye contact Fl.Pp/SaF:Pd. Engravers acid. Incompatibilities and Reactivities: Fluorine. yellow. Sol: 5% Wash skin: N. carbides. suffocating odor. [Note: Often used in an aqueous solution. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Formula: CAS#: RTECS#: IDLH: HNO3 7697-37-2 QU5775000 25 ppm Conversion: 1 ppm = 2. combustible materials.Pp:AScba IP: 11. IP: 9. metals.] Exposure Routes. Nitrogen monoxide Exposure Limits: Measurement Methods NIOSH REL: TWA 25 ppm (30 mg/m3) (see Table 1): 3 NIOSH 6014 OSHA PEL: TWA 25 ppm (30 mg/m ) OSHA ID190 Physical Description: Colorless gas. muc memb. Con Eye: Irr immed SY: Irrit eyes.95 eV Remove: When wet or contam Escape: GmFS¿/ScbaE Sp. but Incompatibilities and Reactivities: Combustible materials. Ing.Pp/SaF:Pd. VP: 48 mmHg Provide: Eyewash (pH<2.04 VP: 34. Skin: Water flush immed Breath: Resp support bron. BP: -241°F 100 ppm: Sa:Cf*/CcrFS¿/PaprS*¿/ Eyes: N. skin. fuming liquid with an acrid. nose. hydrogen sulfide.R. drow. White fuming nitric acid (WFNA) Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 ppm (5 mg/m3) 3 NIOSH 7903 ST 4 ppm (10 mg/m ) 3 OSHA ID165SG OSHA PEL†: TWA 2 ppm (5 mg/m ) Physical Description: Colorless.

Pp:AScba VP(77°F): 0.1 30 mg/m3: Sa* Eyes: Prevent eye contact BP: 630°F Wash skin: When contam/Daily Sol: 0. blood. 4-Nitrobenzenamine. resp arrest.] Exposure Routes. anemia. liver. methemo. convuls.Pp/SaF:Pd. tacar. chemically-active metals such as tin or zinc Exposure Routes.92 eV ScbaF/SaF 200 ppm: SaF:Pd. Skin: Water flush immed Breath: Resp support vomit.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 123.00002 mmHg Escape: GmFOv100/ScbaE MLT: 295°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. phosphorus pentachloride. 4-Nitroaniline. derm.Pp Provide: Quick drench Sp.R. PNA Exposure Limits: Measurement Methods NIOSH REL: TWA 3 mg/m3 [skin] (see Table 1): 3 NIOSH 5033 OSHA PEL†: TWA 6 mg/m (1 ppm) [skin] Physical Description: Bright yellow. diarr. Ing. testicular effects Swallow: Medical attention immed TO: Eyes. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. kidneys.Pp/SaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 138.Gr: 1. cyan. nitrogen tetroxide. heart. Abs. caustics. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. methemo. Con Eye: Irr immed SY: Irrit nose.20 §: ScbaF:Pd.P: 390°F 150 mg/m3: ScbaF/SaF Change: Daily IP: 8. dysp. skin. in animals: Skin: Soap wash immed Breath: Resp support liver.P: 190°F Change: Daily IP: 9. blood.42 §: ScbaF:Pd.04 mg/m3 DOT: 1662 152 Synonyms/Trade Names: Essence of mirbane. Oil of mirbane Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (5 mg/m3) [skin] (see Table 1): 3 NIOSH 2005.3 mmHg Escape: GmFOv/ScbaE FRZ: 42°F UEL: ? LEL(200°F): 1.8% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Concentrated nitric acid. strong reducers [Note: May result in spontaneous heating of organic materials in the presence of moisture. irrity. anoxia. Nitrobenzol. Symptoms. jaundice Swallow: Medical attention immed TO: Resp sys. repro sys Nitrobenzene 226 . CVS. skin. 2017 OSHA PEL: TWA 1 ppm (5 mg/m ) [skin] Physical Description: Yellow.2% 50 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl. liver p-Nitroaniline Formula: CAS#: RTECS#: IDLH: C6H5NO2 98-95-3 DA6475000 200 ppm Conversion: 1 ppm = 5.Gr: 1. tachypnea. Con Eye: Irr immed SY: Irrit eyes.Pp Provide: Quick drench Sp.85 eV 300 mg/m3: SaF:Pd.1 10 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 411°F 25 ppm: Sa:Cf*/PaprOv* Wash skin: N. Abs. [Note: A solid below 42°F. anemia. kidney damage.Pp:AScba VP: 0. ataxia.08% 75 mg/m3: Sa:Cf* Remove: When wet or contam Fl. throat. oily liquid with a pungent odor like paste shoe polish. Ing. Sol: 0. crystalline powder with a slight ammonia-like odor.N Formula: CAS#: RTECS#: IDLH: NO2C6H4NH2 100-01-6 BY7000000 300 mg/m3 Conversion: DOT: 1661 153 Synonyms/Trade Names: para-Aminonitrobenzene. p-Nitrophenylamine.

52 Provide: Eyewash VP(86°F): 0. 4-Chloronitrobenzene. alkalis First Aid (see Table 6): Exposure Routes.6 NIOSH Skin: Prevent skin contact BP: 468°F ¥: ScbaF:Pd.96 eV Change: Daily Sp. 4-Nitrodiphenyl. Con Skin: Soap wash immed SY: Head.Gr: 1. Abs.P: 261°F Remove: When wet or contam IP: 9. Abs. crystalline solid with a sweetish odor. methemo. urinary Breath: Resp support burning. drow. blood [in animals: bladder tumors] 4-Nitrobiphenyl N Formula: CAS#: RTECS#: IDLH: ClC6H4NO2 100-00-5 CZ1050000 Ca [100 mg/m3] Conversion: DOT: 1578 152 Synonyms/Trade Names: p-Chloronitrobenzene.] Conversion: DOT: Synonyms/Trade Names: p-Nitrobiphenyl. Con Skin: Soap wash immed SY: Anoxia. PNB Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH P&CAM273 (II-4) See Appendix A OSHA PV2082 OSHA PEL: [1910. lass. needle-like. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 157.P: 290°F Remove: When wet or contam IP: ? See Appendix E (page 351) Change: Daily Sp. in animals: hema. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 199. 1-Chloro-4-nitrobenzene. kidney. spleen. or burns with difficulty.2 mmHg MLT: 182°F Quick drench UEL: ? LEL: ? Solid that does not burn. PCNB. ataxia. 4-Nitrochlorobenzene. Target Organs (see Table 5): Eye: Irr immed ER: Inh. bone marrow changes. PNCB Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 2005 See Appendix A [skin] 3 OSHA PEL: TWA 1 mg/m [skin] Physical Description: Yellow.Pp/SaF:Pd. [carc] Swallow: Medical attention immed TO: Bladder. Symptoms.2 NIOSH Skin: Prevent skin contact BP: 644°F ¥: ScbaF:Pd. anemia. acute hemorrhagic cystitis.Formula: CAS#: RTECS#: IDLH: C6H5C6H4NO2 92-93-3 DV5600000 Ca [N. bone marrow. dizz.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: 100F/ScbaE Wash skin: When contam/Daily Fl.Gr: ? Provide: Eyewash VP: ? MLT: 237°F Quick drench UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong reducers Exposure Routes. repro effects. liver. crystalline solid with a sweet odor.1003] See Appendix B Physical Description: White to yellow. kidneys. p-Phenylnitrobenzene. 4-Phenylnitrobenzene. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. [carc] Swallow: Medical attention immed TO: Blood.Pp:AScba Eyes: Prevent eye contact Sol: Slight Escape: 100F/ScbaE Wash skin: When contam/Daily Fl.Pp/SaF:Pd. Symptoms. Ing. CVS. Incompatibilities and Reactivities: Strong oxidizers. Breath: Resp support spleen. methemo. unpleasant taste.D. p-Nitrodiphenyl. dysp. Ing. repro sys [in animals: vascular & liver tumors] p-Nitrochlorobenzene 227 .

Pp:AScba Wash skin: When contam Fl.P: 82°F Escape: ScbaE Remove: When wet (flamm) IP: 10. resp sys. mucoid frothy sputum.75 eV Change: N. Con Eye: Irr immed SY: Irrit eyes. in animals: lac. Sp. cyan. cough.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 46. Symptoms. liver. CNS. [Note: In solid form (below 15°F) it is found structurally as N2O4. Skin: Water flush immed Breath: Resp support chronic bron.R.8 mg/m3) (see Table 1): 3 OSHA PEL†: C 5 ppm (9 mg/m ) NIOSH 6014 Physical Description: Yellowish-brown liquid or reddish-brown gas (above 70°F) with OSHA ID182 a pungent.Pp/SaF:Pd. oily liquid with a mild. ammonia [Note: Reacts with water to form nitric acid. but will accelerate the burning of combustible materials. kidneys. Nitrogen peroxide Exposure Limits: Measurement Methods NIOSH REL: ST 1 ppm (1.Gr: 1.Pp/SaF:Pd. RGasD: 2.Pp:AScba Wash skin: When contam Fl. Symptoms.1 NIOSH/OSHA Skin: Prevent skin contact BP: 237°F 1000 ppm: ScbaF/SaF Eyes: Prevent eye contact Sol: 5% §: ScbaF:Pd.4% Class IC Flammable Liquid Incompatibilities and Reactivities: Amines. Incompatibilities and Reactivities: Combustible material.05 VP(77°F): 21 mmHg FRZ: -130°F UEL: ? LEL: 3.88 eV Change: N. CVS Nitrogen dioxide 228 . liver Swallow: Medical attention immed Formula: CH3CH2NO2 DOT: 2842 129 CAS#: 79-24-3 RTECS#: KI5600000 IDLH: 1000 ppm Formula: CAS#: RTECS#: IDLH: NO2 10102-44-0 QW9800000 20 ppm Conversion: 1 ppm = 1. Ing.P: NA Escape: GmFS¿/ScbaE Remove: When wet or contam IP: 9. decr pulm func. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 75. strong acids.Gr: 1.] Exposure Routes. metal oxides First Aid (see Table 6): Exposure Routes. tachypnea. Con SY: Derm. tacar Swallow: Medical attention immed TO: Eyes. edema.88 mg/m3 DOT: 1067 124 Synonyms/Trade Names: Dinitrogen tetroxide (N2O4). Ing. resp sys. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. pulm rales. water. chlorinated hydrocarbons. chest pain. Target Organs (see Table 5): Eye: Irr immed ER: Inh.62 Provide: Eyewash Sp.0 NIOSH Skin: Prevent skin contact BP: 70°F 20 ppm: Sa:Cf£/ScbaF/SaF Eyes: Prevent eye contact Sol: Reacts §: ScbaF:Pd.07 mg/m3 Synonyms/Trade Names: Nitroetan Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (310 mg/m3) (see Table 1): 3 NIOSH 2526 OSHA PEL: TWA 100 ppm (310 mg/m ) Physical Description: Colorless. acrid odor.R. fruity odor. kidney inj. alkalis & oxidizers. hydrocarbons.Nitroethane N Conversion: 1 ppm = 3. dysp. throat. combustibles. narco Skin: Soap wash prompt Breath: Resp support TO: Skin. nose. pulm edema.44 (Liquid at 68°F) VP: 720 mmHg Quick drench FRZ: 15°F UEL: NA LEL: NA Noncombustible Liquid/Gas. dysp. carbon disulfide.

BP: -200°F 100 ppm: CcrS/Sa Eyes: N. methemo. kidneys Nitrogen trifluoride N Formula: CAS#: RTECS#: IDLH: CH2NO3CHNO3CH2NO3 55-63-0 QX2100000 75 mg/m3 DOT: 1204 127 (≤ 1% solution in alcohol). flush.R. Sol: Slight 250 ppm: Sa:Cf/PaprS Wash skin: N. viscous liquid or solid (below 56°F).Pp:AScba FRZ: -340°F Escape: GmFS/ScbaE UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Water. methane.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 227. Trifluorammonia Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (29 mg/m3) (see Table 1): 3 OSHA PEL: TWA 10 ppm (29 mg/m ) None available Physical Description: Colorless gas with a moldy odor.2 ppm (2 mg/m ) [skin] OSHA 43 Physical Description: Colorless to pale-yellow. shock.R. Conversion: 1 ppm = 9.R. kidney inj TO: Blood. NG.2. IP: 12. Target Organs (see Table 5): Breath: Resp support ER: Inh SY: In animals: anoxia. skin irrit Swallow: Medical attention immed TO: CVS. oil.1 mg/m3 [skin] 3 NIOSH 2507 OSHA PEL†: C 0.0 NIOSH/OSHA Skin: N.97 eV Change: N. CNS depres. Skin: Soap wash immed Breath: Resp support palp.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 71. dizz. delirium.1% Wash skin: When contam Fl.Pp Provide: Quick drench VP: 0. [Note: An explosive ingredient in dynamite (20-40%) with ethylene glycol dinitrate (80-60%). liver. diborane First Aid (see Table 6): Exposure Routes. nau.Pp/SaF:Pd. cyan. grease. activated charcoal. Trifluoramine. Symptoms.Pp/SaF:Pd. acids [Note: An OSHA Class A Explosive (1910. Target Organs (see Table 5): Eye: Irr immed ER: Inh.0003 mmHg §: ScbaF:Pd. Ing. liver. head.R. oxidizable materials. Symptoms. methemo.60 75 mg/m3: SaF:Pd.Pp:AScba FRZ: 56°F Escape: GmFOv100/ScbaE UEL: ? LEL: ? Explosive Liquid Incompatibilities and Reactivities: Heat. ozone. vomit.Gr: 1. ammonia.P: NA 500 ppm: CcrFS/GmFS/PaprTS*/ Remove: N.5 mg/m3: Sa:Cf* Remove: When wet (flamm) IP: ? 5 mg/m3: SaT:Cf*/ScbaF/SaF Change: Daily Sp.90 mg/m3 DOT: 2451 122 Synonyms/Trade Names: Nitrogen fluoride.Formula: CAS#: RTECS#: IDLH: NF3 7783-54-2 QX1925000 1000 ppm Conversion: 1 ppm = 2.P: Explodes 2. Trinitroglycerine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: ST 0. blood. Fl. Con SY: Throb head.3-Propanetriol trinitrate.46 SaT:Cf*/ScbaF/SaF 1000 ppm: SaF:Pd. CNS Nitroglycerine 229 .109).29 mg/m3 3064 127 (1-5% solution in alcohol) Synonyms/Trade Names: Glyceryl trinitrate. hydrogen. 1. carbon monoxide.Pp VP: >1 atm §: ScbaF:Pd. abdom pain. hydrogen sulfide. skin. dizz.R. RGasD: 2.] First Aid (see Table 6): Exposure Routes. hypotension. angina.1 NIOSH BP: Begins to decompose at 122-140°F Skin: Prevent skin contact 1 mg/m3: Sa* Eyes: Prevent eye contact Sol: 0. Abs. lass. [Note: Shipped as a nonliquefied compressed gas.

Ing.P: 95°F Escape: ScbaE Remove: When wet (flamm) IP: 11. resp sys [bladder cancer] Swallow: Medical attention immed Formula: C10H7NO2 DOT: 2538 133 CAS#: 581-89-5 RTECS#: QJ9760000 IDLH: Ca [N. metallic oxides [Note: Slowly corrodes steel & copper when wet.] First Aid (see Table 6): Exposure Routes.Nitromethane N Conversion: 1 ppm = 2.R.Gr: 1. liver damage Breath: Resp support TO: Eyes.] OSHA PEL: none Physical Description: Colorless solid.50 mg/m3 Synonyms/Trade Names: Nitrocarbol Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL: TWA 100 ppm (250 mg/m ) NIOSH 2527 Physical Description: Colorless.3% Class IC Flammable Liquid Incompatibilities and Reactivities: Amines.Gr: ? VP: ? Quick drench MLT: 174°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: For “Nitrates” in general: Aluminum. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 61. Con Skin: Soap wash prompt SY: Derm. thiocyanates. resp sys. liver Swallow: Medical attention immed Formula: CH3NO2 DOT: 1261 129 CAS#: 75-52-5 RTECS#: PA9800000 IDLH: 750 ppm 2-Nitronaphthalene Conversion: Synonyms/Trade Names: β-Nitronaphthalene Exposure Limits: Measurement Methods NIOSH REL: Ca* (see Table 1): See Appendix A None available [*Note: Since metabolized to β-Naphthylamine.Pp:AScba Eyes: Prevent eye contact BP: ? Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: Insoluble Remove: When wet or contam Fl. [carc] Breath: Resp support TO: Skin.Pp:AScba Wash skin: When contam Fl.P: ? Change: Daily IP: 8. cyanides.] 230 . in animals: irrit eyes.Pp/SaF:Pd. hydrocarbons & other combustible materials. Con Skin: Soap wash immed SY: Irrit skin. alkalis & oxidizers. resp sys. Ing. Symptoms. convuls.Pp/SaF:Pd.D. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Symptoms. CNS.67 eV Provide: Eyewash Sp. Abs. Sp.08 eV Change: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 178. strong acids. phosphorus. narco. esters. skin.2 ¥: ScbaF:Pd. oily liquid with a disagreeable odor. tin chlorides.0 OSHA Skin: Prevent skin contact BP: 214°F 750 ppm: Sa:Cf£/ScbaF/SaF Eyes: Prevent eye contact Sol: 10% §: ScbaF:Pd. derm. sodium hypophosphite Exposure Routes.14 VP: 28 mmHg FRZ: -20°F UEL: ? LEL: 7.

2-NP Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 2528 See Appendix A 3 OSHA 15.00 Escape: ScbaE VP: 8 mmHg FRZ: -162°F UEL: ? LEL: 2. Ing. in animals: liver.2% Class IC Flammable Liquid Incompatibilities and Reactivities: Amines. Target Organs (see Table 5): Eye: Irr immed ER: Inh.R. kidneys Swallow: Medical attention immed Formula: CH3CH2CH2NO2 DOT: 2608 129 CAS#: 108-03-2 RTECS#: TZ5075000 IDLH: 1000 ppm N Formula: CAS#: RTECS#: IDLH: (CH3)2CH(NO2) 79-46-9 TZ5250000 Ca [100 ppm] Conversion: 1 ppm = 3.1-Nitropropane Conversion: 1 ppm = 3. fruity odor.99 VP: 13 mmHg FRZ: -135°F UEL: 11.71 eV Sp. head.P: 96°F 1000 ppm: ScbaF/SaF Remove: When wet (flamm) IP: 10. head. Sp.Pp:AScba Eyes: Prevent eye contact BP: 249°F Escape: ScbaE Wash skin: When contam Sol: 2% Remove: When wet (flamm) Fl. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 89.81 eV §: ScbaF:Pd.1 NIOSH/OSHA Skin: N.64 mg/m3 Synonyms/Trade Names: Nitropropane. nau. Con Eye: Irr immed SY: Irrit eyes. skin. Symptoms. CNS.P: 75°F Change: N. skin. iso-Nitropropane.R. Fl. alkalis & oxidizers. Con Skin: Soap wash prompt SY: Irrit eyes. strong acids. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 89. diarr. metal oxides. kidneys.Pp/SaF:Pd. [carc] TO: Eyes. kidney damage Breath: Resp support TO: Eyes. vomit. alkalis & oxidizers. liver [in animals: liver tumors] Swallow: Medical attention immed 2-Nitropropane 231 .Gr: 0. liver. liver damage. Skin: Soap wash prompt Breath: Resp support kidney. Ing. 1-NP Exposure Limits: Measurement Methods NIOSH REL: TWA 25 ppm (90 mg/m3) (see Table 1): 3 OSHA 46 OSHA PEL: TWA 25 ppm (90 mg/m ) Physical Description: Colorless liquid with a somewhat disagreeable odor. 46 OSHA PEL†: TWA 25 ppm (90 mg/m ) Physical Description: Colorless liquid with a pleasant.Gr: 1. resp sys.Pp:AScba Change: N.Pp/SaF:Pd. anor.R.1 ¥: ScbaF:Pd.6% Class IC Flammable Liquid Incompatibilities and Reactivities: Amines. vomit. nau. strong acids. BP: 269°F 250 ppm: Sa* Eyes: Prevent eye contact Sol: 1% 625 ppm: Sa:Cf* Wash skin: N.64 mg/m3 DOT: 2608 129 Synonyms/Trade Names: Dimethylnitromethane. hydrocarbons & other combustible materials. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. CNS. IP: 10. nose. metal oxides First Aid (see Table 6): Exposure Routes. resp sys. Symptoms.R. combustible materials Exposure Routes. diarr.0% LEL: 2.

6% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.D. [carc] Swallow: Medical attention immed TO: Liver. IP: 9. Target Organs (see Table 5): Eye: Irr immed ER: Inh. meta-Nitrotoluene. lass.Gr: 1. enlarged liver. Symptoms.N-Dimethylnitrosamine.Pp/SaF:Pd. [Note: A solid below 59°F. NDMA.1016] See Appendix B OSHA 38 Physical Description: Yellow.48 eV §: ScbaF:Pd.N-dimethylamine Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 2522 See Appendix A OSHA PEL: [1910.Gr: 1. CVS. decr liver. Skin: Soap wash immed Breath: Resp support jaun. pulm func.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 137. abdom cramps.Pp Change: N. fever. oily liquid with a faint. Ing. Ing. Abs. head.lungs [in animals.Pp:AScba Sp.1 mmHg FRZ: 59°F UEL: ? LEL: 1. diarr. 3-Methylnitrobenzene.] (CH3)2N2O Conversion: DOT: Synonyms/Trade Names: Dimethylnitrosamine. Con Skin: Soap wash immed SY: Anoxia. kidneys. tacar. vomit. dysp.Pp:AScba Eyes: Prevent eye contact BP: 306°F Escape: 100F/ScbaE Wash skin: When contam/Daily Sol: Soluble Remove: When wet or contam Fl. ataxia. GI tract Swallow: Medical attention immed m-Nitrotoluene 3 232 .69 eV Provide: Eyewash Sp. Symptoms.005 VP: 3 mmHg Quick drench FRZ: ? UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Should be stored in dark bottles. CNS. sulfuric acid First Aid (see Table 6): Exposure Routes. head.P: 223°F 200 ppm: SaF:Pd. Con Eye: Irr immed SY: Nau.1 ¥: ScbaF:Pd. aromatic odor. kidney.P: ? See Appendix E (page 351) Change: Daily IP: 8. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. lung.] Exposure Routes. skin. N-Methyl-N-nitroso-methanamine. dizz.R.1 20 ppm: Sa* Eyes: Prevent eye contact BP: 450°F 50 ppm: Sa:Cf* Wash skin: When contam Sol: 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 74.Pp/SaF:Pd. N.05% 100 ppm: SaT:Cf*/ScbaF/SaF Remove: When wet or contam Fl.N CAS#: RTECS#: IDLH: Formula: 62-75-9 IQ0525000 Ca [N.61 mg/m DOT: 1664 152 Synonyms/Trade Names: m-Methylnitrobenzene. liver & nasal cavity tumors] N-Nitrosodimethylamine Formula: CAS#: RTECS#: IDLH: NO2C6H4CH3 99-08-1 XT2975000 200 ppm Conversion: 1 ppm = 5. kidney. 3-Nitrotoluene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 ppm (11 mg/m3) [skin] 3 NIOSH 2005 OSHA PEL†: TWA 5 ppm (30 mg/m ) [skin] Physical Description: Yellow liquid with a weak. characteristic odor. vomit Breath: Resp support TO: Blood. cyan. DMNA. Abs. nau. N-Nitroso-N.16 Escape: GmFOv100/ScbaE VP: 0.

1 NIOSH Skin: Prevent skin contact BP: 432°F 20 ppm: Sa* Eyes: Prevent eye contact Sol: 0.61 mg/m3 DOT: 1664 152 Synonyms/Trade Names: o-Methylnitrobenzene.61 mg/m3 DOT: 1664 152 Synonyms/Trade Names: p-Methylnitrobenzene. Con Skin: Soap wash immed SY: Anoxia. 4-Methylnitrobenzene.Pp/SaF:Pd.1 mmHg Escape: GmFOv100/ScbaE FRZ: 25°F UEL: ? LEL: 2. GI tract Swallow: Medical attention immed o-Nitrotoluene N Formula: CAS#: RTECS#: IDLH: NO2C6H4CH3 99-99-0 XT3325000 200 ppm Conversion: 1 ppm = 5. nau. Sp. dysp.Pp:AScba Sp. Ing. dizz. Abs.2% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. head. 2-Nitrotoluene Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (11 mg/m3) [skin] (see Table 1): 3 NIOSH 2005 OSHA PEL†: TWA 5 ppm (30 mg/m ) [skin] Physical Description: Yellow liquid with a weak. dizz. head.07% 50 ppm: Sa:Cf* Wash skin: When contam Fl.P: 223°F 100 ppm: SaT:Cf*/ScbaF/SaF Remove: When wet or contam IP: 9.P: 223°F 200 ppm: SaF:Pd.Pp Change: N.16 §: ScbaF:Pd. Symptoms.Gr: 1. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 137. Con Skin: Soap wash immed SY: Anoxia.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 137.R. [Note: A solid below 25°F. Abs. cyan. CVS. CNS. aromatic odor.43 eV 200 ppm: SaF:Pd. skin.1 20 ppm: Sa* Eyes: Prevent eye contact BP: 460°F 50 ppm: Sa:Cf* Wash skin: When contam Sol: 0. tacar. lass.12 Escape: GmFOv100/ScbaE VP: 0. para-Nitrotoluene.Pp:AScba VP: 0. GI tract p-Nitrotoluene 233 . lass. tacar. Ing. cyan. CNS. vomit Breath: Resp support TO: Blood.04% 100 ppm: SaT:Cf*/ScbaF/SaF Remove: When wet or contam Fl. ortho-Nitrotoluene.Pp/SaF:Pd.Gr: 1. 2-Methylnitrobenzene.50 eV §: ScbaF:Pd. nau.1 mmHg MLT: 126°F UEL: ? LEL: 1.6% Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. sulfuric acid First Aid (see Table 6): Exposure Routes. dysp. CVS. ataxia. 4-Nitrotoluene Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (11 mg/m3) [skin] (see Table 1): 3 OSHA PEL†: TWA 5 ppm (30 mg/m ) [skin] NIOSH 2005 Physical Description: Crystalline solid with a weak. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. ataxia. Breath: Resp support vomit Swallow: Medical attention immed TO: Blood. Symptoms. aromatic odor.Formula: CAS#: RTECS#: IDLH: NO2C6H4CH3 88-72-2 XT3150000 200 ppm Conversion: 1 ppm = 5. Target Organs (see Table 5): Eye: Irr immed ER: Inh. sulfuric acid Exposure Routes. skin.Pp Change: Daily IP: 9.

asphy.R. Ing.Gr: 0.89 eV Change: N. Symptoms. throat. Conversion: 1 ppm = 5. dizz. liquid: frostbite Breath: Fresh air TO: Resp sys. phosphine. [inhalation anesthetic] [Note: Shipped as a liquefied compressed gas.g.3 Skin: N.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.21 eV Change: N. repro effects.R.0 Skin: Frostbite BP: -127°F Not available. Laughing gas Exposure Limits: Measurement Methods NIOSH REL*: TWA 25 ppm (46 mg/m3) (TWA over the time exposed) (see Table 1): NIOSH 3800. nau. skin. peroxides. IP: 12.25 mg/m3 DOT: 1920 128 Synonyms/Trade Names: n-Nonane.72 Provide: Eyewash VP: 3 mmHg FRZ: -60°F UEL: 2. Con Skin: Soap wash immed SY: Irrit eyes.8% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers (e. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 128.9% LEL: 0. inco.R. sodium Exposure Routes. skin. head. conf. BP: 303°F Not available. drow. resp sys. 2201 122 (refrigerated liquid) Synonyms/Trade Names: Dinitrogen monoxide. Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl. Con (liquid) Skin: Frostbite SY: Dysp. Eyes: Frostbite Sol(77°F): 0. Incompatibilities and Reactivities: Aluminum.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 44.R. Fl.P: 88°F Remove: When wet (flamm) IP: 10.D.3 atm FRZ: -132°F UEL: NA LEL: NA Nonflammable Gas.] OSHA ID166 OSHA PEL: none Physical Description: Colorless gas with a slightly sweet odor. but supports combustion at elevated temperatures. Breath: Resp support tremor. Nonyl hydride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 200 ppm (1050 mg/m3) OSHA PEL†: none None available Physical Description: Colorless liquid with a gasoline-like odor. N2O Conversion: 1 ppm = 1. CNS.1% Wash skin: N. perchlorates) Exposure Routes. Hyponitrous acid anhydride.53 Provide: Frostbite wash VP: 51. nose. drow. 6600 [*Note: REL for exposure to waste anesthetic gas.N CAS#: RTECS#: IDLH: Formula: 10024-97-2 QX1350000 N. boron. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh.D. hydrazine. lithium hydride..80 mg/m3 DOT: 1070 122. nitrates. repro sys Nitrous oxide Formula: CAS#: RTECS#: IDLH: CH3(CH2)7CH3 111-84-2 RA6115000 N. head. Symptoms. CNS Nonane 234 . RGasD: 1.P: NA Remove: N. chemical pneu (aspir liquid) Swallow: Medical attention immed TO: Eyes. Sp.

Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.CAS#: RTECS#: IDLH: Formula: 1455-21-6 N. IP: ? ScbaF/SaF §: ScbaF:Pd. Con Eye: Irr immed SY: Irrit eyes. strong acids & bases. Symptoms. skin.Pp:AScba Sol: Insoluble Remove: When wet or contam Escape: GmFOv100/ScbaE Fl.1 mg/m [skin] Physical Description: Waxy. 1. lass. vomit Swallow: Medical attention immed TO: Eyes.Pp:AScba Sp.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl. Symptoms.R. nau. CNS 1-Nonanethiol Formula: CAS#: RTECS#: IDLH: C10Cl8 2234-13-1 QK0250000 See Appendix F Conversion: DOT: Synonyms/Trade Names: Halowax® 1051. blood. liver damage.7 1 mg/m3: Sa/ScbaF Eyes: Prevent eye contact BP: 770°F Wash skin: When contam/Daily §: ScbaF:Pd. skin. Nonylthiol Exposure Limits: Measurement Methods NIOSH REL: C 0.P: ? Change: N. Perchloronaphthalene Exposure Limits: Measurement Methods NIOSH REL: TWA 0.Pp/SaF:Pd.Pp/SaF:Pd. cyan. pale-yellow solid with an aromatic odor.3 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: ? 12. Ing. resp sys. Con Skin: Water flush immed SY: Acne-form derm. reducing agents.8-Octachloronaphthalene.00 VP: <1 mmHg MLT: 365°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. liver Swallow: Medical attention immed Octachloronaphthalene O 235 .5 ppm (3. n-Nonyl mercaptan.6.4.P: NA Change: Daily IP: ? See Appendix F Sp. nose. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 160.3 mg/m [skin] 3 OSHA PEL†: TWA 0.56 mg/m3 DOT: 1228 131 Synonyms/Trade Names: 1-Mercaptononane. throat. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 403.1 mg/m3 (see Table 1): 3 NIOSH S97 (II-2) ST 0. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Gr: ? Escape: GmFOv/ScbaE VP: ? FRZ: ? UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Oxidizers.3.Gr: 2. incr respiration. Abs. head. jaun Breath: Resp support TO: Skin. alkali metals Exposure Routes. Skin: Soap wash Breath: Resp support drow.3 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Liquid.5. Ing. CH3(CH2)8SH Conversion: 1 ppm = 6.D.7.2.

reducing agents.Gr: 0.Gr: 0. CNS.72 mg/m3 DOT: 1228 131 (liquid) Synonyms/Trade Names: 1-Mercaptooctadecane.Pp/SaF:Pd. skin. Abs. drow.P: ? Change: Daily IP: ? ScbaF/SaF §: ScbaF:Pd. derm. skin.Pp:AScba Sp.D. Ing. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl. skin. Breath: Resp support in animals: narco Swallow: Medical attention immed TO: Eyes. Stearyl mercaptan Exposure Limits: Measurement Methods NIOSH REL: C 0. resp sys. cyan.00007% §: ScbaF:Pd.67 mg/m3 DOT: 1262 128 Synonyms/Trade Names: n-Octane.6 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: ? 12.P: 56°F Escape: GmFOv/ScbaE Change: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 286.85 Escape: GmFOv/ScbaE VP: ? MLT: 77°F UEL: ? LEL: ? Combustible Solid Combustible Liquid Incompatibilities and Reactivities: Oxidizers.0% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers First Aid (see Table 6): Exposure Routes. head. resp sys.2 750 ppm: Sa* Eyes: Prevent eye contact BP: 258°F 1000 ppm: Sa:Cf*/ScbaF/SaF Wash skin: When contam Sol(77°F): 0. Con SY: Irrit eyes. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Con Skin: Soap wash prompt SY: Irrit eyes. Symptoms. alkali metals Exposure Routes. Symptoms. nau.9 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Solid or liquid (above 77°F).Pp/SaF:Pd. CH3(CH2)17SH Conversion: 1 ppm = 11. convuls Skin: Soap wash immed Breath: Resp support TO: Eyes. CNS Octane 236 . lass. dizz. resp sys.5 ppm (5. nose. chemical pneu (aspir liquid). strong acids & bases.70 VP: 10 mmHg FRZ: -70°F UEL: 6.R. Ing. blood Swallow: Medical attention immed 1-Octadecanethiol O Formula: CAS#: RTECS#: IDLH: CH3[CH2]6CH3 111-65-9 RG8400000 1000 ppm [10%LEL] Conversion: 1 ppm = 4.5% LEL: 1. Octadecyl mercaptan.82 eV Sp. normal-Octane Exposure Limits: Measurement Methods NIOSH REL: TWA 75 ppm (350 mg/m3) (see Table 1): 3 NIOSH 1500 C 385 ppm (1800 mg/m ) [15-minute] 3 OSHA 7 OSHA PEL†: TWA 500 ppm (2350 mg/m ) Physical Description: Colorless liquid with a gasoline-like odor. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 114.Pp:AScba Remove: When wet (flamm) Fl. IP: 9.CAS#: RTECS#: IDLH: Formula: 2885-00-9 N.

Octylthiol. cyan. IP: ? ScbaF/SaF §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. vomit Swallow: Medical attention immed TO: Eyes. Con Breath: Fresh air SY: Irrit eyes.0 mg/m3) [15-minute] (see Table 1): NIOSH 2510 OSHA PEL: none Physical Description: Water-white liquid with a mild odor.84 Escape: GmFOv/ScbaE VP(212°F): 3 mmHg FRZ: -57°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Oxidizers. head.3 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 390°F 12. reducing agents. CNS 1-Octanethiol Oil mist (mineral) Formula: CAS#: 8012-95-1 RTECS#: PY8030000 IDLH: 2500 mg/m3 O Conversion: DOT: Synonyms/Trade Names: Heavy mineral oil mist. Ing. [Note: Has an odor like burned lubricating oil. lass.Pp/SaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: Varies 50 mg/m3: 100XQ/Sa Eyes: N.Gr: 0. Skin: Soap wash immed Breath: Resp support drow. nose. skin. resp sys TO: Eyes. Symptoms.Gr: 0.Pp:AScba Sp. oily liquid aerosol dispersed in air. Paraffin oil mist. 1-Octylthiol Exposure Limits: Measurement Methods NIOSH REL: C 0. throat.5 mmHg §: ScbaF:Pd. CH3(CH2)7SH Conversion: 1 ppm = 5. Target Organs (see Table 5): First Aid (see Table 6): Skin: Soap wash ER: Inh. n-Octyl mercaptan. resp sys 237 . Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 146. blood.Pp/SaF:Pd.CAS#: RTECS#: IDLH: Formula: 111-88-6 N. Symptoms.R.98 mg/m3 DOT: 1228 131 Synonyms/Trade Names: 1-Mercaptooctane.5 ppm (3. alkali metals Exposure Routes. skin. Con Eye: Irr immed SY: Irrit eyes. strong acids & bases.Pp VP: <0.P(oc): 115°F Change: N. skin. White mineral oil mist Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 3 NIOSH 5026.D. BP: 680°F Wash skin: When contam Sol: Insoluble 125 mg/m3: Sa:Cf/PaprHie Remove: When wet or contam Fl. 5524 ST 10 mg/m 3 OSHA PEL: TWA 5 mg/m Physical Description: Colorless. skin.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl.90 2500 mg/m3: Sa:Pd.R. nau. resp sys. incr respiration.Pp:AScba FRZ: 0°F Escape: 100F/ScbaE UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: None reported Exposure Routes.P(oc): 380°F 250 mg/m3: 100F/SaT:Cf/PaprTHie/ Change: Daily IP: ? ScbaF/SaF Sp.

easily oxidized organic materials [Note: Begins to sublime below BP. Symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 126.Gr: 1. Skin: Water flush prompt Breath: Resp support shock. silver compounds. acrid. chlorine-like odor. vis dist.60 eV 1 mg/m3: SaF:Pd. strong alkalis.Pp:AScba Provide: Eyewash VP: 7 mmHg Escape: GmFS100/ScbaE MLT: 105°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Hydrochloric acid.Pp Change: Daily Sp.40 mg/m3 DOT: 2471 154 Synonyms/Trade Names: Osmic acid anhydride. chlorites [Note: Gives off water of crystallization at 215°F and begins to sublime.001 mmHg Escape: 100F/ScbaE MLT: 215°F (Sublimes) UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers.Gr: 5.Pp/SaF:Pd. skin.P: NA ScbaF/SaF Remove: When wet or contam IP: 12. Ing.Pp Change: Daily Sp.] First Aid (see Table 6): Exposure Routes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 254. collapse. resp sys.] Exposure Routes. white solid. eye burns. cyan.1 NIOSH/OSHA Skin: Prevent skin contact BP: Sublimes 25 mg/m3: Sa:Cf£/PaprHie£ Eyes: Prevent eye contact Sol: 14% Wash skin: When contam Fl. skin. Con Eye: Irr immed SY: Irrit eyes. Contact with other materials may cause fire.Pp:AScba Provide: Eyewash VP: <0. head. muc memb. Oxalic acid dihydrate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 mg/m3 3 None available ST 2 mg/m 3 OSHA PEL†: TWA 1 mg/m Physical Description: Colorless. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. conj.P: ? 50 mg/m3: 100F/ScbaF/SaF Remove: When wet or contam IP: ? 500 mg/m3: SaF:Pd. Oxalic acid (aqueous). derm Breath: Resp support TO: Eyes. [Note: The anhydrous form (COOH)2 is an odorless. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Ing.002 mg/m Physical Description: Colorless. lac. dysp. resp sys. kidneys Oxalic acid 238 .90 §: ScbaF:Pd. convuls. cough. local pain. Osmium oxide Exposure Limits: Measurement Methods NIOSH REL: TWA 0.Pp/SaF:Pd.0006 ppm) 3 OSHA PEL†: TWA 0. crystalline solid or pale-yellow mass with an unpleasant.O Formula: CAS#: RTECS#: IDLH: OsO4 20816-12-0 RN1140000 1 mg/m3 Conversion: 1 ppm = 10.2 NIOSH/OSHA Skin: Prevent skin contact BP: 266°F 0. Symptoms.1 mg/m3: CcrFS100/GmFS100/ Eyes: Prevent eye contact Sol(77°F): 6% Wash skin: When contam Fl. skin. [Note: A liquid above 105°F.10 §: ScbaF:Pd.006 mg/m (0. odorless powder or granular solid. Con Skin: Soap wash immed SY: Irrit eyes. resp sys Swallow: Medical attention immed Osmium tetroxide Formula: CAS#: RTECS#: IDLH: HOOCCOOH×2H2O 144-62-7 RO2450000 500 mg/m3 Conversion: DOT: Synonyms/Trade Names: Ethanedioic acid. kidney damage Swallow: Medical attention immed TO: Eyes.0002 ppm) (see Table 1): 3 None available ST 0.002 mg/m3 (0.

05 ppm (0. Fluorine monoxide.1 mg/m3) (see Table 1): 3 OSHA PEL†: TWA 0.001% 2. Symptoms. head. Fl. Target Organs (see Table 5): Eye: Medical attention ER: Inh. [Note: Shipped as a nonliquefied compressed gas. but a strong oxidizer. chronic resp disease TO: Eyes.R.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 54. hydrogen sulfide. skin.R.Pp:AScba VP: >1 atm Escape: GmFS¿/ScbaE FRZ: -315°F UEL: NA LEL: NA Nonflammable Gas.R. skin burns Skin: Water flush immed Breath: Resp support (from contact with the gas under pressure) TO: Eyes.0 NIOSH/OSHA Skin: N.96 mg/m3 Synonyms/Trade Names: Triatomic oxygen Exposure Limits: Measurement Methods NIOSH REL: C 0. water [Note: Reacts very slowly with water to form hydrofluoric acid.52 eV Change: N. IP: 12. 100% O2 SY: Irrit eyes. Symptoms. Incompatibilities and Reactivities: Combustible materials. platinum.Formula: CAS#: RTECS#: IDLH: OF2 7783-41-7 RS2100000 0.88 VP: >1 atm FRZ: -371°F UEL: NA LEL: NA Nonflammable Gas.05 ppm (0.P: NA Escape: GmFS¿/ScbaE Remove: N. pulm edema. resp sys Formula: O3 DOT: CAS#: 10028-15-6 RTECS#: RS8225000 IDLH: 5 ppm 239 . eye.] Exposure Routes. Con Eye: Irr immed SY: Irrit eyes. but a powerful oxidizer.2 mg/m3) (see Table 1): 3 OSHA ID214 OSHA PEL†: TWA 0. Oxygen fluoride Exposure Limits: Measurement Methods NIOSH REL: C 0. skin. metal oxides.5 ppm: Sa:Cf/PaprS¿ Wash skin: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. BP: -230°F 0.1 ppm (0.R.21 mg/m3 DOT: 2190 124 Synonyms/Trade Names: Difluorine monoxide. moist air.R.R.Pp/SaF:Pd.02% §: ScbaF:Pd. RGasD: 1. BP: -169°F 1 ppm: CcrS¿/Sa Eyes: N. iodine.2 mg/m ) Physical Description: Colorless to blue gas with a very pungent odor. chlorine. bromine.11 eV Change: N.0 NIOSH/OSHA Skin: N. resp sys. Sol(32°F): 0. pulm edema. foul odor.1 ppm (0. Con Breath: Fresh air. IP: 13. Incompatibilities and Reactivities: All oxidizable materials (both organic & inorganic) First Aid (see Table 6): Exposure Routes. resp sys Oxygen difluoride O Ozone Conversion: 1 ppm = 1.Pp:AScba Wash skin: N.1 mg/m ) None available Physical Description: Colorless gas with a peculiar.66 ScbaF/SaF §: ScbaF:Pd.5 ppm Conversion: 1 ppm = 2. Sol: 0.P: NA 5 ppm: CcrFS¿/GmFS¿/SaT:Cf/ Remove: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 48. Fl. RGasD: 1.R.R.R.R.5 ppm: Sa/ScbaF Eyes: N. hydrocarbons. muc memb.Pp/SaF:Pd.

