Four types of synthesis

perovskite
1. Single step

2. Two step
3. deposition
4. Vacuum
VASP

Single
Step
No

Title of Journal/Year

1.

2.

3.
4.
5.

6.

7.

8.

Organometal Halide
Perovskites as Visible-Light
Sensitizers for Photovoltaic
Cells 2009

All-solid-state hybrid solar

cells based on a new
organometal halide
perovskite sensitizer and
one-dimensional TiO2

Mesoscopic CH3NH3PbI3/TiO2
nanowire
arrays Solar Cells
Heterojunction
6.5% efficient perovskite
quantum- dot-sensitized
solar Iodide
cell
Lead
Perovskite
Sensitized All-Solid-State
Submicron Thin Film
Mesoscopic Solar Cell with
Efficiency
Exceeding
9%
Effect of Different
Hole
Transport
Materials on Recombination
in CH3NH3PbI3 Perovskite
Sensitized
CH 3 NH 3 PbI 3
Mesoscopic
Solar Cells
Perovskite/Fullerene
Planar-Heterojunction

Perovskite-Based Hybrid Solar

Hybrid Solar Cells
Cells

Thickness
Publication
JACS

Author Effieciency
s
[1]

TiO2

Br=3.1
l=3.8

RSC

[2]

Br=4.87

JACS

[3]

5.5

RSC

[4]

6.5

NATURE

[5]

9.7

12 m
8 m
~1.5
m

40
0
nm
3.6
m
0.6
m-

Perovs
kit e

Jsc
mA
cm2,

Voc
V

FF

IPCE

5.57

0.96 0.59 65%

11.0

0.61 0.57 45%

10.1
2

0.82 0.59

16.1

0.63 0.57 90%

15.8
2
17.6

0.70 0.58 78.6

6

0.88 0.62 50%

8

JACS

[6]

SpirOMeOTAD=8.5

Advanced Materials

[7]

Note below

10.3
2

Advanced Materials

[8]

10.8

21.3

500n
m

0.93 0.54

22
4

Exceeding 10%
Effi ciency with High
Reproducibility
Using a Thin Film
SandwichHybrid
Approach
9. Efficient
Solar Cells
Based on MesoSuperstructured
Organometal Halide
Perovskites
10 Additive
Enhanced
.
Crystallization of
Solution-Processed

AAAS

[9]

10.9

17.8

1.8
Advanced Material

[10]

11.8

NATURE

[11]

12

RSC

[12]

12.3

AAAS

[13]

19.3

~150
nm
300500
nm

7.13

0.98 0.63 >80

%
0.64 0.4

17.5

0.92 0.73 11.8

16.5

0.99
7

18

1.02 0.67

22.75

1.13227755.0
7755. 75.01
.
01

Perovskite for Highly Effi cient

11 PlanarEfficient inorganicorganic
Heterojunction
.
hybrid heterojunction
Solar cells
Cells containing
solar
perovskite compound and
polymeric hole
conductors
12 Low-temperature
processed
.
meso- superstructured to
thin-film perovskite solar
cells
13 Interface
engineering of
.
highly efficient perovskite
solar cells 2014
No
29

Title
Efficient Hybrid Solar Cells Based on
Meso- Superstructured Organometal
Halide Perovskites

~40
0
nm

Jsc (mA
2)
1.8 cm
7.13

Voc (V) FF
0.64
0.4

10.9 17.8

0.98

Thickness of perovskite = ~
150nm

0.63
With MSSC (Al2O3)

0.727

~71

30

Additive Enhanced Crystallization of

Solution- Processed Perovskite for
Highly Effi cient Planar- Heterojunction
Solar Cells

31

Low-temperature processed mesosuperstructured to thin-film perovskite

solar
cells Low Temperature Processing
A
One-Step
Route for
Organolead Halide Perovskite Solar Cells

32

7.9 15.0
10.3 15.6

0.90
0.92

0.58 Pristine provskite with ITO

0.71 Perovskit with IDO ito

9.0

0.90

0.62 e
Pristine
perov
+ FTO
Perovskite
with
IDO + FTO

16.0

11.8 17.5
12.3 18.0

0.92
1.02

7.2

0.925

12.78

0.73
0.67 Perovskite with 400nm
scaffold
0.61

Two step
Deposition
No

Title of Journal/Year

Thickness
Publication

Authors

Effieciency TiO2 Perovskite Jsc

mA
cm2,

1.

2.

