Professional Documents
Culture Documents
For information
ISO/TC 70/SC 8
N 545
N/A
Date: 2012-06-13
Reciprocating internal combustion engines Exhaust emission measurement Part 5: Test fuels
Moteurs alternatifs combustion interne Mesurage des missions de gaz d'chappement Partie 5: Carburants d'essai
Warning This document is not an ISO International Standard. It is distributed for review and comment. It is subject to change without notice and may not be referred to as an International Standard. Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are aware and to provide supporting documentation.
Document type: International Standard Document subtype: Amendment Document stage: (20) Preparatory Document language: E C:\Documents and Version 2.4e - RC2 Settings\smithchr\Desktop\N545_ISO_8178-5_NP_DRAFT_2012-06.doc.doc STD
N/A
Copyright notice
This ISO document is a working draft or committee draft and is copyright-protected by ISO. While the reproduction of working drafts or committee drafts in any form for use by participants in the ISO standards development process is permitted without prior permission from ISO, neither this document nor any extract from it may be reproduced, stored or transmitted in any form for any other purpose without prior written permission from ISO. Requests for permission to reproduce this document for the purpose of selling it should be addressed as shown below or to ISO's member body in the country of the requester: ISO copyright office Case postale 56 CH-1211 Geneva 20 Tel. + 41 22 749 01 11 Fax + 41 22 749 09 47 E-mail copyright@iso.org Web www.iso.org Reproduction for sales purposes may be subject to royalty payments or a licensing agreement. Violators may be prosecuted.
ii
N/A
Contents
Page
Foreword .............................................................................................................................................................v Introduction........................................................................................................................................................vi 1 2 3 3.1 3.2 3.3 3.4 3.5 3.6 3.7 3.8 3.9 4 5 5.1 5.2 5.2.1 5.2.2 5.2.3 5.3 6 6.1 6.1.1 6.1.2 6.2 6.2.1 6.2.2 6.3 6.3.1 6.3.2 6.4 6.4.1 6.4.2 6.5 6.6 6.7 6.8 6.9 Scope ......................................................................................................................................................1 Normative references............................................................................................................................1 Terms and definitions ...........................................................................................................................3 Carbon residue ......................................................................................................................................3 Cetane index ..........................................................................................................................................3 Cetane number ......................................................................................................................................3 Crude oil .................................................................................................................................................4 Diesel fuel...............................................................................................................................................4 Diesel index............................................................................................................................................4 Liquefied petroleum gas .......................................................................................................................4 Octane number ......................................................................................................................................4 Oxygenate ..............................................................................................................................................4 Symbols and abbreviated terms ..........................................................................................................4 Choice of fuel.........................................................................................................................................5 General ...................................................................................................................................................5 Influence of fuel properties on emissions from compression ignition engines.............................6 Fuel sulfur ..............................................................................................................................................6 Specific considerations for marine fuels ............................................................................................8 Other fuel properties .............................................................................................................................8 Influence of fuel properties on emissions from spark ignition engines..........................................9 Overview of fuels.................................................................................................................................10 Natural Gas ..........................................................................................................................................10 Referenced natural gas.......................................................................................................................10 Non-referenced natural gas................................................................................................................10 Liquefied petroleum gas .....................................................................................................................10 Referenced liquefied petroleum gas .................................................................................................10 Non-referenced liquefied petroleum gas ..........................................................................................10 Engine gasolines .................................................................................................................................10 Referenced engine gasolines.............................................................................................................10 Non-referenced engine gasolines......................................................................................................10 Diesel