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Note: For the benefit of the students, specially the aspiring ones, the question of IIT-JEE, 2011 are

are also given in this booklet.


Keeping the interest of students studying in class XI, the questions based on topics from class XI have been marked
with ‘*’, which can be attempted as a test. For this test the time allocated in Chemistry, Mathematics and Physics are
22 minutes, 21 minutes and 25 minutes respectively.

FIITJEE Solutions to IIT-JEE-2011


CODE
PAPER 1
8
Time: 3 Hours Maximum Marks: 240
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

INSTRUCTIONS
A. General:
1. The question paper CODE is printed on the right hand top corner of this sheet and on the back page (page
No. 36) of this booklet.
2. No additional sheets will be provided for rough work.
3. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets
are NOT allowed.
4. Write your name and registration number in the space provided on the back page of this booklet.
5. The answer sheet, a machine-gradable Optical Response Sheet (ORS), is provided separately.
6. DO NOT TAMPER WITH/MULTILATE THE ORS OR THE BOOKLET.
7. Do not break the seals of the question-paper booklet before being instructed to do so by the invigilators.
8. This question Paper contains 36 pages having 69 questions.
9. On breaking the seals, please check that all the questions are legible.

B. Filling the Right Part of the ORS:


10. The ORS also has a CODE printed on its Left and Right parts.
11. Make sure the CODE on the ORS is the same as that on this booklet. If the codes do not match ask for a
change of the booklet.
12. Write your Name, Registration No. and the name of centre and sign with pen in the boxes provided. Do not
write them anywhere else. Darken the appropriate bubble UNDER each digit of your Registration No.
with a good quality HB pencil.

C. Question paper format and Marking scheme:


13. The question paper consists of 3 parts (Chemistry, Physics and Mathematics). Each part consists of four
sections.
14. In Section I (Total Marks: 21), for each question you will be awarded 3 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (–1) mark will be awarded.
15. In Section II (Total Marks: 16), for each question you will be awarded 4 marks if you darken ALL the
bubble(s) corresponding to the correct answer(s) ONLY and zero marks other wise. There are no negative
marks in this section.
16. In Section III (Total Marks: 15), for each question you will be awarded 3 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks if no bubble is darkened. In all other cases,
minus one (–1) mark will be awarded.
17. In Section IV (Total Marks: 28), for each question you will be awarded 4 marks if you darken ONLY the
bubble corresponding to the correct answer and zero marks otherwise. There are no negative marks in
this section.

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IITJEE2011-Paper 1-CPM-2

PAPER-1 [Code – 8]
IITJEE 2011
PART - I: CHEMISTRY
SECTION – I (Total Marks : 21)
(Single Correct Answer Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1. Extra pure N2 can be obtained by heating
(A) NH3 with CuO (B) NH4NO3
(C) (NH4)2Cr2O7 (D) Ba(N3)2
*2. Dissolving 120 g of urea (mol. wt. 60) in 1000 g of water gave a solution of density 1.15 g/mL. The
molarity of the solution is
(A) 1.78 M (B) 2.00 M
(C) 2.05 M (D) 2.22 M
*3. Bombardment of aluminium by α-particle leads to its artificial disintegration in two ways, (i) and (ii) as
shown. Products X, Y and Z respectively are,
( ) 30
Al ⎯⎯ →15 P + Y
27 ii
13

(i )
30
14 Si + X 30
14 Si + Z
(A) proton, neutron, positron (B) neutron, positron, proton
(C) proton, positron, neutron (D) positron, proton, neutron

4. Geometrical shapes of the complexes formed by the reaction of Ni2+ with Cl– , CN– and H2O, respectively,
are
(A) octahedral, tetrahedral and square planar (B) tetrahedral, square planar and octahedral
(C) square planar, tetrahedral and octahedral (D) octahedral, square planar and octahedral

5. The major product of the following reaction is


O
C
()
⎯⎯⎯⎯⎯⎯⎯⎯⎯

i KOH
NH
C (ii) Br CH2Cl
O
O O
C C
(A) N CH2 Br (B) N CH2Cl
C C
O O
O O
C C
N N
(C) (D)
C
O CH2 Br O CH2Cl

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IITJEE2011-Paper 1-CPM-3

*6. Among the following compounds, the most acidic is


(A) p-nitrophenol (B) p-hydroxybenzoic acid
(C) o-hydroxybenzoic acid (D) p-toluic acid

7. AgNO3(aq.) was added to an aqueous KCl solution gradually and the conductivity of the solution was
measured. The plot of conductance ( Λ ) versus the volume of AgNO3 is

Λ Λ Λ Λ

volume volume volume volume


(P) (Q) (R) (S)
(A) (P) (B) (Q)
(C) (R) (D) (S)

SECTION – II (Total Marks : 16)


(Multiple Correct Answers Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

*8. Amongst the given options, the compound(s) in which all the atoms are in one plane in all the possible
conformations (if any), is (are)
H
H H
H C C C
(A) C C (B)
CH2
H2C CH2

(C) H2C C O (D) H2C C CH2

9. Extraction of metal from the ore cassiterite involves


(A) carbon reduction of an oxide ore (B) self-reduction of a sulphide ore
(C) removal of copper impurity (D) removal of iron impurity

*10. According to kinetic theory of gases


(A) collisions are always elastic
(B) heavier molecules transfer more momentum to the wall of the container
(C) only a small number of molecules have very high velocity
(D) between collisions, the molecules move in straight lines with constant velocities

11. The correct statement(s) pertaining to the adsorption of a gas on a solid surface is (are)
(A) Adsorption is always exothermic
(B) Physisorption may transform into chemisorption at high temperature
(C) Physiosorption increases with increasing temperature but chemisorption decreases with increasing
temperature
(D) Chemisorption is more exothermic than physisorption, however it is very slow due to higher energy of
activation

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IITJEE2011-Paper 1-CPM-4

SECTION-III (Total Marls : 15)


(Paragraph Type)
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based on the
other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 12 and 13

An acyclic hydrocarbon P, having molecular formula C6H10, gave acetone as the only organic product through the
following sequence of reaction, in which Q is an intermediate organic compound.

