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2 Name__________________________________ Part I 1.

(15 points) Given the following reactions: PH 3 (g) P(g) + 3H(g) O2 (g) 2O(g) H 2O(g) 2H(g) + O(g) 4P(g) + 5O 2 (g) P4 O10 (s) calculate the enthalpy change for the reaction 4PH 3 (g) + 8O2 (g) 6H2 O(g) + P4 O10 (s) H rxn = 965 kJ H rxn = 490 kJ H rxn = 930 kJ H rxn = -6760 kJ

3 Name__________________________________ 2. (20 points) 16.0g CH4 is introduced into a closed 67.2L container filled with O2 at STP and combusted. (a) Given H fo [CH 4 (g)] = -75 kJ/mole

H fo [CO2 (g)] = -394 kJ/mole


H fo [H 2O(g)] = -242 kJ/mole How much heat is evolved?

(b)

Assuming that all reactants and products remain as gases, what will be the final pressure of the container?

4 Name__________________________________ Part II 1. Nitric oxide, NO, reacts with water, to give ammonia, NH3, and oxygen, O2. The enthalpy of reaction, at 25C and 1 atm pressure for this reaction is:
o 4NO(g) + 6H 2O(g) 4NH 3 (g) + 5O2 (g); Hrxn = 906 kJ

What is the standard enthalpy of formation of ammonia H fo = NH 3 (g)? H fo = [NO(g)] = 90.3 kJ/mol, Hfo = [H2 O(g)] = -241.8 kJ/mol (a) -183.6 kJ/mol (b) +45.9 kJ/mol (c) -45.9 kJ/mol 2. Automobile air bags use the decomposition of sodium azide as their source of gas for rapid inflation. 2NaN3 (s) 2Na (s) + 3N2(g) What mass (g) of NaN3 is required to provide 40.0L of N2 at 25C and 763 Torr? (a) 1.64 3. (b) 1.09 (c) 160 (d) 107 (e) 71.1 (d) +754.5 kJ/mol (e) -188.6 kJ/mol

In the flask diagrammed below, the left bulb contains 3.0L of neon at a pressure of 2.0 atm. The right bulb contains 2.0L of argon at a pressure of 1.0 atm. What is the mole fraction of neon and argon in the final mixture after the valve is opened and a uniform pressure is reached at constant temperature (25C). Ne Ar (a) 0.327, 0.673 (b) 0.245, 0.755 (c) 0.750, 0.250 (d) 0.918, 0.817 (e) 0.613, 0.387
Ne 3.0L 2.0 atm Ar 2.0L 1.0 atm

5 Name__________________________________ 4. A chemist vaporized a liquid compound to determine its molar mass. If the density of the vaporized liquid (collected in a 120 mL flask) at 97C is 3.24 g/L, and the pressure exerted by the vaporized liquid is 0.958 atm, what is its molar mass? (a) 187 g/mol (b) 121 g/mol (c) 103 g/mol 5. (d) (e) 31.6 g/mol Insufficient information was given to calculate molar mass.

The relative speeds for each of the gas molecules Cl2, CO2, He and O2 at the same temperature increase in the order

(a) Cl2 < CO2 < O2 < He


(b) O2 < Cl2 < CO2 < He (c) CO2 < Cl2 < He < O2

(d) (e)

He < Cl2 < O2 < CO2 He < O2 < CO2 < Cl2

6.

Which element has configuration [Xe] 4f15d16s2? (a) Hf (e) Ce (b) Th (c) Pr (d) Ba

7.

Give the actual electron configuration for copper (Cu). (a) [Ar] 3d104s1 (b) [Ar] 3d9 (c) [Ar] 3d94s2 (d) [Ar] 3d84s2 (e) [Ar] 3d104s2

6 Name__________________________________ 8. Which of the following represent impossible combinations of n and l? 1. 4s (a) 2 and 3 (b) 3 only (c) 1 and 4 9. Which of the following is not a permitted set of quantum numbers for an orbital in an atom? (a) n = 2, l = 2, ml = 1 (b) n = 3, l = 1, ml = -1 (c) n = 1, l = 0, ml = 0 (d) n = 6, l = 1, ml = 0 (e) n = 5, l = 4, ml = -4 10. Which of the following sets of quantum numbers describes an electron in the 5f subshell? (a) n = 5, l = 0, ml = 3, ms = -1/2 (b) n = 5, l = 2, ml = 2, ms = +1/2 (c) n = 5, l = 1, ml = 1, ms = -1/2 (d) n = 5, l = 3, ml = 0, ms = +1/2 (e) n = 5, l = 4, ml = 4, ms = -1/2 11. What is the ground state electronic configuration for Cadmium (atomic number = 48)? (a) 1s22s22p63s23p64s23d104p64d45s25p6 (b) 1s22s22p63s23p63d104s24p64d12 (c) 1s22s22p63s23p63d104s24p65s25p65d4 (d) 1s22s22p63s23p63d104s24p64d104f2 (e) 1s22s22p63s23p63d104s24p65s24d10 2. 5f (d) (e) 3. 3 and 4 2 only 1p 4. 2d

7 Name__________________________________ 12. The electron configuration for the ground state of the fluorine atom (Z = 9) is best represented by which of the following orbital diagrams? (a) 1s (b) 1s (c) 1s 13. 2s 2p 3s 2s 2p 3s 2s 2p 3s (e) 1s 2s 2p 3s (d)
1s 2s 2p 3s

What is the maximum number of electrons in an atom that can have the following quantum numbers: n = 3, ms = +1/2 ? (a) 1 (b) 2 (c) 8 (d) 9 (e) 18

Some Potentially Useful Equations for General Chemistry Examinations MM is molar mass PV = nRT P x MM ( g / mol ) = dRT PVi PV2 i = 2 Ti T2 U = q + w, H = q p for a constant pressure process q = m x C(per gram) x T

v = c

E = hv

h p

p = momentum = mass x velocity for matter

Heisenberg Uncertainty Principle: xp x

h 4

Energy levels for the hydrogen atom:

En =

2.179 x 1018 J n2

H o = nH o (products) - mH o (reactants) f f

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