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1. PRODUCT AND COMPANY IDENTIFICATION
Product Name: Product Use: Print date: Revision Date: Company Identification The Valspar Corporation 1000 Lake Road Medina, OH 44256 Manufacturer's Phone: 24-Hour Medical Emergency Phone:
VAL66001 METAL BRONZE Paint product. 03/Jun/2010 03/Jun/2010
2. HAZARDS IDENTIFICATION
Primary Routes of Exposure: Inhalation Ingestion Skin absorption Eye Contact: • Severe eye irritation Skin Contact: • May cause defatting of the skin. Ingestion: • Irritation of the mouth, throat, and stomach. • Harmful if swallowed. • Aspiration hazard if swallowed - can enter lungs and cause damage. Inhalation: • Causes respiratory tract irritation. • Harmful by inhalation. • Asphyxia
Product ID: 465.0066001.076
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0066001.15 5 . if symptoms develop or persist. Get medical attention immediately. Do NOT induce vomiting. Target Organ and Other Health Effects: • Causes headache. Never give anything by mouth to an unconscious person. • Prolonged breathing of mica dust may produce pneumoconiosis. If vomiting occurs. • Blood disorders • Cardiac arrhythmias • Kidney injury may occur.Acute Other Health Effects: • May cause frostbite • Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Chemical Name Weight % 40 . Skin Contact: Remove contaminated clothing and shoes. immediately flush eyes with plenty of water for at least 15 minutes. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. keep head lower than hips to prevent aspiration. Ingestion: Rinse mouth with water. If easy to do. Get medical attention. Product ID: 465.076 Page 2 / 7 .45 Acetone 15 . remove contact lenses. Give one or two glasses of water. drowsiness or other effects to the central nervous system. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS Ingredient Name CAS-No. DIMETHYL KETONEEXEMPT SOLVENT 67-64-1 PROPANE 74-98-6 ISOBUTYL ACETATE 110-19-0 BUTANE 106-97-8 ETHYL 3ETHOXYPROPIONATE 763-69-9 PROPRIETARY INERT Approx. Wash off immediately with plenty of water for at least 15 minutes. Only induce vomiting at the instruction of medical personnel. If medical assistance is not immediately available. Get medical attention immediately. This product contains ingredients that may contribute to the following potential chronic health effects: • Notice: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage.10 5 . 3.20 10 . flush an additional 15 minutes.10 1-5 Propane Isobutyl acetate Butane Ethyl 3-ethoxypropionate PROPRIETARY INERT If this section is blank there are no hazardous components per OSHA guidelines. 4. FIRST AID MEASURES Eye Contact: In case of contact.
foam and/or water fog. HANDLING AND STORAGE Precautions to be taken in handling and storage: Keep away from heat. 8. FIRE FIGHTING MEASURES Flash point (Fahrenheit): Flash point (Celsius): Lower explosive limit (%): Upper explosive limit (%): Autoignition temperature: Sensitivity to impact: Sensitivity to static discharge: Hazardous combustion products: Unusual fire and explosion hazards: None known. If breathing stops. To protect rescuer. oxy-viva or one-way mask. Avoid breathing dust or vapor. for proper container and storage procedures. Empty containers may contain product residue. Activities. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS Personal Protective Equipment Eye and face protection: Chemical goggles. dry chemical. Extinguishing media: Carbon dioxide. Please see bonding and grounding information in Section 7. sparks and open flame. 5. Do not give direct mouthto-mouth resuscitation if inhaled. For breathing difficulties. Do not cut. Please ensure containers and other interconnected equipment are properly bonded and grounded at all times. Fire fighting procedures: Firefighters should be equipped with self-contained breathing apparatus and turn out gear. scrape or soak up in an inert material and put in a container for disposal. "Handling and Storage". -31 -35 1 13 not determined no Subject to static discharge hazards.076 Page 3 / 7 .No smoking. Keep containers and surroundings cool with water spray. also wear a face shield if splashing hazard exists. Remove all sources of ignition. 7. Get medical attention immediately. If the product is used near or above the flashpoint. including flammable or explosive vapors. See section 7. Avoid contact with eyes. Soak up with inert absorbent material. Use only non-sparking tools. (49 degrees C). Medical conditions aggravated by exposure: Any respiratory or skin condition. Keep container closed when not in use. ACCIDENTAL RELEASE MEASURES Action to be taken if material is released or spilled: Ventilate the area. Ontario OH&S regulation 851 section 22.106. Do not store above 120 degrees F. provide artificial respiration. use air-viva. See Section 10. oxygen may be necessary. Based on flash point and vapor pressure. uses. Resuscitate in a wellventilated area. . an ignition hazard may be present. All label warnings must be observed until the container has been commercially cleaned or reconditioned. 6. or operations which liberate vapor (such as mixing or free fall of liquids) may also present an ignition hazard. Skin protection: Product ID: 465. puncture or weld on or near container.0066001. Use self-containing breathing apparatus or airmask for large spills in a confined area. suitable storage should be provided in accordance with OSHA regulation 1910.Inhalation: Move injured person into fresh air and keep person calm under observation. Wipe.