P: NA Sa*/ScbaF Remove: When wet or contam IP: ? §: ScbaF:Pd. Decomposes in presence of ultraviolet light. epis. Eyes: Prevent eye contact Sol: Insoluble Wash skin: N. C36H74).1'-Dimethyl-4.D. GI tract Paraquat (Paraquat dichloride) 240 .R. resp sys.P: 390°F Remove: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.4-bipyridinium ion). alkylaryl-sulfonate wetting agents [Note: Corrosive to metals.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 350-420 Skin: N. Conversion: DOT: Synonyms/Trade Names: Paraffin fume.1-Dimethyl-4. liver.1 mg/m3 (resp) [skin] 3 NIOSH 5003 OSHA PEL†: TWA 0.5 mg/m (resp) [skin] Physical Description: Yellow solid with a faint. derm. [herbicide] [Note: Paraquat may also be found commercially as a methyl sulfate salt C12H14N2×2CH3SO4.Gr: 1. Sp. Paraquat dichloride [Note: Paraquat is a cation (C12H14N2++. N.N'-Dimethyl-4.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 257. [Note: Consists of a mixture of high molecular weight hydrocarbons (e. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Con Breath: Resp support SY: Irrit eyes.Pp/SaF:Pd.2 NIOSH Skin: Prevent skin contact BP: Decomposes 1 mg/m3: CcrOv95*/PaprOvHie*/ Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. nose. Sp. Symptoms.g. heart. odorless solid.R. kidney damage Swallow: Medical attention immed TO: Eyes.88-0. nau TO: Eyes. Ing.Pp:AScba Change: N.] Exposure Routes. Paraffin scale fume Exposure Limits: Measurement Methods NIOSH REL: TWA 2 mg/m3 (see Table 1): OSHA PV2047 OSHA PEL†: none Physical Description: Paraffin wax is a white to slightly yellowish.Gr: 0.. kidneys. IP: ? Change: N.4'-bipyridinium dichloride. resp sys Paraffin wax fume P CAS#: RTECS#: IDLH: Formula: 1910-42-5 DW2275000 1 mg/m3 CH3(C5H4N)2CH3×2Cl Conversion: DOT: Synonyms/Trade Names: 1.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. the commercial product is the dichloride salt of paraquat. resp sys. skin. skin. skin. skin.24 Escape: GmFOv100/ScbaE Provide: Quick drench VP: <0. Con SY: Irrit eyes. liver. fingernail Skin: Water flush immed Breath: Resp support damage.92 VP: ? MLT: 115-154°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes.4'-bipyridinium dichloride. Paraquat chloride. Abs. heart. throat.Formula: CAS#: RTECS#: IDLH: CnH2n+2 8002-74-2 RV0350000 N.0000001 mmHg MLT: 572°F (Decomposes) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers. irrit GI tract. 1. discomfort. ammonia-like odor.R.R. resp sys. BP: ? Not available. Fl. Symptoms.R.

Symptoms.D. alkaline materials First Aid (see Table 6): Exposure Routes.Formula: CAS#: RTECS#: IDLH: (C2H5O)2P(S)OC6H4NO2 56-38-2 TF4550000 10 mg/m3 Conversion: DOT: 2783 152 Synonyms/Trade Names: O. not listed specifically in 1910.R. skin. lar Skin: Soap wash immed spasm. cyan.00004 mmHg §: ScbaF:Pd. Target Organs (see Table 5): Eye: Irr immed ER: Inh.27 10 mg/m3: Sa:Pd. chest tight. skin. CVS.Pp VP: 0. ataxia.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 291. convuls. wheez. whether mineral. anor.Gr: 1. skin. Pesticide that may be absorbed on a dry carrier.R.5 mg/m3: CcrOv95/Sa Eyes: Prevent eye contact BP: 707°F Wash skin: When contam Sol: 0. abdom cramps. Con SY: Irrit eyes. coma. conf. card irreg TO: Eyes. blood chol Parathion Particulates not otherwise regulated Formula: CAS#: RTECS#: IDLH: N. para. Eyes: N. Not available. Parathion-ethyl Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. dizz. head. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. vomit. throat. diarr. Abs. nau. upper resp sys TO: Eyes. Ethyl parathion. sweat.P(oc): 392°F 2. resp sys. Diethyl parathion. Con Breath: Fresh air SY: Irrit eyes. miosis.R. PNOR [Note: Includes all inert or nuisance dusts. Symptoms. rhin. salv. Wash skin: N.] Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): OSHA PEL: TWA 15 mg/m3 (total) NIOSH 0500. lass. low BP.R. CNS. resp sys 241 .Pp/SaF:Pd.001% 1. inorganic.5 mg/m3: CcrFOv100/SaT:Cf/ Change: Daily IP: ? PaprTOvHie/ScbaF/SaF Provide: Eyewash Sp. Ing.05 mg/m3 [skin] 3 NIOSH 5600 OSHA PEL: TWA 0.Pp:AScba Quick drench FRZ: 43°F Escape: GmFOv100/ScbaE UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.3 0. Remove: N. specific solid. P Conversion: DOT: Synonyms/Trade Names: ”Inert” dusts.25 mg/m3: Sa:Cf/PaprOvHie Remove: When wet or contam Fl. [Note: A solid below 43°F. 0600 TWA 5 mg/m3 (resp) Physical Description: Dusts from solid substances without specific occupational exposure standards. resp sys.1000. musc Breath: Resp support Swallow: Medical attention immed fasc. skin.O-Diethyl-O(p-nitrophenyl) phosphorothioate.1 mg/m [skin] OSHA 62 Physical Description: Pale-yellow to dark-brown liquid with a garlic-like odor. Nuisance dusts. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): Properties vary depending upon the Skin: N. Incompatibilities and Reactivities: Varies Exposure Routes.R. Change: N.

Pp Change: N.Gr: 0. kidney. skin.28 eV Change: N. Con Skin: Soap wash immed SY: Irrit eyes. skin. Breath: Resp support musc inco. abdom. Hydrolyzes slowly with heat in water to form boric acid. CNS. halogens.68 Provide: Eyewash VP: 3 mmHg FRZ: -20°F Quick drench UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: (Sodium-potassium alloy + bromoform). Reaction with alkalis & metals produces spontaneously explosive chloroacetylenes. lass.125 ppm: Sa:Cf Wash skin: When contam Sol: Reacts 0.015 ppm (0. alkalis.3 Skin: Prevent skin contact BP: 322°F Not available. Con Skin: Soap wash SY: In animals: irrit eyes. Conversion: DOT: 1669 151 Synonyms/Trade Names: Ethane pentachloride. metals. Symptoms.P: 86°F 1 ppm: Sa:Pd.05% Wash skin: When contam Fl. tremor.R. Sp. Breath: Resp support behavioral changes.005 ppm (0.005 ppm (0. chloroform-like odor.03 mg/m ) 3 OSHA PEL†: TWA 0. head. Eyes: Prevent eye contact Sol: 0. skin.R. Ing. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Formula: CAS#: RTECS#: IDLH: B5H9 19624-22-7 RY8925000 1 ppm Conversion: 1 ppm = 2. water [Note: Hydrolysis produces dichloroacetic acid.05 ppm: Sa Eyes: Prevent eye contact BP: 140°F 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 202.58 mg/m3 DOT: 1380 135 Synonyms/Trade Names: Pentaboron nonahydride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. liver.25 ppm: SaT:Cf/ScbaF/SaF Remove: When wet (flamm) Fl.Pp:AScba Provide: Eyewash Sp.P: ? Remove: When wet or contam IP: 11. drow. tonic spasm face.1 0. Abs. liver. Symptoms. lung changes Swallow: Medical attention immed TO: Eyes. restless.D.90 eV §: ScbaF:Pd. halogenated hydrocarbons [Note: May ignite SPONTANEOUSLY in moist air. kidneys Pentachloroethane 242 . Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 63. dizz.01 mg/m3) (see Table 1): 3 None available ST 0.62 Escape: GmFS/ScbaE VP: 171 mmHg Quick drench FRZ: -52°F UEL: ? LEL: 0. Corrosive to natural rubber. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. water. limbs Swallow: Medical attention immed TO: Eyes. IP: 9. (see Table 1): NIOSH 2517 See Appendix C (Chloroethanes) OSHA PEL: none Physical Description: Colorless liquid with a sweetish. Pentalin Exposure Limits: Measurement Methods NIOSH REL: Handle with care in the workplace. Ing. irreg respiration. convuls. resp sys.] Exposure Routes. inco. skin.01 mg/m ) Physical Description: Colorless liquid with a pungent odor like sour milk. neck.42% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers. CNS Pentaborane P Formula: CAS#: RTECS#: IDLH: CHCl2CCl3 76-01-7 KI6300000 N.] Exposure Routes.Pp/SaF:Pd.Gr: 1.

3. nau. pruritus.Pp:AScba Remove: When wet or contam Fl. kidneys. chest pain.5-Pentachloronaphthalene Exposure Limits: Measurement Methods NIOSH REL: TWA 0.P: NA Escape: GmFOv100/ScbaE Change: Daily IP: ? Sp.4. throat. anor.Gr: 1.5 mg/m [skin] NIOSH 5512 Physical Description: Colorless to white. sneez. crystalline solid with a benzene-like odor. liver.98 VP(77°F): 0. CNS Pentachloronaphthalene Formula: CAS#: RTECS#: IDLH: C6Cl5OH 87-86-5 SM6300000 2. lass. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.3. lass. Ing. Abs. Con Eye: Irr immed SY: Irrit eyes.6-Pentachlorophenol Exposure Limits: Measurement Methods NIOSH REL: TWA 0. CVS.Pp/SaF:Pd.5 mg/m3 [skin] (see Table 1): 3 NIOSH S96 (II-2) OSHA PEL: TWA 0.P: NA Change: Daily Escape: GmFOv100/ScbaE IP: NA Provide: Eyewash Sp. vomit. liver nec Swallow: Medical Attention immed TO: Skin. [fungicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 266.Formula: CAS#: RTECS#: IDLH: C10H3Cl5 1321-64-8 QK0300000 See Appendix F Conversion: DOT: Synonyms/Trade Names: Halowax® 1013. 1.Pp/SaF:Pd.67 See Appendix F VP: <1 mmHg MLT: 248°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.5 mg/m3 Conversion: DOT: 3155 154 Synonyms/Trade Names: PCP. liver. dizz. Symptoms. derm Breath: Resp support Swallow: Medical attention immed TO: Eyes. acids. dysp.4.001% Sa*/ScbaF Remove: When wet or contam §: ScbaF:Pd. Con Eye: Irr immed SY: Head. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.5 mg/m3: CcrOv95*/PaprOvHie*/ Eyes: Prevent eye contact BP: 588°F (Decomposes) Wash skin: When contam Sol: 0. 2.5 mg/m [skin] Physical Description: Pale-yellow or white solid or powder with an aromatic odor. Symptoms. alkalis Exposure Routes. cough.5. head. Skin: Soap wash immed sweat. Ing.Gr: 1. high fever. acne-form skin eruptions. Abs. anor. Penta. low-wgt.0001 mmHg Quick drench MLT: 374°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers. dizz.5 mg/m3 [skin] (see Table 1): 3 OSHA PEL: TWA 0. resp sys.4 5 mg/m3: Sa*/ScbaF Eyes: Prevent eye contact BP: 636°F Wash skin: When contam Sol: Insoluble §: ScbaF:Pd. Skin: Soap prompt/molten flush immed Breath: Resp support jaun. skin. CNS Pentachlorophenol P 243 . nose.Pp:AScba Fl. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 300.4 2.2.

Symptoms. Tetramethylolmethane Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. resp sys Breath: Fresh air TO: Eyes.P: -57°F §: ScbaF:Pd. Con Skin: Water wash SY: Irrit eyes. resp sys.R.63 VP: 420 mmHg FRZ: -202°F UEL: 7. [Note: Technical grade is 88% monopentaerythritol & 12% dipentaerythritol.2-bis(Hydroxymethyl)-1.04% 1500 ppm: Sa:Cf/ScbaF/SaF Wash skin: When contam Fl. derm. Conversion: DOT: Synonyms/Trade Names: 2. Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 72. Sp. Ing.34 eV Escape: GmFOv/ScbaE Change: N. nose. resp sys Swallow: Medical attention immed Pentaerythritol Formula: CAS#: RTECS#: IDLH: CH3[CH2]3CH3 109-66-0 RZ9450000 1500 ppm [10%LEL] Conversion: 1 ppm = 2. chemical pneu (aspir liquid). 0600 TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Colorless to white.2 NIOSH Skin: Prevent skin contact BP: 97°F 1200 ppm: Sa Eyes: Prevent eye contact Sol: 0.R.00000008 mmHg MLT: 500°F (Sublimes) UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Organic acids. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. [Note: A gas above 97°F. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Con Skin: Water wash prompt SY: Irrit eyes.Gr: 0.8% LEL: 1. skin.5% Class IA Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Eyes: N. BP: Sublimes Not available.Gr: 1. Tetrahydroxymethylolmethane.R. Ing. CNS n-Pentane 3 244 .95 mg/m DOT: 1265 128 Synonyms/Trade Names: Pentane. IP: ? Change: N. Symptoms. Sol(59°F): 6% Wash skin: N.3-propanediol.P: ? Remove: N. Methane tetramethylol. skin. in animals: narco Swallow: Medical attention immed TO: Eyes.] Exposure Routes.P Formula: CAS#: RTECS#: IDLH: C(CH2OH)4 115-77-5 RZ2490000 N.R. Monopentaerythritol. PE. Breath: Resp support drow. May be utilized as a fuel. crystalline. Sp.Pp/SaF:Pd.R.D.38 VP: 0.Pp:AScba Remove: When wet (flamm) IP: 10. normal-Pentane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 120 ppm (350 mg/m3) NIOSH 1500 C 610 ppm (1800 mg/m3) [15-minute] OSHA 7 OSHA PEL†: TWA 1000 ppm (2950 mg/m3) Physical Description: Colorless liquid with a gasoline-like odor.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 136.R.2 Skin: N. oxidizers [Note: Explosive compound is formed when a mixture of PE & thiophosphoryl chloride is heated. odorless powder.

5% Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers. nose. head. skin.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: Insoluble 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) Fl.R.1 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Water-white to yellowish liquid with a strong. MPK Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 150 ppm (530 mg/m3) 3 NIOSH 1300. throat.52 mg/m3 DOT: 1249 127 Synonyms/Trade Names: Ethyl acetone.Pp:AScba Remove: When wet (flamm) Fl. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 86.CAS#: RTECS#: IDLH: Formula: 110-66-7 SA3150000 N.2% LEL: 1. CNS Swallow: Medical attention immed 2-Pentanone P 245 . garlic-like odor. Ing.84 Escape: GmFOv/ScbaE VP(77°F): 14 mmHg FRZ: -104°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers. 2555 OSHA PEL†: TWA 200 ppm (700 mg/m ) Physical Description: Colorless to water-white liquid with a characteristic acetone-like odor.Pp/SaF:Pd. Methyl propyl ketone.Pp/SaF:Pd. Con SY: Irrit eyes. Pentyl mercaptan Exposure Limits: Measurement Methods NIOSH REL: C 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Amyl mercaptan. nau. reducing agents.1 1500 ppm: CcrOv*/PaprOv*/GmFOv/ Eyes: Prevent eye contact BP: 215°F Wash skin: When contam Sol: 6% Sa*/ScbaF §: ScbaF:Pd. dizz. skin sens Swallow: Medical attention immed TO: Eyes.Pp:AScba Sp. derm.D. resp sys. Amyl sulfhydrate. skin. derm.P: 45°F Escape: GmFOv/ScbaE Change: N.5 ppm (2. coma Breath: Resp support TO: Eyes.2 5 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 260°F 12. concentrated nitric acid Exposure Routes. alkali metals. resp sys. skin. calcium hypochlorite. muc memb. vomit.R. Skin: Soap wash immed Breath: Resp support diarr.P(oc): 65°F Change: N.Gr: 0.Gr: 0. Symptoms. resp sys. Symptoms. IP: ? ScbaF/SaF §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. IP: 9.39 eV Sp.26 mg/m3 DOT: 1111 130 Synonyms/Trade Names: Amyl hydrosulfide. CH3(CH2)4SH Conversion: 1 ppm = 4. CNS 1-Pentanethiol Formula: CAS#: RTECS#: IDLH: CH3COCH2CH2CH3 107-87-9 SA7875000 1500 ppm Conversion: 1 ppm = 3. head. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 104. skin.81 VP: 27 mmHg FRZ: -108°F UEL: 8. Ing. bromine trifluoride Exposure Routes. narco. Con Skin: Water flush SY: Irrit eyes.

lac. liver.P: NA 5 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam IP: ? Change: N. sulfur & CO2 on contact with water.8 mg/m3) (see Table 1): 3 OSHA PEL: TWA 0. resp sys. reducing agents. Fl.Pp:AScba FRZ: ? Escape: GmFOv/ScbaE UEL: NA LEL: NA Noncombustible Liquid. Skin: Frostbite Breath: Resp support lass. resp sys.5 atm FRZ: -234°F UEL: NA LEL: NA Nonflammable Gas. Symptoms. Incompatibilities and Reactivities: Alkalis. amines.1 ppm (0. dizz. Trichloromethyl sulfur chloride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. blood Perchloryl fluoride 246 . tacar. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp/SaF:Pd. sweet odor. Chlorine oxyfluoride. Target Organs (see Table 5): Eye: Irr immed ER: Inh.06% 75 ppm: Sa:Cf* Wash skin: N. liquid: frostbite. Con Skin: Soap wash immed SY: Irrit eyes. water [Note: Corrosive to most metals. Breath: Resp support coarse rales. Trioxychlorofluoride Exposure Limits: Measurement Methods NIOSH REL: TWA 3 ppm (14 mg/m3) (see Table 1): 3 None available ST 6 ppm (28 mg/m ) 3 OSHA PEL†: TWA 3 ppm (13.5 NIOSH/OSHA Skin: Frostbite BP: -52°F 30 ppm: Sa Eyes: Frostbite Sol: 0. acidosis. Ing. Con (liquid) Eye: Frostbite SY: Irrit resp sys. amines. finely divided metals.R. PMM. Sp.19 mg/m3 DOT: 3083 124 Synonyms/Trade Names: Chlorine fluoride oxide.R.Pp:AScba Change: N. Abs.8 mg/m ) None available Physical Description: Pale-yellow. IP: 13. RGasD: 3. deep breath pain. cyan. kidneys Perchloromethyl mercaptan P CAS#: RTECS#: IDLH: Formula: 7616-94-6 SD1925000 100 ppm ClO3F Conversion: 1 ppm = 4. acrid odor. oily liquid with an unbearable. anoxia TO: Skin.R. [Note: Shipped as a liquefied compressed gas.CAS#: RTECS#: IDLH: Formula: 594-42-3 PB0370000 10 ppm Cl3CSCl Conversion: 1 ppm = 7.] First Aid (see Table 6): Exposure Routes. anuria. Incompatibilities and Reactivities: Combustibles.64 Escape: GmFS¿/ScbaE Provide: Frostbite wash VP: 10. throat. hot iron.69 SaT:Cf*/ScbaF/SaF 10 ppm: SaF:Pd. but will support combustion. Trichloromethane sulfenyl chloride. Symptoms.Gr: 1. cough.R.9 NIOSH/OSHA Skin: Prevent skin contact BP: 297°F (Decomposes) 1 ppm: CcrOv*/Sa* Eyes: Prevent eye contact Sol: Insoluble 2.1 ppm (0. liver. skin.60 eV §: ScbaF:Pd. dysp.Pp/SaF:Pd. head.P: NA 100 ppm: ScbaF/SaF Remove: N. Forms HCl.Pp VP: 3 mmHg §: ScbaF:Pd. nose. kidney damage Swallow: Medical attention immed TO: Eyes. skin. strong bases. in animals: methemo. alcohols Exposure Routes. but will support combustion.5 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Fl.5 mg/m ) Physical Description: Colorless gas with a characteristic. pallor.60 mg/m3 DOT: 1670 157 Synonyms/Trade Names: PCM.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 102. pulm edema. vomit. pneu. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 185.

P: NA Remove: N. resp sys Petroleum distillates (naphtha) Formula: CAS#: 8002-05-9 RTECS#: SE7449000 IDLH: 1100 ppm [10%LEL] P Conversion: 1 ppm = 4.Perlite Formula: CAS#: 93763-70-3 RTECS#: SD5254000 IDLH: N.66 VP: 40 mmHg (approx) FRZ: -99°F UEL: 5.Pp/SaF:Pd.3 (expanded) VP: 0 mmHg (approx) MLT: >2000°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. Fl.05 mg/m3 DOT: Synonyms/Trade Names: Aliphatic petroleum naphtha. IP: ? Sp.63-0.2 . light-gray to glassy-black solid. BP: ? Not available. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.or kerosene-like odor. Con Breath: Fresh air SY: Irrit eyes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 99 (approx) 850 ppm: Sa Eyes: Prevent eye contact BP: 86-460°F 1100 ppm: Sa:Cf*/ScbaF/SaF Wash skin: When contam Sol: Insoluble §: ScbaF:Pd. Sol: <1% Wash skin: N.0. throat. Symptoms.1% Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. head. Petroleum naphtha. resp sys. Sp.R.Pp:AScba Remove: When wet (flamm) Fl. throat. skin.Gr: 2.2. CNS 247 .P: -40 to -86°F Escape: GmFOv/ScbaE Change: N. drow. dry cracked Breath: Resp support skin.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. Rubber solvent Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 350 mg/m3 3 NIOSH 1550 C 1800 mg/m [15-minute] OSHA PEL†: TWA 500 ppm (2000 mg/m3) Physical Description: Colorless liquid with a gasoline. chemical pneu (aspir liquid) Swallow: Medical attention immed TO: Eyes. Eyes: N.05 . nose. skin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: varies Skin: N.Gr: 0. upper resp sys TO: Eyes. Con Skin: Soap wash prompt SY: Irrit eyes.R. white particulate.R. skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. dizz.R. Conversion: DOT: Synonyms/Trade Names: Expanded perlite [Note: An amorphous material consisting of fused sodium potassium aluminum silicate. IP: NA Change: N. Ing.R.9% LEL: 1. Symptoms.D.4 (crude) 0. nau.R. [Note: A mixture of paraffins (C5 to C13) that may contain a small amount of aromatic hydrocarbons. [Note: Expanded perlite is a fluffy. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Odorless.

Incompatibilities and Reactivities: None reported Exposure Routes.Pp/SaF:Pd. Symptoms. hepatitis. cyan. Ing. Hydroxybenzene. derm.P: 175°F Change: Daily IP: 8.6 ppm (60 mg/m ) [15-minute] 3 OSHA PEL: TWA 5 ppm (19 mg/m ) [skin] OSHA 32 Physical Description: Colorless to light-pink. but not a high fire risk. liver.3 Skin: Prevent skin contact BP: 700°F Not available.Pp:AScba Provide: Eyewash Sp. pain.1 50 ppm: CcrOv95/Sa Eyes: Prevent eye contact BP: 359°F 125 ppm: Sa:Cf/PaprOvHie Wash skin: When contam Sol(77°F): 9% 250 ppm: CcrFOv100/GmFOv100/ Remove: When wet or contam Fl. [Note: Phenol liquefies by mixing with about 8% water. Breath: Resp support abdom cramps. CVS.P CAS#: RTECS#: IDLH: Formula: 108-95-2 SJ3325000 250 ppm C6H5OH Conversion: 1 ppm = 3. Abs. resp sys. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. musc ache. Thiodiphenylamine Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 [skin] (see Table 1): OSHA PV2048 OSHA PEL†: none Physical Description: Grayish-green to greenish-yellow solid. Phenyl hydroxide Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (19 mg/m3) [skin] (see Table 1): 3 NIOSH 2546 C 15. 2312 153 (molten). Fenothiazine.8% Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. low-wgt. Con Skin: Soap wash prompt SY: Itching. skin. aluminum chloride. tremor.D. tacar. liver.50 eV PaprTOvHie/ScbaF/SaF §: ScbaF:Pd. crystalline solid with a sweet.6% LEL: 1. throat. twitch TO: Eyes. Abs. Eyes: N. acids Exposure Routes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. kidneys Phenothiazine 248 .85 mg/m3 DOT: 1671 153 (solid). anor.R. kidney damage.4 mmHg Quick drench MLT: 109°F UEL: 8. acrid odor.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 94. nose. 2821 153 (solution) Synonyms/Trade Names: Carbolic acid. Monohydroxybenzene.P: ? Remove: When wet or contam IP: ? Change: Daily Sp. kidney damage.06 Escape: GmFOv100/ScbaE VP: 0. Ing. skin burns. liver. Sol: Insoluble Wash skin: When contam/Daily Fl. hemolytic anemia. Phenyl alcohol. S(C6H4)2NH Conversion: DOT: Synonyms/Trade Names: Dibenzothiazine. Skin: Soap wash immed Breath: Resp support dark urine. Swallow: Medical attention immed ochronosis. lass. kidneys Phenol CAS#: RTECS#: IDLH: Formula: 92-84-2 SN5075000 N. skin photo sens Swallow: Medical attention immed TO: Skin.Gr: 1. convuls. Symptoms. Con SY: Irrit eyes. calcium hypochlorite. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 199. reddening skin.Gr: ? VP: 0 mmHg (approx) MLT: 365°F UEL: ? LEL: ? Combustible Solid. irrit.

Gr: 1. skin. IP: 8. crystalline solid. Con Eye: Irr immed SY: Irrit pharynx.4-Benzenediamine. crystalline solid or liquid (above 82°F) with a geranium-like odor.P: 239°F ScbaF/SaF 100 ppm: SaF:Pd. Con Skin: Soap wash prompt SY: Irrit eyes.02 mmHg MLT: 82°F UEL: 6. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 108. Symptoms. bronchial asthma. 1.4-Diaminobenzene.7% Combustible Solid Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.Pp:AScba Sp. skin Breath: Resp support Swallow: Medical attention immed p-Phenylene diamine Formula: CAS#: RTECS#: IDLH: C6H5OC6H5 101-84-8 KN8970000 100 ppm Conversion: 1 ppm = 6. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp Change: N.2 25 ppm: Sa:Cf£/PaprOvHie£ Eyes: Prevent eye contact BP: 498°F 50 ppm: CcrFOv100/GmFOv100/ Wash skin: When contam Sol: Insoluble Remove: When wet or contam Fl.R.1 mg/m3 [skin] 3 OSHA 87 OSHA PEL: TWA 0. resp sys Phenyl ether (vapor) P 249 .1 mg/m [skin] Physical Description: White to slightly red. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. nau Breath: Resp support TO: Eyes. 1. Symptoms.Pp Change: Daily IP: 6. Phenyl oxide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 ppm (7 mg/m3) 3 NIOSH 1617 OSHA PEL: TWA 1 ppm (7 mg/m ) OSHA PV2022 Physical Description: Colorless. 1. sens derm Skin: Soap wash prompt TO: Resp sys. Ing. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 170.Formula: CAS#: RTECS#: IDLH: C6H4(NH2)2 106-50-3 SS8050000 25 mg/m3 Conversion: DOT: 1673 153 Synonyms/Trade Names: 4-Aminoaniline. Phenoxy benzene. larynx.Pp:AScba Sp.08 Escape: GmFOv100/ScbaE VP(77°F): 0.0% LEL: 0.2 2.Gr: ? Escape: GmFS100/ScbaE VP: <1 mmHg MLT: 295°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Diphenyl oxide.P: 312°F 25 mg/m3: SaF:Pd.09 eV §: ScbaF:Pd.4-Phenylene diamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.5 mg/m3: Sa:Cf£ Eyes: Prevent eye contact BP: 513°F Wash skin: When contam/Daily Sol(75°F): 4% 5 mg/m3: ScbaF/SaF Remove: When wet or contam Fl. Abs.Pp/SaF:Pd. skin. nose.89 eV §: ScbaF:Pd.96 mg/m3 DOT: Synonyms/Trade Names: Diphenyl ether.Pp/SaF:Pd. p-Diaminobenzene.

nose. hemato sys.Formula: CAS#: RTECS#: IDLH: C6H5OC6H5/C6H5C6H5 8004-13-5 DV1500000 10 ppm Conversion: 1 ppm = 6. skin. [Note: A mixture typically contains 75% phenyl ether & 25% biphenyl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 166 (approx) 10 ppm: Sa:Cf£/CcrFOv100/GmFOv100/ Eyes: Prevent eye contact BP: 495°F Wash skin: When contam Sol: Insoluble PaprOvHie£/ScbaF/SaF §: ScbaF:Pd.79 mg/m3 (approx) DOT: Synonyms/Trade Names: Diphenyl oxide-diphenyl mixture. Abs. Skin: Soap wash prompt Breath: Resp support repro effects.Pp/SaF:Pd. repro sys [in animals: nasal cancer] Phenyl glycidyl ether 250 .08 mmHg FRZ: 54°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.14 mg/m3 DOT: Synonyms/Trade Names: 1. skin.2% Remove: When wet or contam Fl. Dowtherm® A Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (7 mg/m3) (see Table 1): 3 OSHA PEL: TWA 1 ppm (7 mg/m ) NIOSH 2013 Physical Description: Colorless to straw-colored liquid or solid (below 54°F) with a disagreeable.Pp:AScba Remove: When wet or contam Fl. Symptoms.R.P: 239°F Escape: GmFOv100/ScbaE Change: N. PGE. strong bases Exposure Routes.Pp/SaF:Pd. Phenyl 2. upper resp sys. skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. [carc] Swallow: Medical attention immed TO: Eyes. CNS.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 150.06 VP(77°F): 0.11 VP: 0.Gr(77°F): 1. [Note: A solid below 38°F.R. strong acids.P: 248°F Change: N. IP: ? Provide: Eyewash Sp. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Ing.2-Epoxy-3-phenoxy propane. narco. Con Skin: Soap wash prompt SY: Irrit eyes. skin sens. Con Eye: Irr immed SY: Irrit eyes.Gr: 1. Symptoms. IP: ? Sp. aromatic odor. Glycidyl phenyl ether. possible hemato.01 mmHg Quick drench FRZ: 38°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.Pp:AScba Eyes: Prevent eye contact BP: 473°F Escape: GmFOv/ScbaE Wash skin: When contam Sol: 0.3-epoxypropyl ether Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 1619 C 1 ppm (6 mg/m ) [15-minute] OSHA 7 See Appendix A OSHA PEL†: TWA 10 ppm (60 mg/m3) Physical Description: Colorless liquid.1 ¥: ScbaF:Pd. amines. resp sys Phenyl ether-biphenyl mixture (vapor) P Formula: CAS#: RTECS#: IDLH: C9H10O2 122-60-1 TZ3675000 Ca [100 ppm] Conversion: 1 ppm = 6. nau Breath: Resp support TO: Eyes. skin.

dysp.24 Change: Daily VP: ? Provide: Eyewash MLT: 226°F Quick drench UEL: ? LEL: ? Incompatibilities and Reactivities: Oxidizers Combustible Solid P N-Phenyl-β-naphthylamine Exposure Routes. liver. liver. bladder [bladder cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash immed Breath: Resp support Swallow: Medical attention immed 251 .Pp:AScba Eyes: Prevent eye contact Sol: Slight Escape: ScbaE Wash skin: When contam/Daily Fl. blood vessels & intestine] Phenylhydrazine Formula: CAS#: RTECS#: IDLH: C10H7NHC6H5 135-88-6 QM4550000 Ca [N. Con Eye: Irr immed SY: Skin sens. Monophenylhydrazine Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 3518 C 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 108. skin [in animals: tumors of the lungs. acne. hemolytic anemia.42 mg/m3 DOT: 2572 153 Synonyms/Trade Names: Hydrazinobenzene. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms. [carc] TO: Eyes. Skin: Soap wash immed Breath: Resp support vascular thrombosis. Target Organs (see Table 5): ER: Inh. Ing.P: ? Wash skin: When contam/Daily IP: ? Remove: When wet or contam Sp.3 (see Table 2): NIOSH BP: 743°F Skin: Prevent skin contact ¥: ScbaF:Pd. PBNA. Phenyl-β-naphthylamine Exposure Limits: Measurement Methods NIOSH REL: Ca* (see Table 1): OSHA 96 See Appendix A [*Note: Since metabolized to β-Naphthylamine.Pp/SaF:Pd. β-Naphthylphenylamine.1 NIOSH Skin: Prevent skin contact BP: 470°F (Decomposes) ¥: ScbaF:Pd. skin.Formula: CAS#: RTECS#: IDLH: C6H5NHNH2 100-63-0 MV8925000 Ca [15 ppm] Conversion: 1 ppm = 4. Abs.] Conversion: DOT: Synonyms/Trade Names: 2-Anilinonaphthalene. cyan. jaun. resp sys.Gr: 1.04 mmHg FRZ: 67°F Quick drench UEL: ? LEL: ? Class IIIA Combustible Liquid Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. aromatic odor.Pp:AScba Sol: Insoluble Eyes: Prevent eye contact Escape: GmFOv100/ScbaE Fl. kidney damage. hypersensitivity to sunlight. [Note: Commercial product may contain 20-30 ppm of β-Naphthylamine. Ing.10 Provide: Eyewash VP(77°F): 0.6 mg/m ) [2-hr] [skin] See Appendix A 3 OSHA PEL†: TWA 5 ppm (22 mg/m ) [skin] Physical Description: Colorless to pale-yellow liquid or solid (below 67°F) with a faint. Symptoms.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 219.P: 190°F Remove: When wet or contam IP: 7.Pp/SaF:Pd.] OSHA PEL: none Physical Description: White to yellow crystals or gray to tan flakes or powder. kidneys. leucoplakia. Con SY: Irritation.64 eV Change: Daily Sp. 2-Phenylaminonaphthalene. lead dioxide Exposure Routes. Abs.D. [carc] Swallow: Medical attention immed TO: Blood.Gr: 1.14 ppm (0.

nau. O. dizz.Gr(59°F): 1.D. skin. Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl. salv. but does not readily ignite. CVS. diarr. Abs. wheez. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. abdom cramps. repro sys Phenylphosphine P Formula: CAS#: RTECS#: IDLH: (C2H5O)2P(S)SCH2SC2H5 298-02-2 TD9450000 N.O-Diethyl S-(ethylthio)methylphosphorodithioate. Sp. vomit. blood chol Phorate 252 . low BP. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Symptoms.001 VP: ? FRZ: ? UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: None reported [Note: Spontaneously combustible in high concentrations in air. toxic) Synonyms/Trade Names: O.P(oc): 320°F Remove: When wet or contam IP: ? Change: N.Formula: CAS#: RTECS#: IDLH: C6H5PH2 638-21-1 SZ2100000 N. Con Skin: Soap flush immed SY: Irrit eyes. lac. cyan. musc fasc. Conversion: DOT: 3018 152 (organophosphorus pesticide. convuls. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 110.50 mg/m3 DOT: Synonyms/Trade Names: Fenylfosfin. Potential exposure to gaseous PF when polyphosphinates are heated above 392°F.Gr(77°F): 1.25 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Clear.0008 mmHg FRZ: -45°F Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid. Symptoms. CNS. Incompatibilities and Reactivities: Water. ataxia. testicular degeneration.P: ? Remove: When wet or contam IP: ? Change: N. derm Swallow: Medical attention immed TO: Blood.D. head. anor. rhin. anemia. Sp. liquid. hind leg tremor.005% Wash skin: When contam Fl.] Exposure Routes. lar spasm.] First Aid (see Table 6): Exposure Routes. Phosphaniline Exposure Limits: Measurement Methods NIOSH REL: C 0. Eyes: Prevent eye contact Sol: 0. resp sys. skin. diarr. card irreg TO: Eyes. Thimet. conf. Conversion: 1 ppm = 4. sweat. PF. alkalis [Note: Hydrolyzed in the presence of moisture and by alkalis.16 Provide: Eyewash VP: 0. Ing.R. colorless liquid with a foul odor.R. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 260. Timet Exposure Limits: Measurement Methods NIOSH REL: TWA 0.4 Skin: Prevent skin contact BP: ? Not available. CNS.O-Diethyl S-ethylthiomethylthiothionophosphate.05 mg/m3 (see Table 1): 3 NIOSH 5600 ST 0. Breath: Resp support Swallow: Medical attention immed lass.05 ppm (0. coma. Con Eye: Irr immed SY: In animals: blood changes. Ing.1 Skin: Prevent skin contact BP: 320°F Not available. para.2 mg/m [skin] OSHA PEL†: none Physical Description: Clear liquid with a skunk-like odor. miosis. Skin: Soap wash Breath: Resp support loss of appetite. skin. resp sys. chest tight.

CVS. Skin: Water flush immed (liquid) Breath: Resp support dysp. chest pain.01 ppm (0. cyan.1 mg/m [skin] Physical Description: Pale-yellow to orange liquid with a weak odor. [Note: A fuming liquid below 47°F. Abs. VP: 1. resp sys.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 224.Pp/SaF:Pd.8 mg/m3) [15-minute] OSHA PEL: TWA 0. nau. diarr.Gr: 1.43 (Liquid at 32°F) Change: N.& trans-isomers. miosis.P(oc): 347°F 0. alkalis. Symptoms. skin. resp sys Phosgene 3 253 .17 mg/m3 DOT: 2783 152 Synonyms/Trade Names: 2-Carbomethoxy-1-methylvinyl dimethyl phosphate. lar Breath: Resp support spasm. Shipped as a liquefied compressed gas.9 (see Table 2): NIOSH/OSHA BP: 47°F Skin: Prevent skin contact (liquid) 1 ppm: Sa* Sol: Slight Eyes: Prevent eye contact (liquid) 2 ppm: ScbaF/SaF Fl. Carbonyl chloride.4 mg/m3) OSHA 61 C 0.2 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 0. chest tight. rhin. head.] First Aid (see Table 6): Exposure Routes. liquid: frostbite TO: Eyes.R. alcohols. cyan. blood chol Phosdrin P Formula: CAS#: RTECS#: IDLH: COCl2 75-44-5 SY5600000 2 ppm Conversion: 1 ppm = 4. Chloroformyl chloride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.6 atm Provide: Quick drench (liquid) FRZ: -198°F UEL: NA Incompatibilities and Reactivities: Moisture. ammonia. CNS.25 §: ScbaF:Pd.R. foamy sputum. vomit.Formula: CAS#: RTECS#: IDLH: C7H13PO6 7786-34-7 GQ5250000 4 ppm Conversion: 1 ppm = 9. dry burning throat. Con Skin: Soap wash immed SY: Irrit eyes. wheez. salv.P: NA Wash skin: When contam (liquid) §: ScbaF:Pd. card irreg TO: Eyes.Pp/SaF:Pd.4 mg/m3) Physical Description: Colorless gas with a suffocating odor like musty hay. Sp. ataxia. LEL: NA copper Nonflammable Gas [Note: Reacts slowly in water to form hydrochloric acid & carbon dioxide.] Exposure Limits: Measurement Methods NIOSH REL: TWA 0.1 ppm: Sa Eyes: Prevent eye contact Sol: Miscible 0. Carbonyl dichloride.] Exposure Routes.25 ppm: Sa:Cf Wash skin: When contam Fl. Mevinphos [Note: Commercial product is a mixture of the cis. Swallow: Medical attention immed convuls. para. anor. [Note: Insecticide that may be absorbed on a dry carrier.1 ppm (0.Pp:AScba Provide: Eyewash VP: 0.3 mg/m ) 3 OSHA PEL†: TWA 0.003 mmHg Escape: GmFOv100/ScbaE FRZ: 44°F (trans-) Quick drench 70°F (cis-) UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers [Note: Corrosive to cast iron. Con (liquid) Eye: Irr immed (liquid) SY: Irrit eyes. skin.05 mg/m DOT: 1076 125 Synonyms/Trade Names: Carbon oxychloride.03 ppm (0. skin.1 mg/m3) [skin] (see Table 1): 3 NIOSH 5600 ST 0.1 ppm (0. some stainless steels & brass. low BP.Gr: 1. abdom cramps. vomit. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms.5 ppm: SaT:Cf/ScbaF/SaF Remove: When wet or contam IP: ? 4 ppm: Sa:Pd.48 (liquid) Sp.Pp:AScba IP: 11.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 98.2 ppm (0.Pp Change: N. Ing. cough. resp sys. Target Organs (see Table 5): Eye: Irr immed ER: Inh.55 eV Remove: When wet or contam Escape: GmFS/ScbaE RGasD: 3.

Phosphoric acid (aqueous). Symptoms.P: NA (Gas) 15 ppm: GmFS/ScbaF/SaF Remove: When wet (flamm) IP: 9.33 (50% solution) VP: 0. upper resp sys.03 mmHg Quick drench (>1.4 mg/m3) (see Table 1): 3 OSHA 1003. most metals [Note: Readily reacts with metals to form flammable hydrogen gas. halogenated hydrocarbons. Symptoms. dysp. DO NOT MIX WITH SOLUTIONS CONTAINING BLEACH OR AMMONIA.Gr(77°F): 1. musc Skin: Frostbite Breath: Resp support pain. chlorine.] Exposure Routes. Phosphorus hydride.6%) MLT: 108°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong caustics.Pp/SaF:Pd. crystalline solid. odorless. oxidizers. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.3 atm Escape: GmFS/ScbaE FRZ: -209°F UEL: ? LEL: 1.18 §: ScbaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 98. Con Eye: Irr immed SY: Irrit eyes. derm Skin: Water flush Immed TO: Eyes. Phosphorus trihydride Exposure Limits: Measurement Methods NIOSH REL: TWA 0.5 ppm: Sa:Cf Wash skin: N.6%) Escape: 100F/ScbaE 1. resp sys Breath: Resp support Swallow: Medical attention immed Phosphoric acid 254 . White phosphoric acid Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): 3 NIOSH 7903 ST 3 mg/m OSHA ID165SG OSHA PEL†: TWA 1 mg/m3 Physical Description: Thick.0 NIOSH/OSHA Skin: Prevent skin contact BP: 415°F 25 mg/m3: Sa:Cf* Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. pulm edema. colorless. 3453 154 (solid) Synonyms/Trade Names: Orthophosphoric acid.4 mg/m ) Physical Description: Colorless gas with a fish. chest tight.Pp:AScba Provide: Frostbite wash VP: 41. vomit. abdom pain.Pp Change: N. [Note: Often used in an aqueous solution.or garlic-like odor.R.3 ppm (0. ID180 ST 1 ppm (1 mg/m ) 3 OSHA PEL†: TWA 0. chills. Con (liquid) SY: Nau. Fl.] Exposure Routes.P: NA 50 mg/m3: 100F/ScbaF/SaF Remove: When wet or contam IP: ? 1000 mg/m3: SaF:Pd. moisture. eye.Pp:AScba Provide: Eyewash (>1.R.0 NIOSH/OSHA Skin: Frostbite BP: -126°F 3 ppm: Sa Eyes: Frostbite Sol: Slight 7. copper [Note: May ignite SPONTANEOUSLY on contact with air.79% Flammable Gas Incompatibilities and Reactivities: Air.Pp/SaF:Pd. Ing. [pesticide] [Note: Shipped as a liquefied compressed gas. thirst. skin. liquid: frostbite TO: Resp sys Phosphine P Formula: CAS#: RTECS#: IDLH: H3PO4 7664-38-2 TB6300000 1000 mg/m3 Conversion: DOT: 1805 154 (liquid or solution). diarr.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 34. burns.39 mg/m3 DOT: 2199 119 Synonyms/Trade Names: Hydrogen phosphide. Pure compound is odorless. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh. Phosphorated hydrogen.87 (pure) §: ScbaF:Pd. acids. RGasD: 1. stupor or syncope.Formula: CAS#: RTECS#: IDLH: PH3 7803-51-2 SY7525000 50 ppm Conversion: 1 ppm = 1.3 ppm (0.96 eV 50 ppm: Sa:Pd.Pp Change: Daily Sp. skin. skin.

lass. Con Eye: Irr immed SY: Irrit eyes.3 Skin: Prevent skin contact BP: 222°F Not available. skin. Con SY: Irrit eyes.6 mg/m3) (see Table 1): 3 None available ST 0. Symptoms.03 mmHg Change: Daily MLT: 111°F Provide: Eyewash UEL: ? LEL: ? Quick drench Flammable Solid Incompatibilities and Reactivities: Air. cachexia. metals (except nickel & lead) [Note: Decomposes in water to hydrochloric & phosphoric acids. waxy solid with acrid fumes in air. halogens [Note: Ignites SPONTANEOUSLY in moist air. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. eye. cough. salv. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.1 mg/m Physical Description: White to yellow.5 ppm (3 mg/m ) OSHA PEL†: none Physical Description: Clear. kidneys Phosphorus oxychloride P 255 . eye.] Exposure Routes.1 mg/m3 (see Table 1): 3 NIOSH 7905 OSHA PEL: TWA 0.] Exposure Routes. skin burns. Incompatibilities and Reactivities: Water. Ing. Phosphorus oxytrichloride. skin.R. dizz.] Eyes: Prevent eye contact IP: ? §: ScbaF:Pd. White phosphorus Exposure Limits: Measurement Methods NIOSH REL: TWA 0. dental pain. dimethyl-formamide. jaun. kidneys. resp tract.Formula: CAS#: RTECS#: IDLH: P4 7723-14-0 TH3500000 5 mg/m3 Conversion: DOT: 1381 136 Synonyms/Trade Names: Elemental phosphorus. vomit. carbon disulfide. Eyes: Prevent eye contact Sol: Decomposes Wash skin: When contam Fl.Gr: 1. skin. resp sys. abdom pain.5 mg/m3: Sa:Cf£ protective equipment should be Fl. Symptoms. skin burns. Phosphoryl chloride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. dysp. teeth. liver. neph Swallow: Medical attention immed TO: Eyes. jaw. head. Conversion: 1 ppm = 6. CNS. jaw pain. abdom pain. colorless to yellow. nau. resp sys.Gr(77°F): 1. [Note: A solid below 34°F. but may set fire to combustible materials. blood Phosphorus (yellow) Formula: CAS#: RTECS#: IDLH: POCl3 10025-87-3 TH4897000 N. Ing.27 mg/m3 DOT: 1810 137 Synonyms/Trade Names: Phosphorus chloride. oily liquid with a pungent & musty odor.Pp/SaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact* MW: 124.1 ppm (0. [Note: Usually shipped or stored in water. resp sys. nau.P: ? 5 mg/m3: ScbaF/SaF provided. Skin: Water flush immed Breath: Resp support anemia.82 Escape: ScbaE Remove: When wet or contam VP: 0. soft. pulm Skin: Water flush immed Breath: Resp support edema.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 153.D.0003% 2.0 1 mg/m3: Sa [*Note: Flame retardant personal BP: 536°F Sol: 0. swell Swallow: Medical attention immed TO: Eyes. Sp. oxidizers (including elemental sulfur & strong caustics). combustible materials.65 Provide: Eyewash VP(81°F): 40 mmHg FRZ: 34°F Quick drench UEL: NA LEL: NA Noncombustible Liquid.P: NA Remove: When wet or contam IP: ? Change: N.Pp:AScba Wash skin: When contam Sp.

Sulfur phosphide Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): 3 None available ST 3 mg/m 3 OSHA PEL†: TWA 1 mg/m Physical Description: Greenish-gray to yellow. Con Skin: Water flush immed SY: Irrit eyes.3 (P2S5) (see Table 2): NIOSH/OSHA Skin: Prevent skin contact 444.Pp/SaF:Pd. Symptoms.P: ? 50 mg/m3: ScbaF/SaF Change: Daily IP: ? 250 mg/m3: SaF:Pd. dizz. derm Breath: Resp support TO: Eyes.Pp/SaF:Pd. crystalline solid with an odor of rotten eggs.] Phosphorus pentasulfide Exposure Routes. sulfur dioxide. unpleasant odor. Phosphoric chloride. Con SY: Irrit eyes. photo.6 (P4S10) 10 mg/m3: Sa* Eyes: Prevent eye contact BP: 957°F Wash skin: When contam Sol: Reacts 25 mg/m3: Sa:Cf* Remove: When wet or contam Fl. acids. SPONTANEOUSLY ignite in alkalis [Note: Reacts with water to form hydrogen sulfide. amines [Note: Hydrolyzes in water (even in humid air) to form hydrochloric acid & phosphoric acid. Corrosive to metals. kerato-conj. lass. water flush Breath: Resp support Swallow: Medical attention immed 256 .09 §: ScbaF:Pd. GI dist TO: Eyes.Pp Sp. strong oxidizers. resp sys. resp sys. resp sys Swallow: Medical attention immed Phosphorus pentachloride P Formula: CAS#: RTECS#: IDLH: P2S5/P4S10 1314-80-3 TH4375000 250 mg/m3 Conversion: DOT: 1340 139 Synonyms/Trade Names: Phosphorus persulfide. bron. Ing. resp sys. crystalline solid with a pungent. Phosphorus sulfide. phosphoric acid. chemically-active metals such as sodium and potassium. CNS First Aid (see Table 6): Eye: Irr immed Skin: Dust off solid.P: NA 25 mg/m3: Sa:Cf* Remove: When wet or contam IP: ? 50 mg/m3: ScbaF/SaF Change: Daily Sp. Target Organs (see Table 5): ER: Inh.3 NIOSH/OSHA Skin: Prevent skin contact BP: Sublimes 10 mg/m3: Sa* Eyes: Prevent eye contact Sol: Reacts Wash skin: When contam Fl. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 222. alcohols.Gr: 2. skin.] Exposure Routes. lac. irrity.Pp:AScba VP(572°F): 1 mmHg Escape: GmFS100/ScbaE MLT: 550°F UEL: ? LEL: ? Flammable Solid.60 70 mg/m3: SaF:Pd. magnesium oxide. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Ing. convuls.Pp Provide: Eyewash VP(132°F): 1 mmHg §: ScbaF:Pd. skin. apnea. and presence of moisture.Pp:AScba MLT: 324°F (Sublimes) Escape: GmFOv100/ScbaE Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Water. conj pain. head. corn vesic. coma. skin. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 208.Gr: 3.Formula: CAS#: RTECS#: IDLH: PCl5 10026-13-8 TB6125000 70 mg/m3 Conversion: DOT: 1806 137 Synonyms/Trade Names: Pentachlorophosphorus. Symptoms. which may Incompatibilities and Reactivities: Water. insom. Phosphorus perchloride Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): 3 NIOSH S257 (II-5) OSHA PEL: TWA 1 mg/m Physical Description: White to pale-yellow. skin. alkalis.

91 eV Remove: When wet or contam Escape: GmFS¿/ScbaE Sp. Symptoms. VP: 100 mmHg Provide: Eyewash FRZ: -170°F Quick drench UEL: NA LEL: NA Noncombustible Liquid.Pp/SaF:Pd. throat. conj.Gr: 1.2 ppm (1. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 148.Gr: 1.58 Change: N. in animals: liver. mobile liquid (molten) with a characteristic. Ing.5% LEL: 1.2-Benzenedicarboxylic anhydride. PAN.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Ing. nose. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 137. upper resp sys.4 (see Table 2): NIOSH BP: 169°F Skin: Prevent skin contact 10 ppm: ScbaF/SaF Sol: Reacts Eyes: Prevent eye contact 25 ppm: SaF:Pd. however.5 mg/m3) (see Table 1): 3 NIOSH 6402 ST 0.] combustibles upon contact. Breath: Resp support bron. eye.53 (Flake) §: ScbaF:Pd. a Incompatibilities and Reactivities: Water. bronchial asthma. organic matter strong oxidizer that may ignite [Note: Hydrolyzes in water to form hydrochloric acid and phosphoric acid. aluminum.62 mg/m3 DOT: 1809 137 Synonyms/Trade Names: Phosphorus chloride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. chemically-active metals such as sodium & potassium.5 ppm (3 mg/m ) Physical Description: Colorless to yellow. Symptoms. liver.7% Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. Phthalic acid anhydride Exposure Limits: Measurement Methods NIOSH REL: TWA 6 mg/m3 (1 ppm) (see Table 1): NIOSH S179 (II-3) OSHA PEL†: TWA 12 mg/m3 (2 ppm) OSHA 90 Physical Description: White solid (flake) or a clear.Pp Fl. skin burns Breath: Resp support TO: Eyes.0015 mmHg MLT: 267°F UEL: 10. skin. acrid odor.06 mg/m DOT: 2214 156 Synonyms/Trade Names: 1. fuming liquid with an odor like hydrochloric acid.1 NIOSH Skin: Prevent skin contact BP: 563°F 30 mg/m3: Qm* Eyes: Prevent eye contact Sol: 0.00 eV Sa*/ScbaF Change: Daily Sp. kidneys Phthalic anhydride P 3 257 . Con Skin: Soap wash prompt SY: Irrit eyes. strong nitric acid.P: NA Wash skin: When contam §: ScbaF:Pd. kidney damage Swallow: Medical attention immed TO: Eyes. nasal ulcer bleeding.] Exposure Routes.Pp:AScba IP: 9. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.5 ppm (3 mg/m ) 3 OSHA PEL†: TWA 0. Exposure Routes.P: 305°F 60 mg/m3: 95XQ*/95F/PaprHie*/ Remove: When wet or contam IP: 10. colorless.Pp/SaF:Pd. pulm edema. derm. water [Note: Converted to phthalic acid in hot water.6% Wash skin: When contam Fl.20 (Molten) VP: 0.Formula: CAS#: RTECS#: IDLH: PCl3 7719-12-2 TH3675000 25 ppm Conversion: 1 ppm = 5. skin. acetic acid.Pp:AScba Escape: 100F/ScbaE 1. Con Skin: Water flush immed SY: Irrit eyes. skin. skin. resp sys. resp sys Swallow: Medical attention immed Phosphorus trichloride CAS#: RTECS#: IDLH: Formula: 85-44-9 TI3150000 60 mg/m3 C6H4(CO)2O Conversion: 1 ppm = 6.

1.D.5 Skin: Prevent skin contact BP: Decomposes Not available. skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.P: ? Remove: N. chlorine.3-Dicyanobenzene.6-trichloropicolinic acid. Conversion: DOT: Synonyms/Trade Names: 4-Amino-3. [herbicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 241.. in animals: irrit eyes.01 mmHg MLT: 324°F (Sublimes) UEL: ? LEL: ? Combustible Solid and a severe explosion hazard.04% Wash skin: When contam Fl. colorless to white. Incompatibilities and Reactivities: Strong oxidizers (e.5. Ing.g. Eyes: Prevent eye contact Sol: 0. in animals: liver. 4-Amino-3. nau. resp sys. skin. nau. kidneys Swallow: Medical attention immed Picloram 258 . skin Breath: Resp support TO: Eyes. ATCP. Con Skin: Soap wash immed SY: Head.42 VP: 0.Gr: ? VP(95°F): 0. kidney changes Breath: Fresh air TO: Eyes. Tordon® Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: See Appendix D 3 3 NIOSH 0500. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 128. fluorine) Exposure Routes.5.6-trichloro-2-picolinic acid. m-PDN Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 OSHA PEL†: none None available Physical Description: Needle-like. liver.R. IP: ? Change: Daily Sp. Abs.0000006 mmHg MLT: 424°F (Decomposes) UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Hot concentrated alkali (hydrolyzes) First Aid (see Table 6): Exposure Routes. skin. Target Organs (see Table 5): Eye: Irr immed ER: Inh. bromine. crystalline.1 Skin: Prevent skin contact BP: Sublimes Not available. Isophthalodinitrile. flaky solid with an almond-like odor. Con Skin: Soap wash SY: Irrit eyes. CNS Swallow: Medical attention immed m-Phthalodinitrile P Formula: CAS#: RTECS#: IDLH: C6H3Cl3O2N2 1918-02-1 TJ7525000 N. Symptoms. Eyes: Prevent eye contact Sol: Slight Wash skin: Daily Fl.D. m-Dicyanobenzene. Ing. Symptoms.Formula: CAS#: RTECS#: IDLH: C6H4(CN)2 626-17-5 CZ1900000 N. Conversion: DOT: Synonyms/Trade Names: 1.P: ? Remove: When wet or contam IP: ? Change: Daily Sp. resp sys.3-Benzenedicarbonitrile.Gr: 4. 0600 OSHA PEL†: TWA 15 mg/m (total) TWA 5 mg/m (resp) Physical Description: Colorless to white crystals with a chlorine-like odor. conf.

[rodenticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 230.3-indandione Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Gr: 1. Pival®. Ing Eye: Irr immed SY: Epis. Symptoms. excess bleeding from minor cuts. hepatitis.1 mg/m [skin] Physical Description: Yellow. skin. Fl.R.3 NIOSH/OSHA Skin: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. back pain TO: Blood prothrombin P Pindone 259 . bruises.Pp/SaF:Pd.1 mg/m None available Physical Description: Bright-yellow powder with almost no odor. myalgia. blood Picric acid Formula: CAS#: RTECS#: IDLH: C9H5O2C(O)C(CH3)3 83-26-1 NK6300000 100 mg/m3 Conversion: DOT: Synonyms/Trade Names: tert-Butyl valone. yellow-stained hair. sens derm.109). IP: ? 2.] Exposure Limits: Measurement Methods NIOSH REL: TWA 0.Gr: 1. Abs.76 5 mg/m3: 100F/SaT:Cf/PaprTHie/ VP(383°F): 1 mmHg ScbaF/SaF MLT: 252°F 75 mg/m3: SaF:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 229. skin. ≥ 10% water).Pp UEL: ? §: ScbaF:Pd.5 mg/m3: Qm Eyes: N. skin.R. ammonia [Note: Corrosive to metals. Conversion: 1 ppm = 9.5 mg/m3: Sa:Cf/PaprHie Change: Daily Sp.Pp:AScba LEL: ? Escape: 100F/ScbaE Incompatibilities and Reactivities: None reported Exposure Routes. Pivalyl. smoky urine. 1.P: ? 1 mg/m3: 95XQ/Sa Remove: N. black Breath: Resp support Swallow: Medical attention immed tarry stools. Breath: Resp support anuria. BP: Decomposes 0. An explosive mixture results when the aqueous solution crystallizes. album. polyuria.1 mg/m3 (see Table 1): 3 NIOSH S228 (II-4) ST 0. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Symptoms.1 mg/m3 3 OSHA PEL: TWA 0. lass.06 5 mg/m3: 100F/SaT:Cf/PaprTHie/ VP: Very low ScbaF/SaF MLT: 230°F 100 mg/m3: SaF:Pd.6-Trinitrophenol [Note: An OSHA Class A Explosive (1910.002% Wash skin: N. salts. kidneys.Pp:AScba LEL: ? Escape: 100F/ScbaE Combustible Solid Incompatibilities and Reactivities: Copper. Con Skin: Soap wash prompt SY: Irrit eyes. odorless solid. zinc & other metals.4.R. hema.37 mg/m3 3364 113 (wetted. [Note: Usually used as an aqueous solution.1 NIOSH/OSHA Skin: Prevent skin contact BP: Explodes above 572°F 0. bitter taste.Pp UEL: ? §: ScbaF:Pd. Ing. plaster. ≥ 10% water) Synonyms/Trade Names: Phenol trinitrate.5 mg/m3: Qm Eyes: Prevent eye contact Sol: 1% Wash skin: When contam/Daily Fl. lead.CAS#: RTECS#: IDLH: Formula: 88-89-1 TJ7875000 75 mg/m3 (NO2)3C6H2OH DOT: 1344 113 (wet. concrete.5 mg/m3: Sa:Cf/PaprHie Change: Daily Sp. GI dist.] First Aid (see Table 6): Exposure Routes. Sol(77°F): 0.3-Dioxo-2-pivaloy-lindane.Pp/SaF:Pd.3 mg/m [skin] 3 OSHA PEL: TWA 0.P: 302°F 1 mg/m3: 95XQ/Sa Remove: When wet or contam IP: ? 2. neph Swallow: Medical attention immed TO: Eyes.R. 2-Pivalyl-1. liver. abdom. 2.

] Exposure Routes.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. Dried calcium sulfate. odorless powder. Sol(77°F): 0. skin. Incompatibilities and Reactivities: Water [Note: Slightly hygroscopic (i.3% Wash skin: N.Gr: 2.R.D. water [Note: Hygroscopic (i.R. skin burns. Ing.R. vomit. resp sys Plaster of Paris 260 . but does not ignite easily. asthma. Symptoms.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 OSHA PEL†: none None available Physical Description: White to cream-colored needles or powder. CNS Piperazine dihydrochloride P CAS#: RTECS#: IDLH: Formula: 26499-65-0 TP0700000 N. skin. BP: ? Not available. finely divided.R.P: ? Remove: When wet or contam IP: ? Change: Daily Sp.CAS#: RTECS#: IDLH: Formula: 142-64-3 TL4025000 N.. CaSO4•0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. GI upset. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 159. resp sys. skin. C4H10N2×2HCl Conversion: DOT: Synonyms/Trade Names: Piperazine hydrochloride [Note: The monochloride. C4H10N2×HCl is also commercially available.R.P: NA Remove: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 145. Hemihydrate gypsum [Note: Plaster of Paris is the hemihydrate form of Calcium Sulfate & Gypsum is the dihydrate form. absorbs moisture from the air). resp sys. skin. Sp.] Exposure Routes. Symptoms. sens. Abs. Gypsum hemihydrate. inco. Con SY: Irrit eyes. muc memb.2 Skin: N. Skin: Water flush immed Breath: Resp support head. 0600 TWA 5 mg/m (resp) OSHA PEL: TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp) Physical Description: White or yellowish..e.D. cough Swallow: Medical attention immed TO: Eyes. IP: NA Change: N. absorbs moisture from the air). Eyes: Prevent eye contact Sol: 41% Wash skin: When contam Fl. Reacts with water to form Gypsum.5H2O Conversion: DOT: Synonyms/Trade Names: Calcium sulfate hemihydrate. Ing.5 VP: 0 mmHg (approx) MLT: 325°F (Loses H2O) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Moisture.1 Skin: Prevent skin contact BP: ? Not available. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Fl. resp sys. Con Breath: Resp support SY: Irrit eyes.e. Eyes: N. musc weak Swallow: Medical attention immed TO: Eyes.Gr: ? Provide: Eyewash VP: ? MLT: 635°F Quick drench UEL: ? LEL: ? Combustible Solid. nau.

Sol: Insoluble Wash skin: N. ductile metal. sens skin. Con Eye: Irr immed SY: Irrit eyes. Ing.R. Eyes: Prevent eye contact Wash skin: When contam 0. S191 (II-7) OSHA PEL: TWA 0. Platinum metal.002 mg/m Physical Description: Appearance and odor vary depending upon the specific soluble platinum salt. BP: 6921°F Not available. Conversion: DOT: Synonyms/Trade Names: Platinum black.1 mg/m3: 100F/ScbaF/SaF Remove: When wet or contam 4 mg/m3: SaF:Pd. dysp. derm. malleable. hydrazine.002 mg/m3 3 NIOSH 7300. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. resp sys Swallow: Medical attention immed Platinum Platinum (soluble salts.P: NA Remove: N. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA Properties vary depending upon Skin: Prevent skin contact 0.Formula: CAS#: RTECS#: IDLH: Pt 7440-06-4 TP2160000 N. derm Breath: Resp support TO: Eyes.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes. skin. Platinum sponge Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): NIOSH 7300. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 195. Fl. Symptoms. IP: NA Change: Daily Sp.Pp Change: Daily §: ScbaF:Pd.05 mg/m3: Sa:Cf£ the specific soluble platinum salt. various fluorides Exposure Routes. 7303 OSHA PEL†: none OSHA ID121. phosphorus. cyan. Incompatibilities and Reactivities: Aluminum. lithium. 7303. nose. arsenic. resp sys P 261 . ID130SG Physical Description: Silvery.Gr: 21. but finely divided powder can be dangerous to handle. hydrogen peroxide.45 VP: 0 mmHg (approx) MLT: 3222°F UEL: NA LEL: NA Noncombustible Solid in bulk form. acetone.R.1 Skin: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.R. as Pt) Formula: CAS#: RTECS#: IDLH: 4 mg/m3 (as Pt) Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific soluble platinum salt.R.D. wheez. ethane. Eyes: N. cough. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Pp/SaF:Pd. Ing. tellurium. skin. Symptoms. resp sys. Skin: Water flush immed Breath: Resp support lymphocytosis Swallow: Medical attention immed TO: Eyes. selenium. whitish-gray. Con Skin: Soap wash SY: Irrit skin.

Con Skin: Soap wash immed SY: Irrit eyes. lass. CNS. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 7904 OSHA PEL*: TWA 5 mg/m [*Note: The REL and PEL also apply to other cyanides (as CN) except Hydrogen cyanide. Ing. odorless powder. Con SY: Irrit eyes. almond-like odor.] First Aid (see Table 6): Exposure Routes. skin.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500 TWA 5 mg/m (resp) OSHA PEL†: TWA 50 mppcf OSHA ID207 Physical Description: Gray. thyroid.P: NA 100 mg/m3: 95XQ/Sa Remove: When wet or contam IP: NA 250 mg/m3: Sa:Cf/PaprHie Change: N. resp sys. but contact with acids releases highly flammable hydrogen cyanide. 3413 157 (solution) Synonyms/Trade Names: Potassium salt of hydrocyanic acid Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: C 5 mg/m3 (4. expectoration. conf. asphy. acid salts. Breath: Resp support incr resp rate. resp sys P Formula: CAS#: RTECS#: IDLH: KCN 151-50-8 TS8750000 25 mg/m3 (as CN) Conversion: DOT: 1680 157 (solid). cough.and dicalcium silicate in addition to alumina.55 Provide: Eyewash VP: 0 mmHg (approx) MLT: 1173°F Quick drench UEL: NA LEL: NA Noncombustible Solid. derm Swallow: Medical attention immed TO: Eyes.] Physical Description: White. exertional dysp. Portland cement silicate [Note: A class of hydraulic cements containing tri.Pp:AScba Remove: When wet or contam IP: NA Escape: GmFS100/ScbaE Change: Daily Sp. Target Organs (see Table 5): Eye: Irr immed ER: Inh.1 NIOSH/OSHA Skin: Prevent skin contact BP: 2957°F 25 mg/m3: Sa/ScbaF Eyes: Prevent eye contact Sol(77°F): 72% Wash skin: When contam Fl. Symptoms. Abs. tricalcium aluminate.Gr: ? 500 mg/m3: 100F/SaT:Cf/PaprTHie/ VP: 0 mmHg (approx) ScbaF/SaF MLT: NA 5000 mg/m3: Sa:Pd. vomit. skin. blood changes Swallow: Medical attention immed TO: Eyes. Ing.Pp/SaF:Pd. Symptoms. chronic bron. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 65.Pp UEL: NA §: ScbaF:Pd. granular or crystalline solid with a faint. Sp.Portland cement Formula: CAS#: 65997-15-1 RTECS#: VV8770000 IDLH: 5000 mg/m3 Conversion: DOT: Synonyms/Trade Names: Cement. upper resp sys. nose.P: NA §: ScbaF:Pd. blood Potassium cyanide (as CN) 262 . skin. Hydraulic cement.Gr: 1. Skin: Soap wash prompt Breath: Fresh air wheez. nau. slow gasping respiration.7 ppm) [10-minute] 3 NIOSH 6010. Incompatibilities and Reactivities: Strong oxidizers (such as acids. CVS. skin. chlorates & nitrates) [Note: Absorbs moisture from the air forming a syrup. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: ? NIOSH Skin: Prevent skin contact BP: NA 50 mg/m3: Qm Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.R. and iron oxide. head. thyroid.Pp:AScba LEL: NA Escape: 100F/ScbaE Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes.Pp/SaF:Pd.

Conversion: DOT: 1813 154 (dry.5% LEL: 2. liquid: frostbite Breath: Resp support TO: CNS Propane 3 263 . 1978 115 Synonyms/Trade Names: Bottled gas. Lye. skin. Con Eye: Irr immed SY: Irrit eyes. Fl. solid).Pp/SaF:Pd. [Note: May be used as an aqueous solution. eye. water.R. however. metals (when wet). RGasD: 1. Ing. conf.Gr: 2. resp sys. diarr Swallow: Medical attention immed TO: Eyes. rods.R. resp sys Potassium hydroxide P Formula: CAS#: RTECS#: IDLH: CH3CH2CH3 74-98-6 TX2275000 2100 ppm [10%LEL] Conversion: 1 ppm = 1.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 56. Symptoms. [Note: A foul-smelling odorant is often added when used for fuel purposes.04 Provide: Eyewash VP(1317°F): 1 mmHg MLT: 716°F Quick drench UEL: NA LEL: NA Noncombustible Solid. Incompatibilities and Reactivities: Acids. n-Propane. odorless gas. Potassium hydrate Exposure Limits: Measurement Methods NIOSH REL: C 2 mg/m3 (see Table 1): NIOSH 7401 OSHA PEL†: none Physical Description: Odorless. maleic anhydride [Note: Heat is generated if KOH comes in contact with H2O & CO2 from the air. excitation. skin.80 mg/m DOT: 1075 115. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh.01% §: ScbaF:Pd. asphy.] Exposure Routes. Propyl hydride Exposure Limits: Measurement Methods NIOSH REL: TWA 1000 ppm (1800 mg/m3) (see Table 1): NIOSH S87 (II-2) OSHA PEL: TWA 1000 ppm (1800 mg/m3) OSHA PV2077 Physical Description: Colorless.D.4 atm FRZ: -306°F UEL: 9. Skin: Water flush immed Breath: Resp support vomit. Dimethyl methane. sticks.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 44. Symptoms.Pp:AScba Wash skin: N. flakes. cough. Eyes: Prevent eye contact Sol(59°F): 107% Wash skin: When contam Fl.P: NA Remove: When wet or contam IP: ? Change: Daily Sp.55 Provide: Frostbite wash VP(70°F): 8. sneez.P: NA (Gas) Escape: ScbaE Remove: When wet (flamm) IP: 11. Con (liquid) Skin: Frostbite SY: Dizz. Shipped as a liquefied compressed gas.07 eV Change: N. skin burns. or pellets.1% Flammable Gas Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.1 NIOSH/OSHA Skin: Frostbite BP: -44°F 2100 ppm: Sa/ScbaF Eyes: Frostbite Sol: 0.Formula: CAS#: RTECS#: IDLH: KOH 1310-58-3 TT2100000 N. halogenated hydrocarbons. 1814 154 (solution) Synonyms/Trade Names: Caustic potash. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.1 Skin: Prevent skin contact BP: 2415°F Not available. white or slightly yellow lumps. may react with H2O & other substances and generate sufficient heat to ignite combustible materials.

CAS#: RTECS#: IDLH: Formula: 1120-71-4 RP5425000 Ca [N. [carc] Breath: Resp support TO: Eyes. kidney damage Swallow: Medical attention immed TO: Eyes.195 eV Change: N. crystalline solid or a colorless liquid (above 86°F). skin.Pp/SaF:Pd.Pp:AScba Eyes: Prevent eye contact BP: ? Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: 10% Remove: When wet or contam Fl. Ing. resp sys.39 VP: ? Quick drench MLT: 86°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. cabbage-like odor.P: >235°F Change: Daily IP: ? Provide: Eyewash Sp. Skin: Soap wash Breath: Resp support in animals: liver.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 122.2 NIOSH Skin: N. skin. throat. 1.R. dizz. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.5 ppm (1.Gr: 0. CNS. BP: 153°F 5 ppm: CcrOv/Sa Eyes: Prevent eye contact Sol: Slight 12. gliomas] Swallow: Medical attention immed Propane sultone P Formula: CAS#: RTECS#: IDLH: CH3CH2CH2SH 107-03-9 TZ7300000 N. resp sys [in animals: skin tumors.D. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 76. skin.R. calcium hypochlorite Exposure Routes. Ing. Conversion: 1 ppm = 3. Propyl mercaptan. head.Pp/SaF:Pd. Symptoms.12 mg/m3 DOT: 2402 130 Synonyms/Trade Names: 3-Mercaptopropane. kidneys 1-Propanethiol 264 . resp sys. [Note: Releases a foul odor as it melts.P: -5°F 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) IP: 9. cyan. nose. Con SY: Irrit eyes. skin. Fl. Con Skin: Water flush immed SY: Irrit eyes.] C3H6O3S Conversion: DOT: Synonyms/Trade Names: 3-Hydroxy-1-propanesulphonic acid sultone. liver. resp sys. Propane-1-thiol. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Symptoms.Gr: 1.3-Propane sultone Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): See Appendix A None available OSHA PEL: none Physical Description: White.5 ppm: Sa:Cf/PaprOv Wash skin: N. leukemia.6 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Colorless liquid with an offensive. Abs.R.84 ScbaF/SaF §: ScbaF:Pd. alkali metals. reducing agents. strong acids & bases. Sp.Pp:AScba Provide: Eyewash VP(77°F): 155 mmHg Escape: GmFOv/ScbaE FRZ: -172°F UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: Oxidizers. nau. n-Propyl mercaptan Exposure Limits: Measurement Methods NIOSH REL: C 0.D.2 ¥: ScbaF:Pd. blood.

Symptoms.] Exposure Routes. Hydroacrylic acid. burns. Ing. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 56.P: 165°F Remove: When wet or contam IP: ? See Appendix E (page 351) Change: Daily Sp.1 Skin: Prevent skin contact BP: 237°F Not available.9% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Acetates. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 72. 3-Hydroxy-β-lactone. halogens. 3-Hydroxy-propionic acid. Symptoms. corn opac.29 mg/m3 DOT: 1986 131 Synonyms/Trade Names: 1-Propyn-3-ol. CNS. thiosulfates [Note: May polymerize upon storage. liver.R.15 Provide: Eyewash VP(77°F): 3 mmHg FRZ: -28°F Quick drench UEL: ? LEL: 2.D] Conversion: DOT: Synonyms/Trade Names: BPL.97 Provide: Eyewash VP: 12 mmHg FRZ: -62°F Quick drench UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Phosphorus pentoxide. CNS depres. kidneys Swallow: Medical attention immed Propargyl alcohol Formula: CAS#: RTECS#: IDLH: C3H4O2 57-57-8 RQ7350000 Ca [N. 2-Propyn-1-ol. oxidizers First Aid (see Table 6): Exposure Routes. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. β-lactone. resp sys. 3-Propiolactone Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca None available See Appendix A OSHA PEL: [1910.P(oc): 97°F Remove: When wet or contam IP: 10. skin & stomach] β-Propiolactone P 265 .CAS#: RTECS#: IDLH: Formula: 107-19-7 UK5075000 N. Abs. Abs. eyes [in animals: tumors of the liver. in animals: liver. thiocyanates. geranium odor. Skin: Soap wash immed Breath: Resp support dysuria. C3H3OH Conversion: 1 ppm = 2. [carc] Swallow: Medical attention immed TO: Kidneys.Pp/SaF:Pd. kidney damage Breath: Resp support TO: Skin. hema. Con Skin: Water flush prompt SY: Irrit skin. Sp. muc memb. Con Eye: Irr immed SY: Skin irrit.Gr: 0.51 eV Change: N.Pp:AScba Eyes: Prevent eye contact Sol: 37% Escape: GmFOv/ScbaE Wash skin: When contam/Daily Fl. β-Lactone. 2-Propynyl alcohol Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (2 mg/m3) [skin] (see Table 1): OSHA 97 OSHA PEL†: none Physical Description: Colorless to straw-colored liquid with a mild.D. 2-Oxetanone.1 NIOSH Skin: Prevent skin contact BP: 323°F (Decomposes) ¥: ScbaF:Pd. frequent urination. Ing. skin. blistering. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Gr: 1. Target Organs (see Table 5): Eye: Irr immed ER: Inh. lungs.1013] See Appendix B Physical Description: Colorless liquid with a slightly sweet odor.

1 Skin: Prevent skin contact BP: 286°F Not available.. IP: 11.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 74. Propiononitrile Exposure Limits: Measurement Methods NIOSH REL: TWA 6 ppm (14 mg/m3) (see Table 1): NIOSH 1606 (adapt) OSHA PEL: none Physical Description: Colorless liquid with a pleasant.] Exposure Routes. skin. skin Skin: Water flush immed Breath: Resp support burns.R.9% 300 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet or contam Fl.9% Class II Combustible Liquid Incompatibilities and Reactivities: Alkalis. CNS. CVS. rancid odor. Ing. Abs. Propanoic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (30 mg/m3) (see Table 1): 3 None available ST 15 ppm (45 mg/m ) OSHA PEL†: none Physical Description: Colorless. chromium trioxide) [Note: Corrosive to steel. strong acids & bases [Note: Hydrogen cyanide is produced when propionitrile is heated to decomposition. Skin: Water flush immed Breath: Resp support convuls. Ethylformic acid.Pp:AScba VP: 35 mmHg Escape: GmFOv/ScbaE FRZ: -133°F UEL: ? LEL: 3.1% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers & reducing agents.] Exposure Routes. corn burns. [Note: Forms cyanide in the body. Conversion: 1 ppm = 2. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. CH3CH2COOH Conversion: 1 ppm = 3. Propionic nitrile.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 55.84 eV ScbaF/SaF 1000 ppm: SaF:Pd. sweetish.D. Metacetonic acid. resp sys Propionic acid P Formula: CAS#: RTECS#: IDLH: CH3CH2CN 107-12-0 UF9625000 N. skin. chest pain.D. abdom pain. [Note: A solid below 5°F. skin. Ethyl cyanide. skin.Gr: 0. resp sys. kidney damage Swallow: Medical attention immed TO: Eyes. Propanenitrile. ethereal odor. Methyl acetic acid. lass.1 60 ppm: CcrOv/Sa Eyes: Prevent eye contact BP: 207°F 150 ppm: Sa:Cf/PaprOv Wash skin: When contam Sol: 11.24 eV Change: N.P: 126°F Remove: When wet or contam IP: 10. nau.99 Provide: Eyewash VP: 3 mmHg FRZ: 5°F Quick drench UEL: 12. strong oxidizers (e. Ethanecarboxylic acid.Pp/SaF:Pd. nau.25 mg/m3 DOT: 2404 131 Synonyms/Trade Names: Cyanoethane. nose. blurred vision. Abs.Gr: 0. Con Eye: Irr immed SY: Irrit eyes. oily liquid with a pungent. kidneys Propionitrile 266 .CAS#: RTECS#: IDLH: Formula: 79-09-4 UE5950000 N. Ing. vomit Swallow: Medical attention immed TO: Eyes. Sp. vomit.g. resp sys. throat.R. liver.78 §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.P: 36°F Change: N. disagreeable. stupor. Symptoms.03 mg/m3 DOT: 1848 132 Synonyms/Trade Names: Carboxyethane. Symptoms. in animals: liver. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.1% LEL: 2.Pp Provide: Quick drench Sp. Con Eye: Irr immed SY: Irrit eyes.

P: >300°F Remove: When wet or contam IP: ? Change: Daily Sp. fruity odor.Gr: ? VP: 0. derm Breath: Resp support TO: Eyes. resp sys. OSHA PV2007 [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 209. skin. salv.Pp/SaF:Pd.R. sweat. alkalis & acids Exposure Routes. Ing. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. characteristic odor.Pp:AScba Remove: When wet (flamm) Fl. Con Eye: Irr immed SY: Miosis. crystalline powder with a faint. musc twitch Swallow: Medical attention immed TO: CNS. head. lass.000007 mmHg MLT: 187-197°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. nau. Abs. liver. Con Skin: Water flush prompt SY: In animals: irrit eyes.2 1700 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 215°F Wash skin: When contam Sol: 2% PaprOv£/ScbaF/SaF §: ScbaF:Pd. IP: 10. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Symptoms. Ing. alkalis [Note: Emits highly toxic methyl isocyanate fumes when heated to decomposition. CNS Swallow: Medical attention immed n-Propyl acetate P 267 . strong oxidizers. throat. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 102. blurred vision. Skin: Soap wash immed Breath: Resp support diarr.Gr: 0.84 VP: 25 mmHg FRZ: -134°F UEL: 8% LEL(100°F): 1.2% Wash skin: Daily Fl. N-Methyl-2-isopropoxyphenyl-carbamate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Formula: CAS#: RTECS#: IDLH: CH3NHCOOC6H4OCH(CH3)2 114-26-1 FC3150000 N. Conversion: DOT: Synonyms/Trade Names: Aprocarb®. o-Isopropoxyphenyl-N-methylcarbamate. Symptoms. narco.D. nose. GI tract. kidneys. Eyes: Prevent eye contact Sol: 0. vomit.P: 55°F Escape: GmFOv/ScbaE Change: N.18 mg/m3 DOT: 1276 129 Synonyms/Trade Names: Propylacetate.3 Skin: Prevent skin contact BP: Decomposes Not available. blood chol Propoxur Formula: CAS#: RTECS#: IDLH: CH3COOCH2CH2CH3 109-60-4 AJ3675000 1700 ppm Conversion: 1 ppm = 4.04 eV Sp.] Exposure Routes.5 mg/m3 NIOSH 5601 OSHA PEL†: none Physical Description: White to tan. n-Propyl ester of acetic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (840 mg/m3) (see Table 1): 3 NIOSH 1450 ST 250 ppm (1050 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 200 ppm (840 mg/m ) Physical Description: Colorless liquid with a mild. abdom cramps.7% Class IB Flammable Liquid Incompatibilities and Reactivities: Nitrates.

Sp. CNS [in animals: liver & mammary Swallow: Medical attention immed gland tumors] Propylene dichloride 3 268 .87 eV Change: N. skin.2-propane.Pp:AScba Eyes: Prevent eye contact Sol: 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. nau. dizz. diarr. resp sys. strong acids. resp sys.R. Abs. Con SY: Irrit eyes. active metals First Aid (see Table 6): Exposure Routes.3% Escape: GmFOv/ScbaE Wash skin: When contam Fl.CAS#: RTECS#: IDLH: Formula: UH8225000 800 ppm CH3CH2CH2OH 71-23-8 Conversion: 1 ppm = 2. Ing.R.5% LEL: 3. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 60. ataxia. Symptoms. resp sys. 1.46 mg/m3 DOT: 1274 129 Synonyms/Trade Names: Ethyl carbinol.7% LEL: 2. IP: 10. nose. drow.2-Dichloropropane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1013 See Appendix A OSHA 7 OSHA PEL†: TWA 75 ppm (350 mg/m3) Physical Description: Colorless liquid with a chloroform-like odor. [pesticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 113. 1-Propanol.2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. in animals: Skin: Soap wash prompt Breath: Resp support CNS depres. n-Propanol. kidneys. dry cracking skin.1 800 ppm: CcrOv*/PaprOv*/GmFOv/ Eyes: Prevent eye contact BP: 207°F Wash skin: When contam Sol: Miscible Sa*/ScbaF §: ScbaF:Pd.4% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers.62 mg/m DOT: 1279 130 Synonyms/Trade Names: Dichloro-1. in animals: narco Swallow: Medical attention immed TO: Eyes.15 eV Sp. kidney damage. liver.16 Provide: Eyewash VP: 40 mmHg FRZ: -149°F Quick drench UEL: 14. vomit.Pp/SaF:Pd. Ing.81 VP: 15 mmHg FRZ: -196°F UEL: 13. Con SY: Irrit eyes.P: 60°F Remove: When wet (flamm) IP: 10. [carc] TO: Eyes. alcohol-like odor.0 NIOSH Skin: Prevent skin contact BP: 206°F ¥: ScbaF:Pd. skin. CNS n-Propyl alcohol P Formula: CAS#: RTECS#: IDLH: CH3CHClCH2Cl 78-87-5 TX9625000 Ca [400 ppm] Conversion: 1 ppm = 4. abdom cramps. 1405 ST 250 ppm (625 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 200 ppm (500 mg/m ) Physical Description: Colorless liquid with a mild. throat. liver.Pp:AScba Remove: When wet (flamm) Fl. skin. Symptoms. Skin: Water flush Breath: Resp support GI pain. Target Organs (see Table 5): Eye: Irr immed ER: Inh.Pp/SaF:Pd. head.Gr: 0.Gr: 1.P: 72°F Escape: GmFOv/ScbaE Change: N. drow. Abs. Propyl alcohol Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (500 mg/m3) [skin] (see Table 1): 3 NIOSH 1401. GI tract.

[Note: A solid below 18°F.6% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers. Eyes: Prevent eye contact Sol: 0. May slowly form reactive peroxides during prolonged storage. dizz. Con Skin: Water wash SY: Irrit eyes.D. ethereal odor. Propylene glycol methyl ether Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (360 mg/m3) (see Table 1): 3 NIOSH 2554 ST 150 ppm (540 mg/m ) OSHA 99 OSHA PEL†: none Physical Description: Clear.07 mmHg FRZ: 18°F UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Ammonia compounds. strong acids [Note: Hygroscopic (i. nau. Abs. Sp. vis dist.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 166. liver. 1-Methoxy-2-hydroxypropane. Conversion: 1 ppm = 3. throat. Fl. nose. colorless liquid with a mild. BP: 248°F Not available.23 VP(72°F): 0. head. kidney damage Swallow: Medical attention immed TO: Eyes.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Ing. reducing agents.D. 1. Sp..Gr: 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. oxidizers. Con SY: Irrit eyes.05 ppm (0. Breath: Resp support vomit.1 Skin: N. Symptoms. kidneys Propylene glycol dinitrate Formula: CAS#: RTECS#: IDLH: CH3OCH2CHCH3 107-98-2 UB7700000 N. skin. conj. CH3CNO2OHCHNO2OH Conversion: 1 ppm = 6. CNS. diarr Swallow: Medical attention immed TO: Eyes. Ing.): 1.R.Gr(77°F): 1. head.CAS#: RTECS#: IDLH: Formula: 6423-43-4 TY6300000 N. methemo. IP: ? Change: N.] Exposure Routes. amines.R.69 mg/m3 DOT: Synonyms/Trade Names: Dowtherm® 209. absorbs moisture from air).2-dinitrate. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 90. drow.2-Propylene glycol dinitrate Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Symptoms. in Skin: Soap wash Breath: Resp support animals: liver.P: ? Remove: N.79 mg/m3 DOT: Synonyms/Trade Names: PGDN.R.P: 97°F Remove: When wet (flamm) IP: ? Change: N.8% LEL(calc.] Exposure Routes. CNS Propylene glycol monomethyl ether P 269 . inco.1 Skin: Prevent skin contact BP: ? Not available.1% Wash skin: N. blood.R.96 VP(77°F): 12 mmHg FRZ: -139°F (Sets to glass) UEL(calc): 13. 2-Methoxy-1-methylethanol.R. 1-Methoxy-2-propanol. Eyes: Prevent eye contact Sol: Miscible Wash skin: N. impaired balance. skin. resp sys. Fl.3 mg/m3) [skin] (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with a disagreeable odor.e. combustible materials [Note: Similar to Ethylene glycol dinitrate in explosion potential. Propylene glycol-1.