Using a two-step
deposition technique
to prepare
perovskite (CH3NH3PbI3)
for thin film solar cells
based
on ZrO2 and TiO2
Depletion
region effect of
mesostructures
highly efficient hole
conductor free
CH3NH3PbI3

RSC

RSC

[14]

[15]

Voc
V

FF

ZnO2 =
10.8%

17.3 1.07 0.59

TiO2 =
9.5%

18.3 0.89

0.58

10.85

19

68%,

0.84

IPCE

3.

4.
5.

6.

perovskite solar cells

Inorganic hole conductorbased
lead
halide
perovskite solar cells with
12.4%
conversion
Compact
Layer Free
efficiency
Perovskite
Solar Cells with
13.5%as a
Sequential
deposition
Efficiency
route
to high-performance
perovskite-sensitized solar
cells
Modified
Two-step Deposition
Method for
High-Efficiency
TiO2/CH3NH3PbI3

19.7

1.016

NATURE

[16]

12.4

JACS

[17]

13.5

NATURE

[18]

15

20.0 0.99 0.73

3

10.47

16.0 0.94 0.69

8

JACS

0.62

Heterojunction

Solar Cells
23
25
26

27
28

FTO/blTiO2/PSCs 1 /HTM/Gold
FTO/blTiO2/ PSCs 5 /HTM/Gold

FTO/blTiO2/PSCs
1/HTM[1]
FTO/blTiO22/nc
FTO/clTiO
/PSCs
TiO2/CH3NH3PbI3/P3HT/carbon
5/HTM
No compact layer
20nm
90 nm
180nm
390nm
FTO/gTiO2/Al2O3/PSCs/spiro/Au
Use grapheme low temp

FTO/cTiO2/mpTiO2/PbI2/HC(NH2)2I

4.2
12.2
4.2
12.2

13.2
17.9
13.2
17.9

0.71
0.97
0.71
0.97

0.45
0.70
0.45
0.70

1.34
1.65
3.17
2.87
1.93

5.59
6.73
12.18
9.88
9.29

0.87
0.92
0.93
0.87
0.89

0.274
0.266
0.279
0.335

15.6

21.9

1.05

0.74

4.30

6.45

0.97

0.687

0.232

Vacuum
Deposition
No

Title of Journal/Year

Publication

Authors

Effiecienc TiO2 Perovskit Jsc

mA
y
e

Voc
V

FF

[19]

15.4

21.5

1.07

0.67

(Sarkar,
2014)

7.3

14.2

0.78
6

0.65

Voc
V

FF

0.92
4

66.3

cm2,

1.

2.

Efficient planar
NATURE
heterojunction
perovskite solar cells
Inorganic
Hole Conducting Layers JACS
by vapour deposition
for

IPCE

Perovskite-Based Solar Cells

Vapor Assisted Solution Process

No

Title of Journal/Year

Publication

Authors

Effiecienc TiO2
y

Planar Heterojunction Perovskite

Solar
Cells via Vapor-Assisted
Solution Process

JACS

[20]

12.1

(VASP)
1.

Perovskit Jsc
mA
e

cm2,

19.8

IPCE

No 7

Device
Perovskite/ C 60
(30 nm) a)
Perovskite/
PCBM (25 nm)
a)
Perovskite/
ICBA (30 nm)
a)
Perovskite/
ICBA (30 nm)
b)
Perovskite(DMF)
/
C 60 (30 nm) a)
Perovskite(DM
F)/ PCBM (25
nm) a)
Perovskite(DMF)
/
ICBA (30 nm) a)

VO
C
[V]
0.55

JSC
[mA/cm 2 ]

FF

5.21

0.57

0.65

5.89

0.63

PC
E
[%
1.6
]
2.4

0.75

5.44

0.51

2.1

0.62

3.17

0.62

2.5

0.55

9.02

0.61

3.0

0.60

10.32

0.63

3.9

0.58

10.03

0.58

3.4

[1] K.T. Akihiro Kojima, Yasuo Shirai, and Tsutomu Miyasaka, Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells.

[2] Y.Q. Jianhang Qiu, Keyou Yan, Min Zhong, Cheng Mu, He Yan, Shihe Yang, All-solid-state hybrid solar cells based on a new
organometal halide perovskite sensitizer and one-dimensional TiO2 nanowire arrays, (2013).
copic CH3NH3PbI3/TiO2
Heterojunction Solar Cells.
[4] C.-R.L. Jeong-Hyeok Im, Jin-Wook Lee, Sang-Won Park and Nam-Gyu Park, 6.5% efficient perovskite quantum-dot-sensitized solar cell.

