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Levi Strauss & Co. (LS&CO.

) Restricted Substances List (RSL) Concerning Materials, Metal Parts, Products and Things of Value Supplied for LS&CO. Textile and Leather Apparel and Accessories
Version: Applicable: July 2006 Fall 2007 Season products and thereafter

Note that substances described herein are listed for a variety of regulatory, scientific and/or other reasons. The presence of a substance on this list should not be interpreted as suggesting that human exposure to that substance may or will cause any adverse health effect.
Levi Strauss & Co. RSL Version: July 2006 Page 1 of 14

Table 1: Substances commonly found in apparel


Restrictions on substances listed in Table 1 are of primary interest to LS&CO. LS&CO. may test materials, metal parts, products and things of value for these substances. LS&CO. suppliers and other contractors declare their compliance with these restrictions.
Chemical Group and Substance CAS Number Limit Value Final Product (mg/kg)1 Test Method2

DYES
Amines from Azo dyes, Disperse dyes, and Other dyes Azo Dyes3 that can form any of the following amines: 4-Amino azobenzene4 60-09-3 o-Aminoazotoluene 97-56-3 4-Aminodiphenyl 92-67-1 2-Amino-4-nitrotoluene 99-55-8 o-Anisidine 90-04-0 Benzidine 92-87-5 p-Chloroaniline 106-47-8 4-Chloro-o-toluidine 95-69-2 p-Cresidine 120-71-8 2,4-Diaminoanisole 615-05-4 4,4-Diamino-diphenylmethane 101-77-9 3,3-Dichlorobenzidine 91-94-1 3,3-Dimethoxybenzidine 119-90-4 4-Dimethylaminoazo-benzene 60-11-7 3,3-Dimethylbenzidine 119-93-7 3,3-Dimethyl-4,4-diamino-diphenylmethane 838-88-0 4,4-Methylene-bis-(2-chloraniline) 101-14-4 2-Naphthylamine 91-59-8 4,4-Oxydianiline 101-80-4 4,4-Thiodianiline 139-65-1 2,4-Toluenediamine 95-80-7 o-Toluidine 95-53-4 2,4,5-Trimethylaniline 137-17-7 2,4-Xylidine 95-68-1 2,6-Xylidine 87-62-7

Not Detected

European Directive 2002/61/EC Textiles General: EN 14362-1 Polyester: EN 14362-2 Leather: ISO 17234 [DL=30]

Any reference to the term Usage Ban indicates that the substance for which there is a usage ban is prohibited from use but that an acceptable trace amount is allowed up to the designated trace value (TR). Any reference to the term Not Detected indicates that the substance must not be detected in the final product. 2 The test method indicated shall be used by the LS&CO.-approved laboratory to determine compliance with the RSL. The methods Detection Limit must be less than or equal to the restricted concentration. A Detection Limit (DL) is indicated when a substance is restricted to a Not Detected amount. 3 See Appendix 1 for a partial list of azo dyes which, through reductive cleavage, may form restricted substances (amines). 4 The LS&CO.-approved laboratory must use a supplemental test method to confirm the presence of this amine. Levi Strauss & Co. RSL Version: July 2006 Page 2 of 14

Disperse Dyes Disperse Blue 1 Disperse Blue 3 Disperse Blue 7 Disperse Blue 26 Disperse Blue 35 Disperse Blue 102 Disperse Blue 106 Disperse Blue 124 Disperse Brown 1 Disperse Orange 1 Disperse Orange 3 Disperse Orange 11 Disperse Orange 37/59/76 Disperse Red 1 Disperse Red 11 Disperse Red 17 Disperse Yellow 1 Disperse Yellow 3 Disperse Yellow 9 Disperse Yellow 39 Disperse Yellow 49 Other Dyes Acid Red 26 Basic Red 9 Basic Violet 14 Direct Black 38 Direct Blue 6 Direct Red 28 Navy Blue6 2-Chloracetamide Sensitizing Isothiazolinones

2475-45-8 2475-46-9 3179-90-6 3860-63-7 12222-75-2 12222-97-8 12223-01-7 61951-51-7 23355-64-8 2581-69-3 730-40-5 82-28-0 12223-33-5 2872-52-8 2872-48-2 3179-89-3 119-15-3 2832-40-8 6373-73-5 12236-29-2 54824-37-2 3761-53-3 569-61-9 632-99-5 1937-37-7 2602-46-2 573-58-0 118685-33-9 BIOCIDES7 79-07-2 26530-20-1 26172-55-4 2682-20-4

Not Detected

DIN 542315 [DL=5] Units in mg/l

50

Solvent extraction / GC-MS

The result for method DIN 54231 is reported in milligrams of dye per liter of extract. Navy Blue dye is the mixture of disodium (6-(4-anisidino)-3-sulfonate-2-(3,5-dinitro-2-oxidophenylazo)-1-naphtholato)(1-(5-chloro-2-oxidophenylazo)-2naphtholato)chromate(1-) and trisodium bis(6-(4-anisidino)-3-sulfonato-2-(3,5-dinitro-2-oxidophenylazo)-1-naphtholato)chromate(1-), Color Index number 611-070-002, EC number 405-665-4. 7 Any biocide use requires LS&CO.s prior approval.
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Chlorinated benzenes Chlorinated toluenes9

