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SET – A
[PHYSICS, CHEMISTRY & MATHEMATICS]
PART A ÷ PHYSICS
1. A projectile is fired at an angle 60° with some
velocity u 
Ans : No correct answer
Sol: R =
g
u
2
sin 2u
x =
R
dR
= 2 cot 2u du
T =
g
si n u 2 u
y =
T
dT
= cotu du
°
°
=
u
u
=
60 cot
120 cot 2
cot
2 cot 2
y
x
= ÷2
¬ x = ÷2y (No correct answer)
2. A ball is dropped down vertically from a tall
building 
Ans : u = 
.

\

÷
h
d
sin
4
1
1
Sol:
u + u + o = 90° ¬ o = (90° ÷ 2u)
d = o = o 2 sin
g
gh 2
.
2
1
2 sin
g
u
2
1
2
= h sin 2 (90° ÷ 2u) = h sin (180° ÷ 4u)
= h sin 4u ¬ u = 
.

\

÷
h
d
sin
4
1
1
3. A photon with an initial frequency 10
11
Hz 
Ans : 4 × 10
3
m s
÷1
Sol: E1 = hu1 = 6.63 × 10
÷34
× 10
11
= 6.63 × 10
÷23
J
E2 = hu2 = 6.63 × 10
÷34
× 0.9 × 10
11
= 5.967 × 10
÷23
J
AE = E1 ÷ E2 = 6.63 × 10
÷24
J
AE =
m
E 2
v mv
2
1
2
A
= ¬ ~ 4 × 10
3
m s
÷1
4. The correct potential energy diagram for 
Ans :
Sol: F =
dr
du
÷
u =
í
÷ dr . F
for r > R
u = dr . r
ˆ
r
k
2 í
÷
=
r
k
1 2
r
k
1 2
=
+ ÷
÷
+ ÷
at r = ·, u ÷ 0
at r = R u =
R
k
for r < R,
u =
í
÷
0
R
dr . F
=
í
÷
÷
0
R
3
r
R
k
=
2
r
R
k
2
3
×
+
=
R 2
k
2
R
R
k
2
3
=
at r = 0, u =
R 2
k
5. Suppose the particle starts from r = · 
Ans : (3/8) (k/R)
Sol: KE = U(R) ÷ U(R/2)
=
R 8
k
R 2
k
÷
=
R 8
k 3
6. Let a particle have an instantaneous position 
Ans : 0 r . a ; 0 v . a ; 0 v . r < > =
u
u
o
u = gh 2
u
u
2
= 2 gh
R
k
R
r
0 
R 2
k
Sol: In circular motion,
0 v . r v r = ¬ ±
r and a make angle u > 90°
¬
O
Me
< 0
v and a may make angle u between
them which is either > 90° or <90° or = 90°
So for general case v . a > 0
7. A large parallel plate capacitor is made of two
metal plates of size 
Ans : ÷5 × 10
5
c0 J
Sol: AC =
( )
d
' A K K
0 2 1
c ÷
=
( )
1 . 0
1 1 . 0 2 3
0
× × c ÷
= c0
Uinitial =
C 2
Q
2
Ufinal =
( ) C C 2
Q
2
A +
W = Ufinal ÷ Uinitial
=
2
CV
2
1
A ÷
= ÷5 × 10
5
c0 J
8. A current I is flowing in a long straight wire along
the zaxis
Ans : vZ (At) = v0
Sol: F on q is along i
ˆ
÷ direction ¬ a of q is
along i
ˆ
÷ direction ¬ component of
velocity in k
ˆ
does not change
¬ vZ (At) = v0
9. A nonconducting sphere of radius R has a
charge Q distributed 
Ans :
Sol: From r = 0 to r = R.
E · r ¬ straight line, inclined to r.
From r = R to r = b.
E ·
2
r
1
At r > b, E = 0
10. The magnetic field at the centre of a loop
carrying 
Ans : k
ˆ
8
7
R 3
0
I u
Sol:
B = B1 + B2 =
R 24
7
R 24
5
R 12
0 0 0
I u
=
I u
+
I u
;
Direction k
ˆ
11. A current I is flowing in a wire of length . The
total momentum 
Ans :
q
m I
Sol: I =
q t
1
t
q I
= ¬
v =
q t
I
=
p = mv =
q
m I
12. In an oil drop experiment, charged oil drops of
mass m and charge q
Ans :
( )
2
2
0
q
R r 4 mg ÷ tc
Sol: The answer must be dimensionless ¬ q
2
is required in denominator to cancel c0 ¬
only (B) can be the answer.
13. Two lenses, one biconvex of focal length f1 and
another 
Ans : M =
2
1
f
f
Sol: m1 =
L
f
u
v
1
1
1
=
m2 =
2 2
2
f
L
u
v
=
M = m1m2 =
2
1
f
f
(L is large ¬ ·)
E
R b
0
x
y
14. The central fringe in a Young’s double slit
experiment 
Ans :
4
3
Sol: Path difference = (u ÷ 1) t
= (1.4 ÷ 1) × 5 × 10
÷6
= 2 × 10
÷6
m
Phase difference Ao =
9
6
10 8 . 632
2 10 2
÷
÷
×
t × ×
= 19.858 rad
= 3.16 × 2t rad
¬ Ao = 0.16 × 2t = 57.6°
¬ I = I0 cm
2

.

