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DEFINITIONS,
CHARACTERISTICS AND
PERSPECTIVES
HYDROLOGIC CYCLE
Atmosphere
Condensation
Evaporation
Evapotranspiration
Earths surface
Surface runoff
Percolation
IMPURITIES IN WATER
1. Surface, or nuclei during condensation
2. Liquid water travels through the
remainder of the hydrologic cycle
contact with other material in air or
earth
3. Human activities industrial and
domestic waste
* Impurities can be both in suspended
and dissolved form
WATER QUALITY
Predicted on the intended use of the
water
Water pollution defined as the presence
in water of impurities in such quantity and
of such nature as to impair the use of the
water for a stated purpose
Standard method analytical procedures
to measure the impact of impurities on
water
PHYSICAL PARAMETERS
1. SUSPENDED SOLIDS
SOURCES
Natural contaminants resulting from the
erosive action of water flowing over
surfaces
Result from human use of water
domestic wastewater
Contain inorganic (clay, silt) or organic
(plant fibers, bacteria)particles,
immiscible liquids (oil and grease)
IMPACT
Aesthetically displeasing
Provide adsorption site for chemical
and biological agents
May be degraded biologically or may
include diseases-causing organisms
MEASUREMENT
Filtering the water, drying the residue
and filter to a constant weight at
104oC and lastly determine the mass
of the residue retained on the filter
2. TURBIDITY
A measure of the extent to which light is
either absorbed or scattered by suspended
material in water
Not a direct quantitative measurement of SS
SOURCES
results from the erosion of colloidal material
such as clay, silt, rock fragments, metal
oxides from the soil, vegetables fiber,
microorganism, soaps, detergent,
emulsifying agents
IMPACT
Aesthetically displeasing opaqueness
will appear
Provides adsorption sites for chemicals
and biological organism that may be
harmful or cause undesirable tastes and
odors
May interfere with light penetration and
photosynthetic reactions in streams and
lakes
MEASUREMENT
Measured photometrically by
determining the percentage of light of a
given intensity that is either absorbed
or scattered
Turbidity is a relative measure, not
absolute measures.
It is usually expressed as nephelometric
turbidity units (NTU) or as metres
depth. Other units, formazin turbidity
units (FTU) or Jackson turbidity units
(JTU)
USE
Made on clean
waters
3. COLOR
Apparent color color of water partly
due to suspended matter
True color color contributed by DS
SOURCES
Yellowish-brown water contact with
organic debris
Reddish cause by iron oxide
Brown/blackish manganese oxide
Industrial waste textile and dyeing
operations, food processing
IMPACT
Unsuitable for laundering, dyeing,
papermaking, dairy production
Affect the market of domestic and
industrial company
Organic compound reduce the
effectiveness of chlorine as
disinfectant
MEASUREMENT
Comparison with standardized colored
materials (unit used TCU)
IMPACT
Consumer associates T&O with
contamination
Organic substances carcinogenic
MEASUREMENT
Can be made if the causative agents
are known
Organic cause gas or liquid
chromatography
Qualitative test threshold odor
number (TON)
TON = (A + B)/A
Where A = volume of odorous water
(mL)
B = volume of odor-free water
required to produce a 200-mL
mixture
USE
Serves as guideline for potable water
TON of 3 recommended by the Public
Health Service
5. TEMPERATURE
Algae growth higher in
warm water, causes algae
mats secrete oil and
dead algae will causes
taste & odor prob.
Affect solubilities
of gases in water
Affect chemical
reaction rate
IMPACT OF
TEMPERATURE
Biological
activities higher
in higher T
1. TDS
2. ALKALINITY
3. HARDNESS
Amount of multivalent metallic cation in
water
Sum of Ca & Mg ions in water
Other ions very little Fe, Mn
IMPACT
4. FLUORIDE
Appears in groundwater in few
geographical regions
Toxic in high conc, beneficial in low
conc
1 mg/L help prevent dental cavities,
stronger teeth
>2 mg/L discoloration of teeth (mottling)
Higher conc bone fluorosis
5. METALS
NONTOXIC METAL
If exist in small amount Zn, Fe, Mn, Al
Ca and Mg hardness ions
Na most common
TOXIC
Mining and industrial industry
Ar, Ba, Cd, Pb, Hg goes up food
chain, greatest danger to top of chain
MEASUREMENT by AAS
6. NUTRIENTS
Nitrogen is often the limiting nutrient
in ocean waters and some streams
Can exist in numerous forms, but
most common are nitrate, nitrite,
ammonia
Sources are primarily from fertilizers
and acid deposition
7. ORGANICS
Soluble in water
Obtained from natural sources and
human activities
Categories of dissolved organic
Biodegradable
Nonbiodegradable
BOD CALCULATION
No. of STP
Total PE
Flow
(m3/day)
BOD Load
(kg/day)
Selangor
2,563
5,908,450
1,329,401
332,350.31
Perak
1,343
1,300,430
292,597
73,149.19
Johor
1010
1,198,417
269,644
67,410.96
Negeri Sembilan
928
931,458
209,578
52,394.51
Kedah
755
556,637
125,243
31,310.83
Melaka
725
570,192
128,293
32,073.30
Pulau Pinang
650
2,149,001
483,525
120,881.31
Pahang
486
314,830
70,837
17,709.19
WP Kuala Lumpur
299
2,571,877
578,672
144,668.08
Terengganu
224
75,184
16,916
4,229.10
Perlis
36
16,156
3,635
908.78
WP Labuan
32
39,265
8,835
2,208.66
72,833
16,387
4,096.86
9,060
15,704,730
3,533,563
883,391.08
WP Putrajaya
Total
Example 1: Determining
BOD5
The BOD of w/water is suspected to range from 50 to 200
mg/L. Three dilutions are prepared to cover this range. The
procedure is the same in each case. First the sample is
placed in the standard BOD bottle and is then diluted to 300
mL with organic-free, oxygen-saturated water. The initial
DO is determined and the bottles tightly stoppered and
placed in the incubator at 20oC for 5 days, after which the
DO is again determined.
Given:
DOf (mg/L)
0.005
9.2
6.9
0.010
9.1
4.4
0.020
8.9
1.5
7.2 NONBIODEGRADABLE
ORGANIC
Some organics materials are resistant to
biological degradation tannic and lignic
acid, cellulose,phenols
Polysaccharides (strong bond) and benzene
(ringed struct) are also nonbiodegradable
e.g detergent compound ABS
Insecticide, herbicide, pesticide accumulate
to top food chain, can cause extinction of
animal species
1.1 BACTERIA
1.2 VIRUSES
1.3 PROTOZOA
1.4 HELMINTHS
BOD
COD
Ammonical nitrogen
pH
DO
SS
Optional heavy metals and bacteria
WQI - continuous
Is used to relate a group of variables to a
common scale
Varies with changes in parameters values
that would be indicative of changes in the
quality of waters
WQI system and parameters vary from
country to country
Measures general water quality conditions
and does not reflect the presence of toxic
compounds or specific toxic conditions
TUTORIAL
2.4, 2.8, 2.24, 2.31, 2.43 and 2.44