23 views

Original Title: Bak

Uploaded by Buket Ibidan

- Converting Biomechanical Energy into Electricity by a Muscle-Movement-Driven Nanogenerator
- 2017 Book CharacterizationOfMineralsMeta
- 2007-08 TE Engg Chemical.pdf
- MMD
- Chemistry Revision Notes
- Carbon Nanotubes Presentation
- 2010 -Growth of Pattern-free InN
- Electrical Resistivity and Conductivity - Wikipedia, The
- HEAT TRANSFER Equations Module 5
- Time Table
- Solution Thermo Part 3
- Part 2 Pressure Vessel Design
- Installation Instructions
- Stress Analysis Report
- Earth Pressure Theory
- strength-aspects-of-glass-fibre-reinforced-concrete.pdf
- Bibl
- Design Calculation, Analysis & Design
- Engr. Humair Ahmed
- 46 Thesis Final ETD Correction

You are on page 1of 2

213 Chemical Engineering Thermodynamics Spring 2002 Problem Set I Due Wednesday, April 24, 2002 in lecture Problem 29 The Redlich-Kwong equation can be written as: P= RT a and manipulated to provide that V b T 0.5 V(V + b)

b ) V bRT1.5

a ln(1 +

d GR 1 dP GR P = o ( Z 1) (eq 6.46) or + Z 1 ln Z (eq 6.57) where = . = o ( Z 1) P V RT RT b) Determine the fugacity of n-butane gas at 500 K and 50 bar using the equation derived in a). c) Determine the fugacity of n-butane gas at 500 K and 50 bar using the values of HR = -4.51 kJ/mol and SR = -6.55 J/mol-K determined in Example 6.4 for n-butane under these conditions (pp 215-216 in SVN&A). d) Determine the fugacity of n-butane gas at 500 K and 50 bar using generalized correlations.

Problem 30 The excess Gibbs free energy of a binary liquid mixture at T and P is given by:

GE = (2.6 x1 1.8 x 2 ) x1 x 2 RT

a) Find expression of ln 1 and ln 2 at T and P. b) Show that when these expressions are combined in accord with Eq 11.95 that the given equation for GE/RT is recovered. c) Show that the expressions in a) satisfy the Gibbs-Duhem equation. d) Show that (d ln 1/dx1)x1=1 = (d ln 2/dx1)x1=0=0. e) Plot GE/RT, ln 1, and ln 2 as calculated by the given equation for GE/RT and by the equations developed in a) vs. x1. Label points ln 1 and ln 2 and show their values. f) Plot G/RT vs x1. g) Does (xi d i) = 0? Should it? Hint: consider the definition of the Gibbs-Duhem equation.

Problem 31 The data tabulated below are experimental values of HE for binary liquid mixtures of 1,2-dichloroethane (1) and dimethyl carbonate (2) at 313.15 K and 1 atm (from R. Francesconi et al. Int. DATA Ser. A, Vol. 25, No. 3, p. 225, 1997). x1 HE (J/mol) x1 HE (J/mol) 0.0426 -23.3 0.5163 -204.2 0.0817 -45.7 0.6156 -191.7 0.1177 -66.5 0.6810 -174.1 0.1510 -86.6 0.7621 -141.0 0.2107 -118.2 0.8181 -116.8 0.2624 -144.6 0.8650 -85.6 0.3472 -176.6 0.9276 -43.5 0.4158 -195.7 0.9624 -22.6 a) Determine from the data numerical values of the parameters a, b, and c in the correlating equation:

HE = x1 x2 (a + b x1 + c x12)

b) c) d) e)

(Hint: consider plotting HE/(x1x2) vs. x1 as a way to determine values of a, b, and c.) Determine the minimum value of HE from the results in part a). At what value of x1 does this occur? Determine expressions for H 1E and H 2E from the results of part a). Prepare a plot of H 1E and H 2E vs. x1 and discuss its features. Plot H vs. x1. What is the relationship between H and HE? Determine values of HE, H 1E , and H 2E for x1 = 0 and x1 = 1. For cases where HE = 0 and either H 1E or H 2E 0, explain how HE can equal 0 while either H 1E or H 2E do not.

Problem 32. Steam undergoes an isothermal change in state from 9000 kPa and 400 C to 300 kPa and 400 C. Determine using steam tables, the ratio of the fugacity in the final state to that in the initial state. (Hint: this question requires only a little bit of calculation, so think first about how to connect fugacities (or rather, fugacity ratios) given the type of data in a steam table.)