\
 o A
2
= 0.767I0 ~
4
3
I0
15. A polarizer is introduced in the path of a beam of
unpolarized light incident 
Ans : u = 30° and the polarizer is placed in P ( It
is assumed that the polarized light is
getting completely transmitted.)
Sol: tano = u (Brewster’s law)
¬ o = ( ) 3 tan
1 ÷
= 60°
on transparent material.
¬ u = 90° ÷ o = 30°
16. A submarine travelling at 10 m s
÷1
is chasing
another one in front of it 
Ans : 13 m s
÷1
Sol: f1 =
( )
( ) 10 c
v c
f
0
+
÷
f2 =
( )
( )
( )( )
( )( ) v c 10 c
10 c v c f
v c
10 c
f
0
1
+ ÷
+ ÷
=
+
+
=
( )( )
( )( ) 10 c v c
10 c v c
f
0
÷ +
+ ÷
f0 = 25000 Hz; f2 = 24900 Hz
c = 1500 m s
÷1
; v = 13 m s
÷1
17. When light of intensity I reflects from a surface
separating two 
Ans : u =
2 1
u u ; 2ut =
( )
2
1 n 2 + ì
18. A point object is placed below a wide glass plate
of refractive index n. As an 
Ans :
1 n
n
tan 2
2
1
÷
÷
Sol:
u = 2C’; tanC’ =
d
nr
' d
r
=
= n tan C = 
.

\

=
÷
n
1
C sin
1 n
n
2
¬ u =
1 n
n
tan 2
2
1
÷
÷
19. A light sensor is fixed at one corner of the
bottom of a rectangular tank 
Ans : A quarter of a circle of radius = m 3 10
Sol: tanC =
d
r
1 n
1
2
=
÷
¬ r = m 3 10
1 n
d
2
=
÷
20. The average pressure on a sphere submerged
in water is the pressure 
Ans : 63 N
Sol: P = pressure at centre = pg H
= 1000 × 10 × (0.1 + 0.1)
= 2000 N m
÷2
F = P × area
= 2000 × t × (0.1)
2
= 20t = 63 N
21. Laplace correction to the speed of sound is
made only for gases and not 
Ans :Much smaller relative pressure change
when the wave is passing through them.
Sol: Knowledge based.
22. Three rods of equal lengths and cross sectional
areas are joined 
Ans : T1 =
B A
T
5
2
T
5
3
+ ; T2 =
B A
T
5
3
T
5
2
+
Sol:
( ) ( ) ( )
L
T T KA
L
T T KA 2
L
T T KA
B C 2 1 1 A
÷
=
÷
=
÷
On solving,
T1 =
B A
T
5
2
T
5
3
+ and
C’
C
d
d’
r
0
T2 =
B A
T
5
3
T
5
2
+
23. The diameter of a metal wire is measured using
a screw gauge, 
Ans : 1.21 × 10
÷5
O m
Sol: Pitch = 0.5 mm
L.C =
50
5 . 0
N
Pi tch
= = 0.01 mm
P.S.R = 4 × 0.5 = 2.0 mm
CSR = 20 × LC = 20 × 0.01 = 0.2 mm
d = 2.2 mm = 2.2 × 10
÷3
m
p =
RA
¬ p = 1.21 × 10
÷5
O m
24. Which of the following quantities has the least
number of 
Ans : 0.08765
Sol: Knowledge based.
25. In an experiment designed to determine the
universal gravitational 
Ans : a + 3b + 2c
Sol: [G] = M
÷1
L
3
T
÷2
=
2
3
MT
L
T
T 2
M
M
L
L 3
G
dG A
+
A
+
A
=
= 3b + a + 2c
= a + 3b + 2c
PART B ÷ CHEMISTRY
26. The relative stability of the octahedral complexes