CHLORINATED AROMATICS Various CAS numbers Usage Ban (TR=4) Various CAS numbers 63449-39-8 59536-65-1 32534-81-9 32536-52-0 78-30-8 126-72-7 5412-25-9 5455-55-1 FLAME RETARDANTS10 Usage Ban (TR=1) Usage Ban (TR=1) Usage Ban (TR=50) Usage Ban (TR=50) Usage Ban (TR=5) Usage Ban (TR=5) Usage Ban (TR=5) Usage Ban (TR=5) ISOCYANATES Free: 1 Blocked: 50 Free: 1 Blocked: 50 Free: 1 Blocked: 100 Free: 1 Blocked: 100 Free: 1 Blocked: 15 MONOMERS 100 1 50 50 10 50 50 Usage Ban (TR=1)

Solvent extraction / GC-MS

Chlorinated paraffins11 Polybrominated biphenyls (PBBs) Penta-bromodiphenyl ether (pentaBDE) Octa-bromodiphenyl ether (octaBDE) Tri-o-cresyl phosphate Tris (2,3-dibromopropyl) phosphate (TRIS) Bis (2,3-dibromopropyl) phosphate Tris (1-aziridinyl)-phosphine oxide (TEPA)

Solvent extraction / GC-MS

KOH digestion / headspace analysis of ethyleneimine fragment by GC-MS

Diphenylmethane diisocyanate (MDI) Hexamethylene diisocyanate (HDI) Isophorone diisocyanate (IPDI)12 Tetramethylxylene diisocyanate (TMXDI) Toluene diisocyanate (TDI)13

101-68-8 822-06-0 4098-71-9 2778-42-9 584-84-9 91-08-7 79-06-1 107-13-1 141-32-2 97-88-1 140-88-5 97-63-2 80-62-6 75-01-4

Analysis of free isocyanates: Solvent extraction / HPLC Analysis of releasable (blocked) isocyanates: Solvent extraction / GC-MS with injector block temperature at 300C.

Acrylamide Acrylonitrile Butyl acrylate Butyl methacrylate Ethyl acrylate Ethyl methacrylate Methyl methacrylate Vinylchloride
8

Solvent extraction / GC-MS Multiple headspace / GC-MS Solvent extraction / GC-MS Solvent extraction / GC-MS Solvent extraction / GC-MS Solvent extraction / GC-MS Solvent extraction / GC-MS Multiple headspace / GC-MS

Chlorinated benzenes include monochlorobenzene (108-90-7), all isomers of di-, tri-, and tetra-chlorobenzene, pentachlorobenzene (608-93-5) and hexachlorobenzene (118-74-1). 9 Chlorinated toluenes include all isomers of mono-, di-, tri-, and tetra-chlorotoluene and pentachlorotoluene (877-11-2). 10 Textiles supplied to LS&CO. are to meet LS&CO.s Class 1 Flammability ratings and manufactured without the use of flame retardants. Any Flame Retardant use requires LS&CO.s prior approval. 11 Including short chain chlorinated paraffins from C10H22-nCln to C30H62-nCln, where n=1-28, chlorine content 20% to 70%. Use LC-MS for C20 to C30. 12 LS&CO. does not allow the use of IPDI in materials, products or things of value intended for the U.S. market. 13 TDI restriction applies to both 2,4-TDI (CAS # 584-84-9) and 2,6-TDI (CAS # 91-08-7), individually. Levi Strauss & Co. RSL Version: July 2006 Page 4 of 14

METALS14 Restrictions for textile substrates Antimony (Sb) Arsenic (As) Cadmium (Cd) Chromium (Cr) total Cobalt (Co) Copper (Cu) Lead (Pb) Mercury (Hg) Nickel (Ni) Restrictions for natural leather substrates Antimony (Sb) Arsenic (As) Cadmium (Cd) Chromium (Cr+6) hexavalent Cobalt (Co) Copper (Cu) Lead (Pb) Mercury (Hg) Restrictions for metal parts16 Antimony (Sb) Cadmium (Cd) Chromium (Cr) total Chromium (Cr+6) hexavalent Lead (Pb)17 Mercury (Hg) Nickel (Ni)18 7440-36-0 7440-38-2 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7439-97-6 7440-02-0 7440-36-0 7440-38-2 7440-43-9 18540-29-9 7440-48-4 7440-50-8 7439-92-1 7439-97-6 7440-36-0 7440-43-9 7440-47-3 18540-29-9 7439-92-1 7439-97-6 7440-02-0 30 / 260 15 Usage Ban (TR=0.2) Usage Ban (TR=0.1) 1 1 25 Usage Ban (TR=0.2) Usage Ban (TR=0.02) 1 30 Not Detected Usage Ban (TR=75) Not Detected 1 25 Not Detected Usage Ban (TR=0.02) 60 75 60 Not Detected Extractable: 90 Total in surface coating: 0.06% 60 0.5 g/cm2/week

EN ISO 105-E04 / ICP-MS

EN ISO 105-E04 CEN TC 309 WI 065 [DL=20] CEN TC 309 WI 065 DIN 53314 [DL=3] EN ISO 105-E04 EN ISO 105-E0-4 CEN TC 309 WI 065 [DL=20] EN ISO 105-E04 EN 71: Part III EN 71: Part III EN 71: Part III DIN 53314 [DL=3] Extractable content: EN 71: Part III Total Content in Surface Coating: ASTM E1613/E1645 EN 71: Part III CEN EN 181119

