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pH Absorb

ance
[λ=305
nm]

3 1.72
4 1.67
5 1.46
6 1.28
7 1.22
8 1.2
9 1.19
10 1.18
11 1.18
Fig (23) Spectra of the compound (49-e)
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1
0.9
A

0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
Row 3 Row 4 Row 5 Row 6 Row 7 Row 8 Row 9 Row 10 Row 11 Row 12 Row 13
pH
Row 13
pH Absorb Absorb
ance ance
[λ=314 [λ=378
nm] nm]

3 1.88 0.06
4 1.83 0.13
5 1.48 0.39
6 0.96 0.75
7 0.84 0.9
8 0.8 0.92
9 0.8 0.93
10 0.77 0.93
11 0.76 0.93
Fig (25): Spectra of the compound (49-g)
2

1.8

1.6

1.4

1.2

1
A

0.8

0.6

0.4

0.2

0
Row 3 Row 4 Row 5 Row 6 Row 7 Row 8 Row 9 Row 10 Row 11 Row 12 Row 13
pH
Row 13
pH Absorb Absorb
ance ance
[λ=315 [λ=374
nm] nm]

3 1.6 0.1
4 1.51 0.18
5 1.19 0.55
6 0.8 1.07
7 0.65 1.25
8 0.65 1.31
9 0.61 1.31
10 0.56 1.31
11 0.56 1.31

Fig (19): Spectra of the compound (49-a)


Fig (19): Spectra of the compound (49-a)
1.6
1.5
1.4
1.3
1.2
1.1
1
0.9
0.8
A

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
Row 3 Row 4 Row 5 Row 6 Row 7 Row 8 Row 9 Row 10 Row 11 Row 12 Row 13
pH
Row 13
pH Absorb Absorb
ance ance
[λ=260 [λ=305
nm] nm]

3 1.28 1.85
4 1.39 1.72
5 1.6 1.4
6 1.86 1.25
7 1.86 1.14
8 1.86 1.1
9 1.85 1.08
10 1.88 1.08
11 1.87 1.08

Fig (22): Spectra of the compound (49-d)


Fig (22): Spectra of the compound (49-d)
2

1.8

1.6

1.4

1.2

1
A

0.8

0.6

0.4

0.2

0
Row 3 Row 4 Row 5 Row 6 Row 7 Row 8 Row 9 Row 10 Row 11 Row 12 Row 13
pH
Row 13
pH Absorb Absorb
ance ance
[λ=280 [λ=305
nm] nm]

3 0.9 1.27
4 0.97 1.13
5 1.06 0.93
6 1.25 0.74
7 1.29 0.71
8 1.28 0.72
9 1.29 0.77
10 1.3 0.77
11 1.31 0.77

Fig (21): Spectra of the compound (49-c)


Fig (21): Spectra of the compound (49-c)
1.4
1.3
1.2
1.1
1
0.9
0.8
0.7
A

0.6
0.5
0.4
0.3
0.2
0.1
0
Row 3 Row 4 Row 5 Row 6 Row 7 Row 8 Row 9 Row 10 Row 11 Row 12 Row 13
pH
Row 13
pH Absorb Absorb
ance ance
[λ=280 [λ=376
nm] nm]

3 1.04 0.22
4 1.14 0.4
5 1.29 1
6 1.44 1.46
7 1.45 1.48
8 1.53 1.54
9 1.53 1.51
10 1.6 1.51
11 1.67 1.56

Fig (24): Spectra of the compound (49-f)


Fig (24): Spectra of the compound (49-f)
1.6
1.5
1.4
1.3
1.2
1.1
1
0.9
0.8
A

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
Row 3 Row 4 Row 5 Row 6 Row 7 Row 8 Row 9 Row 10 Row 11 Row 12 Row 13
pH
Row 13
pH Absorb Absorb
ance ance
[λ=266 [λ=311
nm] nm]

3 0.79 1.44
4 0.91 1.39
5 1.12 0.96
6 1.24 0.77
7 1.25 0.73
8 1.3 0.74
9 1.33 0.73
10 1.45 0.7
11 1.45 0.68

Fig (20): Spectra of the compound (49-b)


