4/15/12

2-Butanone

Standard Reference Data Program

Data Gateway

Chemistry WebBook

2-Butanone
Formula: C4 H8 O Molecular weight: 72.1057 IUPAC Standard InChI:
ICI1/48/13425hH,-H nh=SCHOc--()/32123

Download the identifier in a file. IUPAC Standard InChIKey: Z E N R P V G - H F A Y A N WHKNOVHUFFOSCAS Registry Number: 78-93-3 Chemical structure:

This structure is also available as a 2d Mol file or as a computed 3d Mol file. Other names: Butan-2-one; Butanone; Ethyl methyl ketone; Ketone, methyl ethyl; Methyl ethyl ketone; MEK; C2H5COCH3; Acetone, methyl-; Aethylmethylketon; 3-Butanone; Butanone 2; Ethyl methyl cetone; Ethylmethylketon; Ketone, ethyl methyl; Meetco; Methyl acetone; Metiletilchetone; Metyloetyloketon; Rcra waste number U159; UN 1193; 2-Oxobutane; 2-Butanal; 2-butanone (MEK; methyl ethyl ketone); 2-butanone (MEK) Permanent link for this species. Use this link for bookmarking this species for future reference. Information on this page: Phase change data References Notes / Error Report Other data available: Gas phase thermochemistry data Condensed phase thermochemistry data Reaction thermochemistry data Henry's Law data Gas phase ion energetics data Ion clustering data IR Spectrum Mass spectrum (electron ionization) Vibrational and/or electronic energy levels Gas Chromatography Data at other public NIST sites: Computational Chemistry Comparison and Benchmark Database Gas Phase Kinetics Database Options: Switch to calorie-based units
webbook.nist.gov/cgi/cbook.cgi?ID=C78933&Mask=4 1/7

F. but require an annual fee to access. Hearing CAL .01 K. Brown and S. TRC AVG N/A Reference Reference Wilhoit. TRC Parks. Value 186.4 186. References.00.S. University of Missouri -.03 K. Jr. J. All rights reserved. 1985 Units Method K Units Method K K K K K N/A N/A N/A N/A N/A AVG N/A Andon. "lite" edition (thermophysical and thermochemical data) NIST / TRC Web Thermo Tables.F.1 Value 535. TRC Uncertainty assigned by TRC = 0. Afeefy.E. Uncertainty assigned by TRC = 0. 1/f = 1.D. Liebman. et al.04 K.5 186. Chao.1 K.L. professional edition (thermophysical and thermochemical data) NIST subscription sites provide data under the NIST Standard Reference Data Program. 1964 Sinke and Oetting. Individual data points Comment Average of 7 values. Stein ALS .06 K. measured for the sample. Data compiled as indicated in comments: TRC . 1964 Uncertainty assigned by TRC = 0. and S. Secretary of Commerce on behalf of the U. Individual data points 2/7 Units Method K AVG N/A webbook. Stein DH . Notes / Error Report Data compilation copyright by the U.gov/cgi/cbook. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. et al.E. Students of Chem 202 (Introduction to the Literature of Chemistry). TRC 1968 Sinke and Oetting. NIST Boulder Laboratories. ± 2.St. Louis Quantity Tboil Quantity Tfus Quantity Ttriple Ttriple Ttriple Ttriple Ttriple Quantity Tc Value 353. Your institution may already be a subscriber.47 186.00.5 Value 186.S.48 186. Uncertainty assigned by TRC = 0. measured for the sample.S. et al. Acree.Thermodynamics Research Center. Liebman. Phase change data Go To: Top. Kennedy.. TRC 1956 Reference Comment Average of 9 values.Y. M.S.H. Individual data points Comment Uncertainty assigned by TRC = 0.A.. 1/f = 1..cgi?ID=C78933&Mask=4 . Follow the links above to find out more about the data in these sites and their terms of usage. Units Method K Reference Comment Average of 89 out of 90 values.4/15/12 2-Butanone Data at NIST subscription sites: NIST / TRC Web Thermo Tables.E.. Domalski and E. J. Chickos.R. W. Frenkel director BS . ± 1.E.J. Counsell.5 ± 0.nist.

