TRUONG DHSP HA NOI TRUONG THPT CHUYEN Mii di: 241

nE THI

THU D';'I HQC LAN THU IV NA.M 2012 M6~H6AaQC Thili gian lam bai: 90 phiit_._. _ _ _ ~ hoahocphothong.vn

I. PHA.N CHUNG CHO TAT cA THi SINH: (40 diu, tic ciiu 1din ciiu 40) ~ fiJlupn JfF, ~ Cau 1: Cho m gam h6n hop X g6m hai nrou no, dan chirc kS tiSp nhau trong day dong dang tac dung voi CuO (dir) nung nong, thu diroc h6n hop r~n Z va h6nhQ'P hoi Y. Ti kh6i cua h6n hop Y so voi hidro la 27,5. Cho Y phan irng voi mQt hrong du AgN03 trong dung dich NH3 dun n6ng, sinh ra 12,96 gam Ag. Gia tri cua m la A.l,56. D.3,30. B. 3,42. C. 1,48. Cau 2: Cho cac nguyen til: Li (Z = 3), Cl (Z = 17), Na (Z = 23) va F (Z tang d~n thea thir tu A. ir', Na+, F, cr B. F, u', Na+, cr C. F, u', Cr,Na+
=

9). Ban kinh cac ion dtroc s~p xep D.

u', F-, Na+, cr

Cau 3: Cho ch~t htru co X co cong thirc phan til C3Hl203N2 tac dung voi dung dich NaOH (du) sau d6 co can thu duoc chat htru co dan chirc Y va phan r~ chi chua cac chat.vo ca. NSu eho X tac dung voi dung dich HCl (du) sau do cling co can thi thu duoc ph~n r~n va giai ph6ng khi Z. Kh6i IUQ'l1g han nr (theo dvC) p cua Yva Z la A. 45 va 44 B. 31 va 44 C. 31 va 46 D. 45 va 46 Cau 4: MQt binh phan irng co dung tich khong d6i chua h6n hQ'Pkhi S02 va 02 voi nong dQ tuong img la 0,7M va 0,3M. Sau khi dun nong binh mQt thai gian, phan img dat trang thai can bang, khi S03 chiem 50% th~ tich h6n hQ'Pthu diroc: Hang s6 can bing Kc a nhiet dQ tren cua phan img co gia tri la A.21,1l B.17,78 C.13,33 D.4,44 Cau 5: Trong mot binh kin dung tich khong d6i chua h6n hop A gem etan va mQt ankin X (di~u kien thuong a th~ khi) co ti l~ s6 mol la 1:1. Them oxi VaGbinh thi duoc h6n hQ'Pkhi B co ti kh5i so voi hidro la 18. £)6t chay hoan toan h6n hop B sau do dira binh v~ OoC thay h6n hQ'Pkhi trong binh eo ti khoi so voi hidro la 21,4665. X la A. C2H2 B. C3H4 C. C4H6 D. CsHs Can 6: H6n hop khi A g6m amin dan chirc X va hai hidrocacbon d6ng dang lien tiSp. £)6t chay hoan toan 100ml han hQ'P A bang mot IUQ11g xi vira du, thu duoc 550ml han hQP.B g6m khi va hoi mroc: NSu o cho B di qua dung dich axit sunfuric dac (du) thi can lai 200thl khi (cac the tich khi va hoi do cling di~u kien). Nhan xet nao sau day dung? A. Amin no va hai hidrocacbon la ankan. B. Amin no va hai hidrocacbon la anken. C. Amin khong no chua mot n6i dOi va hai hidrocacbon la ankan. D. Amin khong no chira mot n6i doi va hai hidrocacbon la anken.

a

Can 7: Nung 5,575 gam h6n hQ'PX g6m cac kim loai Fe, AI, Zn, Mg trong oxi, sau mQt thai gian thu duoc 6,775 gam h6n hQ'P y. Hoa tan hoan toan Y VaGdung dich HN03 (dir), thu duoc 1,68 lit khi NO (san pham klnr duy nh~t, a dktc). S6 mol HN03 da phan irng la A.O,30. B. 0,35. C. 0,40. D. 0,45. Cau 8: Cho ba ch~t htru co mach ho: C2H2 (X), C3H4 (Y), C4H6 (Z). Nhan xet nao sau day dung? A. X, Y, Z la d6ng dkg kS tiep, B. Ba chat tren khong th~ la d6ng dkg cua nhau. C. X va Y la d6ng dkg kS tiSp can Z co th~ cling day d6ng dkg voi X va Y. D. Ba ch~t tren co th~ cling day d6ng dkg hoac khong phai la d6ng d~ng CU~ nhattCau 9: Cho cac dung dich co cling nong dQ mol/I: Na2C03 (1), H2S04 cac dung dich duoc s~p xSp thea chiSu tang tir trai sang phai la A. (2), (3), (4), (1) B. (1), (2), (3), (4) C. (4), (1), (2), (3)

(If He!

