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Maximum Marks: 120


Question paper format and Marking scheme:

1. This question paper has 30 questions of equal weight age. Each question is allotted 4(four) marks for each
correct response.

2. (one fourth) of total marks allotted to each question i.e., 1 mark will be deducted for indicating incorrect
response

3. No deduction from the total score will be made if no response is indicated for an item in the answer sheet.

4. There is only one correct response for each question. Filling up more than one response in each question
will be treated as wrong response and marks for wrong response will be deducted accordingly.







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1. A sample consists of a mixture of H-atoms in 2
nd
excited state and He
+
ions in 5
th
excited state.
Then, the maximum number of different spectral lines observed in the emission spectrum of
sample is
(1) 18 (2) 17 (3) 16 (4) 15

2. That conformational isomer of n-butane (C
2
- C
3
bond) which has 120 dihedral angle is
known as
(1) Gauche (2) Anti (3) Paritally eclipsed (4) Fully eclipsed

3. The empirical formula of sheet silicates & the number of oxygens shared per tetrahedron are
respectively,
(1)
( )
2n
3
n
SiO , 2


(2)
( )
6n
7 2
n
Si O , 3


(3)
( )
2n
5 2
n
Si O , 3


(4)
( )
6n
4 11
n
Si O , 4




4. 25 mL of 2N HCl, 50 mL of 4N
3
HNO and x mL of 2M
2 4
H SO are mixed together and the total
volume is made upto 1L after dilution. 50 mL of this acid mixture completely reacted with 25 mL
of 1N
2 3
Na CO solution. The value of x is
(1) 250 mL (2) 62.5 mL (3) 100 mL (4) 50 mL

5. Reaction of cyclohexanonewith dimethylamine in the presence of catalytic amount of an acid
forms a compound. If water during the reaction is continuously removed the compound formed
is generally known as
(1) an amine (2) an imine (3) an enamine (4) a Schiff's base

6. In the extraction of aluminium
Process X : Employed for red bauxite to remove iron oxide (main impurity)
Process Y : (Serpeck`s process) : used for white bauxite to remove Z (main impurity) then,
Select correct option for the process X and impurity Z.
(1) X = Hall and Heroult`s process and Z = SiO
2

(2) X = Bayer`s process and Z = SiO
2

(3) X = Serpeck`s process and Y = iron oxide
(4) X = Bayer`s process and Y = iron oxide

7. Which of the following ions will be most effective in coaogulating the As
2
S
3
sol
(1) Fe
3+
(2) Ba
2+
(3) Cl
-
(4) PO
4
3-


8. The reagent used to get 3-Phenylprop-2-en-1-oic acid from 4-phenylbut-3-en-2-one is
(1) HIO
4
(2) KMnO
4
(3) I
2
/OH
-
(4) K
2
Cr
2
O
7


9. The thermal stability of hydrides of oxygen family is in order
(1) H
2
Po < H
2
Te < H
2
Se < H
2
S < H
2
O
(2) H
2
Po < H
2
O < H
2
Te < H
2
Se < H
2
S
(3) H
2
S < H
2
O < H
2
Te < H
2
Se < H
2
Po
(4) H
2
O < H
2
S < H
2
Te < H
2
Se < H
2
Po
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10.

( ) ( ) ( )
5 3 2 g g g
PCl PCl Cl +


The degree of dissociation of
5
PCl at one atmosphere is 0.3. The pressure at which
5
PCl is
dissociated to 50% is nearly
1) 2.73 atm 2) 0.3 atm 3) 0.273 atm 4) 1.67 atm



11. Which of the following will not give syn addition

12. Which of the following statements is incorrect?
(1) ClF
3
has T-shape. (2) In SF4 , F-S-F equatorial bond angle is less than 120
o
.
(3) In [ ICl4]
-
, Cl-I- Cl bond angle is 90
o
(4) Shape of I
3
+
molecule is linear.

13. Freezing point of an aqueous solution is 0.186 C , Elevation in boiling point of the same solution
is, if
1
0.512
b
K K molality

= and
1
1.86
f
K K molality

=
(1) 0.186 C (2) 0.0512 C (3) 0.092 C (4) 0.273 C

14. Which one of the following does not react with grignard reagent
(1) CO
2
(2) ROH (3) R
3
N (4) R-CN

15. In qualitative analysis, ammonia is used to separate


(1) NaCl from KCl (2)
AgCl from
2 2
Hg Cl

(3)
2
PbCl
from
( )
2
Mg OH

(4) 3
FeCl
from
3
AlCl




16. A certain reaction proceeds in a sequence of three elementary steps with the rate constants
1 2
k , k
and
3
k . If the observed rate constant,
obs
k of the reaction is expressed as
1/ 2
1
obs 3
2
k
k k
k
(
=
(