Metal restrictions are separated into three categories: (1) metal restrictions for textile substrates, (2) metal restrictions for natural leather substrates, and (3) metal restrictions for metal parts. 15 LS&CO.s antimony limit for natural fibers is 30 mg/kg. For polyester fibers, LS&CO.s antimony limit is 260 mg/kg. 16 Metal parts include items such as buttons, zippers, rivets, snaps, etc. 17 Metal parts must comply with LS&CO.s extractable lead limit of 90 mg/kg (EN 71: Part III). A coated metal part must meet the extractable lead limit of 90 mg/kg (EN71:Part III) and LS&CO.s total lead in surface coating limit of a maximum of 0.06% (ASTM E1613/E1645). 18 For metallic parts used on garments, only the surface of the metallic part that has direct and prolonged skin contact must comply with the nickel limit value. 19 For metallic parts without a surface coating or plating, test in accordance with method EN 1811. For metallic parts with a surface coating or plating, test in accordance with method EN 12472. The same limit value of 0.5 g/cm2/week applies regardless of the test method used. Levi Strauss & Co. RSL Version: July 2006 Page 5 of 14

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SOLVENTS Benzene N,N-Dimethylformamide (DMF) Ethoxyethanol Ethoxyethanol acetate 2-Methoxyethanol 2-Methoxyethanol acetate 2-Methoxypropanol 2-Methoxypropanol acetate N-Methylpyrrolidone (NMP) 2-Phenoxyethanol o-Phenylphenol Tetrachloroethene (Perchloroethylene) Trichloroethylene (TCE) 2-Aminoethanol Diethylenetriamine Dipropylene triamine Formaldehyde20 Perflurooctane sulfonate (PFOS) Perfluorooctanoic acid, ammonium salt (PFOA) Thiourea Tributyltin (TBT) Triphenyltin (TPhT) Di(ethylhexyl) phthalate (DEHP) Di-iso-nonyl phthalate (DINP)
20

71-43-2 68-12-2 110-80-5 111-15-9 109-86-4 110-49-6 1589-47-5 70657-70-4 872-50-4 122-99-6 90-43-7 127-18-4 79-01-6 141-43-5 111-40-0 56-18-8

Usage Ban (TR=5) 2000 80 80 80 300 1000 2000 Usage Ban (TR=10) 400 50 10 50 AUXILIARY CHEMICALS 1000 50 50 Kids: 20 Adults: 75 Natural Leather Kids: 30 Adults: 150 Usage Ban (TR=1) Usage Ban (TR=1) 10
21

Solvent extraction / GC-MS or LC-MS

Solvent extraction / GC-MS Solvent extraction / GC-MS Solvent extraction / GC-MS

50-00-0 2795-39-3 3825-26-1 62-56-6 56573-85-4 668-34-8 117-81-7 28553-12-0

ISO method 14184-1 Solvent extraction / LC-MS Solvent extraction / LC-MS-MS Solvent extraction / GC-MS Ethanol extraction / GC-MS22 [DL=0.05]

ORGANOTIN COMPOUNDS (JAPAN ONLY) Not Detected PHTHALATES (JAPAN ONLY)23

Usage Ban [TR=1,000 mg/kg total phthalate]

Solvent extraction / LC-MS under high fragmentation

EXCEPTION: For baby products (age 0 24 months) intended for the Japanese market, the formaldehyde concentration must be below an absorbancy (A-A0) limit of 0.05 using JIS L1041-1983, Method A. 21 LS&CO.s organotin restriction only applies to products intended for the Japanese market. 22 When analyzing for organotin, the laboratory measures the concentration of tin from each compound. Thus, the results should be expressed in mg tin / kg. 23 LS&CO.s phthalate restriction only applies to products intended for the Japanese market. DEHP is restricted for products intended for age 0-6 years and DINP for age 0-3 years. For other markets, LS&CO. prefers that products do not contain phthalates in so far as practicable. Levi Strauss & Co. RSL Version: July 2006 Page 6 of 14

Table 2: Substances NOT commonly found in apparel


Restrictions listed in Table 2 are not commonly found in apparel products. Suppliers and contractors commit to implementing best business processes towards achieving compliance with these restrictions.
Limit Value Final Product (mg/kg) Usage Ban Test Method for Analysis of the Final Product U.S. EPA/600/R-93/116

Chemical Group and Substance

CAS Number ASBESTOS

actinolite, amosite, anthophylite, tremolite, chrysotile, crocidolite Group 1: 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 2,3,7,8-Tetrachlorodibenzofuran 2,3,4,7,8-Pentachlorodibenzofuran Group 2: 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 1,2,3,7,8-Pentachlorodibenzofuran 1,2,3,4,7,8-Hexachlorodibenzofuran 1,2,3,7,8,9-Hexachlorodibenzofuran 1,2,3,6,7,8-Hexachlorodibenzofuran 2,3,4,6,7,8-Hexachlorodibenzofuran Group 3: 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin 1,2,3,4,6,7,8-Heptachlorodibenzofuran 1,2,3,4,7,8,9-Heptachlorodibenzofuran 1,2,3,4,6,7,8,9-Octachlorodibenzofuran Group 4: 2,3,7,8-Tetrabromodibenzo-p-dioxin 1,2,3,7,8-Pentabromodibenzo-p-dioxin 2,3,7,8-Tetrabromodibenzofuran 2,3,4,7,8-Pentabromodibenzofuran Group 5: 1,2,3,4,7,8-Hexabromodibenzo-p-dioxin 1,2,3,7,8,9-Hexabromodibenzo-p-dioxin 1,2,3,6,7,8-Hexabromodibenzo-p-dioxin 1,2,3,7,8-Pentabromodibenzofuran

