Assignment 01 – Spring 2012
(Due date: 07-05-2012) Course Code: Class: Total Marks: 10
RM-572 MS Textile Engineering,

Course Title: Analytical Techniques Semester:
2nd

You are being provided with forty set of problems. Each problem consists of different spectra (IR, 1H-NMR, 13C-NMR, Mass etc). Give assignments to every peak in the spectra and finally deduce the actual structure of the said compound and submit the assignment within the due date positively.

Problem 1

C 5 H 10 O

Problem-2,

C7 H 14 O

Problem 3:

C 4 H 10 O

Problem 4: C6 H 14 O .

Problem 6: C4 H 8O 2 .

Problem 7: C 5 H 10 O 2 .

Problem 8: C 5 H10 O .

Problem 9: C8H8O .

Problem 10: C 9 H 10O 2 .

Problem 11: C3 H 6 O 2 .

Problem 12 : C 11 H 14 O 2 .

Problem 13: C8 H 8 O 2 .

Problem 14: C7H9N .

Problem 15: C5H13N .

Problem 16: C8H14O .

Problem 17: C4H9Br .

Problem 18: C 10 H 14 O. .

Problem 19 : C 13 H 10 O 3 .

.Problem 20: C8H14.

.Problem 21: C9H13N.

Problem 22 C3H5BrO2. MW = 152 .

MW = 174 Problem 23 . C8H14O4.1H NMR spectrum (CDCl3.Problem 23. 500 MHz) .

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Problem 24 . 125 MHz) .13C NMR spectrum (CDCl3.

Problem 25. C9H12. MW = 120 Problem 25 .1H NMR spectrum (CDCl3. 500 MHz) .

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13C NMR spectrum (CDCl 3 .Problem 26 .IR spectrum Problem 26 . 125 MHz .

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IR spectrum Problem 27 .1H NMR spectrum (CDCl 3 . 500 MHz) . MW = 176 Problem 27 .Problem 27 C 7 H 13 Br.

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125 MHz) .Problem 27 .13C NMR spectrum (CDCl 3 .

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Problem 28. MW = 84 Problem 28 .IR spectrum Problem 28 . 500 MHz) . C 5 H 8 O.1H NMR spectrum (CDCl 3 .

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Problem 28 .13C NMR spectrum (CDCl 3 . 125 MHz) .

500 MHz) .1H NMR spectrum (CDCl 3 .IR spectrum Problem 29 .Problem 29 C 9 H 13 NO MW = 151 Problem 29 .

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125 MHz) .13C NMR spectrum (CDCl 3 .Problem 29 .

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1H NMR spectrum (CDCl 3 . 500 MHz) .IR spectrum Problem 30 .Problem 30 MW = 82 C 6 H 10 Problem 30 .

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125 MHz) .Problem 30 .13C NMR spectrum (CDCl 3 .

IR spectrum Problem 31 . 500 MHz) .Problem 31 MW = 137 C 8 H 11 NO Problem 31 .1H NMR spectrum (CDCl 3 .

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Problem 31 .13C NMR spectrum (CDCl 3 . 125 MHz) .

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Problem 31 .positive EI Mass Spectrum .

1H NMR spectrum (CDCl 3 .IR spectrum Problem 32 . 500 MHz) .Problem 32 C 10 BrH 7 MW = 206 Problem 32 .

Problem 32 - 13C NMR spectrum (CDCl 3 , 125 MHz)

Problem 32 - positive EI Mass Spectrum

Problem 33 MW = 265

C 14 H 19 NO 4
Problem 33 - IR spectrum

Problem 33 - 1H NMR spectrum (CDCl 3 , 500 MHz)

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13C NMR spectrum (CDCl 3 . 125 MHz) .Problem 33 .

positive EI Mass Spectrum .Problem 33 .

1H NMR spectrum (CDCl 3 .Problem 34 MW = 116 C 6 H 12 O 2 Problem 34 .IR spectrum Problem 1 . 500 MHz) .

13C NMR spectrum (CDCl 3 . 125 MHz) .Problem 34 .

positive EI Mass Spectrum .Problem 34 .

IR spectrum Problem 35 .1H NMR spectrum (DMSO-d 6 . 500 MHz) .Problem 35 MW = 167 C 7 H 5 NO 4 Problem 35 .

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125 MHz) .13C NMR spectrum (DMSO-d 6 .Problem 35 .

Problem 35 .positive EI Mass Spectrum .

Problem 36 C 5 H 10 O 4 MW = 134 Problem 36 .1H NMR spectrum (DMSO-d 6 .IR spectrum Problem 36 . 500 MHz) .

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13C NMR spectrum (DMSO-d 6 . 125 MHz) .Problem 36 .

positive EI Mass Spectrum .Problem 36 .

Problem 37 C8H6O2 MW = 134 Problem 37 .IR spectrum Problem 37 .1H NMR spectrum (CDCl 3 . 500 MHz) .

positive EI Mass Spectrum .13C NMR spectrum (CDCl 3 .Problem 37 . 125 MHz) Problem 37 .

IR spectrum Problem 38 .1H NMR spectrum (CDCl 3 .Problem 38 MW = 214 C 13 H 10 O 3 Problem 38 . 500 MHz) .

Problem 38 . 125 MHz) .13C NMR spectrum (CDCl 3 .

positive EI Mass Spectrum .Problem 38 .

Problem 39 C7H6O2 MW = 122 Problem 39 . 500 MHz) .IR spectrum Problem 39 .1H NMR spectrum (CDCl 3 .

125 MHz) .13C NMR spectrum (CDCl 3 .Problem 39 .

Problem 39 .positive EI Mass Spectrum .

1H NMR spectrum (CDCl 3 .IR spectrum Problem 40 .Problem 40 MW = 166 C 9 H 10 O 3 Problem 40 . 500 MHz) .

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Problem 40 . 125 MHz) Problem 40 .13C NMR spectrum (CDCl 3 .positive EI Mass Spectrum .