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Rmf Rw
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Computation of Liquid-Liquid Junction Potential
v u RT C1
ED ln
vu nF C2
Let t = 25 C, so T = 298 K : R = 8.314 Joules : F = 96540 Coulombs
[ Rw] C1 = 100 Kppm [ Rmf] C2 = 10 Kppm n=1
v = mobility of Cl- = 67.6 x 10-5 cm/sec/volt
u = mobility of Na+ = 45.6 x 10-5 cm/sec/volt
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Calculate Membrane Potential Example
RT C1 C1
Em ln 59.1log 59.1 millivolts
nF C2 C2
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Streaming or Electro-kinetic Potential
SP
Bed boundary
picked on
inflection point
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(–) (+) Shallow
SP Behavior Over
a Long Log Very fresh
in Fresh Mud
• SP deflection Fresh Rmf = Rw
direction and magnitude is
dependent upon relationship
and magnitude of Rw and Rmf
Salty
Very salty
Deep
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(–) (+) Shallow
SP Behavior Over
a Long Log Very fresh
in Salty Mud
• SP deflection Fresh
direction and magnitude is
dependent upon relationship
and magnitude of Rw and Rmf
Salty Rmf = Rw
Very salty
Deep
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Shape of the SP Curve
• Sharpness of SP curve at bed boundary,
and therefore vertical resolution,
depends on pattern of current flows
at bed boundary
• This is a complicated function of:
– Relative resistivities of:
• Mud
• Invaded zone
• Undisturbed zone
• Shale
– Hole diameter
– Depth of invasion
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Rw from SP
SP amplitude at
maximum
deflection
(cleanest rock)
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Computation of Rw from SP
1. Read SP value from log SSP = – 68 mv at 4,170 ft
• Relative difference between shale line
and maximum sand deflection
• WATCH THE SIGN!
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Computation of Rw from SP
5. Convert Rwe to Rw using
• Schlumberger Chart SP-2 or
• Baker Atlas Chart 3-3 or
• Halliburton Chart SP-3
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Rw
from Rwe
Rwe at 129°F
= 0.048 ohm-m
Rw at 129°F
= 0.063 ohm-m
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Formation Water
Salinity, Resistivity & Temperature
conc(NaCl) = conc(Cl-)x 1.65
Rw (ohm-m) = 1000 / Cw (mmho/m)
NaCl Cw Rw
Temperature Cw Rw
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