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The Atom

Development of Atomic Theory

Philosophical Ideas of Atoms




Democritus called natures basic particle an atom, Greek word that means indivisible

Aristotle believed in the continuity of matter there is no limit to subdividing matter.

Both remained speculations as no experimental evidence were presented until 2000 years later, scientists began to gather evidence favoring the atomic theory of matter

John Dalton - Early 1800s




Conservation of Matter Mass is conserved in a reaction. The amount you begin with is equal to the amount you end up with.

Daltons Theory The Pool Ball (Billiard Ball) Model


      

All matter is made up of atoms. Atoms are tiny, indivisible, indestructible, fundamental particles. Atoms cannot be created or destroyed. Atoms of a particular element are alike. Atoms of different elements are different. A chemical change involves the union or separation of individual atoms.

Problems with Pool Ball Model


 

Doesnt explain bonding. Doesnt explain ions Michael Farraday demonstrated that some matter can be charged or can carry a charge.

Michael Faraday


When certain substances are dissolved in water, they conduct electricity. Certain compounds decompose into their elements when current is passed through them. Atoms of some elements are then attracted to the negative electrode, others to the positive electrode.

J. J. Thompsons Plum Pudding Model


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Cathode Ray Tube Experiments A charge was applied across a tube filled with various gases or a vacuum. Tiny charges flowed out of the cathode (-) and traveled towards the anode(+). These particles were negatively charged. Where were they coming from?

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J.J.Thompsons Plum Pudding Model


- - - n

Tiny, negatively charged particles which Thompson called corpuscles and are now known as electrons were imbedded in a positive mass, like raisins in a plum pudding.

Rutherfords Scattering Experiment

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Rutherford shot alpha particles (+ charged, 7000x the mass of an electron) at gold foil. Prediction - They would go straight through. Results - The particles were scattered, sometimes at wide angles.

Rutherfords Findings Based on his Alpha Scattering Experiment




Rutherford found that the atom contains a tiny nucleus The nucleus has all the positive charge of the atom The nucleus has most of the mass of the atom The diameter of the atom is 100,000 times more than that of the nucleus (the atom is mostly empty space)

 

Rutherford wrote -----Scattered! It was as if you fired a 15 inch shell at a piece of tissue paper, and the shell bounced back and hit you. Rutherfords new evidence allowed him to propose a more detailed model with a central nucleus.

The Neutron


Discovered by James Chadwick in 1932 About the same mass as a proton No charge (neutral)

Proton

Neutron

Electron(-)

Inside the Atom




atoms are composed of particles like neutrons, electrons, and protons

The electron always has a "-" or negative charge. The proton always has a "+" or positive charge. If the charge of an entire atom is "0", that means there are equal numbers of positive and negative particles, equal numbers of electrons and protons. The third particle is the neutron. It has a neutral charge (a charge of zero).

Other sub-atomic particles


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are even smaller particles moving around in atoms. These super-small particles can be found inside the protons and neutrons. Scientists have many names for those pieces, but you may have heard of nucleons and quarks.

Selected Properties of the Three Basic Subatomic Particles


Name Electron (e) Proton (p) Neutron (n) Charge Mass(amu) -1 +1 0 5.4 x 10-4 1.00 1.00 Mass(g) 9.1095 x 10-28 1.6725 x 10-24 1.6750 x 10-24

There are over 100 elements in the periodic table. The thing that makes each of those elements different is the number of electrons, protons, and neutrons. The protons and neutrons are always in the center of the atom. Scientists call the center of the atom the nucleus. The electrons are always found whizzing around the center in areas called orbitals.

It is the number of protons that determines the atomic number, e.g., H = 1. The number of protons in an element is constant (e.g., H=1, Ur=92) but neutron number may vary, so mass number (protons + neutrons) may vary.

Calculate the numbers of protons, neutrons, and electrons in an atom of fluorine. The atomic symbol for the fluorine atom is 199F. Solution: Step 1. The mass number tells us that the total number of protons + neutrons is 19. Step 2. The atomic number, 9, represents the number of protons. Step 3. The difference, 19 9, or 10, is the number of neutrons. Step 4. The number of electrons must be the same as the number of protons, hence, 9, for a neutral fluorine atom.


Determining the Composition of an Atom

Practice on the board




Calculate the number of protons, neutrons, and electrons in each of the following atoms: sulphur, sodium, plutonium, potassium

Seatwork
Answer the following: 2.31 2.33 a-b, 2.35 a-b, 2.36 a-b 2.41 On page 77 *Describe the properties of protons, electrons, and neutrons. *Briefly describe Rutherfords alpha scattering experiment his findings and how he interpreted them.


Isotopes


Atoms of the same element can have different numbers of neutrons; the different possible versions of each element are called isotopes. For example, the most common isotope of hydrogen has no neutrons at all; there's also a hydrogen isotope called deuterium, with one neutron, and another, tritium, with two neutrons.

Hydrogen

Deuterium

Tritium

Isotopes are often written with the name of the element followed by the mass number. For example, the isotopes 126C and 146C may be written as carbon-12 (or C-12) and carbon-14 (or C-14) respectively. The existence of isotopes explains why the average masses, measured in atomic mass units (amu), of the various elements are not whole numbers. This is contrary to what we would expect from proton and neutron masses, which are very close to unity.

Uses of Isotopes


Certain isotopes (radioactive isotopes) of elements emit particles and energy that can be used to trace the behavior of biochemical systems.

What are Ions?




Electrically charged particles that result from a gain of one or more electrons by the parent atom (forming negative ions, or anions) or a loss of one or more electrons from the parent atom (forming positive ions, or cations).

Formation of Ions
 199F

+ 1e23

19

F9

 2311Na

Na + 1e11

Determining Atomic Mass


 

Page 45/Example 2.2 Calculate the atomic mass of naturally occurring chlorine if 75.77% of chlorine atoms are 3517Cl (chlorine-35) and 24.23% of chlorine atoms are 3717Cl (chlorine-37).

Solution
Step 1. Convert each percentage to a decimal fraction. 75.77% = 0.7577 and 24.23% = 0.2423 Step 2. Multiply the decimal fraction by the mass of that isotope 0.7577 x 35 = 26.52 a.m.u 0.2423 x 37 = 8.965 amu Step 3. Get the sum 26.52 amu + 8.965 amu = 35.49 amu

Board Exercises
 

2.2 on page 46 2.29 on page 77

Homework
   

Answer 2.16 page 77 2.26 2.27 2.30

Inadequacies of Rutherfords Model of the Atom




First, he could not explain the composition of what he called the nucleus. Although he said that most of the atoms mass and positive charges were to be concentrated into this very small and dense area called the nucleus, he could not explain what was in the nucleus. (The existence of protons and neutrons were not known at the time).

The biggest problem that Rutherford failed to explain was how the negative electrons could stay away from the positive nucleus without collapsing into it.

Although he proposed that the electrons should be placed around the nucleus, he did not know how exactly to arrange the electrons around the nucleus, except like planets around the Sun. We will address this problem when we study Bohrs atom.