132207-33-1 DIOXINS AND FURANS 1746-01-6 40321-76-4 51207-31-9 57117-31-4 39227-28-6 19408-74-3 57653-85-7 57117-41-6 70648-26-9 72918-21-9 57117-44-9 60851-34-5 35822-46-9 3268-87-9 67562-39-4 55673-89-7 39001-02-0 50585-41-6 109333-34-8 67933-57-7 131166-92-2 110999-44-5 110999-46-7 110999-45-6 107555-93-1

Unavoidable traces acceptable up to 1 g/kg for Group 1

Unavoidable traces acceptable up to 5 g/kg for sum of Groups 1 & 2

Unavoidable traces acceptable up to 100 g/kg for sum of Groups 1, 2, and 3 Unavoidable traces acceptable up to 1 g/kg for Group 4 Unavoidable traces acceptable up to 5 g/kg for sum of Groups 4 & 5

U.S. EPA Method 8290

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Aldicarb Aldrin Chlordane Chlordimeform 1,2-Dibromo-3-Chloropropane (DBCP) p,p-Dichlorodiphenyldichloroethane (p,p-DDD) o,p-Dichlorodiphenyldichloroethane (o,p-DDD) p,p-Dichlorodiphenyldichloroethylene (p,p-DDE) o,p-Dichlorodiphenyldichloroethylene (o,p-DDE) p,p-Dichlorodiphenyltrichloroethane (p,p-DDT) o,p-Dichlorodiphenyltrichloroethane (o,p-DDT) 2,4-Dichlorophenoxyacetic acid, its salts and compounds Dicofol Dieldrin Endosulfan (Thiosulfan) Endrin Ethylene Dibromide (EDB) Hexachlorocyclohexane (HCH), all isomers24 Heptachlor Heptachlor epoxide Isodrin Kelevan Kepone Malathion Methoxychlor Methyl Parathion Mirex Paraquat Parathion Perthane Quintozene Strobane Telodrin Timiperone (DTTB) Toxaphene 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T), salts, compounds 2-(2,4,5-Trichlorophenoxy) propionic acid, salts, compounds Pentachlorophenol (PCP), salts, esters and compounds of PCP Tetrachlorophenol (TeCP), salts and compounds of TeCP

PESTICIDES 116-06-3 309-00-2 57-74-9 6164-98-3 96-12-8 72-54-8 53-19-0 72-55-9 3424-82-6 50-29-3 789-02-6 97-75-7 115-32-2 60-57-1 115-29-7 72-20-8 106-93-4 608-73-1 76-44-8 1024-57-3 465-73-6 4234-79-1 143-50-0 121-75-5 72-43-5 298-00-0 2385-85-5 1910-42-5 56-38-2 72-56-0 82-68-8 8001-50-1 297-78-9 57648-21-2 8001-35-2 93-76-5 93-72-1 87-86-5 25167-83-3

Not Detected

U.S. EPA Methods: 8081A / 8151A [DL=0.5]

Not Detected

35 LMBG B82.02-825 [DL=0.5]

24 25

All isomers of HCH, including alpha (319-84-6), beta (319-85-7), delta (319-86-8), epsilon (6108-10-7), and gamma (lindane, 58-89-9). EXCEPTION: PCP and TeCP analysis for leather substrates requires test method DIN 53313. Version: July 2006 Page 8 of 14

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OTHER ORGANIC CHEMICALS Halogenated biphenyls, including - Polychlorinated biphenyl (PCB) Halogenated diarylalkanes Halogenated naphthalenes Halogenated terphenyls, including - Polychlorinated terphenyl (PCT) Halogenated diphenyl methanes, including - Monomethyl-dibromo-diphenyl methane26 - Monomethyl-dichloro-diphenyl methane27 N-Methylaniline 1336-36-3 53469-21-9 Various CAS #s Various CAS #s Various CAS #s 99688-47-8 81161-70-8 76253-60-6 100-61-8

Usage Ban (TR=1)

Solvent extraction / GC-MS

- Monomethyl-tetrachloro-diphenyl methane28

Usage Ban (TR=30)

26 27

Also DBBT Also Ugilec 121 or Ugilec 21 28 Also Ugilec 141 Levi Strauss & Co. RSL Version: July 2006 Page 9 of 14

Appendix 1: Azo Dyes which, through reductive cleavage, may form restricted substances (amines)
Dye Name Color Index #
Acid Black 29 Acid Black 94 Acid Black 131 Acid Black 132 Acid Black 209 Acid Brown 415 Acid Orange 24 Acid Orange 45 Acid Red 4 Acid Red 5 Acid Red 24 Acid Red 73 Acid Red 85 Acid Red 114 Acid Red 115 Acid Red 116 Acid Red 128 Acid Red 148 Acid Red 150 Acid Red 158 Acid Red 167 Acid Red 264 Acid Red 265 Acid Red 420 Acid Violet 12 Acid Violet 49 Basic Brown 4 Basic Red 42 Basic Red 111 Direct Black 4 Direct Black 29 Direct Black 38 Direct Black 91 Direct Black 154 Direct Blue 1 Direct Blue 2 Direct Blue 3 Direct Blue 6

