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UNIVERSITY OF CAMBRIDGE INTERNATIONAL EXAMINATIONS International General Certificate of Secondary Education CHEMISTRY Paper 1 Multiple Choice May/June

2006 45 minutes
Additional Materials: Multiple Choice Answer Sheet Soft clean eraser Soft pencil (type B or HB is recommended)

0620/01

w w w e tr .X m ap eP s er om .c

READ THESE INSTRUCTIONS FIRST Write in soft pencil. Do not use staples, paper clips, highlighters, glue or correction fluid. Write your name, Centre number and candidate number on the Answer Sheet in the spaces provided unless this has been done for you. There are forty questions on this paper. Answer all questions. For each question there are four possible answers A, B, C and D. Choose the one you consider correct and record your choice in soft pencil on the separate Answer Sheet. Read the instructions on the Answer Sheet very carefully. Each correct answer will score one mark. A mark will not be deducted for a wrong answer. Any rough working should be done in this booklet. A copy of the Periodic Table is printed on page 20. You may use a calculator.

This document consists of 18 printed pages and 2 blank pages.
IB06 06_0620_01/3RP  UCLES 2006

[Turn over

2 1 At room temperature, in which substance are the particles furthest apart? A 2 H2 B H2O C Mg D MgO

Which method can be used to obtain crystals from aqueous copper(II) sulphate? A B C D chromatography electrolysis evaporation neutralisation

3

Five elements have proton numbers 10, 12, 14, 16 and 18. What are the proton numbers of the three elements that form oxides? A B C D 10, 12 and 14 10, 14 and 18 12, 14 and 16 14, 16 and 18

4

The rows P, Q and R in the table show three pairs of structures.

e e 1n 2p

e e 2n 2p

key e electron

P

n neutron p proton nucleus

Q

atoms of the same element

H R H C H
Which pair or pairs are isotopes? A P only B P and Q only C

H H H C H

H C H H

Q only

D

Q and R only

© UCLES 2006

0620/01/M/J/06

HCl and H2O. It gains a proton. It loses a proton.3 5 Which numbers are added to give the nucleon number of an ion? A B C D 6 number of electrons + number of neutrons number of electrons + number of protons number of electrons + number of protons + number of neutrons number of protons + number of neutrons In the molecules CH4. It loses an electron. which atoms use all of their outer shell electrons in bonding? A B C D C and Cl C and H Cl and H H and O 7 Which change to an atom occurs when it forms a positive ion? A B C D It gains an electron. 8 For which compound is the formula correct? compound A B C D ammonia carbon dioxide potassium oxide zinc chloride formula NH4 CO P2O ZnCl2 © UCLES 2006 0620/01/M/J/06 [Turn over .

4 9 The diagrams show the molecules of three elements. + ve – ve concentrated hydrochloric acid Which line correctly describes the colours of the gases at the electrodes? anode (+ve) A B C D colourless colourless yellow-green yellow-green cathode (–ve) colourless yellow-green colourless yellow-green © UCLES 2006 0620/01/M/J/06 . 1 2 3 Which of these elements are present in water? A B C D 1 and 2 only 1 and 3 only 2 and 3 only 1. 2 and 3 10 The diagram shows that two gases are formed when concentrated hydrochloric acid is electrolysed between inert electrodes.

+ 1 2 Ni Ni – 3 4 Ni Ni aqueous copper(II) sulphate Which nickel electrodes are plated with a metal? A B C D 1 only 1 and 3 only 2 only 2 and 4 only aqueous sodium chloride 12 The diagram shows an experiment in which magnesium oxide powder is added to dilute hydrochloric acid.5 11 The diagram shows an electrolysis experiment to electroplate nickel with a different metal. magnesium oxide powder dilute hydrochloric acid 20 oC pH2 before Which terms describe the experiment? exothermic A B C D     neutralisation     after aqueous magnesium chloride 22 oC pH7 © UCLES 2006 0620/01/M/J/06 [Turn over .

6 13 Coal. methane and hydrogen are burned as fuels. Which descriptions of this process are correct? what happens to the fuel A B C D oxidised oxidised reduced reduced type of reaction endothermic exothermic endothermic exothermic 14 Two reactions involving water are shown. X Y FeSO4 + water → hydrated iron(II) sulphate Fe + O2 + water → rust Which of these reactions are reversible by heating? X A B C D     Y     © UCLES 2006 0620/01/M/J/06 .

Which line of the table is correct? increase concentration of acid A B C D decrease speed of reaction decrease speed of reaction increase speed of reaction increase speed of reaction increase temperature decrease speed of reaction increase speed of reaction decrease speed of reaction increase speed of reaction 16 Barium hydroxide is an alkali. hydrogen magnesium excess of dilute hydrochloric acid at 25 oC Increasing the concentration of the acid and increasing the temperature both affect the speed of reaction. The pH decreases from 14 to about 1. aqueous barium hydroxide pH meter hydrochloric acid What happens to the pH of a solution of hydrochloric acid as an excess of aqueous barium hydroxide is added? A B C D The pH decreases from 14 but becomes constant at 7.7 15 The diagram shows a speed of reaction experiment. The pH increases from 1 to about 14. It reacts with hydrochloric acid. The pH increases from 1 but becomes constant at 7. © UCLES 2006 0620/01/M/J/06 [Turn over .