CAS#: RTECS#: IDLH: Formula: 75-55-8 CM8050000 Ca [100 ppm] C3H7N Conversion: 1 ppm = 2. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 57.Pp:AScba Eyes: Prevent eye contact Sol: 41% Escape: GmFS/ScbaE Wash skin: When contam Fl. skin.P: -35°F Remove: When wet (flamm) IP: 9.1 (see Table 2): NIOSH BP: 152°F Skin: Prevent skin contact ¥: ScbaF:Pd. 1.00 eV Remove: When wet (flamm) Sp. VP: 112 mmHg Provide: Eyewash FRZ: -85°F Quick drench UEL: ? Incompatibilities and Reactivities: Acids. skin. Methyl ethylene oxide.2-Epoxy propane.83 Provide: Quick drench VP: 445 mmHg FRZ: -170°F UEL: 36% LEL: 2.Pp/SaF:Pd. [carc] Breath: Resp support TO: Eyes. aqueous acids. 2-Methylethyleneimine. strong oxidizers. Propyleneimine. resp sys [in animals: nasal tumors] Swallow: Medical attention immed Propylene oxide 270 .P: 25°F Wash skin: When contam IP: 9.3% Class IA Flammable Liquid Incompatibilities and Reactivities: Anhydrous metal chlorides.Gr: 0. Symptoms.80 Change: N.1 NIOSH Skin: Prevent skin contact BP: 94°F ¥: ScbaF:Pd. water. Propylene imine (inhibited). Symptoms.34 mg/m3 DOT: 1921 131P (inhibited) Synonyms/Trade Names: 2-Methylaziridine.Pp:AScba Sol: Miscible Eyes: Prevent eye contact Escape: GmFS/ScbaE Fl. resp sys. sulfonyl halides Class IB Flammable Liquid [Note: Subject to violent polymerization in contact with acids.R. [carc] Breath: Resp support TO: Eyes. Ing. skin blisters. caustics & peroxides [Note: Polymerization may occur due to high temperatures or contamination with alkalis. [Note: A gas above 94°F. Abs. Methyloxirane. Sp.] Exposure Routes. Con Skin: Water flush immed SY: Irrit eyes. Propene oxide. Hydrolyzes in water to form methylethanolamine.Gr: 0. oily liquid with an ammonia-like odor. burns.38 mg/m3 DOT: 1280 127P Synonyms/Trade Names: 1. skin burns.81 eV Change: N. Con Skin: Water flush immed SY: Eye. amines & acidic alcohols. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. strong acids.2-Propylene oxide Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1612 See Appendix A OSHA 88 OSHA PEL†: TWA 100 ppm (240 mg/m3) Physical Description: Colorless liquid with a benzene-like odor. Propylenimine Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 TWA 2 ppm (5 mg/m ) [skin] None available See Appendix A 3 OSHA PEL: TWA 2 ppm (5 mg/m ) [skin] Physical Description: Colorless.] Exposure Routes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 58. Ing. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. iron. skin [in animals: nasal tumors] Swallow: Medical attention immed Propylene imine P Formula: CAS#: RTECS#: IDLH: C3H6O 75-56-9 TZ2975000 Ca [400 ppm] Conversion: 1 ppm = 2. carbonyl LEL: ? compounds. quinones.R.Pp/SaF:Pd.

combustible materials [Note: Forms explosive mixtures with combustible materials.P: 180-190°F 250 mg/m3: CcrFOv100/PaprTOvHie*/ Change: Daily IP: ? ScbaF/SaF Sp. Con Skin: Soap wash immed SY: Erythema. Symptoms.Gr: 1. and Pyrethrin. skin. Ing.R.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 3 NIOSH 5008 OSHA PEL: TWA 5 mg/m OSHA 70 Physical Description: Brown. asthma Breath: Resp support TO: Resp sys. head Swallow: Medical attention immed TO: Eyes.30 mg/m3 DOT: 1865 131 Synonyms/Trade Names: Propyl ester of nitric acid Exposure Limits: Measurement Methods NIOSH REL: TWA 25 ppm (105 mg/m3) (see Table 1): 3 NIOSH S227 (II-3) ST 40 ppm (170 mg/m ) 3 OSHA 7 OSHA PEL†: TWA 25 ppm (110 mg/m ) Physical Description: Colorless to straw-colored liquid with an ether-like odor.Pp VP: Low §: ScbaF:Pd. pruritus. Pyrethrum I or II [Note: Pyrethrum is a variable mixture of Cinerin. derm. [insecticide] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 316-374 50 mg/m3: CcrOv95*/Sa* Eyes: Prevent eye contact BP: ? Wash skin: When contam Sol: Insoluble 125 mg/m3: Sa:Cf*/PaprOvHie* Remove: When wet or contam Fl. Jasmolin. Pyrethrin I or II.P: 68°F §: ScbaF:Pd. Symptoms. papules. rhin. Jasmolin I or II. Sp.Pp:AScba Remove: When wet (flamm) IP: 11.] Exposure Routes. blood n-Propyl nitrate Formula: CAS#: RTECS#: IDLH: C20H28O3/C21H28O5/C21H30O3/ 8003-34-7 UR4200000 5000 mg/m3 C22H30O5/C21H28O3/C22H28O5 Conversion: DOT: Synonyms/Trade Names: Cinerin I or II. anoxia. viscous oil or solid. dysp. sneez. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 105. methemo.Pp/SaF:Pd.Formula: CAS#: RTECS#: IDLH: CH3CH2CH2ONO2 627-13-4 UK0350000 500 ppm Conversion: 1 ppm = 4.07 VP: 18 mmHg FRZ: -148°F UEL: 100% LEL: 2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. dizz.Gr: 1 (approx) 5000 mg/m3: SaF:Pd. cyan. Breath: Resp support lass. CNS Swallow: Medical attention immed Pyrethrum P 271 .Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Con Skin: Soap wash prompt SY: In animals: irrit eyes. skin. skin.Pp:AScba MLT: ? Escape: GmFOv100/ScbaE UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Ing.1 NIOSH/OSHA Skin: Prevent skin contact BP: 231°F 250 ppm: Sa Eyes: Prevent eye contact Sol: Slight 500 ppm: Sa:Cf/ScbaF/SaF Wash skin: When contam Fl.07 eV Escape: GmFS¿/ScbaE Change: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.

Pp Change: Daily IP: 9. nau. conj. Azine Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (15 mg/m3) (see Table 1): 3 NIOSH 1613 OSHA PEL: TWA 5 ppm (15 mg/m ) OSHA 7 Physical Description: Colorless to yellow liquid with a nauseating.1 125 ppm: Sa:Cf£/PaprOv£ Eyes: Prevent eye contact BP: 240°F 50 ppm: CcrFOv/GmFOv/PaprTOv£/ Wash skin: When contam Sol: Miscible Remove: When wet (flamm) Fl. p-Benzoquinone.27 eV §: ScbaF:Pd.Pp/SaF:Pd. liver. IP: 9.Gr: 1.4% LEL: 1. Con Eye: Irr immed SY: Irrit eyes. Ing.1 mmHg Quick drench MLT: 240°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.Pp/SaF:Pd. skin irrit Breath: Resp support TO: Eyes.Pyridine Conversion: 1 ppm = 3. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 108.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 79. Formula: C5H5N DOT: 1282 129 CAS#: 110-86-1 RTECS#: UR8400000 IDLH: 1000 ppm Q Formula: CAS#: RTECS#: IDLH: OC6H4O 106-51-4 DK2625000 100 mg/m3 3 Conversion: 1 ppm = 4.8% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. fish-like odor. anor. dizz.P: 68°F ScbaF/SaF 1000 ppm: SaF:Pd.42 mg/m DOT: 2587 153 Synonyms/Trade Names: 1.1 10 mg/m3: Sa:Cf£ Eyes: Prevent eye contact BP: Sublimes Wash skin: When contam 20 mg/m3: ScbaF/SaF Sol: Slight Remove: When wet or contam Fl.1 ppm) (see Table 1): 3 OSHA PEL: TWA 0. insom. kera.4 mg/m3 (0.1 ppm) NIOSH S181 (II-4) Physical Description: Pale-yellow solid with an acrid.68 eV §: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp:AScba Provide: Eyewash Sp.98 Escape: GmFOv/ScbaE VP: 16 mmHg Quick drench FRZ: -44°F UEL: 12. CNS.Gr: 0.4 mg/m (0. chlorine-like odor. skin. p-Quinone Exposure Limits: Measurement Methods NIOSH REL: TWA 0. anxi. Skin: Water flush immed Breath: Resp support kidney damage Swallow: Medical attention immed TO: Eyes.Pp:AScba Provide: Eyewash Sp.4-Cyclohexadiene dioxide. GI tract. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.4-Benzoquinone. Ing. skin Swallow: Medical attention immed Quinone 272 . strong acids Exposure Routes.24 mg/m3 Synonyms/Trade Names: Azabenzene. derm. Abs. Symptoms. Con Skin: Soap wash immed SY: Eye irrit.Pp Change: N.32 Escape: GmFOv100/ScbaE VP(77°F): 0. head. liver.P: 100-200°F 100 mg/m3: SaF:Pd. kidneys. 1. Symptoms.

upper resp sys. BP: 6741°F 0. liver changes.P: NA 1 mg/m3: 95XQ/Sa Remove: N.Pp:AScba LEL: NA Escape: 100F/ScbaE Metal: Noncombustible Solid in bulk form. CVS. strong Class IIIB Combustible Liquid. menthol.Pp/SaF:Pd.R. CNS.4% antipyrine. Ing. [Note: Turns pink on exposure to air or light. Symptoms.1 mg/m NIOSH S188 (II-3) Physical Description: Metal: White. liver. or powder with a faint odor.0002 mmHg Provide: Eyewash MLT: 228°F UEL: ? Incompatibilities and Reactivities: Acetanilide. but flammable as dust or powder. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 102.e.D. spleen.27 Change: Daily VP(77°F): 0. IP: NA 2. Incompatibilities and Reactivities: Chlorine trifluoride. dizz. resp sys. cyan. but oxidizers & bases may be difficult to ignite. camphor. kidneys Resorcinol Rhodium (metal fume and insoluble compounds. alkalis.41 (metal) 5 mg/m3: 100F/SaT:Cf/PaprTHie/ VP: 0 mmHg (approx) ScbaF/SaF MLT: 3571°F 100 mg/m3: Sa:Pd. m-Hydroxyphenol Exposure Limits: Measurement NIOSH REL: TWA 10 ppm (45 mg/m3) Methods (see Table 1): 3 NIOSH 5701 ST 20 ppm (90 mg/m ) OSHA PEL†: none OSHA PV2053 Physical Description: White needles. hema. dysp. Symptoms.50 mg/m3 DOT: 2876 153 Synonyms/Trade Names: 1. hypothermia.Pp UEL: NA §: ScbaF:Pd. plates. Fl.3-Dihydroxybenzene. spirit nitrous ether.R. derm TO: Eyes.1 mg/m3 (see Table 1): 3 OSHA PEL: TWA 0. Swallow: Medical attention immed spleen. blood. Sol: 110% Eyes: Prevent eye contact Fl.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 110. kidney. Conversion: 1 ppm = 4. oxygen difluoride Exposure Routes.P: 261°F Wash skin: When contam IP: 8. 3-Hydroxyphenol. Sp. absorbs moisture from the air). Sol: Insoluble Wash skin: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. skin. albumin. malleable solid with a bluish-gray luster. incr heart rate. drow. as Rh) Formula: Rh (metal) CAS#: 7440-16-6 (metal) RTECS#: IDLH: VI9069000 100 mg/m3 (as Rh) Conversion: DOT: Synonyms/Trade Names: Rhodium metal: Elemental rhodium Synonyms of other insoluble rhodium compounds vary depending upon the specific compound. Skin: Water wash immed Breath: Resp support restless. hard.63 eV Remove: When wet or contam Sp. [Note: Hygroscopic (i. crystals.R. m-Benzenediol.. Con Eye: Irr immed SY: Irrit eyes. methemo. or contact with iron. ductile. convuls. nose. Exposure Limits: Measurement Methods NIOSH REL: TWA 0. LEL(392°F): 1.1 (see Table 2): BP: 531°F Skin: Prevent skin contact Not available. ferric salts. m-Dihydroxybenzene. flakes.3-Benzenediol. throat.9 NIOSH/OSHA Skin: N.R. bluish skin. 1. Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh Swallow: Medical attention immed SY: Possible resp sens TO: Resp sys R 273 .5 mg/m3: Sa:Cf/PaprHie Change: N.] Exposure Routes.Gr: 1.R. skin.5 mg/m3: Qm Eyes: N.Gr: 12.Formula: CAS#: RTECS#: IDLH: C6H4(OH)2 108-46-3 VG9625000 N.

O-Dimethyl O-(2. 2 mg/m3: SaF:Pd.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes. Con Skin: Water flush SY: In animals: irrit eyes.05 mg/m3: 100F/PaprTHie*/ScbaF/SaF Change: N. CNS damage Breath: Resp support TO: Eyes.0008 mmHg Escape: GmFOv100/ScbaE MLT: 106°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.Rhodium (soluble compounds. kidney damage Breath: Resp support TO: Eyes. chol inhibition. blood plasma Swallow: Medical attention immed Ronnel 274 . Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.4.004% 250 mg/m3: Sa:Cf/PaprOvHie Remove: When wet or contam Fl.001 mg/m Physical Description: Appearance and odor vary depending upon the specific soluble rhodium compound.Pp:AScba VP(77°F): 0. Symptoms. liver. liver.5-trichlorophenyl) phosphorothioate. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact Properties vary depending 0. CNS Swallow: Medical attention immed R Formula: CAS#: RTECS#: IDLH: (CH3O)2P(S)OC6H2Cl3 299-84-3 TG0525000 300 mg/m3 Conversion: DOT: Synonyms/Trade Names: O.Pp §: ScbaF:Pd. Con Skin: Soap wash prompt SY: In animals: irrit eyes.01 mg/m3: 100XQ*/Sa* Eyes: Prevent eye contact upon the specific soluble Wash skin: When contam 0.P: NA 300 mg/m3: CcrFOv100/GmFOv100/ Change: Daily IP: ? PaprTOvHie*/ScbaF/SaF Sp. Remove: When wet or contam 0.001 mg/m3 (see Table 1): 3 NIOSH S189 (II-3) OSHA PEL: TWA 0.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 321. crystalline solid. Exposure Limits: Measurement Methods NIOSH REL: TWA 0. as Rh) Formula: CAS#: RTECS#: IDLH: 2 mg/m3 (as Rh) Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific soluble rhodium compound.Pp/SaF:Pd.Gr(77°F): 1.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp/SaF:Pd.6 100 mg/m3: CcrOv95/Sa Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol(77°F): 0. Ing. Fenchlorophos Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (see Table 1): NIOSH 5600 OSHA PEL†: TWA 15 mg/m3 OSHA PV2054 Physical Description: White to light-tan.025 mg/m3: Sa:Cf*/PaprHie* rhodium compound. Ing. Symptoms.49 §: ScbaF:Pd. kidneys. [insecticide] [Note: A liquid above 106°F.

R. nau. CO & CO2. Acetaldehyde.12a-Tetrahydro-8. skin.4-b]furo[2.R. odorless.00004 mmHg 2500 mg/m3: Sa:Pd. [insecticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 394.9-dimethoxy-2-(1-methylethenyl)-[1]benzopyrano[3.R. crystalline solid.D. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: Not available. In the presence of Formaldeyde. throat. Acetaldehyde. CNS Formula: C23H22O6 DOT: CAS#: 83-79-4 RTECS#: DJ2800000 IDLH: 2500 mg/m3 R 275 .Pp/SaF:Pd. aliphatic aldehydes. acetaldehyde. solder being used. Symptoms. Breath: Resp support abdom pain. or malonaldehyde. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. inco. or Malonaldehyde)] TO: Eyes. Properties vary depending Skin: N. upper resp sys [carc (in the presence of Breath: Resp support Formaldehyde. numb muc memb.27 ScbaF/SaF VP: <0. upon the specific rosin core Eyes: N.P: ? 250 mg/m3: CcrFOv100/GmFOv100/ Change: Daily IP: ? PaprTOvHie/SaT:Cf/ Sp.1 mg/m3 NIOSH 2541.] OSHA PEL†: none Physical Description: Pyrolysis products of rosin core solder include acetone. Rosin core soldering flux pyrolysis products Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: TWA 0. nose. Wash skin: N.12. various abietic acids (the major components of rosin). resp sys.2. skin.Pp:AScba UEL: ? Escape: GmFOv100/ScbaE LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers. Remove: N. alkalis Exposure Routes. ethane.4 5 mg/m3: CcrOv95/Sa Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: Insoluble 125 mg/m3: Sa:Cf/PaprOvHie Remove: When wet or contam Fl. vomit. Ing.Rosin core solder. stupor Swallow: Medical attention immed TO: Eyes. pyrolysis products (as formaldehyde) Formula: CAS#: RTECS#: IDLH: N. Con Skin: Soap wash prompt SY: Irrit eyes. 3500 [*Note: ”Ca” in the presence of formaldehyde.Gr: 1.Pp:AScba Escape: GmFOv100/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes. clonic convuls.R. thyroid gland tumors in animals (in the presence of Formaldehyde. musc tremor.Pp/SaF:Pd. NIOSH ¥: ScbaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh Eye: Irr immed SY: Irrit eyes. or Malonaldehyde: Change: N.Pp MLT: 330°F §: ScbaF:Pd. Acetaldehyde. resp sys.R. or Malonaldehyde)] Rotenone Conversion: Synonyms/Trade Names: 1.3-h][1]benzopyran-6(6aH)-one Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 NIOSH 5007 OSHA PEL: TWA 5 mg/m Physical Description: Colorless to red. methyl alcohol. methane. resp sys [nasal cancer. Conversion: DOT: Synonyms/Trade Names: Rosin flux pyrolysis products. See Appendices A & C (Aldehydes).

P: NA §: ScbaF:Pd. Symptoms.R. resp sys. fever. resp sys Rouge S Formula: CAS#: RTECS#: IDLH: Se 7782-49-2 VS7700000 1 mg/m3 (as Se) Conversion: DOT: 2658 152 (powder) Synonyms/Trade Names: Elemental selenium.24 VP: 0 mmHg (approx) MLT: 2849°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Calcium hypochlorite.Gr: 5. BP: ? Not available.R. Eyes: N. spleen Selenium 276 . OSHA PEL*: TWA 0.R.Pp:AScba Change: N. potassium bromate. chromium trioxide. blood. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Red iron oxide. Con SY: Irrit eyes. garlic breath. skin. Sp. Con Breath: Fresh air SY: Irrit eyes.P: NA Remove: N. strong oxidizers.R.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 79. vis dist. Selenium alloy Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: TWA 0. skin. 0600 3 TWA 5 mg/m (resp) Physical Description: A fine. nose. kidneys. IP: NA Escape: 100F/ScbaE Provide: Quick drench Sp. Skin: Soap wash immed metallic taste.7 Skin: N. Target Organs (see Table 5): Eye: Irr immed ER: Inh. in animals: Breath: Resp support Swallow: Medical attention immed anemia.D. red to gray solid. throat.R. liver.R. resp sys TO: Eyes.Formula: CAS#: RTECS#: IDLH: Fe2O3 1309-37-1 NO7400000 N.2 mg/m3 3 NIOSH 7300. spleen damage TO: Eyes. cirr.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 159. Symptoms. [Note: Occurs as an impurity in most sulfide ores.] Physical Description: Amorphous or crystalline.Pp/SaF:Pd. GI dist.2 mg/m [*Note: The REL and PEL also apply to other selenium 9102. Ing. chills. Iron oxide red. cadmium First Aid (see Table 6): Exposure Routes. Red oxide Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 15 mg/m (total) NIOSH 0500. S190 (II-7) OSHA ID121 compounds (as Se) except Selenium hexafluoride. liver nec. IP: NA Change: N. skin burns.28 VP: 0 mmHg (approx) MLT: 392°F UEL: NA LEL: NA Combustible Solid Incompatibilities and Reactivities: Acids. eye. kidney. Sol: Insoluble Wash skin: N. derm.0 1 mg/m3: Qm*/95XQ*/100F/PaprHie*/ Eyes: N. [Note: Usually used in cake form or impregnated in paper or cloth. dysp. Conversion: DOT: Synonyms/Trade Names: Iron(III)oxide. head. hydrogen peroxide First Aid (see Table 6): Exposure Routes. 7301. bron. red powder of ferric oxide.R. skin.Gr: 4. Fl. BP: 1265°F Wash skin: When contam Sol: Insoluble PaprHie*/Sa*/ScbaF Remove: When wet or contam Fl. 7303. carbon monoxide. skin.

05 ppm (0. Target Organs (see Table 5): Eye: Irr immed ER: Inh.Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Fluorine. 60 mg/m3: 95XQ/Sa Sol: Insoluble Remove: N.R.89 mg/m3 Synonyms/Trade Names: Selenium fluoride Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Symptoms.R. BP: 4046°F Wash skin: N.5 ppm: Sa Eyes: N. amorphous S 277 . resp sys Silica. Fl. oxygen difluoride.R.Pp MLT: 3110°F §: ScbaF:Pd. [Note: Amorphous silica is the non-crystalline form of SiO2.R.R.Selenium hexafluoride Conversion: 1 ppm = 7. Fl.R.05 ppm (see Table 1): 3 OSHA PEL: TWA 0.P: NA §: ScbaF:Pd.Gr: 2.R. edema TO: Resp sys Formula: SeF6 DOT: 2194 125 CAS#: 7783-79-1 RTECS#: VS9450000 IDLH: 2 ppm Formula: CAS#: RTECS#: IDLH: SiO2 7631-86-9 VV7310000 3000 mg/m3 Conversion: DOT: Synonyms/Trade Names: Diatomaceous earth.R. Target Organs (see Table 5): Breath: Resp support ER: Inh SY: In animals: pulm irrit. MW: 60.66 VP: >1 atm FRZ: -59°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Water [Note: Hydrolyzes very slowly in cold water. odorless powder. Diatomite.R.0 0.Pp/SaF:Pd. Sol: Insoluble 2 ppm: SaT:Cf/ScbaF/SaF Remove: N.4 mg/m ) None available Physical Description: Colorless gas.] First Aid (see Table 6): Exposure Routes.25 ppm: Sa:Cf Wash skin: N.R. BP: -30°F 1. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N. MW: 193.P: NA 150 mg/m3: Sa:Cf/PaprHie Change: N. pneumoconiosis TO: Eyes. IP: NA 300 mg/m3: 100F/SaT:Cf/PaprTHie/ Sp.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: N.20 ScbaF/SaF VP: 0 mmHg (approx) 3000 mg/m3: Sa:Pd. Silicon dioxide (amorphous) Exposure Limits: Measurement Methods NIOSH REL: TWA 6 mg/m3 (see Table 1): 3 OSHA PEL†: TWA 20 mppcf [(80 mg/m )/%SiO2] NIOSH 7501 Physical Description: Transparent to gray.Pp:AScba Change: N. Diatomaceous silica. Silica gel.Pp/SaF:Pd. IP: ? Escape: GmFS/ScbaE RGasD: 6. Precipitated amorphous silica. chlorine trifluoride First Aid (see Table 6): Exposure Routes.1 30 mg/m3: Qm Eyes: N. Con Breath: Fresh air SY: Irrit eyes. Symptoms.

] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 28. Sp. skin.Silica.66 Change: N.5 mg/m3: 95XQ Sol: Insoluble Eyes: N. Symptoms.Pp/SaF:Pd. decr pulm func. [Note: The amorphous form is a dark-brown powder. Con Breath: Fresh air SY: Irrit eyes.R. skin. Noncombustible Solid acetylene. Eyes: Prevent eye contact Sol: Insoluble Wash skin: N. Fl.1 (see Table 2): NIOSH BP: 4046°F Skin: N. IP: NA Change: N. etc. 0. 1.33 VP: 0 mmHg (approx) MLT: 2570°F UEL: NA LEL: NA MEC: 160 g/m3 Combustible Solid in powder form.D. [Note: A component of many mineral dusts.R. needle-like crystals. oxygen difluoride. 7602 TWA 0.R. tridymite).Pp VP: 0 mmHg (approx) §: ScbaF:Pd. Symptoms.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500. Con Breath: Fresh air SY: Cough.1 Skin: N. [carc] TO: Eyes. manganese trioxide.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 278 . but is found in silicon dioxide (silica) & in various silicates. Fl. 50 mg/m3 (quartz. wheez. resp sys [in animals: lung cancer] Silicon S Conversion: Synonyms/Trade Names: Elemental silicon [Note: Does not occur free in nature. tripoli)] Conversion: DOT: Synonyms/Trade Names: Cristobalite. oxidizers. Tripoli Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 7500. 25 mg/m3: Sa:Pd. dysp.Pp:AScba MLT: 3110°F Escape: 100F/ScbaE UEL: NA Incompatibilities and Reactivities: Powerful oxidizers: fluorine. Ing. Tridymite. fluorine.R. alkaline carbonates Exposure Routes.Gr: 2. lustrous. BP: 4271°F Not available.R. irrit eyes.P: NA Wash skin: N. cesium carbide. ammonia Exposure Routes.R. Incompatibilities and Reactivities: Chlorine.5 mg/m3: 100F/PaprTHie Sp. hydrogen peroxide.. 2. crystalline (as respirable dust) Formula: SiO2 CAS#: 14808-60-7 RTECS#: VV7330000 IDLH: Ca [25 mg/m3 (cristobalite.R. 0600 TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) TWA 5 mg/m3 (resp) Physical Description: Black to gray. Quartz. odorless solid. calcium.25 mg/m3: PaprHie/Sa:Cf IP: NA Remove: N. chlorine LEL: NA trifluoride. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 60.P: NA Remove: N. 7601.05 mg/m OSHA ID142 See Appendix A OSHA PEL: See Appendix C (Mineral Dusts) Physical Description: Colorless. resp sys Formula: CAS#: RTECS#: Si 7440-21-3 VW0400000 DOT: 1346 170 (amorphous powder) IDLH: N. progressive resp symptoms (silicosis).Gr(77°F): 2.R. upper resp sys. cough Swallow: Medical attention immed TO: Eyes.

R.11 VP: >1 atm FRZ: -301°F UEL: ? LEL: ? Flammable Gas (may ignite SPONTANEOUSLY in air).R. skin. head TO: Eyes.Gr: 3. Eyes: N. resp sys. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh SY: Irrit eyes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 40. resp sys Silicon carbide Formula: CAS#: RTECS#: IDLH: SiH4 7803-62-5 VV1400000 N.D. RGasD: 1. BP: -169°F Not available.30 eV Change: N. Fl. tin(IV) chloride).R. 0600 TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Yellow to green to bluish-black.P: NA Remove: N.R. Silicane Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (7 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless gas with a repulsive odor. Incompatibilities and Reactivities: Halogens (bromine. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 32. IP: ? Change: N. muc memb. Fl.] Exposure Routes. Conversion: DOT: Synonyms/Trade Names: Carbon silicide. cough Swallow: Medical attention immed TO: Eyes. Silicon monocarbide Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. Sol: Decomposes Wash skin: N. Con Breath: Fresh air SY: Irrit eyes. IP: 9. Silane.31 mg/m3 DOT: 2203 116 Synonyms/Trade Names: Monosilane.R. upper resp sys. BP: Sublimes Not available. skin. chlorine.R. skin. CNS Silicon tetrahydride S 279 .R. Sp.P: NA (Gas) Remove: N. Sol: Insoluble Wash skin: N. Ing.R. water Exposure Routes. nau. iridescent crystals.1 Skin: N.D.Formula: CAS#: RTECS#: IDLH: SiC 409-21-2 VW0450000 N.23 VP: 0 mmHg (approx) MLT: 4892°F (Sublimes) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported [Note: Sublimes with decomposition at 4892°F. Conversion: 1 ppm = 1. antimony pentachloride. Eyes: N. skin.1 Skin: N. Symptoms. Carborundum®. carbonyl chloride.

ulceration skin. Target Organs (see Table 5): ER: Inh. as Ag) Formula: Ag (metal) CAS#: 7440-22-4 (metal) RTECS#: VW3500000 (metal) IDLH: 10 mg/m3 (as Ag) Conversion: DOT: Synonyms/Trade Names: Silver metal: Argentum Synonyms of soluble silver compounds such as Silver nitrate (AgNO3) vary depending upon the specific compound. 7301.9 BP: 3632°F Sol: Insoluble Fl. tartaric acid Exposure Routes.Pp/SaF:Pd. BP: ? Wash skin: N. 9102 OSHA ID121 Physical Description: Metal: White. oxalic acid. Fl. throat.3 Eyes: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms.R. Chemical & Physical Properties: MW: 107. Personal Protection/Sanitation (see Table 2): Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contam Remove: When wet or contam (AgNO3) Change: Daily Provide: Eyewash Respirator Recommendations (see Tables 3 and 4): NIOSH/OSHA 0. Con Eye: Irr immed SY: Blue-gray eyes. Symptoms. eyes Soapstone (containing less than 1% quartz) Formula: 3MgO-4SiO2-H2O CAS#: RTECS#: VV8780000 IDLH: 3000 mg/m3 S Conversion: DOT: Synonyms/Trade Names: Massive talc.01 mg/m NIOSH 7300. CVS Measurement Methods (see Table 1): NIOSH 0500 Respirator Recommendations (see Tables 3 and 4): NIOSH 30 mg/m3: Qm 60 mg/m3: 95XQ/Sa 150 mg/m3: PaprHie 300 mg/m3: 100F/SaT:Cf*/PaprTHie*/ ScbaF/SaF 3000 mg/m3: SaF:Pd. MW: 379. skin. Personal Protection/Sanitation Chemical & Physical (see Table 2): Properties: Skin: N. Sol: Insoluble Remove: N. dysp.Gr: 10. lustrous solid. white-gray powder.01 mg/m3 (see Table 1): 3 OSHA PEL: TWA 0.Pp:AScba Escape: 100F/ScbaE First Aid (see Table 6): Eye: Irr immed Breath: Resp support 280 .Pp §: ScbaF:Pd.8 VP: 0 mmHg (approx) MLT: ? UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. nasal septum. IP: NA Sp. ethyleneimine.Silver (metal dust and soluble compounds.P: NA IP: NA Sp.5 mg/m3: 100F/ScbaF/SaF 10 mg/m3: SaF:Pd. Con SY: Pneumoconiosis: cough. but flammable in form of dust or powder.R. skin.7-2. Skin: Water flush Breath: Resp support GI dist Swallow: Medical attention immed TO: Nasal septum.Pp §: ScbaF:Pd. bromoazide.Pp/SaF:Pd. digital clubbing.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Acetylene.49 (metal) VP: 0 mmHg (approx) MLT: 1761°F UEL: NA LEL: NA Metal: Noncombustible Solid.R.R. cor pulmonale TO: Resp sys.Gr: 2. ammonia. chlorine trifluoride. hydrogen peroxide. Exposure Limits: Measurement Methods NIOSH REL: TWA 0.R. cyan. Ing. Soapstone silicate.P: NA Change: N. Steatite Exposure Limits: NIOSH REL: TWA 6 mg/m3 (total) TWA 3 mg/m3 (resp) OSHA PEL†: TWA 20 mppcf Physical Description: Odorless.25 mg/m3: Sa:Cf£/PaprHie£ 0. basal crackles. irrit.

kidney changes Swallow: Medical attention immed TO: Eyes. Symptoms. Cryolite.90 250 mg/m3: SaF:Pd. stiff spine. skin.Pp/SaF:Pd.70 eV Change: Daily Sp.5 mg/m3 (see Table 1): 3 NIOSH 7902 OSHA PEL*: TWA 2. CNS.P: ? Remove: When wet or contam IP: 11. [pesticide] [Note: Forms hydrazoic acid (HN3) in water. lass. CVS. Incompatibilities and Reactivities: Acids. Abs. [pesticide] [Note: Loses color on heating. crystalline solid. abdom pain. or solder in plumbing systems to form an accumulation of the HIGHLY EXPLOSIVE compounds of lead azide & copper azide. skin.85 Provide: Eyewash VP: ? MLT: 527°F (Decomposes) Quick drench UEL: ? LEL: ? Combustible Solid (if heated above 572°F). Ing. skeleton. calcification of ligaments of ribs. Symptoms. Sodium salt of hydrazoic acid Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0.5 mg/m3: Qm Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: 0. resp sys.] Physical Description: Colorless to dark odorless solid. head. solid fluorides (as F). Ing. blurred vision. nau. Azium.Gr: 2. water [Note: Over a period of time. Skin: Soap wash prompt Breath: Fresh air sweat. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. ID211 C 0.5 mg/m OSHA ID110 [*Note: The REL and PEL also apply to other inorganic. derm. kidneys Sodium azide S 281 . Conversion: DOT: 1687 153 Synonyms/Trade Names: Azide. Con Eye: Irr immed SY: Irrit eyes. skin.1 ppm (as HN3) [skin] 3 OSHA ID121. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. diarr.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 209.04% 25 mg/m3: 95XQ*/Sa* Remove: When wet or contam Fl. sodium azide may react with copper. resp sys.P: NA 62. CNS.D. Sodium hexafluoroaluminate Exposure Limits: Measurement Methods NIOSH REL*: TWA 2.Pp VP: 0 mmHg (approx) §: ScbaF:Pd. pelvis Swallow: Medical attention immed TO: Eyes. salv.Pp:AScba MLT: 1832°F Escape: 100F+/ScbaE UEL: NA LEL: NA +Note: May need acid gas sorbent Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Con Skin: Water flush immed SY: Irrit eyes. Breath: Resp support bradycardia. metals. low BP. thirst. lead. kidneys Sodium aluminum fluoride (as F) Formula: CAS#: RTECS#: IDLH: NaN3 26628-22-8 VY8050000 N.Formula: CAS#: RTECS#: IDLH: Na3AlF6 15096-52-3 WA9625000 250 mg/m3 (as F) Conversion: DOT: Synonyms/Trade Names: Cryocide.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 65. Cryodust.3 mg/m (as NaN3) [skin] OSHA PEL†: none Physical Description: Colorless to white.0 Skin: Prevent skin contact BP: Decomposes Not available.] Exposure Routes. odorless. dizz.5 mg/m3: Sa:Cf*/PaprHie*+ Change: Daily IP: NA 125 mg/m3: 100F+/ScbaF/SaF Sp. brass.Gr: 1.9 12. Eyes: Prevent eye contact Sol(63°F): 42% Wash skin: When contam Fl.

R.Pp/SaF:Pd.R. skin. Fl. Sp. Conversion: DOT: 2693 154 (solution) Synonyms/Trade Names: Monosodium salt of sulfurous acid.0 NIOSH/OSHA Skin: Prevent skin contact BP: 2725°F 25 mg/m3: Sa/ScbaF Eyes: Prevent eye contact Sol(77°F): 58% Wash skin: When contam §: ScbaF:Pd. 7904 OSHA PEL*: TWA 5 mg/m [*Note: The REL and PEL also apply to other cyanides (as CN) except Hydrogen cyanide. head. Ing.48 VP: ? MLT: Decomposes UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Heat (decomposes) [Note: Slowly oxidized to the sulfate on exposure to air. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R.Gr: 1. slow gasping respiration. CVS. Ing. Symptoms. Incompatibilities and Reactivities: Strong oxidizers (such as acids. Sol: 29% Wash skin: N.D. incr resp Skin: Soap wash immed Breath: Resp support rate.P: NA Remove: When wet or contam Escape: GmFS100/ScbaE IP: NA Change: Daily Sp.] Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 49. Sodium bisulphite. Sodium acid bisulfite.R.P: NA Remove: N. skin. thyroid. granular or crystalline solid with a faint. but contact with acids releases highly flammable hydrogen cyanide. Con SY: Irrit eyes. Abs.7 ppm) [10-minute] 3 NIOSH 6010. blood changes Swallow: Medical attention immed TO: Eyes. Symptoms. Con Breath: Fresh air SY: Irrit eyes. almond-like odor. vomit. thyroid. asphy.60 Provide: Eyewash VP: 0 mmHg (approx) MLT: 1047°F Quick drench UEL: NA LEL: NA Noncombustible Solid. skin. 3414 157 (solution) Synonyms/Trade Names: Sodium salt of hydrocyanic acid Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: C 5 mg/m3 (4. BP: Decomposes Not available.1 Skin: N. conf. IP: NA Change: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 104.] Physical Description: White.Gr: 1. lass. CNS. muc memb Swallow: Medical attention immed TO: Eyes. skin. nau.] Exposure Routes. acid salts.R. Sodium hydrogen sulfite Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 NIOSH 0500 OSHA PEL†: none Physical Description: White crystals or powder with a slight odor of sulfur dioxide. Eyes: N.Pp:AScba Fl. chlorates & nitrates) [Note: Absorbs moisture from the air forming a syrup. resp sys Sodium bisulfite S Formula: CAS#: RTECS#: IDLH: NaCN 143-33-9 VZ7525000 25 mg/m3 (as CN) Conversion: DOT: 1689 157 (solid). blood Sodium cyanide (as CN) 282 .Formula: CAS#: RTECS#: IDLH: NaHSO3 7631-90-5 VZ2000000 N.

derm. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. abdom pain. [Note: Pesticide grade is often dyed blue. kidneys Sodium fluoride (as F) CAS#: RTECS#: IDLH: Formula: 62-74-8 AH9100000 2.5 mg/m3 FCH2COONa Conversion: DOT: 2629 151 Synonyms/Trade Names: SFA.15 mg/m [skin] 3 OSHA PEL†: TWA 0. nystagmus.P: NA 0.5 mg/m3: Sa:Cf*/PaprHie*+ Change: Daily Sp. stiff spine.5 mg/m3 (see Table 1): 3 NIOSH 7902. CVS. thirst. calcification of ligaments of ribs. pulm edema. ectopic heartbeat. kidneys.05 mg/m3 (see Table 1): 3 NIOSH S301 (II-5) ST 0. liver. solid fluorides (as F).] Physical Description: Odorless. [Note: A liquid above 95°F.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 42.0 NIOSH/OSHA Skin: Prevent skin contact BP: 3099°F 12. Symptoms. Swallow: Medical attention immed convuls. Ing. odorless powder. Target Organs (see Table 5): Eye: Irr immed ER: Inh.25 mg/m3: Sa:Cf/PaprHie Change: Daily Sp. facial pares.5 mg/m3: 100F/SaT:Cf/PaprTHie/ Provide: Quick drench VP: Low ScbaF/SaF MLT: 392°F §: ScbaF:Pd. anxi. diarr.05 mg/m [skin] Physical Description: Fluffy.Pp:AScba UEL: NA Escape: 100F/ScbaE LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes.] [rodenticide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 100.Gr: ? 2. CNS. Con Skin: Soap wash prompt SY: Irrit eyes. Breath: Fresh air sweat. 7906 OSHA PEL*: TWA 2. Ing.25 mg/m3: Qm Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. white powder or colorless crystals. tacar. pelvis Swallow: Medical attention immed TO: Eyes. Symptoms. skeleton.P: NA 25 mg/m3: 95XQ*/Sa* Remove: When wet or contam IP: NA 62.5 mg/m3: 95XQ/Sa Remove: When wet or contam IP: ? 1.5 mg/m3: Qm Eyes: Prevent eye contact Sol: 4% Wash skin: When contam Fl.Pp/SaF:Pd. auditory halu.Formula: CAS#: RTECS#: IDLH: NaF 7681-49-4 WB0350000 250 mg/m3 (as F) Conversion: DOT: 1690 154 Synonyms/Trade Names: Floridine. pulsus Breath: Resp support altenans. resp sys. twitch face musc.0 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 0. card arrhy.78 125 mg/m3: 100F+/ScbaF/SaF VP: 0 mmHg (approx) 250 mg/m3: SaF:Pd. liver. Sodium monofluoride Exposure Limits: Measurement Methods NIOSH REL*: TWA 2.5 mg/m OSHA ID110 [*Note: The REL and PEL also apply to other inorganic.Pp/SaF:Pd. CNS Sodium fluoroacetate S 283 . salv.Pp:AScba UEL: NA Escape: 100F+/ScbaE LEL: NA +Note: May need acid gas sorbent Noncombustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. colorless to white (sometimes dyed black).Pp MLT: 1819°F §: ScbaF:Pd. nau. kidney damage TO: Resp sys. Abs.Gr: 2. skin. Con Skin: Water flush immed SY: Vomit. Sodium monofluoroacetate Exposure Limits: Measurement Methods NIOSH REL: TWA 0. resp sys.

eye.0 NIOSH/OSHA Skin: Prevent skin contact BP: 2534°F 10 mg/m3: Sa:Cf£/100F/PaprHie£/ Eyes: Prevent eye contact Sol: 111% Wash skin: When contam Fl. BP: Decomposes Not available. skin. Sp.1 Skin: N. Symptoms. resp sys Sodium metabisulfite 284 . Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 190. Sodium metabisulphite. skin burns. odorless solid (flakes. temporary Skin: Water flush immed Breath: Resp support loss of hair Swallow: Medical attention immed TO: Eyes. organic halogens.D.Formula: CAS#: RTECS#: IDLH: NaOH 1310-73-2 WB4900000 10 mg/m3 Conversion: DOT: 1823 154 (dry.4 VP: ? MLT: >302°F (Decomposes) UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Heat (decomposes) [Note: Slowly oxidized to the sulfate on exposure to air & moisture. Con Eye: Irr immed SY: Irrit eyes.R.Gr: 2. Con Breath: Fresh air SY: Irrit eyes. solid).R. Ing. Incompatibilities and Reactivities: Water. 1824 154 (solution) Synonyms/Trade Names: Caustic soda. acids.R.R. granular form). Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. pneu. Sodium hydrate Exposure Limits: Measurement Methods NIOSH REL: C 2 mg/m3 (see Table 1): 3 NIOSH 7401 OSHA PEL†: TWA 2 mg/m Physical Description: Colorless to white. Lye. but when in contact with water may generate sufficient heat to ignite combustible materials.Pp/SaF:Pd.Pp:AScba Change: Daily Sp. Conversion: DOT: Synonyms/Trade Names: Disodium pyrosulfite. skin. Sodium pyrosulfite Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 NIOSH 0500 OSHA PEL†: none Physical Description: White to yellowish crystals or powder with an odor of sulfur dioxide.] Exposure Routes. flammable liquids. muc memb.P: NA ScbaF/SaF Remove: When wet or contam IP: NA §: ScbaF:Pd. Soda lye. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.13 Escape: 100F/ScbaE Provide: Eyewash VP: 0 mmHg (approx) MLT: 605°F Quick drench UEL: NA LEL: NA Noncombustible Solid. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 40.P: NA Remove: N. skin. muc memb Swallow: Medical attention immed TO: Eyes.] Exposure Routes. tin & zinc. Sol: 54% Wash skin: N.R. beads. skin. IP: NA Change: N.Gr: 1. Ing. resp sys Sodium hydroxide S Formula: CAS#: RTECS#: IDLH: Na2S2O5 7681-57-4 UX8225000 N. Symptoms. nitromethane [Note: Corrosive to metals. metals such as aluminum. Fl. Eyes: N.

liver.51 eV §: ScbaF:Pd.P: NA Remove: When wet or contam IP: NA Change: Daily Sp. lumbar pain.31 Escape: GmFS/ScbaE VP: >1 atm FRZ: -126°F UEL: ? LEL: ? Flammable Gas Incompatibilities and Reactivities: Acids. [Note: A carbohydrate polymer composed of 25% amylose & 75% amylpectin. ozone.5 mg/m ) Physical Description: Colorless gas with a disagreeable odor like hydrogen sulfide. cough.8 NIOSH/OSHA Skin: N.5 ppm: Sa:Cf Wash skin: N. Ing. iodine. muc memb.Starch Conversion: Formula: (C6H10O5)n DOT: CAS#: 9005-25-8 RTECS#: GM5090000 IDLH: N. Sorghum gum. Fl.45 VP: 0 mmHg (approx) MLT: Decomposes UEL: NA LEL: NA MEC: 50 g/m3 Noncombustible Solid. α-Starch. moisture. hema. IP: 9.R.P: NA (Gas) 5 ppm: SaT:Cf/ScbaF/SaF Remove: N. Con Skin: Soap wash SY: Irrit eyes. ammonia First Aid (see Table 6): Exposure Routes. Antimony trihydride. Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl. nau. Symptoms. kidneys. chlorine. rhin Breath: Fresh air TO: Eyes. lass.5 mg/m3) (see Table 1): 3 NIOSH 6008 OSHA PEL: TWA 0.Pp:AScba Change: N. BP: -1°F 1 ppm: Sa Eyes: N.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 124. Synonyms/Trade Names: Corn starch. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin. halogenated hydrocarbons. chest pain. Starch gum.R.10 mg/m DOT: 2676 119 Synonyms/Trade Names: Antimony hydride. Symptoms. odorless powder. alkalis Exposure Routes. jaun.Pp/SaF:Pd. Hydrogen antimonide Exposure Limits: Measurement Methods NIOSH REL: TWA 0. white. oxidizers. Incompatibilities and Reactivities: Oxidizers.1 ppm (0. resp sys Swallow: Medical attention immed Formula: CAS#: RTECS#: IDLH: SbH3 7803-52-3 WJ0700000 5 ppm Conversion: 1 ppm = 5. pulm irrit TO: Blood. Tapioca starch Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500. abdom pain.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: varies Skin: Prevent skin contact BP: Decomposes Not available.R. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Fine. resp sys Stibine 3 S 285 .D. skin. Rice starch. derm. Target Organs (see Table 5): Breath: Resp support ER: Inh SY: Head. Sol: Slight 2. hemolytic anemia.R. acids. RGasD: 4.Gr: 1.1 ppm (0. but may form explosive mixture with air.

but difficult to ignite. in animals: kidney damage Swallow: Medical attention immed TO: Eyes.36 ScbaF/SaF VP: Low §: ScbaF:Pd. IP: ? 3 mg/m3: Sa:Cf/PaprHie/100F/ Change: Daily Sp. anxi.P: ? 1.000 mg/m3: SaF:Pd.CAS#: RTECS#: IDLH: 8052-41-3 WJ8925000 20. IP: ? ScbaF/SaF Sp.Pp VP: ? §: ScbaF:Pd.78 20. Symptoms.o.R. Con Skin: Soap wash prompt SY: Stiff neck.Pp:AScba MLT: 514°F Escape: 100F/ScbaE UEL: ? LEL: ? Combustible Solid. derm.500 mg/m3: CcrFOv/GmFOv/PaprTOv*/ Change: N. skin. and containing >65% C10 or higher hydrocarbons. Target Organs (see Table 5): Eye: Irr immed ER: Inh. cyan.) Synonyms/Trade Names: Dry cleaning safety solvent. kidneys Stoddard solvent Formula: S Formula: CAS#: RTECS#: IDLH: C21H22N2O2 57-24-9 WL2275000 3 mg/m3 Conversion: DOT: 1692 151 Synonyms/Trade Names: Nux vomica.4 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 0.Pp/SaF:Pd.15 mg/m3 3 NIOSH 5016 OSHA PEL: TWA 0.] Exposure Limits: Measurement Methods NIOSH REL: TWA 350 mg/m3 (see Table 1): 3 NIOSH 1550 C 1800 mg/m [15-minute] 3 OSHA PEL†: TWA 500 ppm (2900 mg/m ) Physical Description: Colorless liquid with a kerosene-like odor.P: 102-110°F 17.Gr: 0. [pesticide] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 334. Symptoms. nose.75 mg/m3: Qm Eyes: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. n.5 mg/m3: 95XQ/Sa Remove: N. tetanic convuls with opisthotonos Swallow: Medical attention immed TO: CNS Strychnine 286 .s.000 mg/m3 Conversion: DOT: 1268 128 (petroleum distillates. crystalline solid. resp sys.Gr: 1. Sol: 0. Spotting naphtha [Note: A refined petroleum solvent with a flash point of 102-110°F.Pp:AScba FRZ: ? Escape: GmFOv/ScbaE UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Incompatibilities and Reactivities: Strong oxidizers First Aid (see Table 6): Exposure Routes. facial musc.R. throat. restless. Ing. boiling point of 309-396°F. Con Skin: Soap wash prompt SY: Irrit eyes.15 mg/m Physical Description: Colorless to white. Mineral spirits.02% Wash skin: When contam Fl. incr Breath: Resp support reflex excitability. chemical pneu (aspir Breath: Resp support liquid). Petroleum solvent. dizz. Strynchnos Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0.Pp/SaF:Pd. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: Varies 3500 mg/m3: CcrOv*/Sa* Eyes: Prevent eye contact BP: 309-396°F Wash skin: When contam Sol: Insoluble 8750 mg/m3: Sa:Cf*/PaprOv* Remove: When wet or contam Fl.R. CNS. odorless. Ing. incr acuity of perception.