(3), KN03 (4). Gia tri pH cua

D. (3),(2), (4), (1)

Cau 10: £)6t chay hoan toan 5,8 gam mot ch~t htru co X thu diroc 2,65 gam Na2C03 ; 12,1 gam CO2 va 2,25 gam H20. Xac dinh cong tlnrc phan til cua XbiSt m6i phan til X chua mot nguyen nr oxi. A. C2HSONa B. CH3COONa C. C6HsONa D. C7H70Na Cau 11: Hai nguyen t6 X va Y thuoc hai 0 lien tiSp nhau trong bang tu~n hoan, T6ng s6 hat mang di~n trong ca hai nguyen til X va Y la 66. Trong cac cau sau day: (1) Hai nguyen t6 X va Y d~u la phi kim va d~u nam

a cac nhom

A trong bang tuan hoan. Trang 1/5- Mii (ti thi 241

(2) Chung d~u tao diroc oxit cao 11h.1t hop chat khi voi hidro. va (3) Tinh phi kim, dQ am dien va nang hrong ion hoa (II) cua Y d~u I6n han X. (4) Oxit cao nh~t va hidroxit cua Y co tinh axit manh han so voi X. S6 phat bieu dung la A.4 B. 1 C. 2 D. 3

. Cau 12: Ch~t 3-MCPD'(3-monoc1opropandiol) thuong lfu1trong mroc tuong va co the gay ra benh ung thu. Chat nay co cong thirc du tao la A. CH(OH)2-CH2-CH2CI B. CH20H-CHCI-CH20H C. CH3-CHCI-CH(OH)2 D. CH2CI-CHOH-CH20H Cau 13: Nung 3,08 gam b9t s~t trong khong khi thu $1ugc 3,72 gam h6n hop A g6m Fe203, Fe304, FeO va ]:;,,, U)_...... ( hO hrvn dich .L.1..Lu 4.Lvu.u ,uu. \.. J giai pU.V.1J. ' Y J.H. l\.i.u (dktc) Gia tr; ,""U , la L.L<::!O· loang dirthav .... hong Ht I,hf Ul\.\..\,IJ. '-'1. ... v \ dir) Hca tan J.L ?::'" .u.Yl' A

a',... Uu.u. v dung U! '-.if ","au ... A. 0,336 B. 0,504 . C. 0,224 D. Dap an khac
J.
.l.l .1.1 1. 1. J.

Cau 14: Thuy phan m gam pentapeptit A co cong thirc Gly-Gly-Gly-Gly-Gly thu duoc h6n hop B g6m 0,3 gam Gly ; 0,792 gam Gly-Gly ; 1,701 gam Gly-Gly-Gly ; 0,738 gam Gly-Gly-Gly-Glyva 0,303 gam GlyGly-Gly-Gly-Gly. Gia tri cua m la A. 4,545 gam B.3,636 C. 3,834 D.3,672 Cau 15: Anken di~u kien thuong a th~ khi, khi cong HBr chi thu diroc mot san pharn duy nh~t co: A.lch~ B.2ch~ C.4ch~ D.3ch~

Can 16: Til eh~t X bing mot phan irng di~u che duoc C2HsOH va til C2HsOH bing mot phan (rug dieu che duoc X. Trong cac chat: C21-h, C2H4, C2HsCOOCH3, CH3CHO, CH3COOH, CH3COOC2Hs, C2HsONa, C2HsCl s6 ch~t phu hop voi X la A. 4 B. 3 C. 6 D. 5 Can 17: Trong cac 10l;1i quang sat, quang co ham hrong s~t cao nh~t la A. hematit nau B. manhetit· C. xiderit D. hematitdo

Can 18: Dien phan nong chay muoi A tao boi kim loai M va halogien X thu diroc 0,96 gam kim 10l;1i catot a va 0,896 lit khi (dktc) anot, N~u cho mu6i A tren tac dung voi dung dich AgN03 du thi thu duoc, 15,04 gam k~t tua trang. Cong thirc muoi A la A. NaBr B. NaCI C. MgCh D. MgBr2

a

a

Cfiu 19: £)6t chay hoan toan mot axit no, mach thing thu dircc 4,032 lit CO2 (dktc) va 2,7 gam mroc: Cong thirc du tao cua axit la A. HOOC(CH2)4COOH B.CH3COOU· .. · C.HCOOH. D. nooc-coon" Can 20: Este X khong no, mach ho co ti kh6i hoi so voi oxi bing 3,125vakhi tham gia phan ling xa phong hoa tao ra mot chat hiru ca Y va mot muoi ella axit hiru ca. Ch~t Y khong tac dung voi natri va khong co kha nang lam m~t mall dung dich bromo C6 bao nhieu d:6ng phan du tao phu hQ1J voi X ? A. 5 B. 3 C. 2 D. 4 Can 21: T6ng s6 miligam KOH dS trung hoi h~t Iuong axit tv do vi xa phong hoa h~t luong este trong 1 gam ch~t bee goi la chi s6 xi phong hoa cua eh~t beo, Tinh chi 86 xa phong hoa cua m&u eh~t beo co chi s6 axit bing 7 chua tristearoylglixerol e6 l~n mot luong axit stearic A. 171 B. 189 C.164 D.I92 Cau 22: Oxi hoa khong hoan toan aneol sec butylic bing CuO nung nong, thu duoc eh~t htru co X. Ten goi cua X la A. etyl, metyl xeton. B.2-meylpropanal. C. dimetyl xeton. D. metyl propanon. Cau 23: Trang cac po lime sau: (1) poli(metyl metacrylat) ; (2) polistiren ; (3) nilon-7 ; (4) poli(etylenterephtalat) ; (5) nilon-6,6 ; (6) poli(vinyl axetat) s6 polime la san pham cua phan ling trung ngung la A. 4 B. 2 C. 5 D. 3 Can 24: Cho 14,4 gam mot axit caeboxylie dan chirc X tac dung hoan toan voi 500 ml dung dich g6m KOH 0,32M va-NaOHO,48M-.co.,.~dung,dJch tliu ducc 28,64 gam h6n hopchat dn khan. Cong thirc phan til cua X la A. C2H3COOH B. HCOOH C. CH3COOH D. C3HsCOOH _

