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    Edgar Berrospi
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    8 views2 pages

    Ejercicio 01 de Fisicoquimica

    Uploaded by

    Edgar Berrospi
    ejercicio

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 2

    EJERCICIO 01.

    Si se introducen 0,1500 moles de O2 (g) en un recipiente vacío, y se alcanza el equilibrio


    a 3700 K y 895 torr, se encuentran al final 0,1027 moles de O (g). Calcule 𝐾𝑃𝑜 y ∆𝐺°para la
    reacción O2 (g) ↔ 2O (g) a 3700 K. suponga gases ideales.

    SOLUCION:

    O2 (g) ↔ 2O (g)
    INICIO 0.1500 -
    REACCION 𝑿 𝟐𝑿
    EQUILIBRIO 𝟎. 𝟏𝟓𝟎𝟎 − 𝑿 𝟐𝑿

    Equilibrio. Final: 2x = 0.1027  moles de O2

    Moles O2 = 0.15 – 0.051135 = 0.09865

    x = 0.05135

    𝑛𝑇 = 0.1500 – 0.05135 + 0.1027 = 0.2014

     Ahora, calculamos 𝐾𝑃𝑜 :


    (𝑃𝑂 /𝑃𝑜 )2
    𝐾𝑃𝑜 =
    𝑃𝑂2 /𝑃𝑜

     Para gases ideales:


    𝑝𝑖 = 𝑦𝑖 . 𝑃𝑇
    Donde:
    𝑛𝑖
    𝑦𝑖 =
    𝑛𝑇
    0.09865
     𝑦𝑜 = = 0.489
    0.2014
    0.1027
     𝑦𝑂2 = = 0.510
    0.2014
    Luego, lo multiplicamos por la presión en el recipiente:
    - 0. 489 x 895 torr = 437.665
    - 0. 510 x 985 torr = 456.45
    Dividimos la 𝑃𝑜 = 760 𝑡𝑜𝑟𝑟
    (𝑃𝑂 /𝑃𝑜 )2
    𝐾𝑃𝑜 =
    𝑃𝑂2 /𝑃𝑜

    (456.45⁄760)2
    𝐾𝑃𝑜 = = 0.626
    437.67⁄760

    Por último, se calcula


    ∆𝐺° = −𝑅𝑇𝑙𝑛𝐾𝑃𝑜
    ∆𝐺° = −8,314 𝐽/𝑚𝑜𝑙. 𝐾 𝑥 3700 𝐾 𝑥 ln(0.626)
    ∆𝐺° = 14408. 97 ≈ 14 𝑘𝐽/𝑚𝑜𝑙

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