Fig (20): Spectra of the compound (49-b)
1.5
1.4
1.3
1.2
1.1
1
0.9
0.8
A

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
Row 3 Row 4 Row 5 Row 6 Row 7 Row 8 Row 9 Row 10 Row 11 Row 12 Row 13
pH
Row 13
Cppm Absorb
ance
[λ=327
nm]
0
5 0.03
10 0.06
25 0.16
50 0.32 500
100 0.64 400
200 1.31 300
300 1.98 200
400 2.65 100
500 3.3 50
25
10
5

Fig (33): Spectra of Hf- (49-a)


Fig (33): Spectra of Hf- (49-a)
3.5
3.25
3
2.75
2.5
2.25
2
1.75
A

1.5
1.25
1
0.75
0.5
0.25
0
0 5 10 25 50 100 200 300 400 500
Cppm
500
Cppm Absorb F
ance
[λ=329
nm]
0
Out of 143 500
5 scale
10 0.08 142 400
25 0.16 140 300
50 0.34 141 200
100 0.69 144.5 100
200 1.42 147 50
300 2.14 25
400 2.82 10
500 3.5 5

Fig (34)
Spectra of Hf- (49-f)
Fig (34): Spectra of Hf- (49-f)
3.5
3.25
3
2.75
2.5
2.25
2
1.75
A

1.5
1.25
1
0.75
0.5
0.25
0
0 5 10 25 50 100 200 300 400 500
Cppm
500
Cppm Absorb F
ance
[λ=329
nm]
0 135
5 Out of 131
scale
10 0.07 132
25 0.18 134
50 0.36 136
100 0.74 140
200 1.49 138
300 2.27 143
400 3.05
500 3.7

Fig (35)
Spectra of Hf- (49-g)
Fig (35): Spectra of Hf- (49-g)
3.75
3.5
3.25
3
2.75
2.5
2.25
2
A

1.75
1.5
1.25
1
0.75
0.5
0.25
0
0 5 10 25 50 100 200 300 400 500
Cppm
500
Cppm Absorb F
ance
[λ=322
nm]
0 169.5
5 0.15 168.8
10 0.32 166.1
25 0.47 164.6
50 0.62 162.16
100 0.93 162.6
200 1.22 158.23
300 1.81 157.23
400 2.37 166.67
500 2.95

Fig (36)
Spectra of Hf- (49-b)
Fig (36): Spectra of Hf- (49-b)
3
2.75
2.5
2.25
2
1.75
1.5
A

1.25
1
0.75
0.5
0.25
0
0 5 10 25 50 100 200 300 400 500
Cppm
500
Cppm Absorb F
ance
[λ=343
nm]
0 526
5 Out of 539
scale
10 0.02 559
25 0.05 553
50 0.1 549
100 0.2 543
200 0.39 531
300 0.57 513
400 0.74 512
500 0.91 526
600 1.09 531
800 1.43 526
900 1.67
1000 1.9

Fig (37)
Spectra of Hf- (49-e)
Fig (37): Spectra of Hf- (49-e)
2

1.8

1.6

1.4

1.2

1
A

0.8

0.6

0.4

0.2

0
0 5 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
0 1000
Cppm Absorb F
ance
[λ=384
nm]
0 1818
10 0.02 1818
25 0.03 1882
50 0.07 1916
100 0.06 1915
200 0.11 1886
300 0.16 1886
400 0.21 1770
500 0.26
600 0.31
800 0.43
900 0.5
1000 0.55

Fig (38)
Spectra of Zr- (49-a)
Fig (38): Spectra of Zr- (49-a)
0.6
0.55
0.5
0.45
0.4
0.35
0.3
A

0.25
0.2
0.15
0.1
0.05
0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000
Cppm Absorb F
ance
[λ=415
nm]
0
10 0.03
25 0.03
50 0.04
100 0.05
200 0.06
300 0.09
400 0.1
500 0.12
600 0.14
800 0.17
900 0.2
1000 0.23

Fig (39)
Spectra of Zr- (49-a)
Fig (39): Spectra of Zr- (49-a)
0.24
0.22
0.2
0.18
0.16
0.14
0.12
A

0.1
0.08
0.06
0.04
0.02
0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000
Cppm Absorb F
ance
[λ=417
nm]
0 1801
10 0.02 1800
25 0.03 1873
50 0.04 1863
100 0.06 1894
200 0.11 1887
300 0.16 1887
400 0.21 1802
500 0.26
600 0.32
800 0.43
900 0.5
1000 0.56