fuels...........................................................................................................................................11 Diesel reference fuels .........................................................................................................................11 Non-referenced diesel fuels ...............................................................................................................11 Distillate fuel oils .................................................................................................................................11 Residual fuel oils .................................................................................................................................11 Crude oil ...............................................................................................................................................12 Alternative fuels...................................................................................................................................12 Requirements and additional information ........................................................................................12
Annex A (informative) Calculation of the fuel specific factors.....................................................................28 A.1 Fuel specific factors............................................................................................................................28 A.2 Estimation of the fuel composition without elemental analysis.....................................................31 A.2.1 Method 1 ...............................................................................................................................................31 A.2.2 Method 2 ...............................................................................................................................................31 A.2.3 Method 3 ...............................................................................................................................................31 A.3 Ignition quality .....................................................................................................................................32 A.3.1 Application ...........................................................................................................................................32
iii
N/A
A.3.2
Annex B (informative) Equivalent non-ISO test methods ............................................................................ 34 Annex C (informative) Organizations capable of providing specifications for commercial fuels ........... 36 Bibliography ..................................................................................................................................................... 37
iv
N/A
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 8178-5 was prepared by Technical Committee ISO/TC 70, Reciprocating internal combustion engines, Subcommittee SC 8, Exhaust emission measurement. This third edition cancels and replaces the second edition (ISO 8178-5:2008) which has been technically revised. ISO 8178 consists of the following parts, under the general title Reciprocating internal combustion engines Exhaust emission measurement: Part 1: Test-bed measurement of gaseous and particulate exhaust emissions Part 2: Measurement of gaseous and particulate exhaust emissions under field conditions Part 3: Definitions and methods of measurement of exhaust gas smoke under steady-state conditions Part 4: Steady-state test cycles for different engine applications Part 5: Test fuels Part 6: Report of measuring results and test Part 7: Engine family determination Part 8: Engine group determination Part 9: Test cycles and test procedures for test bed measurement of exhaust gas smoke emissions from compression ignition engines operating under transient conditions Part 10: Test cycles and test procedures for field measurement of exhaust gas smoke emissions from compression ignition engines operating under transient conditions Part 11: Test-bed measurement of gaseous and particulate exhaust emissions from engines used in nonroad mobile machinery under transient test conditions
N/A
Introduction
In comparison with engines for on-road applications, engines for off-road use are made in a much wider range of power output and configuration and are used in a great number of different applications. Since fuel properties vary widely from country to country a broad range of different fuels is listed in this part of ISO 8178 both reference fuels and commercial fuels. Reference fuels are usually representative of specific commercial fuels but with considerably tighter specifications. Their use is primarily recommended for test bed measurements described in ISO 8178-1 and ISO 8178-11. For measurements typically at site where emissions with commercial fuels, whether listed or not in this part of ISO 8178 are to be determined, uniform analytical data sheets (see Clause 5) are recommended for the determination of the fuel properties to be declared with the exhaust emission results.
vi
N/A
Reciprocating internal combustion engines Exhaust emission measurement Part 5: Test fuels
Scope
This part of ISO 8178 specifies fuels whose use is recommended for performing the exhaust emission test cycles given in ISO 8178-4 and ISO 8178-11. It is applicable to reciprocating internal combustion engines for mobile, transportable and stationary installations excluding engines for engine vehicles primarily designed for road use. This part of ISO 8178 may be applied to engines used, e.g. earth-moving machines and generating sets, and for other applications.
Normative references
The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 2160:1998, Petroleum products Corrosiveness to copper Copper strip test ISO 2719:2002, Determination of flash point Pensky-Martens closed cup method ISO 3007:1999, Petroleum products and crude petroleum Determination of vapour pressure Reid Method ISO 3015:1992, Petroleum products Determination of cloud point ISO 3016:1994, Petroleum products Determination of pour point ISO 3104:1994, Petroleum products Transparent and opaque liquids Determination of kinematic viscosity and calculation of dynamic viscosity ISO 3105:1994, Glass capillary kinematic viscometers Specifications and operating instructions ISO 3405:2011, Petroleum products Determination of distillation characteristics at atmospheric pressure ISO 3675:1998, Crude petroleum and liquid petroleum products Laboratory determination of density or relative density Hydrometer method ISO 3733:1999, Petroleum products and bituminous materials Determination of water Distillation method ISO 3735:1999, Crude petroleum and fuel oils Determination of sediment Extraction method ISO 3830:1993, Petroleum products Determination of lead content of gasoline Iodine monochloride Method ISO 3837:1993, Liquid petroleum products Determination of hydrocarbon types Fluorescent indicator absorption method ISO 3993:1984, Liquefied petroleum gas and light hydrocarbons Determination of density or relative