Ing.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.000 (approx) Skin: Prevent skin contact BP: ? Not available.Pp:AScba Change: N. Con Skin: Soap wash SY: Irrit eyes. repro sys Styrene Subtilisins Formula: CAS#: 1395-21-7 (BPN) 9014-01-1 (Carlsburg) RTECS#: CO9450000 (BPN) CO9550000 (Carlsburg) IDLH: N. dizz. unsteady Skin: Water flush Breath: Resp support gait. Sp. nose. flu-like symptoms.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 28. Subtilisin BPN. Vinyl benzene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 50 ppm (215 mg/m3) 3 NIOSH 1501. resp sys.Gr: ? VP: 0 mmHg (approx) MLT: ? UEL: NA LEL: NA Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. resp sys S 287 . Con Eye: Irr immed SY: Irrit eyes.Formula: CAS#: RTECS#: IDLH: C6H5CH=CH2 100-42-5 WL3675000 700 ppm Conversion: 1 ppm = 4. resp sys. Styrol.91 Escape: GmFOv/ScbaE VP: 5 mmHg FRZ: -23°F UEL: 6. 89 OSHA PEL†: TWA 100 ppm C 200 ppm 600 ppm (5-minute maximum peak in any 3 hours) Physical Description: Colorless to yellow. drow. floral odor.00006 mg/m3 [60-minute] (see Table 1): OSHA PEL†: none None available Physical Description: Light-colored. defatting derm. skin. Subtilisin Carlsburg [Note: Commercial proteolytic enzymes are used in laundry detergents. resp sys. conf. Proteolytic enzymes.P: NA Remove: When wet or contam IP: NA Change: Daily Sp. Styrene monomer.2 NIOSH Skin: Prevent skin contact BP: 293°F 500 ppm: CcrOv*/Sa* Eyes: Prevent eye contact Sol: 0. strong acids. Conversion: DOT: Synonyms/Trade Names: Bacillus subtilis.] Exposure Routes. Symptoms. mal. Bacillus subtilis Carlsburg. narco. breathlessness.8% LEL: 0. Eyes: Prevent eye contact Sol: ? Wash skin: When contam Fl. head. Abs. repro effects Swallow: Medical attention immed TO: Eyes.P: 88°F Remove: When wet (flamm) IP: 8.40 eV PaprOv*/ScbaF/SaF §: ScbaF:Pd.Gr: 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 104. 3800 ST 100 ppm (425 mg/m ) OSHA 9. resp sens (enzyme asthma): sweat. Bacillus subtilis BPN. wheez Swallow: Medical attention immed TO: Eyes. possible liver inj. cough. Target Organs (see Table 5): Eye: Irr immed ER: Inh. liver. peroxides. skin. Phenylethylene. lass. [Note: A protein containing numerous amino acids. oily liquid with a sweet.D.26 mg/m3 DOT: 2055 128P (inhibited) Synonyms/Trade Names: Ethenyl benzene. Breath: Resp support chest pain. CNS.R. head. free-flowing powders.03% 700 ppm: Sa:Cf*/CcrFOv/GmFOv/ Wash skin: When contam Fl. Ing.] Exposure Limits: Measurement Methods NIOSH REL: ST 0. Symptoms. aluminum chloride [Note: May polymerize if contaminated or subjected to heat.9% Class IC Flammable Liquid Incompatibilities and Reactivities: Oxidizers. catalysts for vinyl polymers. skin. Usually contains an inhibitor such as tert-butylcatechol.

Ethylene dicyanide. Sol: 200% Eyes: N. dysp.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 80. Symptoms.99 Escape: GmFOv/ScbaE Provide: Eyewash VP(212°F): 2 mmHg MLT: 134°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Oxidizers Exposure Routes.P: 270°F 250 ppm: ScbaF/SaF Remove: When wet or contam IP: ? §: ScbaF:Pd. Sugar.1 NIOSH Skin: Prevent skin contact BP: 509°F 60 ppm: Sa Eyes: Prevent eye contact Sol: 13% 150 ppm: Sa:Cf Wash skin: When contam Fl.CAS#: RTECS#: IDLH: Formula: 110-61-2 WN3850000 N. Cane sugar. white. or powder.28 mg/m3 DOT: Synonyms/Trade Names: Butanedinitrile. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. CNS. nau. Confectioner's sugar. skin. resp sys First Aid (see Table 6): Eye: Irr immed Breath: Fresh air 288 .P: NA Wash skin: N. lass. cough TO: Eyes. VP: 0 mmHg (approx) MLT: 320-367°F (Decomposes) UEL: NA LEL: NA MEC: 45 g/m3 Noncombustible Solid. head.R.Gr: 0.Pp:AScba Change: Daily Sp. IP: NA Remove: N. Breath: Resp support blurred vision. odorless crystals. Symptoms. resp sys. Conversion: DOT: Synonyms/Trade Names: Beet sugar.Pp/SaF:Pd.Gr: 1. odorless. 1. NCCH2CH2CN Conversion: 1 ppm = 3. Abs. caramel odor when heated. waxy solid. dizz.R. Fl. [Note: May have a characteristic. upper resp sys. Target Organs (see Table 5): ER: Inh.R. vomit Swallow: Medical attention immed TO: Eyes. Granulated sugar.3 (see Table 2): BP: Decomposes Skin: N. sulfuric acid. nitric acid dust may explode.D. lumps. convuls. conf.R. Succinic dinitrile Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 6 ppm (20 mg/m3) NIOSH Nitriles Criteria Document OSHA PEL: none Physical Description: Colorless.D. skin. Con SY: Irrit eyes. Sucrose Exposure Routes. Ing. Dinile. Saccarose. Sp. Rock candy. Con Skin: Water wash immed SY: Irrit eyes. CVS Succinonitrile S Formula: CAS#: RTECS#: IDLH: C12H22O11 57-50-1 WN6500000 N. [Note: Forms cyanide in the body. but fine airborne Incompatibilities and Reactivities: Oxidizers.R. resp sys. Ethylene cyanide.59 Change: N. Not available.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 342. abdom pain. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) TWA 5 mg/m3 (resp) Physical Description: Hard.2-Dicyanoethane. skin. Table sugar Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500.

11 Provide: Frostbite wash VP: 21.2 atm Escape: GmFS/ScbaE Provide: Frostbite wash FRZ: -104°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Powdered alkali metals (such as sodium & potassium). Symptoms. Symptoms.98 mg/m3 DOT: 1080 126 Synonyms/Trade Names: Sulfur fluoride [Note: May contain highly toxic sulfur pentafluoride as an impurity.Formula: CAS#: RTECS#: IDLH: SO2 7446-09-5 WS4550000 100 ppm Conversion: 1 ppm = 2. nau.003% Wash skin: N.5 atm FRZ: -83°F (Sublimes) UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Disilane Exposure Routes. odorless gas. choking. water. aluminum. ID200 OSHA PEL†: TWA 5 ppm (13 mg/m ) Physical Description: Colorless gas with a characteristic. zinc.1 NIOSH Skin: Frostbite BP: 14°F 20 ppm: CcrS*/Sa* Eyes: Frostbite Sol: 10% 50 ppm: Sa:Cf*/PaprS* Wash skin: N.P: NA 100 ppm: CcrFS/GmFS/PaprTS*/ Remove: When wet or contam IP: 12. nose. convuls. Conversion: 1 ppm = 5. cough. Fl.Pp:AScba Change: N. irritating. Sulfurous oxide. pungent odor. throat.Pp/SaF:Pd. Breath: Resp support emotional upset. brass.30 eV RGasD: 2.62 mg/m3 DOT: 1079 125 Synonyms/Trade Names: Sulfurous acid anhydride. RGasD: 5. reflex Skin: Frostbite Breath: Resp support bronchoconstriction. lass. rhin.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 64. [Note: A liquid below 14°F.P: NA Remove: N. VP: 3. Sulfur oxide Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (5 mg/m3) (see Table 1): 3 NIOSH 3800. Eyes: Frostbite Sol(77°F): 0.1 Skin: Frostbite BP: Sublimes Not available.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 146. Con Eye: Frostbite SY: Irrit eyes. 6004 ST 5 ppm (13 mg/m ) 3 OSHA ID104. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh Skin: Frostbite SY: Asphy: incr breath rate. slight musc inco.R. liquid: frostbite TO: Eyes. Shipped as a liquefied compressed gas.R. [Note: Shipped as a liquefied compressed gas.R.D.] Exposure Limits: Measurement Methods NIOSH REL: TWA 1000 ppm (6000 mg/m3) (see Table 1): 3 NIOSH 6602 OSHA PEL: TWA 1000 ppm (6000 mg/m ) Physical Description: Colorless.30 eV Change: N.] Exposure Routes. vomit. IP: 19. ammonia.R.R. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Fl. copper [Note: Reacts with water to form sulfurous acid (H2SO3). resp sys Sulfur dioxide Formula: CAS#: RTECS#: IDLH: SF6 2551-62-4 WS4900000 N.26 SaT:Cf*/ScbaF/SaF (liquid) §: ScbaF:Pd. Condenses directly to a solid upon cooling. liquid: frostbite TO: Resp sys Sulfur hexafluoride S 289 . pulse rate. skin.

sulfite. fulminates. cough. Incompatibilities and Reactivities: Organic materials.40 eV Escape: GmFS/ScbaE Change: N. eye. Thiosulfurous dichloride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 1 ppm (6 mg/m3) 3 OSHA PEL†: TWA 1 ppm (6 mg/m ) None available Physical Description: Light-amber to yellow-red.] Exposure Routes.Gr: 1.Pp:AScba Provide: Eyewash (>1%) VP: 0.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 98.52 mg/m DOT: 1828 137 Synonyms/Trade Names: Sulfur chloride. Oil of vitriol. Ing. irritating odor. Sp. skin.0 NIOSH/OSHA Skin: Prevent skin contact BP: 280°F 5 ppm: CcrFS/GmFS/PaprS£/ Eyes: Prevent eye contact Sol: Decomposes Wash skin: When contam Fl. 1831 137 (fuming). 1832 137 (spent) Synonyms/Trade Names: Battery acid.R. skin. sulfur.84 (96-98% acid) §: ScbaF:Pd. Symptoms. teeth Sulfuric acid S Formula: CAS#: RTECS#: IDLH: S2Cl2 10025-67-9 WS4300000 5 ppm Conversion: 1 ppm = 5. thiosulfate. oily.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Sulfur subchloride. conj. dental erosion. sulfur dioxide.Pp/SaF:Pd. Con SY: Irrit eyes. Sp. resp sys.Pp/SaF:Pd. pulm edema. skin. Con SY: Irrit eyes. and hydrogen sulfide. skin burns. water.Gr: 1.68 Provide: Eyewash VP: 7 mmHg FRZ: -107°F Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Peroxides. bron. nose. muc memb. but capable of igniting finely divided combustible materials. oily liquid with a pungent. Ing. organics. pulm edema Skin: Water flush immed Breath: Resp support TO: Eyes. Corrosive to metals. throat. Sulfuric acid (aqueous) Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): 3 NIOSH 7903 OSHA PEL: TWA 1 mg/m OSHA ID113. Corrosive to metals.P: NA CcrFAg100/GmFAg100/ Remove: When wet or contam IP: ? ScbaF/SaF Change: N. skin burns. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 135.1 NIOSH/OSHA Skin: Prevent skin contact BP: 554°F 15 mg/m3: Sa:Cf£/PaprAgHie£/ Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl. powdered metals [Note: Reacts violently with water with evolution of heat.Pp:AScba Remove: When wet or contam IP: 9. Hydrogen sulfate. lac. Symptoms. resp sys Swallow: Medical attention immed Sulfur monochloride 3 290 . eye. emphy.] First Aid (see Table 6): Exposure Routes. ID165SG Physical Description: Colorless to dark-brown.Formula: CAS#: RTECS#: IDLH: H2SO4 7664-93-9 WS5600000 15 mg/m3 Conversion: DOT: 1830 137. Often used in an aqueous solution. odorless liquid. water [Note: Decomposes violently in water to form hydrochloric acid. oxides of phosphorous. Target Organs (see Table 5): Eye: Irr immed ER: Inh. [Note: Pure compound is a solid below 51°F. nauseating. skin. Skin: Water flush immed Breath: Resp support stomatis. carbides. derm Swallow: Medical attention immed TO: Eyes.P: 245°F ScbaF/SaF §: ScbaF:Pd.001 mmHg Escape: GmFAg100/ScbaE FRZ: 51°F Quick drench (>1%) UEL: NA LEL: NA Noncombustible Liquid. chlorates.

skin.4 mg/m3) OSHA ID110 OSHA PEL†: none Physical Description: Colorless gas with an odor like sulfur dioxide.1 Skin: Frostbite BP: -41°F Not available.08 Escape: GmFAg/ScbaE VP: 561 mmHg Quick drench FRZ: -134°F UEL: NA LEL: NA Noncombustible Liquid Nonflammable Gas Incompatibilities and Reactivities: None reported Exposure Routes. resp sys Sulfur tetrafluoride S 291 . resp sys. eye. dioxygen difluoride [Note: Readily hydrolyzed by moisture.R. hemorr Breath: Resp support TO: Eyes.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 108. RGasD: 8.Formula: CAS#: RTECS#: IDLH: S2F10 5714-22-7 WS4480000 1 ppm Conversion: 1 ppm = 10. skin burns (from SF4 releasing hydrofluoric Skin: Frostbite Breath: Resp support acid on exposure to moisture). Fl.025 ppm (0. lass.1 ppm: Sa Eyes: Prevent eye contact Sol: Insoluble 0.Pp:AScba Provide: Eyewash Sp. Target Organs (see Table 5): Eye: Frostbite ER: Inh. in animals: dysp.R.1 NIOSH Skin: Prevent skin contact BP: 84°F 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 254.P: NA 0. in animals: pulm edema. Ing. forming hydrofluoric acid & thionyl fluoride.Gr(32°F): 2. Con Skin: Soap wash immed SY: Irrit eyes.78 Provide: Frostbite wash VP(70°F): 10. Symptoms. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Con SY: Irrit eyes. resp sys.5 ppm: SaT:Cf/ScbaF/SaF Remove: When wet or contam IP: ? 1 ppm: Sa:Pd.Pp Change: N.5 atm FRZ: -185°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Moisture.25 ppm: Sa:Cf Wash skin: N. CNS Swallow: Medical attention immed Sulfur pentafluoride Formula: CAS#: RTECS#: IDLH: SF4 7783-60-0 WT4800000 N.25 mg/m ) None available Physical Description: Colorless liquid or gas (above 84°F) with an odor like sulfur dioxide.01 ppm (0.D. liquid: frostbite.1 ppm (0. Conversion: 1 ppm = 4.42 mg/m3 DOT: 2418 125 Synonyms/Trade Names: Tetrafluorosulfurane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. Sulfur decafluoride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. IP: 12. concentrated sulfuric acid. RGasD: 3. Symptoms.R. Eyes: Frostbite Sol: Reacts Wash skin: N.R. muc memb. rhin TO: Eyes.P: NA Remove: N. skin.] First Aid (see Table 6): Exposure Routes.Pp/SaF:Pd. skin. [Note: Shipped as a liquefied compressed gas.63 eV Change: N.39 mg/m3 DOT: Synonyms/Trade Names: Disulfur decafluoride.77 §: ScbaF:Pd. skin.R.1 mg/m3) 3 OSHA PEL†: TWA 0. Fl.

head. Sol: Low Wash skin: When contam Fl. Ing SY: Nau. lass. [insecticide/fumigant] [Note: Shipped as a liquefied compressed gas. musc fasc. odorless gas. rhin. blood chol 292 . Sulprofos Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 322. IP: 13. Symptoms. blurred vision.P: NA §: ScbaF:Pd. kidney inj TO: Eyes. Skin: Frostbite Breath: Resp support tremor.18 mg/m3 DOT: 2191 123 Synonyms/Trade Names: Sulfur difluoride dioxide.Pp/SaF:Pd.72 VP(70°F): 15.R. kidneys Sulfuryl fluoride S Formula: CAS#: RTECS#: IDLH: C12H19O2PS3 35400-43-2 TE4165000 N. Con (liquid) Eye: Frostbite SY: Conj. convuls. Skin: Soap wash immed Breath: Resp support chest tight. Sp.19 mg/m3 DOT: Synonyms/Trade Names: Bolstar®. rhinitis.P: ? Remove: When wet or contam IP: ? Change: N. Vikane® Exposure Limits: Measurement Methods NIOSH REL: TWA 5 ppm (20 mg/m3) (see Table 1): 3 NIOSH 6012 ST 10 ppm (40 mg/m ) 3 OSHA PEL†: TWA 5 ppm (20 mg/m ) Physical Description: Colorless. diarr.Pp:AScba Change: N. resp sys. dysp Swallow: Medical attention immed TO: Resp sys.5 Skin: Prevent skin contact BP: ? Not available.8 atm FRZ: -212°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: None reported Exposure Routes. skin. Sol(32°F): 0.Formula: CAS#: RTECS#: IDLH: SO2F2 2699-79-8 WT5075000 200 ppm Conversion: 1 ppm = 4. CNS. vomit. pulm edema. O-Ethyl O-(4-methylthio)phenyl S-propylphosphorodithioate Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): NIOSH 5600 OSHA PEL†: none OSHA PV2037 Physical Description: Tan-colored liquid with a sulfide-like odor.20 VP: <8 mmHg FRZ: ? UEL: ? LEL: ? Incompatibilities and Reactivities: None reported Exposure Routes. pharyngitis. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. card irreg.1 50 ppm: Sa* Eyes: Frostbite BP: -68°F 125 ppm: Sa:Cf* Wash skin: N.04 eV Escape: GmFS/ScbaE Provide: Frostbite wash RGasD: 3. liquid: frostbite: in animals: narco.D. CNS. pares. abdom cramps. Eyes: N.R.Gr: 1. Symptoms.2% 200 ppm: ScbaF/SaF Remove: N. CVS.R. dizz.R.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Frostbite MW: 102. Fl. Conversion: 1 ppm = 13.R. salv. miosis.

4.03% Wash skin: N. acne-like rash.Pp:AScba LEL: NA Escape: 100F/ScbaE Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes.R. Incompatibilities and Reactivities: None reported Exposure Routes. liver damage Breath: Resp support TO: Skin.R. but burns with difficulty. IP: NA 50 mg/m3: PaprHie/Sa:Cf Change: N. Sp. Ing. GI tract Swallow: Medical attention immed 2.Pp UEL: NA §: ScbaF:Pd.5-Trichlorophenoxyacetic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (see Table 1): 3 NIOSH 5001 OSHA PEL: TWA 10 mg/m Physical Description: Colorless to tan.Pp/SaF:Pd.R.R. Sol(77°F): 0. Sol: Insoluble Wash skin: N.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: Varies NIOSH Skin: N. Fl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp:AScba Escape: 100F/ScbaE MLT: 307°F UEL: ? LEL: ? Combustible Solid.5 NIOSH/OSHA Skin: N. liver. resp sys. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. Symptoms. [herbicide] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 255.R. BP: Decomposes 50 mg/m3: Qm Eyes: N. IP: ? 250 mg/m3: Sa:Cf/100F/PaprHie/ Change: N.R. Fl.CAS#: RTECS#: IDLH: Formula: AJ8400000 250 mg/m3 Cl3C6H2OCH2COOH 93-76-5 Conversion: DOT: 2765 152 Synonyms/Trade Names: 2.80 100 mg/m3: 100F/SaT:Cf/PaprTHie/ VP: 0 mmHg (approx) ScbaF/SaF MLT: 1652°F to 1832°F 1000 mg/m3: Sa:Pd. Con Skin: Soap wash SY: In animals: ataxia. crystalline solid.R. Con Breath: Fresh air SY: Fibrotic pneumoconiosis.4.Pp/SaF:Pd. odorless. skin irrit.70-2.R.5-T Talc (containing no asbestos and less than 1% quartz) Formula: Mg3Si4O10(OH)2 CAS#: 14807-96-6 RTECS#: WW2710000 IDLH: 1000 mg/m3 Conversion: DOT: Synonyms/Trade Names: Hydrous magnesium silicate.Gr: 1. irrit eyes TO: Eyes. CVS T 293 . Sp.80 ScbaF/SaF VP: 1 x 10-7 mmHg §: ScbaF:Pd.P: NA 20 mg/m3: 95XQ/Sa Remove: N. Steatite talc Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 2 mg/m3 (resp) NIOSH P&CAM355 (III) OSHA PEL†: TWA 20 mppcf Physical Description: Odorless. BP: ? 10 mg/m3: Qm Eyes: N. white powder.P: ? 100 mg/m3: 95XQ/Sa Remove: N.Gr: 2. Symptoms.

blood chol TEDP 3 294 .P: NA Wash skin: N. resp sys T CAS#: RTECS#: IDLH: Formula: XN4375000 10 mg/m3 [(CH3CH2O)2PS]2O 3689-24-5 Conversion: 1 ppm = 13. Target Organs (see Table 5): Eye: Irr immed ER: Inh. odorless powder.9 (see Table 2): NIOSH/OSHA BP: 9797°F Skin: N.Pp:AScba Provide: Eyewash VP: 0. bromine trifluoride. eye pain. skin. local sweat. rhin. cyan. Ing.Pp/SaF:Pd. Breath: Resp support nau.2 mg/m3 [skin] (see Table 1): 3 OSHA PEL: TWA 0.Pp/SaF:Pd. fluorine Exposure Routes.2 mg/m [skin] None available Physical Description: Pale-yellow liquid with a garlic-like odor. Dithion®. as Ta) Formula: CAS#: Ta (metal) 7440-25-7 (metal) IDLH: RTECS#: 2500 mg/m3 (as Ta) WW5505000 (metal) Conversion: DOT: Synonyms/Trade Names: Tantalum metal: Tantalum-181 Synonyms of other tantalum dusts (including oxide dusts) vary depending upon the specific compound. [Note: A pesticide that may be absorbed on a solid carrier or mixed in a more flammable liquid. iron [Note: Corrosive to iron. Tetraethyl dithiopyrophosphate.0007% Wash skin: When contam Fl.Gr(77°F): 1.20 §: ScbaF:Pd. resp sys. skin.0002 mmHg Escape: GmFOv100/ScbaE FRZ: ? Quick drench UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. vomit. Tetraethyl dithionopyrophosphate. 50 mg/m3: 95XQ/Sa IP: NA Remove: N.3 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 2 mg/m3: Sa Eyes: Prevent eye contact Sol: 0. skin. Cheyne-Stokes Swallow: Medical attention immed respiration.40 (powder) ScbaF/SaF VP: 0 mmHg (approx) 2500 mg/m3: Sa:Pd.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 322.] First Aid (see Table 6): Exposure Routes. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 180.18 mg/m DOT: 1704 153 Synonyms/Trade Names: Bladafum®.Pp MLT: 5425°F §: ScbaF:Pd. powder Incompatibilities and Reactivities: Strong oxidizers.R. Sulfotep. CNS. lass. Symptoms. lac. ignites SPONTANEOUSLY in air.R. diarr. Fl.Pp:AScba UEL: NA Escape: HieF/ScbaE LEL: NA 3 MEC: <200 g/m Metal: Combustible Solid. skin. Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 NIOSH 0500 ST 10 mg/m 3 OSHA PEL: TWA 5 mg/m Physical Description: Metal: Steel-blue to gray solid or black. Sp. head. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. blurred vision.R. CVS. 125 mg/m3: Sa:Cf/PaprHie Sp.Tantalum (metal and oxide dust.R. Con Breath: Resp support SY: Irrit eyes.65 (metal) Change: N. low BP. in animals: pulm irrit TO: Eyes. 250 mg/m3: 100F/SaT:Cf/PaprTHie/ 14.R.R. anor.Gr: 16. Symptoms. para. 25 mg/m3: Qm Sol: Insoluble Eyes: N. Thiotepp® Exposure Limits: Measurement Methods NIOSH REL: TWA 0. card irreg TO: Eyes.P: ? 5 mg/m3: Sa:Cf Remove: When wet or contam IP: ? 10 mg/m3: ScbaF/SaF Change: N. Abs. twitch. convuls. Con Skin: Soap wash immed SY: Irrit eyes.

34 Escape: GmFS/ScbaE VP: >1 atm FRZ: -36°F (Sublimes) UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Water [Note: Hydrolyzes slowly in water to telluric acid. Fl.24 25 mg/m3: Sa:Pd. BP: Sublimes 0.6 NIOSH/OSHA Skin: N.R.R.R.R. brittle solid.R. derm. BP: 1814°F Wash skin: N. sweat. 7301. IP: ? §: ScbaF:Pd. Fl.Formula: CAS#: RTECS#: IDLH: Te 13494-80-9 WY2625000 25 mg/m3 (as Te) Conversion: DOT: Synonyms/Trade Names: Aurum paradoxum.2 mg/m3) (see Table 1): 3 NIOSH S187 (II-3) OSHA PEL: TWA 0. in animals: CNS. Sol: Insoluble 1 mg/m3: 95XQ/Sa Remove: N. 9102 OSHA PEL*: TWA 0. blood Tellurium Tellurium hexafluoride Conversion: 1 ppm = 9.Pp:AScba MLT: 842°F Escape: 100F/ScbaE UEL: NA LEL: NA Combustible Solid Incompatibilities and Reactivities: Oxidizers. dry mouth. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.5 mg/m3: Sa:Cf/PaprHie Change: N. amorphous powder or grayish-white.88 mg/m3 Synonyms/Trade Names: Tellurium fluoride Exposure Limits: Measurement Methods NIOSH REL: TWA 0.2 ppm: Sa Eyes: N. chlorine.P: NA 1 ppm: SaT:Cf/ScbaF/SaF Remove: N.5 ppm: Sa:Cf Wash skin: N.P: NA 2.] Exposure Routes. Symptoms. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 241. Sol: Decomposes 0.1 mg/m OSHA ID121 [*Note: The REL and PEL also apply to other tellurium compounds (as Te) except Tellurium hexafluoride and Bismuth telluride. Ing. Metallum problematum Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: TWA 0. drow. 7303.2 mg/m ) Physical Description: Colorless gas with a repulsive odor. red blood cell changes Swallow: Medical attention immed TO: Skin. metallic taste. garlic breath. anor.6 0. MW: 127.1 mg/m3 3 NIOSH 7300.Gr: 6.Pp/SaF:Pd.R. Symptoms.R.R.R.Pp:AScba Change: N. no sweat. dysp. RGasD: 8. Skin: Soap wash prompt Breath: Resp support nau. dark-gray to brown.R. IP: NA 5 mg/m3: 100F/SaT:Cf/PaprTHie/ScbaF/SaF Sp. in animals: pulm edema TO: Resp sys Formula: TeF6 DOT: 2195 125 CAS#: 7783-80-4 RTECS#: WY2800000 IDLH: 1 ppm T 295 . Con Eye: Irr immed SY: Garlic breath.5 mg/m3: Qm Eyes: N. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N.Pp VP: 0 mmHg (approx) §: ScbaF:Pd.02 ppm (0.02 ppm (0. CNS. Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh SY: Head.Pp/SaF:Pd.] Physical Description: Odorless. cadmium Exposure Routes.

diarr. blood chol TEPP 296 .] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 290. Cheyne-Stokes Swallow: Medical attention immed respiration. para. Symptoms. fruity odor.00000007 mmHg MLT: 87°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. salv.Formula: CAS#: RTECS#: IDLH: S[C6H4OP(S)(OCH3)2]2 3383-96-8 TF6890000 N. card irreg. blurred vision.D.P: ? Remove: When wet or contam IP: ? Change: Daily Sp. crystalline solid or liquid (above 87°F).P: NA 1. Skin: Soap wash immed Breath: Resp support nau. Symptoms. Abs. O. vomit Swallow: Medical attention immed TO: Eyes. Abs. resp sys. resp sys.5 Skin: Prevent skin contact BP: 248-257°F (Decomposes) Not available.O'-thiodi-p-phenylene phosphorothioate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500.2 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 0. water [Note: Hydrolyzes quickly in water to form pyrophosphoric acid. Ing. Temefos. CNS. lass. Tetraethyl pyrophosphate. sweat TO: Eyes. 3018 152 (liquid) Synonyms/Trade Names: Ethyl pyrophosphate.5 mg/m3: Sa Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl.O'O'-Tetramethyl O. brown liquid. convuls. CNS.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 466. rhin. dizz.Pp:AScba FRZ: 32°F Escape: GmFOv100/ScbaE Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Strong oxidizers. [insecticide] [Note: Technical grade is a viscous. alkalis.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.0002 mmHg §: ScbaF:Pd.32 VP(77°F): 0. twitch. abdom cramps.Gr: 1.05 mg/m3 [skin] (see Table 1): 3 NIOSH 2504 OSHA PEL: TWA 0.Gr: 1. nau.O. cyan. CVS. Tetron® Exposure Limits: Measurement Methods NIOSH REL: TWA 0.05 mg/m [skin] Physical Description: Colorless to amber liquid with a faint. Ing.] Exposure Routes. dysp. blurred vision. chest tight. blood chol Temephos T Formula: CAS#: RTECS#: IDLH: [(CH3CH2O)2PO]2O 107-49-3 UX6825000 5 mg/m3 Conversion: 1 ppm = 11.R. GI tract. Sp.Pp Provide: Eyewash VP: 0. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. diarr. Con Eye: Irr immed SY: Eye pain. Conversion: DOT: Synonyms/Trade Names: Abate®. CVS. Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl. vomit. low BP. head. lac. Con Eye: Irr immed SY: Irrit eyes.87 mg/m3 DOT: 2783 152 (solid).25 mg/m3: Sa:Cf Remove: When wet or contam IP: ? 2.5 mg/m3: SaT:Cf/ScbaF/SaF Change: N.19 5 mg/m3: Sa:Pd. Skin: Water flush immed Breath: Resp support anor. 0600 TWA 5 mg/m (resp) 3 OSHA PV2056 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: White. [insecticide] [Note: A solid below 32°F.

liver. kidneys m-Terphenyl Formula: CAS#: RTECS#: IDLH: C6H5C6H4C6H5 84-15-1 WZ6472000 500 mg/m3 Conversion: 1 ppm = 9. in animals: liver.09 mmHg §: ScbaF:Pd. sore Breath: Resp support throat. kidney damage Swallow: Medical attention immed TO: Eyes. resp sys. 3-Phenylbiphenyl.01 250 mg/m3: 100F/ScbaF/SaF Provide: Eyewash Sp. muc memb. resp sys. thermal skin burns. 1. ortho-Terphenyl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. meta-Terphenyl. Ing.Gr: 1. head. skin.57 mg/m3 DOT: Synonyms/Trade Names: m-Diphenylbenzene.99 eV 250 mg/m3: 100F/ScbaF/SaF Provide: Eyewash Sp.Pp:AScba Quick drench MLT: 192°F Escape: 100F/ScbaE UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. skin.2-Terphenyl.Formula: CAS#: RTECS#: IDLH: C6H5C6H4C6H5 92-06-8 WZ6470000 500 mg/m3 Conversion: 1 ppm = 9. Ing.3 25 mg/m3: Qm£ Eyes: Prevent eye contact BP: 689°F Wash skin: When contam Sol: Insoluble 50 mg/m3: 95XQ£/Sa£ Remove: When wet or contam Fl. o-Triphenyl Exposure Limits: Measurement Methods NIOSH REL: C 5 mg/m3 (0. liver.5 ppm) 3 NIOSH 5021 OSHA PEL†: C 9 mg/m (1 ppm) Physical Description: Yellow solid (needles). Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 230. skin.Pp VP(200°F): 0.42 mg/m3 DOT: Synonyms/Trade Names: o-Diphenylbenzene. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 230.3-Terphenyl. 2-Phenylbiphenyl.P(oc): 375°F 125 mg/m3: Sa:Cf£/PaprHie£ Change: Daily IP: 8. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. 1.Pp VP(200°F): 0.01 mmHg §: ScbaF:Pd.Pp/SaF:Pd. skin. m-Triphenyl Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 5 mg/m3 (0.3 25 mg/m3: Qm£ Eyes: Prevent eye contact BP: 630°F Wash skin: When contam Sol: Insoluble 50 mg/m3: 95XQ£/Sa£ Remove: When wet or contam Fl. muc memb. Con Skin: Water flush immed SY: Irrit eyes. 1. Isodiphenylbenzene. kidneys o-Terphenyl T 297 . Con Skin: Water flush immed SY: Irrit eyes. Symptoms.5 ppm) (see Table 1): 3 NIOSH 5021 OSHA PEL†: C 9 mg/m (1 ppm) Physical Description: Colorless or light-yellow solid. 1. head.P(oc): 325°F 125 mg/m3: Sa:Cf£/PaprHie£ Change: Daily IP: 7.23 500 mg/m3: SaF:Pd.Gr: 1. kidney damage Swallow: Medical attention immed TO: Eyes.Pp/SaF:Pd. thermal skin burns. sore Breath: Resp support throat.3-Diphenylbenzene. Symptoms. in animals: liver.Pp:AScba Quick drench MLT: 136°F Escape: 100F/ScbaE UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes.2-Diphenylbenzene.1 500 mg/m3: SaF:Pd.

[carc] TO: Eyes. liver.Pp/SaF:Pd.] T Conversion: DOT: Synonyms/Trade Names: Dioxin.] Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): See Appendix A None available OSHA PEL: none Physical Description: Colorless to white. para-Terphenyl. 2. hemorr.Pp/SaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 230.P: 405°F 50 mg/m3: 95XQ£/Sa£ Remove: When wet or contam IP: 7. Symptoms.7. Ing. repro sys [in animals: tumors at many sites] First Aid (see Table 6): Eye: Irr immed Skin: Soap flush immed Breath: Resp support Swallow: Medical attention immed 298 .5-trichlorophenol. Symptoms.5 ppm) 3 NIOSH 5021 OSHA PEL†: C 9 mg/m (1 ppm) Physical Description: White or light-yellow solid. head.5-T & 2(2.3. sore Skin: Water flush immed Breath: Resp support throat.78 125 mg/m3: Sa:Cf£/PaprHie£ Change: Daily Sp.00000002% Remove: When wet or contam Fl.Pp:AScba Quick drench UEL: ? Escape: 100F/ScbaE LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. kidneys.Gr: 1. TCDD. terato effects. liver.Formula: CAS#: RTECS#: IDLH: C6H5C6H4C6H5 92-94-4 WZ6475000 500 mg/m3 Conversion: 1 ppm = 9. muc memb.23 250 mg/m3: 100F/ScbaF/SaF Provide: Eyewash VP: Very low 500 mg/m3: SaF:Pd. skin.3. Target Organs (see Table 5): ER: Inh. kidney damage Swallow: Medical attention immed TO: Eyes.8-TCDD [Note: Formed during past production of 2. 2. thermal skin burns.5-trichlorophenoxy)propionic acid. kidneys p-Terphenyl 2. Abs. chloracne.Gr: ? VP(77°F): 0. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. skin.P: ? Change: Daily IP: ? Provide: Eyewash Sp. in animals: liver. kidney damage. possible repro.4-Diphenylbenzene.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 322. in animals: liver.4.57 mg/m3 DOT: Synonyms/Trade Names: p-Diphenylbenzene. resp sys.Pp MLT: 415°F §: ScbaF:Pd.3 NIOSH Skin: Prevent skin contact BP: 761°F 25 mg/m3: Qm£ Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl.000002 mmHg Quick drench MLT: 581°F UEL: ? LEL: ? Incompatibilities and Reactivities: UV light (decomposes) Exposure Routes. 4-Phenylbiphenyl.7. Con Eye: Irr immed SY: Irrit eyes. [Note: Exposure may occur through contact at previously contaminated worksites. skin. Con SY: Irrit eyes.D.8-Tetrachloro-dibenzo-p-dioxin C H Cl O 12 4 4 2 Formula: CAS#: 1746-01-6 RTECS#: HP3500000 IDLH: Ca [N. porphyria. allergic derm. 1. TCDBD. crystalline solid.4. 1.4. p-Triphenyl Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 5 mg/m3 (0.4-Terphenyl. Dioxine. GI dist. Ing.0 ¥: ScbaF:Pd.Pp:AScba Eyes: Prevent eye contact BP: Decomposes Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: 0.

acids Exposure Routes.01% §: ScbaF:Pd.2-tetrachloroethane. pulm edema. skin. Con Skin: Soap wash prompt SY: Irrit eyes.2-difluoroethane T 299 . magnesium.8 NIOSH/OSHA Skin: Prevent skin contact BP: 197°F 2000 ppm: Sa/ScbaF Eyes: Prevent eye contact Sol: 0.Formula: CAS#: RTECS#: IDLH: CCl3CClF2 76-11-9 KI1425000 2000 ppm Conversion: 1 ppm = 8.1.2-Difluoro-1.2-Difluoro-1.30 eV Change: N. Freon® 112. powdered aluminum.2-Tetrachloro-1. skin.1.1. resp sys.Pp/SaF:Pd.65 VP: 40 mmHg MLT: 77°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Chemically-active metals such as potassium. skin. magnesium & sodium. calcium. ether-like odor.2.2-tetrachloroethane. ether-like odor.34 mg/m3 DOT: Synonyms/Trade Names: 1.1. CNS Swallow: Medical attention immed 1.1. Freon® 112a.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 203. CNS Swallow: Medical attention immed 1. Ing. Halocarbon 112a.Gr: 1. zinc.R. dysp Breath: Resp support TO: Eyes.Pp:AScba Wash skin: When contam Fl.2. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.01% §: ScbaF:Pd.R. [Note: A liquid above 105°F. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Halocarbon 112. conj.Pp:AScba Wash skin: When contam Fl.34 mg/m3 DOT: Synonyms/Trade Names: 2.Gr: 1. drow. narco Breath: Resp support TO: Eyes. Refrigerant 112 Exposure Limits: Measurement Methods NIOSH REL: TWA 500 ppm (4170 mg/m3) (see Table 1): 3 NIOSH 1016 OSHA PEL: TWA 500 ppm (4170 mg/m ) OSHA 7 Physical Description: Colorless solid or liquid (above 77°F) with a slight. Con Skin: Soap wash prompt SY: In animals: irrit eyes. Refrigerant 112a Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 500 ppm (4170 mg/m3) 3 NIOSH 1016 OSHA PEL: TWA 500 ppm (4170 mg/m ) OSHA 7 Physical Description: Colorless solid with a slight. Sp. acids Exposure Routes.65 VP: 40 mmHg MLT: 105°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Chemically-active metals such as potassium. Symptoms.8 NIOSH/OSHA Skin: Prevent skin contact BP: 199°F 2000 ppm: Sa/ScbaF Eyes: Prevent eye contact Sol(77°F): 0. zinc.Pp/SaF:Pd. resp sys. skin. beryllium.1. calcium & sodium. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 203. CNS depres. pulm edema.P: NA Escape: GmFOv/ScbaE Remove: When wet or contam IP: 11. Sp. powdered aluminum. beryllium. Symptoms.P: NA Escape: GmFOv/ScbaE Remove: When wet or contam IP: ? Change: N. Ing.2-difluoroethane Formula: CAS#: RTECS#: IDLH: CCl2FCCl2F 76-12-0 KI1420000 2000 ppm Conversion: 1 ppm = 8.2-Tetrachloro-2.