Fig (40)
Spectra of Zr- (49-f)
Fig (40): Spectra of Zr- (49-f)
0.6
0.55
0.5
0.45
0.4
0.35
0.3
A

0.25
0.2
0.15
0.1
0.05
0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000
Cppm Absorb F
ance
[λ=389
nm]
0 633
10 0.04 631
25 0.06 661
50 0.1 666
100 0.16 682
200 0.3 681
300 0.44 682
400 0.59 664
500 0.73 625
600 0.9
800 1.12
900 1.43
1000 1.58

Fig (41)
Spectra of Zr- (49-f)
Fig (41): Spectra of Zr- (49-f)
1.6
1.5
1.4
1.3
1.2
1.1
1
0.9
0.8
A

0.7
0.6
0.5
0.4
0.3
0.2
0.1
0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000
Cppm Absorb F
ance
[λ=433
nm]
0 4166
10 0.02 4411
25 0.03 4494
50 0.03 4444
100 0.04 4310
200 0.06 4124
300 0.08 3896
400 0.08 3226
500 0.12 2500
600 0.14
800 0.18
900 0.2
1000 0.24

Fig (42)
Spectra of Zr- (49-g)
Fig (42): Spectra of Zr- (49-g)
0.25

0.23

0.2

0.18

0.15

0.13
A

0.1

0.08

0.05

0.03

0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000
Cppm Absorb F
ance
[λ=392
nm]
0 1845
10 0.03 1859
25 0.04 1937
50 0.07 1941
100 0.08 1945
200 0.12 1960
300 0.16 1863
400 0.2
500 0.26
600 0.31
800 0.41
900 0.48
1000 0.54

Fig (43)
Spectra of Zr- (49-g)
Fig (43): Spectra of Zr- (49-g)
0.55

0.5

0.45

0.4

0.35

0.3
A

0.25

0.2

0.15

0.1

0.05

0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000
Cppm Absorb F
ance
[λ=417
nm]
0 1429
10 0.02 1782
25 0.03 1937
50 0.04 2040
100 0.06 2049
1000 0.07 2150
200 0.1 2127
300 0.14 2141
400 0.19
500 0.24
600 0.29
800 0.41
900 0.51

Fig (44)
Spectra of Zr- (49-b)
Fig (44): Spectra of Zr- (49-b)
0.55

0.5

0.45

0.4

0.35

0.3
A

0.25

0.2

0.15

0.1

0.05

0
0 10 25 50 100 1000 200 300 400 500 600 800 900
Cppm
900
Cppm Absorb F
ance
[λ=395
nm]
0 730
10 0.03 822
25 0.05 894
50 0.07 926
100 0.11 947
200 0.21 975
300 0.3 990
400 0.41 971
500 0.53 893
600 0.65
800 0.89
900 1.1
1000 1.37

Fig (45)
Spectra of Zr- (49-b)
Fig (45): Spectra of Zr- (49-b)
1.4
1.3
1.2
1.1
1
0.9
0.8
0.7
A

0.6
0.5
0.4
0.3
0.2
0.1
0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000
Cppm Absorb F
ance
[λ=410
nm]
0 2857
10 0.02 2857
25 0.04 2877
50 0.05 2857
100 0.08 2778
200 0.1 2758
300 0.11 2655
400 0.15
500 0.18
600 0.21
10 0.23
800 0.28
900 0.32
1000 0.35

Fig (46)
Spectra of Zr- (49-e)
Fig (46): Spectra of Zr- (49-e)
0.38
0.35
0.33
0.3
0.28
0.25
0.23
0.2
A

0.18
0.15
0.13
0.1
0.08
0.05
0.03
0
0 10 25 50 100 200 300 400 500 600 10 800 900 1000
Cppm
0 1000
Cppm Absorb F
ance
[λ=383
nm]
0 980
10 0.04 1000
25 0.06 1021
50 0.1 1010
100 0.16 990
200 0.21 1000
300 0.3 990
400 0.4 952
500 0.51
600 0.59
800 0.78
900 0.9
1000 1.02

Fig (47)
Spectra of Zr- (49-e)
Fig (47): Spectra of Zr- (49-e)
1.1

0.9

0.8

0.7

0.6
A

0.5

0.4

0.3

0.2

0.1

0
0 10 25 50 100 200 300 400 500 600 800 900 1000
Cppm
1000