Ans : (i) > (ii) > (iii) > (iv)
Sol: oxygen ligands have high affinity for Fe(III)
and affinity of Fe(III) for amines is low
27. Number of isomers that 
Ans : 3
Sol: The complex is square planar and is of the
type Mabcd. It has three geometrical
isomers.
28. When a metal is in its low oxidation state, 
Ans :Chloride is a o donor and the carbon
monoxide is both a o donor as well as t
acceptor
Sol: Metal ÷ CO bond is stronger than Metal ÷
Cl bond because CO act as a o donor as
well as t acceptor ligand
29. Freshly prepared, bright blue coloured, 
Ans : ( )   ( ) el ectron an i s ' e ' NH e
n 3
÷
Sol: Ammoniated electron brings about the
reduction of the functional group
30. The statement that is NOT 
Ans : silicates are mainly built through ‘SiO2’
units
Sol: silicates are built through tetrahedral
SiO4
4÷
units
31. The (SIO3
2÷
)n 
Ans : cyclic silicates
Sol: Linear single chain silicates have
empirical formula ( )  
n
2
3
Si O
÷
32. The oxoacid of sulphur that 
Ans : pyrosulphuric acid (H2S2O7)
Sol: pyrosulphuric acid (H2S2O7)
is
H O S
O
O
O S
O
O
O H
33. The reason for the formation 
Ans : *acidic nature of B(OH)3
Sol: B(OH)3 is a Lewis acid. It reacts with water
to form [B(OH)4]
÷
& H
+
*If B is the answer B (OH)3 should be a
tribasic acid. But actually it is monobasic
acid
34. An optically active alcohol (X) 
Ans : 2ethyl3buten1ol
Sol:
H
2
C CH CH
CH
2
CH
3
CH
2
OH
(optically active)
H
2
/ Ni
H
3
C CH
2
CH
CH
2
CH
3
CH
2
OH
(optically inactive)
35. The major product formed in the 
Ans :
O
Me
Sol: Ozonolysis of the given unsaturated
compound gives
CH
3 C
O
(CH
2
)
3
C
O
CH
3
This undergoes intramolecular aldol
condensation to form the compound
having structure (A)
36. The following transformation 
Ans : NaOH / I2
Sol: Iodoform reaction will bring about the
given conversion
37. Among the following halides, 
Ans : III
Sol:
Cl
(III)
does not undergo ionisation
because the resultant cation is
antiaromatic
38. Isopropanol can be converted 
Ans : pyridinium chlorochromate followed by
peracetic acid
Sol: ÷ ÷ ÷ ÷ ÷ ÷
PCC
3 3
CH CHOH CH
CH
3
C
O
CH
3
CH
3
CO
3
H
CH
3
C
O
OCH
3
39. Among the isomeric butylbenzenes, the one 
Ans :
C(CH
3
)
3
Sol: For the oxidation of the side chain, the
carbon attached to the benzene ring must
contain at least one hydrogen
40. The following reaction is 
Ans : i (CH3)2CHCOCl / AlCl3 :
ii. Br2 / FeBr3 : iii. NH2. NH2 / KOH
Sol:
(CH
3
)
2
CHCOCl / AlCl
3
O
Br
2
/ Fe
O
Br
H
2
N  NH
2
KOH
41. The major product of the following
Ans :
O
CH
3
CH
3
Sol: Protonation of oxygen followed by
cleavage of three membered ring gives a
3° carbocation. This undergoes ring
expansion followed by loss of proton gives
(B)
42. Conversion of benzene into 1, 3
Ans : i. HNO3 / conc. H2SO4: ii. Br2 / FeBr3
iii. Sn / HCl iv. NaNO2 / HCl,05°C
v. CuBr
Sol:
HNO
3
/ H
2
SO
4
NO
2
Br
2
/ FeBr
3
NH
2
NO
2
Br
Sn / HCl
Br
NaNO
2
/ HCl
05
0
C
Br
N
2
Cl
CuBr
Br
Br
43. Liquid oxygen and liquid nitrogen are 
Ans : Liquid oxygen will be attracted but liquid
nitrogen unaffected
Sol: Oxygen is paramagnetic and nitrogen is
diamagnetic
44. The highest transition energy 
Ans : 27434.25 cm
÷1
Sol:
÷ = u
2
2
2
1
H
n
1
n
1
R
= 109737
÷0
4
1
= 27434.25 cm
÷1
45. A one litre glass bulb is evacuated and 
Ans : 30
Sol: RT
M
W
PV =
1 1
5 . 312 08 . 0 2 . 1
M
×
× ×
=
= 30
46. The van der Waals coefficient of the inert 
Ans : Induced dipole Induced dipole : increased
atomic volume
Sol: ‘a’ is a measure of attraction between the
molecules and ‘b’ is a measure of the size
of the molecules
47. Assuming AH
0
and S
0
do not change with 
Ans : 300 K
Sol:
) g ( ) (
A A ÷÷ ÷
AH° = 30 kJ mol
÷1
AS° = 100 J mol
÷1
T =
S
H
A
A
= 300 K
48. A solution of CaCl2 was prepared by 
Ans : 0.0006
Sol: ATf =i × Kf × m
=
112
0112 . 0 2 3 × ×
= 0.0006
49. Of thr four values of pH given below which 
Ans : 4.4
Sol:
3 2
CO H
÷ +
+
3
HCO H ;
÷
3
HCO
÷ +
+
2
3
CO H
C . K C ] H [
1
a
= o =
+
since
1
a
K >>
2
a
K
=
3 7
10 4 10 4
÷ ÷
× × ×
= 4 × 10
÷5
pH = 4.4
50. The Habers’s process process for the 
Ans : Ammonia dissociates spontaneously
above 500 K
Sol: AG°= AH° ÷ TAS°
At equilibrium AG° = 0
T = K 500
190
10 95
S
H
3
=
÷
× ÷
=
A
A
Above 500 K, AG° is +ve
PART C ÷ MATHEMATICS
51. Martin throws two dice simultaneously. 
Ans :
20
1
Sol: Let L denote the event of offering lunch
P(L) = P (12). P(L  12) + P(7) .P(L  7)
+ P (others). P(L  others)
P(12) = ( ) ( )
36
29
others P
36
6
7 P ;
36
1
= =
P(12  L)
3
1
36
29
2
1
36
6
3
2
36
1
3
2
36
1
× + × + ×
×
=
=
20
1
52. A spices has an initial population 4
10
. 
Ans : 20
Sol: P = 4
10
P1 = 4
10
2
3
; P2 = 4
10
2
1
.
2
3
P3 = 4
10
2
1
2
3
2

.

\

;P4 = 4
10
2 2
2
1
2
3

.

\


.

\

Pt = 4
10
2
t
2
t
2
1
.
2
3

.

\


.

\

when t  even
4
10
10
2
t
2
t
3
2
1
2
3
= 
.

\


.

\

10
2
t
4
3
4
3
10
2
t
= ¬ 
.

\

= 
.

\

t = 20
53. If 4 squares are chosen at random 
Ans :
4
64
4
8
C
C
2
Sol: Eight squares lie on a main diagonal and
there are 2 main diagonals.
Probability =
4
64
4
8
C
C
2
54. A student was calculating the variance 
Ans :
100
825
Sol: V
n
x
n
x
2
2
=


.

\

÷
¯ ¯
( )
2
2
c
x x 10
¯ ¯
÷ = 100 V ___(1)
( )
2
2
c
x x 10
¯ ¯
÷ = 100 Vc ___(2)
∵
¯
= 46 x
¯ ¯ ¯
+ = + ÷ = 9 x 10 1 x x
c
¯ ¯ ¯
+ = + ÷ = 99 x 10 1 x x
2 2 2 2 2
c
From (2) ¬ 10
( ) ( )
2
2
9 x 99 x
¯ ¯
+ ÷ + = 100 Vc
¬
( ) 81 46 18 990 x x 10
2
2
÷ + ÷ +

.

\

÷
¯ ¯
= 100 Vc
100 V +81 = 100 Vc
Vc =
100
81 744+
=
100
825
55. A fair coin is tossed 6 times 
Ans :
32
5
Sol: Head appears as the 6
th
trial for the third
time. So in the first 5 trials .Head
appeared twice.
Probability =
32
5
2
1
C
6
2
5
= 
.