4-dinitrophenyl disulfide Exposure Routes. [carc] TO: Skin. abdom pain. musc inco. Sp. Ing. lass. CNS. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 167.87 mg/m3 DOT: 1702 151 Synonyms/Trade Names: Acetylene tetrachloride. Con Eye: Irr immed SY: Irrit eyes. jaun. liver.9 NIOSH Skin: Prevent skin contact BP: 296°F ¥: ScbaF:Pd. Symptoms. derm. Eyes: Prevent eye contact Sol: 0. Symptoms. kidney damage. skin.1. leucyt.2-Tetrachloroethane Conversion: Synonyms/Trade Names: None Exposure Limits: Measurement Methods NIOSH REL: Handle with caution in the workplace.P: ? Remove: When wet or contam IP: ? Change: N.54 Provide: Eyewash VP(77°F): 14 mmHg FRZ: -94°F Quick drench UEL: ? LEL: ? Incompatibilities and Reactivities: Potassium. T Formula: CAS#: RTECS#: IDLH: CHCl2CHCl2 79-34-5 KI8575000 Ca [100 ppm] Conversion: 1 ppm = 6. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. 2. liver Formula: CCl3CH2Cl DOT: 1702 151 CAS#: 630-20-6 RTECS#: KI8450000 IDLH: N. nitrogen tetroxide.9 Skin: Prevent skin contact BP: 267°F Not available.Gr(77°F): 1.1% Wash skin: When contam Fl.2-Tetrachloroethane 300 .2. potassium hydroxide. tremor fingers. Sp. hepatitis.D.Pp:AScba Eyes: Prevent eye contact Sol: 0. irreg respiration.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.1.] Exposure Routes.3% Escape: GmFOv/ScbaE Wash skin: When contam Fl. restless.Gr: 1.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 167. chloroform-like odor. GI tract [in animals: liver tumors] Swallow: Medical attention immed 1.1. liver Skin: Soap wash prompt Breath: Resp support tend. vomit.P: NA Remove: When wet or contam IP: 11. (see Table 1): See Appendix C (Chloroethanes) None available OSHA PEL: none Physical Description: Yellowish-red liquid. Abs. Con SY: Nau. CNS.R. sodium potassium alloy.1. 2562 TWA 1 ppm (7 mg/m ) [skin] OSHA 7 See Appendix A See Appendix C (Chloroethanes) 3 OSHA PEL†: TWA 5 ppm (35 mg/m ) [skin] Physical Description: Colorless to pale-yellow liquid with a pungent. Symmetrical tetrachloroethane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 1019. skin. strong caustics. dinitrogen tetraoxide. in Skin: Soap wash immed Breath: Resp support animals: liver changes Swallow: Medical attention immed TO: Eyes. sodium.10 eV Change: N. fuming sulfuric acid [Note: Degrades slowly when exposed to air. kidneys.59 Provide: Eyewash VP: 5 mmHg FRZ: -33°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Chemically-active metals. Ing.

neck.Pp/SaF:Pd. skin. skin. Con Eye: Irr immed SY: Irrit eyes.P: NA Wash skin: When contam IP: 9. nose. caustic soda. skin eryt.Pp:AScba Sol: 0. nau. drow. anor. Skin: Soap wash prompt Breath: Resp support inco. Abs. head. sodium hydroxide.Gr: 1. CNS [in animals: liver tumors] Tetrachloroethylene Formula: CAS#: RTECS#: IDLH: C10H4Cl4 1335-88-2 QK3700000 See Appendix F Conversion: DOT: Synonyms/Trade Names: Halowax®. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Perk. Symptoms. liver inj Breath: Resp support TO: Liver. kidneys. dizz.78 mg/m3 DOT: 1897 160 Synonyms/Trade Names: Perchlorethylene. Perchloroethylene. but Incompatibilities and Reactivities: Strong oxidizers. Nibren wax. throat.8 (see Table 2): NIOSH BP: 250°F Skin: Prevent skin contact ¥: ScbaF:Pd. Abs.Gr: 1. Con Skin: Soap wash immed SY: Acne-form derm. flush face.59-1.65 VP: <1 mmHg See Appendix F MLT: 360°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. Ing. [carc] Swallow: Medical attention immed TO: Eyes. chloride and phosgene. OSHA 1001 See Appendix A OSHA PEL†: TWA 100 ppm C 200 ppm 300 ppm (5-minute maximum peak in any 3-hours) Physical Description: Colorless liquid with a mild.62 Change: N.32 eV Remove: When wet or contam Sp. potash Exposure Routes.Pp:AScba Remove: When wet or contam IP: ? Escape: GmFOv100/ScbaE Change: Daily Sp. dizz. beryllium & barium.Formula: CAS#: RTECS#: IDLH: Cl2C=CCl2 127-18-4 KX3850000 Ca [150 ppm] Conversion: 1 ppm = 6. skin. VP: 14 mmHg Provide: Eyewash FRZ: -2°F Quick drench UEL: NA LEL: NA Noncombustible Liquid. Tetrachlorethylene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1003 Minimize workplace exposure concentrations. jaun. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 265.02% Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl.9 NIOSH/OSHA Skin: Prevent skin contact BP: 599-680°F 20 mg/m3: ScbaF/SaF Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl. Ing. resp sys. chemically-active decomposes in a fire to hydrogen metals such as lithium. head. liver. resp sys. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 165. liver damage. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp/SaF:Pd. lass.R.P(oc): 410°F §: ScbaF:Pd. chloroform-like odor. CNS Swallow: Medical attention immed Tetrachloronaphthalene T 301 . Seekay wax Exposure Limits: Measurement Methods NIOSH REL: TWA 2 mg/m3 [skin] (see Table 1): 3 NIOSH S130 (II-2) OSHA PEL: TWA 2 mg/m [skin] Physical Description: Colorless to pale-yellow solid with an aromatic odor. Symptoms.

1%) Fl.Pp Provide: Quick drench (>0. tremor.Pp/SaF:Pd. Symptoms.1%) Sol: 0.1 2000 ppm: Sa:Cf£/CcrFOv/GmFOv/ Eyes: Prevent eye contact BP: 151°F Wash skin: When contam Sol: Miscible PaprOv£/ScbaF/SaF Remove: When wet (flamm) §: ScbaF:Pd.1%) MW: 323.5 0. eyes Tetraethyl lead (as Pb) T CAS#: RTECS#: IDLH: Formula: 109-99-9 LU5950000 2000 ppm [10%LEL] C4H8O Conversion: 1 ppm = 2.Formula: CAS#: RTECS#: IDLH: Pb(C2H5)4 78-00-2 TP4550000 40 mg/m3 (as Pb) Conversion: DOT: 1649 131 Synonyms/Trade Names: Lead tetraethyl. hypothermia.8% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers.4-Epoxybutane.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact (>0. coma. TEL.P: 200°F 3. rust. Escape: GmFOv/ScbaE IP: 9. kidneys. [Note: Main usage is in anti-knock additives for gasoline.Gr: 1. Ing Skin: Water flush prompt SY: Irrit eyes. mania.10 eV 40 mg/m3: Sa:Pd.00002% 1.075 mg/m3 [skin] 3 NIOSH 2533 OSHA PEL: TWA 0. 1.] Exposure Routes. lithium-aluminum alloys [Note: Peroxides may accumulate upon prolonged storage in presence of air. lass. resp sys. Con Skin: Soap wash immed SY: Insom. hyper-reflexia. lowSwallow: Medical attention immed wgt. conf.8% LEL: 2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Tetramethylene oxide. orange.Pp:AScba VP: 0.65 §: ScbaF:Pd. Tetraethylplumbane Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. halu. potassium permanganate [Note: Decomposes slowly at room temperature and more rapidly at higher temperatures.2 mmHg Escape: GmFOv/ScbaE FRZ: -202°F UEL: ? LEL: 1. CVS.] Exposure Routes. head. eye irrit TO: CNS. convuls. sulfuryl chloride. nau. anor.1%) Sp. Breath: Resp support bradycardia.R. hypotension.95 mg/m DOT: 2056 127 Synonyms/Trade Names: Diethylene oxide.075 mg/m [skin] Physical Description: Colorless liquid (unless dyed red.75 mg/m3: Sa Eyes: Prevent eye contact BP: 228°F (Decomposes) Wash skin: When contam (>0. CNS Swallow: Medical attention immed Tetrahydrofuran 3 302 . sweet odor.75 mg/m3: SaT:Cf/ScbaF/SaF Change: Daily IP: 11. nau.89 VP: 132 mmHg FRZ: -163°F UEL: 11.45 eV Sp. CNS depres Breath: Resp support TO: Eyes. spasticity. or blue) with a pleasant. Ing. Con. Symptoms. 3800 ST 250 ppm (735 mg/m ) OSHA 7 OSHA PEL†: TWA 200 ppm (590 mg/m3) Physical Description: Colorless liquid with an ether-like odor.P: 6°F Change: N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Gr: 0.Pp/SaF:Pd. Abs.Pp:AScba Fl. anxiety. dizz. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 72. upper resp sys. pallor. psychosis. THF Exposure Limits: Measurement Methods NIOSH REL: TWA 200 ppm (590 mg/m3) (see Table 1): 3 NIOSH 1609.875 mg/m3: Sa:Cf Remove: When wet or contam (>0.

[Note: Forms cyanide in the body.Pp Provide: Quick drench (>0. nau. TMSN Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 3 mg/m3 (0. CVS.75 mg/m3: SaT:Cf/ScbaF/SaF Change: Daily IP: 8. Tetramethylplumbane.1%) Sp. odorless solid.075 mg/m [skin] Physical Description: Colorless liquid (unless dyed red.50 eV 40 mg/m3: Sa:Pd.002% 1.P: ? Change: Daily IP: ? Sp.2 28 mg/m3: Sa/ScbaF Eyes: Prevent eye contact BP: Sublimes Wash skin: When contam §: ScbaF:Pd. Con Skin: Soap wash immed SY: Insom.P: 100°F 3.Formula: CAS#: RTECS#: IDLH: Pb(CH3)4 75-74-1 TP4725000 40 mg/m3 (as Pb) Conversion: DOT: Synonyms/Trade Names: Lead tetramethyl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. convuls. Abs. Symptoms. kidneys Tetramethyl lead (as Pb) Formula: CAS#: RTECS#: IDLH: (CH3)2C(CN)C(CN)(CH3)2 3333-52-6 WN4025000 5 ppm Conversion: 1 ppm = 5. kidney. [Note: Main usage is in anti-knock additives for gasoline. Abs. liver. liver.5 ppm) [skin] OSHA 7 Physical Description: Colorless. convuls.Pp/SaF:Pd. TML Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. Breath: Resp support anor. nau.5 ppm) [skin] 3 NIOSH S155 (II-3) OSHA PEL: TWA 3 mg/m (0.07 VP: ? MLT: 338°F (Sublimes) UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes.Gr: 2.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 136.57 mg/m3 DOT: Synonyms/Trade Names: Tetramethyl succinodinitrile. delirium. Ing. or blue) with a fruity odor. bad dreams. coma Swallow: Medical attention immed TO: CNS.1%) Sol: 0. kidneys.875 mg/m3: Sa:Cf Remove: When wet or contam (>0. Ing.1%) Fl. orange.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact (>0. hypotension. Con Skin: Soap wash prompt SY: Head.Pp/SaF:Pd. GI effects Breath: Resp support TO: CNS.3 0.Gr: 1. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. anxious. restless. coma.Pp:AScba Sol: Insoluble Remove: When wet or contam Escape: GmFOv100/ScbaE Fl.Pp:AScba VP: 23 mmHg Escape: GmFOv/ScbaE FRZ: -15°F UEL: ? LEL: ? Class II Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers such as sulfuryl chloride or potassium permanganate Exposure Routes.75 mg/m3: Sa Eyes: Prevent eye contact BP: 212°F (Decomposes) Wash skin: When contam (>0.1%) MW: 267. GI tract Swallow: Medical attention immed Tetramethyl succinonitrile T 303 .00 §: ScbaF:Pd. mania. Symptoms.075 mg/m3 [skin] 3 NIOSH 2534 OSHA PEL: TWA 0.

Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. resp sys Swallow: Medical attention immed Tetrasodium pyrophosphate 304 .02 mg/m3 Synonyms/Trade Names: Tetan. Con Skin: Water wash prompt SY: Irrit eyes. TSPP Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 5 mg/m3 NIOSH 0500 OSHA PEL†: none Physical Description: Odorless. Ing. throat. Tetrasodium pyrophosphate (anhydrous). Breath: Resp support methemo. oxidizers. white powder or granules. transparent crystals. aluminum. skin.P: NA Remove: When wet or contam IP: NA Change: Daily Sp. head.Pp/SaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 196.Gr: 2. nose. cotton [Note: Combustible material wet with tetranitromethane may be highly explosive. throat.P: ? Escape: GmFS¿/ScbaE Change: Daily IP: ? Provide: Eyewash Sp. skin. chest pain.62 VP: 8 mmHg FRZ: 57°F UEL: ? LEL: ? Combustible Liquid. [Note: The decahydrate (Na4P2O7×10H2O) is in the form of colorless. dizz. nose. Incompatibilities and Reactivities: Hydrocarbons. TNM Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (8 mg/m3) (see Table 1): 3 NIOSH 3513 OSHA PEL: TWA 1 ppm (8 mg/m ) Physical Description: Colorless to pale-yellow liquid or solid (below 57°F) with a pungent odor. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. dysp.45 Provide: Eyewash (solution) VP: 0 mmHg (approx) MLT: 1810°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Strong acids Exposure Routes. Eyes: Prevent eye contact Sol(77°F): 7% Wash skin: When contam Fl.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 265. resp sys. Sodium pyrophosphate. CNS Formula: C(NO2)4 DOT: 1510 143 CAS#: 509-14-8 RTECS#: PB4025000 IDLH: 4 ppm T Formula: CAS#: RTECS#: IDLH: Na4P2O7 7722-88-5 UX7350000 N. alkalis. derm Breath: Resp support TO: Eyes. Symptoms.9 Skin: Prevent skin contact BP: Decomposes Not available. cyan. skin. Con Skin: Soap wash prompt SY: Irrit eyes. Ing. skin. blood. skin burns Swallow: Medical attention immed TO: Eyes. Tetrasodium diphosphate.Pp:AScba Remove: When wet (flamm) Fl.] Exposure Routes. metals.Gr: 1.D. toluene. Conversion: DOT: Synonyms/Trade Names: Pyrophosphate.Tetranitromethane Conversion: 1 ppm = 8.0 4 ppm: Sa:Cf£/CcrFS¿/GmFS¿/ Eyes: Prevent eye contact BP: 259°F Wash skin: When contam Sol: Insoluble PaprS¿£/ScbaF/SaF §: ScbaF:Pd. Symptoms. but difficult to ignite.

Nitramine.5 mg/m3 [skin] 3 NIOSH S225 (II-3) OSHA PEL: TWA 1.6-Trinitrophenyl-N-methylnitramine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1. resp sys. Abs.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes. chest pain.o.5 mg/m3: Qm Eyes: Prevent eye contact upon the specific soluble Wash skin: When contam 1 mg/m3: 95XQ/Sa thallium compound. Con Skin: Soap wash prompt SY: Sens derm. pares legs TO: Eyes.02% Wash skin: When contam/Daily Fl.6-Tetryl. ptosis. 2.Pp MLT: 268°F §: ScbaF:Pd. as Tl) Formula: CAS#: RTECS#: IDLH: 15 mg/m3 (as Tl) Conversion: DOT: 1707 151 (compounds. 9102 OSHA PEL: TWA 0. Symptoms. mal. hydrazine First Aid (see Table 6): Exposure Routes. tremor. itch. pulm edema. 7303. anemia.Pp §: ScbaF:Pd. kidneys Tetryl Thallium (soluble compounds.5 mg/m3: Sa:Cf/PaprHie Change: Daily 5 mg/m3: 100F/SaT:Cf/PaprTHie/ScbaF/SaF 15 mg/m3: SaF:Pd. resp sys. Ing. kidneys. edema on nasal folds. abdom pain. cheeks.) Synonyms/Trade Names: Synonyms vary depending upon the specific soluble thallium compound. nau.Pp/SaF:Pd. insom. peri Breath: Resp support neuritis. odorless.4. alopecia. kidney damage. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Remove: When wet or contam 2. 7301.s. Swallow: Medical attention immed chorea.1 mg/m3 [skin] (see Table 1): 3 NIOSH 7300.P: Explodes 15 mg/m3: 95XQ*/Sa* Remove: When wet or contam IP: ? 37. strabismus.5 mg/m3: Qm Eyes: Prevent eye contact Sol: 0. Symptoms. Target Organs (see Table 5): Eye: Irr immed ER: Inh.2. retster tight. CNS.5 mg/m3: Sa:Cf*/PaprHie* Change: Daily Sp. cough.Formula: CAS#: RTECS#: IDLH: (NO2)3C6H2N(NO2)CH3 479-45-8 BY6300000 750 mg/m3 Conversion: DOT: Synonyms/Trade Names: N-Methyl-N.4. diarr.57 75 mg/m3: 100F/ScbaF/SaF VP: <1 mmHg 750 mg/m3: SaF:Pd. liver. irrity. Swallow: Medical attention immed liver. vomit.2 NIOSH/OSHA Skin: Prevent skin contact BP: 356-374°F (Explodes) 7. CNS. psychosis. head.1 mg/m [skin] Physical Description: Appearance and odor vary depending upon the specific OSHA ID121 soluble thallium compound. GI tract. skin. liver. convuls.5 mg/m [skin] Physical Description: Colorless to yellow. coryza.Gr: 1. kidney damage TO: Eyes. crystalline solid.Pp:AScba UEL: ? Escape: 100F/ScbaE LEL: ? Combustible Solid (Class A Explosive) Incompatibilities and Reactivities: Oxidizable materials. Ing. lass. liver. vomit. Con Skin: Water flush prompt SY: Nau.6-tetranitroaniline. body hair T 305 . n. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Properties vary depending Skin: Prevent skin contact 0.4. 2.Pp/SaF:Pd. Abs. kera. Breath: Resp support sneez. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 287. eryt. neck.

active metals (e. skin. throat. [Note: Olfactory fatigue may occur after short exposures. Con Breath: Fresh air SY: Irrit eyes. IP: ? Change: N. Eyes: N.R. Symptoms. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl.R.P: >230°F Remove: When wet or contam IP: ? Change: N.R..4'-Thiobis(3-methyl-6-tert-butylphenol). Mercaptoacetate.P: 420°F Remove: N. Sp.] First Aid (see Table 6): Exposure Routes. bases.g. 2-Mercaptoacetic acid. 0600 TWA 5 mg/m (resp) 3 OSHA PEL†: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: Light-gray to tan powder with a slightly aromatic odor.R.0000006 mmHg MLT: 302°F UEL: NA LEL: NA Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. HSCH2COOH Conversion: 1 ppm = 3.4'-Thiobis(6-tert-butyl-m-cresol) T CAS#: RTECS#: IDLH: Formula: 68-11-1 AI5950000 N. resp sys Swallow: Medical attention immed TO: Eyes. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. sodium potassium.32 Provide: Eyewash VP(64°F): 10 mmHg FRZ: 2°F Quick drench UEL: ? LEL: 5. magnesium.1'-Thiobis(2-methyl-4-hydroxy-5-tert-butylbenzene) Exposure Limits: Measurement Methods NIOSH REL: TWA 10 mg/m3 (total) (see Table 1): 3 NIOSH 0500. nose. Symptoms. lac. Target Organs (see Table 5): Eye: Irr immed ER: Inh.77 mg/m3 DOT: 1940 153 Synonyms/Trade Names: Acetyl mercaptan.D. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 358. Breath: Resp support blisters. calcium) [Note: Readily oxidized by air.9% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Air.D. Abs. Thiovanic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (4 mg/m3) [skin] (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with a strong.Gr: 1.1 Skin: Prevent skin contact BP: ? Not available. BP: ? Not available. skin.R. Mercaptoacetic acid. Con Skin: Water flush immed SY: Irrit eyes.Gr: 1.6 Skin: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 92. gasping respirations. disagreeable odor characteristic of mercaptans. convuls Swallow: Medical attention immed TO: Eyes. Ing. resp sys 4.10 VP: 0. 2-Thioglycolic acid. skin.08% Wash skin: N. 1.R. Ing.CAS#: RTECS#: IDLH: Formula: GP3150000 N. Sp. [CH3(OH)C6H2C(CH3)3]2S 96-69-5 Conversion: DOT: Synonyms/Trade Names: 4. resp sys Thioglycolic acid 306 . skin burns. corn damage. Fl. skin. in animals: lass. strong oxidizers. Sol: 0.

P: ? PaprOvHie*/ScbaF/SaF Change: Daily IP: ? §: ScbaF:Pd. resp sys Swallow: Medical attention immed Thionyl chloride Formula: CAS#: RTECS#: IDLH: C6H12N2S4 137-26-8 JO1400000 100 mg/m3 Conversion: DOT: 2771 151 Synonyms/Trade Names: bis(Dimethylthiocarbamoyl) disulfide. eye.87 mg/m3 DOT: 1836 137 Synonyms/Trade Names: Sulfinyl chloride. strong acids. muc memb. skin. Ing.] Exposure Routes. [Note: Fumes form when exposed to moist air. skin burns Breath: Resp support TO: Eyes. Sulfurous oxychloride.P: NA Remove: When wet or contam IP: ? Change: N.Pp:AScba Sp.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Prevent skin contact MW: 240. Conversion: 1 ppm = 4.003% 100 mg/m3: Sa:Cf*/CcrFOv100/GmFOv100/ Remove: When wet or contam Fl. resp sys. acids.29 Escape: GmFOv100/ScbaE VP: 0. [Note: Commercial pesticide products may be dyed blue. oxidizable materials Exposure Routes. Ing. Antabuse-like effects Breath: Resp support TO: Eyes. Thionyl dichloride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 1 ppm (5 mg/m3) OSHA PEL†: none None available Physical Description: Colorless to yellow to reddish liquid with a pungent odor like sulfur dioxide.000008 mmHg MLT: 312°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers.Formula: CAS#: RTECS#: IDLH: SOCl2 7719-09-7 XM5150000 N. skin. skin. Eyes: Prevent eye contact Sol: Reacts Wash skin: When contam Fl. crystalline solid with a characteristic odor. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.4 50 mg/m3: CcrOv95*/Sa* Eyes: Prevent eye contact BP: Decomposes Wash skin: When contam Sol: 0. Sulfur chloride oxide. Con Skin: Water flush immed SY: Irrit eyes. Con Skin: Soap wash prompt SY: Irrit eyes.Pp/SaF:Pd.Gr: 1.0 Skin: Prevent skin contact BP: 169°F Not available. CNS Swallow: Medical attention immed Thiram T 307 . skin. Symptoms.D.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 119. ammonia. Sulfurous dichloride. Sp.R. alkalis.64 Provide: Eyewash VP(70°F): 100 mmHg FRZ: -156°F Quick drench UEL: NA LEL: NA Noncombustible Liquid Incompatibilities and Reactivities: Water. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. chloryl perchlorate [Note: Reacts violently with water to form sulfur dioxide & hydrogen chloride. muc memb.Gr: 1. derm. Symptoms. Tetramethylthiuram disulfide Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): 3 NIOSH 5005 OSHA PEL: TWA 5 mg/m Physical Description: Colorless to yellow.

Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 118. cough. skin.Pp §: ScbaF:Pd. ID206 tin oxides. para with Skin: Soap wash immed Breath: Resp support musc twitch Swallow: Medical attention immed TO: Eyes.1 mg/m3 [*Note: The PEL applies to all organic tin compounds. [Note: Also see specific listing for Cyhexatin. Tin powder Exposure Limits: Measurement Methods NIOSH REL*: TWA 2 mg/m3 (see Table 1): 3 OSHA PEL*: TWA 2 mg/m NIOSH 7300. Con Skin: Water flush immed SY: Irrit eyes. Sol: Insoluble Wash skin: N. abdom pain. as Sn) Formula: CAS#: RTECS#: IDLH: 25 mg/m3 (as Sn) T Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific organic tin compound. Symptoms. urine retention.] Physical Description: Appearance and odor vary depending upon the specific organic tin compound. focal anes. Sp.Formula: CAS#: RTECS#: IDLH: Sn 7440-31-5 XP7320000 100 mg/m3 (as Sn) Conversion: DOT: Synonyms/Trade Names: Metallic tin. Abs. Fl.Pp:AScba Escape: GmFOv100/ScbaE Incompatibilities and Reactivities: Varies First Aid (see Table 6): Exposure Routes. paresis. skin. 5 mg/m3: CcrFOv100/GmFOv100/ compound.R. malleable.Pp:AScba MLT: 449°F Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid. Target Organs (see Table 5): Eye: Irr immed ER: Inh. blood 308 . Symptoms. diarr. vomit. kidney damage TO: Eyes. skin. in animals: hemolysis.] NIOSH 5504 OSHA PEL*: TWA 0.5 mg/m3: Sa:Cf/PaprOvHie depending upon the specific tin compound.Gr: 7. Tin flake. turpentine.R. pruritus. kidneys. psycho-neurologic dist. skin.R. resp sys. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. PaprTOvHie/SaT:Cf/ScbaF/SaF 25 mg/m3: SaF:Pd. urinary tract. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Properties vary depending Recommendations regarding 1 mg/m3: CcrOv95/Sa personal protective clothing vary upon the specific organic 2. Con Eye: Irr immed SY: Irrit eyes.] Physical Description: Gray to almost silver-white. 7301.R.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: TWA 0.1 mg/m3 [skin] [*Note: The REL applies to all organic tin compounds except Cyhexatin. ductile. but powdered form may ignite. IP: NA 50 mg/m3: Sa:Cf*/PaprHie* Change: N. liver. head.7 NIOSH/OSHA Skin: N.R.Pp/SaF:Pd. BP: 4545°F 10 mg/m3: Qm* Eyes: N. skin Breath: Resp support Swallow: Medical attention immed burns. Incompatibilities and Reactivities: Chlorine. in animals: vomit. Ing. CNS. Tin metal.Pp/SaF:Pd. dizz. hepatic nec. sore throat. acids. 7303 [*Note: The REL and PEL also apply to other inorganic tin compounds (as Sn) except OSHA ID121. resp sys.P: NA 20 mg/m3: 95XQ*/Sa* Remove: N. lustrous solid.28 100 mg/m3: 100F/ScbaF/SaF VP: 0 mmHg (approx) §: ScbaF:Pd. resp sys Tin Tin (organic compounds. resp sys. alkalis Exposure Routes.

Sp.P: NA Remove: N. Eyes: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 150.R.R. IP: NA Change: N.Gr: 6. Con Breath: Fresh air SY: Stannosis (benign pneumoconiosis): dysp. 7303 OSHA PEL†: none Physical Description: Brownish-black powder. decr pulm func TO: Resp sys Tin(II) oxide (as Sn) Formula: CAS#: RTECS#: IDLH: SnO2 18282-10-5 XQ4000000 N. Symptoms. 7303 OSHA PEL†: none Physical Description: White or slightly gray powder.R.Formula: CAS#: RTECS#: IDLH: SnO 21651-19-4 XQ3700000 N. Fl.7 Skin: N. decr pulm func TO: Resp sys Tin(IV) oxide (as Sn) T 309 . Symptoms.Gr: 6.D. White tin oxide [Note: Also see specific listing for Tin(II) oxide (as Sn).R. 7301.7 Skin: N.R. IP: NA Change: N. Eyes: N. Fl. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 134.R. BP: Decomposes Not available.R. BP: Decomposes Not available.P: NA Remove: N. Stannic oxide.D. Tin protoxide [Note: Also see specific listing for Tin(IV) oxide (as Sn).] Exposure Limits: Measurement Methods NIOSH REL: TWA 2 mg/m3 (see Table 1): NIOSH 7300. Con Breath: Fresh air SY: Stannosis (benign pneumoconiosis): dysp. Sol: Insoluble Wash skin: N.95 VP: 0 mmHg (approx) MLT: 2966°F (Decomposes) UEL: NA LEL: NA Incompatibilities and Reactivities: Chlorine trifluoride Exposure Routes. Sol: Insoluble Wash skin: N.3 VP: 0 mmHg (approx) MLT(600 mmHg): 1976°F (Decomposes) UEL: NA LEL: NA Incompatibilities and Reactivities: None reported Exposure Routes.R.R.] Exposure Limits: Measurement Methods NIOSH REL: TWA 2 mg/m3 (see Table 1): NIOSH 7300. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Sp. Conversion: DOT: Synonyms/Trade Names: Stannic dioxide. Conversion: DOT: Synonyms/Trade Names: Stannous oxide. 7301.

3. Ing.3'-Dimethylbenzidine.Pp/SaF:Pd. Sol: Insoluble Escape: 100F/ScbaE Wash skin: N. [carc] Skin: Soap flush immed TO: Eyes. resp sys.Pp/SaF:Pd.26 VP: 0 mmHg (approx) MLT: 3326-3362°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. [carc] TO: Resp sys [in animals: lung tumors] Titanium dioxide T Formula: CAS#: RTECS#: IDLH: C14H16N2 119-93-7 DD1225000 Ca [N. Fl.R.3'-dimethylbiphenyl.Pp:AScba Eyes: Prevent eye contact Sol: 0. nose. IP: NA Change: Daily Sp. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 79.02 mg/m [60-minute] [skin] OSHA 71 See Appendix A See Appendix C OSHA PEL: See Appendix C Physical Description: White to reddish crystals or powder.Gr: 4.4'-Diamino-3. Symptoms.R. [Note: Darkens on exposure to air. Titanium peroxide Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH S385 (II-3) See Appendix A 3 OSHA PEL†: TWA 15 mg/m Physical Description: White. 3. Often used in paste or wet cake form. kidneys [in animals: liver.R. liver. odorless powder. Con Eye: Irr immed SY: Irrit eyes. kidney damage. Abs.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 212.9 NIOSH Skin: N. Used as a basis for many dyes.P: ? Remove: When wet or contam IP: ? Change: Daily Sp.3'-Dimethyl-4. Symptoms.1% Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Fl. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Diaminoditolyl. in animals: liver. Target Organs (see Table 5): First Aid (see Table 6): Breath: Resp support ER: Inh SY: Lung fib.Pp:AScba Eyes: N.] Conversion: DOT: Synonyms/Trade Names: 4.Gr: ? Provide: Eyewash VP: ? MLT: 264°F Quick drench UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. BP: 4532-5432°F ¥: ScbaF:Pd.D.R.P: NA Remove: N. Titanium oxide. bladder & Breath: Resp support Swallow: Medical attention immed mammary gland tumors] o-Tolidine 310 .Formula: CAS#: RTECS#: IDLH: TiO2 13463-67-7 XR2275000 Ca [5000 mg/m3] Conversion: DOT: Synonyms/Trade Names: Rutile.4'-diphenyldiamine. 3.3'-Tolidine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 5013 C 0.3 NIOSH Skin: Prevent skin contact BP: 572°F ¥: ScbaF:Pd.

blood. resp sys. tacar. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. derm.4-TDA) 95-80-7 (2.] XS9625000 (2. lac.1 NIOSH Skin: Prevent skin contact BP: 232°F 500 ppm: CcrOv*/PaprOv*/ Eyes: Prevent eye contact Sol(74°F): 0.87 VP: 21 mmHg FRZ: -139°F UEL: 7. 4000 ST 150 ppm (560 mg/m ) OSHA 111 OSHA PEL†: TWA 200 ppm C 300 ppm 500 ppm (10-minute maximum peak) Physical Description: Colorless liquid with a sweet.1% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. head.Gr: 0.07% Wash skin: When contam Fl. 3800. bluish skin.4-TDA) Conversion: DOT: 1709 151 (2. Phenyl methane. conf.4-TDA. Symptoms. Methylphenylene diamine.Gr: 1. Abs. [carc] TO: Eyes.Formula: CAS#: RTECS#: IDLH: C6H5CH3 108-88-3 XS5250000 500 ppm Conversion: 1 ppm = 3.2 (see Table 2): NIOSH BP: 558°F Skin: Prevent skin contact ¥: ScbaF:Pd. 1501. Toluenediamine isomers.4-Toluenediamine) Synonyms/Trade Names: Diaminotoluene. skin. resp sys.D. skin & mammary gland tumors] First Aid (see Table 6): Eye: Irr immed Skin: Water flush immed Breath: Resp support Swallow: Medical attention immed 311 . Con Eye: Irr immed SY: Irrit eyes. anxi. liver. liver. Sp. Ing.05 (Liquid at 212°F) Change: Daily VP(224°F): 1 mmHg Provide: Eyewash MLT: 210°F Quick drench UEL: ? LEL: ? Incompatibilities and Reactivities: None reported Combustible Solid Toluenediamine Formula: CH3C6H3(NH2)2 T Exposure Routes. benzene-like odor. Symptoms. Toluol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 100 ppm (375 mg/m3) 3 NIOSH 1500. ataxia. insom. nose.Pp/SaF:Pd. kidney damage Swallow: Medical attention immed TO: Eyes. lass. needle-shaped crystals or powder. pares.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 122. euph. Ing. [Note: Tends to darken on storage and exposure to air. cyan. methemo.Pp/SaF:Pd.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca (all isomers) NIOSH 5516 See Appendix A OSHA 65 OSHA PEL: none Physical Description: Colorless to brown. Tolylenediamine [Note: Various isomers of TDA exist. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 92. Methyl benzol. pungent. convuls.82 eV Escape: GmFOv/ScbaE Change: N. dizz.R. dilated pupils. liver inj. Abs. derm. skin. Properties given are for 2. liver [in animals: liver. vomit.Pp:AScba Sol: Soluble Eyes: Prevent eye contact Escape: GmFOv/ScbaE Fl. kidneys Toluene RTECS#: CAS#: IDLH: XS9445000 25376-45-8 Ca [N.1% LEL: 1.P: 40°F GmFOv/Sa*/ScbaF §: ScbaF:Pd. dizz. head. resp depres.P: 300°F Wash skin: When contam/Daily IP: ? Remove: When wet or contam Sp. skin. Skin: Soap wash prompt Breath: Resp support musc ftg. CVS. throat. nau. lass.77 mg/m3 DOT: 1294 130 Synonyms/Trade Names: Methyl benzene. nose. Target Organs (see Table 5): ER: Inh.Pp:AScba Remove: When wet (flamm) IP: 8. TDA. CNS. Con SY: Irrit eyes.

R. dysp. 2.Gr: 0. Breath: Resp support retster soreness. chest pain.4-diisocyanate T Formula: CAS#: RTECS#: IDLH: CH3C6H4NH2 108-44-1 XU2800000 N. bases & amines (may cause foam & spatter).22 Provide: Eyewash VP(77°F): 0. Symptoms. pulm Swallow: Medical attention immed edema. Con Eye: Irr immed SY: Irrit eyes. anemia. mammary gland. meta-Toluidine.2 Skin: Prevent skin contact BP: 397°F Not available. 33.D.14 mg/m ) Physical Description: Colorless to pale-yellow solid or liquid (above 71°F) with a sharp.4-TDI. abdom pain. bron.5 ppm] Conversion: 1 ppm = 7. vomit. water. [Note: Used as a basis for many dyes. Ing. choke.13 mg/m3 DOT: 2078 156 Synonyms/Trade Names: TDI. Con Skin: Soap wash immed SY: Irrit eyes. pungent odor.02 ppm (0. derm. liver. lac. 3-Methylbenzenamine.Formula: CAS#: RTECS#: IDLH: CH3C6H3(NCO)2 584-84-9 CZ6300000 Ca [2. skin. 1-Aminophenylmethane. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Target Organs (see Table 5): Eye: Irr immed ER: Inh.50 eV Change: N. nau.999 VP(106°F): 1 mmHg FRZ: -23°F UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Oxidizers. skin sens.4-Toluene diisocyanate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 2535. methemo. Conversion: DOT: 1708 153 Synonyms/Trade Names: 3-Amino-1-methylbenzene.2 NIOSH Skin: Prevent skin contact BP: 484°F ¥: ScbaF:Pd. CVS m-Toluidine 312 . resp sys [in animals: pancreas. Abs. circulatory sys & skin tumors] Toluene-2.] First Aid (see Table 6): Exposure Routes. derm. blood. [carc] TO: Eyes. hema. nau.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 107. nose.Gr: 1. amine-like odor. Ing. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 174. Symptoms. lass Swallow: Medical attention immed TO: Eyes. Skin: Soap wash immed Breath: Resp support convuls. Eyes: Prevent eye contact Sol: 2% Wash skin: When contam Fl. m-Tolylamine Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): OSHA PEL†: none NIOSH 2002 OSHA 73 Physical Description: Colorless to light-yellow liquid with an aromatic. acids.9% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. 2. 42 OSHA PEL†: C 0. skin.P: 187°F Remove: When wet or contam IP: 7. 3-Toluidine. 3-Methylaniline.5% LEL: 0. low BP. 5525 See Appendix A 3 OSHA 18. paroxysmal cough.Pp:AScba Eyes: Prevent eye contact Sol: Insoluble Escape: GmFOv/ScbaE Wash skin: When contam/Daily Fl. conj. alcohols [Note: Reacts slowly with water to form carbon dioxide and polyureas. vomit.01 mmHg MLT: 71°F Quick drench UEL: 9. cyan. skin. asthma. m-Aminotoluene. acids Exposure Routes. skin. 5522.Pp/SaF:Pd. 5521.P: 260°F Remove: When wet or contam IP: ? Change: Daily Sp. Sp. bronchospasm. throat.

Pp/SaF:Pd. drow. 4-Toluidine. nau.P: 185°F Remove: When wet or contam IP: 7. derm.Gr: 1. 8317 See Appendix A 3 OSHA 73 OSHA PEL: TWA 5 ppm (22 mg/m ) [skin] Physical Description: Colorless to pale-yellow liquid with an aromatic.50 eV Provide: Eyewash Sp.D. 2-Methylaniline. vomit. anemia. 2017. Sp. aniline-like odor. dizz. skin. micro hema.05 VP(108°F): 1 mmHg Quick drench MLT: 111°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Oxidizers. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. acids Exposure Routes. ortho-Toluidine.3 mmHg FRZ: 6°F Quick drench UEL: ? LEL: ? Class IIIA Combustible Liquid Incompatibilities and Reactivities: Strong oxidizers. Ing.38 mg/m3 DOT: 1708 153 Synonyms/Trade Names: o-Aminotoluene. skin.Pp:AScba Eyes: Prevent eye contact BP: 393°F Escape: GmFOv100/ScbaE Wash skin: When contam/Daily Sol: 0. [carc] Swallow: Medical attention immed TO: Eyes.] Conversion: DOT: 1708 153 Synonyms/Trade Names: 4-Aminotoluene. CVS [bladder cancer] o-Toluidine Formula: CAS#: RTECS#: IDLH: CH3C6H4NH2 106-49-0 XU3150000 Ca [N. low BP. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 107.R.Pp:AScba Eyes: Prevent eye contact Sol: 2% Escape: GmFOv/ScbaE Wash skin: When contam Fl. anoxia. hema.P: 188°F Change: Daily IP: 7. head. [Note: Used as a basis for many dyes. para-Toluidine. [carc] Swallow: Medical attention immed TO: Eyes.Formula: CAS#: RTECS#: IDLH: CH3C6H4NH2 95-53-4 XU2975000 Ca [50 ppm] Conversion: 1 ppm = 4.2 ¥: ScbaF:Pd.Gr: 1. skin.2 NIOSH Skin: Prevent skin contact BP: 392°F ¥: ScbaF:Pd. Abs. lass. CVS [in animals: liver tumors] p-Toluidine T 313 . kidneys. Symptoms.Pp/SaF:Pd. cyan. Con Eye: Irr immed SY: Irrit eyes. bases Exposure Routes. 4-Methylaniline. lass. Con SY: Irrit eyes.01 Provide: Eyewash VP: 0. liver. 2-Aminotoluene. 1-Methyl-2-aminobenzene. nitric acid. 4-Methylbenzenamine. o-Tolylamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca [skin] NIOSH 2002. derm. Skin: Soap wash immed Breath: Resp support convuls.44 eV Change: N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 107. Abs. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. Symptoms. p-Tolylamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 2002 See Appendix A OSHA 73 OSHA PEL†: none Physical Description: White solid with an aromatic odor.7% Remove: When wet or contam Fl. blood. Ing. o-Methylaniline. methemo. blood. Skin: Soap wash immed Breath: Resp support eye burns. cyan.

