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Date issued: Replaces: 11-07-2001 21-06-2001
IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY
PRODUCT NAME: COMPANY IDENTIFICATION: NALCO 73202 NALCO EUROPE BV P.O. Box 627 2300 AP Leiden The Netherlands Tel. : 0031 71 5241100
ONDEO NALCO DEUTSCHLAND GMBH (D) NALCO ESPAÑOLA, SA (E) NALCO PORTUGUESA LTDA. (P) NALCO CHEMICAL AB (SE) NALCO APPLIED SERVICES OF EUROPE BV NALCO FRANCE SAS MAUREPAS (F) NALCO FRANCE SAS 59441 WASQUEHAL (F) NALCO FRANCE SAS 38921 CROLLES (F) IWC GMBH (A) HOUSEMAN WATERBEHANDELING BV (NL) +49 (0)69-79340 +34 93-4095555 +351 214130996 +46 (0)8-50074000 +31 (0)73 6456980 ONDEO NALCO ITALIA S.R.L. (I) ONDEO NALCO LIMITED (GB) NALCO NORGE AS (NO) SUOMEN NALCO OY (FI) NALFLEET LIMITED (GB) +39 06-542971 +44 (0)1-60674488 +47-22 08 79 30 +358 (0)9-251 733 60 +44 (0)1-60674488 + 43(0)1 27026350 +31 (0)13-5952200 +32 3-4576264
Ir. G. Tjalmaweg 1 2342 BV Oegstgeest The Netherlands
+33 (0)1 30 05 10 00 NALCO CHEMICAL GMBH (A) +33 (0)3 20 11 70 00 NALCO CHEMICAL BV (NL) +33 (0)4 76 08 00 11 NALCO BELGIUM NV/SA (B) +43 (0)1 600 29 11 +31 164-214141
ONDEO NALCO DANMARK A/S +45-48195800 (DK)
EMERGENCY TELEPHONE NUMBER:
See section 16, for Emergency Telephone Numbers.
COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL DESCRIPTION: Water, Sodium bisulfite, Polymer. HAZARDOUS INGREDIENTS: CAS NO. 7631-90-5 EINECS NO. 2315480 CHEMICAL NAME Sodium bisulfite WT % 0 - 10 SYMBOL Xn R-PHRASES 22, 31, 37
HUMAN HEALTH HAZARDS - ACUTE: INHALATION: May cause irritation of mucous membranes. SKIN CONTACT: Can cause mild irritation. PAGE 1 OF 6
PAGE 2 OF 6 . INGESTION: Do not induce vomiting without medical advice. Obtain medical attention. Ensure adequate ventilation. SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING: In case of fire. obtain medical attention. Obtain medical attention. Move eyeball and keep eyelids wide open and apart whilst irrigating.CHRONIC: Chronic exposure to sulfites may cause symptoms of upper respiratory disease and affect sense of taste and smell. SKIN CONTACT: Remove contaminated clothing. FIRE AND EXPLOSION HAZARD Oxides of sulphur. After contact with skin. wash immediately with plenty of water. 11-07-2001 4. PHYSICAL AND CHEMICAL HAZARDS: Contact with acids liberates toxic gas. 5. HUMAN HEALTH HAZARDS . In case of contact with eyes. rest. rinse immediately with plenty of water and seek medical advice. EYE CONTACT: Immediately gently irrigate with clean water for at least 15 minutes. Avoid contact with skin and eyes. Wash off affected area immediately with plenty of water. Sulfites can cause an allergic reaction in sensitive individuals. If skin irritation persists. Oxides of nitrogen. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS: Do not breathe vapour. If conscious washout mouth and give one pint of water to drink. Obtain medical attention. FIRST-AID MEASURES INHALATION: Remove to fresh air. treat symptomatically. wear a full face positive-pressure self contained breathing apparatus and protective suit. Use personal protective equipment recommended in Section 8. Oxides of carbon. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire.MATERIAL SAFETY DATA SHEET NALCO 73202 Date issued: EYE CONTACT: Can cause mild irritation. INGESTION: May cause mucosal damage.
