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Solutions to Homework 2 1. (a) In the figure below is shown a [110] direction within a BCC unit cell.

For this [110] direction there is one atom at each of the two unit cell corners, and, thus, there is the equivalence of 1 atom that is centered on the direction vector. The length of this direction vector is denoted by x in this figure, which is equal to

x= z 2 y2

4R 3

where y is the unit cell edge length, which, from Equation (3.3) is equal to

Furthermore, z is the length of the unit cell diagonal, which is equal to 4R Thus, using the above equation, the length x may be calculate as follows:

2 4R = 32R = 4R 2 x = (4 R ) 3 3 3 2 2

LD110 =

number of atoms centered on [110] direction vector length of [110] direction vector 1atom 4R 2 3 3 4R 2

A BCC unit cell within which is drawn a [111] direction is shown below.

For although the [111] direction vector shown passes through the centers of three atoms, there is an equivalence of only two atoms associated with this unit cellonehalf of each of the two atoms at the end of the vector, in addition to the center atom belongs entirely to the unit cell. Furthermore, the length of the vector shown is equal to 4R, since all of the atoms whose centers the vector passes through touch one another. Therefore, the linear density is equal to number of atoms centered on [111] direction vector length of [111] direction vector = 2 atoms 1 = 4R 2R

LD111 =

(b) From the table inside the front cover, the atomic radius for iron is 0.124 nm. Therefore, the linear density for the [110] direction is

3 3

LD110 ( Fe) =

4 R 2 (4)(0.124 nm) 2

While for the [111] direction 1 1 = = 4.03 nm 1 = 4.03 x10 9 m 1 2 R (2)(0.124 nm)

LD111 ( Fe) =

2. (a) In the figure below is shown a (100) plane for an FCC unit cell.

For this (100) plane there is one atom at each of the four cube corners, each of which is shared with four adjacent unit cells, while the center atom lies entirely within the unit cell. Thus, there is the equivalence of 2 atoms associated with this FCC (100) plane. The planar section represented in the above figure is a square, wherein the side lengths are equal to the unit cell edge length, 2R 2 [Equation (3.1)]; and, thus,

2 2R the area of this square is just ( 2 ) = 8R2. Hence, the planar density for this

(100) plane is just number of atoms centered on (100) plane area of (100) plane

= 2 atoms 8R 2 = 1 4R 2

PD100 =

That portion of an FCC (111) plane contained within a unit cell is shown below.

There are six atoms whose centers lie on this plane, which are labeled A through F. One-sixth of each of atoms A, D, and F are associated with this plane (yielding an equivalence of one-half atom), with one-half of each of atoms B, C, and E (or an equivalence of one and one-half atoms) for a total equivalence of two atoms. Now, the area of the triangle shown in the above figure is equal to one-half of the product of the base length and the height, h. If we consider half of the triangle, then

4 R ( h) ( 4 R ) 2 R 3 = = 4R 2 3 2 2

Area=

PD111 =

2

3 2R 2 3

(b) From the table inside the front cover, the atomic radius for aluminum is 0.143 nm. Therefore, the planar density for the (100) plane is

PD100 ( Al ) =

1 4R

= 2

1 4(0.143 nm)

2

2

3 2 3 (0.143 nm)

1

2

3.

(a) From the data given in the problem, and realizing that 36.12 = 2 , the interplanar spacing for the (311) set of planes may be computed using Equation (3.3W) as

d 311 = (1)(0.0711 nm) n = = 0.1147 nm 36.12 2 sin (2) sin 2

(b) In order to compute the atomic radius we must first determine the lattice parameter, a, using Equation (3.3W), and then R from Equation (3.1) since Rh has an FCC crystal structure. Therefore,

a = d 311 (3) 2 + (1) 2 + (1) 2 = (0.1147 nm) 11 = 0.3804 nm And R=

( )

a

2 2

0.3804 nm 2 2

= 0.1345 nm

4.

(a) Since W has a BCC crystal structure, only those peaks for which h + k + l are even will appear. Therefore, the first peak results by diffraction from (110) planes. (b) For each peak, in order to calculate the interplanar spacing we must employ Equation (3.2W). For the first peak which occurs at 40.2

d 110 = (1)(0.1542 nm) n = = 0.2244 nm 2 sin 40.2 (2) sin 2

(c) Employment of Equations (3.3W) and (3.3) is necessary for the computation of R for W as a 3 4

R=

(d hkl )(

(0.2244 nm )(

= 0.1374 nm

5.

Determination of the number of vacancies per cubic meter in gold at 900 C (1173 K) requires the utilization of Equations (4.1) and (4.2) as follows:

Q N Q N V = N exp V = A Au exp V A Au kT kT

(6.023 x 10

23

atoms / mol 19.32 g / cm 3 0.98 eV / atom exp 5 196.9 g / mol 8.62 x 10 eV / atom K (1173 K )

)(

6.

In this problem we are asked to cite which of the elements listed form with Cu the three possible solid solution types. For complete substitutional solubility the following criteria must be met: 1) the difference in atomic radii between Cu and the other element ( R%) must be less than 15%, 2) the crystal structures must be the same, 3) the electronegativities must be similar, and 4) the valences should be the same, or nearly the same. Below are tabulated, for the various elements, these criteria. Crystal Structure

FCC

Element

Cu C H O Ag Al Co Cr Fe Ni Pd Pt Zn

R%

Electronegativity

Valence

2+

1+ 3+ 2+ 3+ 2+ 2+ 2+ 2+ 2+

(a) Ni, Pd, and Pt meet all of the criteria and thus form substitutional solid solutions having complete solubility. (b) Ag, Al, Co, Cr, Fe, and Zn form substitutional solid solutions of incomplete solubility. All these metals have either BCC or HCP crystal structures, and/or the difference between their atomic radii and that for Cu are greater than 15%, and/or have a valence different than 2+. (c) C, H, and O form interstitial solid solutions. These elements have atomic radii that are significantly smaller than the atomic radius of Cu.

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