- Converting Biomechanical Energy into Electricity by a Muscle-Movement-Driven NanogeneratorUploaded bymagda
- 2017 Book CharacterizationOfMineralsMetaUploaded byEdward Giovanni Rodriguez Arias
- 2007-08 TE Engg Chemical.pdfUploaded byDheeraj Shukla
- MMDUploaded byEngr Zubair Ahmed
- Chemistry Revision NotesUploaded byFarhan Rahman
- 2010 -Growth of Pattern-free InNUploaded bySurica Soricel
- Electrical Resistivity and Conductivity - Wikipedia, TheUploaded byEhsan Fallahi
- Solution Thermo Part 3Uploaded byainmnrh
- Carbon Nanotubes PresentationUploaded byrajualag
- HEAT TRANSFER Equations Module 5Uploaded bygaza001
- Part 2 Pressure Vessel DesignUploaded bySyedZainAli
- Earth Pressure TheoryUploaded byTon Phichit
- Time TableUploaded byPrachee
- Installation InstructionsUploaded byAbidán Ponce
- strength-aspects-of-glass-fibre-reinforced-concrete.pdfUploaded byTushar Sharma
- Design Calculation, Analysis & DesignUploaded byarif_rubin
- Stress Analysis ReportUploaded byIhsan Samoh
- BiblUploaded byMiguel Cojal Aguilar
- Engr. Humair AhmedUploaded bymsaqibraza93
- 46 Thesis Final ETD CorrectionUploaded byarafat mohmmed
- Holton QuesUploaded byBùi Anh Tuấn Trần
- 17834-63948-1-PB.pdfUploaded byAli Beetle
- Material Science Sharing KnowledgeUploaded byReyan Qowi Dzakyprasetyo
- Measuremens of Soil Strength in Simple Shaer TestUploaded byHoracio Ulloa
- Material Science IntroUploaded byGleden Guardario Umayam
- Lecture 11.pdfUploaded byAdnen Nouri
- IJOGST_Volume 4_Issue 1_Pages 66-80.pdfUploaded bychemsac2
- Literature Cited apa formatUploaded byDe Leon Kai
- dftr pstkUploaded byudin
- Chapter 3Uploaded byUdai Singh

- Chapter 7-Second LawUploaded byIsrael Emmanuel
- GEOTEXTILESUploaded bySENTHIL KUMAR
- Photoelectric EXP84Uploaded byResy Apolinario
- Ch38FUploaded byVijay Kumar
- CE 2306 QB UNIT-IUploaded byManikandan Selvam
- Polymer Expansion PresentationUploaded byDeva Raj
- Cuo Wo3 PaperUploaded byperiasamy_nano
- Modelling of Metal Flow for Bearing DesignUploaded byLucian Dragos
- Oblique ShockUploaded byedsedg
- Sua Chua Vong BiUploaded bylinhcdt3
- Heat TreatmentUploaded bysurajitgupta
- Mex306 ExamUploaded byVaratharajaha Niroshan
- Tensile Test 2Uploaded byIkedi Uche
- Bala-Thermal Sprayed CoatingsUploaded byArunprasad Murugesan
- L11a_4345_Sp02Uploaded bySanjay Garg
- SampleUploaded bystreetranpu
- F1089Uploaded byGustavo Suarez
- AADE-07-NTCE-49Uploaded bynikhil_barshettiwat
- 1988 Brewe Khonsari New Current CavitationUploaded byRaman Kumar
- Homework 1 2017Uploaded byHemant Rathod
- AECT360Uploaded bykrmchari
- Behavior of r.c.c. Beam With Circular Opening Strengthened by Cfrp and Gfrp Sheets,2013, Mithun Kumar,IndiaUploaded by01010
- Attachment 2Uploaded byjoshibec
- Space GroupUploaded bybalachandar r k
- Orifice MeterUploaded byNur Dahlia
- TH2015PEST1096 CompleteUploaded byStefan Guran
- Photoluminescence Properties of Manganese-Doped Zinc Selenide Quantum Dots.pdfUploaded bysoumendra ghorai
- The Seismic Performance of Reinforced Concrete Wide Band Beam ConstructionUploaded byMahadi Hasan
- Cam ClayUploaded byWan
- Owl DistUploaded bypmarteene