ACHIEVEMENT POST-TEST ITEM (APTI)

INSTRUCTION i) ii) Answer all the question s in section A and B in the space provided Write your name and class number in the space provided

Time: 1 hour

NameNumber

1. If a thermometer records a decrease in temperature in a given reaction mixture, it is an indication that the reaction is a) Slow b) Fast c) Endothermic d) Exothermic 2. CH4(g) + 2O2(g) CO2(g) + 2H2O(g) H=xkJ In the above equation, x represent a) Enthalpy of combustion b) enthalpy of solution c) Enthalpy of neutralization d) enthalpy of atomization 3. Bomb calorimeter is the standard instrument for determining the enthalpy of a) Solution b) neutralization c) combustion d) activation 4. When sodium hydroxide (NaOH) pellets dissolves in water, the container becomes warm. The process of dissolution is a) Exothermic b) isothermal c) endothermic d) salvation Use the energy profile diagram below to answer question 5 and 6

5. The activation energy is a) x b) y c) x-y d) x+y 6. the overall reaction is a) exothermic b) endothermic c) isothermal d) feasible

7. given that for the reaction N2 (g) + 3H2 (g) = 2NH3 (g) H= -92kJ -1 -1 a) -92kJmol b) -46kJmol c) +46kJmol-1 d) +92kJmol-1 8. How much heat will be liberated if 3.0g of carbon burns in excess oxygen according to the following equation C(s) + O2(g) CO2(g) H= -393kJmol-1 (C=12, O= 16) a) -98.3kJ b) -131kJ c) -196.5 kJ d) -157.2 kJ 9. When the value H is positive for a given reaction, it means the reaction is a) Exothermic b) endothermic c) spontaneous d) activated 10. Given that H for the reaction NaOH(aq) + HCl(aq) NaCl(aq) + H2O(l) is -57.3kJmol-1, what is the value of H for the reaction; 2NaOH(aq) + H2SO4(aq) Na2SO4(aq) + 2H2O(l) a) -114.6 kJ b) -104.6 kJ c) -124.6 kJ d) 106.6 kJ 11. The value of H for an equilibrium reaction is a) Zero b) positive c) neutral d) negative 12. In the determination of heat of neutralization, we normally add a) Acid to alkali b) Alkali to acid c) water to acid d) water to alkali 13.

The stirrer is to ensure a) Even distribution of heat b) acid and alkali are perfectly mixed c) prevention of heat loss d) increase in temperature 14. Which of the following is not true of an energy profile diagram a) It gives the value of H b) it gives the activation energy c) it gives the activation complex d) It gives the lattice energy 15. Which of the following is not true of exothermic reaction in terms of heat of product(H p) and heat of reaction(Hr) a) Hp>Hr b) Hp<Hr c) Hr < O d) Hp< O b)

SHORT ANSWER-TYPE QUESTIONS

1. List any two materials you would use to determine the heat of combustion in the laboratory 2. Draw an energy profile diagram for the following reactions a) N2(g) + 3H2(g) 2NH3(g) H = -ve b) N2O4(g) 2NO2(g) H = +ve a)

b)

3. On dissolving some crystals of Zinc tetraoxosulphate (vi) in water, a student observed an exceptional coldness on the surface of the containing vessel. a) What name is given to the reaction? b) Suggest what H will be and why? ...

4. How much heat will be liberated if 6.0g of hydrogen burns in excess oxygen according to the following equation? 2H2(g) + O2(g) 2H2O(g) H = -571.7kJmol-1

5. Define heat of formation 6. State Hesss law of constant summation 7. List two type of enthalpy of reaction known to you . 8. Name three compounds that can be used in the determination of heat of solution in the laboratory: