8 views

Uploaded by kuthappady

- Chemical Kinetics
- UNIT 2 Kinetics and Equilibrium as Chem Kajana
- 1. Review of Organic Chemistry I
- Chandamama, Jan 2011
- W. T. M. L. Fernando et al- Gas-Phase Inorganic Chemistry: Laser Spectroscopy of Calcium and Strontium Monothiolates and Monohydrosulfides
- Rev Mole Balances 0
- SCH4U Equilibrium Questions With Solutions
- Lesson Plan
- 34_562ln08
- CFX Combust Radiation 16.0 L01 Intro
- Heat Capacities and Volumes of Dissociation of Phosphoric Acid
- Carbonilación Del Metanol
- Kinetics and Equilibrium - Precipitation of Lead Iodide C12!3!01
- Chapter 5 Chemical Equilibrium
- Catalytic and kinetic study of the liquid-phase hydrogenation of acetophenone over CuSiO2 catalyst.pdf
- Removal of Ammonia as Struvite From Anaerobic Digester Effluents and Recycling of Magnesium and Phosphate
- CH 6_Equilibrium-1 (1)
- A General Approach to Describe the Antimicrobial Agent Release From Highly Swellable Films Intended for Food Packaging Applications
- Anna L. Mallam and Sophie E. Jackson- A Comparison of the Folding of Two Knotted Proteins: YbeA and YibK
- Waste___Biomass_Valor__2916__7__237__266

You are on page 1of 5

Equilibrium constants can be calculated for any chemical system from the partition functions for the species involved. In terms of the partition function q, the chemical potential of a species (essentially the molar Gibbs free energy) is given by = RT lnq

k

Consider the reaction aA + bB pP + qQ. At equilibrium the free energy of the reactants is equal to the free energy of the products. Greact = Gprod aA + bB = pP + qQ RTln(NA/qA)a + RTln(NB/qB)b = RTln(NP/qP)p + RTln(NQ/qQ)q Rearranging gives NPpNQq qPpqQq = = Kn NAaNBb qAaqBb We recognise this as the equilibrium constant in terms of concentrations. We are often interested in Kp, the equilibrium constant in terms of partial pressures. For the case where all species involved are gases, we can convert from Kn to Kp using the ideal gas equation, p=nRT/V. Kp = pPppQq NPpNQq a b = pA pB NAaNBb

p q kT(p+q-a-b) qP qQ kTn = V a b qA qB V

energy, we need to include the extra factor eD0/kT (see previous tutorial). The equilibrium constant then becomes Kp =

where n = p+q-l-m is the change in the number of moles during reaction. If we use vibrational partition functions defined with energies measured from the zero-point

The quantity (pD0P+qD0Q-aD0A-bD0B) is recognised as the heat of reaction or standard enthalpy H00, the change in enthalpy in going from the reactant to product zero point energy.

We can also use statistical mechanics to obtain rate constants from partition functions. For a reaction A+B AB P, we assume that the reactions involved in forming the

activated complex AB are much faster than the formation of products from the complex. Kinetically, the reaction can then be treated as a pre-equilibrium, with K = [AB] [A][B]

rate = k [AB] = kK [A][B] = kobs[A][B] where kobs=kK is the observed rate constant and k is the rate constant for decomposition of the activated complex into products. The equilibrium constant K can be rewritten in terms of the appropriate partition functions, giving kobs = k qAB -H/RT e q Aq B

where the partition functions are evaluated with respect to the zero-point levels of the reactants and transition state. We can derive a complete expression for kobs by treating the motion of the activated complex over the top of the energy barrier (i.e. the reaction coordinate) as either a very loose vibration or as a translation.

DERIVATION 1 REACTION COORDINATE AS A VIBRATION Reactants A and B have 3N-6 vibrational degrees of freedom if non-linear, 3N-5 if linear. The same is true of the activated complex, which has 3(NA+NB)-6 vibrational modes if it is non-linear. One of these modes is of a different character from the rest, corresponding to a very loose vibration that allows the complex to dissociate into products. For this degree of freedom we can use a vibrational partition function q* in which the vibrational frequency tends to zero. i.e. lim q* = n0 1 1 kT = = 1-e-h/kT 1-(1-h/kT) h

The rate constant is now given by kT qAB -H/RT kobs = k e h qAqB where qAB is now less one degree of freedom corresponding to the reaction coordinate. The frequency is the vibrational frequency of the activated complex in the degree of freedom corresponding to its decomposition. It is therefore the frequency of decomposition i.e. the rate constant k. This means that kq*=kT/h, and the experimental rate constant is given by

kobs =

kT qAB -H/RT e h q Aq B

DERIVATION 2 REACTION COORDINATE AS A TRANSLATION Instead of using a vibrational partition function to describe the motion of the activated complex over the reaction barrier, we can also use a translational partition function. We consider all complexes lying within a distance x of the barrier (see diagram) to be activated complexes. The translational partition function for a particle of mass m in a box of length x is given by (2mkT)1/2x q* = h giving a rate constant (2mkT)1/2 qAB -H/RT kobs = k x e h q Aq B where qAB is less one degree of freedom as before. The average velocity of the particles moving from left to right over the barrier is given by kinetic theory as

kT 1/2 v = 2m

The frequency with which the complexes pass over the barrier is the rate constant k, given by k = v 1 kT 1/2 = x x 2m