20 10 . Respiratory protection: If exposure cannot be controlled below applicable limits. Ensure adequate ventilation. Ovens used for curing should contain a fresh air purge to prevent vapours from accumulating and creating a possible explosive mixture.45 15 .20 10 .15 1-5 TWA (final) 1000 ppm TWA 2400 mg/m3 TWA 1000 ppm TWA 1800 mg/m3 TWA 150 ppm TWA 700 mg/m3 TWA 2.076 Page 4 / 7 . DIMETHYL KETONEEXEMPT SOLVENT 67-64-1 PROPANE 74-98-6 ISOBUTYL ACETATE 110-19-0 PROPRIETARY INERT Approx. PHYSICAL PROPERTIES Odor: Physical State: pH: Vapor pressure: Vapor density (air = 1.Appropriate chemical resistant gloves should be worn.5 mg/m3 F_ Ceilings limits (final) Skin designations ACGIH Threshold Limit Value (TLV's) Ingredient Name CAS-No. use explosion-proof electrical/ventilating/lighting/equipment. especially in confined areas.0066001. Consult the respirator manufacturer's literature to ensure that the respirator will provide adequate protection.45 15 .0): Boiling point: Solubility in water: Normal for this product type.0 not determined not determined Product ID: 465. DIMETHYL KETONEEXEMPT SOLVENT 67-64-1 PROPANE 74-98-6 ISOBUTYL ACETATE 110-19-0 BUTANE 106-97-8 PROPRIETARY INERT Approx. Other Personel Protection Data: Usual industrial work clothes. Read and follow all respirator manufacturer's instructions. Exposure Guidelines OSHA Permissible Exposure Limits (PEL's) Ingredient Name CAS-No. use the appropriate NIOSH approved respirator such as an air purifying respirator with organic vapor cartridge and dust/mist filter. Weight % 40 . Where the product is used in a hazardous classified area. Ventilation Use only in well-ventilated areas. Weight % 40 .15 5 . Aerosol not determined NOT DETERMINED mmHg @ 68ºF (20ºC) 5.10 1-5 TWA 500 ppm TWA 1000 ppm TWA 150 ppm TWA 1000 ppm TWA 3 mg/m3 TWA respirable fraction STEL 750 ppm STEL Ceiling limits Skin designations 9.
076 Page 5 / 7 . NIOSH . Carbon monoxide and carbon dioxide.10 = 658 mg/L Inhalation LC50 Rat 4 h = 13400 mg/kg Oral LD50 Rat > 5000 mg/kg Dermal LD50 Rabbit = 658 mg/L Inhalation LC50 Rat 4 h = 10 mL/kg Dermal LD50 Rabbit = 3200 mg/kg Oral LD50 Rat Mutagens/Teratogens/Carcinogens: None known. 12.S.0066001.9.10 5 .45 = 5800 mg/kg Oral LD50 Rat 15 . 11. DIMETHYL KETONEEXEMPT SOLVENT 67-64-1 PROPANE 74-98-6 ISOBUTYL ACETATE 110-19-0 BUTANE 106-97-8 ETHYL 3ETHOXYPROPIONATE 763-69-9 Approx. Department of Transportation UN ID Number (msds): CONCOM Proper Shipping Name: CONSUMER COMMODITY ORM-D Product ID: 465.38 5.6 -31 -35 1 13 not determined 10.15 5 . 14. state and local regulations. Strong oxidizing agents None anticipated. TRANSPORTATION INFORMATION U. 13. PHYSICAL PROPERTIES Coefficient of water/oil distribution: Density (lbs per US gallon): Evaporation rate (butyl acetate = 1.Selected LD50s and LC50s Weight % 40 . Please see bonding and grounding information in Section 7. Subject to static discharge hazards. ECOLOGICAL DATA No information on ecology is available.0): Flash point (Fahrenheit): Flash point (Celsius): Lower explosive limit (%): Upper explosive limit (%): Autoignition temperature: not determined 6. TOXICOLOGICAL INFORMATION Ingredient Name CAS-No. STABILITY AND REACTIVITY Stability: Conditions to Avoid: Incompatibility: Hazardous Polymerization: Hazardous Decomposition Products: Sensitivity to static discharge: Stable under normal conditions. Heat. DISPOSAL CONSIDERATIONS Disposal should be made in accordance with federal.20 10 .