Trang 2/5 - Ma di thi 241

· Oill 25: H6n hop A g6m S02 va O2 co ti kh6i so voi H2 bang 24. Dun nong h6n hop A voi xuc tac V 20S sau met thai gian duoc h6n hop khi B, ti kh6i cua B so voi H2 bang 30. Hieu su~t phan irng oxi hoa S02 thanh S031a A. 40%. B. 80%. C. 60%. D. 20%. Call 26: Khi oxi hoa nrou etilic bang dung djch KMn04 thu ducc mot k€t tua mau nau den, phan img nhu sau: KMn04 + C2HSOH -? CH3COOK + .,. Sau khi can bang phirong trinh tong cac M s6 (nguyen, t6i gian) la A.18 B.19 C.22 D.20 Call 27: Trong cac cong tlnrc phan ill sau: C2~02, C3H402, C3Hg02, C3H603, C4Hg02, C2H602. S6 chat c6 d6ng phan este la . A. 3 B, 5 C. 4 D. 6 Call 28: Cho 9,12 gam h6n hop g6m FeO, Fe203 va Fe304 tac dung voi dung dich HCl (du). Sau khi cac phan img xay ra hoan toan ducc dung dich Y. Co can Y thu duoc 7,62 gam FeCh va m gam FeCb. Gia tri cua rn la A.6,50 B.7,80 C. 9,75 D.8,75 Call 29: Nhan xet nao sau day khtmg dung? A. Dung dich metylamin him cho quy chuyen sang mau xanh. B. Metylamin la ch~t khi, mui khai, d€ tan trong mroc C. Nhung hai dfia thuy tinh vao cac dung dich d~m d~c chua metylamin va HCl sau do cho hai diia g§n nhau thi th~y co hien tuong kh6i trang, D. Voi cac amin mach ho, tinh bazo cua amin bac cao manh hon b?c thap. Call 30: Dien phan dung dich chua a mol. CUS04 va b mol NaCI (voi dien eire tro, co mang ngan x6p) cho toi khi mroc bit d~u bi dien phan 6 hai di~n eire thi dung. Them vai giot dung dich phenolphtalein vao dung dich thu duoc sau di~n phan th~y phenolphtalein khong mau, f)i~u kien cua a va b la (biet ion sol khong bi dien pharr trong dung dich) .. A. b ::;2a B. b < 2a C. b = 2a D. b > 2a Cau 31: Trang cac diu sau day: (1) Nguyen til co 7 electron nam trong cac phan lap s la kali. (2) Nguyen til co 10 electron nam trong cac phan lap p hi hru huynh, (3) Nguyen til co 5 electron n~m trong cac phan lop d la mangan. (4) Nguyen til co 14 electron nam trong cac phan lap s va d la sit. (5) Nguyen ill co 14 electron nam trong cac phan lap s va p la silic S6 cau dung la A.5 B.3 C.2 D.4 Call 32: Cho sa db phan trng sau: A ~ B (nrou b?c 1) ~ C ~ D (ruou b?c 2) ~ E ~ F (nrou b~c 3). Bi€t A c6 cong thirc phan tu CSHll Cl. Ten goi cua Ala A. l-clo-2-metylbutan. B. l-clo-3-metylbutan. C.2-clo-3-metylbutan. D.l-clopentan.

Call 33: Day g6m cac ch~t d€u tac dung duoc voi dung dich HClloang la A. Mg(HC03)2, HCOONa, CuO, Pb(N03)2 B. AgN03, (N~)2C03, CuS, CaC03 C"FeS, BaS04, KOH, MgC03 D. KN03, CaC03, Fe(OH)3, AgN03 Call 34: Khi cho caosubuna-S phan irng hoan toan voi dung dich brom du nguoi ta nhan th~y cu 10,48 gam caosub\lha-S,~thi,~ irng h~t 6,4 gam bromo Ti l~ s6 mit xich butadien voi stren la A.l:1" "B.l:2 C.2:1 _' D.l:3 Call 35: Nung nong tirng cap ch~t sau trong binh kin: (1) Fe + S (r) ; (2) Fe203 + CO (k) ; (3) Au + 02 (k) ; (4) Cu + Cu(N03)2 (r) ; (5) Cu + KNOir) ; (6) Al + NaCl(r) ; (7) Ag + Cl, ; (8) Mg + AgBr. S6 tnrong hop xay ra phan irng oxi hoa kim loai la A. 4 B. 3 C. 6 D. 5 Call 36: Cho can bang sau: CaC03 + CO2 + H20 ( ) Ca(HC03)2 (l)

Tac dong nao sau day khtmg lam chuyen dich can bang (1) ? A. Them dung dich NaOH vao. B. Tang nhiet dQ. C. Them CaC03 vao, D. Tang ap suat.
Trang 3/5 - Mil

iii thi

241

Call 37: Hoa tan hoan toan mot Im;mg bQt kern VaG mot dung dich axit X, sau phan ling thu diroc dung dich Y va khi Z. Nh6 nr tir dung dich NaOH (dir) VaG Y, dun n6ng thu duoc khi khong mau T. Axit X la A. HN03 B. H3P04 C. H2S04loang D. H2S04 di_ie Call 38: Thanh phan hoa hoc chinh cua supephotphat kep la A. Ca3(P04)2. B. CaHP04. C. Ca(H2P04)2. D. Ca(H2P04)2 va CaS04 . Call 39: Chi a 24,48 gam h6n hop A g6m glucozo va mantozo thanh hai phan bang nhau: - Phan 1 tac dung voi dung dich AgN03 trong NH3 dir thu diroc 10,8 gam Ag. - Ph~n 2 dun voi dung dich axit vo cadS cho phan irng thuy phan xay ra voi hieu su~t 75% sau do ciing cho phan img voi dung dich AgN03 trong NH3 du thi )hu duoc m gam Ag. Gia tri ella m la A. 12,96 B. 14,04 C.6,48 D.7,56 Call 40: Hoa tan hoan toan 24,9 gam h6n hop X g6m Zn va Sn bang dung dich HCI (dir) thu duoc 6,72 lit khi H2 (6 dktc). ThS tich khi O2 (6 dktc) dn d~ phan ung hoan loan voi h6n hop X tren lei A. 2,80 lit B. 3,36 lit C. 4,48 lit D. 3,92 lit