8 Majer and Svoboda.2925 536.06 mol/l.73 kJ/mol Δvap H° Δvap H° 35. et al.gov/cgi/cbook.92 kJ/mol 34. 1983 ALS Uncertainty assigned by TRC = 0.08 kJ/mol 32. et al.49 Value Units Method Units Method mol/l mol/l N/A N/A Reference Reference Comment Average of 8 values. .3 Reference Comment 352. 1985 Enthalpy of vaporization Δvap H = A exp(-βTr) (1 − Tr)β Δvap H = Enthalpy of vaporization (at saturation pressure) (kJ/mol) Tr = reduced temperature (T / Tc) View plot Requires a Java capable browser. TRC 1955 Rosenbaum. Majer.0 ± 0. Crawford. Uncertainty assigned by TRC = 0. Individual data points Comment bar AVG N/A Kobe.8 Majer and Svoboda. 1985 Uchytilova. ± 2.cgi?ID=C78933&Mask=4 3/7 . β Tc (K) Reference Comment 51.74 3. 1926 ALS Enthalpy of vaporization ΔvapH (kJ/mol) Temperature (K) 31. TRC Comment Units Method N/A V 34. Svensson.21 mol/l.51 ± 0. Temperature (K) A (kJ/mol) 298. ALS 1979 Mathews.nist. 1985 Antoine Equation Parameters log10 (P) = A − (B / (T + C)) P = vapor pressure (bar) T = temperature (K) webbook.01 kJ/mol C V Sunner..4/15/12 2-Butanone Quantity Pc Quantity ρc ρc Quantity Δvap H° Δvap H° Value 42.371. Value 3. et al.87 0. 1951 Reference Majer and Svoboda...

Enthalpy of fusion Δfus H (kJ/mol) Temperature (K) 8. webbook.98 45.48 Sinke and Oetting. 1968. 1956..6 3..6 . 1991 186. 2 186. 1964. much more physical and chemical property data is available from the following TRC products: SRD 103a – Thermo Data Engine (TDE) for pure compounds.1 Parks. Counsell.47 Andon. Counsell.904 Nickerson.5 Acree.A.4/15/12 2-Butanone View plot Requires a Java capable browser. 2 186. Notes / Error Report Data compilation copyright by the U.gov/cgi/cbook. Kennedy.1 Parks. et al. 1968.48 Sinke and Oetting.nist. Kennedy. et al.. et al.4387 8. Kobe. SRD 103b – Thermo Data Engine (TDE) for pure compounds.207 -63. binary mixtures and chemical reactions SRSD 2 – Web Thermo Tables (WTT). et Coefficents calculated by NIST from al. et al. All rights reserved.47 Andon. Secretary of Commerce on behalf of the U.385 8. 1956. professional edition SRD 147 – Ionic Liquids Database SRD 156 – Clathrate Hydrate Physical Property Database References Go To: Top.370. "lite" edition SRSD 3 – Web Thermo Tables (WTT).9894 1150.25 45..cgi?ID=C78933&Mask=4 4/7 . Temperature (K) A B C Reference Comment 314.485 Reference Comment DH CAL 186.59 Reference Comment DH 186. 2 DH Entropy of fusion Δfus S (J/mol*K) Temperature (K) 44.44 8. 1964. 2 DH 186.S. 2 DH 186. 2 DH In addition to the Thermodynamics Research Center (TRC) data available from this site.S. Phase change data.. 1961 author's data.