Highway & Rail Shipments The supplier may apply one of the following exceptions: Combustible Liquid.S. Weight % DIMETHYL KETONE40 . as allowed under 49CFR Hazmat Regulations. TRANSPORTATION INFORMATION U.076 SARA 313 CERCLA RQ in lbs. Page 6 / 7 . REGULATORY INFORMATION U. 5000 5000 yes yes yes no yes Trade Secret Not photochemically reactive.EXEMPT SOLVENT 67-64-1 PROPANE 74-98-6 ETHYL 3-ETHOXYPROPIONATE 763-69-9 Additional Non-Hazardous Materials PROPRIETARY RESIN Rule 66 status of product INTERNATIONAL REGULATIONS .14.S. FLAMMABLE Hazard Class: 2. Please consult 49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions.Chemical Inventories Product ID: 465. Chapter 317. or others. Pennsylvania Right To Know: BUTANE 106-97-8 ISOBUTYL ACETATE 110-19-0 PROPRIETARY INERT Trade Secret DIMETHYL KETONE. Limited Quantity. Viscous Liquid.45 EXEMPT SOLVENT 67-64-1 ISOBUTYL ACETATE 10 .1 15.15 110-19-0 SARA 311/312 Hazard Class: Acute: Chronic: Flammability: Reactivity: Sudden Pressure: U. FLAMMABLE Hazard Class: 2. Reportable Quantity Description: International Air Transport Association (IATA): UN ID Number (msds): UN1950 Proper Shipping Name: AEROSOLS. Does Not Sustain Combustion.0066001. Consumer Commodity. FEDERAL REGULATIONS: Ingredient Name Approx.S.1 International Maritime Organization (IMO): IMO UN/ID Number (msds): UN1950 Proper Shipping Name: AEROSOLS. SARA 302 CAS-No. STATE REGULATIONS: Right to Know: The specific chemical identity of a component may be withheld as a trade secret under 34 Pennsylvania Code.
parts per million. PEL . C .Time Weighted Average. IATA .National Toxicology Program. RQ Reportable quantity.0066001.Not applicable.Celsius.Lead. TSCA Chemical Substance Inventory Requirements. IARC . WT .Millions of particles per cubic foot. TWA . Preparation Information: Prepared By: Print date: Revision Date: Regulatory Affairs Department 03/Jun/2010 03/Jun/2010 Product ID: 465.Milligrams per cubic meter.American Conference of Governmental Industrial Hygienists.Short term exposure limit.International Agency for Research on Cancer. IMO . EXPRESS OR IMPLIED. SCAQMD . NIOSH National Institute of Occupational Safety and Health. INCIDENTAL OR CONSEQUENTIAL DAMAGES.International Maritime Organization. Canada Domestic Substances List: All components of this product are listed on the Domestic Substances List. STEL . F . Your only remedy for any defect in this product is the replacement of the defective product.South Coast Air Quality Management District.S.Fahrenheit. G/L .Millimeters. at our option. VALSPAR MAKES NO WARRANTIES. this information should serve only as a general guide. OTHER INFORMATION HMIS Codes Health: Flammability: Reactivity: PPE: 2* 4 1 X . UNLESS VALSPAR AGREES OTHERWISE IN WRITING. NA . VALSPAR WILL NOT BE LIABLE FOR ANY SPECIAL.A.See Section 8 for Personal Protective Equipment (PPE). N. PPM .US TSCA Inventory: All components of this product are in compliance with U. or a refund of its purchase price. TSCA Toxic Substances Control Act. AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. ACGIH .parts per thousand. NTP . PB . MG/CU M . This MSDS contains additional information required by the state of Pennsylvania. Since application variables are a major factor in product performance. Abbreviations: OSHA .Tag closed cup / Pensky-Martens.Grams per liter.V. 16.076 Page 7 / 7 .International Air Transport Association.Department of Transportation.Weight. MM .Not established. DOT . Disclaimer: The data on this sheet represent typical values. Valspar assumes no obligation or liability for use of this information.Occupational Safety and Health Administration. . TCC/PM .Not available. MPPCF .Permissible exposure level. NOT ESTAB . PPT .
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