When we substitute this equation into our expression for kobs, we obtain the same expression as obtained in derivation 1. kobs = 1 kT 1/2 (2mkT)1/2 qAB -H/RT x e 2m h q Aq B x kT qAB -H/RT = e h q Aq B

This equation is sometimes known as the Eyring equation. The main difficulty in applying transition state theory lies in determining qAB. However, modern methods and educated guesswork on the nature of the activated complex AB usually allow rate constants for bimolecular reactions to be estimated to within a factor of two using this theory.

There are two origins of the kinetic isotope effect. The first, quantum mechanical tunnelling through the reaction potential energy barrier, is usually only important at very low temperatures and for reactions involving very light atoms. For the simplest model case of a square barrier, the probability of tunnelling through the barrier is approximately P = exp-2

2m(V0-E) 1/2 a h2

The tunnelling probability therefore depends on the particle mass m, the particle energy E and the height V0 and width a of the barrier, but is independent of temperature. At normal temperatures, tunnelling makes only a small contribution to the overall reaction rate. However, since the rate of normal reaction falls off with temperature as less and less reactants have enough energy to surmount the activation barrier, at low temperatures the constant tunnelling contribution can make up a significant fraction of the overall reaction. The mass dependence of the tunnelling probability means that tunnelling rates are significantly different for different isotopes, which can lead to large kinetic isotope effects in some cases. More usually, kinetic isotope effects are caused by differences in the activation energy for reactions involving different isotopes due to either the reactants, the transition state, or both, having different zero point vibrational energies. Vibrational frequencies, and therefore vibrational zero point energies, depend on the reduced mass of the vibrating system. e = 2

1 k

The vibrational zero point energy he is inversely proportional to 1/2. The effect on the activation barrier for a reaction involving an H/D atom is shown below.

Since the transition state is (usually) more loosely bound than the reactants, the vibrational levels are more closely spaced. The net effect is that the activation energy is higher, and therefore reaction slower, for the heavier isotopomer (a normal isotope

effect). The maximum isotope effect is obtained when the bond involving the isotope is completely broken in the transition state, in which case the difference in activation energies is simply the difference in zero point energies of the reactants. In some reactions it is the zero point energy difference between the transition states which governs the kinetic isotope effect. In this case the activation energy is greater for the lighter isotope and an inverse isotope effect is observed, in which the heavier isotopomer undergoes faster reaction. To obtain a mathematical expression for the kinetic isotope effect we can use either the Arrhenius equation or the Eyring equation from transition state theory. Using the Arrhenius equation, the rates for the two isotopomers are kH = AH exp[-EA(H)/kBT] kD = AD exp[-EA(D)/kBT] Assuming the pre-exponential factors are the same for both isotopes (this is usually a reasonable approximation; if using transition state theory we can treat the problem properly and calculate the ratio using the partition functions for the two isotopic cases), the kinetic isotope effect, kH/kD, is therefore kH/kD = exp[-{EA(H)-EA(D)}/kBT] or in the limiting case of the maximum kinetic isotope effect, kH/kD = exp[-{E0(H)-E0(D)}/kBT] where E0(H) and E0(D) are the zero point energies of the H- and D-containing reactants.

- Chemical KineticsUploaded byEr Sunil Kumar
- UNIT 2 Kinetics and Equilibrium as Chem KajanaUploaded byKajana Sivarasa
- 1. Review of Organic Chemistry IUploaded byYan Li
- Chandamama, Jan 2011Uploaded byemediage
- W. T. M. L. Fernando et al- Gas-Phase Inorganic Chemistry: Laser Spectroscopy of Calcium and Strontium Monothiolates and MonohydrosulfidesUploaded byUasnsda
- Rev Mole Balances 0Uploaded byyudhaputra
- SCH4U Equilibrium Questions With SolutionsUploaded bySuvas Patel
- Lesson PlanUploaded bySomayazhini
- 34_562ln08Uploaded byavdv
- CFX Combust Radiation 16.0 L01 IntroUploaded byneurolepsia3790
- Heat Capacities and Volumes of Dissociation of Phosphoric AcidUploaded byVandenberg Soares de Andrade
- Carbonilación Del MetanolUploaded byPedro Juan
- Kinetics and Equilibrium - Precipitation of Lead Iodide C12!3!01Uploaded byCristian Navarro
- Chapter 5 Chemical EquilibriumUploaded byfit3akmal
- Catalytic and kinetic study of the liquid-phase hydrogenation of acetophenone over CuSiO2 catalyst.pdfUploaded byFrancisco Armas
- Removal of Ammonia as Struvite From Anaerobic Digester Effluents and Recycling of Magnesium and PhosphateUploaded byphaneufdl
- CH 6_Equilibrium-1 (1)Uploaded byCynthia Tran
- A General Approach to Describe the Antimicrobial Agent Release From Highly Swellable Films Intended for Food Packaging ApplicationsUploaded byArlette Pineda
- Anna L. Mallam and Sophie E. Jackson- A Comparison of the Folding of Two Knotted Proteins: YbeA and YibKUploaded byKeomss
- Waste___Biomass_Valor__2916__7__237__266Uploaded bypapapa14
- David Soloveichik, Matthew Cook, Erik Winfree and Jehoshua Bruck- Computation with Finite Stochastic Chemical Reaction NetworksUploaded byCogsms
- Kinetics of Formic AcidUploaded byhafizahmache