\

56. The sum of the roots of the equation 
Ans : log211
Sol: Rewriting
0 ) 2 10 ( log ) 3 2 ( log 2 log 2 log
x
2
2 x
2 2
x
2
= ÷ + + ÷ +
÷
1 ) 2 10 (
) 3 2 (
2 2
x
2 x
x
=


.

\

÷ ×
+
×
÷
Rearranging
2 × (10 × 2
x
÷ 1) = (2
x
+ 3)
2
2(10y ÷ 1) = y
2
+ 6y + 9, taking y = 2
x
Y
2
÷ 14y + 11 = 0
2 1
x x
2
+
= 11
x1 + x2 = log2 11
57. Let z = 
.

\
 t
+
t
5
sin i
5
cos a 
Ans :
z 1
a
2010
÷
Sol: 
.

\

t +
t
=
5
2010
sin i
5
2010
cos a z
2010 2010
= ( ) t + t 2 sin i 2 cos a
2010
=
2010
a
..... z z z
2012 2011 2010
+ + +
= 
.

\

÷ z 1
1
z
2010
=
z 1
a
2010
÷
58. The locus of the point z satisfying arg
Ans : a single point
Sol: let z = x + iy
Z +1 = (x +1) + i y
arg (z +1) = tan
÷1

.

\

+1 x
y
= o
arg (z ÷1) = tan
÷1

.

\

÷1 x
y
= 
tan o =
1 x
y
tan
1 x
y
÷
= 
+
Since 2
tan
1
tan
1
=

÷
o
¬
( )
2
y
1 x
y
1 x
=
÷
÷
+
¬ 2 = 2y ¬ y = 1
line parallel to the x ÷ axis
59. For the equation, sin x + cos x= 
Ans : there is a solution, for exactly one a> 0
Sol: Equation can be written as

.

\

+ = 
.

\
 t
÷
a
1
a
2
1
4
x cos
2
1
cos
a
1
a
4
x + = 
.

\
 t
÷
if a> 0 ¬ 2
a
1
a > + , equality for a = 1
but cos 
.

\
 t
÷
4
x s 1
Equation has one solution
60. The number of solutions of the equation 
Ans : 6
Sol:
From the following graph it is seen that
there are 6 intersection points.
2
1.5
1
0.5
0
0.5
1
1.5
2
2.5
360 180 0 180 360 540
61. Consider the circles C
1
: x
2
÷ y
2
= 64 
Ans :


.

\

2
6
,
2
6
Sol: .Let centre of the circle be (o, o)
Equation is
x
2
+ y
2
÷ 2ox ÷ 2yo + 2o
2
= 100 ÷÷ (1)
Equation of given circle
x
2
+ y
2
= 64 ÷÷ (2)
Equation of common chord
¬ S1 ÷ S2 = 0
¬xo + yo ÷ o
2
+ 18 = 0 ÷÷ (3)
Since length of common chord = 16
which is a diameter of x
2
+ y
2
= 64
¬ o
2
= 18
o =


.

\

=
2
6
2 3
Centre


.

\

2
6
,
2
6
62. A line segment joining (1, 0, 1) and the origin 
Ans : x
2
÷y
2
÷ z
2
= 0
Sol: The semi vertical angle o is given by
sin o =
2
1
r
x
=
¬ locus of any point on the cone is
2
1
r
x
=
i.e
2
1
z y x
x
2 2 2
2
=
+ +
or x
2
÷ y
2
÷ z
2
= 0
63. Let (x, y, z) be any point on the line passing 
Ans : i + j ÷ 2k
Sol: (x, y, z) passing through a line which is
parallel to that vector i+ j+ k.
Then the vector perpendicular to the plane
passing through (x, y, z) will be
perpendicular to i + j + k
i.e., i + j ÷ 2k
64. A tangent to the ellipse 1
16
y
25
x
2 2
= + 
Ans : 82
Sol: Equation tangent is
4
y
cos
5
x
+ sinu = 1
A 
.

\

u

.

\

u sin
4
0 B and 0 ,
cos
5
sin OAB is isosceles OA = OB ¬
k
si n
4
cos
5
=
u
=
u
cosu = 41 k
k
4
si n as
k
5
= ¬ = u
AB = 82 k k
2 2
= +
65. Let an = ( ) ( ) ( )  
n / 1
n n 2 ... 2 n 2 1 n 2
n
1
+ + + 
Ans :
í
3
2
dx x l og
Sol: log an =

.

\

+ + + 
.

\

+ + 
.

\

+
n
n
2 log ....
n
2
2 log
n
1
2 log
n
1
¯
=
· ÷ ÷·

.

\

+ =
n
1 r
n
n
n n
r
2 l og
n
1
l i m ) a (l og l i m
= ( )
í
= +
1
0
dx x 2 l og
í
3
2
dx x l og = L
66. The value of
( )
is
n 3
n 3 .... 2 1
lim
4
3 3 3
x n
+ + +
÷

Ans : 27/4
Sol:
( )
=
¯
o ÷
4
34
1
3
n
n 3
r
lim
4
27
n 3
2
1 n 3 (
n 3
lim
4
2
13 n
=

.

\
 +
=
÷
67. The value of
í
t
t
+
+
2 /
0
2 /
i s dx e
x cos 1
x si n 2

Ans :
4
e 2
t
Sol:
í í
t

.