Storage for more than two years is not recommended. STORAGE CONDITIONS: Keep container tightly closed and in a well-ventilated place. 11-07-2001 7. Large spills: Dam up. METHODS FOR CLEANING UP: Small spills: Soak up with inert absorbent material. Clean up promptly by scoop or vacuum. remove clothing and thoroughly wash the affected area. Use with adequate ventilation. HAND PROTECTION: PVC gloves. EYE PROTECTION: Chemical splash goggles. SKIN PROTECTION: Standard protective clothing. Wash hands during breaks and at end of the shift. EXPOSURE CONTROLS/PERSONAL PROTECTION OCCUPATIONAL EXPOSURE LIMITS NATIONAL REGULATIONS UK Sodium bisulfite OES 5 mg/m 3 (TWA) NATIONAL REGULATIONS FRANCE Sodium bisulfite: 5 mg/m 3 VME ENGINEERING MEASURES Use general ventilation with local exhaust ventilation. If spillage does enter sewers or water courses. PAGE 3 OF 6 . Keep a safety shower available. immediately inform the appropriate water authorities. Launder contaminated clothing before reuse. Avoid generating aerosols and mists. If clothing is contaminated. 8.MATERIAL SAFETY DATA SHEET NALCO 73202 Date issued: ENVIRONMENTAL PRECAUTIONS: Do not allow to enter sewers or water courses. Store separately from acids. HYGIENE RECOMMENDATIONS: Keep an eye wash fountain available. Reclaim into recovery or salvage drums. Avoid contact with skin and eyes. RESPIRATORY PROTECTION: An approved respirator must be worn if the occupational exposure limit is likely to be exceeded. Avoid breathing vapors from headspace of newly opened containers. HANDLING AND STORAGE HANDLING: Do not breathe vapour.
HAZARDOUS DECOMPOSITION PRODUCTS: Contact with acids liberates toxic gas. TOXICOLOGICAL INFORMATION Hazard classification is based on 88/379/EEC. STABILITY AND REACTIVITY STABILITY: Stable under ambient conditions. 11. NA = not applicable. Oxides of sulphur. CONDITIONS TO AVOID: None known.MATERIAL SAFETY DATA SHEET NALCO 73202 Date issued: 11-07-2001 9. Sulphur dioxide. Please refer to section 3 for hazards identification.27 4. Oxides of nitrogen (under fire conditions).Brown VALUE BOILING POINT: FLASH POINT: RELATIVE DENSITY: pH VISCOSITY ( 21.6 °C ) 100 ( 760 mmHg ) None 1. MATERIALS TO AVOID: Acids.6 cps °C UNIT °C PMCC TEST METHOD ASTM D-86 ASTM D-93 ASTM D-1298 ASTM E-70 ASTM D-2983 ASTM D-1177 FREEZING POINT: Abbreviation: NE = not evaluated.6. 67/548/EEC and available ingredient toxicity data. PAGE 4 OF 6 . Oxides of carbon. NR = not relevant 10.5 . CHRONIC TOXICITY DATA: Sulfites can cause an allergic reaction in sensitive individuals. PHYSICAL AND CHEMICAL PROPERTIES NOTE: These physical properties are typical values for this product FORM: COLOUR: Liquid Colourless .0 570 -10.
NATIONAL REGULATIONS UK In accordance with the Environmental Protection ( Duty of Care) Regulations 1991. PAGE 5 OF 6 . S24/25 Avoid contact with skin and eyes. 14. wash immediately with plenty of water. gloves and eye/face protection. S26 In case of contact with eyes. ADDITIONAL ECOLOGICAL DATA: Depletes oxygen content in water courses. NATIONAL REGULATIONS UK COSHH regulations apply. 13. If this product becomes a waste. the final user must define and assign the appropriate European Waste Catalogue code. DISPOSAL CONSIDERATIONS Via authorized contractor. TRANSPORT INFORMATION Class: Not regulated 0000 20000320 15. S28 After contact with skin. NATIONAL REGULATIONS FRANCE Tableau des maladies professionnelles n°66A. REGULATORY INFORMATION CLASSIFICATION: HAZARD SYMBOL: Not applicable Contains: Sodium bisulfite RISK PHRASES: R31 Contact with acids liberates toxic gas. rinse immediately with plenty of water and seek medical advice. SAFETY PHRASES: S7 Keep container tightly closed.MATERIAL SAFETY DATA SHEET NALCO 73202 Date issued: 11-07-2001 12. ECOLOGICAL INFORMATION No data available on the product. S36/37/39 Wear suitable protective clothing.
4711 +44 (0)1-865407333 PAGE 6 OF 6 .MATERIAL SAFETY DATA SHEET NALCO 73202 Date issued: 11-07-2001 16. OTHER INFORMATION EMERGENCY TELEPHONE NUMBER Austria: Benelux Germany: Spain: Portugal: Sweden: France: Italy: United Kingdom: Denmark: Norway: Finland: NALFLEET INTERNATIONAL +43 1 406 43 43 +31 (0)13 5952233 +49 (0)69 7934251 or +49 (0)69 79340 +34 972 492003 +34 972 492003 020 996000 ORFILA +33 (0)1-45425959 +39 (0)6 968321 +44 (0)1-865407333 +46 (0)8 337043 +46 (0)8 337043 +358 (0)9.
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