N/A
density Pressure hydrometer method ISO 4256:1996, Liquefied petroleum gases Determination of gauge vapour pressure LPG method ISO 4260:1987, Petroleum products and hydrocarbons Determination of sulfur content Wickbold combustion method ISO 4262:1993, Petroleum products Determination of carbon residue Ramsbottom method ISO 4264:2007, Petroleum products Calculation of cetane index of middle-distillate fuels by the four-variable equation ISO 5163:2005, Petroleum products Determination of knock characteristics of engine and aviation fuels Engine method ISO 5164:2005, Petroleum products Determination of knock characteristics of engine fuels Research Method ISO 5165:1998, Petroleum products Determination of the ignition quality of diesel fuels Cetane engine Method ISO 6245:2001, Petroleum products Determination of ash ISO 6246:1995, Petroleum products Gum content of light and middle distillate fuels Jet evaporation Method ISO 6326-5:1989, Natural gas Determination of sulfur compounds Part 5: Lingener combustion method ISO 6615:1993, Petroleum products Determination of carbon residue Conradson method ISO 6974 (all parts), Natural gas Determination of composition with defined uncertainty by gas Chromatography ISO 7536:1994, Petroleum products Determination of oxidation stability of gasoline Induction period Method ISO 7941:1988, Commercial proprane and butane Analysis by gas chromatography ISO 8178-1:2006, Reciprocating internal combustion engines Exhaust emission measurement Part 1: Test-bed measurement of gaseous and particulate exhaust emissions ISO 8216-1:2010, Petroleum products Fuels (class F) Classification Part 1: Categories of marine Fuels ISO 8217:2010, Petroleum products Fuels (class F) Specifications of marine fuels ISO 8691:1994, Petroleum products Low levels of vanadium in liquid fuels Determination by flameless atomic absorption spectrometry after ashing ISO 8754:2003, Petroleum products Determination of sulfur content Energy-dispersive X-ray fluorescence spectrometry ISO 8973:1997, Liquefied petroleum gases Calculation for density and vapour pressure ISO 10307-1, Petroleum products Total sediment in residual fuel oils Part 1: Determination by hot Filtration ISO 10307-2, Petroleum products Total sediment in residual fuel oils Part 2: Determination using standard procedures for ageing
N/A
ISO 10370, Petroleum products Determination of carbon residue Micro method ISO 10478:1994, Petroleum products Determination of aluminium and silicon in fuel oils Inductively coupled plasma emission and atomic absorption spectroscopy methods ISO 13757:1996, Liquefied petroleum gases Determination of oily residues High-temperature method ISO 14597:1997, Petroleum products Determination of vanadium and nickel content Wavelengthdispersive X-ray fluorescence spectrometry EN 116:1997, Diesel and domestic heating fuels Determination of cold filter plugging point EN 238:1996, Liquid petroleum products Determination of the benzene content by infrared spectrometry
For the purposes of document, the following terms and definitions apply. NOTE
Also see any applicable definitions contained in the standards listed in the tables in Annex B.
N/A
3.9 Oxygenate
Oxygen containing organic compound which may be used as a fuel or fuel supplement, such as various alcohols and ethers.
The symbols and abbreviations used in this part of ISO 8178 are identical with those given in ISO 8178-1:2006 (Clause 4 and Annex A). Those which are essential for this part of ISO 8178 are repeated below in order to facilitate comprehension.
N/A
Symbol SI
Definition Excess air factor (in kilogrammes dry air per kilogramme of fuel) Fuel specific factor for exhaust flow calculation on wet basis Fuel specific factor for the carbon balance calculation Intake air mass flow rate on wet Fuel mass flow rate Mass fraction of hydrogen in the fuel Mass fraction of carbon in the fuel Mass fraction of sulfur in the fuel Mass fraction of nitrogen in the fuel Mass fraction of oxygen in the fuel Fuel factor for calculation of wALF basis1) Exhaust gas mass flow rate on wet basis1)
Choice of fuel
5.1 General
As far as possible, reference fuels should be used for certification of engines. Reference fuels reflect the characteristics of commercially available fuels in different countries and are therefore different in their properties. Since fuel composition influences exhaust emissions, emission results with different reference fuels are not usually comparable. For lab-to-lab comparison of emissions even the properties of the specified reference fuel are recommended to be as near as possible to identical. This can theoretically best be accomplished by using fuels from the same batch. For all fuels (reference fuels and others), the analytical data shall be determined and reported with the results of the exhaust measurement. For non-reference fuels, the data to be determined are listed in the following tables: Table 4 (Universal analytical data sheet Natural gas); Table 8 (Universal analytical data sheet Liquefied petroleum gas);
Table 12 (Universal analytical data sheet Engine gasolines); Table 17 (Universal analytical data sheet Diesel fuels); Table 19 (Universal analytical data sheet Distillate fuel oils); Table 21 (Universal analytical data sheet Residual fuel oils); Table 22 (Universal analytical data sheet Crude oil).
N/A
An elemental analysis of the fuel shall be carried out when the possibility of an exhaust mass flow measurement or combustion air flow measurement, in combination with the fuel consumption, is not possible. In such cases, the exhaust mass flow can be calculated using the concentration measurement results of the exhaust emission, and using the calculation methods given in ISO 8178-1:2006, Annex A. In cases where the fuel analysis is not available, hydrogen and carbon mass fractions can be obtained by calculation. The recommended methods are given in A.2.1, A.2.2 and A.2.3. Emissions and exhaust gas flow calculations depend on the fuel composition. The calculation of the fuel specific factors, if applicable, shall be done in accordance with ISO 8178-1:2006, Annex A.