\

+ =
+
+
t
2
0
2
x
2
2
x
0
dx e
2
x
tan
2
x
sec dx e
x cos 1
x si n 2
4
= ( )
í
t
+
4
0
u
du e u tan u sec 2
= ( )
4 /
0
u
u tan e 2
t
= 2e
t/4
68. The differential equation satisfied by
Ans : x+3yy
1
= 0
Sol: y = o x
3
¬ y
1
= 3 o x
2
¬ o =
2
1
x 3
y
Differential equation of given
come in y =
2
3 1
x 3
x y
¬ 3y = xy
1
Corresponding curve perpendicular to it
ie 3y = x
1
y
1 ÷
¬ 3yy
1
+ x = 0
69. Let f(x) = x ( ) t ÷ x 
Ans : onto but NOT oneone
Sol: f(x) = x t ÷ x (2 + cos
2
x)
F(x) is continuous everywhere. f (÷·) =
÷·, f ((÷·) = ·
f is onto
If 0 <x < t
f(x) = x (t ÷x) (2+ cos
2
x)
f (t ÷x) =t ÷x (x) (2 + cos
2
x)
f is not one ÷ one
70. The equation 2x
3
÷ 3x
2
÷ p = 0 
Ans : (0, 1)
Sol: Let f(x) = 2x
3
÷ 3x
2
+ p
f’(x) = 6x (x ÷ 1);
f’’(0) = ÷6 < 0; f’’(1) = 6 > 0
f(0) = p ; f(1) = ÷1 + p
p
O
1
÷1 + p
f(x) will have 3 distinct real roots if p > 0
and ÷1 + p < 0
i.e. p e (0, 1)
71. For a real number x let 
Ans : continuous at x = 1 but NOT continuous at
x = 2
Sol: f(x) = { } x
2
cos x
] x [
t
) h 1 ( f lim ) x ( f lim
0 h 1 x
÷ =
÷ ÷
÷
{ } ) h 1 (
2
cos h 1 l i m
] h 1 [
0 h
÷
t
÷ =
÷
÷
= 0
=
+
÷
) x ( f lim
1 x
{ } ) h 1 (
2
cos h 1 l i m
] h 1 [
0 h
+
t
+
+
÷
= 0
f(1) = 0 and f(x) is continuous at x = 1.
Again, ) h 2 ( f lim ) x ( f lim
0 h 2 x
÷ =
÷ ÷
÷
{ } ) h 2 (
2
cos h 2 l i m
] h 2 [
0 h
÷
t
÷ =
÷
÷
{ } ) h 2 (
2
cos h 2 l i m
1
0 h
÷
t
÷ =
÷
= 1 × cos t = ÷1.
{ } ) h 2 (
2
cos h 2 l i m ) x ( f l i m
2
0 h 2 x
+
t
+ =
÷ ÷
+
= 0.
f(x) is not continuous at x = 2.
72. Let f : (0, ·) ÷ R be
Ans : 2
Sol: f(x) = 2x
sin2x
cos2x
( )
x 2 sin
0 x 0 x
x lim 2 x f lim
÷ ÷
=
=
x 2 ec cos
x log
lim
0 x
e 2
÷
= 2.
73. The distance of the point (1, 2, 3) 
Ans : 3 3
Sol: Equation of line passing through (1, 2, 3)
and parallel to ( ) ( ) k
ˆ
j
ˆ
i
ˆ
j
ˆ
2 i
ˆ
3 r + + ì + + ÷ =
is
( ) ( ) k
ˆ
j
ˆ
i
ˆ
k
ˆ
3 j
ˆ
2 i
ˆ
r + + ì + + + =
ì =
÷
=
÷
=
÷
1
3 z
2
2 y
1
1 x
x = 1 + ì, y = 2 + ì, z = 3 + ì
2x + y + 2z + 5 = 0
2(1 + ì) + (2 + ì) + 2(3 + ì) + 5 = 0
ì = ÷3
point of intersection is (÷2, ÷1, 0)
Distance from (1, 2, 3)
= 3 3 3 3 3
2 2 2
= + + .
74. If the vector
Ans : 92
Sol: Let V1 = ( ) k
ˆ
j
ˆ
i
ˆ
+ ÷ ì
V2 = ( ) k
ˆ
c j
ˆ
b i
ˆ
a + + u
V2 . ( ) 0 k
ˆ
i
ˆ
2 = ÷ ¬ c = 2a
( ) ( ) ( )k
ˆ
a 2 j
ˆ
b i
ˆ
a V V
2 1
u + ì + u + ì ÷ + u + ì = +
3 b , 4 a , 1 = u = u ÷ = ì
( ) ( )
2 2 2
2
2
2
1
b a 5 3 V V u + u + ì = +
= 3 + 5 × 16 + 9 = 92.
75. A plane H passes through the intersection
Ans : ( ) k
ˆ
3 j
ˆ
i
ˆ
3 r + ÷ = 1
Sol: Point dividing (3, 0, 2) and (0, 3, ÷1) in the
ratio 2:1 internally is (1, 2, 0)
Equation of the required plane is
(x + y + z + 3) + ì (x ÷ y +3z ÷ 2) = 0
¬ 6 + ì (÷3) = 0 ¬ ì = 2
Equation is 3x ÷ y + 3z ÷ 1 = 0, i.e.
( ) k
ˆ
3 j
ˆ
i
ˆ
3 r + ÷ = 1
E = 0 M = m1m2 = f1 f2 (L is large ) . Two lenses. A current is flowing in a wire of length . A nonconducting sphere of radius R has a charge Q distributed Ans : E The answer must be dimensionless q is required in denominator to cancel 0 only (B) can be the answer. inclined to r.Sol: In circular motion. The total momentum Ans : m q q 1 t t q v= t q m p = mv = q Uinitial = Ufinal = Q2 2C Q2 2C C W = Ufinal Uinitial 1 = CV 2 2 5 = 5 10 0 J Sol: = 8. charged oil drops of mass m and charge qmg40 r R2 q2 Ans : Sol: vZ (t) = v0 9. r v r.v > 0 7. In an oil drop experiment. From r = R to r = b. A large parallel plate capacitor is made of two metal plates of size Ans : 5 10 0 J 5 Sol: 0 x B = B1 + B2 = ˆ Direction k 0 5 7 0 0 .1 d 11.v 0 a and r make angle > 90 <0 a and v may make angle between O Me 10. 1 E 2 r At r b. 2 13. The magnetic field at the centre of a loop carrying Ans : 0 7 ˆ k 3R8 y them which is either > 90 or <90 or = 90 So for general case a. E r straight line. A current is flowing in a long straight wire along the zaxisAns : vZ (t) = v0 Sol: i F on q is along ˆ direction a of q is ˆ direction component of along i ˆ velocity in k does not change 12.1 1 0 . 12 R 24 R 24 R Sol: C = = = 0 K1 K 2 0 A' 3 20 0. one biconvex of focal length f1 and another Ans : M = f1 f2 v1 f1 u1 L v2 L u2 f2 R b Sol: m1 = m2 = Sol: From r = 0 to r = R.