( i ) conc. H2SO4
O
( catalytic amount )
( i ) dil. H 2SO4 / HgSO4 ( − H2 O)
P ⎯⎯⎯⎯⎯⎯⎯
( ) → Q ⎯⎯⎯⎯⎯⎯
( ) ⎯→2 C
( C6 H10 ) ii NaBH 4 / ethanol ii O3
( iii ) dil.acid ( iii ) Zn / H2 O
CH3
H3C

*12. The structure of compound P is


(A) CH 3 CH 2 CH 2 CH 2 − C ≡ C − H (B) H 3 CH 2 C − C ≡ C − CH 2 CH 3
H3C H3C
(C) H C C C CH3 (D) H3C C C C H
H3C H3C

*13. The structure of the compound Q is


OH OH
H3C H3C
(A) H C C CH2 CH3 (B) H3C C C CH3
H3C H3C
H H
OH
H3C OH
(C) H C CH2CHCH3 (D)
CH3 CH2 CH2 CHCH2 CH3
H3C

Paragraph for Question Nos. 14 to 16

When a metal rod M is dipped into an aqueous colourless concentrated solution of compound N, the solution turns
light blue. Addition of aqueous NaCl to the blue solution gives a white precipitate O. Addition of aqueous NH3
dissolves O and gives an intense blue solution.

14. The metal rod M is


(A) Fe (B) Cu
(C) Ni (D) Co

15. The compound N is


(A) AgNO3 (B) Zn(NO3)2
(C) Al(NO3)3 (D) Pb(NO3)2

16. The final solution contains


2+ 3+ 2+
(A) ⎡⎣ Pb ( NH 3 )4 ⎤⎦ and [ CoCl4 ] (B) ⎡⎣ Al ( NH 3 )4 ⎤⎦ and ⎡⎣ Cu ( NH 3 )4 ⎤⎦
2−

+ 2+ + 2+
(C) ⎡⎣ Ag ( NH 3 )2 ⎤⎦ and ⎡⎣ Cu ( NH 3 )4 ⎤⎦ (D) ⎡⎣ Ag ( NH 3 )2 ⎤⎦ and ⎡⎣ Ni ( NH 3 )6 ⎤⎦

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IITJEE2011-Paper 1-CPM-5

SECTION-IV (Total Marks : 28)


(Integer Answer Type)
This section contains 7 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The bubble corresponding to the correct is to be darkened in the ORS.

*17. The difference in the oxidation numbers of the two types of sulphur atoms in Na2S4O6 is

18. A decapeptide (Mol. Wt. 796) on complete hydrolysis gives glycine (Mol. Wt. 75), alanine and
phenylalanine. Glycine contributes 47.0% to the total weight of the hydrolysed products. The number of
glycine units present in the decapeptide is

*19. The work function ( φ) of some metals is listed below. The number of metals which will show
photoelectric effect when light of 300 nm wavelength falls on the metal is
Metal Li Na K Mg Cu Ag Fe Pt W
φ (eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

*20. The maximum number of electrons that can have principal quantum number, n = 3, and spin quantum
1
number, ms = − , is
2

*21. Reaction of Br2 with Na2CO3 in aqueous solution gives sodium bromide and sodium bromate with
evolution of CO2 gas. The number of sodium bromide molecules involved in the balanced chemical
equation is

*22. To an evacuated vessel with movable piston under external pressure of 1 atm, 0.1 mol of He and 1.0 mol of
an unknown compound (vapour pressure 0.68 atm. at 0oC) are introduced. Considering the ideal gas
behaviour, the total volume (in litre) of the gases at 0oC is close to

*23. The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane using


alcoholic KOH is

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IITJEE2011-Paper 1-CPM-6

PART - II: PHYSICS


SECTION – I (Total Marks : 21)
(Single Correct Answer Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

*24. A police car with a siren of frequency 8 kHz is moving with uniform velocity 36 km/hr towards a tall
building which reflects the sound waves. The speed of sound in air is 320 m/s. The frequency of the siren
heard by the car driver is
(A) 8.50 kHz (B) 8.25 kHz
(C) 7.75 kHz (D) 7.50 kHZ

o
25. The wavelength of the first spectral line in the Balmer series of hydrogen atom is 6561 A . The wavelength
of the second spectral line in the Balmer series of singly-ionized helium atom is
o o
(A) 1215 A (B) 1640 A
o o
(C) 2430 A (D) 4687 A

z
26. Consider an electric field E = E 0 xˆ , where E0 is a constant. The flux
through the shaded area (as shown in the figure) due to this field is (a,0,a) (a,a,a)

(A) 2E0 a2 (B) 2E 0 a 2


E0 a 2 y
(C) E0 a2 (D) x (0,0,0) (0,a,0)
2

*27. 5.6 liter of helium gas at STP is adiabatically compressed to 0.7 liter. Taking the initial temperature to be
T1, the work done in the process is
9 3
(A) RT1 (B) RT1
8 2
15 9
(C) RT1 (D) RT1
8 2

28. A 2 µF capacitor is charged as shown in the figure. The percentage of its 1 2


stored energy dissipated after the switch S is turned to position 2 is S
(A) 0 % (B) 20 %
V
(C) 75 % (D) 80 % 2µ F 8µ F

29. A meter bridge is set-up as shown, to determine an


unknown resistance ‘X’ using a standard 10 ohm resistor. X 10 Ω
The galvanometer shows null point when tapping-key is at
52 cm mark. The end-corrections are 1 cm and 2 cm
respectively for the ends A and B. The determined value of A B
‘X’ is
(A) 10.2 ohm (B) 10.6 ohm
(C) 10.8 ohm (D) 11.1 ohm

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IITJEE2011-Paper 1-CPM-7

*30. A ball of mass (m) 0.5 kg is attached to the end of a string having length
(L) 0.5 m. The ball is rotated on a horizontal circular path about vertical
axis. The maximum tension that the string can bear is 324 N. The L
maximum possible value of angular velocity of ball (in radian/s) is
(A) 9 (B) 18
(C) 27 (D) 36
m

SECTION – II (Total Marks : 16)


(Multiple Correct Answers Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE OR MORE may be correct.

