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You are on page 1of 4

BACHELOR OF SCIENCE EDUCATION

DATE: TIME:

Instructions to Candidates

2. All the questions carry equal marks.

3. Use a fresh page for each new question

4. Illustrate your answers with equations and diagrams where possible

5. Check that this Examination Paper has 4 printed pages

DATA

1

1. a) The van’t Hoff equation is of the form:

a products

∆G = ∆G θ + RT ln

a reac tan ts

Use it to derive the relationship between the standard Gibbs free energy,

temperature, T?

SO2(g) -206.8 kJ mol-1 -300.2 kJ mol-1

SO3(g) -395.7 kJ mol-1 -371.1 kJ mol-1

(10 marks)

(25 marks)

2

c) Calculate the composition of a benzene-toluene mixture which at

moles of liquid B. The pure constituents have svp’s poA and poB,

respectively, and their partial pressures above the mixture are pA and pB.

pressures. (9 marks)

(25 marks)

i) isolated system,

∆G = ∆H − T∆S

ii) State the conditions under which the following factors are used as

∆H

iii) Under what circumstances can the expression ∆S = be

T

3

(∆Hor = +131 kJ mol-1; ∆Sor = +134 J K-1)

(25 marks)

of a solution. (5 marks)

(7 marks)

freezing point or boiling point of a given pure solvent and the amount of

2kg of benzene?

(5 marks)

(25 marks)

END

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