4 1) 5 106 = 2 106 m Phase difference = 2 106 2 632.1 + 0.) Sol: tan = (Brewster’s law) = tan1 3 = 60 on transparent material. 2t = 22. The central fringe in a Young’s double slit experiment Ans : 3 4 Sol: d d’ C’ r C Sol: Path difference = ( 1) t = (1.858 rad = 3.14.16 2 = 57. As an Ans : 2 tan1 n n2 1 Sol: KATA T1 2KAT1 T2 KA TC TB L L L On solving.1) = 2000 N m2 F = P area = 2000 (0. 3 2 T1 = TA TB and 5 5 . 17. A polarizer is introduced in the path of a beam of unpolarized light incident  n n2 1 19. A light sensor is fixed at one corner of the bottom of a rectangular tank Ans : A quarter of a circle of radius = 10 3 m 1 2 Sol: Ans : = 30 and the polarizer is placed in P ( It is assumed that the polarized light is getting completely transmitted. v = 13 m s1 21.1)2 = 20 = 63 N c v c 10 c 10 f0 c v c 10 f2 = f1 c v c 10c v c v c 10 = f0 c v c 10 f1 = f0 f0 = 25000 Hz. Sol: Knowledge based.6 3 2 = 0 cm = 0. Three rods of equal lengths and cross sectional areas are joined Ans : T1 = 3 2 TA TB . The average pressure on a sphere submerged in water is the pressure Ans : 63 N Sol: P = pressure at centre = g H = 1000 10 (0.16 2 rad = 0. A submarine travelling at 10 m s1 is chasing another one in front of it Ans : 13 m s1 Sol: tanC = r= n 1 d 10 3 m n2 1 r d 20. f2 = 24900 Hz c = 1500 m s1. A point object is placed below a wide glass plate of refractive index n. 5 5 2n 1 2 T2 = 2 3 TA TB 5 5 18. tanC’ = = n tan C = = 2 tan1 r nr d' d n 1 sin C 2 n n 1 = 19. When light of intensity reflects from a surface separating two Ans : = 1 2 .8 109 0 = 2C’. = 90 = 30 16. Laplace correction to the speed of sound is made only for gases and not Ans :Much smaller relative pressure change when the wave is passing through them.7670 0 4 2 15.
It reacts with water + to form [B(OH)4] & H *If B is the answer B (OH)3 should be a tribasic acid. An optically active alcohol (X) Ans : 2ethyl3buten1ol .21 105 m 28. The relative stability of the octahedral complexes Ans : (i) > (ii) > (iii) > (iv) Sol: oxygen ligands have high affinity for Fe(III) and affinity of Fe(III) for amines is low 33.R = 4 0. bright blue coloured. Ans : eNH3 n Sol: ' e' is an electron Ammoniated electron brings about the reduction of the functional group 24.5 = 2.01 = 0. Which of the following quantities has the least number of Ans : 0.5 mm Pitch 0.2 103 m RA = = 1. Ans :Chloride is a donor and the carbon monoxide is both a donor as well as acceptor Sol: Metal CO bond is stronger than Metal Cl bond because CO act as a donor as well as acceptor ligand 29. 30. Number of isomers that Ans : 3 Sol: The complex is square planar and is of the type Mabcd. The diameter of a metal wire is measured using a screw gauge. Freshly prepared.08765 Sol: Knowledge based.2 mm = 2. 34.21 105 m Sol: Pitch = 0.0 mm CSR = 20 LC = 20 0.S. The oxoacid of sulphur that Ans : pyrosulphuric acid (H2S2O7) Sol: pyrosulphuric acid (H2S2O7) O O is H O S O O S O O H PART B CHEMISTRY 26.T2 = 2 3 TA TB 5 5 23.2 mm d = 2.01 mm N 50 P.5 L. In an experiment designed to determine the universal gravitational Ans : a + 3b + 2c Sol: [G] = M1L3T2 MT2 dG 3L M 2T G L M T = 3b + a + 2c = a + 3b + 2c 31. It has three geometrical isomers. The reason for the formation Ans : *acidic nature of B(OH)3 Sol: B(OH)3 is a Lewis acid. The (SIO32)n Ans : cyclic silicates Sol: Linear single chain = L3 empirical formula SiO 3 2 silicates n have 32. But actually it is monobasic acid 27. When a metal is in its low oxidation state. Ans : 1.C = = 0. The statement that is NOT Ans : silicates are mainly built through ‘SiO2’ units Sol: silicates are built through tetrahedral SiO44 units 25.
