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Examen 6 ETS 10/01/2012

Martnez Medina Luis Fernando


Solucion ETS 10/01/2012
Reaccin: WO2(s)+2H2W(s)+2H2O(g)

Datos:
T=1150K
Presencia de Hidrogeno
Calcular: de H , Kg, W

Realizar el balance:

i i ni ni =ni + i
WO2(s) -1 x x-
H2(g) -2 1 1-2
W(s) 1 0
H2O(g) 2 0 2
Total 0 1+x 1+x
Convirtiendo:
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4Kg H2 =1Kmol H2
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R,T=2(-58900+13.1T)-(-131600+36.6T)

1380010.4
R,T=13800-10.4T si ln(Keq)= - Ln(Keq)=-( )
1.987

1380010.4 1150
( )
Keq= 1.987 1150 = Keq=0.4470

Utilizando la ecuacin:

2 2 1
Keq= ( )
12 2 1+
Substituyendo Keq=0.4470

2 2
Keq=0.4470=
12 2

Despejando . =0.2003kmol

183.85
Kg*W=0.2003Kmol( )=36Kg
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=conversin ; ( H)= conversin de Hidrogeno

Substituyendo

(1)(0.2003)
=- x100= ; = 100 = 20.03%
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