CAS Number (if available)


12217-14-0 6358-80-1 12219-01-1 12219-02-2 No CAS number No CAS number 1320-07-6 2429-80-3 5858-39-9 No CAS number No CAS number 5413-75-2 3567-65-5 6459-94-5 No CAS number No CAS number 6548-30-7 No CAS number No CAS number 8004-55-5 No CAS number No CAS number 6358-43-6 No CAS number 6625-46-3 1694-09-3 5421-66-9 No CAS number 113741-92-7 25156-49-4 No CAS number 1937-37-7 6739-62-4 54804-85-2 3814-14-3 2429-73-4 No CAS number 2602-46-2

Dye Name Color Index #


Direct Blue 8 Direct Blue 9 Direct Blue 10 Direct Blue 14 Direct Blue 15 Direct Blue 22 Direct Blue 25 Direct Blue 35 Direct Blue 53 Direct Blue 76 Direct Blue 151 Direct Blue 160 Direct Blue 173 Direct Blue 192 Direct Blue 201 Direct Blue 215 Direct Blue 295 Direct Brown 1 Direct Brown 1:2 Direct Brown 2 Direct Brown 6 Direct Brown 25 Direct Brown 27 Direct Brown 31 Direct Brown 33 Direct Brown 51 Direct Brown 59 Direct Brown 79 Direct Brown 95 Direct Brown 101 Direct Brown 154 Direct Brown 222 Direct Green 1 Direct Green 6 Direct Green 8 Direct Green 8:1 Direct Green 85 Direct Orange 1

CAS Number (if available)


2429-71-2 No CAS number 4198-19-0 72-57-1 2429-74-5 2586-57-4 25180-27-2 No CAS number 314-13-6 16143-79-6 110735-25-6 No CAS number No CAS number 159202-76-3 60800-55-7 6771-80-8 6420-22-0 3811-71-0 2586-58-5 25255-06-5 25180-39-6 33363-87-0 No CAS number 25180-41-0 No CAS number No CAS number 6247-51-4 6483-77-8 16071-86-6 No CAS number 6360-54-9 No CAS number 3626-28-6 4335-09-5 25180-47-6 No CAS number 72390-60-4 54579-28-1

Dye Name Color Index #


Direct Orange 6 Direct Orange 7 Direct Orange 8 Direct Orange 10 Direct Orange 108 Direct Red 1 Direct Red 2 Direct Red 7 Direct Red 10 Direct Red 13 Direct Red 17 Direct Red 21 Direct Red 22 Direct Red 24 Direct Red 26 Direct Red 28 Direct Red 37 Direct Red 39 Direct Red 44 Direct Red 46 Direct Red 62 Direct Red 67 Direct Red 72 Direct Violet 1 Direct Violet 12 Direct Violet 21 Direct Violet 22 Direct Yellow 1 Direct Yellow 24 Direct Yellow 48 Disperse Orange 149 Disperse Red 151 Disperse Yellow 7 Disperse Yellow 23 Disperse Yellow 56 Solvent Orange 7 Solvent Red 19 Solvent Red 23

CAS Number (if available)


6637-88-3 2868-76-0 64083-59-6 6405-94-3 No CAS number 25188-24-3 992-59-6 No CAS number 25188-29-8 25188-30-1 No CAS number 6406-01-5 No CAS number No CAS number No CAS number 573-58-0 3530-19-6 6358-29-8 6548-29-4 2302-97-8 No CAS number No CAS number 8005-64-9 25188-44-7 2429-75-6 No CAS number 25329-82-2 No CAS number 6486-29-9 No CAS number No CAS number No CAS number No CAS number 6250-22-3 No CAS number 3118-98-6 6368-72-5 85-86-9

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Appendix 2: Index of CAS Numbers


CAS Number
50-00-0 50-29-3 53-19-0 56-18-8 56-38-2 57-74-9 58-89-9 60-09-3 60-11-7 60-57-1 62-56-6 68-12-2 71-43-2 72-20-8 72-43-5 72-54-8 72-55-9 72-56-0 72-57-1 75-01-4 76-44-8 78-30-8 79-01-6 79-06-1 79-07-2 80-62-6 82-28-0 82-68-8 85-86-9 87-62-7 87-86-5 90-04-0 90-43-7 91-08-7 91-59-8 91-94-1 92-67-1 92-87-5

Substance
Formaldehyde p,p-Dichlorodiphenyltrichloroethane (p,p-DDT) o,p-Dichlorodiphenyldichloroethane (o,p-DDD) Dipropylene triamine Parathion Chlordane Lindane (-HCH) 4-Amino azobenzene 4-Dimethylaminoazo-benzene Dieldrin Thiourea N,N-Dimethylformamide (DMF) Benzene Endrin Methoxychlor p,p-Dichlorodiphenyldichloroethane (p,p-DDD) p,p-Dichlorodiphenyldichloroethylene (p,p-DDE) Perthane Direct Blue 14 Vinylchloride Heptachlor Tri-o-cresyl phosphate Trichloroethylene (TCE) Acrylamide 2-Chloracetamide Methyl methacrylate Disperse Orange 11 Quintozene Solvent Red 23 2,6-Xylidine Pentachlorophenol (PCP) o-Anisidine o-Phenylphenol 2,6-Toluene diisocyanate (2,6-TDI) 2-Naphthylamine 3,3-Dichlorobenzidine 4-Aminodiphenyl Benzidine