8 17 Element X is at the left-hand side of the Periodic Table. Z W X Y Which elements form ionic bonds with oxygen? A B C D W only W and X only Y only Y and Z only © UCLES 2006 0620/01/M/J/06 . Which line in the table shows the correct type and property of the oxide of X? type of oxide A B C D metallic metallic non-metallic non-metallic property of oxide acidic basic acidic basic 18 The diagram shows the positions of some elements in the Periodic Table.

9 19 The diagrams show three experiments using dilute sulphuric acid. 2 and 3 2 3 20 The equation shows the reaction between a halogen and aqueous bromide ions. Three different powders are added to the acid. Cu powder Cu(OH)2 powder CuCO3 powder H2SO4(aq) H2SO4(aq) H2SO4(aq) 1 The mixtures are stirred. Which test-tubes then contain Cu2+(aq) ions? A B C D 1 and 2 only 1 and 3 only 2 and 3 only 1. X2 …1… + 2Br–(aq) …2… → 2X–(aq) + Br2 …3… Which words should be written in gaps 1. 2 and 3? 1 A B C D chlorine chlorine iodine iodine 2 brown colourless brown colourless 3 colourless brown colourless brown © UCLES 2006 0620/01/M/J/06 [Turn over .

Metallic and non-metallic elements are classified in the ……1……. P carbon dioxide Q helium R hydrogen Which of the balloons float up into the air when the children let go? A B C D P only P and R only Q only Q and R only © UCLES 2006 0620/01/M/J/06 . W X Y Z Which two elements could form a covalent compound? A W and X B W and Y C X and Y D X and Z 22 A student is asked to complete two sentences. Which words correctly complete the gaps? gap 1 A B C D Periodic Table Periodic Table reactivity series reactivity series gap 2 measure predict measure predict 23 The diagram shows three balloons held by children. This can be used to ……2…… the properties of elements.10 21 The diagram shows an outline of part of the Periodic Table.

Cu and Mg are reactive enough to reduce the iron oxide to iron? A B C D C and Cu only C and Mg only Cu and Mg only C. Which of the elements C. Which of these three metals are also used in the form of alloys? copper A B C D     iron     zinc     27 Which diagram shows a common use of stainless steel? A B C D © UCLES 2006 0620/01/M/J/06 [Turn over . Cu and Mg 25 Which property do all metals have? A B C D Their densities are low. 26 Copper. They act as catalysts. Their melting points are high.11 24 Three mixtures are made. They conduct electricity. 1 2 3 C + Fe2O3 Cu + Fe2O3 Mg + Fe2O3 The mixtures are heated strongly. iron and zinc are all used to make things.

One student set up his apparatus as shown. some students are each given two metal objects to study.12 28 The diagram shows stages in the purification of water. Which stage uses chlorine? water at pH9 + bacteria + large solids + fine solids A water at pH9 + bacteria + fine solids B water at pH9 + bacteria C pure water at pH7 D water at pH7 + bacteria 29 In experiments on rusting. nitrogen air chromeplated keyring brass screw water Which objects rusted? brass screw A B C D     chrome-plated keyring     30 Which substance is not a pollutant of clean air? A B C D argon carbon monoxide nitrogen dioxide sulphur dioxide © UCLES 2006 0620/01/M/J/06 .

2 and 3 1 and 2 only 1 and 3 only 2 and 3 only 33 The diagram shows an experiment. 1 2 3 during respiration when calcium carbonate reacts with hydrochloric acid when methane burns in air Which statements are correct? A B C D 1.13 31 Which metallic element is needed in a complete fertiliser? A B C D calcium magnesium potassium sodium 32 A newspaper article claims that carbon dioxide is formed as follows. damp litmus paper gas given off mixture of ammonium chloride and sodium hydroxide heat What is the name of the gas and the final colour of the litmus paper? gas A B C D ammonia ammonia chlorine chlorine colour blue red white red © UCLES 2006 0620/01/M/J/06 [Turn over .

5 The house owner wishes to use lime to neutralise the soil in one part of the garden. and why? part of garden A B C D X X Y Y because lime is acidic basic acidic basic 35 In the molecule shown. two parts of the garden of a house. H H 1 O C H H C H H C H C O 2 H O Which of these –OH groups react with aqueous sodium hydroxide? 1 2 A B C D         © UCLES 2006 0620/01/M/J/06 . the two –OH groups are numbered.0 Y pH 5.14 34 The diagram shows the pH values of the soil in X and Y. To which part should the lime be added. X pH 7.