*31. A metal rod of length ‘L’ and mass ‘m’ is pivoted at one end. A thin disk of mass
‘M’ and radius ‘R’ (<L) is attached at its center to the free end of the rod. Consider
two ways the disc is attached: (case A). The disc is not free to rotate about its
centre and (case B) the disc is free to rotate about its centre. The rod-disc system
performs SHM in vertical plane after being released from the same displaced
position. Which of the following statement(s) is (are) true?
(A) Restoring torque in case A = Restoring torque in case B
(B) restoring torque in case A < Restoring torque in case B
(C) Angular frequency for case A > Angular frequency for case B.
(D) Angular frequency for case A < Angular frequency for case B.

32. A spherical metal shell A of radius RA and a solid metal sphere B of radius RB (<RA) are kept far apart and
each is given charge ‘+Q’. Now they are connected by a thin metal wire. Then
(A) E inside
A =0 (B) QA > QB
σA R B
(C) = (D) E on surface
< E on surface

σB R A
A B

*33. A composite block is made of slabs A, B, C, D and E of 0 1L 5L 6L


heat
different thermal conductivities (given in terms of a A B 3K E
constant K) and sizes (given in terms of length, L) as 1L
shown in the figure. All slabs are of same width. Heat 6K
‘Q’ flows only from left to right through the blocks. Then 2K C 4K
in steady state 3L
(A) heat flow through A and E slabs are same.
D 5K
(B) heat flow through slab E is maximum. 4L
(C) temperature difference across slab E is smallest.
(D) heat flow through C = heat flow through B + heat flow through D.

34. An electron and a proton are moving on straight parallel paths with same velocity. They enter a semi-
infinite region of uniform magnetic field perpendicular to the velocity. Which of the following
statement(s) is / are true?
(A) They will never come out of the magnetic field region.
(B) They will come out travelling along parallel paths.
(C) They will come out at the same time.
(D) They will come out at different times.

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IITJEE2011-Paper 1-CPM-8

SECTION-III (Total Marls : 15)


(Paragraph Type)
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based on the
other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.
Paragraph for Question Nos. 35 and 36
A dense collection of equal number of electrons and positive ions is called neutral plasma. Certain solids containing
fixed positive ions surrounded by free electrons can be treated as neutral plasma. Let ‘N’ be the number density of
free electrons, each of mass ‘m’. When the electrons are subjected to an electric field, they are displaced relatively
away from the heavy positive ions. If the electric field becomes zero, the electrons begin to oscillate about the
positive ions with a natural angular frequency ‘ωp’ which is called the plasma frequency. To sustain the oscillations,
a time varying electric field needs to be applied that has an angular frequency ω, where a part of the energy is
absorbed and a part of it is reflected. As ω approaches ωp all the free electrons are set to resonance together and all
the energy is reflected. This is the explanation of high reflectivity of metals.

35. Taking the electronic charge as ‘e’ and the permittivity as ‘ε0’. Use dimensional analysis to determine the
correct expression for ωp.
Ne mε 0
(A) (B)
mε 0 Ne
Ne 2 mε 0
(C) (D)
mε 0 Ne 2

36. Estimate the wavelength at which plasma reflection will occur for a metal having the density of electrons
N ≈ 4 × 1027 m-3. Taking ε0 = 10-11 and m ≈ 10-30, where these quantities are in proper SI units.
(A) 800 nm (B) 600 nm
(C) 300 nm (D) 200 nm
Paragraph for Question Nos. 37 to 39
Phase space diagrams are useful tools in analyzing all kinds of dynamical problems.
They are especially useful in studying the changes in motion as initial position and Momentum
momenum are changed. Here we consider some simple dynamical systems in one-
dimension. For such systems, phase space is a plane in which position is plotted along
horizontal axis and momentum is plotted along vertical axis. The phase space diagram is
x(t) vs. p(t) curve in this plane. The arrow on the curve indicates the time flow. For
example, the phase space diagram for a particle moving with constant velocity is a Position
straight line as shown in the figure. We use the sign convention in which positon or
momentum upwards (or to right) is positive and downwards (or to left) is negative.
*37. The phase space diagram for a ball thrown vertically up from ground is
Momentum Momentum

(A) (B)
Position Position

Momentum Momentum

(C) (D)
Position Position

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IITJEE2011-Paper 1-CPM-9

*38. The phase space diagram for simple harmonic motion is a circle Momentum
centered at the origin. In the figure, the two circles represent the same
E1
oscillator but for different initial conditions, and E1 and E2 are the
E2
total mechanical energies respectively. Then
2a
(A) E1 = 2E 2 (B) E1 = 2E2
a Position
(C) E1 = 4E2 (D) E1 = 16E2

*39. Consider the spring-mass system, with the mass submerged in


water, as shown in the figure. The phase space diagram for one
cycle of this system is

(A) Momentum (B) Momentum

Position Position

(C) Momentum (D) Momentum

Position Position

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IITJEE2011-Paper 1-CPM-10

SECTION-IV (Total Marks : 28)


(Integer Answer Type)
This section contains 7 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The bubble corresponding to the correct is to be darkened in the ORS.