Chemical Group
Auxiliary Chemicals Pesticides Pesticides Auxiliary Chemicals Pesticides Pesticides Pesticides Azo Amines Azo Amines Pesticides Auxiliary Chemicals Solvents Solvents Pesticides Pesticides Pesticides Pesticides Pesticides Azo Dyes Monomers Pesticides Flame Retardants Solvents Monomers Biocides Monomers Disperse Dyes Pesticides Azo Dyes Azo Amines Pesticides Azo Amines Solvents Isocyanates Azo Amines Azo Amines Azo Amines Azo Amines

CAS Number
93-72-1 93-76-5 95-53-4 95-68-1 95-69-2 95-80-7 96-12-8 97-56-3 97-63-2 97-75-7 97-88-1 99-55-8 100-61-8 101-14-4 101-68-8 101-77-9 101-80-4 106-47-8 106-93-4 107-13-1 108-90-7 109-86-4 110-49-6 110-80-5 111-15-9 111-40-0 115-29-7 115-32-2 116-06-3 117-81-7 118-74-1 119-15-3 119-90-4 119-93-7 120-71-8 121-75-5 122-99-6 126-72-7

Substance
2-(2,4,5-Trichlorophenoxy) propionic acid 2,4,5-Trichlorophenoxyacetic acid (2,4,5-T) o-Toluidine 2,4-Xylidine 4-Chloro-o-toluidine 2,4-Toluenediamine 1,2-Dibromo-3-Chloropropane (DBCP) o-Aminoazotoluene Ethyl methacrylate 2,4-Dichlorophenoxyacetic acid Butyl methacrylate 2-Amino-4-nitrotoluene N-Methylaniline 4,4-Methylene-bis-(2-chloraniline) Diphenylmethane diisocyanate (MDI) 4,4-Diamino-diphenylmethane 4,4-Oxydianiline p-Chloroaniline Ethylene Dibromide (EDB) Acrylonitrile Monochlorobenzene 2-Methoxyethanol 2-Methoxyethanol acetate Ethoxyethanol Ethoxyethanol acetate Diethylenetriamine Endosulfan (Thiosulfan) Dicofol Aldicarb Di(ethylhexyl) phthalate (DEHP) Hexachlorobenzene Disperse Yellow 1 3,3-Dimethoxybenzidine 3,3-Dimethylbenzidine p-Cresidine Malathion 2-Phenoxyethanol Tris (2,3-dibromopropyl) phosphate (TRIS)

Chemical Group
Pesticides Pesticides Azo Amines Azo Amines Azo Amines Azo Amines Pesticides Azo Amines Monomers Pesticides Monomers Azo Amines Other Organic Chems Azo Amines Isocyanates Azo Amines Azo Amines Azo Amines Pesticides Monomers Chlorinated Aromatics Solvents Solvents Solvents Solvents Auxiliary Chemicals Pesticides Pesticides Pesticides Phthalates Chlorinated Aromatics Disperse Dyes Azo Amines Azo Amines Azo Amines Pesticides Solvents Flame Retardants

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CAS Number
127-18-4 137-17-7 139-65-1 140-88-5 141-32-2 141-43-5 143-50-0 297-78-9 298-00-0 309-00-2 314-13-6 319-84-6 319-85-7 319-86-8 465-73-6 569-61-9 573-58-0 584-84-9 608-73-1 608-93-5 615-05-4 632-99-5 668-34-8 730-40-5 789-02-6 822-06-0 838-88-0 872-50-4 877-11-2 992-59-6 1024-57-3 1320-07-6 1336-36-3 1589-47-5 1694-09-3 1746-01-6 1910-42-5 1937-37-7 2302-97-8 2385-85-5 2429-71-2 2429-73-4 2429-74-5

Substance
Tetrachloroethene (Perchloroethylene) 2,4,5-Trimethylaniline 4,4-Thiodianiline Ethyl acrylate Butyl acrylate 2-Aminoethanol Kepone Telodrin Methyl Parathion Aldrin Direct Blue 53 -HCH -HCH -HCH Isodrin Basic Red 9 Direct Red 28 2,4-Toluene diisocyanate (2,4-TDI) Hexachlorocyclohexane (HCH) Pentachlorobenzene 2,4-Diaminoanisole Basic Violet 14 Triphenyltin (TPhT) Disperse Orange 3

Chemical Group
Solvents Azo Amines Azo Amines Monomers Monomers Auxiliary Chemicals Pesticides Pesticides Pesticides Pesticides Azo Dyes Pesticides Pesticides Pesticides Pesticides Other Dyes Azo / Other Dyes Isocyanates Pesticides Chlorinated Aromatics Azo Amines Other Dyes Organotin Compounds Disperse Dyes Pesticides Isocyanates Azo Amines Solvents Chlorinated Aromatics Azo Dyes Pesticides Azo Dyes Other Organic Chems Solvents Azo Dyes Dioxins and Furans Pesticides Azo / Other Dyes Azo Dyes Pesticides Azo Dyes Azo Dyes Azo Dyes