; The
observed energy of activation of the reaction is
(1)
1
3
2
1 E
E
2 E
| |
+
|
\
(2)
1 3
2
E E
E
2
| |
+
|
\
(3)
1/ 2
1
3
2
E
E
E
| |
|
\
(4)
1 2
3
E E
E
2

+
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17. Products P and Q in the following reactions are respectively


18. Which is not correctly matched ?
(i) Basic strength of oxides Cs
2
O<Rb
2
O< K
2
O < Na
2
O < Li
2
O
(ii) Stability of peroxides Na
2
O
2
< K
2
O
2
< Rb
2
O
2
< Cs
2
O
2

(iii) Stability of bicarbonates LiHCO
3
< NaHCO
3
< KHCO
3
< RbHCO
3
< CsHCO
3

(iv) Melting point NaF < NaCl < NaBr < NaI
(1) (i) and (iv)
(2) (i) and (iii)
(3) (i) and (ii)
(4) (ii) and (iii)

19. A mixture of Ne
23
and Ar
37
was left standing for long times shows the presence of some traces of
common salt. The result can be explained as follows:
(1) Ne and Ar could have decayed by emission and electron capture respectively
(2) Ne and Ar could have decayed by positron emission and electron capture respectively
(3) Ne and Ar could have decayed by emission and emission respectively.
(4) Ne and Ar could have decayed by K capture and positron emission respectively

20. Molecular formula C
3
H
9
N represents
(1) Only primary amine (2) Only secondary amine
(3) Three primary amine, two secondary amine and one tertiary amine
(4) Two primary amine, one secondary amine and one tertiary amine

21. Phosphine, acetylene and ammonia can be formed by treating water with
(1) Mg
3
P
2
,Al
4
C
3
.Li
3
N (2) Ca
3
P
2
, CaC
2
.NaN
3

(3) Ca
3
P
2
, CaC
2
, CaCN
2
(4) Ca
3
P
2
, Mg
2
C, NH
4
NO
3


22. At 18C the conductivities at infinite dilution of NH
4
Cl, NaOH& NaCl are 130, 220 & 100 mho
respectively. If the equivalent conductivity of N/100 solution of NH
4
OH is 10 Mho, then find the
pH of the NH
4
OH solution.
(1) 10.6 (2) 4.6 (3) 7 (4) 3.4
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23. If one strand of DNA has the sequence ATGCTTGA, the sequence in the complimentary strand
would be
(1) TCCGAACT (2) TACGTAGT
(3) TACGAACT (4) TAGCTAGT

24. A large difference in atomic radius is observed in the pair

(1)
, Zr Hf

(2)
, Nb Ta

(3)
, Mo W

(4) , V Nb




25. For 10minute each, at 0 C, from two identical holes nitrogen and an unknown gas are leaked
into a common vessel of 4 litre capacity. The resulting pressure is 2.8 atm and the mixture
contains 0.4 mole of nitrogen. What is the molar mass of unknown gas?
(1) 448 g mol
-1
(2) 224 g mol
-1

(3) 226g mol
-1
(4) None of these

26. Product (B) of the given reaction is :

(1) Glycine (2)Alanine (3) Lactic acid (4) Glyceraldehyde

27. A solid compound 'X' on heating gives CO
2
gas and a residue. The residue mixed with
water forms 'Y'. On passing an excess of CO
2
through 'Y' in water a clear solution 'Z' is
obtained. On boiling 'Z' compound 'X' is reformed. The compound 'X' is
(1) Ca(HCO
3
)
2
(2) CaCO
3
(3) Na
2
CO
3
(4) K
2
CO
3


28. An element crystallises in fcc lattice. If the effective number of atoms of the element per unit cell
in the crystal is decreased by 0.25% due to Schottky defect then the density of crystal is (At. Wt.
= 50 and edge length = 0.50 nm)
(1) 2g / cc (2) 2.6 g / cc
(3) 3.06 g / cc (4) 4 g / cc

29.

X and Z are respectively
(1) Ethanol and Chlorobenzene (2) Phenol and lodoethane
(3) lodoethane and Chlorobenzene (4) Phenol and Chloroethane

30. A co-ordination complex has the formula PtCl
4
.2KCl. Electrical conductance measurements
indicate the presence of three ion in one formula unit. Treatment withAgNO
3
produces no ppt.
of AgCl. What is the co-ordination number of Pt in this complex
(1) 5 (2) 6 (3) 4 (4) 3