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MAHESH JANMANCHI

AIEEE – 2012

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MAHESH JANMANCHI

AIEEE – 2012

Maximum Marks: 120

Question paper format and Marking scheme: 1. This question paper has 30 questions of equal weight age. Each question is allotted 4 marks for each correct response. 2. ¼ (one fourth) of total marks allotted to each question i.e., 1 mark will be deducted for indicating incorrect response 3. No deduction from the total score will be made if no response is indicated for an item in the answer sheet. 4. There is only one correct response for each question. Filling up more than one response in each question will be treated as wrong response and marks for wrong response will be deducted accordingly.

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MAHESH JANMANCHI
31. 2-Hexyne gives trans 2-Hexene on treatment with (1) Li/NH3 (2) Pd/BaSO4 (3) LiAlH4 (1) Birch reduction Li / NH3 CH3 –CH2 –CH2 −C ≡ C –CH3  → (4) Pt / H2

AIEEE – 2012

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32.

Which of the following on thermal decomposition yields a basic as well as an acidic oxide ? (1) KClO3 (2) CaCO3 (3) NH4NO3 (4) NaNO3 (2) ∆ CaCO3  CaO + CO2 . → CaO is metallic oxide. So, basic in nature CO2 is non metallic oxide. So, acidic in nature Which one of the following statements is correct ? (1) All amino acids are optically active (2) All amino acids except glycine are optically active (3) All amino acids except glutamic acid are optically active (4) All amino acids except lysine are optically active (2) All amino acids except glycine are optically active

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33.

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34.

The density of a solution prepared by dissolving 120 g of urea (mol. mass = 60 u) in 1000 g of water is 1.15 g / mL. The molarity of this solution is (1) 1.78 M (2) 1.02 M (3) 2.05 M (4) 0.50M (3) Total mass of solution = 1000 + 120 = 1120 g 1120 Total volume of solution in (L) = ×10−3 1.15 w 1 Molarity = × M V ( in L )
120 1.15 ×103 × 60 1120 = 2.05 M =

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MAHESH JANMANCHI
35. The incorrect expression among the following is : Vf (1) In isothermal process, wreversible = −nRT ln Vi

AIEEE – 2012

∆H 0 − T ∆S 0 (2) ln K = RT −∆G 0 / RT (3) K = e ∆G sys (4) = −T ∆S Total
Sol. (2) ∆G 0 = ∆H 0 − T ∆S 0

∆G 0 = − RT ln K From these, − RT ln K = ∆H 0 − T ∆S 0
ln K = − ∆H 0 − T ∆S 0 RT

36.

Which branched chain isomer of the hydrocarbon with molecular mass 72 u gives only one isomer of mono substituted alkyl halide ? (1) Neopentane (2) Isohexane (3) Neohexane (4) Tertiary butyl chloride (1) Neo pentane has only one type of hydrogens. So it can give only one monohalogenation product

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37.

According to Freundlich adsorption isotherm, which of the following is correct ? x x x (1) ∝ p1 (2) ∝ p1/n (3) ∝ p0 m m m (4) All the above are correct for different ranges of pressure (4)
According to Freundlich adsorption isotherm,

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x ∝ p1/n m The factor 1/n can have values between 0 and 1(probable range 0.1 to 0.5).
When 1/n = 0, x/m= constant, the adsorption is independent of pressure.i.e., When 1/n = 1, x/m= k P, i.e.

x ∝ p0 m

x ∝ p the adsorption varies directly with pressure. m
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MAHESH JANMANCHI
38. In which of the following pairs the two species are not isostructural ? (1) PCl4+ and SiCl4 (2) PF5 and BrF5 3– (4) CO32– and NO3– (3) AlF6 and SF6 (2) Acc to VSEPR theory, PF5 is trigonal bipyramidal as it has 5 bonded pairs and no lone pairs BrF5 is square pyramidal as it has 5 bonded pairs and 1 lone pairs.

AIEEE – 2012

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39.

How many chiral compounds are possible on monochlorination of 2 - Methyl butane ? (1) 2 (2) 4 (3) 6 (4) 8 (2) Monochlorination of 2 - Methyl butane yields 6 stero isomers among which 4 are chiral

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These are chiral compounds. Each one exists as d and l. So total no of chiral conmpounds = 4 Remaining two are

40.

The increasing order of the ionic radii of the given isoelectronic species is : (1) S2– , Cl– , Ca2+ , K+ (2) Ca2+ , K+ , Cl– , S2– (3) K+ , S2– , Ca2+ , Cl– (4) Cl– , Ca2+ , K+ , S2– (2) In case of isoelectronic species, as the magnitude of + ve charge increases, size decreases And as the magnitude of - ve charge increases, size increases Ca2+ , K+ , Cl– , S2– all have 18 electrons and are arranged in increasing order of ionic radii.