[5] C.-R.L. Hui-Seon Kim, Jeong-Hyeok Im, Ki-Beom Lee, Thomas Moehl, Arianna Marchioro,Soo-Jin Moon, Robin HumphryBaker, Jun-Ho Yum, Jacques E. Moser, Michael Gratzel & Nam-Gyu Park, Lead Iodide Perovskite Sensitized All-Solid-State
Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%.
[6] L.Y. Dongqin Bi, Gerrit Boschloo, Anders Hagfeldt, and Erik M. J. Johansson, Effect of Different Hole Transport Materials on
Recombination in
CH3NH3PbI3 Perovskite-Sensitized Mesoscopic Solar Cells.
8
p
D D
J DH
J n Manca , and Hans-Gerd Boyen, Perovskite-Based Hybrid Solar Cells
[7] J.e. al, CH 3 NH 3 PbI 3 Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells.
Efficiency with High Reproducibility Using a Thin Film Sandwich Approach.
bb
Exceeding 10%

[9] J.T. Michael M. Lee, Tsutomu Miyasaka,Takurou N. Murakami, Henry J. Snaith, Efficient Hybrid Solar Cells Based on MesoSuperstructured Organometal
Halide Perovskites.

[10] C.-Y.L. Po-Wei Liang , Chu-Chen Chueh , Fan Zuo , Spencer T. Williams ,, J.L. Xu-Kai Xin , and Alex K.-Y. Jen, Additive
Enhanced Crystallization of Solution- Processed Perovskite for Highly Effi cient Planar-Heterojunction Solar Cells.
[11] S.H.I. Jin Hyuck Heo, Jun Hong Noh, Tarak N. Mandal, Choong-Sun Lim, Jeong Ah Chang, Yong Hui Lee, Hi-jung Kim,
Arpita Sarkar, Md. K. Nazeeruddin, Michael Gratzeland Sang Il Seok, Efficient inorganicorganic hybrid heterojunction solar
cells containing perovskite compound and polymeric hole conductors.
[12] M.M.L. James M. Ball, Andrew Hey and Henry J. Snaith, Low-temperature processed meso-superstructured to thin-film
perovskite solar cells.
[13] Q.C. Huanping Zhou, Gang Li, Song Luo, Tze-bing Song, Hsin-Sheng Duan, Ziruo Hong, Jingbi You, Yongsheng Liu,
Yang Yang, Interface engineering of highly efficient perovskite solar cells.
[14] S.-J.M. Dongqin Bi, Leif Haggman,Gerrit Boschloo,Lei Yang,Erik M. J. Johansson, Mohammad K. Nazeeruddin, Michael
Gratzelb
andCH3NH3PbI3
Anders Hagfeldt,
Using
two-step
deposition technique to prepare perovskite (CH3NH3PbI3) for thin film
conductor free
perovskite
solara cells,
(2014).
solar
cells
based
on
ZrO2
and
TiO2
mesostructures.
[16] S.T. Peng Qin, Seigo Ito, Nicolas Tetreault, Kyohei Manabe, Hitoshi Nishino,, M.K.N.M. Gratzel, the
[15]
S.G. Sigalit
Aharon,
Bat El
Cohen and Lioz Etgar, Depletion region effect of highly efficient hole
mesoporous
TiO2
films were
heated
using a hot plate at 70 C, Inorganic hole conductor-based lead
halide
perovskite solar cells with 12.4%
conversion

efficiency.

[17] J.Y. Dianyi Liu, and Timothy L. Kelly, Compact Layer Free Perovskite Solar Cells with 13.5% Efficiency.
[18] N.P. Julian Burschka, Soo-Jin Moon, Robin Humphry-Baker, Peng Gao, Mohammad K. Nazeeruddin, M. Gratzel,
Sequential deposition as a route to high-performance perovskite-sensitized solar cells.
[19] M.B.J.H.J.S. Mingzhen Liu, Efficient planar heterojunction perovskite solar cells by vapour deposition.
[20] H.Z. Qi Chen, Ziruo Hong, Song Luo, Hsin-Sheng Duan,Hsin-Hua Wang, Yongsheng Liu, Gang Li, and Yang Yang, Planar Heterojunction
Perovskite Solar

Cells via Vapor-Assisted Solution Process.