H. PHAN RIENG [10 caul A. Theo chuong trinh CllUAn (10 diu, tit: diu 41 (tin diu 50)
Call 41: X la h6n hQ]J 2 andehit dan chirc, mach ho. Cho 0,04 mol X (co khoi hrong 1,98 gam) tham gia phan irng h€t voi dung dich AgNOiNH3 dir thu diroc 10,8 gam Ag. Mat khac m gam X k€t hop vira du voi 0,35 gam H2. Gia tri ella m lit A. 9,90 gam. B. 6,93 gam. C. 5,94 gam. D. 4,95 gam. Call 42: Triglixerit lit trieste cua glixerol. Khi dun n6ng glixerol voi h6n hop ba axit bee: axit panmitie, axit stearic va axit oleie thi thu diroc bao nhieu triglixerit rna trong m6i triglixerit d~u co chua hai g6c axit khac nhau? A .:24. B. 12. C. 15. D.27 Call 43: Hoa tan 26,64 gam ch~t tinh thS muoi sunfat ella kim loai M VaG mroc diroc dung dich X. Cho X tac dung voi dung dich NH3 vira du thu duoc k€t tua Y, nung Y nhiet dQ cao d€n khoi hrong khong d6i duoc 4,08 gam oxit. Mi_itkhac, eho X tac dung voi dung dich BaCh du duoc 27,96 gam k~t tua. Cong tlnrc ~~~~~ -

a

A. Fe2(S04)3.12H20.

B. Ah(S04)3.24H20.

C. CuS04.5H20.

D. Ah(S04h24H20 HN02. Dung dich

Call 44: Cho cac dung dich: HCl, FeCh, H2S04, NaHS04, CH3COOH, Na2C03, dimetylamin e6 th~ tac dung duoc voi bao nhieu eh~t trong cac chat dff cho ? A.6. B.S. C.4. D.3. Call 45: Tinh ch~t nao duoi day khimg phai la tinh ch~t cua NaHC03 A. Tac dung voi dung dich Ca(OH)2 cho k~t tua trang. B. La chit luang tinh. C. Thuy phan eho moi truong axit y€u. D. Bi phan huy boi nhiet. ?

Call 46: Tron 0,54 gam b9t Al voi Fe203 va CuO r6i tien hanh pharr irng nhiet nhorn 6 di~u kien khong co khong khi, thu duoc h6n hop ch~t r~n X, Hoa tan X trong dung dich HN03 thu duoc 0,89611t (dktc) h6n hQ'P khi Y g6m N02 va NO. Ti kh6i cua h6n hop Y so voi H2 la A.19. B.21 C.17. D.20. Call 47: Pharr irng nao sau day khong dung? A. Fe304 + 8HI ~ Fel, + 2Feh + 4H20

B. Fedu+ 4HN03
C. 3FeC03+10 D. 2FeS

d~c~

Fe(N03)z ~Fe2(S04)3

+ 2N02+ 2 H20 + 9S02 + 10H20

HN03101ing~

3Fe(N03)3 + NO + 3C02+5H20

+

10H2S04

Call 48: Cho m gam ancol dan chirc X tac dung voi Na dir thu duge3,36 lit H2.Oxi hoa m gam aneo1 nay mot thai gian, san pham thu duoc (g6m andehit, axit, aneol du va H20) lai cho tac dung voi Na du th§.y thoat ra 4,48 lit H2. Cac th€ tich khi d~u do 6 dktc: Hieu su~t chuyen hoa ancol thanh axit la A.25,00%. B. 66,67%. C.75,00%. D.33,33%

Trang 4/5 - ]}!ii ([~ thi 241

Call 50: Hop chftt hiru co A co cong tlnrc phan tir C9H100~. Xa phan~ hoa hO,antoan 7,5 mol f\ dn vira du la 100ml, d~ng dich N~OH 1M thu duoc h5n hop hai muoi, hai muoi nay de c6 phan til khoi Ion han 80 (dvC). So dong phan cau tao cua A la A. phuong in khac B. 5 C. 4 D. 6 B. Theo chuong trinh Nang cao (l0 ciiu, tit diu 51 dilt ciiu 60) Call 51: Dung dich A chua d6ng thai cac chftt tan: NaCIO,12M ; CUS04 0,04M ; KCI 0,08M va Cu(N03h 0,06M. Dien phan 200ml dung dich A cho toi khi mroc bi di~n phan 6 ca hai di~n eire thi dung. Nhan xet nao sau day dung ? A. Dungdich sau di~n phan c6 moi tnrong trung tinh, pH = 7. B. Dung dich sau di~n phan co moi truong axit, pH < 7. C. Dung dich sau dien phan co moi tnrong bazo, pH > 7. D. Dung dich sau di~n phan co moi tnrong axit hoac bazo. Call 52: Dung dich A chua d6ng thai cac chat tan: NaOH 0,2M va Ba(OH)2 O,lM. Khi dfrn 0,336 lit khi CO2 hay 1,456 lit khi CO2 vao Vml dung dich A thi d~u thu duoc k€t tua co s6 gam bang nhau (cac th~ tich khi d€u do 6 dktc), Th~ tich V dli dung la A. 200 ml. B.300m!. C. 240 ml. D. 150 m1

Call 49: Dun nong m gam bQt s~t ngoai khong khi, sau mQt thai gian thuduoc 8,8 gam h?n hop X gom Fe, FeO, Fe304, Fe203. Cho X tac dung hoan toan voi dung dich H2S04 d~c, dir.dun nong thay giai phong 1,68 lit khi S02 duy nhat (dktc). Gia tri cua m la A.5,6 B.6,72. C.5,88. D.4,9.

Call 53: Cho cac khi khong mau sau: CH4 ; S02 ; C02; C2H4 ; C2H2 ; H2S. se chftt khi colma nang lam mftt rnau dung dich Br2 la A. 2. B. 5 C. 4. D. 3. Call 54: H6n hop X g6m 2 hidrocacbon mach ho co ti khoi so voi H2 la 11. D§n 1,792 lit h6n hop X (dktc) di th~t cham qua binh dung dung dich brom du, sau phan irng thfty khoi hrong binh tang 0,8 gam. X phai chua hidrocacbon nao dum day? A. metan va prop en B. etan va propadien, C. metan va propin. D. Axetilen va propan. Call 55: Cho m gam Na tan hch vao 100mI dung dich H2S04 1M thu diroc 4,48 lit khi H2 6 dktc: Co can dung dich sau phan irng kh6i hrong chftt r~n thu diroc la . A. 28,4 gam. B. 22,2 gam. C. 18,2 gam. D. 14,2 gam. 2+,Mg2+, Na+, HC0 - va cr. C6 th~ dung hoa chftt nao duoi day chi Call 56: MQt c6c mroc chua cac ion: Ca 3 d~ him mftt dQcirng tarn thai ? A. NaHC03 B. H2S04 C. Ca(OHh D. Na2C03 Call 57: Oxi hoa mot ankol dan chirc bang CuO dun nong thu QUQ'c h6n hop X g6m andehit, mroc va ankol dir, Chia X thanh hai phan bang nhau: - Phan 1cho tac dung voi dung dich AgN03INH3 du thu diroc 6,48 gam Ag. - PhAn 2 cho tac dung voi Na dir th~y giai phong 448 crrr' H2 (6 dktc). Hieu su~t phan irng oxi hoa ankol la A.66,67% B.80% C. 37,5% D.75%

Call 58: X la hop ch~t hiru co chua cac nguyen t6 C, H, N trong do nita chi€m 13,08% vS kh6i luong, Khi cho X vao dung dich HCI dir th~y X tac dung voi Hel theo ti I~ moll: 1. se d6ng phan c~u tao c6 chua vong benzen cua X la A.3. B. 2. C.5. D.4. Call ·59: Dung dich X chua Na2S04 0,05M; NaCI 0,05M ; K2S04 0,2M va KCI O,IM. 8~ pha ch€ dung dich X phai hoa tan it nhftt bao nhieu muoi vao mrcc ? A. 5 B. 4. C. 3. D. 2. .. Call 60: H5n hop X gom etan, etilen, axetilen va butadien-l ,3,. 86t chay h€t mgam h6n h9'P X r6i cho san pham chay hftp thu vao dung dich nuoc voi dir, thu duoc 20 gam k€t tua kh6i hrong dung dich mroc voi .sau phan img giam 7,96 gam. Tri s6 cua m la A. 11,75 gam. B. 12,04 gam. C. 2,76 gam. D. 6,88 gam.

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DAP AN DE THI THI1 041 HOC LAN IV NAM 2012
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2A

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J.
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Cau 14: Thuy phan m gam pentapeptit A co cong thirc Gly-Gly-Gly-Gly-Gly thu duoc h6n hop B g6m 0,3 gam Gly ; 0,792 gam Gly-Gly ; 1,701 gam Gly-Gly-Gly ; 0,738 gam Gly-Gly-Gly-Glyva 0,303 gam GlyGly-Gly-Gly-Gly. Gia tri cua m la A. 4,545 gam B.3,636 C. 3,834 D.3,672 Cau 15: Anken di~u kien thuong a th~ khi, khi cong HBr chi thu diroc mot san pharn duy nh~t co: A.lch~ B.2ch~ C.4ch~ D.3ch~

Can 16: Til eh~t X bing mot phan irng di~u che duoc C2HsOH va til C2HsOH bing mot phan (rug dieu che duoc X. Trong cac chat: C21-h, C2H4, C2HsCOOCH3, CH3CHO, CH3COOH, CH3COOC2Hs, C2HsONa, C2HsCl s6 ch~t phu hop voi X la A. 4 B. 3 C. 6 D. 5 Can 17: Trong cac 10l;1i quang sat, quang co ham hrong s~t cao nh~t la A. hematit nau B. manhetit· C. xiderit D. hematitdo

Can 18: Dien phan nong chay muoi A tao boi kim loai M va halogien X thu diroc 0,96 gam kim 10l;1i catot a va 0,896 lit khi (dktc) anot, N~u cho mu6i A tren tac dung voi dung dich AgN03 du thi thu duoc, 15,04 gam k~t tua trang. Cong thirc muoi A la A. NaBr B. NaCI C. MgCh D. MgBr2

a

a

Cfiu 19: £)6t chay hoan toan mot axit no, mach thing thu dircc 4,032 lit CO2 (dktc) va 2,7 gam mroc: Cong thirc du tao cua axit la A. HOOC(CH2)4COOH B.CH3COOU· .. · C.HCOOH. D. nooc-coon" Can 20: Este X khong no, mach ho co ti kh6i hoi so voi oxi bing 3,125vakhi tham gia phan ling xa phong hoa tao ra mot chat hiru ca Y va mot muoi ella axit hiru ca. Ch~t Y khong tac dung voi natri va khong co kha nang lam m~t mall dung dich bromo C6 bao nhieu d:6ng phan du tao phu hQ1J voi X ? A. 5 B. 3 C. 2 D. 4 Can 21: T6ng s6 miligam KOH dS trung hoi h~t Iuong axit tv do vi xa phong hoa h~t luong este trong 1 gam ch~t bee goi la chi s6 xi phong hoa cua eh~t beo, Tinh chi 86 xa phong hoa cua m&u eh~t beo co chi s6 axit bing 7 chua tristearoylglixerol e6 l~n mot luong axit stearic A. 171 B. 189 C.164 D.I92 Cau 22: Oxi hoa khong hoan toan aneol sec butylic bing CuO nung nong, thu duoc eh~t htru co X. Ten goi cua X la A. etyl, metyl xeton. B.2-meylpropanal. C. dimetyl xeton. D. metyl propanon. Cau 23: Trang cac po lime sau: (1) poli(metyl metacrylat) ; (2) polistiren ; (3) nilon-7 ; (4) poli(etylenterephtalat) ; (5) nilon-6,6 ; (6) poli(vinyl axetat) s6 polime la san pham cua phan ling trung ngung la A. 4 B. 2 C. 5 D. 3 Can 24: Cho 14,4 gam mot axit caeboxylie dan chirc X tac dung hoan toan voi 500 ml dung dich g6m KOH 0,32M va-NaOHO,48M-.co.,.~dung,dJch tliu ducc 28,64 gam h6n hopchat dn khan. Cong thirc phan til cua X la A. C2H3COOH B. HCOOH C. CH3COOH D. C3HsCOOH _

Trang 2/5 - Ma di thi 241

· Oill 25: H6n hop A g6m S02 va O2 co ti kh6i so voi H2 bang 24. Dun nong h6n hop A voi xuc tac V 20S sau met thai gian duoc h6n hop khi B, ti kh6i cua B so voi H2 bang 30. Hieu su~t phan irng oxi hoa S02 thanh S031a A. 40%. B. 80%. C. 60%. D. 20%. Call 26: Khi oxi hoa nrou etilic bang dung djch KMn04 thu ducc mot k€t tua mau nau den, phan img nhu sau: KMn04 + C2HSOH -? CH3COOK + .,. Sau khi can bang phirong trinh tong cac M s6 (nguyen, t6i gian) la A.18 B.19 C.22 D.20 Call 27: Trong cac cong tlnrc phan ill sau: C2~02, C3H402, C3Hg02, C3H603, C4Hg02, C2H602. S6 chat c6 d6ng phan este la . A. 3 B, 5 C. 4 D. 6 Call 28: Cho 9,12 gam h6n hop g6m FeO, Fe203 va Fe304 tac dung voi dung dich HCl (du). Sau khi cac phan img xay ra hoan toan ducc dung dich Y. Co can Y thu duoc 7,62 gam FeCh va m gam FeCb. Gia tri cua rn la A.6,50 B.7,80 C. 9,75 D.8,75 Call 29: Nhan xet nao sau day khtmg dung? A. Dung dich metylamin him cho quy chuyen sang mau xanh. B. Metylamin la ch~t khi, mui khai, d€ tan trong mroc C. Nhung hai dfia thuy tinh vao cac dung dich d~m d~c chua metylamin va HCl sau do cho hai diia g§n nhau thi th~y co hien tuong kh6i trang, D. Voi cac amin mach ho, tinh bazo cua amin bac cao manh hon b?c thap. Call 30: Dien phan dung dich chua a mol. CUS04 va b mol NaCI (voi dien eire tro, co mang ngan x6p) cho toi khi mroc bit d~u bi dien phan 6 hai di~n eire thi dung. Them vai giot dung dich phenolphtalein vao dung dich thu duoc sau di~n phan th~y phenolphtalein khong mau, f)i~u kien cua a va b la (biet ion sol khong bi dien pharr trong dung dich) .. A. b ::;2a B. b < 2a C. b = 2a D. b > 2a Cau 31: Trang cac diu sau day: (1) Nguyen til co 7 electron nam trong cac phan lap s la kali. (2) Nguyen til co 10 electron nam trong cac phan lap p hi hru huynh, (3) Nguyen til co 5 electron n~m trong cac phan lop d la mangan. (4) Nguyen til co 14 electron nam trong cac phan lap s va d la sit. (5) Nguyen ill co 14 electron nam trong cac phan lap s va p la silic S6 cau dung la A.5 B.3 C.2 D.4 Call 32: Cho sa db phan trng sau: A ~ B (nrou b?c 1) ~ C ~ D (ruou b?c 2) ~ E ~ F (nrou b~c 3). Bi€t A c6 cong thirc phan tu CSHll Cl. Ten goi cua Ala A. l-clo-2-metylbutan. B. l-clo-3-metylbutan. C.2-clo-3-metylbutan. D.l-clopentan.