*40. A boy is pushing a ring of mass 2 kg and radius 0.5 m with a stick as Stick
shown in the figure. The stick applies a force of 2N on the ring and rolls it
without slipping with an acceleration of 0.3 m/s2. The coefficient of
friction between the ground and the ring is large enough that rolling
always occurs and the coefficeint of friction between the stick and the ring
is (P/10). The value of P is

Ground

*41. Four solid spheres each of diameter 5 cm and mass 0.5 kg are placed with their centers at the corners of
a square of side 4 cm. The moment of inertia of the system about the diagonal of the square is N × 10−4 kg-
m2, then N is

*42. Steel wire of lenght ‘L’ at 40°C is suspended from the ceiling and then a mass ‘m’ is hung from its free
end. The wire is cooled down from 40°C to 30°C to regain its original length ‘L’. The coefficient of linear
thermal expansion of the steel is 10−5/°C, Young’s modulus of steel is 1011 N/m2 and radius of the wire is 1
mm. Assume that L diameter of the wire. Then the value of ‘m’ in kg is nearly

43. Four point charges, each of +q, are rigidly fixed at the four corners of a square planar soap film of side ‘a’.
The surface tension of the soap film is γ. The system of charges and planar film are in equilibrium, and
1/ N
⎡ q2 ⎤
a = k⎢ ⎥ , where ‘k’ is a constant. Then N is
⎣γ⎦

*44. A block is moving on an inclined plane making an angle 45° with the horizontal and the coefficient of
friction is µ. The force required to just push it up the inclined plane is 3 times the force required to just
prevent it from sliding down. If we define N = 10 µ, then N is

45. The activity of a freshly prepared radioactive sample is 1010 disintegrations per second, whose mean life is
109 s. The mass of an atom of this radioisotope is 10−25 kg. The mass (in mg) of the radioactive sample is

46. A long circular tube of length 10 m and radius 0.3 m carries a current I along its
curved surface as shown. A wire-loop of resistance 0.005 ohm and of radius 0.1 m is
placed inside the tube with its axis coinciding with the axis of the tube. The current
varies as I = I0cos(300 t) where I0 is constant. If the magnetic moment of the loop is
Nµ0I0sin(300 t), then ‘N’ is
I

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IITJEE2011-Paper 1-CPM-11

PART - III: MATHEMATICS


SECTION – I (Total Marks : 21)
(Single Correct Answer Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.

*47. Let (x0, y0) be solution of the following equations


(2x)ln2 = (3y)ln3
3lnx = 2lny
Then x0 is
1 1
(A) (B)
6 3
1
(C) (D) 6
2

*48. Let P = {θ : sin θ − cos θ = 2 cos θ} and Q = {θ : sin θ + cos θ = 2 sin θ} be two sets. Then
(A) P ⊂ Q and Q − P ≠ ∅ (B) Q ⊄ P
(C) P ⊄ Q (D) P = Q

49. Let a = ˆi + ˆj + kˆ , b = ˆi + ˆj + kˆ and c = ˆi − ˆj − kˆ be three vectors. A vector v in the plane of a and b , whose
1
projection on c is , is given by
3
(A) ˆi − 3ˆj + 3kˆ (B) −3ˆi − 3ˆj + kˆ
(C) 3ˆi − ˆj + 3kˆ (D) ˆi + 3ˆj − 3kˆ

ln 3
x sin x 2
50. The value of ∫ sin x 2 + sin ( ln 6 − x 2 )
dx is
ln 2
1 3 1 3
(A) ln (B) ln
4 2 2 2
3 1 3
(C) ln (D) ln
2 6 2

*51. A straight line L through the point (3, −2) is inclined at an angle 60° to the line 3x + y = 1 . If L also
intersects the x-axis, then the equation of L is
(A) y + 3x + 2 − 3 3 = 0 (B) y − 3x + 2 + 3 3 = 0
(C) 3y − x + 3 + 2 3 = 0 (D) 3y + x − 3 + 2 3 = 0

a10 − 2a 8
*52. Let α and β be the roots of x2 – 6x – 2 = 0, with α > β. If an = αn – βn for n ≥ 1, then the value of
2a 9
is
(A) 1 (B) 2
(C) 3 (D) 4

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IITJEE2011-Paper 1-CPM-12

53. Let the straight line x = b divides the area enclosed by y = (1 − x)2, y = 0 and x = 0 into two parts R1(0 ≤ x
1
≤ b) and R2(b ≤ x ≤ 1) such that R1 − R2 = . Then b equals
4
3 1
(A) (B)
4 2
1 1
(C) (D)
3 4

SECTION – II (Total Marks : 16)


(Multiple Correct Answers Type)
This section contains 4 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONE or MORE may be correct.

54. Let f: R → R be a function such that f(x + y) = f(x) + f(y), ∀ x, y ∈ R. If f(x) is differentiable at x = 0, then
(A) f(x) is differentiable only in a finite interval containing zero
(B) f(x) is continuous ∀ x ∈ R
(C) f′(x) is constant ∀ x ∈ R
(D) f(x) is differentiable except at finitely many points

55. The vector(s) which is/are coplanar with vectors ˆi + ˆj + 2kˆ and ˆi + 2ˆj + kˆ , and perpendicular to the vector
ˆi + ˆj + kˆ is/are

(A) ˆj − kˆ (B) −ˆi + ˆj


(C) ˆi − ˆj (D) −ˆj + kˆ

x2 y2
*56. Let the eccentricity of the hyperbola 2
− 2
= 1 be reciprocal to that of the ellipse x2 + 4y2 = 4. If the
a b
hyperbola passes through a focus of the ellipse, then
x 2 y2
(A) the equation of the hyperbola is − =1 (B) a focus of the hyperbola is (2, 0)
3 2
5
(C) the eccentricity of the hyperbola is (D) the equation of the hyperbola is x2 – 3y2 = 3
3

57. Let M and N be two 3 × 3 non-singular skew symmetric matrices such that MN = NM. If PT denotes the
transpose of P, then M2N2 (MTN)–1 (MN–1)T is equal to
(A) M2 (B) – N2
2
(C) – M (D) MN

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IITJEE2011-Paper 1-CPM-13

SECTION-III (Total Marls : 15)


(Paragraph Type)
This section contains 2 paragraphs. Based upon one of paragraphs 2 multiple choice questions and based on the
other paragraph 3 multiple choice questions have to be answered. Each of these questions has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

Paragraph for Question Nos. 58 to 59

Let U1 and U2 be two urns such that U1 contains 3 white and 2 red balls, and U2 contains only 1 white ball. A fair
coin is tossed. If head appears then 1 ball is drawn at random from U1 and put into U2. However, if tail appears then
2 balls are drawn at random from U1 and put into U2. Now 1 ball is drawn at random from U2.