NOTE For non-ISO test methods equivalent to those of ISO International Standards mentioned in this part of ISO 8178, see Annex B.
Sulfur naturally occurs in crude oil. The sulfur still contained in the fuel after the refining process is oxidized during the combustion process in the engine to SO2, which is the primary source of sulfur emission from the engine. Part of the SO2 is further oxidized to sulfate (SO4) in the engine exhaust system, the dilution tunnel, or by an exhaust aftertreatment system. Sulfate will react with the water present in the exhaust to form sulfuric acid with associated water that will condense and finally be measured as part of the particulate emission (PM). Consequently, fuel sulfur has a significant influence on the PM emission. The mass of sulfates emitted from an engine depends on the following parameters: the fuel consumption of the engine (BSFC); the fuel sulfur content (FSC); the S SO4 conversion rate (CR); the weight increase by water absorption standardized to H2SO47H2O. Fuel consumption and fuel sulfur content are measurable parameters, whereas the conversion rate can only be predicted, since it may vary from engine to engine. Typically, the conversion rate is approximately 2 % for engines without aftertreatment systems. The following formula has been applied for estimating the sulfur impact on PM, as presented below:
SulphurPM = BSFC
Where
BSFC is the brake specific fuel consumption, expressed in grams per kilowatt-hour (g/kWh); FSC is the fuel sulfur content, expressed in milligrams per kilogram (mg/kg); CR = is the S SO4 conversion rate, expressed in percent % is the S H2SO47H2O conversion factor
6.9375 =
N/A
The relationship between fuel sulfur content and sulfate emission is shown in Figure 1 for an engine without aftertreatment and a S SO4 conversion rate of 2 %. Many aftertreatment systems contain an oxidation catalyst as integral part of the overall aftertreatment system. The major purpose of the oxidation catalyst is to enhance specific chemical reactions necessary for the proper function of the aftertreatment system. Since the oxidation catalyst will also oxidize a considerable amount of SO2 to SO4, the aftertreatment system is likely to produce a high amount of additional particulates in the presence of fuel sulfur. When using such aftertreatment systems, the conversion rate can drastically increase to about 30 % to 70 % depending on the efficiency of the catalytic converter. This will have a major impact on the PM emission, as shown in Figure 2 for sulfur levels below 0,05 % (500 ppm).
Figure 1 Relationship between fuel sulfur and sulfate emission for engines without aftertreatment
N/A
Key X sulfur content, in % Y sulfur PM, in g/kW.h a 70% conversion b 30% conversion
Figure 2 Relationship between fuel sulfur and sulfate emission for engines with aftertreatment
5.2.2
For marine fuels (distillate and residual fuel oils), sulfur and nitrogen have a significant impact on PM and NOx emissions, respectively. Typically, the sulfur content is higher than for onroad or nonroad diesel fuels by a factor of approximately 10, as shown in Table 20. Even without any aftertreatment system, the PM sulfur level will be approximately 0,4 g/kWh for a 2 % sulfur fuel. In addition, the high ash, vanadium and sediment fractions will significantly contribute to the total PM emission. As a consequence, the inherent engine PM emission, which is mainly soot, is only a very small fraction of the total PM emission. In the application of aftertreatment systems, 5.2.1 should be carefully considered. The average nitrogen content of residual fuel oil is currently around 0,4 %, but steadily increasing. In some cases, nitrogen contents between 0,8 % and 1,0 % have been reported. Assuming a 55 % conversion rate at a nitrogen level of 0,8 % will increase the NOx emission of the engine by more than 2 g/kWh. This is a significant portion of the total NOx emission, and has therefore to be carefully taken into account. 5.2.3 Other fuel properties
There are a couple of other fuel parameters that have a significant influence on emissions and fuel consumption of an engine. Contrary to the sulfur influence, their magnitude is less predictable and
N/A
unambiguous, but there is always a general trend that is valid for all engines. The most important of these parameters are the cetane number, density, poly-aromatic content, total aromatics content and distillation characteristics. Their influence is briefly summarized, below. For NOx, total aromatics is the predominant parameter whereas the effect of poly-aromatics and density is less significant. This can be explained by an increase of the flame temperature with higher aromatics content during combustion, which results in increased NOx emission. For PM, density and poly-aromatics are the most significant fuel parameters. In general, NOx will be reduced by 4 % if aromatics are reduced from 30 % to 10 %. A similar reduction is possible for PM when reducing poly-aromatics from 9 % to 1 %. Increasing the cetane number (CN) will improve engine cold start and therefore white smoke emission. It has also a favorable influence on NOx emission particularly at low loads, where reductions of up to 9 % can be achieved if CN is increased from 50 to 58, and fuel consumption with improvements of up to 3 % for the same CN range.