NH2 KOH 37. the carbon attached to the benzene ring must contain at least one hydrogen Ans : Me 40. The major product formed in the Sol: O For the oxidation of the side chain. Ans : III 41. the one C(CH 3)3 Ans : (optically inactive) 35. HNO3 / conc. The following transformation O Ans : NaOH / I2 Sol: Iodoform reaction will bring about the given conversion Br H2N . 3Ans : pyridinium chlorochromate followed by peracetic acid Sol: CH3 CHOH CH3 PCC Ans : i. Br2 / FeBr3 iii. NH2. The following reaction is Ans : i (CH3)2CHCOCl / AlCl3 : ii. Br2 / FeBr3 : iii.Sol: CH2CH3 H2C CH CH CH2OH (optically active) H2 / Ni CH2CH3 H3C CH2 CH CH2OH CH3 C O CH3 CH3CO3H CH3 C O OCH3 39. H2SO4: ii. NH2 / KOH Sol: Ozonolysis of the given unsaturated compound gives CH3 C (CH2)3 C CH3 O O This undergoes intramolecular aldol condensation to form the compound having structure (A) Sol: (CH3)2CHCOCl / AlCl3 O Br2 / Fe 36. Isopropanol can be converted 42. This undergoes ring expansion followed by loss of proton gives (B) 38. Sn / HCl iv. Among the isomeric butylbenzenes. NaNO2 / HCl. CuBr . The major product of the followingO does not undergo ionisation Ans : CH3 CH3 Sol: Cl (III) because the antiaromatic Sol: resultant cation is Protonation of oxygen followed by cleavage of three membered ring gives a 3 carbocation.05C v. Conversion of benzene into 1. Among the following halides.
5 M 1 1 PV spontaneously = 30 46. Assuming H and S do not change with NO2 Sn / HCl Br N2Cl NaNO2 / HCl 050C Br Br CuBr Br NH2 Ans : 300 K Sol: Br A() A ( g) H = 30 kJ mol1 S = 100 J mol1 T= H S = 300 K 48.4 50.25 cm1 45.08 312.4 Sol: H2CO3 HCO 3 H HCO 3 . The van der Waals coefficient of the inert  .25 cm1 1 1 RH 2 2 n1 n2 1 = 109737 0 4 [H ] C K a1 .0006 43. A solution of CaCl2 was prepared by Ans : 0. A one litre glass bulb is evacuated and Ans : 30 Sol: W RT M 1. The Habers’s process process for the Ans : Ammonia dissociates above 500 K Sol: G= H TS At equilibrium G = 0 T= H S Above 500 K. Of thr four values of pH given below which Ans : 4.0112 = 112 = 0.0006 Sol: Tf =i Kf m 3 2 0. The highest transition energy Ans : 27434. Liquid oxygen and liquid nitrogen are Ans : Liquid oxygen will be attracted but liquid nitrogen unaffected Sol: Oxygen is paramagnetic and nitrogen is diamagnetic 49. 2 H CO 3 44. C since K a1 >> K a2 = Sol: 4 107 4 103 = 4 105 pH = 4.Sol: HNO3 / H2SO4 Ans : Induced dipole. G is +ve 95 103 500K 190 = 27434.Induced dipole : increased atomic volume Sol: ‘a’ is a measure of attraction between the molecules and ‘b’ is a measure of the size of the molecules 0 0 NO 2 Br2 / FeBr3 47.2 0.
Ans : 20 = 100 Vc 100 V +81 = 100 Vc 744 81 825 Vc = = 100 100 55.P(L  7) + P (others).PART C MATHEMATICS Sol: 51. P7 Pothers 36 36 36 1 2 36 3 P(12  L) 1 2 6 1 29 1 36 3 36 2 36 3 1 = 20 10 2 xc x = 100 V ___(1) 2 2 10 xc x = 100 V ___(2) ∵ x 46 xc x 1 10 x 9 2 x c x 2 12 102 x 2 99 10 c x From 2 99 x 9 2 (2) = 100 Vc 10 2 10 x2 x 990 18 46 81 52. So in the first 5 trials . Probability = 2 8 2x 2 (10 2 x ) 1 (2x 3)2 Rearranging 2 (10 2x 1) = (2x + 3)2 2(10y 1) = y2 + 6y + 9. 2 2 2 2 Ans : 2 2 5 32 3 P3 = 410 2 1 3 1 . 5 1 Probability = 5 C2 32 2 6 4 10 3 2 1 2 310 2 2 10 56. Let z = a cos i sin 5 5 a2010 1 z Ans : . P(L  12) + P(7) . taking y = 2x 2 Y 14y + 11 = 0 C4 C4 64 2x1 x 2 = 11 x1 + x2 = log2 11 54. P(L  others) 1 6 29 P(12) = . P2 = 410 . A fair coin is tossed 6 times  Sol: P = 410 P1 = 410 3 3 1 .even 2 2 t t Head appears as the 6th trial for the third time. 1 Ans : 20 x2 x n n 2 V 2 Sol: Let L denote the event of offering lunch P(L) = P (12).Head appeared twice. when t . A spices has an initial population 4 . Martin throws two dice simultaneously. If 4 squares are chosen at random 8 Ans : 2 C4 C4 64 Sol: Eight squares lie on a main diagonal and there are 2 main diagonals. The sum of the roots of the equation Ans : log211 Sol: Rewriting log2 2x log2 2 log2 (2x 3)2 log2 (10 2 x ) 0 t 3 2 3 4 4 t = 20 t 10 2 53.P4 = 410 2 2 2 t t Sol: Pt = 4 10 3 2 1 2 . A student was calculating the variance Ans : 825 100 57.