What is the structure of the compound formed? A H H C H H C H O H H O H C H B H C H O H C H H C H C O H H O O C O D O C O H 37 The diagram shows the separation of crude oil into fractions. petrol X Y crude oil Z bitumen What could X.15 36 When a suitable catalyst is used. ethene reacts with steam. Y and Z represent? X A B C D diesel lubricating oil lubricating oil paraffin Y lubricating oil diesel paraffin diesel Z paraffin paraffin diesel lubricating oil © UCLES 2006 0620/01/M/J/06 [Turn over .

16 38 Which of the compounds shown are used as fuels? H H C H 1 H C H H H H C H 2 H C H O H H H C H 3 C O H O 1 A B C D     2     3     39 Which set of diagrams shows three substances that are all in the same homologous series? H A H C H H H H C H O H H C O O H H B H C H H C H H H C H C H H H C C H H C H C C H H H H C H H C C H H H H C H H C H H C C H H H D H C H C O H H H C H O C H C H H H H C H H C H O H C H H C H H © UCLES 2006 0620/01/M/J/06 .

CH3 C H C H H Which chain-like molecule is formed when these small molecules link together? A CH3 H C C CH3 H C C CH3 H C H C H B CH3 H C H C H C CH3 CH3 CH3 CH3 C C C C CH3 H C H C D CH3 H C C CH3 CH3 H CH3 H CH3 CH3 CH3 CH3 CH3 H © UCLES 2006 0620/01/M/J/06 [Turn over .17 40 The diagram shows the structure of a small molecule.

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p. 49 201 204 50 207 51 209 52 53 54 Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible.DATA SHEET The Periodic Table of the Elements Group III 1 I H Hydrogen II IV V VI VII 0 4 He Helium 1 11 12 14 16 19 2 20 7 9 Li Boron Carbon Be 5 27 28 6 7 B C N Nitrogen O Oxygen F Fluorine Ne Neon Lithium Beryllium 3 4 8 31 32 9 35. the publisher will be pleased to make amends at the earliest possible opportunity. 0620/01/M/J/06 Rubidium Strontium Yttrium Zirconium 37 38 39 40 133 137 139 178 Cs Tantalum Iridium Tungsten Rhenium Osmium Platinum Ba 73 77 74 75 76 78 La Ta W Re Os Pt Hf Ir Au Gold Hg Mercury Tl Thallium Pb Lead Bi Bismuth Po Polonium At Astatine Rn Radon Caesium Barium Lanthanum Hafnium 55 56 57 * 72 79 80 81 82 83 84 85 86 226 227 Fr 140 141 144 150 Ra Ac 152 157 159 162 165 167 169 173 175 Francium Radium Actinium 87 88 89 *58-71 Lanthanoid series 90-103 Actinoid series Ce Cerium Praseodymium Neodymium Promethium Pr 59 60 238 61 Nd Pm 62 Sm Samarium Eu Europium Gd Gadolinium Tb Terbium Dy Dysprosium Ho Holmium Er Erbium Tm Thulium Yb Ytterbium Lu Lutetium 58 232 63 64 65 66 67 68 69 70 71 a a = relative atomic mass Key Th Thorium Protactinium Uranium X Pa 91 92 X = atomic symbol 90 U 93 Np Neptunium Pu Plutonium Am Americium Cm Curium Bk Berkelium Cf Californium Es Einsteinium Fm Fermium Md Mendelevium No Nobelium Lr Lawrencium b b = proton (atomic) number 94 95 96 97 98 99 100 101 102 103 The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r. Every reasonable effort has been made by the publisher (UCLES) to trace copyright holders. which is itself a department of the University of Cambridge.t. but if any items requiring clearance have unwittingly been included.5 10 40 23 24 Na Aluminium Mg 13 51 52 55 56 59 59 64 65 70 Al 14 Si Silicon P Phosphorus S Sulphur Cl Chlorine Ar Argon Sodium Magnesium 11 12 15 73 75 16 79 17 80 18 84 39 40 45 48 K Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Ca 23 93 96 101 103 106 108 112 24 25 26 27 28 29 30 Sc Ti V Cr Mn Fe Co Ni Cu Zn 31 Ga Gallium Ge Germanium As Arsenic Se Selenium Br Bromine Kr Krypton Potassium Calcium Scandium Titanium 19 20 21 22 32 115 119 33 122 34 128 35 127 36 131 20 85 88 89 91 Rb Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Sr 41 181 184 186 190 192 195 197 42 43 44 45 46 47 Y Zr Nb Mo Tc Ru Rh Pd Ag 48 Cd Cadmium In Indium Sn Tin Sb Antimony Te Tellurium I Iodine Xe Xenon University of Cambridge International Examinations is part of the University of Cambridge Local Examinations Syndicate (UCLES). .).