58. The probability of the drawn ball from U2 being white is


13 23
(A) (B)
30 30
19 11
(C) (D)
30 30

59. Given that the drawn ball from U2 is white, the probability that head appeared on the coin is
17 11
(A) (B)
23 23
15 12
(C) (D)
23 23

Paragraph for Question Nos. 60 to 62

⎡1 9 7 ⎤
Let a, b and c be three real numbers satisfying [ a b c] ⎢⎢8 2 7 ⎥⎥ = [ 0 0 0] ……(E)
⎣⎢7 3 7 ⎥⎦

60. If the point P(a, b, c), with reference to (E), lies on the plane 2x + y + z = 1, then the value of 7a + b + c is
(A) 0 (B) 12
(C) 7 (D) 6

61. Let ω be a solution of x3 – 1 = 0 with Im(ω) > 0. If a = 2 with b and c satisfying (E), then the value of
3 1 3
+ b + c is equal to
ωa
ω ω
(A) –2 (B) 2
(C) 3 (D) – 3

62. Let b = 6, with a and c satisfying (E). If α and β are the roots of the quadratic equation ax2 + bx + c = 0,
∞ n
⎛ 1 1⎞
then ∑ ⎜α +β⎟
n =0 ⎝ ⎠
is

(A) 6 (B) 7
6
(C) (D) ∞
7

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IITJEE2011-Paper 1-CPM-14

SECTION-IV (Total Marks : 28)


(Integer Answer Type)
This section contains 7 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The bubble corresponding to the correct is to be darkened in the ORS.

*63. Consider the parabola y2 = 8x. Let ∆1 be the area of the triangle formed by the end points of its latus rectum
⎛1 ⎞
and the point P ⎜ , 2 ⎟ on the parabola, and ∆2 be the area of the triangle formed by drawing tangents at P
⎝2 ⎠

and at the end points of the latus rectum. Then 1 is
∆2

⎛ ⎛ sin θ ⎞ ⎞ π π d
64. Let f(θ) = sin ⎜ tan −1 ⎜ ⎟ ⎟ , where − 4 < θ < 4 . Then the value of d ( tan θ ) ( f ( θ ) ) is
⎝ ⎝ cos 2θ ⎠⎠

x
65. ∫
Let f: [1, ∞) → [2, ∞) be a differentiable function such that f(1) = 2. If 6 f ( t ) dt = 3xf ( x ) − x 3 for all x ≥
1
1, then the value of f(2) is

1 1 1
*66. The positive integer value of n > 3 satisfying the equation = + is
⎛π⎞ ⎛ 2π ⎞ ⎛ 3π ⎞
sin ⎜ ⎟ sin ⎜ ⎟ sin ⎜ ⎟
⎝n⎠ ⎝ n ⎠ ⎝ n ⎠

p
*67. Let a1, a2, a3, …, a100 be an arithmetic progression with a1 = 3 and Sp = ∑a
i =1
i , 1 ≤ p ≤ 100. For any integer

Sm
n with 1 ≤ n ≤ 20, let m = 5n. If does not depend on n, then a2 is
Sn

*68. If z is any complex number satisfying |z – 3 – 2i| ≤ 2, then the minimum value of |2z – 6 + 5i| is

*69. The minimum value of the sum of real numbers a–5, a–4, 3a–3, 1, a8 and a10 with a > 0 is

******

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IITJEE2011-Paper 1-CPM-15

PAPER-1 [Code – 8]
IITJEE 2011
ANSWERS

PART - I: CHEMISTRY

1. D 2. C 3. A 4. B
5. A 6. C 7. D 8. B, C
9. A, C, D 10. A, B, C, D 11. A, B, D 12. D
13. B 14. B 15. A 16. C
17. 5 18. 6 19. 4 20. 9
21. 5 22. 7 23. 5

PART - II: PHYSICS


24. A 25. A 26. C 27. A
28. D 29. B 30. D 31. A, D
32. A, B, C, D 33. A, C, D or A, B, C, D 34. B, D
35. C 36. B 37. D 38. C
39. B 40. 4 41. 9 42. 3
43. 3 44. 5 45. 1 46. 6

PART - III: MATHEMATICS


47. C 48. D 49. C 50. A
51. B 52. C 53. B 54. B, C
55. A, D 56. B, D 57. C 58. B
59. D 60. D 61. A 62. B
63. 2 64. 1 65. 6 66. 7
67. 9 68. 5 69. 8

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IITJEE2011-Paper 1-CPM-16

HINTS AND SOLUTIONS

PART - I: CHEMISTRY
1. Ba ( N3 )2 ⎯⎯

→ Ba + 3N 2

2. Total mass of solution = 1000 + 120 = 1120 g


1120
Total volume of solution in (L) = × 103
1.15
W 1 120 1.15 × 103
M= × = × = 2.05 M
M V ( in L ) 60 1120

3. 27
13 Al + 2 α 4 →14
30
Si + 1p1 ( X )
27
13 Al + 2 α 4 →15
30
P + 0 n1 ( Y )
30
15 P → 14
30
Si + +1 β0 ( Z )

[ NiCl4 ] → Tetrahedral
2−
4.
2−
⎡⎣ Ni ( CN )4 ⎤⎦ → Square Planar
2+
⎡⎣ Ni ( H 2 O )6 ⎤⎦ → Octahedral

5. O O

()
⎯⎯⎯⎯⎯⎯⎯⎯⎯

i KOH
NH N CH2 Br
( ii ) Br CH2 Cl

O O
[Reason: Due to partial double bond character along C−Br bond prevents the attack of nucleophile at
phenylic position]

6. Due to ortho effect o-hydroxy benzoic acid is strongest acid and correct order of decreasing Ka is
COOH COOH COOH OH

OH

> > >

CH3 OH NO2

7. AgNO3 + KCl ( aq ) → AgCl ( s ) + KNO3 ( aq )


Initially there is aq. KCl solution now as solution of AgNO3 is added, AgCl(s) is formed. Hence
conductivity of solution is almost compensated (or slightly increase) by the formation of KNO3. After end
point conductivity increases more rapidly because addition of excess AgNO3 solution.