R. oxidizers.6% 5 ppm: Sa:Cf Wash skin: When contam Fl. throat. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. eye. vomit. skin burns. Con Eye: Irr immed SY: Irrit eyes.62 Provide: Eyewash VP(124°F): 1 mmHg MLT: 136°F Quick drench UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Moisture.5 mg/m3) (see Table 1): 3 NIOSH 5034 OSHA PEL†: TWA 5 mg/m Physical Description: Colorless to pale-yellow. resp sys. skin. derm. strong oxidizers [Note: Decomposes on heating to form phosgene & hydrogen chloride.D. moist air Exposure Routes. Trichloroethanoic acid Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (7 mg/m3) (see Table 1): OSHA PV2017 OSHA PEL†: none Physical Description: Colorless to white. Ing.4 Skin: Prevent skin contact BP: 388°F Not available.2 ppm (2. Symptoms. diarr Swallow: Medical attention immed TO: Eyes.] Exposure Routes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 266.98 §: ScbaF:Pd. Corrosive to metals.CAS#: RTECS#: IDLH: Formula: TC7700000 30 ppm (CH3[CH2]3O)3PO 126-73-8 Conversion: 1 ppm = 10. crystalline solid with a sharp. TBP. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. nau Breath: Resp support TO: Eyes. odorless liquid. nose. resp sys. iron. salv. cough. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl.Gr: 0. aluminum. zinc. water. skin.P(oc): 295°F 10 ppm: ScbaF/SaF Remove: When wet or contam IP: ? 30 ppm: SaF:Pd. Tributyl ester of phosphoric acid. Con Skin: Soap wash prompt SY: Irrit eyes. pungent odor. head. resp sys.Pp Change: N.3 NIOSH Skin: Prevent skin contact BP: 552°F (Decomposes) 2 ppm: Sa Eyes: Prevent eye contact Sol: 0.Pp/SaF:Pd.P: NA Remove: When wet or contam IP: ? Change: Daily Sp. dysp. Ing. CCl3COOH Conversion: 1 ppm = 6.Gr: 1. skin.89 mg/m3 DOT: Synonyms/Trade Names: Butyl phosphate.004 mmHg Escape: GmFOv100/ScbaE FRZ: -112°F UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Alkalis. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 163. Sp. Symptoms. 2564 153 (solution) Synonyms/Trade Names: TCA. delayed Skin: Water flush immed Breath: Resp support pulm edema.Pp:AScba VP(77°F): 0. skin. GI tract Trichloroacetic acid 314 . resp sys Swallow: Medical attention immed Tributyl phosphate T CAS#: RTECS#: IDLH: Formula: 76-03-9 AJ7875000 N.68 mg/m3 DOT: 1839 153 (solid). Tri-n-butyl phosphate Exposure Limits: Measurement Methods NIOSH REL: TWA 0.

P: ? Remove: When wet or contam IP: 11. CNS. steam Combustible Solid 1. Conversion: 1 ppm = 7. Symptoms.44 Provide: Eyewash VP: 19 mmHg FRZ: -34°F Quick drench UEL: 15. kidney damage.Pp/SaF:Pd.46 mg/m 3 Formula: CHCl2CH2Cl DOT: CAS#: 79-00-5 RTECS#: KJ3150000 IDLH: Ca [100 ppm] Synonyms/Trade Names: Ethane trichloride. skin.D.5% Class IIIB Combustible Liquid Incompatibilities and Reactivities: Acids. Con Skin: Soap wash prompt SY: Irrit eyes.003% Eyes: Prevent eye contact Fl.Formula: CAS#: RTECS#: IDLH: C6H3Cl3 120-82-1 DC2100000 N.1. kidneys [in animals: liver cancer] Swallow: Medical attention immed T 315 .4% Escape: GmFOv/ScbaE Wash skin: When contam Fl.4-Trichlorobenzene Exposure Routes.6% LEL(302°F): 2. forms dense soot. liver. Incompatibilities and Reactivities: Strong oxidizers & caustics.42 mg/m3 DOT: 2321 153 (liquid) Synonyms/Trade Names: unsym-Trichlorobenzene. derm. oxidizers. Sp. β-Trichloroethane. Ing. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Abs.5% LEL: 6% Combustible Liquid.P: 222°F Wash skin: When contam IP: ? Remove: When wet or contam Sp. 1. magnesium powders. in animals: liver.Gr: 1.4 NIOSH Skin: Prevent skin contact BP: 237°F ¥: ScbaF:Pd.4-Trichlorobenzol Exposure Limits: Measurement Methods NIOSH REL: C 5 ppm (40 mg/m3) (see Table 1): NIOSH 5517 OSHA PEL†: none Physical Description: Colorless liquid or crystalline solid (below 63°F) with an aromatic odor. [carc] Breath: Resp support TO: Eyes.2.R. chemically-active metals (such as aluminum. nose.2-Trichloroethane Conversion: 1 ppm = 5.Gr: 1. resp sys. liver.00 eV Change: N. repro sys First Aid (see Table 6): Eye: Irr immed Skin: Soap wash Breath: Resp support Swallow: Medical attention immed 1.R. Abs. chloroform-like odor. Symptoms. Sol: 0.45 Change: N. sodium & potassium) First Aid (see Table 6): Exposure Routes. possible terato effects TO: Eyes. VP: 1 mmHg FRZ: 63°F UEL(302°F): 6. resp sys. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 181.2. acid fumes. Ing. kidney damage. muc memb. skin.Pp:AScba Eyes: Prevent eye contact Sol: 0. liver. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 133. Con SY: Irrit eyes. CNS depres. Target Organs (see Table 5): ER: Inh. Vinyl trichloride Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 1003 TWA 10 ppm (45 mg/m ) [skin] OSHA 11 See Appendix A See Appendix C (Chloroethanes) OSHA PEL: TWA 10 ppm (45 mg/m3) [skin] Physical Description: Colorless liquid with a sweet.4 (see Table 2): BP: 416°F Skin: Prevent skin contact Not available.

resp sys. jaun.Gr: 1. Symptoms. Incompatibilities and Reactivities: Strong caustics & alkalis. liver inj. lass. dizz. Con Skin: Soap wash SY: Anor. Symptoms. [carc] TO: Eyes. Ing. heart. drow. Skin: Soap wash prompt Breath: Resp support vomit. nau. head. Seekay wax Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 [skin] (see Table 1): 3 NIOSH S128 (II-2) OSHA PEL: TWA 5 mg/m [skin] Physical Description: Colorless to pale-yellow solid with an aromatic odor. titanium & beryllium) Exposure Routes. chemically-active metals (such as barium. lithium.P(oc): 392°F §: ScbaF:Pd.1% Escape: GmFOv/ScbaE Wash skin: When contam Fl.5 NIOSH/OSHA Skin: Prevent skin contact BP: 579-669°F 50 mg/m3: ScbaF/SaF Eyes: Prevent eye contact Sol: Insoluble Wash skin: When contam Fl. Abs. vis dist. skin.Pp/SaF:Pd. card arrhy. kidneys. magnesium.Pp:AScba Eyes: Prevent eye contact Sol: 0. nau. liver. Trichloroethene. sodium.45 eV Change: N.Gr: 1.46 Provide: Eyewash VP: 58 mmHg FRZ: -99°F Quick drench UEL(77°F): 10. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp:AScba Remove: When wet or contam IP: ? Escape: GmFOv100/ScbaE Change: Daily Sp. TCE. Con SY: Irrit eyes.58 VP: <1 mmHg See Appendix F MLT: 199°F UEL: ? LEL: ? Combustible Solid Incompatibilities and Reactivities: Strong oxidizers Exposure Routes. pares. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 131.Pp/SaF:Pd. dizz. CNS [in animals: Swallow: Medical attention immed liver & kidney cancer] Trichloroethylene T Formula: CAS#: RTECS#: IDLH: C10H5Cl3 1321-65-9 QK4025000 See Appendix F Conversion: DOT: Synonyms/Trade Names: Halowax®.R.P: ? Remove: When wet or contam IP: 9. skin. tremor. derm. but burns with difficulty.4 NIOSH Skin: Prevent skin contact BP: 189°F ¥: ScbaF:Pd. Abs. liver inj Breath: Resp support TO: Liver Swallow: Medical attention immed Trichloronaphthalene 316 . Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 231. Sp. 3800 See Appendix A OSHA 1001 See Appendix C OSHA PEL†: TWA 100 ppm C 200 ppm 300 ppm (5-minute maximum peak in any 2 hours) Physical Description: Colorless liquid (unless dyed blue) with a chloroform-like odor. Trilene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1022.Formula: CAS#: RTECS#: IDLH: ClCH=CCl2 79-01-6 KX4550000 Ca [1000 ppm] Conversion: 1 ppm = 5. Nibren wax.5% LEL(77°F): 8% Combustible Liquid. Ing.37 mg/m3 DOT: 1710 160 Synonyms/Trade Names: Ethylene trichloride. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.

but the gas will ignite calcium.6% LEL(248°F): 3. Ing.R. in animals: card Breath: Resp support arrhy. Sp. kidney inj.02% Eyes: Prevent eye contact §: ScbaF:Pd. powdered aluminum. skin. CFC-113.2-trifluoroethane T 317 . heart.2. CNS.R. nose.P: 160°F Remove: When wet or contam IP: ? Change: N. throat. zinc. liver. strong caustics & oxidizers Exposure Routes.] First Aid (see Table 6): Exposure Routes. CVS 1.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 187. Symptoms. CNS depres.03 mg/m3 DOT: Synonyms/Trade Names: Allyl trichloride.39 Provide: Eyewash VP: 3 mmHg FRZ: 6°F Quick drench UEL(302°F): 12. Ing. throat. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 147. Halocarbon 113. TTE Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1000 ppm (7600 mg/m3) 3 NIOSH 1020 ST 1250 ppm (9500 mg/m ) 3 OSHA 113 OSHA PEL†: TWA 1000 ppm (7600 mg/m ) Physical Description: Colorless to water-white liquid with an odor like carbon tetrachloride at high concentrations. in animals: liver. Breath: Resp support Swallow: Medical attention immed liver & mammary gland cancer] 1. kidneys [in animals: forestomach.3-Trichloropropane Formula: CAS#: RTECS#: IDLH: CCl2FCClF2 76-13-1 KJ4000000 2000 ppm Conversion: 1 ppm = 7. resp sys. Abs.Gr: 1. VP: 285 mmHg FRZ: -31°F UEL: ? LEL: ? Noncombustible Liquid at ordinary Incompatibilities and Reactivities: Chemically-active metals such as temperatures. Con Eye: Irr immed SY: Irrit eyes. CNS depres.Gr(77°F): 1. Target Organs (see Table 5): Eye: Irr immed ER: Inh. [Note: Decomposes if in contact with alloys containing >2% magnesium.56 Change: N.2-Trichloro-1. Glycerol trichlorohydrin. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.2% Class IIIA Combustible Liquid Incompatibilities and Reactivities: Chemically-active metals.4 (see Table 2): NIOSH/OSHA BP: 118°F Skin: Prevent skin contact 2000 ppm: Sa/ScbaF Sol(77°F): 0. Trichlorohydrin Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 NIOSH 1003 TWA 10 ppm (60 mg/m ) [skin] OSHA 7 See Appendix A 3 OSHA PEL†: TWA 50 ppm (300 mg/m ) Physical Description: Colorless liquid with a chloroform-like odor. Genetron® 113. Glyceryl trichlorohydrin. Con Skin: Soap wash prompt SY: Irrit skin. Symptoms.1% Escape: GmFOv/ScbaE Wash skin: When contam Fl.Pp/SaF:Pd.Pp:AScba Eyes: Prevent eye contact Sol: 0. derm.Pp/SaF:Pd.Pp:AScba Fl. narco Swallow: Medical attention immed TO: Skin.67 mg/m3 DOT: Synonyms/Trade Names: Chlorofluorocarbon-113. Refrigerant 113.1.4 NIOSH Skin: Prevent skin contact BP: 314°F ¥: ScbaF:Pd.99 eV Remove: When wet or contam Sp. Freon® 113. CNS. [carc] Skin: Soap wash TO: Eyes.CAS#: RTECS#: IDLH: Formula: TZ9275000 Ca [100 ppm] CH2ClCHClCH2Cl 96-18-4 Conversion: 1 ppm = 6. [Note: A gas above 118°F. drow. magnesium & beryllium and burn weakly at 1256°F.2.P: ? Wash skin: When contam Escape: GmFOv/ScbaE IP: 11.

50 eV Change: N. Fl. powdered aluminum. IP: 11. Fluorocarbon 1301.14 VP: >1 atm FRZ: -267°F UEL: NA LEL: NA Nonflammable Gas Incompatibilities and Reactivities: Chemically-active metals (such as calcium.R. resp sys. skin. Ing.R. [Note: Shipped as a liquefied compressed gas. zinc. card arrhy.73 Provide: Eyewash (>1%) VP: 54 mmHg FRZ: -175°F Quick drench (>1%) UEL: 8.000 ppm: SaT:Cf/ScbaF/SaF Remove: N.03% 40. Target Organs (see Table 5): Eye: Irr immed ER: Inh. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 101. Halocarbon 13B1.2% Class IB Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers.14 mg/m3 Synonyms/Trade Names: TEA Exposure Limits: Measurement Methods NIOSH REL: See Appendix D (see Table 1): 3 OSHA PEL†: TWA 25 ppm (100 mg/m ) NIOSH S152 (II-3) OSHA PV2060 Physical Description: Colorless liquid with a strong. kidneys Swallow: Medical attention immed Formula: (C2H5)3N DOT: 1296 132 CAS#: 121-44-8 RTECS#: YE0175000 IDLH: 200 ppm T Formula: CAS#: RTECS#: IDLH: CBrF3 75-63-8 PA5425000 40. Trifluoromonobromomethane Exposure Limits: Measurement Methods NIOSH REL: TWA 1000 ppm (6100 mg/m3) (see Table 1): 3 OSHA PEL: TWA 1000 ppm (6100 mg/m ) NIOSH 1017 Physical Description: Colorless.Triethylamine Conversion: 1 ppm = 4.Pp:AScba Wash skin: When contam Fl. liquid: frostbite Breath: Resp support TO: CNS.R.09 mg/m3 DOT: 1009 126 Synonyms/Trade Names: Bromotrifluoromethane. Monobromotrifluoromethane. Symptoms.Gr: 0.000 ppm: Sa:Cf Wash skin: N. chlorine. Freon® 13B1. skin. heart Trifluorobromomethane 318 .0% LEL: 1.R.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: Frostbite MW: 148. in animals: myocardial. Sol: 0. liver damage Skin: Soap wash immed Breath: Resp support TO: Eyes. strong acids.Pp:AScba Change: N. Refrigerant 13B1. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh.Pp/SaF:Pd. resp sys. halogenated compounds First Aid (see Table 6): Exposure Routes. Halon® 1301. Con SY: Irrit eyes.78 eV Escape: GmFOv/ScbaE Provide: Frostbite wash RGasD: 5.000 ppm Conversion: 1 ppm = 6. Abs. Con (liquid) Skin: Frostbite SY: Dizz. hypochlorite. Sp.P: NA §: ScbaF:Pd.2 OSHA Skin: Prevent skin contact BP: 193°F 200 ppm: Sa:Cf£/ScbaF/SaF Eyes: Prevent eye contact Sol: 2% §: ScbaF:Pd. Symptoms.P: 20°F Escape: GmFS/ScbaE Remove: When wet (flamm) IP: 7. ammonia-like odor. kidney. CVS.9 10. and magnesium) Exposure Routes.000 ppm: Sa Eyes: Frostbite BP: -72°F 25.Pp/SaF:Pd. odorless gas. liver.

VP(70°F): 1454 mmHg Provide: Eyewash (liquid/solution) FRZ: -179°F UEL: 11.1 (see Table 2): BP: ? Skin: Prevent skin contact Not available. Ing.. strong acids [Note: Corrosive to many metals (e. Trimellic acid anhydride [Note: TMA is also a synonym for Trimethylamine.0% Frostbite wash Flammable Gas Incompatibilities and Reactivities: Strong oxidizers (including bromine). [Note: A liquid below 37°F.6% Quick drench (liquid/solution) LEL: 2. dysp. skin.42 mg/m DOT: 1083 118 (anhydrous). musc aches.Gr: ? Change: Daily VP: 0. corn nec. nose.] First Aid (see Table 6): Exposure Routes. nose.04 mg/m3) (see Table 1): NIOSH 5036 Should be handled in the workplace as an extremely toxic substance. skin burns. resp sys.Formula: CAS#: RTECS#: IDLH: C9H4O5 552-30-7 DC2050000 N.4-Benzenetricarboxylic anhydride.] Exposure Limits: Measurement Methods NIOSH REL: TWA 0. Target Organs Eye: Irr immed (liquid/solution)/Frostbite (see Table 5): Skin: Water flush immed (liquid/solution)/Frostbite ER: Inh. cough. asthma. copper). aluminum. wheez. Swallow: Medical attention immed (solution) liquid: frostbite TO: Eyes. or 40% TMA.P: NA Wash skin: When contam IP: ? Remove: When wet or contam Sp. brass. TMA [Note: May be used in an aqueous solution (typically 25%. amine odor.] Exposure Limits: Measurement Methods NIOSH REL: TWA 10 ppm (24 mg/m3) (see Table 1): OSHA PEL†: none OSHA PV2060 ST 15 ppm (36 mg/m3) Physical Description: Colorless gas with a fishy. 30%. sodium nitrite).. BP: 37°F Sol(86°F): 48% Frostbite Eyes: Prevent eye contact (liquid/solution) Fl.1 Skin: Prevent skin contact (liquid/solution) Not available.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 59.N-Dimethylmethanamine. Target Organs (see Table 5): ER: Inh.000004 mmHg MLT: 322°F UEL: NA LEL: NA Incompatibilities and Reactivities: None reported Combustible Solid Trimellitic anhydride Exposure Routes. 1297 132 (aqueous solution) Synonyms/Trade Names: N. resp sys Trimethylamine 3 T 319 . ethylene oxide. skin. cough. resp sens. fever. throat. Con SY: Irrit eyes. mal. resp sys. skin. delayed pulm edema. pulm edema. blurred vision. rhinitis.2.P: NA (Gas) Frostbite 20°F (Liquid) Wash skin: When contam (solution) IP: 7. Con Breath: Resp support SY: Irrit eyes. TMA.09 Change: N. Sol: ? Eyes: Prevent eye contact Fl. Shipped as a liquefied compressed gas. resp sys First Aid (see Table 6): Eye: Irr immed Skin: Soap wash Breath: Resp support Swallow: Medical attention immed CAS#: RTECS#: IDLH: Formula: 75-50-3 PA0350000 N. zinc.86 mg/m3 DOT: Synonyms/Trade Names: 1. 4-Carboxyphthalic anhydride. dysp. Conversion: 1 ppm = 7.R.D.82 eV Remove: When wet (flamm) RGasD: 2. sneez TO: Eyes. nitrosating agents (e.005 ppm (0.D.g. Ing (solution). Symptoms. skin. TMAN. Symptoms. OSHA 98 OSHA PEL†: none Physical Description: Colorless solid. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 192.g. mercury. (CH3)3N Conversion: 1 ppm = 2.

bron.92 mg/m3 Synonyms/Trade Names: Hemellitol [Note: Hemimellitene is a mixture of the 1.R. Con Eye: Irr immed SY: Irrit eyes.3-Trimethylbenzene Conversion: 1 ppm = 4.48 eV Change: N. dizz. skin. Conversion: 1 ppm = 4.2. throat. Ing. colorless liquid with a distinctive.89 VP(62°F): 1 mmHg FRZ: -14°F UEL: 6.Gr: 0. T Formula: CAS#: RTECS#: IDLH: C6H3(CH3)3 95-63-6 DC3325000 N.3-isomer with up to 10% of related aromatics such as the 1.P: ? Remove: When wet or contam IP: 8. vomit. Skin: Soap wash Breath: Resp support drow. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. lass. drow. Eyes: Prevent eye contact Sol: 0. skin. chemical pneu (aspir liquid) Breath: Resp support Swallow: Medical attention immed TO: Eyes. resp sys. resp sys. hypochromic anemia. head. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 120. Symptoms.3-isomer with up to 10% of related aromatics such as the 1. chemical pneu (aspir liquid) Swallow: Medical attention immed TO: Eyes. dizz.88 VP(56°F): 1 mmHg FRZ: -77°F UEL: 6. bron.R.D. Ing. throat. Sp.P: 112°F Remove: When wet or contam IP: 8. CNS.2. resp sys.2.2. inco.2 Skin: Prevent skin contact BP: 337°F Not available.2. Pseudocumene [Note: Hemimellitene is a mixture of the 1. CNS. blood 1.2.4% LEL: 0.27 eV Change: N. nose.006% Wash skin: When contam Fl. conf. Eyes: Prevent eye contact Sol: Low Wash skin: When contam Fl. nose. nitric acid Exposure Routes. Skin: Soap wash head. nau. psi-Cumene. hypochromic anemia. Target Organs (see Table 5): Eye: Irr immed ER: Inh.1.4-Trimethylbenzene 320 . nitric acid First Aid (see Table 6): Exposure Routes. skin.8% Flammable Liquid Incompatibilities and Reactivities: Oxidizers. lass.Gr: 0. conf. Sp.6% LEL: 0. colorless liquid with a distinctive.9% Class II Flammable Liquid Incompatibilities and Reactivities: Oxidizers.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 25 ppm (125 mg/m3) OSHA PV2091 OSHA PEL†: none Physical Description: Clear.4-isomer.2 Skin: Prevent skin contact BP: 349°F Not available. inco. Symptoms. vomit. aromatic odor.92 mg/m3 DOT: Synonyms/Trade Names: Asymmetrical trimethylbenzene. nau.4-isomer. aromatic odor. skin.D. Con SY: Irrit eyes. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 120. resp sys. blood Formula: C6H3(CH3)3 DOT: CAS#: 526-73-8 RTECS#: DC3300000 IDLH: N.] Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 25 ppm (125 mg/m3) OSHA PV2091 OSHA PEL†: none Physical Description: Clear.

(CH3O)3P Conversion: 1 ppm = 5. vomit.R.Gr: 1. Eyes: Prevent eye contact Sol: 0.39 eV Change: N. inco. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 124. Target Organs (see Table 5): Eye: Irr immed ER: Inh.92 mg/m3 DOT: 2325 129 Synonyms/Trade Names: Mesitylene. Target Organs (see Table 5): Eye: Irr immed ER: Inh. resp sys. Trimethyl ester of phosphorous acid Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (10 mg/m3) (see Table 1): OSHA PEL†: none None available Physical Description: Colorless liquid with a distinctive.P: 122°F Remove: When wet or contam IP: 8. conf. Symptoms. blood 1.] First Aid (see Table 6): Exposure Routes. skin.R. nose. aromatic odor.Gr: 0. Trimethoxyphosphine. in animals: terato effects Skin: Soap flush immed Breath: Resp support TO: Eyes. Con SY: Irrit eyes.3. repro sys Swallow: Medical attention immed Trimethyl phosphite T 321 . resp sys.86 VP: 2 mmHg FRZ: -49°F UEL: ? LEL: ? Class II Flammable Liquid Incompatibilities and Reactivities: Oxidizers. Skin: Soap wash Breath: Resp support drow. Sp. derm. lass. throat.05 Provide: Quick drench VP(77°F): 24 mmHg FRZ: -108°F UEL: ? LEL: ? Class IC Flammable Liquid Incompatibilities and Reactivities: Magnesium perchlorate. Sp.2 Skin: Prevent skin contact BP: 329°F Not available. pungent odor. head. Ing.08 mg/m3 DOT: 2329 129 Synonyms/Trade Names: Methyl phosphite. skin.5-Trimethylbenzene CAS#: RTECS#: IDLH: Formula: 121-45-9 TH1400000 N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 120. colorless liquid with a distinctive. Conversion: 1 ppm = 4.D. dizz. sym-Trimethylbenzene Exposure Limits: Measurement Methods NIOSH REL: TWA 25 ppm (125 mg/m3) (see Table 1): OSHA PV2091 OSHA PEL†: none Physical Description: Clear. nitric acid First Aid (see Table 6): Exposure Routes. water [Note: Reacts (hydrolyzes) with water. Eyes: Prevent eye contact Sol: Reacts Wash skin: When contam Fl. Symptoms. upper resp sys. bron. hypochromic anemia. Symmetrical trimethylbenzene. skin. CNS.D. Ing.P: 82°F Remove: When wet (flamm) IP: ? Change: N.Formula: CAS#: RTECS#: IDLH: C6H3(CH3)3 108-67-8 OX6825000 N. skin. chemical pneu (aspir liquid) Swallow: Medical attention immed TO: Eyes. resp sys. Con SY: Irrit eyes.002% Wash skin: When contam Fl.1 Skin: Prevent skin contact BP: 232°F Not available. nau.

sens derm. Target Organs (see Table 5): Eye: Irr immed ER: Inh.Formula: CAS#: RTECS#: IDLH: CH3C6H2(NO2)3 118-96-7 XU0175000 500 mg/m3 Conversion: DOT: 1356 113 (wet) Synonyms/Trade Names: 1-Methyl-2. kidney damage. combustible materials. Ing. strong alkalis.Pp/SaF:Pd. TNT.5 mg/m3: Sa:Cf* Fl. sneez. Symptoms. heat [Note: Rapid heating will result in detonation. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 368.4. card irreg TO: Eyes. odorless solid or crushed flakes. Trinitrotoluene. peri neur. Breath: Resp support weak feet. muc memb. cyan.5 mg/m3: Sa:Cf/PaprHie Change: N. Abs.0002 mmHg §: ScbaF:Pd.4 NIOSH/OSHA Skin: Prevent skin contact BP: 770°F (Decomposes) 0. liver. sore throat. Tri-o-cresyl ester of phosphoric acid. peri neur.1 mg/m3 [skin] 3 NIOSH 5037 OSHA PEL†: TWA 0. CNS Triorthocresyl phosphate 322 .59 eV 25 mg/m3: ScbaF/SaF Change: Daily Sp.6-trinitrobenzene.Pp:AScba LEL: ? Escape: 100F/ScbaE Class IIIB Combustible Liquid Incompatibilities and Reactivities: Oxidizers First Aid (see Table 6): Exposure Routes.1 mg/m Physical Description: Colorless to pale-yellow.Pp UEL: ? §: ScbaF:Pd. Ing.20 5 mg/m3: 100F/SaT:Cf/PaprTHie/ VP(77°F): 0. leucyt. wrist drop. musc pain.Pp/SaF:Pd. Con Skin: Soap wash prompt SY: Irrit skin. ammonia. skin. pares in feet or hands.4.65 500 mg/m3: SaF:Pd.1 NIOSH Skin: Prevent skin contact BP: 464°F (Explodes) 5 mg/m3: Sa* Eyes: Prevent eye contact Sol(77°F): 0. Sol: Slight Wash skin: When contam 1 mg/m3: 95XQ/Sa Fl. kidneys 2.00002 mmHg ScbaF/SaF FRZ: 52°F 40 mg/m3: Sa:Pd. resp sys.Pp VP: 0. Trinitrotoluol Exposure Limits: Measurement Methods NIOSH REL: TWA 0.5 mg/m3: Qm Eyes: N. TOCP. blood. Abs.6-Trinitrotoluene T CAS#: RTECS#: IDLH: Formula: TD0350000 40 mg/m3 (CH3C6H40)3PO 78-30-8 Conversion: DOT: 2574 151 Synonyms/Trade Names: TCP.Pp:AScba MLT: 176°F Escape: GmFOv100/ScbaE UEL: ? LEL: ? Combustible Solid (Class A Explosive) Incompatibilities and Reactivities: Strong oxidizers. Breath: Resp support Swallow: Medical attention immed anemia.P: ? (Explodes) Remove: When wet or contam IP: 10. cramps in calves.01% Wash skin: When contam/Daily 12. Con Skin: Soap wash immed SY: GI dist.R. cough.Gr: 1. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 227. Sp. jaun. sym-Trinitrotoluene. Target Organs (see Table 5): Eye: Irr immed ER: Inh.P: 437°F Remove: When wet or contam IP: ? 2. cataract. CVS. CNS.R.Gr: 1. Tri-o-cresyl phosphate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 0. odorless liquid or solid (below 52°F). liver damage. Symptoms.] First Aid (see Table 6): Exposure Routes.5 mg/m3 [skin] (see Table 1): 3 OSHA 44 OSHA PEL†: TWA 1.5 mg/m [skin] Physical Description: Colorless to pale-yellow. para Swallow: Medical attention immed TO: PNS.

Symptoms.N-Diphenylaniline. in animals: musc weak.R.77 VP: ? MLT: 261°F UEL: ? LEL: ? Incompatibilities and Reactivities: None reported Exposure Routes. MW: 326.Gr: 1. crystalline powder with a phenol-like odor.N-Diphenylbenzenamine Exposure Limits: Measurement Methods NIOSH REL: TWA 5 mg/m3 (see Table 1): OSHA PEL†: none None available Physical Description: Colorless solid.R. (C6H5)3N Conversion: DOT: Synonyms/Trade Names: N.Pp/SaF:Pd. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.3 Skin: Prevent skin contact BP: 689°F Not available.R.R. TPP. Ing. PNS Triphenyl phosphate T 323 .Pp:AScba UEL: ? Escape: 100F/ScbaE LEL: ? Combustible Solid Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes.R. Fl.3 15 mg/m3: Qm Eyes: N. Symptoms. Target Organs (see Table 5): Breath: Resp support ER: Inh.R.Pp MLT: 120°F §: ScbaF:Pd. IP: ? 150 mg/m3: 100F/SaT:Cf/PaprTHie/ Sp.P: ? Remove: N. Con Skin: Soap wash SY: In animals: irrit skin Breath: Resp support TO: Skin Swallow: Medical attention immed Triphenylamine Formula: CAS#: RTECS#: IDLH: (C6H5O)3PO 115-86-6 TC8400000 1000 mg/m3 Conversion: DOT: Synonyms/Trade Names: Phenyl phosphate. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N.CAS#: RTECS#: IDLH: Formula: 603-34-9 YK2680000 N. Ing Swallow: Medical attention immed SY: Minor changes in blood enzymes. para TO: Blood. Eyes: Prevent eye contact Sol: Insoluble Wash skin: Daily Fl.002% 30 mg/m3: 95XQ/Sa Remove: N.29 ScbaF/SaF VP(380°F): 1 mmHg 1000 mg/m3: Sa:Pd. Triphenyl ester of phosphoric acid Exposure Limits: Measurement Methods NIOSH REL: TWA 3 mg/m3 (see Table 1): NIOSH 5038 OSHA PEL: TWA 3 mg/m3 Physical Description: Colorless. BP: 776°F Wash skin: N. Sol(129°F): 0. IP: 7.P: 428°F 75 mg/m3: Sa:Cf/PaprHie Change: N. N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 245.Gr: 0.60 eV Change: Daily Sp.D.

701°F 50 mg/m3: 100XQ/Sa/ScbaF Eyes: N. Incompatibilities and Reactivities: Bromine trifluoride.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Varies Exposure Routes.R.P: NA §: ScbaF:Pd. GI tract First Aid (see Table 6): Eye: Irr immed Skin: Water wash Breath: Resp support Swallow: Medical attention immed 324 . IP: NA Escape: 100XQ/ScbaE Change: N. resp sys.9 NIOSH Skin: N. steel-gray to tin-white solid. Con SY: Irrit eyes.D.Gr: 19. loss of appetite.R. skin.Pp:AScba Remove: N.R. Sp. Con Eye: Irr immed SY: Irrit eyes. brittle. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp/SaF:Pd. resp sys.] OSHA ID213 OSHA PEL†: none Physical Description: Hard. fluorine. Conversion: DOT: Synonyms/Trade Names: Tungsten metal. T Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific soluble tungsten compound. Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): 3 NIOSH 7074. Skin: Soap wash Breath: Fresh air nau. skin. Wolfram Exposure Limits: Measurement Methods NIOSH REL*: TWA 5 mg/m3 (see Table 1): 3 NIOSH 7074. blood changes Swallow: Medical attention immed TO: Eyes. Symptoms. skin.Formula: CAS#: RTECS#: IDLH: W 7440-33-7 YO7175000 N. resp sys.Pp/SaF:Pd.R. blood changes TO: Eyes. in animals: CNS disturbances.3 VP: 0 mmHg (approx) MLT: 6170°F UEL: NA LEL: NA Combustible in the form of finely divided powder. behavioral. resp sys. iodine pentafluoride Exposure Routes. Fl. 7300. chlorine trifluoride. Ing.D. resp failure. as W) Formula: CAS#: RTECS#: IDLH: N. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 183. BP: 10. 7300. 7301 ST 10 mg/m [*Note: The REL also applies to other insoluble tungsten compounds (as W). 7301 ST 3 mg/m OSHA ID213 OSHA PEL†: none Physical Description: Appearance and odor vary depending upon the specific soluble tungsten compound. diarr. skin. CNS. Sol: Insoluble Wash skin: N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Recommendations regarding personal Properties vary depending 10 mg/m3: 100XQ/Sa protective clothing vary depending upon upon the specific soluble 25 mg/m3: Sa:Cf the specific compound. Target Organs (see Table 5): ER: Inh. tungsten compound.R. body weight. may ignite spontaneously. Symptoms. diffuse pulm fib. 50 mg/m3: 100F/ScbaF/SaF §: ScbaF:Pd. Ing. cough. blood Tungsten Tungsten (soluble compounds.

prot. Skin: Soap wash Breath: Fresh air diffuse pulm fib. Con SY: Irrit eyes. kidneys First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed 325 . 14% Co. resp sys. Chemical & Physical Properties: Personal Protection/Sanitation Respirator Recommendations (see Tables 3 and 4): MW: 136 (approx) (see Table 2): NIOSH/OSHA BP: 309-338°F Skin: Prevent skin contact 800 ppm: Sa:Cf£/PaprOv£/CcrFOv/ Sol: Insoluble Eyes: Prevent eye contact Fl. lead dioxide Exposure Routes. 8% Ti] Exposure Limits: Measurement Methods NIOSH REL: See Appendix C OSHA PEL†: See Appendix C (see Table 1): None available Physical Description: A mixture of tungsten carbide. head.Pp:AScba Escape: 100F/ScbaE Tungsten carbide (cemented) containing Nickel: NIOSH ¥:ScbaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact Properties vary 0.Tungsten carbide (cemented) Formula: WC/Co/Ni/Ti CAS#: 1: 11107-01-0 2: 12718-69-3 3: 37329-49-0 RTECS#: 1: YO7350000 IDLH: 2: YO7525000 N.Pp/SaF:Pd.D. chlorine. 3: YO7700000 Conversion: DOT: Synonyms/Trade Names: Cemented tungsten carbide. throat. 8% Co. oxides of nitrogen.P: 95°F Wash skin: When contam GmFOv/ScbaF/SaF §: ScbaF:Pd.86 Change: N. chemical pneu (aspir liquid) TO: Eyes. nau. Spirits of turpentine. Steam distilled turpentine. 3: 78% WC. Sulfate wood turpentine. cough.25 mg Co/m3: Qm Eyes: Prevent eye contact depending upon the Wash skin: When contam/Daily (Ni) 0. LEL: 0.5 mg Co/m3: 100F/ScbaF/SaF 20 mg Co/m3: SaF:Pd.R.Pp/SaF:Pd. Con SY: Irrit eyes. Ing. Cemented WC. skin sens. loss of appetite. nau. Symptoms. Target Organs (see Table 5): ER: Inh. and sometimes other metals & metal oxides or carbides. convuls. Abs. hema. Wood turpentine Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (560 mg/m3) (see Table 1): 3 NIOSH 1551 OSHA PEL: TWA 100 ppm (560 mg/m ) Physical Description: Colorless liquid with a characteristic odor. resp sys.8% chromic anhydride. Hard metal [Note: The tungsten carbide (WC) content is generally 85-95% & the cobalt content is generally 5-15%. abdom pain. Gum turpentine. VP: 4 mmHg FRZ: -58 to -76°F UEL: ? Incompatibilities and Reactivities: Strong oxidizers. 2: 92% WC. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.Pp/SaF:Pd. chlorine trifluoride.Pp:AScba IP: ? Remove: When wet (flamm) Escape: GmFOv/ScbaE Sp.5 mg Co/m3: 95XQ*/Sa* specific mixture. nose. Remove: When wet or contam 1. chromyl chloride Class IC Flammable Liquid Turpentine 3 T Exposure Routes. resp sys. blood changes Swallow: Medical attention immed TO: Eyes.] [1: 85% WC. Turps.Pp:AScba Escape: 100F/ScbaE Incompatibilities and Reactivities: Tungsten carbide: Fluorine.Gr: 0.56 mg/m (approx) DOT: 1299 128 Synonyms/Trade Names: Gumspirits. skin. CNS. diarr. possible skin sens to cobalt. cobalt. skin. 15% Co. blood CAS#: RTECS#: IDLH: Formula: 8006-64-2 YO8400000 800 ppm C10H16 (approx) Conversion: 1 ppm = 5. skin. vomit. skin. Symptoms.25 mg Co/m3: Sa:Cf*/PaprHie*/PaprHie* Change: Daily 2. stannic chloride. Ing. dizz. nickel. kidney damage.Pp §: ScbaF:Pd.

2 mg/m None available 3 ST 0.71 mg/m3 Synonyms/Trade Names: Undecyl mercaptan Exposure Limits: Measurement Methods NIOSH REL: C 0. pyrophoric) Synonyms/Trade Names: Uranium metal: Uranium I Synonyms of other insoluble uranium compounds vary depending upon the specific compound. Con SY: Irrit eyes. lymph node damage. vomit. blood changes. dizz. kidneys. conf.R. [carc]. TO: Skin. Symptoms. resp sys. radon).Pp/SaF:Pd. Sp.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 238.0 (see Table 2): NIOSH BP: 6895°F Skin: Prevent skin contact ¥: ScbaF:Pd.Pp:AScba VP: ? Escape: GmFOv/ScbaE FRZ: 27°F UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: Oxidizers. CNS Formula: CH3(CH2)10SH DOT: 1228 131 CAS#: 5332-52-5 RTECS#: IDLH: N. Ing. bone marrow.1-Undecanethiol Conversion: 1 ppm = 7. Symptoms. Con SY: Derm. fluorine [Note: Complete coverage of uranium metal scrap with oil is essential for prevention of fire. ductile. head.Pp:AScba Sol: Insoluble Eyes: Prevent eye contact Escape: 100F/ScbaE Fl.5 ppm: Sa:Cf/PaprOv Wash skin: When contam Fl. Abs.Pp/SaF:Pd.P: NA Wash skin: When contam/Daily IP: NA Remove: When wet or contam Sp. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 188. convuls Swallow: Medical attention immed TO: Eyes.4 NIOSH Skin: Prevent skin contact BP: 495°F 5 ppm: CcrOv/Sa Eyes: Prevent eye contact Sol: Insoluble 12. especially nitric acid. resp sys. lustrous solid. Ing. Uranium (insoluble compounds. skin. Target Organs (see Table 5): ER: Inh. reducing agents.84 ScbaF/SaF §: ScbaF:Pd.5 ppm (3. MEC: 60 g/m3 Metal: Combustible Solid. strong acids & bases.. alkali metals Exposure Routes. Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 TWA 0.Gr: 0.D. kidney damage.Gr: 19.05 (metal) Change: Daily VP: 0 mmHg (approx) Provide: Eyewash MLT: 2097°F UEL: NA LEL: NA Incompatibilities and Reactivities: Carbon dioxide. lymphatic sys [lung cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed 326 . nau.P: ? 25 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) IP: ? Change: N.6 mg/m See Appendix A OSHA PEL†: TWA 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. [Note: Weakly radioactive. drow.] turnings and powder.9 mg/m3) [15-minute] (see Table 1): OSHA PEL: none None available Physical Description: Liquid. Skin: Soap wash Breath: Resp support lass. malleable.25 mg/m3 Physical Description: Metal: Silver-white.g. in animals: lung. Exposure Routes. skin. carbon tetrachloride. [carc] Potential for cancer is a result of alpha-emitting properties & radioactive decay products (e. as U) Formula: U (metal) CAS#: 7440-61-1 (metal) RTECS#: YR3490000 (metal) IDLH: Ca [10 mg/m3 (as U)] U Conversion: DOT: 2979 162 (metal.

cough. vomit. radon). kidneys. Valeraldehyde. pungent odor. Valeric aldehyde Exposure Limits: Measurement Methods NIOSH REL: TWA 50 ppm (175 mg/m3) (see Table 1): NIOSH 2018. Quick drench Incompatibilities and Reactivities: Uranyl nitrate: combustibles. nau.05 mg/m Physical Description: Appearance and odor vary depending upon the specific soluble uranium compound. conj. Sp. blood. [carc] Potential for cancer is a result of alpha-emitting Swallow: Medical attention properties & radioactive decay products (e.g.53 mg/m3 DOT: 2058 129 Synonyms/Trade Names: Amyl aldehyde. 2536 See Appendix C (Aldehydes) OSHA PEL†: none OSHA 85 Physical Description: Colorless liquid with a strong. CH3(CH2)3CHO Conversion: 1 ppm = 3.Gr: 0.Pp:AScba upon the specific soluble Wash skin: When contam/Daily Escape (Halides): GmFAg100/ScbaE uranium compound.Pp/SaF:Pd. Ing.82 eV Change: N.81 Provide: Eyewash VP: 26 mmHg FRZ: -133°F Quick drench UEL: ? LEL: ? Class IB Flammable Liquid Incompatibilities and Reactivities: None reported Exposure Routes. chest rales. resp sys Swallow: Medical attention immed n-Valeraldehyde V 327 . Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 TWA 0. high BUN.P: 54°F Remove: When wet (flamm) IP: 9. Uranium hexafluoride: water First Aid (see Table 6): Exposure Routes. lymphatic sys. acrid. liver. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. skin.D. as U) Formula: CAS#: RTECS#: IDLH: Ca [10 mg/m3 (as U)] Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific soluble uranium compound.05 mg/m None available See Appendix A 3 OSHA PEL: TWA 0. Target Organs (see Table 5): Eye: Irr immed ER: Inh. TO: Resp sys.2 Skin: Prevent skin contact BP: 217°F Not available. RBC. Valeral. skin burns. Symptoms. skin. Remove: When wet or contam Escape (Non-halides): 100F/ScbaE Change: Daily Provide: Eyewash (UF6). casts Skin: Water flush immed Breath: Resp support in urine. Pentanal. throat Breath: Resp support TO: Eyes. Con Skin: Soap flush immed SY: Irrit eyes. Ing.R. Eyes: Prevent eye contact Sol: Slight Wash skin: When contam Fl. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical (see Table 2): (see Tables 3 and 4): Properties: NIOSH Properties vary depending Skin: Prevent skin contact Eyes: Prevent eye contact ¥: ScbaF:Pd. prot. nose.Uranium (soluble compounds. short breath. Symptoms. bone marrow [lung cancer] immed CAS#: RTECS#: IDLH: Formula: 110-62-3 YV3600000 N.. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 86. skin. Con SY: Lac.

