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67,-89:%‫م‬/ 5‫&א‬/'‫א‬1234(...‫"و! قون‬#$‫א‬%‫*"אص ('&"و‬+,-
‫مא‬/ 
A- ;(( ( (
‫و"نא‬AH @‫א‬$AB‫א‬CD!? 8‫وא‬E(F?‫א‬:=(3(*‫( א?عא‬l'acide acétylsalicylique);(( ( (
‫א‬ 

:25°C?-:' 2

pKA à 25 °C

AH / A : 3,5
H2O / HO
M(AH) = 180 g.mol-1
H3O+
HO –

:=(3(*‫א?عא‬

λ (mS.m2.mol-1)

35,0

: 14
A–

19,9

3,6

:QD( S @CD!2:=!‫ل‬P! VS = 500,0 mLKLMN‫א‬AH63H‫ذא&&! (?&!א‬J 
C S = 5,55 × 10-3 mol.L-1ِ 

pH‫(س‬/:=(3(*‫א &אلא‬$‫(د‬1
2,9 ,'-"25°C?-S‫ل‬U‫א‬pH‫(س‬ 
.SKU‫لא‬U‫[ א‬H3O+] éq‫?אאزن‬-‫د‬W

(1.1 

Y‫א‬Z!AH63H‫א‬-4 &‫! د‬X‫א‬

(1.2

(:4]‫&^ولא‬2  _‫)`*א‬-4‫\אא‬Xf :=?‫مא‬/‫"و[א‬

(1.3 

-48A/‫مא‬/‫دא‬W

(1.4 

. -‫؟‬:‫وس‬$Y‫אلא‬c،-4τ:=?‫مא‬/‫&א‬a 2‫د‬W

(1.5 

&]‫א‬Y‫(سא‬/-4‫& אزنא‬e9(2 
‫ل‬U‫א‬#[‫א‬Y‫א‬g2
‫א‬D(‫א‬h&'a Y‫لא‬U‫](&א‬f2.σ = 44 mS.m-1,'-" 25°C?- S ‫ل‬U‫(س!](&א‬

σ = λ H O . [H3O+] + λ A . [A-] + λ
3

+

:&(‫ &א‬
HO −

. [HO -] 

:laA &/ ‫لوא &א‬U‫!](&א‬HO-g2"&3c !‫ل‬3ci*`&j‫وطא‬+

σ = λ H O . [H3O+] éq + λ A . [A-]éq
3

+

(1) 

((3.1:&[m:]‫&^ولא‬2  _‫)`*א‬σ&_Y‫א‬Z!AH-4Xf:=?‫مא‬/‫א‬--(2.1

Xf&3(n? ‫(א‬2.2 

H3O+‫ و‬A- ‫ و‬AH:‫?אאزن‬-&(‫(=(&א‬3(*‫אعא‬2o‫?אאزن‬-&(Y‫א‬D(‫א‬h‫א‬X W‫(א‬2.3 
3(X W‫א‬qe،Y‫א‬Z!AH-4K‫&אאزن‬epa E-‫(א‬2.4 
&]‫א‬Y‫&و(سא‬h!pH:r3  Y‫א‬r(?/‫(د&א‬3
-1 

2,8r#$AP‫ *ن‬pH&3(‫"ن‬8".1 mS. m @( $s(/&]‫א‬Y‫[ز(سא‬3?(#W‫و‬0,1@( $pH &3(h!pHs(/ 
45 mS. m-1‫و‬43 mS:r#$AP‫ل‬U‫!](&א‬3?(3,0 ‫و‬

σ&(]Y‫وא‬pH‫ل‬q(/‫א‬tuY:=?‫مא‬/Mu!:‫א^ولא‬:' 

xf (en mol)

pH= 2,8

pH = 3,0

σ= 43 mS. m-1

σ= 45 mS. m-1

7,9 × 10-4

5,0 × 10-4

5,6 × 10-4

5,8 × 10-4 

v ?‫ (@א‬$_‫ @א‬W‫[א;دون‬-،&‫"د‬r'‫א‬8"