2 y arg (z +1) = tan1 = x 1 y arg (z 1) = tan1 = x 1 y y tan x 1 x 1 1 1 2 Since tan tan tan = x 1 x 1 2 y y 2 = 2y y = 1 line parallel to the x axis 59. 1) and the origin Ans : x2 y2 z2 = 0 Sol: The semi vertical angle is given by x 1 sin = r 2 locus of any point on the cone is x 1 r 2 i.5 1 1.. 0.5 2 1.e. A line segment joining (1. 2 62. Consider the circles C1 : x y = 64 2 2 6 6 Ans : 2. Let (x. The number of solutions of the equation Ans : 6 Sol: From the following graph it is seen that there are 6 intersection points. The locus of the point z satisfying argAns : a single point Sol: let z = x + iy Z +1 = (x +1) + i y 61. z) be any point on the line passing Ans : i + j 2k Sol: (x. Then the vector perpendicular to the plane passing through (x..5 2 0 180 360 540 = a 1 z 2010 58.. for exactly one a> 0 Sol: Equation can be written as 1 1 1 cos x a 4 a 2 2 Sol: .. z) will be perpendicular to i + j + k i.Sol: 2010 2010 z2010 a2010 cos i sin 5 5 = a 2010 2. sin x + cos x= Ans : there is a solution. 360 180 0. For the equation. y. y. 1 2 2 2 or x y z = 0 2 63. i + j 2k .e x2 x y z 2 2 2 1 cos x a 4 a 1 if a> 0 a 2 . ) Equation is 2 2 2 x + y 2x 2y + 2 = 100 (1) Equation of given circle 2 2 x + y = 64 (2) Equation of common chord S1 S2 = 0 x + y 2 + 18 = 0 (3) Since length of common chord = 16 which is a diameter of x2 + y2 = 64 2 = 18 6 = 3 2 2 6 6 Centre 2.5 0 0.5 1 cos 2 i sin 2 2011 2012 = a2010 z z z 1 = z2010 1 z 2010 . equality for a = 1 a but cos x 1 4 Equation has one solution 60. y. z) passing through a line which is parallel to that vector i+ j+ k..Let centre of the circle be (.
Let f(x) = x x  Sol: log an = 1 1 2 n log 2 log 2 . 3n3 3n4 nx is  Ans : 27/4 Ans : (0... f () = .... The equation 2x 3x p = 0 3 2 lim (log an ) lim n 1 n 3 log 2 n r 1 n r = log2 x dx 2 log x dx = L 0 66.0 and B 0 cos sin sin OAB is isosceles OA = OB 5 4 k cos sin 5 4 cos = as sin k 41 k k AB = k 2 k 2 82 = 2 e tan u 0 / 4 = 2e/4 68. f’’(0) = 6 < 0. f (() = f is onto If 0 <x < f(x) = x ( x) (2+ cos2 x) f ( x) = x (x) (2 + cos2x) f is not one one 70.64. The value of 0 /2 2 sin x / 2 e dx is 1 cos x Let f(x) = 2x3 3x2 + p f’(x) = 6x (x 1).. A tangent to the ellipse x2 y2 1 25 16 Sol: 0 4 2 sin x 2 e dx 1 cos x x 2 0 x x sec 2 tan e 2 dx 2 2 x Ans : Sol: 82 = 2 Equation tangent is x y cos sin = 1 5 4 4 5 A . 1) r3 34 1 Sol: n lim 3n4 (3n 1 3n 27 2 lim 4 n13 4 3n 2 Sol: 67. Let an = 2n 1 2n 2.2n n1/ n n 3x Corresponding curve perpendicular to it 1 ie 3y = x 1 y Ans : 2 log x dx 3 3yy1 + x = 0 69.. log 2 n n n n n 1 Ans : onto but NOT oneone Sol: f(x) = x x (2 + cos2x) F(x) is continuous everywhere. f’’(1) = 6 > 0 f(0) = p . The value of lim 13 23 . The differential equation satisfied byAns : x+3yy1 = 0 y=x y =3x = 3 1 2 4 0 u sec u tan ueudu Sol: y1 3x2 Differential equation of given come in y = y1x3 2 3y = xy1 1 65. f(1) = 1 + p Ans : 2e 4 p 1 O 1 + p ..
b 3 . 1) 71. Again. 1) in the ratio 2:1 internally is (1. 3. 2.f(x) will have 3 distinct real roots if p > 0 and 1 + p < 0 i. 2. 73. 3) and parallel to r 3ˆ 2ˆ ˆ ˆ k is i j i j ˆ ˆ ˆ r i 2ˆ 3k ˆ ˆ k j i j ˆ lim log x x 1 y 2 z 3 1 2 1 x = 1 + . 3) . 3) Ans : 3 3 Sol: Equation of line passing through (1. 2. 0) Equation of the required plane is (x + y + z + 3) + (x y +3z 2) = 0 6 + (3) = 0 = 2 Equation is 3x y + 3z 1 = 0. lim f ( x ) lim2 h2 cos (2 h) h0 2 x 2 = 0. 2. ) R beAns : 2 Sol: f(x) = 2xsin2x cos2x x 0 x 0 lim f x 2 lim xsin 2x = 2e x 0 cos ec 2x = 2. 75. 2 i 2 2 h0 1 a 4. z = 3 + 2x + y + 2z + 5 = 0 2(1 + ) + (2 + ) + 2(3 + ) + 5 = 0 = 3 point of intersection is (2. lim f ( x) lim f (2 h) x2 h0 = 3 + 5 16 + 9 = 92. 0. [ 2 h ] Sol: Point dividing (3. Let f : (0. V1 V2 32 5a 2 b 2 lim h[1h] cos (1 h) = 0 1 h0 2 lim f ( x) lim h[1h] cos (1 h) = 0 1 h0 2 x 1 f(1) = 0 and f(x) is continuous at x = 1. 1. 0) Distance from (1. y = 2 + . A plane H passes through the intersectionˆ Ans : r 3ˆ ˆ 3k = 1 i j lim2 h cos (2 h) h 0 2 lim2 h1 cos (2 h) h0 2 = 1 cos = 1. 2) and (0. i. If the vectorAns : 92 Sol: Let V1 = ˆ ˆ k i j ˆ ˆ V2 = a ˆ bˆ ck i j V2 f(x) = x[ x ] cos x1 ˆ V1 V2 aˆ bˆ 2ak i j ˆ k 0 c = 2a ˆ . p (0. 74. f(x) is not continuous at x = 2. The distance of the point (1.e. ˆ r 3ˆ ˆ 3k = 1 i j 72.e. For a real number x let Ans : continuous at x = 1 but NOT continuous at x=2 Sol: x 2 lim f ( x) lim f (1 h) = 32 32 32 3 3 .
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