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IITJEE2011-Paper 1-CPM-17

8. Along C−C single bond conformations are possible in butadiene in which all the atoms may not lie in the
same plane.

9. SnO 2 + 2C → 2CO + Sn
The ore cassiterite contains the impurity of Fe, Mn, W and traces of Cu.

Solution for the Q. No. 12 to 13


O H3C OH
H3C H3C
( i ) NaBH 4 / EtOH
( ii ) dil. H +
H ⎯⎯⎯⎯ → H3C CH3 ⎯⎯⎯⎯⎯⎯
→H3C C CH CH3
dil. H 2 SO4
H3C C C C HgSO 4 C C
(Q)
H3C (P) H3C H3C
∆ H 2 SO 4 ( conc.)

H3C CH3 H3C CH3


C O+ O C ←⎯⎯⎯⎯

O3 / Zn / H 2 O
C C
H3C CH3 H3C CH3

14. Cu + 2AgNO3 → Cu ( NO3 )2 + 2Ag


M N Blue
While Cu partially oxidizes to Cu(NO3)2 and remaining AgNO3 reacts with NaCl.

16. AgNO3 + NaCl → AgCl ↓ + NaNO3


( N) (O)
+
AgCl + 2NH 3 → ⎡⎣ Ag ( NH 3 )2 ⎤⎦ Cl−
2+
Cu ( NO3 )2 + 4NH 4 OH → ⎡⎣ Cu ( NH 3 )4 ⎤⎦

17. O O
Na O S S S S O Na
O O
S will have oxidation number = +5, 0
Difference in oxidation number = 5

18. For n-units of glycine,


n × 75
× 100 = 47
( 796 + 9 ×18 )
⇒n=6
hc
19. The energy associated with incident photon =
λ
6.6 × 10−34 × 3 ×108
⇒E= J
300 × 10−9
6.6 ×10−34 × 3 × 108
E in eV = = 4.16 eV
300 ×10−9 ×1.6 ×10−19
So, number of metals showing photo-electric effects will be (4), i.e., Li, Na, K, Mg

20. For principal quantum number (n = 3)


Number of orbitals = n2 = 9

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IITJEE2011-Paper 1-CPM-18

1
So, number of electrons with ms = − will be 9.
2

21. 3Br2 + 3Na 2 CO3 ⎯⎯


→ 5NaBr + NaBrO3 + 3CO2
So, number of NaBr molecules = 5

22. For any ideal gas, PV = nRT 1 atm


0.32 × V = 0.1 × 0.0821 × 273
V = 7 litre
(unknown compound X will not follow
ideal gas equation) He + X
For He, n = 0.1, P = 0.32 atm., V = ?, T = 273

23. Total no. of alkenes will be = 5


Br
H3C CH2 CH2 C CH2 CH3 H3C CH2 CH2 C CH CH3

( E & Z)
⎯⎯⎯⎯
alc. KOH

H3C CH2 CH C CH2 CH3


or ( E & Z)

H3C CH2 CH2 C CH2 CH3


or ( only 1)

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IITJEE2011-Paper 1-CPM-19

PART - II: PHYSICS

320 320 + 10
24. f= × 8 × 103 ×
320 − 10 320
= 8.5 kHz

1 ⎛ 1 1 ⎞ 5R
25. = R⎜ − ⎟ =
6561 ⎝ 4 9 ⎠ 36
1 ⎛ 1 1 ⎞ 3R × 4
= 4R ⎜ − ⎟ =
λ ⎝ 4 16 ⎠ 16
λ = 1215A0

26. (E0) (Projected area ) = E0a2

27. TVγ-1 = C
⇒ T2 = T1(8)2/3 = 4T1
T1(5.6)2/3 = T2 (0.7)2/3
nR∆T 9
∴ ∆w(work done on the system) = = RT1
γ −1 8

1
28. Ui = × 2 × V2 = V2
2 2V-q q
qi = 2V
Now, switch S is turned to position 2
2V − q q
=
2 8
8V – 4q = q
8V
⇒q=
5
⎛ 64V 2 4V 2 ⎞
∆H = V2 - ⎜ + ⎟
⎝ 2 × 25 × 8 2 × 25 × 2 ⎠
4V 2
=
5

29. X (48 + 2) = (10) (52 + 1)


530
X= = 10.6Ω
50

30. 324 = 0.5 ω2 (0.5)


ω2 = 324 × 4
ω = 1296 = 36 rad / s

31. In case A
⎛ m 2 MR 2 ⎞
mg( /2) sin θ + Mg sin θ = ⎜ + + M 2 ⎟ αA
⎝ 3 2 ⎠

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IITJEE2011-Paper 1-CPM-20

In case B
⎛m 2 ⎞
mg ( /2) sin θ + Mg sin θ = ⎜ +M 2
⎟ αB
⎝ 3 ⎠
τA = τB, ωA < ωB

32. RB < RA
QA + QB = 2Q
kQ A kQ B
=
RA RB
σARA = σBRB
2QR A
QA =
RA + RB
2QR B
QB =
RA + RB

33. Let width of each rod is d


1 4
R1 = , R2 = 2
8kd 3kd
1 4 5
R3 = , R4 = 1 3
2kd 5kd
1
R5 = ,
24kd 4

R2
R1 R5

R3

R4

34. Both will travel in semicircular path

Since, m is different, hence time will be different

36. ω = 2πc / λ

38. E ∝ A2

40. Now R

N − fs = ma ∴ fs = 1.4 N a

and (fs − fK)R = Iα, a = Rα


∴ fK = 0.8 N α
N
P fk
So, µ = = 0.4
10 fs
P=4 Mg

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IITJEE2011-Paper 1-CPM-21

⎛2 2 ⎞
⎡2 2 ⎛ a ⎞ ⎤
2

41. I = 2 ⎜ × mr ⎟ + 2 ⎢ mr + m ⎜ ⎟ ⎥ m, r
⎝5 ⎠ ⎢⎣ 5 ⎝ 2 ⎠ ⎥⎦
I = 9 × 10−4 kg-m2
∴N=9

MgL
42. Change in length ∆L = = Lα∆T
YA
∴ m ≈ 3 kg

q2
43. Since Felectric ∝ ∝ γa
a2
1/3
⎛ q2 ⎞
∴ a = k⎜ ⎟
⎝ γ ⎠
∴N=3

44. mg(sin θ + µcosθ) = 3mg(sinθ − µcosθ)