Call 33: Day g6m cac ch~t d€u tac dung duoc voi dung dich HClloang la A. Mg(HC03)2, HCOONa, CuO, Pb(N03)2 B. AgN03, (N~)2C03, CuS, CaC03 C"FeS, BaS04, KOH, MgC03 D. KN03, CaC03, Fe(OH)3, AgN03 Call 34: Khi cho caosubuna-S phan irng hoan toan voi dung dich brom du nguoi ta nhan th~y cu 10,48 gam caosub\lha-S,~thi,~ irng h~t 6,4 gam bromo Ti l~ s6 mit xich butadien voi stren la A.l:1" "B.l:2 C.2:1 _' D.l:3 Call 35: Nung nong tirng cap ch~t sau trong binh kin: (1) Fe + S (r) ; (2) Fe203 + CO (k) ; (3) Au + 02 (k) ; (4) Cu + Cu(N03)2 (r) ; (5) Cu + KNOir) ; (6) Al + NaCl(r) ; (7) Ag + Cl, ; (8) Mg + AgBr. S6 tnrong hop xay ra phan irng oxi hoa kim loai la A. 4 B. 3 C. 6 D. 5 Call 36: Cho can bang sau: CaC03 + CO2 + H20 ( ) Ca(HC03)2 (l)

Tac dong nao sau day khtmg lam chuyen dich can bang (1) ? A. Them dung dich NaOH vao. B. Tang nhiet dQ. C. Them CaC03 vao, D. Tang ap suat.
Trang 3/5 - Mil

iii thi

241

Call 37: Hoa tan hoan toan mot Im;mg bQt kern VaG mot dung dich axit X, sau phan ling thu diroc dung dich Y va khi Z. Nh6 nr tir dung dich NaOH (dir) VaG Y, dun n6ng thu duoc khi khong mau T. Axit X la A. HN03 B. H3P04 C. H2S04loang D. H2S04 di_ie Call 38: Thanh phan hoa hoc chinh cua supephotphat kep la A. Ca3(P04)2. B. CaHP04. C. Ca(H2P04)2. D. Ca(H2P04)2 va CaS04 . Call 39: Chi a 24,48 gam h6n hop A g6m glucozo va mantozo thanh hai phan bang nhau: - Phan 1 tac dung voi dung dich AgN03 trong NH3 dir thu diroc 10,8 gam Ag. - Ph~n 2 dun voi dung dich axit vo cadS cho phan irng thuy phan xay ra voi hieu su~t 75% sau do ciing cho phan img voi dung dich AgN03 trong NH3 du thi )hu duoc m gam Ag. Gia tri ella m la A. 12,96 B. 14,04 C.6,48 D.7,56 Call 40: Hoa tan hoan toan 24,9 gam h6n hop X g6m Zn va Sn bang dung dich HCI (dir) thu duoc 6,72 lit khi H2 (6 dktc). ThS tich khi O2 (6 dktc) dn d~ phan ung hoan loan voi h6n hop X tren lei A. 2,80 lit B. 3,36 lit C. 4,48 lit D. 3,92 lit

H. PHAN RIENG [10 caul A. Theo chuong trinh CllUAn (10 diu, tit: diu 41 (tin diu 50)
Call 41: X la h6n hQ]J 2 andehit dan chirc, mach ho. Cho 0,04 mol X (co khoi hrong 1,98 gam) tham gia phan irng h€t voi dung dich AgNOiNH3 dir thu diroc 10,8 gam Ag. Mat khac m gam X k€t hop vira du voi 0,35 gam H2. Gia tri ella m lit A. 9,90 gam. B. 6,93 gam. C. 5,94 gam. D. 4,95 gam. Call 42: Triglixerit lit trieste cua glixerol. Khi dun n6ng glixerol voi h6n hop ba axit bee: axit panmitie, axit stearic va axit oleie thi thu diroc bao nhieu triglixerit rna trong m6i triglixerit d~u co chua hai g6c axit khac nhau? A .:24. B. 12. C. 15. D.27 Call 43: Hoa tan 26,64 gam ch~t tinh thS muoi sunfat ella kim loai M VaG mroc diroc dung dich X. Cho X tac dung voi dung dich NH3 vira du thu duoc k€t tua Y, nung Y nhiet dQ cao d€n khoi hrong khong d6i duoc 4,08 gam oxit. Mi_itkhac, eho X tac dung voi dung dich BaCh du duoc 27,96 gam k~t tua. Cong tlnrc ~~~~~ -

a

A. Fe2(S04)3.12H20.

B. Ah(S04)3.24H20.

C. CuS04.5H20.

D. Ah(S04h24H20 HN02. Dung dich

Call 44: Cho cac dung dich: HCl, FeCh, H2S04, NaHS04, CH3COOH, Na2C03, dimetylamin e6 th~ tac dung duoc voi bao nhieu eh~t trong cac chat dff cho ? A.6. B.S. C.4. D.3. Call 45: Tinh ch~t nao duoi day khimg phai la tinh ch~t cua NaHC03 A. Tac dung voi dung dich Ca(OH)2 cho k~t tua trang. B. La chit luang tinh. C. Thuy phan eho moi truong axit y€u. D. Bi phan huy boi nhiet. ?

