Chemistry 210.

002 Spring 2014
MWF 8:00 - 8:50 AM Neckers 240 Instructor: Kevin Smith Phone: 453-6471 Office: Neckers 285 e-mail: ksmith@chem.siu.edu Office Hours: Open door policy or by appointment

Silberberg 3rd Ed.

Textbook, i-clicker response pad, Calculator Required Lecture Materials: •Principles of General Chemistry, 3rd ed., Silberberg, McGraw Hill 2013. •An i-clicker RF response pad is also required. •CONNECT subscription •A scientific calculator with “log” function is required, no cell phones may be used as calculators.

5% 11.For all students enrolled in the Structured Learning Workshop (CHEM 212). A 85 – 100%. F 0 – 54% .6% 27. the final grade for both CHEM 210 and CHEM 212 will be based on the total points accumulated from the following sources: Structured Learning Workshop(CHEM 212) Assigned On-Line Homework Average i>clicker In-Class Response Average Exam Average Final Exam 10% 5% 10% 50% 25% For Engineering Majors who have been issued an override by the College of Engineering and are not registered for CHEM 212. the final grade for CHEM 210 will be based on the total points accumulated from the following sources (Note: withdrawal from CHEM 212 at any point during the semester will also result in the following grading scheme being utilized): Assigned On-Line Homework Average i>clicker In-Class Response Average Exam Average Final Exam 5.8% Grading: Letter grades will be assigned as follows. C 65 – 74%.1% 55. D 55 – 64%. B 75 – 84%.

Week of 1/13 M Ch 11 W Ch 11-12 F Ch 12 *tentative 1/20 1/27 2/03 2/10 2/17 2/24 3/03 3/10 MLK Day Ch 13 Ch 14 Ch 16 Ch 16 Ch 17 Exam 2 Ch 12 Ch 13 Ch 14 Ch 16 Ch 16-17 Ch 17 Ch 18 Spring Break Ch 12 Ch 13 Exam 1 Ch 16 Ch 17 Ch 17 Ch 18 3/17 3/24 3/31 4/07 4/14 Ch 18 Ch 19 Ch 19 Ch 20 Ch 21 Ch 18 Ch 19 Exam 3 Ch 20 Ch 21 Ch 18.19 Ch 19 Ch 20 Ch 21 Ch 23 4/21 4/28 5/05 Ch 23 Review Ch 23 Review Exam 4 Review Final Monday 7:50-9:50AM .

and a student ID. you can’t take the exam. Exams On exam day you will need a pencil (scantrons). If you are late. Tardiness Arriving late is considered a classroom disturbance. calculator (batteries). A second offense will not be tolerated. . Excessive tardiness will not be tolerated. email) may result in a class wide quiz. texting.Cell Phones Cell phones are considered a classroom disturbance. calls. any cell phone use in the classroom (rings.

If you have a question. Then…work more problems. Foreign language Come to lecture. Make a commitment. . so do others. Immediately after class. look over your notes. Ask questions. Free tutoring may be available. Work more problems. Work problems. during office hours or in lab. Exam review sessions. Form your own study groups. You are responsible for missed material Review notes. Spend 2 hours per credit hour.Tips for Success: Read the chapter before class. Ask in class. Fill in details while the topic is fresh.

online.siu.edu Network ID and password .

Course selection ? .

Use this part of the window to navigate through the different folders .

Homework is found under the “QUIZZES” tab .

210 HW Ch11-12 link .

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http://connect.mcgraw-hill.com/class/k_smith_chem_210_spring_2014 .

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Chapter 11 29 .

Orbitals? S P D F .

Valence electrons? O Lewis structures? H H2O Covalent bonds? .

Covalent bonds .

Hybridization? Be s p Hybridization s p sp Hybridized sp sp .

• The two unhybridized 2p-orbitals are perpendicular to the sp hybrid orbitals and to each other.• The two sp hybrid orbitals point in opposite directions. 34 .

Be (Z=4): [He]2s2 + 2Cl (Z=17 ):[Ne]3s23p5  BeCl2    Cl Be  sp-hybridize  Cl   Linear Hybridized Be:  sp __ __ + 2Cl:     .  BeCl2 2p 3s 3p Covalent bonds form from overlap of sp and p orbitals 35 .

 BF3 2p 2s 2p Covalent bonds form from overlap of sp2 and p orbitals 36 .B(Z=5): [He] 2s22p1 + 3F (Z=9 ):[He]2s22p5  BF3    F   sp2 -hybridize  B   F F     Hybridized B atom Trigonal planar Isolated B atom Hybridized B :    sp2 __ + 3F:     .

C (Z=6): [He] 2s22p2 + 4H (Z=1 ):1s1  CH4 H C sp3 -hybridize H H H tetrahedral Covalent bonds form from overlap of sp3 and s orbitals Hybridized C :     sp3 + 4H:   CH4 1s 37 .

sp3d and sp3d2 Hybridization. VB theory rationalizes the trigonal bipyramid and octahedral arrangements of five and six electron groups by mixing one 3s-orbital + three 3p-orbitals + one 3d-orbital = five sp3d hybrid orbitals P(Z=15): [Ne]3s23p3 + 5Cl (Z=17):[Ne]3s23p5  PCl5 Cl Cl P sp3d-hybridize Cl Cl Trigonal bipyramid Cl Covalent bond forms from overlap of sp3d and p orbitals Hybridized P :      __ __ __ __ + 5Cl:     .  PCl5 sp3d 3d 3s 3p 38 .

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