∴ µ = 0.5
∴N=5

dN
45. = λN
dt
⎛ dN ⎞
⎜ ⎟
∴N= ⎝
dt ⎠
= 1010 × 109 = 1019 atoms
λ
msample = 10−25 × 1019 kg = 1 mg

µo I
46. Binside = µ0ni =
L
dφ µ (πr 2 ) dI
∴ Eind = − =− 0
dt L dt
⎛E ⎞ 2
So magnetic moment = ⎜ ind ⎟ πr
⎝ R ⎠
= 6µ0I0sin(300t)
Therefore, n = 6

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IITJEE2011-Paper 1-CPM-22

PART - III: MATHEMATICS

47. (2x)ln2 = (3y)ln3 …(i)


3lnx = 2lny …(ii)
⇒ (logx) (log3) = (logy)log2
(log x)(log 3)
⇒ logy = …(iii)
log 2
In (i) taking log both sides
(log2) {log2 + logx} = log3{log3 + logy}
(log 3)2 (log x )
(log2)2 + (log2) (logx) = (log3)2 + from (iii)
log 2
(log 3)2 − (log 2)2 1 1
⇒ (log2)2 − (log3)2 = (log x) ⇒ −log2 = logx ⇒ x = ⇒ x0 = .
log 2 2 2

48. In set P, sinθ =( 2 + 1) cos θ ⇒ tanθ = 2 +1

In set Q, ( 2 − 1) sin θ = cos θ ⇒ tan θ =


1
= 2 + 1 ⇒ P = Q.
2 −1

49. ( ) (
v = λ a + µb = λ ˆi + ˆj + kˆ + µ ˆi − ˆj + kˆ )
Projection of v on c
v⋅c
=
1
⇒ ⎣
(
⎦ )
⎡( λ + µ ) ˆi + ( λ − µ ) ˆj + ( λ + µ ) kˆ ⎤ ⋅ ˆi − ˆj − kˆ
=
1
|c| 3 3 3
⇒λ+µ−λ+µ−λ−µ=1⇒µ−λ=1⇒λ=µ−1
( ) ( ) ( )
v = ( µ − 1) ˆi + ˆj + kˆ + µ ˆi − ˆj + kˆ = µ 2iˆ + 2kˆ − ˆi − ˆj − kˆ

v = ( 2µ − 1) ˆi − ˆj + ( 2µ − 1) kˆ
At µ = 2, v = 3iˆ − ˆj + 3kˆ .

50. x2 = t ⇒ 2x dx = dt
1
ln 3
sin t 1
ln 3
sin ( ln 6 − t )
I= ∫ dt and I = ∫ dt
2 ln 2 sin t + sin ( ln 6 − t ) 2 ln 2 sin ( ln 6 − t ) + sin t
ln 3
1 1 3
2 ln∫2
2I = 1dt ⇒ I = ln .
4 2

m+ 3
51. = 3 y =− 3x + 1
1 − 3m
m
⇒ m+ 3 = ± ( 3 − 3m ) (0, 1)
⇒ 4m = 0 ⇒ m = 0
or 2m = 2 3 ⇒ m = 3 60°
∴ Equation is y + 2 = 3 ( x − 3) (3, −2)

⇒ (
3x − y − 2 + 3 3 = 0 . )

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IITJEE2011-Paper 1-CPM-23

52. an = αn − βn
α2 − 6α − 2 = 0
Multiply with α8 on both sides
⇒ α10 − 6α9 − 2α8 = 0 …(i)
similarly β10 − 6β9 − 2β8 = 0 …(ii)
(i) and (ii)
⇒ α10 − β10 − 6(α9 − β9) = 2(α8 − β8)
a − 2a 8
⇒ a10 − 6a9 = 2a8 ⇒ 10 =3.
2a 9
b 1
1
∵ ∫ (1 − x ) dx − ∫ (1 − x ) dx =
2 2
53.
0 b
4
3 b 1
( x − 1) ( x − 1)3 1 R1
⇒ − = R2
3 0 3 b 4
o b 1
( b − 1)3 1 ⎛ ( b − 1)3 ⎞ 1
⇒ + −⎜0 − ⎟=
3 3 ⎝ 3 ⎠ 4
2 ( b − 1)
3
1 1 1
⇒ =− ⇒ (b – 1)3 = – ⇒ b = .
3 12 8 2

54. ∵ f(0) = 0
f (x + h ) − f (x ) f (h )
and f′(x) = lim = = lim = f′(0) = k(say)
h
h →0 h →0 h
⇒ f(x) = kx + c ⇒ f(x) = kx (∵ f(0) = 0).
55. Any vector in the plane of ˆi + ˆj + 2kˆ and ˆi + 2ˆj + kˆ is r = ( λ + µ ) ˆi + ( λ + 2µ ) ˆj + ( 2λ + µ ) kˆ
Also, r ⋅ c = 0 ⇒ λ + µ = 0
⇒ ⎡⎣ r a b ⎤⎦ = 0 .