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MAHESH JANMANCHI
41. The compressibility factor for a real gas at high pressure is : (1) 1 (2) 1 + pb / RT (3) 1 – pb / RT (2) Vanderwaal’s equation for 1 mole of gas a ( P + 2 )(V − b) = RT V a At high pressure, 2 can be neglected V So, Vanderwaals equation gets reduced to
P(V − b) = RT PV − Pb = RT PV Pb − =1 RT RT PV Pb ∴Z = = 1+ RT RT

AIEEE – 2012

(4) 1 + RT / pb

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42.

Which among the following will be named as dibromidobis (ethylene diamine) chromium (III) bromide ? (1) [Cr (en)2 Br2 ]Br (2) [Cr (en) Br4 ]– (3) [Cr (en) Br2 ]Br (4) [Cr (en)3 ] Br3 (1) Cation is named first followed by anion. In coordination sphere the ligands are named alphabetically followed by name of metal ion and then its oxidation state in Roman numeral. In the given complex, chromium is in +3 oxidation state and the complex is cationic. So, the complex dibromidobis (ethylene diamine) chromium (III) must be [Cr (en)2 Br2 ]Br In the given transformation, the following is the most appropriate reagent ?

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43.

(1) Zn – Hg / HCl Sol.

(2) Na, Liq. NH3

(3) NaBH4

(4) NH2NH2,OH-

(4) NH2NH2,OH- i.e., wolff kischner reagent, doesn’t affect – OH group Zn – Hg / HCl i.e., Clemmensen’s reagent can’t be used as it affects – OH group ( doesn’ work with acid sensitive groups)

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MAHESH JANMANCHI
44.

AIEEE – 2012

Lithium forms body centred cubic structure. The length of the side of its unit cell is 351 pm. Atomic radius of the lithium will be : (1) 300 pm (2) 240 pm (3) 152 pm (4) 75 pm (3) For BCC structure, 3a = 4r

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r=
45.

3 x351 = 152 pm 4

Kf for water is 1.86 K kg mol –1 . If your automobile radiator holds 1.0 kg of water, how many grams of ethylene glycol (C2H6O2 ) must you add to get the freezing point of the solution lowered to – 2.8º C ? (1) 93 g (2) 39 g (3) 27 g (4) 72 g (1) ∆T f = K f .m

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0 − (−2.8) = 1.86 x w=
46.

w 1000 x 62 1000

2.8 x62 = 93.3 g 1.86

The molecule having smallest bond angle is : (1) AsCl 3 (2) SbCl3 (3) PCl3

(4) NCl3

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(2) As the electronegativity of central atom decreases, bond angle decreases. What is DDT among the following (1) A fertilizer (3) Non biodegradable pollutant

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(2) Biodegradable pollutant (4) Greenhouse gas

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(3) DDT (Dichloro diphenyl trichloro ethane) is a nonbiodegradable pollutant.. The pH of a 0.1 molar solution of the acid HQ is 3. The value of the ionization constant, Ka of this acid is : (1) 1 × 10–3 (2) 1 × 10–5 (3) 1 × 10–7 (4) 3 × 10–1 (2) pH = 3 ∴[ H + ] = 10−3
∴[ H + ] = ka .C 10−3 = ka .(0.1) ka = 10−5

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MAHESH JANMANCHI
49. Very pure hydrogen (99.9%) can be made by which of the following processes ? (1) Mixing natural hydrocarbons of high molecular weight (2) Electrolysis of water (3) Reaction of salt like hydrides with water (4) Reaction of methane with steam (3) Very pure hydrogen (99.9%) can be obtained by the action of H2O on NaH NaH + H2O → NaOH + H2 Aspirin is known as : (1) Phenyl salicylate (3) Methyl salicylic acid (2) Acetyl salicylate (4) Acetyl salicylic acid

AIEEE – 2012

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50.

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(4) Aspirin is o – acetyl salicylic acid. It is analgesic as well as antipyretic

51.

Which of the following compounds can be detected by Molisch’s test ? (1) Sugars (2) Amines (3) Primary alcohols (4) Nitro compounds (1) Molisch’s test is used as a test for sugars One or two drops of alcoholic solution of α-naphthol is added to 2 ml of glucose solution. 1 ml of conc. H2SO4 solution is added along the sides of the test tube. Formation of a violet ring at the juncture of two liquids confirms the presence of a sugar The standard reduction potentials for Zn2+ / Zn, Ni2+ / Ni, and Fe2+ / Fe are –0.76, – 0.23 and –0.44 V respectively. The reaction X + Y2+ →X2+ + Y will be spontaneous when (1) X = Ni, Y = Zn (2) X = Fe, Y = Zn (3) X = Zn, Y = Ni (4) X = Ni, Y = Fe (3) A metal with high – ve SRP, being more reactive can displace all other metals with low – ve SRP from their salt solutions So, From the given E0 values, Zn can displace both Fe and Ni whereas Fe can displace Ni only and Ni cannot displace any of these. Therefore, among given, option (3) is correct

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MAHESH JANMANCHI
53.