Call 46: Tron 0,54 gam b9t Al voi Fe203 va CuO r6i tien hanh pharr irng nhiet nhorn 6 di~u kien khong co khong khi, thu duoc h6n hop ch~t r~n X, Hoa tan X trong dung dich HN03 thu duoc 0,89611t (dktc) h6n hQ'P khi Y g6m N02 va NO. Ti kh6i cua h6n hop Y so voi H2 la A.19. B.21 C.17. D.20. Call 47: Pharr irng nao sau day khong dung? A. Fe304 + 8HI ~ Fel, + 2Feh + 4H20

B. Fedu+ 4HN03
C. 3FeC03+10 D. 2FeS

d~c~

Fe(N03)z ~Fe2(S04)3

+ 2N02+ 2 H20 + 9S02 + 10H20

HN03101ing~

3Fe(N03)3 + NO + 3C02+5H20

+

10H2S04

Call 48: Cho m gam ancol dan chirc X tac dung voi Na dir thu duge3,36 lit H2.Oxi hoa m gam aneo1 nay mot thai gian, san pham thu duoc (g6m andehit, axit, aneol du va H20) lai cho tac dung voi Na du th§.y thoat ra 4,48 lit H2. Cac th€ tich khi d~u do 6 dktc: Hieu su~t chuyen hoa ancol thanh axit la A.25,00%. B. 66,67%. C.75,00%. D.33,33%

Trang 4/5 - ]}!ii ([~ thi 241

Call 50: Hop chftt hiru co A co cong tlnrc phan tir C9H100~. Xa phan~ hoa hO,antoan 7,5 mol f\ dn vira du la 100ml, d~ng dich N~OH 1M thu duoc h5n hop hai muoi, hai muoi nay de c6 phan til khoi Ion han 80 (dvC). So dong phan cau tao cua A la A. phuong in khac B. 5 C. 4 D. 6 B. Theo chuong trinh Nang cao (l0 ciiu, tit diu 51 dilt ciiu 60) Call 51: Dung dich A chua d6ng thai cac chftt tan: NaCIO,12M ; CUS04 0,04M ; KCI 0,08M va Cu(N03h 0,06M. Dien phan 200ml dung dich A cho toi khi mroc bi di~n phan 6 ca hai di~n eire thi dung. Nhan xet nao sau day dung ? A. Dungdich sau di~n phan c6 moi tnrong trung tinh, pH = 7. B. Dung dich sau di~n phan co moi truong axit, pH < 7. C. Dung dich sau dien phan co moi tnrong bazo, pH > 7. D. Dung dich sau di~n phan co moi tnrong axit hoac bazo. Call 52: Dung dich A chua d6ng thai cac chat tan: NaOH 0,2M va Ba(OH)2 O,lM. Khi dfrn 0,336 lit khi CO2 hay 1,456 lit khi CO2 vao Vml dung dich A thi d~u thu duoc k€t tua co s6 gam bang nhau (cac th~ tich khi d€u do 6 dktc), Th~ tich V dli dung la A. 200 ml. B.300m!. C. 240 ml. D. 150 m1

Call 49: Dun nong m gam bQt s~t ngoai khong khi, sau mQt thai gian thuduoc 8,8 gam h?n hop X gom Fe, FeO, Fe304, Fe203. Cho X tac dung hoan toan voi dung dich H2S04 d~c, dir.dun nong thay giai phong 1,68 lit khi S02 duy nhat (dktc). Gia tri cua m la A.5,6 B.6,72. C.5,88. D.4,9.

Call 53: Cho cac khi khong mau sau: CH4 ; S02 ; C02; C2H4 ; C2H2 ; H2S. se chftt khi colma nang lam mftt rnau dung dich Br2 la A. 2. B. 5 C. 4. D. 3. Call 54: H6n hop X g6m 2 hidrocacbon mach ho co ti khoi so voi H2 la 11. D§n 1,792 lit h6n hop X (dktc) di th~t cham qua binh dung dung dich brom du, sau phan irng thfty khoi hrong binh tang 0,8 gam. X phai chua hidrocacbon nao dum day? A. metan va prop en B. etan va propadien, C. metan va propin. D. Axetilen va propan. Call 55: Cho m gam Na tan hch vao 100mI dung dich H2S04 1M thu diroc 4,48 lit khi H2 6 dktc: Co can dung dich sau phan irng kh6i hrong chftt r~n thu diroc la . A. 28,4 gam. B. 22,2 gam. C. 18,2 gam. D. 14,2 gam. 2+,Mg2+, Na+, HC0 - va cr. C6 th~ dung hoa chftt nao duoi day chi Call 56: MQt c6c mroc chua cac ion: Ca 3 d~ him mftt dQcirng tarn thai ? A. NaHC03 B. H2S04 C. Ca(OHh D. Na2C03 Call 57: Oxi hoa mot ankol dan chirc bang CuO dun nong thu QUQ'c h6n hop X g6m andehit, mroc va ankol dir, Chia X thanh hai phan bang nhau: - Phan 1cho tac dung voi dung dich AgN03INH3 du thu diroc 6,48 gam Ag. - PhAn 2 cho tac dung voi Na dir th~y giai phong 448 crrr' H2 (6 dktc). Hieu su~t phan irng oxi hoa ankol la A.66,67% B.80% C. 37,5% D.75%

Call 58: X la hop ch~t hiru co chua cac nguyen t6 C, H, N trong do nita chi€m 13,08% vS kh6i luong, Khi cho X vao dung dich HCI dir th~y X tac dung voi Hel theo ti I~ moll: 1. se d6ng phan c~u tao c6 chua vong benzen cua X la A.3. B. 2. C.5. D.4. Call ·59: Dung dich X chua Na2S04 0,05M; NaCI 0,05M ; K2S04 0,2M va KCI O,IM. 8~ pha ch€ dung dich X phai hoa tan it nhftt bao nhieu muoi vao mrcc ? A. 5 B. 4. C. 3. D. 2. .. Call 60: H5n hop X gom etan, etilen, axetilen va butadien-l ,3,. 86t chay h€t mgam h6n h9'P X r6i cho san pham chay hftp thu vao dung dich nuoc voi dir, thu duoc 20 gam k€t tua kh6i hrong dung dich mroc voi .sau phan img giam 7,96 gam. Tri s6 cua m la A. 11,75 gam. B. 12,04 gam. C. 2,76 gam. D. 6,88 gam.

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