- Introduction to Bacteriological AnalysisUploaded bykuthappady
- Dilutions and StandardsUploaded bykuthappady
- UNIT III - PhotochemistryUploaded bykuthappady
- Analytical MethodsUploaded bykuthappady
- Raman SpectroscopyUploaded bykuthappady
- Estimation of Iodine Content in Iodized Common SaltUploaded bykuthappady
- Ammonia NitrogenUploaded bykuthappady
- Dissolved OxygenUploaded bykuthappady
- Volumetric AnalysisUploaded bykuthappady
- Residual ChlorineUploaded bykuthappady
- Determination of Suspended, Volatile and Fixed SolidsUploaded bykuthappady
- Determination of Optimum Coagulant DosageUploaded bykuthappady
- Determination of Available Chlorine in Bleaching PowderUploaded bykuthappady
- SulphateUploaded bykuthappady
- Chloride sUploaded bykuthappady
- BOD_Procedure (1).docxUploaded bySarah Idris
- Bod Procedure 2Uploaded bykuthappady
- Coagulation and FlocculationUploaded bykuthappady
- dilUploaded byVanesa Uy
- Troubleshooting GuideUploaded bySaber Ebeid
- HardnessUploaded bykuthappady
- pHUploaded bykuthappady
- Activated Sludge, Part 3Uploaded bykuthappady
- Activated Sludge - Troubleshooting GuideUploaded bykuthappady
- Iron and FluorideUploaded bykuthappady
- Bod Procedure 1Uploaded bykuthappady
- Activated Sludge, Part 2Uploaded bykuthappady
- Activated Sludge, Part 1Uploaded bykuthappady
- TURBIDITYUploaded bykuthappady
- Determination of Dissolved Oxygen in WaterUploaded bykuthappady

- Realistically Light and Render Interior Scenes Using 3ds Max and VrayUploaded byDafini Karagyozova
- Body of ThesisUploaded byyasas
- Accuracy StatementUploaded bymushroom0320
- X线指导整脊的可靠性分析综述9608381Uploaded byMac Peng
- Pressure Rating A269 (Tubing)Uploaded byMichel Lupien
- Dr Risza PaperUploaded byUsama Niazi
- RHA effectiveness in cement and concrete as a fuction of reactive silica and fineness.pdfUploaded byTran Huynh Nam
- MatlabUploaded byengr.abdulkareem9262
- Tubular and Immersion HeatersUploaded byElias
- Biology Chapter Five NotesUploaded byHew Jun Heng
- SeparationsUploaded byHidayat Kesuma
- Structures to Resist the Effects of Blast Loading ufc_3_340_02_pdfUploaded byChris Evans
- Ecmorxi RoUploaded byAna Carolina Loyola
- GrammarUploaded byMohamed H. Shedid
- NGC2 Analysis of Questions Sep2009 - (Sample)Uploaded byasimnaqvi2008
- FX05 SeriesUploaded byjohnvyn
- InstrumentSeparationAnalysisofMulti-usedProTaperUniversalRotarySystemduringRootCanalTherapy.pdfUploaded byGeorgiana Valeanu
- An Experimental Investigation on Concrete by Using Glass as a Fine Aggregate ReplacementUploaded byUDAYA M.E.T COLLEGE
- Panasonic PVL354DUploaded bygheoda8926
- 07 - Steam Generator FamiliarizationUploaded byJoren Huerno
- Ece 2007 2011 Batch SyllabusUploaded byBuji Subha
- Manual de Operaciones FMR20Uploaded byericleiva66
- CNC for HobbyistsUploaded bychnardelli
- Frozen Yogurt Machine.pdfUploaded bySilvia Perero Campusano
- Enabling_Vehicular_Visible_Light_Communication-libre.pdfUploaded byAna Smaal
- ForceUploaded byNestor Balboa
- DSM to DTMUploaded bymark canola
- No BS Guide to Vision Improvement - Sept 2016Uploaded byShaiabb
- Hoek-Brown Failure Criterion Sharan & Naznin.pdfUploaded byDaniel Zabala
- Discussion_ Design Concepts for Jib CranesUploaded byheitor29