CAS Number
2429-75-6 2429-80-3 2475-45-8 2475-46-9 2581-69-3 2586-57-4 2586-58-5 2602-46-2 2682-20-4 2778-42-9 2795-39-3 2832-40-8 2868-76-0 2872-48-2 2872-52-8 3118-98-6 3179-89-3 3179-90-6 3268-87-9 3424-82-6 3530-19-6 3567-65-5 3626-28-6 3761-53-3 3811-71-0 3814-14-3 3825-26-1 3860-63-7 4098-71-9 4198-19-0 4234-79-1 4335-09-5 5412-25-9 5413-75-2 5421-66-9 5455-55-1 5858-39-9 6108-10-7 6164-98-3 6247-51-4 6250-22-3 6358-29-8 6358-43-6

Substance
Direct Violet 12 Acid Orange 45 Disperse Blue 1 Disperse Blue 3 Disperse Orange 1 Direct Blue 22 Direct Brown 1:2 Direct Blue 6 Sensitzing Isothiazolinones Tetramethylxylene diisocyanate (TMXDI) Perflurooctane sulfonate (PFOS) Disperse Yellow 3 Direct Orange 7 Disperse Red 11 Disperse Red 1 Solvent Orange 7 Disperse Red 17 Disperse Blue 7 1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin o,p-Dichlorodiphenyldichloroethylene (o,pDDE) Direct Red 37 Acid Red 85 Direct Green 1 Acid Red 26 Direct Brown 1 Direct Blue 1 Perfluorooctanoic acid (PFOA) Disperse Blue 26 Isophorone diisocyanate (IPDI) Direct Blue 10 Kelevan Direct Green 6 Bis (2,3-dibromopropyl) phosphate Acid Red 73 Basic Brown 4 Tris (1-aziridinyl)-phosphine oxide (TEPA) Acid Red 4 -HCH Chlordimeform Direct Brown 59 Disperse Yellow 23 Direct Red 39 Acid Red 265

Chemical Group
Azo Dyes Azo Dyes Disperse Dyes Disperse Dyes Disperse Dyes Azo Dyes Azo Dyes Azo / Other Dyes Biocides Isocyanates Auxiliary Chemicals Disperse Dyes Azo Dyes Disperse Dyes Disperse Dyes Azo Dyes Azo Dyes Disperse Dyes Dioxins and Furans Pesticides Azo Dyes Azo Dyes Azo Dyes Other Dyes Azo Dyes Azo Dyes Auxiliary Chemicals Disperse Dyes Isocyanates Azo Dyes Pesticides Azo Dyes Flame Retardants Azo Dyes Azo Dyes Flame Retardants Azo Dyes Pesticides Pesticides Azo Dyes Azo Dyes Azo Dyes Azo Dyes

o,p-Dichlorodiphenyltrichloroethane (o,p-DDT)
Hexamethylene diisocyanate (HDI) 3,3-Dimethyl-4,4-diaminodiphenylmethane N-Methylpyrrolidone (NMP) Pentachlorotoluene Direct Red 2 Heptachlor epoxide Acid Orange 24 Polychlorinated Biphenyls (PCBs) 2-Methoxypropanol Acid Violet 49 2,3,7,8-Tetrachlorodibenzo-p-dioxin Paraquat Direct Black 38 Direct Red 46 Mirex Direct Blue 8 Direct Blue 2 Direct Blue 15

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CAS Number
6358-80-1 6360-54-9 6368-72-5 6373-73-5 6405-94-3 6406-01-5 6420-22-0 6459-94-5 6483-77-8 6486-29-9 6548-29-4 6548-30-7 6625-46-3 6637-88-3 6739-62-4 6771-80-8 7439-92-1 7439-97-6 7440-02-0 7440-36-0 7440-38-2 7440-43-9 7440-47-3 7440-48-4 7440-50-8 8001-35-2 8001-50-1 8004-55-5 8005-64-9 8005-78-5 9002-86-2 12217-14-0 12219-01-1 12219-02-2 12222-75-2 12222-97-8 12223-01-7 12223-33-5 12236-29-2 16071-86-6 16143-79-6 18540-29-9 19408-74-3 23355-64-8 25156-49-4 25167-83-3

Substance
Acid Black 94 Direct Brown 154 Solvent Red 19 Disperse Yellow 9 Direct Orange 10 Direct Red 21 Direct Blue 295 Acid Red 114 Direct Brown 79 Direct Yellow 24 Direct Red 44 Acid Red 128 Acid Violet 12 Direct Orange 6 Direct Black 91 Direct Blue 215 Lead (Pb) Mercury (Hg) Nickel (Ni) Antimony (Sb) Arsenic (As) Cadmium (Cd) Chromium (Cr) Cobalt (Co) Copper (Cu) Toxaphene Strobane Acid Red 158 Direct Red 72 Basic Brown 4 Polyvinyl Chloride (PVC) Acid Black 29 Acid Black 131 Acid Black 132 Disperse Blue 35 Disperse Blue 102 Disperse Blue 106 Disperse Orange 37/59/76 Disperse Yellow 39 Direct Brown 95 Direct Blue 76 Chromium (Cr+6) hexavalent 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin Disperse Brown 1 Direct Black 4 Tetrachlorophenol

Chemical Group
Azo Dyes Azo Dyes Azo Dyes Disperse Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Metals Metals Metals Metals Metals Metals Metals Metals Metals Pesticides Pesticides Azo Dyes Azo Dyes Azo Dyes Polyvinyl Chloride Azo Dyes Azo Dyes Azo Dyes Disperse Dyes Disperse Dyes Disperse Dyes Disperse Dyes Disperse Dyes Azo Dyes Azo Dyes Metals Dioxins and Furans Disperse Dyes Azo Dyes Pesticides

