This action might not be possible to undo. Are you sure you want to continue?
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Product Name: Other name(s): Recommended Use: Supplier: ABN: Street Address:
Ethanedioic acid; Ethanedionic acid; Dicarboxylic acid. Textile cleaning, rust removal, metal cleaning. Orica Australia Pty Ltd 99 004 117 828 1 Nicholson Street, Melbourne 3000 Australia +61 3 9665 7111 +61 3 9665 7937
Telephone Number: Facsimile: Emergency Telephone:
1 800 033 111 (ALL HOURS)
2. HAZARDS IDENTIFICATION
This material is hazardous according to criteria of ASCC; HAZARDOUS SUBSTANCE. Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail; NON-DANGEROUS GOODS. Risk Phrases: Safety Phrases: Harmful in contact with skin and if swallowed. Risk of serious damage to eyes. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. S6 Poison.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Components Oxalic acid CAS Number 144-62-7 Proportion 100% Risk Phrases R21/22 R41
4. FIRST AID MEASURES
For advice, contact a Poisons Information Centre (Phone eg. Australia 131 126; New Zealand 0 800 764766) or a doctor. Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Keep at rest until fully recovered. Seek medical advice if effects persist. Skin Contact: If skin or hair contact occurs, immediately remove any contaminated clothing and wash skin and hair thoroughly with running water. If swelling, redness, blistering or irritation occurs seek medical assistance. Eye Contact: Immediately wash in and around the eye area with large amounts of water for at least 15 minutes. Eyelids to be held apart. Remove clothing if contaminated and wash skin. Urgently seek medical assistance. Transport to hospital or medical centre.
Product Name: OXALIC ACID Substance No: 000030127001 Issued: 24/02/2009 Version: 2
Page 1 of 6
Keep containers closed when not in use . Store away from incompatible materials described in Section 10. dry. EXPOSURE CONTROLS/PERSONAL PROTECTION Oxalic acid: 8hr TWA = 1 mg/m3. clean up immediately. dry chemical powder). Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to products of decomposition. Suitable Extinguishing Media: Not combustible.check regularly for spills. Give a glass of water.Material Safety Data Sheet Ingestion: Rinse mouth with water. well ventilated place and out of direct sunlight. normal foam. If swallowed. Store away from foodstuffs. 5. Wear protective equipment to prevent skin and eye contact and breathing in dust. however. but avoid generating dust. dry agent (carbon dioxide. Collect and seal in properly labelled containers or drums for disposal. Medical attention and special treatment: Treat symptomatically. Keep containers cool with water spray. 6. maintained and used in accordance with the relevant regulations. do NOT induce vomiting. Conditions for safe storage: Store in a cool. 7. if material is involved in a fire use: Fine water spray. Precautions for fire fighters and special protective equipment: Decomposes on heating emitting toxic fumes. Methods and materials for containment and clean up: Avoid accidents. Can cause corneal burns. Avoid handling which leads to dust formation. Sweep up. If contamination of sewers or waterways has occurred advise local emergency services. Precautions for safe handling: Avoid skin and eye contact and breathing in dust. HANDLING AND STORAGE This material is a Scheduled Poison S6 and must be stored. ACCIDENTAL RELEASE MEASURES Emergency procedures: Clear area of all unprotected personnel. 8. Seek immediate medical assistance. FIRE FIGHTING MEASURES Hazards from combustion products: Non-combustible material. 15 min STEL = 2 mg/m3 Product Name: OXALIC ACID Substance No: 000030127001 Issued: 24/02/2009 Version: 2 Page 2 of 6 .
the physical form of the chemical. 1998: F . PHYSICAL AND CHEMICAL PROPERTIES Physical state: Colour: Odour: Solubility: Specific Gravity: Relative Vapour Density (air=1): Vapour Pressure (20 °C): Flash Point (°C): Flammability Limits (%): Autoignition Temperature (°C): Melting Point/Range (°C): Boiling Point/Range (°C): Decomposition Point (°C): pH: Product Name: OXALIC ACID Substance No: 000030127001 Granules or Crystals White to Clear Odourless Soluble in water . Keep containers closed when not in use.5 (dihydrate) 149 . chemical goggles and impervious gloves. Personal Protective Equipment: The selection of PPE is dependant on a detailed risk assessment. glycerol and alcohol.The time-weighted average airborne concentration over an eight-hour working day. nearly all workers. Orica Personal Protection Guide No. Partially soluble in ether. STEL (Short Term Exposure Limit) . Insoluble in chloroform.160 (dihydrate) Not available 1. These exposure standards should not be used as fine dividing lines between safe and dangerous concentrations of chemicals.3 (0.65 at 20°C Not available <0.14 Pa Not applicable Not applicable Not applicable 101. TWA . DUST MASK. 1. Wear overalls. Avoid generating and inhaling dusts. eating. According to current knowledge this concentration should neither impair the health of. petroleum ether and benzene .1m soln) Issued: 24/02/2009 Version: 2 Page 3 of 6 . Always wash hands before smoking. nor cause undue discomfort to. for a five-day working week over an entire working life. and environmental factors. GLOVES.the average airborne concentration over a 15 minute period which should not be exceeded at any time during a normal eight hour work day. All atmospheric contamination should be kept to as low a level as is workable. They are not a measure of relative toxicity. CHEMICAL GOGGLES. The risk assessment should consider the work situation. Wash contaminated clothing and other protective equipment before storage or re-use. SAFETY SHOES. wear dust mask/respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716. 1. Ensure ventilation is adequate and that air concentrations of components are controlled below quoted Exposure Standards. Engineering controls: Use with local exhaust ventilation or while wearing dust mask.OVERALLS.Material Safety Data Sheet As published by the National Occupational Health and Safety Commission. drinking or using the toilet. the handling methods. These Exposure Standards are guides to be used in the control of occupational health hazards. 9. If dust exists.
