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this presentation
is probably too
long, select from:
z
z What
cont...
Agenda - Cont.
z
Do
Products?
Get
Crude
to
Separations
Chemical Reactions
Major Equipment
Minimizing Pollution
z What
Overview
IS TO TRANSFORM RELATIVELY
HIGH VALUE PRODUCTS AS
ENVIRONMENTALLY SOUND A
Overview - Cont.
price
quality crudes constantly
changing. The price and specifications of the
products is constantly changing. Government
regulations add additional constraints. There is
not much differential between the price of crude
and products.
d
d t
OK, But...
WHAT GOES ON IN AN OIL
REFINERY?
THE REFINERY
Very
Natura
lGas
Separation
s
RX
Polyethylene
Butane RX
(C
C10))
(C55 -- C
(C5 - C1010)
Naphtha
(Aspi
(B
(7 UP Bottles)
asolin
G
Organic
OrganicChemicals (Aspirin,eHair
X
Organic
Chemicals
(Aspirin,
Chemicals
Spray)
R
elmet, Astro
)
XX
RX
More Polymers
Kerosene &
Kerosene &
Gas Oils (C10+)
(Football
H Turf,
Nylon
Asphalt
RX = Chemical Reactions
Jet
Fuel
iesel Fuels
D
Home
Cok
(Carbon
e Material Similar to
Coal)
Gas
Stove
ad Bags)
Fue
arb
arbeque
l
Grills)
Propane &
Separations
and
Pur
ficatio
ns
Well
Crud
e
Co
versions
Oil
Ethylene
(Gl
Simplified
Petroleum
and
Petrochemi
cal
Flowchart
RX
Road
s
Pot
Holes
Heating Oil,
Lubricating
Oil, Wax
Fuel
Steel Making
Graphite
Fibers
(Tennis
Racquets)
(Propane/Butane)
z GASOLINE (hundreds of blends)
z JET FUELS
z DIESEL FUELS
z HEATING OILS
z GREASES
z ASPHALTS
z COKE (not the kind you drink )
Gasoline Specifications
Gasoline must meet many criteria
change withlocation. Some
the time of yearwhich
and geographic
critical specifications are:
z Vapor Pressure
z Octane
Aromatics / Benzene Content
z Sulfur Content
Gasolines are always a blend of a number of streams
in the refinery
z
Other Specifications
refinery
must
specifications such as:
z Cetane number
z Density
Pour Point
Flash Point
Viscosity
z
z
z
other
SEPARATIONS
SEPARATIONS C
z HUGE
CRUDE
AC O A O
FRACTIONATION
DISTILLATION COLUMNS
ATMOSPHERIC DISTILLATION
VACUUM DISTILLATION
z TYPICAL
SIZE: 1
z 750 DEGREES F
,000 ARRELS/DAY
OTHER SEPARATIONS
z
z DISTILLATION
z ABSORPTION
z ADSORPTION
z SETTLING
(WATER/OIL)
REACTIONS
REACTIONS
Almost all the reactions in the refinery use
special catalysts
increase
rate
selectivity of the reaction. This improves
reduces
efficiency
byproducts.
CAT CRACKING
heavy oil --> gasoline + propylene, butane,
other light ends
550 F
300 F
MINIMIZING POLLUTION
Furnaces
z Waste Material Goes To The Flare Stack
z Avoid Spills & Accidental Releases
z Special Treatment of Sewer Water
z Lots of Paper Work!
z
Sulfur
converted to elemental sulfur
in high sulfur fuel oil
in coke
WHAT ROLE DO
ENGINEERS
REFINERY?
PLAY
IN THE
REFINERY?
Engineer
z Maintenance Engineer
z Control Systems Engineer
z Design Engineer
z Health/Safety/Environmental
Engineer
z Planning / Scheduling Engineer
z
Engineer
z Plant Manager
rmation
training
z List books, articles, electronic sources
z Consulting services, other sources
z
Summary
are
complicated
processing plants that use reactions and
separations to
crude
into
gasoline and other valuable products
z Chemical engineers play an important role
in keeping these plants running safely and
efficiently
z