IDEAL PLUG FLOW REACTOR Characteristics of ideal plug flow PERFECT MIXING IN THE RADIAL DIMENSION (UNIFORM CROSS

SECTION CONCENTRATION) NO MIXING IN THE AXIAL DIRECTION, OR NO AXIAL DISPERSION (SEGREGATED FLOW)

Q CO

Q CL

0

L

0

time

TRACER PULSE INPUT AT t = 0 TRANSLATED TO EQUAL PULSE OUTPUT AT t = = L/v (L = PFR length, v = average velocity) COMPARE WITH CSTR RESPONSE TO TRACER PULSE DISPERSION

0

time 1

where dV = differential volume A = cross sectional area dx = differential distance and dV = Adx Mass balance over differential element on a reactant. concentration is a function of both distance along the flow path. x. t: C = C(x.In an ideal PFR. C In = QCx Out = QCx+dx Generation = dVrC = AdxrC Accumulation = dV Q Cx Q Cx+dx A x x+dx Cx t Adx Cx t QCx – QCx+dx + dVrC = dV Cx+dx = Cx + dCx Cx t Q(Cx – Cx – dCx) + dVrC = dV Cx t rC since Q is constant Q Cx V rC Cx t Cx V Q 2 . take mass balance on differential axial element with uniform reaction potential (concentration). and time.t) For a mass balance on a reacting compound.

the concentration of a reactant at any single point along the PFR is constant at Cx. not the average residence time as in a CSTR. C x 2. At steady-state. Overall a stable concentration profile is obtained at steady state.(V/Q) = Cx rC Cx t is the non-steady state ideal PFR mass balance for a reactant. Cx t 0 And the ordinary differential can be substituted for the partial differential Comments dCx d rC 1. At steady state. 3. is the absolute residence time for mass flowing through the reactor. In an ideal PFR. Compare ideal batch and ideal PFR mass balances: dC rC d dC Ideal batch : rC dt Position in a PFR is equivalent to time in a batch reactor Ideal PFR : 3 . with the concentration varying in space as the reaction occurs along the flow path.

steady-state 1st order reaction profile 1.4 0. r = -kC.For a 1st order reaction.8 0.6 0.2 0 0 1 2 3 4 5 6 Example: Chlorine contact basin for disinfection Q. Co Xo Q. Xe 4 .2 1 C/Co 0. Ce. in a PFR at steady state dC d CL kC kd 0 dC Co C CL = C0exp(-k ) Ideal PFR.

chlorine concentration which must be added to insure that there is detectable chlorine at PFR exit (detection level = CL = 0.25 m3/s*3600 s/hr*1. L. 2 coupled mass balances find: 1.Where Q = 0.260 m3/18 m2 = 70 m 3.4 hr = 1. Steady state mass balance on chlorine 5 .25 m3/s A = channel cross section between baffles = 18 m2 rd = rate of microorganism kill in presence of chlorine = -kdX X = concentration of microorganisms at any point in contact reactor Xo = influent concentration of microorganisms = 106 E.260 m3 L = V/A = 1. reactor volume and flow path length. such that XL < 103 cells/100 ml 2. Steady-state mass balance on cells XL = Xoexp(-kd ) = (1/kd)ln(Xo/XL) = (1/5)(hr)ln(106/103) = 1. coli/100 ml kd = 5 hr-1 rc = rate of chlorine decay (from microorganism Cl-demand) = -kcX kc = 10-5 (mg-chlorine/L)(#/100mL)-1hr-1 2 rate expressions.05 mg/L) 1.4 hr V = Q = 0. 2 constituents.

0E+03 1.0E+06 4.05 + (10-5(106)/5)(1-exp(-5(1.8 = x/v (hr) 1 1.4)) = 2.00 Cc (mg-chlorine/L) E.0E+04 2.4 0.0E+05 3.4 1.2 0.00 1.00 X Cc 1.6 0.00 1. coli (#/100 mL) 6 .2 1.0E+02 0 0.00 1.dC c d CL k cX k c X o exp( k d d ) dC c Cco k c X o exp( k d )d 0 CL CL C co C co (k c X o ) kd k c X o exp( k d ) kd (k c X o ) (1 exp( k d )) kd CCO = 0.6 0.05 mg/L Chlorine contact PFR 1.

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