Incompatible with most metals in the presence of moisture. Solutions of 5% to 10% oxalic acid are irritating to the skin after prolonged exposure and can cause corrosive injury. Accelerated decomposition occurs when mixed with strong oxidising agents. drop in blood pressure and signs of heart failure. which will support combustion. Toxicological Data: Oral LD50 (rat): 475 mg/kg Dermal LD50 (rabbit): 2000 mg/kg Exposure to this compound can result in systemic effects including kidney damage.Material Safety Data Sheet 10. Reacts exothermically with alkalis . Contact with skin may result in irritation. Oxygen. pain and twitching in muscles. Inhaled oxalic acid is readily absorbed into the body and may cause headaches and nausea. especially sodium chlorite and sodium hypochlorite. May react violently with alkali metals producing flammable hydrogen gas. TOXICOLOGICAL INFORMATION No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. 12. convulsions. DISPOSAL CONSIDERATIONS Product Name: OXALIC ACID Substance No: 000030127001 Issued: 24/02/2009 Version: 2 Page 4 of 6 . Symptoms or effects that may arise if the product is mishandled and overexposure occurs are: Ingestion: Swallowing can result in a severe burning pain of the mouth. cramps and nervous system complaints. A severe eye irritant. Hygroscopic. Breathing in dust may result in respiratory irritation. Reacts strongly with oxidising agents. 13. ECOLOGICAL INFORMATION Ecotoxicity Avoid contaminating waterways. Hydrogen. and cramps. Large doses rapidly cause a shock-like state. Conditions to avoid: Incompatible materials: Hazardous decomposition products: Hazardous reactions: 11. throat and stomach followed by profuse vomiting (sometimes bloody). and with acid chlorides producing toxic fumes. Eye contact: Skin contact: Inhalation: Long Term Effects: Long term exposure can result in kidney stones and stone formation in the urinary tract. muscle twitching . coma and possibly death. Dry oxalic acid is not corrosive to metals. Larger doses can cause weak and irregular heartbeat. Avoid alkali material in storage and in use. Small doses of oxalate in the body can cause headache. Vigorous reaction may occur with alkalies yielding heat and pressure. Contamination of eyes can result in permanent injury. Can react with some silver compounds to form explosive silver oxalates. STABILITY AND REACTIVITY Chemical stability: Stable under normal ambient and anticipated storage and handling conditions of temperature and pressure. Carbon monoxide.
Dispose of material through a licensed waste contractor. 14. S26: In case of contact with eyes. R41: Risk of serious damage to eyes. S24/25: Avoid contact with skin and eyes. REGULATORY INFORMATION Classification: Hazard Category: This material is hazardous according to criteria of ASCC. S6 Poison. TRANSPORT INFORMATION Road and Rail Transport Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail. S36/37/39: Wear suitable protective clothing. rinse immediately with plenty of water and seek medical advice. Marine Transport Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea. gloves and eye/face protection. 16. 08/ 2006. Orica. HAZARDOUS SUBSTANCE.Material Safety Data Sheet Disposal methods: Refer to local government authority for disposal recommendations. NON-DANGEROUS GOODS. Xn: Harmful Xi: Irritant R21/22: Harmful in contact with skin and if swallowed. Risk Phrase(s): Safety Phrase(s): Poisons Schedule: This material is listed on the Australian Inventory of Chemical Substances (AICS). 15. OTHER INFORMATION Supplier Material Safety Data Sheet. NON-DANGEROUS GOODS. Air Transport Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air. Reason(s) for Issue: 5 Yearly Revised Primary MSDS Change in Personal Protection Requirements Product Name: OXALIC ACID Substance No: 000030127001 Issued: 24/02/2009 Version: 2 Page 5 of 6 . This material safety data sheet has been prepared by SH&E Shared Services. NON-DANGEROUS GOODS.
Orica Limited's responsibility for the material as sold is subject to the terms and conditions of sale. the user should contact their Orica representative or Orica Limited at the contact details on page 1. assess and control the risks arising from its use of the material. Since Orica Limited cannot anticipate or control the conditions under which the product may be used. If clarification or further information is needed.Material Safety Data Sheet This MSDS summarises to our best knowledge at the date of issue. Product Name: OXALIC ACID Substance No: 000030127001 Issued: 24/02/2009 Version: 2 Page 6 of 6 . prior to usage. a copy of which is available upon request. each user must. the chemical health and safety hazards of the material and general guidance on how to safely handle the material in the workplace.
This action might not be possible to undo. Are you sure you want to continue?
We've moved you to where you read on your other device.
Get the full title to continue reading from where you left off, or restart the preview.