CAS Number
25180-27-2 25180-39-6 25180-41-0 25180-47-6 25188-24-3 25188-29-8 25188-30-1 25188-44-7 25255-06-5 25329-82-2 26172-55-4 26530-20-1 28553-12-0 32534-81-9 32536-52-0 33363-87-0 35822-46-9 39001-02-0 39227-28-6 40321-76-4 50585-41-6 51207-31-9 53469-21-9 54579-28-1 54804-85-2 54824-37-2 55673-89-7 56573-85-4 57117-31-4 57117-41-6 57117-44-9 57648-21-2 57653-85-7 59536-65-1 60800-55-7 60851-34-5 61951-51-7 63449-39-8 64083-59-6 67562-39-4 67933-57-7 70648-26-9 70657-70-4 72390-60-4 72918-21-9 76253-60-6

Substance
Direct Blue 25 Direct Brown 6 Direct Brown 31 Direct Green 8 Direct Red 1 Direct Red 10 Direct Red 13 Direct Violet 1 Direct Brown 2 Direct Violet 22 Sensitzing Isothiazolinones Sensitzing Isothiazolinones Di-iso-nonyl phthalate (DINP) Penta-bromodiphenyl ether (pentaBDE) Octa-bromodiphenyl ether (octaBDE) Direct Brown 25 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1,2,3,4,6,7,8,9-Octachlorodibenzofuran 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 2,3,7,8-Tetrabromodibenzo-p-dioxin 2,3,7,8-Tetrachlorodibenzofuran Polychlorinated biphenyl Direct Orange 1 Direct Black 154 Disperse Yellow 49 1,2,3,4,7,8,9-Heptachlorodibenzofuran Tributyltin (TBT) 2,3,4,7,8-Pentachlorodibenzofuran 1,2,3,7,8-Pentachlorodibenzofuran 1,2,3,6,7,8-Hexachlorodibenzofuran Timiperone (DTTB) 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin Polybrominated biphenyls (PBBs) Direct Blue 201 2,3,4,6,7,8-Hexachlorodibenzofuran Disperse Blue 124 Chlorinated paraffins Direct Orange 8 1,2,3,4,6,7,8-Heptachlorodibenzofuran 2,3,7,8-Tetrabromodibenzofuran 1,2,3,4,7,8-Hexachlorodibenzofuran 2-Methoxypropanol acetate Direct Green 85 1,2,3,7,8,9-Hexachlorodibenzofuran Monomethyltetrachlorodiphenylmethane

Chemical Group
Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Azo Dyes Biocides Biocides Phthalates Flame Retardants Flame Retardants Azo Dyes Dioxins and Furans Dioxins and Furans Dioxins and Furans Dioxins and Furans Dioxins and Furans Dioxins and Furans Other Organic Chems Azo Dyes Azo Dyes Disperse Dyes Dioxins and Furans Organotin Compounds Dioxins and Furans Dioxins and Furans Dioxins and Furans Pesticides Dioxins and Furans Flame Retardants Azo Dyes Dioxins and Furans Disperse Dyes Flame Retardants Azo Dyes Dioxins and Furans Dioxins and Furans Dioxins and Furans Solvents Azo Dyes Dioxins and Furans Other Organic Chems

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CAS Number
81161-70-8 99688-47-8 107555-93-1 109333-34-8 110735-25-6 110999-44-5 110999-45-6

Substance
Monomethyldichlorodiphenylmethane Monomethyldibromodiphenylmethane 1,2,3,7,8-Pentabromodibenzofuran 1,2,3,7,8-Pentabromodibenzo-p-dioxin Direct Blue 151

Chemical Group
Other Organic Chems Other Organic Chems Dioxins and Furans Dioxins and Furans Azo Dyes Dioxins and Furans Dioxins and Furans

CAS Number
110999-46-7 113741-92-7 118685-33-9 131166-92-2 132207-33-1 159202-76-3

Substance
1,2,3,7,8,9-Hexabromodibenzo-p-dioxin
Basic Red 111 Navy Blue 2,3,4,7,8-Pentabromodibenzofuran Asbestos Direct Blue 192

Chemical Group
Dioxins and Furans Azo Dyes Other Dyes Dioxins and Furans Asbestos Azo Dyes

1,2,3,4,7,8-Hexabromodibenzo-pdioxin 1,2,3,6,7,8-Hexabromodibenzo-pdioxin

Azo Dyes Without CAS Numbers


Acid Black 209 Acid Brown 415 Acid Red 5 Acid Red 24 Acid Red 115 Acid Red 116 Acid Red 148 Acid Red 150 Acid Red 167 Acid Red 264 Acid Red 420 Basic Red 42 Direct Black 29 Direct Blue 3 Direct Blue 9 Direct Blue 35 Direct Blue 160 Direct Blue 173 Direct Brown 27 Direct Brown 33 Direct Brown 51 Direct Brown 101 Direct Brown 222 Direct Green 8:1 Direct Orange 108 Direct Red 7 Direct Red 17 Direct Red 22 Direct Red 24 Direct Red 26 Direct Red 62 Direct Red 67 Direct Violet 21 Direct Yellow 1 Direct Yellow 48 Disperse Orange 149 Disperse Red 151 Disperse Yellow 7 Disperse Yellow 56

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Version: July 2006

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