x 2 y2
56. Ellipse is + =1
22 12
3
12 = 22 (1 − e2) ⇒ e =
2
2 ⎛4 ⎞
∴ eccentricity of the hyperbola is ⇒ b2 = a 2 ⎜ − 1⎟ ⇒ 3b2 = a2
3 ⎝3 ⎠
Foci of the ellipse are ( )
3, 0 and − 3, 0 .( )
Hyperbola passes through ( 3, 0 )
3
= 1 ⇒ a2 = 3 and b2 = 1
a2
∴ Equation of hyperbola is x2 − 3y2 = 3
⎛ 2 ⎞
Focus of hyperbola is (ae, 0) ≡ ⎜ 3 × , 0 ⎟ ≡ (2, 0).
⎝ 3 ⎠
57. MN = NM
M2N2(MTN)−1(MN−1)T
M2N2N−1(MT)−1(N−1)T.MT
= M2N.(MT)−1(N−1)TMT = −M2.N(M)−1(NT)−1MT
= +M2NM−1N−1MT = −M.NMM−1N−1M = −MNN−1M = −M2.
Note: A skew symmetric matrix of order 3 cannot be non-singular hence the question is wrong.

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IITJEE2011-Paper 1-CPM-24

58. H → 1 ball from U1 to U2


T → 2 ball from U1 to U2
E : 1 ball drawn from U2
1 ⎛ 3 ⎞ 1 ⎛ 2 1 ⎞ 1 ⎛ 3 C 2 ⎞ 1 ⎛ 2 C 2 1 ⎞ 1 ⎛ 3 C1 ⋅2 C1 2 ⎞ 23
P/W from U2 = × ⎜ × 1⎟ + × ⎜ × ⎟ + × ⎜ × 1⎟ + × ⎜ × ⎟ + ×⎜ × ⎟ = .
2 ⎝ 5 ⎠ 2 ⎝ 5 2 ⎠ 2 ⎜⎝ 5 C 2 ⎟⎠ 2 ⎜⎝ 5 C 2 3 ⎟⎠ 2 ⎜⎝ 5 C 2 3 ⎟⎠ 30

1⎛3 2 1⎞
P( W / H ) × P( H ) ⎜ × 1 + × ⎟ 12
⎛H⎞ 2⎝5 5 2⎠ =
59. P⎜ ⎟ = = .
⎝ W ⎠ P( W / T ) ⋅ P( T ) + ( W / H ) ⋅ P ( H ) 23 / 30 23

60. a + 8b + 7c = 0
9a + 2b + 3c = 0
a+b+c=0
Solving these we get
b = 6a ⇒ c = – 7a
now 2x + y + z = 0
⇒ 2a + 6a + (–7a) = 1 ⇒ a = 1, b = 6, c = – 7.

61. a = 2, b and c satisfies (E)


b = 12, c = – 14
3 1 3 3 1 3
+ + = + + = – 2.
ωa ωb ωc ω2 ω12 ω−14

62. ax2 + bx + c = 0 ⇒ x2 + 6x – 7 = 0
⇒ α = 1, β = – 7
∞ n ∞ n
⎛ 1 1⎞ ⎛1 1 ⎞
∑ ⎜α +β⎟ =
n =0 ⎝ ⎠ n =0

⎜ − ⎟ = 7.
⎝1 7 ⎠

63. y2 = 8x = 4.2.x L
∆LPM A (2, 4)
=2
∆ABC
P(1/2, 2)
∆1
B(0, 2)
=2
∆2 C
(0, 0) (2, 0)

M
(2, −4)
x=−2

⎛ ⎛ sin θ ⎞ ⎞ ⎛ π π⎞
64. sin ⎜ tan −1 ⎜ ⎟ ⎟ , where θ ∈ ⎜ − , ⎟
⎝ ⎝ cos 2θ ⎠ ⎠ ⎝ 4 4⎠
⎛ ⎛ sin θ ⎞⎞
sin ⎜ tan −1 ⎜⎜ ⎟⎟ ⎟⎟

⎝ 2 cos θ − 1 ⎠ ⎠
2

= sin ( sin −1 ( tan θ ) ) = tan θ.
d ( tan θ )
=1.
d ( tan θ )

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IITJEE2011-Paper 1-CPM-25

x
65. 6 ∫ f ( t ) dt = 3x f(x) – x3 ⇒ 6f(x) = 3f(x) + 3xf′(x) – 3x2
1

⇒ 3f(x) = 3xf′(x) – 3x2 ⇒ xf′(x) – f(x) = x2


dy dy 1
⇒ x − y = x2 ⇒ − y = x …(i)
dx dx x
1
I.F. = e ∫ x = e − loge x
− dx

1
Multiplying (i) both sides by
x
1 dy 1 d ⎛ 1⎞
− y =1 ⇒ ⎜ y. ⎟ = 1
x dx x 2 dx ⎝ x ⎠
integrating
y
= x+c
x
Put x = 1, y = 2
⇒ 2 = 1 + c ⇒ c = 1 ⇒ y = x2 + x
⇒ f(x) = x2 + x ⇒ f(2) = 6.
Note: If we put x = 1 in the given equation we get f(1) = 1/3.

3π π ⎛ π 2π ⎞ 2π
− sin
sin ⎜ 2sin cos ⎟ sin
66.
1

1
=
1
⇒ n n = 1 ⎝ n n ⎠ n
=1
π 3π 2π π 3π 2π π 3π
sin sin sin sin sin sin sin sin
n n n n n n n n
4π 3π 4π 3π
⇒ sin = sin ⇒ + = π ⇒ n = 7.
n n n n

67. a1, a2, a3, … a100 is an A.P.


p
a1 = 3, Sp = ∑a
i =1
i , 1 ≤ p ≤ 1 00

Sm S5n
5n
( 6 + ( 5n − 1) d )
= = 2
n
Sn Sn
( 6 − d + nd )
2
Sm
is independent of n of 6 − d = 0 ⇒ d = 6.
Sn

5
68. Length AB =
2 C (3, 2)
⇒ Minimum value = 5.

(0, 0) B (3, 0)

A(3, −5/2)

a −5 + a −4 + a −3 + a −3 + a −3 + a 8 + a10 + 1
69. ≥1
8
minimum value = 8.
******

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