Other synonyms vary depending upon the specific vanadium compound. Measurement Methods Exposure Limits: (see Table 1): NIOSH REL*: C 0.R.Pp Sp.8% Wash skin: When contam Fl. Vanadium pentaoxide dust. fine rales.Pp VP: 0 mmHg (approx) §: ScbaF:Pd. throat.Gr: 3. green tongue. dysp. Vanadic anhydride dust.9 NIOSH (as V) Skin: Prevent skin contact BP: 3182°F (Decomposes) 0.1 mg V2O5/m3 OSHA ID185 Physical Description: Finely divided particulate dispersed in air. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 181. wheez. [*Note: The REL applies to all vanadium compounds except Vanadium metal and 7504.Formula: CAS#: RTECS#: IDLH: V2O5 1314-62-1 YW2450000 35 mg/m3 (as V) Conversion: DOT: 2862 151 Synonyms/Trade Names: Divanadium pentoxide dust. but may increase intensity of fire when in contact with combustible materials. odorless flakes dispersed in air. chlorine trifluoride Exposure Routes. chlorine trifluoride First Aid (see Table 6): Exposure Routes.R. dysp Swallow: Medical attention immed TO: Eyes. Con Eye: Irr immed SY: Irrit eyes. eczema TO: Eyes. 7303.8% 1.5 mg V2O5/m (resp) Physical Description: Yellow-orange powder or dark-gray. Skin: Soap wash prompt Breath: Resp support cough. bron. green tongue. resp sys Vanadium fume 328 .25 mg/m3: Sa:Cf*/PaprHie* Remove: N. resp sys Vanadium dust V Formula: CAS#: RTECS#: IDLH: V2O5 1314-62-1 YW2460000 35 mg/m3 (as V) Conversion: DOT: 2862 151 Synonyms/Trade Names: Divanadium pentoxide fume. Target Organs (see Table 5): Breath: Resp support ER: Inh.Pp:AScba VP: 0 mmHg (approx) Escape: 100F/ScbaE MLT: 1274°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Lithium. bron. skin. Vanadium pentaoxide fume.Gr: 3. Sol: 0.P: NA 1.Pp:AScba MLT: 1274°F Escape: 100F/ScbaE UEL: NA LEL: NA Noncombustible Solid. 7504 OSHA PEL†: C 0.R. Vanadium oxide dust. MW: 181. metallic taste. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH (as V) Skin: N. fine rales. Exposure Limits: Measurement Methods NIOSH REL: C 0. Vanadium oxide fume.Pp/SaF:Pd.P: NA 2. throat. eczema. skin. Other synonyms vary depending upon the specific vanadium compound. Fl.9 0.R. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.R.25 mg/m3: Sa:Cf*/PaprHie* Remove: When wet or contam IP: NA 2. Incompatibilities and Reactivities: Lithium. Con SY: Irrit eyes. Ing. 7303. skin. 7301.36 §: ScbaF:Pd. metallic taste.5 mg/m3: 100XQ*/Sa* Eyes: N. Symptoms.R. Symptoms.05 mg V/m3 [15-minute] NIOSH 7300.5 mg/m3: 100F/PaprTHie*/ScbaF/SaF Change: N.Pp/SaF:Pd. Vanadic anhydride fume.05 mg V/m3 [15-minute] (see Table 1): NIOSH 7300. wheez.36 35 mg/m3: SaF:Pd. cough.5 mg/m3: 100F/PaprTHie*/ScbaF/SaF Change: N.5 mg/m3: 100XQ*/Sa* Eyes: Prevent eye contact Sol: 0. BP: 3182°F (Decomposes) Wash skin: N. Sp.] 3 OSHA ID185 OSHA PEL†: C 0. 7301. IP: NA 35 mg/m3: SaF:Pd. 9102 Vanadium carbide (see Ferrovanadium dust).

Sp.P: 323-540°F Remove: N. bases. cough.Gr: 0. skin blisters Swallow: Medical attention immed TO: Eyes.. Vinyl acetate monomer.R. oxidizers. Conversion: DOT: Synonyms/Trade Names: Vegetable mist Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) 3 NIOSH 0500. Con Breath: Fresh air SY: Irrit eyes. hydroquinone or diphenylamine) to prevent polymerization.4% LEL: 2.R.P: 18°F Change: N.1 40 ppm: CcrOv*/Sa* Eyes: Prevent eye contact BP: 162°F 100 ppm: Sa:Cf*/PaprOv* Wash skin: When contam Sol: 2% 200 ppm: CcrFOv/GmFOv/PaprTOv*/ Remove: When wet or contam Fl. Target Organs (see Table 5): Eye: Irr immed ER: Inh. ozone [Note: Usually contains a stabilizer (e.52 mg/m3 DOT: 1301 129P Synonyms/Trade Names: 1-Acetoxyethylene.93 §: ScbaF:Pd. fruit. Ethenyl acetate.D. Sol: Insoluble Wash skin: N. alumina.R.19 eV ScbaF/SaF 4000 ppm: Sa:Pd. Ing. hoarseness. eye Skin: Soap flush immed Breath: Resp support burns.R. Conversion: 1 ppm = 3.Pp:AScba VP: 83 mmHg Quick drench Escape: GmFOv/ScbaE FRZ: -136°F UEL: 13. resp sys Determine based on working conditions Formula: CAS#: RTECS#: IDLH: CH2=CHOOCCH3 108-05-4 AK0875000 N. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: varies Skin: N.Pp* Provide: Eyewash Sp. [Note: Raw material for many polyvinyl resins. or nuts of vegetables or other plant matter.R. BP: ? Not available. skin.Vegetable oil mist Formula: CAS#: 68956-68-3 RTECS#: YX1850000 IDLH: N. Target Organs (see Table 5): Eye: Irr immed ER: Inh. silica gel. resp sys.D.] First Aid (see Table 6): Exposure Routes. skin.R. Ethenyl ethanoate.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 86.Gr: 0.6% Class IB Flammable Liquid Incompatibilities and Reactivities: Acids. Vinyl ethanoate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 4 ppm (15 mg/m3) [15-minute] NIOSH 1453 OSHA PEL†: none OSHA 51 Physical Description: Colorless liquid with a pleasant.95 VP: ? FRZ: ? UEL: ? LEL: ? Combustible Liquid Incompatibilities and Reactivities: None reported First Aid (see Table 6): Exposure Routes. lac TO: Eyes. Eyes: N. fruity odor. skin.g. Con SY: Irrit eyes. Fl.91-0. Symptoms. IP: 9. IP: ? Change: N. skin. 0600 TWA 5 mg/m (resp) 3 OSHA PEL: TWA 15 mg/m (total) 3 TWA 5 mg/m (resp) Physical Description: An oil extracted from the seeds. loss of smell. VAC. throat. Symptoms. nose. azo compounds.Pp/SaF:Pd. resp sys Vinyl acetate V 329 .

aluminum. lymphatic sys [liver cancer] Vinyl chloride 3 330 . VP: 3. Chloroethylene. UEL: 15% peroxides. vomit.1017] TWA 1 ppm C 5 ppm [15-minute] Physical Description: Colorless gas or liquid (below 7°F) with a pleasant odor at high concentrations. [carc] Swallow: Medical attention immed (liquid) TO: Eyes.R. abdom pain. [Note: Shipped as a liquefied compressed gas. Con Eye: Irr immed (liquid) SY: Irrit eyes.R.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 107.3 atm Provide: Frostbite wash FRZ: -256°F UEL: 33. Attacks iron & steel in presence of moisture. GI bleeding. Bromoethylene. pallor or cyan Skin: Frostbite Breath: Resp support of extremities. inco. or heat unless stabilized Flammable Gas by inhibitors such as phenol. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. sunlight. Symptoms. skin. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh. enlarged liver.99 eV Remove: When wet (flamm) See Appendix E (page 351) RGasD: 2.Pp:AScba Sol(77°F): 0.5 (see Table 2): NIOSH BP: 7°F Skin: Frostbite ¥: ScbaF:Pd.) LEL: 9% [Note: May polymerize in sunlight. chlorates.6% iron. Sp.1% Eyes: Frostbite Escape: GmFS/ScbaE Fl.38 mg/m3 DOT: 1085 116P (inhibited) Synonyms/Trade Names: Bromoethene. dizz. permanganates & nitrates. 75 OSHA PEL: [1910. skin. oxidizers.49 (Liquid at 60°F) VP: 1..56 mg/m DOT: 1086 116P (inhibited) Synonyms/Trade Names: Chloroethene.0% Incompatibilities and Reactivities: Copper. nau.1% phenol added to prevent polymerization. narco. Monobromoethylene Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1009 See Appendix A OSHA 8 OSHA PEL†: none Physical Description: Colorless gas or liquid (below 60°F) with a pleasant odor.] Flammable Gas Exposure Routes. Ethylene monochloride.Pp/SaF:Pd. perchlorates. Vinyl chloride monomer (VCM) Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca NIOSH 1007 See Appendix A OSHA 4. blood. Con (liquid) SY: Lass.Pp:AScba Sol: Insoluble Eyes: Prevent eye contact (liquid) Escape: GmFOv/ScbaE Fl.P: NA (Gas) Wash skin: When contam (liquid) IP: 9. LEL: 3. IP: 9. VC.P: NA (Gas) Wash skin: N.] Conversion: 1 ppm = 2.CAS#: RTECS#: IDLH: Formula: 593-60-2 KU8400000 Ca [N.R. Monochloroethylene.Pp/SaF:Pd.] Exposure Routes.g. peroxides.D.79 Change: N. Monochloroethene. steel [Note: Polymerizes in air.] CH2=CHBr Conversion: 1 ppm = 4. liquid: frostbite.21 Change: N. liquid: Skin: Water flush immed (liquid) Breath: Resp support frostbite.0 (see Table 2): NIOSH BP: 60°F Skin: Prevent skin contact (liquid) ¥: ScbaF:Pd. CNS.4 atm FRZ: -219°F Incompatibilities and Reactivities: Strong oxidizers (e. resp sys.80 eV Remove: When wet (flamm) RGasD: 3. [Note: Shipped as a liquefied compressed gas with 0.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 62. CNS.D. [carc] TO: Liver. conf.Gr: 1. liver [in animals: liver & lymph node tumors] Vinyl bromide V Formula: CAS#: RTECS#: IDLH: CH2=CHCl 75-01-4 KU9625000 Ca [N. Symptoms. Ing (liquid).

4-epoxy-cyclohexane. ethereal odor. Vinyl fluoride monomer Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 1 ppm None available C 5 ppm [use 1910.] Exposure Routes.Pp:AScba Eyes: Prevent eye contact Sol: High Escape: GmFOv/ScbaE Wash skin: When contam Fl. nec Skin: Water wash immed Breath: Resp support thymus. dizz.60 §: ScbaF:Pd. repro sys [in animals: skin tumors] Vinyl cyclohexene dioxide Formula: CAS#: RTECS#: IDLH: CH2=CHF 75-02-5 YZ3510000 N.] Conversion: 1 ppm = 5. liquid: frostbite Breath: Resp support TO: CNS Vinyl fluoride V 331 . water [Note: Slowly hydrolyzes in water.Gr: 1.89 mg/m3 DOT: 1860 116P (inhibited) Synonyms/Trade Names: Fluoroethene.1 10 ppm: CcrOv/Sa Eyes: Frostbite BP: -98°F 25 ppm: Sa:Cf/PaprOv Wash skin: N. Con (liquid) Skin: Frostbite SY: Head.6% Flammable Gas Incompatibilities and Reactivities: None reported [Note: Inhibited with 0. Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh. Monofluoroethylene. Symptoms.Pp/SaF:Pd.R. Sol: Insoluble 50 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) Fl. Conversion: 1 ppm = 1. Abs.1017] OSHA PEL: none Physical Description: Colorless gas with a faint.Pp Provide: Frostbite wash RGasD: 1.] Exposure Routes. thymus.73 mg/m3 DOT: Synonyms/Trade Names: 1-Epoxyethyl-3.Pp/SaF:Pd. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 140. resp sys.P: NA (Gas) Change: N. Ing. inco. skin sens. Con Eye: Irr immed SY: In animals: irrit eyes. IP: 10. testicular atrophy. 4-Vinyl-1-cyclohexene dioxide Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): 3 OSHA PV2083 TWA 10 ppm (60 mg/m ) [skin] See Appendix A OSHA PEL†: none Physical Description: Colorless liquid. amines.2 atm Escape: GmFOv/ScbaE FRZ: -257°F UEL: 21. blood. Symptoms. skin. Sp.1 mmHg FRZ: -164°F Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: Alcohols.Formula: CAS#: RTECS#: IDLH: C8H12O2 106-87-6 RN8640000 Ca [N.] Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Frostbite MW: 46. nau.37 eV ScbaF/SaF 200 ppm: SaF:Pd. conf. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. resp sys. skin.D.R.P(oc): 230°F Remove: When wet or contam IP: ? Change: N.10 Provide: Eyewash VP: 0.7% LEL: 2.2 NIOSH Skin: Prevent skin contact BP: 441°F ¥: ScbaF:Pd. Fluoroethylene. [carc] Swallow: Medical attention immed TO: Eyes. leupen.D. 4-Vinylcyclohexene diepoxide.R. [Note: Shipped as a liquefied compressed gas. vomit.Pp:AScba VP: 25. narco.2% terpenes to prevent polymerization.

Fl.] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 64. head. pneu. sweet.Pp:AScba Eyes: Prevent eye contact Sol: 0. Con SY: Irrit eyes.D.Formula: CAS#: RTECS#: IDLH: CH2=CCl2 75-35-4 KV9275000 Ca [N. 1. nitric acid.P: NA (Gas) 50 ppm: CcrFOv/GmFOv/PaprTOv/ Remove: When wet (flamm) IP: 10. Vinylidene dichloride Exposure Limits: Measurement Methods NIOSH REL: Ca (see Table 1): NIOSH 1015 See Appendix A OSHA 19 OSHA PEL†: none Physical Description: Colorless liquid or gas (above 89°F) with a mild. skin. Halocarbon 1132A. VDC. head. 1. dizz.] Exposure Routes. Abs. [Note: Shipped as a liquefied compressed gas.1-Dichloroethene. resp sys. Con (liquid) Skin: Frostbite SY: Dizz.R. copper. ethereal odor. CNS.Pp Provide: Frostbite wash VP: 35. Ing. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 96. Conversion: 1 ppm = 2. nau. aluminum chloride [Note: Violent reaction with hydrogen chloride when heated under pressure.D. liquid: frostbite Breath: Resp support TO: CNS Vinylidene fluoride 3 332 . Target Organs (see Table 5): First Aid (see Table 6): Eye: Frostbite ER: Inh.1-DCE.0 NIOSH Skin: Frostbite BP: -122°F 10 ppm: CcrOv/Sa Eyes: Frostbite Sol: Insoluble 25 ppm: Sa:Cf/PaprOv Wash skin: N. chloroform-like odor. or oleum. heat [Note: Polymerization may occur if exposed to oxidizers. Symptoms. Vinylidene chloride monomer.R. nau.04% Escape: GmFOv/ScbaE Wash skin: When contam Fl.62 mg/m DOT: 1959 116P Synonyms/Trade Names: Difluoro-1.Pp/SaF:Pd.5% Class IA Flammable Liquid Incompatibilities and Reactivities: Aluminum.00 eV Change: N.5% LEL: 6.2 atm §: ScbaF:Pd. 1.P: -2°F Remove: When wet (flamm) IP: 10. Sp.3% LEL: 5. sunlight.] First Aid (see Table 6): Exposure Routes. kidney dist.9 NIOSH Skin: Prevent skin contact BP: 89°F ¥: ScbaF:Pd. Target Organs (see Table 5): Eye: Irr immed ER: Inh. liver.Pp/SaF:Pd. kidneys [in animals: liver & kidney tumors] Vinylidene chloride V Formula: CAS#: RTECS#: IDLH: CH2=CF2 75-38-7 KW0560000 N.5% Flammable Gas Incompatibilities and Reactivities: Oxidizers. VDF.1-Difluoroethylene.1017] OSHA PEL: none Physical Description: Colorless gas with a faint.21 Provide: Eyewash VP: 500 mmHg FRZ: -189°F Quick drench UEL: 15. throat. Vinylidene difluoride Exposure Limits: Measurement Methods NIOSH REL: TWA 1 ppm (see Table 1): NIOSH 3800 C 5 ppm [use 1910.Pp:AScba FRZ: -227°F Escape: GmFOv/ScbaE UEL: 21. liver. dysp. RGasD: 2.R. skin.1-ethylene.1-Dichloroethylene. Inhibitors such as the monomethyl ether of hydroquinone are added to prevent polymerization.1-Difluoroethene. chlorosulfonic acid.Gr: 1. Symptoms.] Conversion: DOT: 1303 130P (inhibited) Synonyms/Trade Names: 1. Skin: Soap flush immed Breath: Resp support [carc] Swallow: Medical attention immed TO: Eyes.29 eV Change: N. 1. air.21 ScbaF/SaF 200 ppm: SaF:Pd.

Escape: GmFOv/ScbaE Sp. chemical pneu Skin: Soap wash prompt Breath: Resp support (aspir liquid) Swallow: Medical attention immed TO: Eyes.o. CNS VM & P Naphtha Formula: V 333 . Petroleum ether. Ing. derm.2% Class IB Flammable Liquid Incompatibilities and Reactivities: None reported [Note: VM&P Naphtha is a refined petroleum solvent predominantly C7-C11 which is typically 55% paraffins. Con Skin: Soap flush prompt SY: Irrit eyes.009% Wash skin: When contam Fl. skin. Tolyethylene Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (480 mg/m3) (see Table 1): 3 NIOSH 1501 OSHA PEL: TWA 100 ppm (480 mg/m ) OSHA 7 Physical Description: Colorless liquid with a strong.D. Conversion: DOT: 1268 128 (petroleum distillates.2 NIOSH/OSHA Skin: Prevent skin contact BP: 339°F 400 ppm: CcrOv*/PaprOv*/ Eyes: Prevent eye contact Sol: 0. Ing.500 mg/m3: CcrFOv/GmFOv/PaprTOv/ Change: N.20 eV Change: N. resp sys.Pp/SaF:Pd. iron or aluminum salts [Note: Usually inhibited with tert-butyl catechol to prevent polymerization.76 §: ScbaF:Pd.Pp/SaF:Pd. Varnish makers' & painters' naphtha Exposure Limits: Measurement Methods NIOSH REL: TWA 350 mg/m3 (see Table 1): 3 NIOSH 1550 C 1800 mg/m [15-minute] OSHA 48 OSHA PEL†: none Physical Description: Clear to yellowish liquid with a pleasant.) Synonyms/Trade Names: Ligroin. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): (see Table 2): MW: 118.Formula: CAS#: RTECS#: IDLH: CH2=CHC6H4CH3 25013-15-4 (inhibited) WL5075000 400 ppm Conversion: 1 ppm = 4.P: 20-55°F 17.0% LEL: 0. 2% dicycloparaffins & 12% alklybenzenes.] Exposure Routes. Methylstyrene.0% LEL: 1.Pp:AScba IP: 8.] Exposure Routes.89 VP: 1 mmHg FRZ: -106°F UEL: 11.73-0.Pp:AScba VP: 2-20 mmHg Escape: GmFOv/ScbaE FRZ: ? UEL: 6. n.P: 127°F GmFOv/Sa*/ScbaF Remove: When wet or contam §: ScbaF:Pd.R. CNS Swallow: Medical attention immed Vinyl toluene CAS#: RTECS#: IDLH: 8032-32-4 OI6180000 N.8% Class II Combustible Liquid Incompatibilities and Reactivities: Oxidizers. skin. 30% monocycloparaffins. Symptoms. disagreeable odor.Gr: 0. Painters naphtha.s.83 mg/m3 DOT: 2618 130P (inhibited) Synonyms/Trade Names: Ethenylmethylbenzene. resp sys.R. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. Petroleum spirit. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. IP: ? ScbaF/SaF Sp. aromatic odor. Symptoms. skin. upper resp sys. Con Eye: Irr immed SY: Irrit eyes.Gr(60°F): 0. CNS depres. drow. peroxides. in animals: narco Breath: Resp support TO: Eyes. upper resp sys. strong acids. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH Skin: Prevent skin contact MW: 87-114 (approx) 3500 mg/m3: CcrOv/Sa Eyes: Prevent eye contact BP: 203-320°F Wash skin: When contam Sol: Insoluble 8750 mg/m3: Sa:Cf/PaprOv Remove: When wet (flamm) Fl. Refined solvent naphtha.

R. Con SY: Hema.1 mg/m3 (see Table 1): 3 NIOSH 5002 OSHA PEL: TWA 0. 4-Hydroxy-3-(3-oxo-1-phenyl butyl)-2H-1-benzopyran-2-one. Exposure Limits: Measurement Methods (see Table 1): NIOSH REL: Ca NIOSH 7300.] W Conversion: DOT: Synonyms/Trade Names: Synonyms vary depending upon the specific component of the welding fumes. petechial rash.Pp:AScba Eyes: N. vomit. fumes. epis.P: ? 1 mg/m3: 95XQ/Sa Remove: When wet or contam IP: ? 2.1 mg/m Physical Description: Colorless. [rodenticide] Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 308. [carc] TO: Eyes. Con SY: Symptoms vary depending upon the specific component of the welding fumes. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): Properties vary depending upon the NIOSH Skin: N. abnor Swallow: Medical attention immed hematologic indices TO: Blood.Warfarin Conversion: Formula: C19H16O4 DOT: CAS#: 81-81-2 RTECS#: GN4550000 IDLH: 100 mg/m3 Synonyms/Trade Names: 3-(α-Acetonyl)-benzyl-4-hydroxycoumarin. skin. resp sys.09 mmHg ScbaF/SaF MLT: 322°F 100 mg/m3: Sa:Pd.D. fecal blood. back pain. CNS [lung cancer] First Aid (see Table 6): Eye: Irr immed Skin: Soap wash Breath: Resp support 334 .Pp UEL: ? §: ScbaF:Pd. Symptoms. hematoma arms.Pp/SaF:Pd. musc pain. Symptoms. legs. Escape: GmFOv100/ScbaE Wash skin: N.002% Wash skin: When contam Fl. CVS Welding fumes Formula: CAS#: RTECS#: ZC2550000 IDLH: Ca [N.Pp:AScba LEL: ? Escape: 100F/ScbaE Combustible Solid Incompatibilities and Reactivities: Strong oxidizers First Aid (see Table 6): Exposure Routes. Change: N. Incompatibilities and Reactivities: Varies Exposure Routes. fever.R. Target Organs (see Table 5): ER: Inh. Abs. odorless. muc Skin: Soap wash prompt Breath: Resp support memb hemorr. Remove: N. pressure. metal fume fever: flu-like symptoms.Pp/SaF:Pd.R. cough.R. Sol: 0.Gr: ? 5 mg/m3: 100F/SaT:Cf/PaprTHie/ VP(71°F): 0. specific component of the welding ¥: ScbaF:Pd. dysp. 7303 See Appendix A OSHA PEL†: none Physical Description: Fumes generated by the process of joining or cutting pieces of metal by heat. WARF Exposure Limits: Measurement Methods NIOSH REL: TWA 0.R. Ing. interstitial pneu. bleeding lips.5 mg/m3: Sa:Cf/PaprHie Change: Daily Sp. abdom pain. crystalline powder.3 NIOSH/OSHA Skin: Prevent skin contact BP: Decomposes 0.R. chills.5 mg/m3: Qm Eyes: N. or both. 7301. Target Organs (see Table 5): Eye: Irr immed ER: Inh.

86 VP: 9 mmHg FRZ: -54°F UEL: 7. epis. [carc] TO: Eyes. skin. prolonged colds.D.P: NA Remove: N. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. wheez. Target Organs (see Table 5): Eye: Irr immed ER: Inh. kidneys m-Xylene X 335 . vomit.0% LEL: 1. nau. granulomatous Skin: Soap wash Breath: Fresh air pneu. liver. derm.Gr: 0. resp sys [nasal cancer] Formula: CAS#: RTECS#: IDLH: C6H4(CH3)2 108-38-3 ZE2275000 900 ppm Conversion: 1 ppm = 4. 3800 ST 150 ppm (655 mg/m ) 3 OSHA 1002 OSHA PEL†: TWA 100 ppm (435 mg/m ) Physical Description: Colorless liquid with an aromatic odor. cough.Wood dust Formula: CAS#: RTECS#: ZC9850000 IDLH: Ca [N. throat. Sp.1% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. Symptoms. blood. Fl. drow. Western red cedar dust Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: Ca 3 NIOSH 0500 TWA 1 mg/m See Appendix A 3 OSHA PEL†: TWA 15 mg/m (total) TWA 5 mg/m3 (resp) Physical Description: Dust from various types of wood. excitement. BP: NA ¥: ScbaF:Pd. nose. abdom pain. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): (see Table 2): MW: 106. Sol: ? Escape: 100F/ScbaE Wash skin: N.Gr: ? VP: 0 mmHg (approx) MLT: NA UEL: NA LEL: NA Combustible Solid Incompatibilities and Reactivities: None reported Exposure Routes. CNS.3-Dimethylbenzene.P: 82°F Sa*/ScbaF §: ScbaF:Pd. Symptoms. Con Eye: Irr immed SY: Irrit eyes. m-Xylol Exposure Limits: Measurement Methods NIOSH REL: TWA 100 ppm (435 mg/m3) (see Table 1): 3 NIOSH 1501. Ing. strong acids First Aid (see Table 6): Exposure Routes. skin.34 mg/m3 DOT: 1307 130 Synonyms/Trade Names: 1.2 NIOSH/OSHA Skin: Prevent skin contact BP: 282°F 900 ppm: CcrOv*/PaprOv*/ Eyes: Prevent eye contact Sol: Slight Wash skin: When contam Fl. IP: NA Change: N.R. asthma.R.R. Sp. dizz.56 eV Escape: GmFOv/ScbaE Change: N. meta-Xylene. resp sys. skin.R.Pp:AScba Remove: When wet (flamm) IP: 8.Pp/SaF:Pd.Pp/SaF:Pd. Soft wood dust. sinusitis.R. staggering Skin: Soap wash prompt Breath: Resp support gait. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: varies NIOSH Skin: N. derm Swallow: Medical attention immed TO: Eyes. corn vacuolization.R.Pp:AScba Eyes: N. resp hypersensitivity. GI tract. Con SY: Irrit eyes. inco. Abs. anor.] Conversion: DOT: Synonyms/Trade Names: Hard wood dust.

liver. derm Swallow: Medical attention immed TO: Eyes. nau.4-Dimethylbenzene. [Note: A solid below 56°F. liver. blood. Target Organs (see Table 5): ER: Inh. drow. p-Xylol Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 100 ppm (435 mg/m3) 3 NIOSH 1501.9% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. abdom pain.44 eV Escape: GmFOv/ScbaE Change: N. staggering Skin: Soap wash prompt Breath: Resp support gait. inco. anor.] Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): (see Table 2): MW: 106. kidneys p-Xylene 336 . throat. vomit. kidneys o-Xylene RTECS#: ZE2450000 IDLH: 900 ppm Measurement Methods (see Table 1): NIOSH 1501. throat. resp sys.Formula: CAS#: C6H4(CH3)2 95-47-6 Conversion: 1 ppm = 4. inco. Ing.1% Class IC Flammable Liquid Incompatibilities and Reactivities: Strong oxidizers. 3800 OSHA 1002 Respirator Recommendations (see Tables 3 and 4): NIOSH/OSHA 900 ppm: CcrOv*/PaprOv*/ Sa*/ScbaF §: ScbaF:Pd.86 VP: 9 mmHg FRZ: 56°F UEL: 7. skin. nose.02% Remove: When wet (flamm) Fl. dizz. IP: 8.0% LEL: 1. para-Xylene. skin. GI tract. GI tract. excitement. Con Eye: Irr immed SY: Irrit eyes. vomit. strong acids Exposure Routes.2-Dimethylbenzene. anor. ortho-Xylene.88 VP: 7 mmHg FRZ: -13°F UEL: 6. Sp. dizz.P: 90°F Change: N. corn vacuolization. Personal Protection/Sanitation Chemical & Physical (see Table 2): Properties: Skin: Prevent skin contact MW: 106. excitement. corn vacuolization.R. strong acids Exposure Routes. abdom pain. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh.Pp/SaF:Pd. derm TO: Eyes. Abs. Abs. Con SY: Irrit eyes. drow.R.02% Wash skin: When contam Fl. CNS. blood. skin. o-Xylol Exposure Limits: NIOSH REL: TWA 100 ppm (435 mg/m3) ST 150 ppm (655 mg/m3) OSHA PEL†: TWA 100 ppm (435 mg/m3) Physical Description: Colorless liquid with an aromatic odor.Pp/SaF:Pd.P: 81°F Sa*/ScbaF §: ScbaF:Pd. Symptoms. Symptoms.Gr: 0. resp sys. staggering gait.34 mg/m3 DOT: 1307 130 Synonyms/Trade Names: 1. skin.2 NIOSH/OSHA Skin: Prevent skin contact BP: 281°F 900 ppm: CcrOv*/PaprOv*/ Eyes: Prevent eye contact Sol: 0. nau. CNS.7% LEL: 0.41 mg/m3 DOT: 1307 130 Synonyms/Trade Names: 1.56 eV Sp.Gr: 0.Pp:AScba Escape: GmFOv/ScbaE First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed X Formula: CAS#: RTECS#: IDLH: C6H4(CH3)2 106-42-3 ZE2625000 900 ppm Conversion: 1 ppm = 4.Pp:AScba Remove: When wet (flamm) IP: 8. nose.2 Eyes: Prevent eye contact BP: 292°F Wash skin: When contam Sol: 0. Ing. 3800 ST 150 ppm (655 mg/m ) 3 OSHA 1002 OSHA PEL†: TWA 100 ppm (435 mg/m ) Physical Description: Colorless liquid with an aromatic odor.

skin.6-) Escape: GmFOv/ScbaE Provide: Eyewash Sp.P: 206°F (2. Xylidine isomers (e. kidney.3-) Incompatibilities and Reactivities: Strong oxidizers.3-bis(Aminomethyl)benzene.α'-diamine Formula: CAS#: RTECS#: IDLH: (CH3)2C6H3NH2 1300-73-8 ZE8575000 50 ppm Conversion: 1 ppm = 4. Aminoxylene.N-Dimethylaniline.4-Dimethylaniline) [Note: Dimethylaniline is also used as a synonym for N. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh.3-Benzenedimethanamine. Con Skin: Soap wash immed SY: Anoxia.Pp/SaF:Pd. liver. Eyes: Prevent eye contact Sol: Miscible Wash skin: When contam Fl.D.Gr: 1.R. resp sys. liver. kidney damage Breath: Resp support TO: Resp sys. Dimethylaniline.1 mg/m3 [skin] OSHA 105 OSHA PEL†: none Physical Description: Colorless liquid. 1.Formula: CAS#: RTECS#: IDLH: C6H4(CH2NH2)2 1477-55-0 PF8970000 N.P: 243°F Remove: When wet or contam IP: ? Change: N. kidneys.R. 2. liver. cyan.Gr: 0.g.65 eV (2. CVS Swallow: Medical attention immed Xylidine X 337 . liver. 7. Symptoms. m-Xylylenediamine Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: C 0. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 136.03 mmHg FRZ: 58°F Quick drench UEL: ? LEL: ? Class IIIB Combustible Liquid Incompatibilities and Reactivities: None reported Exposure Routes. Dimethylaminobenzene. kidneys Swallow: Medical attention immed m-Xylene α. Symptoms.2 Skin: Prevent skin contact BP: 477°F Not available.. m-Phenylenebis(methylamine). Ing.98 VP: <1 mmHg Quick drench FRZ: -33°F UEL: ? LEL: 1.] Exposure Limits: Measurement Methods NIOSH REL: TWA 2 ppm (10 mg/m3) [skin] (see Table 1): 3 NIOSH 2002 OSHA PEL†: TWA 5 ppm (25 mg/m ) [skin] Physical Description: Pale-yellow to brown liquid with a weak. Abs. skin.96 mg/m3 DOT: 1711 153 Synonyms/Trade Names: Aminodimethylbenzene. aromatic.3-) Remove: When wet or contam IP: 7.2 NIOSH Skin: Prevent skin contact BP: 415-439°F 20 ppm: CcrOv/Sa Eyes: Prevent eye contact Sol: Slight 50 ppm: Sa:Cf/CcrFOv/GmFOv/ Wash skin: When contam Fl. methemo. MXDA. lung damage Breath: Resp support TO: Eyes. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): (see Table 2): MW: 121.0% (o-isomer) Class IIIB Combustible Liquid (2. hypochlorite salts Exposure Routes. blood.30 eV (2. Abs. Target Organs (see Table 5): First Aid (see Table 6): Eye: Irr immed ER: Inh. lung.Pp:AScba Change: N. Conversion: DOT: Synonyms/Trade Names: 1.4-) PaprOv/ScbaF/SaF §: ScbaF:Pd. Con Skin: Water flush immed SY: In animals: irrit eyes. amine-like odor. Ing.032 Provide: Eyewash VP(77°F): 0. Sp.

Gr(77°F): 2. 7301. BP: 1350°F Wash skin: N.Gr: 4. in animals: pulm irrit. cor pulmonale. Con Breath: Resp support SY: Irrit eyes. Sp. skin. Fl. odorless solid. conj. eye inj.R. MW: 136.P: NA 50 mg/m3: 100F/PaprTHie*/ScbaF/SaF Change: N. BP: 5301°F Eyes: N.Pp:AScba Sp. IP: NA §: ScbaF:Pd. tachypnea.Yttrium Conversion: Synonyms/Trade Names: Yttrium metal Exposure Limits: NIOSH REL*: TWA 1 mg/m3 OSHA PEL*: TWA 1 mg/m3 [*Note: The REL and PEL also apply to other yttrium compounds (as Y). Chemical & Physical Properties: Personal Protection/Sanitation (see Table 2): MW: 88. 25 mg/m3: Sa:Cf*/PaprHie* Sol(70°F): 435% Remove: N. CVS Zinc chloride fume 338 .R. Respirator Recommendations Personal Protection/Sanitation Chemical & Physical (see Tables 3 and 4): (see Table 2): Properties: NIOSH/OSHA Skin: N. Con SY: Irrit eyes.R.91 Escape: 100F/ScbaE VP: 0 mmHg (approx) MLT: 554°F UEL: NA LEL: NA Noncombustible Solid Incompatibilities and Reactivities: Potassium Exposure Routes. 7303.9 Skin: N. Symptoms.R.3 10 mg/m3: 95XQ*/Sa* Eyes: N. cyan.47 VP: 0 mmHg (approx) MLT: 2732°F UEL: NA LEL: NA Noncombustible Solid in bulk form. Target Organs (see Table 5): ER: Inh. fever.] Physical Description: Dark-gray to black. skin burns TO: Eyes. Symptoms.R.P: NA Remove: N. Incompatibilities and Reactivities: Oxidizers Exposure Routes. IP: NA Change: N. throat. liver Formula: Y DOT: CAS#: 7440-65-5 RTECS#: ZG2980000 IDLH: 500 mg/m3 (as Y) Measurement Methods (see Table 1): NIOSH 7300. pneu. possible liver damage TO: Eyes.Pp §: ScbaF:Pd. nose. Fl.Pp:AScba Escape: 100F/ScbaE First Aid (see Table 6): Eye: Irr immed Skin: Soap wash prompt Breath: Resp support Swallow: Medical attention immed Y Z Formula: CAS#: RTECS#: IDLH: ZnCl2 7646-85-7 ZH1400000 50 mg/m3 Conversion: DOT: 2331 154 Synonyms/Trade Names: Zinc dichloride fume Exposure Limits: Measurement Methods NIOSH REL: TWA 1 mg/m3 (see Table 1): 3 OSHA ID121 ST 2 mg/m 3 OSHA PEL†: TWA 1 mg/m Physical Description: White particulate dispersed in air. copious sputum. dysp.R.R. resp sys. resp sys.R.R.R. skin. cough. Ing. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. 9102 OSHA ID121 Respirator Recommendations (see Tables 3 and 4): NIOSH/OSHA 5 mg/m3: Qm 10 mg/m3: 95XQ/Sa 25 mg/m3: Sa:Cf/PaprHie 50 mg/m3: 100F/SaT:Cf/PaprTHie/ ScbaF/SaF 500 mg/m3: Sa:Pd.Pp/SaF:Pd.Pp/SaF:Pd. chest pain. Sol: Soluble in hot H2O Wash skin: N. pulm fib. pulm edema.

R. Sp.R. fever. nau.R.P(oc): 530°F Wash skin: N.10 Change: N.4 Skin: N. dysp. Not available.Pp VP: 0 mmHg (approx) §: ScbaF:Pd. characteristic odor. chest tight. 250 mg/m3: 100F/SaT:Cf/PaprTHie/ IP: NA Change: N.Pp/SaF:Pd. 50 mg/m3: 95XQ/Sa BP: ? Eyes: N. dry throat.4 (see Table 2): BP: ? Skin: N.R. Ing.Pp:AScba MLT: 3587°F Escape: 100F/ScbaE UEL: NA LEL: NA Incompatibilities and Reactivities: Chlorinated rubber (at 419°F). Target Organs (see Table 5): ER: Inh.R. rales. Conversion: DOT: Synonyms/Trade Names: Dibasic zinc stearate. upper resp sys. dilute acids Combustible Solid [Note: Hydrophobic (i. musc ache. Fl. skin.] First Aid (see Table 6): Exposure Routes. blurred vision..R. Zinc salt of stearic acid.R. vomit. water Noncombustible Solid [Note: Slowly decomposed by water. IP: NA Remove: N. ID143 Fume: TWA 5 mg/m 3 ST 10 mg/m 3 OSHA PEL†: TWA 5 mg/m (fume) TWA 15 mg/m3 (total dust) TWA 5 mg/m3 (resp dust) Physical Description: White.e.Gr: 1.61 500 mg/m3: Sa:Pd. skin. repels water). 7502 C 15 mg/m 3 OSHA ID121. resp sys First Aid (see Table 6): Eye: Irr immed Skin: Soap wash Breath: Fresh air Swallow: Medical attention immed 339 . head. cough TO: Eyes.Zinc oxide Conversion: Synonyms/Trade Names: Zinc peroxide Exposure Limits: Measurement Methods NIOSH REL: Dust: TWA 5 mg/m3 (see Table 1): 3 NIOSH 7303.Gr: 5. mal. decr pulm func TO: Resp sys Formula: ZnO DOT: 1516 143 CAS#: 1314-13-2 RTECS#: ZH4810000 IDLH: 500 mg/m3 Formula: CAS#: RTECS#: IDLH: Zn(C18H35O2)2 557-05-1 ZH5200000 N. low back pain. Symptoms. Zinc distearate Measurement Methods Exposure Limits: (see Table 1): NIOSH REL: TWA 10 mg/m3 (total) OSHA PEL†: TWA 15 mg/m3 (total) NIOSH 0500. 125 mg/m3: Sa:Cf/PaprHie Fl.R. Symptoms. 0600 TWA 5 mg/m3 (resp) TWA 5 mg/m3 (resp) Physical Description: Soft.P: NA Remove: N. metallic taste. cough. odorless solid.0004% Wash skin: N. VP: 0 mmHg (approx) MLT: 266°F UEL: ? LEL: ? MEC: 20 g/m3 Incompatibilities and Reactivities: Oxidizers.] Zinc stearate Z Exposure Routes. white powder with a slight. Target Organs (see Table 5): Breath: Resp support ER: Inh SY: Metal fume fever: chills.D. ScbaF/SaF Sp.R. Sol(64°F): 0. Respirator Recommendations Chemical & Physical Personal Protection/Sanitation (see Tables 3 and 4): Properties: (see Table 2): NIOSH/OSHA MW: 81. lass.R. Sol: Insoluble Eyes: N. Respirator Recommendations Chemical & Physical Properties: Personal Protection/Sanitation (see Tables 3 and 4): MW: 632. Con SY: Irrit eyes.

but solid form is difficult to ignite. lung granulomas.RTECS#: IDLH: ZH7070000 (metal) 50 mg/m3 (as Zr) Conversion: DOT: 1358 170 (powder. powder form may ignite SPONTANEOUSLY and can continue burning under water. ductile. Personal Protection/Sanitation Respirator Recommendations Chemical & Physical Properties: (see Tables 3 and 4): (see Table 2): MW: 91. Target Organs (see Table 5): First Aid (see Table 6): ER: Inh. amorphous powder.Pp:AScba VP: 0 mmHg (approx) Escape: 100F/ScbaE MLT: 3375°F UEL: NA LEL: NA Metal: Combustible. however. 9102 ST 10 mg/m [*Note: The REL applies to all zirconium compounds (as Zr) except Zirconium OSHA ID121 tetrachloride. Con Eye: Irr immed SY: Skin.Pp/SaF:Pd. 1932 135 (scrap). Incompatibilities and Reactivities: Potassium nitrate. 2008 135 (powder. resp sys Zirconium compounds (as Zr) Zr (metal) 7440-67-7 (metal) Formula: CAS#: Z 340 . oxidizers [Note: Fine powder may be stored completely immersed in water. muc memb.P: NA 50 mg/m3: 95XQ/PaprHie/100F/ depending upon the specific IP: NA compound. wet). Sa/ScbaF Sp. 7301. in animals: irrit skin.] OSHA PEL†: TWA 5 mg/m3 Physical Description: Metal: Soft.51 (Metal) §: ScbaF:Pd. solid or gray to gold. malleable. Exposure Limits: Measurement Methods NIOSH REL*: TWA 5 mg/m3 (see Table 1): 3 NIOSH 7300.Gr: 6. Symptoms.] Exposure Routes. dry) Synonyms/Trade Names: Zirconium metal: Zirconium Synonyms of other zirconium compounds vary depending upon the specific compound. Skin: Soap wash Breath: Resp support X-ray evidence of retention in lungs Swallow: Medical attention immed TO: Skin.2 NIOSH/OSHA BP: 6471°F Recommendations regarding Sol: Insoluble personal protective clothing vary 25 mg/m3: Qm Fl.

APPENDICES 341 .

271:200-207.” The effect of this new policy will be the development. respirators will be consistently recommended regardless of whether a substance is a carcinogen or a non-carcinogen.. including but not limited to the exposure levels at which no employee will suffer impaired health or functional capacities or diminished life expectancy as a result of his work experience. but also exposure levels at which there may be residual risks. This policy applies to all workplace hazards. This was in response to a generic OSHA rulemaking on carcinogens. NIOSH adopted several quantitative RELs for carcinogens from OSHA's permissible exposure limit (PEL) update. and is responsive to Section 20(a)(3) of the Occupational Safety and Health Act of 1970.g. . .] Under the new policy. In this way. NIOSH has adopted a more inclusive policy. Fairchild. and on an assessment of what levels can be feasibly achieved by engineering controls and measured by analytical techniques. Associate Director for Cincinnati Operations. NIOSH will also recommend the complete range of respirators (as determined by the NIOSH Respirator Decision Logic) for carcinogens with quantitative RELs. benzene. NIOSH recommended exposure limits (RELs) will be based on risk evaluations using human or animal health effects data. NIOSH has subscribed to a carcinogen policy that was published in 1976 by Edward J. in 1989. which called for “no detectable exposure levels for proven carcinogenic substances” (Annals of the New York Academy of Sciences. of quantitative RELs that are based on human and/or animal data. NIOSH will project not only a no effect exposure. Because of advances in science and in approaches to risk assessment and risk management. Under the old policy.A P P E N D I X A Appendix A NIOSH POTENTIAL OCCUPATIONAL CARCINOGENS New Policy (Adopted September 1995) For the past 20 plus years. and ethylene oxide are quantitative values based primarily on analytical limits of detection or technological feasibility). as well as on the consideration of technological feasibility for controlling workplace exposures to the REL. whenever possible. RELs for most carcinogens were non-quantitative values labeled “lowest feasible concentration (LFC). which charges NIOSH to “. formaldehyde. II. To the extent feasible.” [Note: There are a few exceptions to LFC RELs for carcinogens (e. RELs for asbestos.describe exposure levels that are safe for various periods of employment. Also. 1976). 342 . including carcinogens.

which causes an increased incidence of benign and/or malignant neoplasms.103. NIOSH identified numerous substances that should be treated as potential occupational carcinogens even though OSHA might not have identified them as such. NIOSH usually recommended that occupational exposures to carcinogens be limited to the lowest feasible concentration. respiratory or dermal exposure. In A determining the