Thermodynamic properties of organic oxygen compounds.. Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation. et al.. Stephenson. et al..S. et al. Enthalpies of vaporization at 298. Soc. 1968 Andon. R.. 562-576. Entropy and Free Energy Data for Seven Compounds Containing Oxygen. J. Am. et al. 1354-8. V. Part 1. 1956 Parks. Tex. K. Oxford. Zelepuga. 1985 Majer.. Martin. 68.F.. 1983 Uchytilova. The Thermodynamic Properties of the Methyl Ketone Series.F. J... J.. Kobe. J. [all data] Sunner.. R. Counsell. 1894-7. Martin. Properties of Condensed Phases. Thermodyn. Chem.. V. G. R. webbook. 1951 Rosenbaum. 1926 Mathews. Soc. Chem... Counsell.. 1979. 1968. The Chemical Thermodynamic Properties of Methyl Ethyl Ketone. G. Ref. Svoboda. [all data] Nickerson. Majer. 1. TX.J. Svensson.L. [all data] Mathews. [all data] Uchytilova. J. 78. 15. M. J. Thesis. The low. S.. W. Soc.E. G.. Thermodyn.C. Chem.. J. J. 1968.S. 1985. Hynek. [all data] Kobe. 14. 1968.D. M. 65.. Chao. Blackwell Scientific Publications. 1983. Svoboda. Some Heat Capacity... Kennedy.K.. A. 1956.. 48. 1955 Kobe.. R. 1037-1043.S.J. Chem... 2 Andon. McKetta... J. F. Crawford. V. V.. Chem..15 K for some 2alkanones and methyl alkanoates. Kennedy. 1964. Chao.. [all data] Rosenbaum. J. 1767-72.F. 56-9. et al.cgi?ID=C78933&Mask=4 5/7 . J. K. 1964 Sinke. J. 1985. Majer.C.nist. Crawford..L. Univ. [all data] Andon. 11.. R. Counsell. Mosley.. Part XX. 491-495. et al.4/15/12 2-Butanone Wilhoit... Chem. 1961.. Thermal Data on Organic Compounds XXVI. J. et al.. Phys.. 1985 Wilhoit. Gates. Thermodynamic properties of organic oxygen compounds. [all data] Parks..L. Moore.. Chem.. Enthalpies of vaporization and cohesive enrgies for seven aliphatic ketones..A. The accurate measurement of heats of vaporization of liquids. Renquist. 1926. H. Ch. Chem. Chem. et al. V. Svensson. Hall. V. 47.. Data. 1955..temperature heat capacity and entropy of C4 and C5 ketones.L. Phys. M. Ind. [all data] Majer and Svoboda. J.. [all data] Sinke and Oetting. Counsell. Critical Properties and Vapor Pressures of Some Ketones.. Am.. 300. [all data] Andon. . Thermodynamic Properties of Key Organic Compounds in the Carbon Range C1 to C4.R. A.R. Oetting. Phys.gov/cgi/cbook..J.. 853-858.R.F.W. Kobe. K... J. Austin.A. Eng. J. 1961 Nickerson.R.H. 1979 Sunner. 1951. J.

Chem. J. R. Acta. please fill out the error report form for this page.S.. Jr.. J... Soc. 2 Parks. entropy and free energy data for seven compounds containing oxygen. 37. 1991 Acree.L. M. 68.cgi?ID=C78933&Mask=4 6/7 . XXVI. W. [all data] Sinke and Oetting. References Symbols used in this document: Pc Tboil Tc Tfus Ttriple ΔfusH ΔfusS Δvap H Δvap H° ρc Critical pressure Boiling point Critical temperature Fusion (melting) point Triple point temperature Enthalpy of fusion Entropy of fusion Enthalpy of vaporization Enthalpy of vaporization at standard conditions Critical density Data from NIST Standard Reference Database 69: NIST Chemistry WebBook The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. et al. A. and NIST shall not be liable for any damage that may result from errors or omissions in the Database. J.E.. If you believe that this page may contain an error. 1956. Thermochim. 1354-1358.. Take the NIST Measurement Services Customer Satisfaction Survey. Phys..S. W. Phase change data.D.C. © 2011 by the U. 78. G. Gates. [all data] Acree. Renquist. 1964.. G. Mosley. Oetting. Moore. [all data] Parks. G. 1968. Kennedy.. NIST makes no warranties to that effect. Secretary of Commerce on behalf of the United States of America.E. Some heat capacity. 1894-1897.R. 1956.R. Not In System..nist.. 1991. 2 Sinke. Thermal data on organic compounds.gov/cgi/cbook. 1964. The low-temperature heat capacity and entropy of C4 and C5 ketones. F.L. All rights webbook. 56-59.4/15/12 2-Butanone Part XX. However. Rate our products and services. The chemical thermodynamic properties of methyl ethyl ketone.. Kennedy. [all data] Notes / Error Report Go To: Top. Chem..

please contact us.4/15/12 2-Butanone reserved.cgi?ID=C78933&Mask=4 7/7 . Copyright for NIST Standard Reference Data is governed by the Standard Reference Data Act.gov/cgi/cbook.nist. Standard Reference Data Program If you have comments or questions about this site. Data Gateway Chemistry WebBook webbook.

Sign up to vote on this title
UsefulNot useful