AIEEE – 2012

Ortho Nitrophenol is less soluble in water than p–and m–Nitrophenols because : (1) o–Nitrophenol shows Intramolecular H–bonding. (2) o–Nitrophenol shows Intermolecular H–bonding. (3) Melting point of o–Nitrophenol is lower than those of m–and p–isomers. (4) o–Nitrophenol is more volatile in steam than those of m– and p–isomers (1) Ortho Nitrophenol is less soluble in water than p–and m–Nitrophenols because o–Nitrophenol has intramolecular H–bonding due towhich there is chelation among ortho groups which restricts further bonding or solubility

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54.

Iodoform can be prepared from all except : (1) Isopropyl alcohol (2) 3–Methyl–2–butanone (3) Isobutyl alcohol (4) Ethyl methyl ketone (3)

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Isobutyl alcohol has no methyl keto group or methyl carbinol group. So, it cannot give iodoform. 55. The species which can best serve as an initiator for the cationic polymerization is : (1) HNO3 (2) AlCl3 (3) BuLi (4) LiAlH4 (2) The initiator for a cationic polymerization is a Lewis acid like AlCl3 or BF3 The equilibrium constant (Kc ) for the reaction N2 (g) + O2 (g) → 2NO(g) at temperature T is 4 × 10–4 . The value of Kc for the reaction, NO(g) →1/2N2 (g) + 1/2O2 (g) at the same temperature is (1) 2.5 × 102 (2) 4 × 10–4 (3) 50.0 (4) 0.02 (3) Equation is reversed and divided by 2 1 Therefore, K = 2 K
1

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56.

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1 K = 2 4 x10−4 1 = 2 x10−2 = 50

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MAHESH JANMANCHI
57.

AIEEE – 2012

For a first order reaction, (A) →products, the concentration of A changes from 0.1 M to 0.025 M in 40 minutes. The rate of reaction when the concentration of A is 0.01 M is : (1) 3.47 × 10–4 M/min (2) 3.47 × 10–5 M/min –4 (3) 1.73 × 10 M/min (4) 1.73 × 10–5 M/min (1) First order rate constant expression is 1 a K = ln (where a = initial conc and x is conc. reacted and (a-x) is conc left) t ( a − x) 1 0.1 1 K = ln = ln 4 40 0.025 40 1 R = k[ A] = ln 4(0.01) 40 2 ln 2 = (0.01) 40 = 3.47 x10−4 Which method of purification is represented by the following equation :
523K 1700K Ti(s) + 2I2 (g)  TiI4 (g)  Ti(s) + 2I2 (g) → →

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58.

1)Cupellation

(2) Poling

(3) Van Arkel

(4) Zone refining

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(3) van Arkel Method is used for refining Zirconium or Titanium This method is very useful for removing all the oxygen and nitrogen present in the form of impurity in metals like Zr and Ti. The crude metal is heated in an evacuated vessel with iodine. The metal iodide being more covalent, volatilises Ti + 2I2 → TiI4 The metal iodide is decomposed on a tungsten filament, electrically heated to about 1675K. The pure metal is thus deposited on the filament. TiI4 → Ti + 2I2 Iron exhibits +2 and +3 oxidation states. Which of the following statements about iron is incorrect? (1) Ferrous compounds are relatively more ionic than the corresponding ferric compounds (2) Ferrous compounds are less volatile than the corresponding ferric compounds (3) Ferrous compounds are more easily hydrolysed than the corresponding ferric compounds (4) Ferrous oxide is more basic in nature than the ferric oxide. (3) Fe3+ is hydrolysed more readily than Fe2+ due to greater positive charge. Page 10

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MAHESH JANMANCHI
60. The electrons identified by quantum numbers n and 1 : (a) n = 4, 1 = 1 (b) n = 4, 1 = 0 (c) n = 3, l = 2 (d) n = 3, 1 = 1 Can be placed in order of increasing energy as : (1) (d) < (b) < (c) < (a) (2) (b) < (d) < (a) < (c) (3) (a) < (c) < (b) < (d) (4) (c) < (d) < (b) < (a) (1) Based on ( n + l) rule, Greater the (n +l) value , greater is the energy If (n +l) value is same, greater the value of n , greater is the energy Therefore, the order of increasing energy is (d) < (b) < (c) < (a)

AIEEE – 2012

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