N/A
Overview of fuels
The referenced natural gases whose use is recommended for certification purposes are the following: a) b) c) aEU reference fuels: see Table 1; USA certification test fuel: see Table 2; Japanese certification test fuel: see Table 3. Non-referenced natural gas
6.1.2
Often, referenced gaseous fuels cannot be used as their use depends on the availability of the gas at site. Their properties, including the fuel(s) analysis, shall be known and reported with the results of the emissions test. A universal data sheet containing the analytical properties to be reported is given in Table 4.
The referenced liquefied petroleum gas whose use is recommended for certification purposes is the following: a) b) c) EU reference fuels: see Table 5; USA certification test fuel: see Table 6; Japanese certification test fuel: see Table 7. Non-referenced liquefied petroleum gas
6.2.2
Often, referenced liquefied petroleum gas cannot be used as its use depends on the availability of the gas at site. The properties, including the gas analysis, shall be known and reported with the results of the emissions test. A universal data sheet containing the analytical properties to be reported is given in Table 8.
The referenced engine gasolines whose use is recommended for certification purposes are the following: a) b) c) EU reference fuels: see Table 9; USA certification test fuel: see Table 10; Japanese certification test fuels: see Table 11. Non-referenced engine gasolines
6.3.2
If it is necessary to use non-referenced engine gasolines, the properties of the individual fuel shall be reported
10
N/A
with the results of the test. Table 12 represents a universal analytical data sheet giving the properties which shall be reported. Standards or specification of commercial fuels may be obtained from the organizations listed in Annex C.
The referenced diesel fuels whose use is recommended for certification purposes are the following: a) b) c) d) EU reference fuels: see Table 13; USA certification test fuels: see Table 14; Californian test fuel: see Table 15; Japanese certification test fuel: see Table 16. Non-referenced diesel fuels
6.4.2
If it is necessary to use non-referenced diesel fuels, the properties of the individual fuel shall be reported with the results of the test. Table 17 represents a universal analytical data sheet giving the properties which shall be reported. Standards or specifications of commercial fuels may be obtained from the organizations listed in Annex C.
11
N/A
comparable to the cetane index for pure distillate fuels. A calculation based on the distillation characteristics is not suitable. For the time being, the best approach is to calculate CCAI (calculated carbon aromaticity index) or CII (calculated ignition index) figures for general indication. It is too early to specify a supplementary maximum ignition quality level in the fuel specification during exhaust emission acceptance tests. Clause A.4 A.3.2.2 gives equations for CCAI and CII. Another method, which is currently under investigation, is the fuel ignition analyzer (FIA). The ignition quality of a fuel is determined as an ignition delay and time delay for start of main combustion (both in milliseconds). By use of calibration fuels, the recorded ignition delay can be converted into an instrument-related cetane number. In addition, the rate of heat release (ROHR) is determined, reflecting the actual heat release process and thus the combustion characteristics of the fuel tested. The test results appear to reflect the differences in ignition and combustion properties of marine fuels due to variations in their chemical composition. At the present time, a large number of heavy fuels are being tested for the purpose of relating the results obtained from the instruments to the fuel ignition performance as well as correlating the results with engine performance. In co-operation with engine manufacturers, fuel testing laboratories and users of marine heavy fuel, typical limits for satisfactory fuel ignition and combustion quality at which operational disturbances are not encountered, are being established.
12
N/A
Property
Unit
Test method
Table 2 Natural gas USA certification test fuel [Source: Title 40, Code of Federal Regulations, 1065.715]
as of 2008 Property Unit Test method min. Molar fraction of methane Molar fraction of ethane Molar fraction of C3+ components Molar fraction of C6+ components Molar fraction of inert gases, CO2 and N2 mol % mol % mol % mol % mol % ASTM D 1945 ASTM D 1945 ASTM D 1945 ASTM D 1945 ASTM D 1945 89 max. 4,5 2,3 0,2 4,0 min. 87 max. 5,5 1,7 0,1 5,1
Table 3 Natural gas Japanese certification test fuel [Source: Details of Safety Regulations for Road Vehicles, Attachment 41and 42]
Property Unit
3
Test method
Equivalent of 13A min. max. 11 050 13 730 37,5 10,0 6,0 4,0 8,0 0,1 14,0 10
Total calorific amount Wobbe index Combustion speed index Molar fraction of methane Molar fraction of ethane Molar fraction of propane Molar fraction of butene Molar fraction of C3 + C4 components Molar fraction of C5+ components Molar fraction of other gas (H2 + O2 + N2 + CO + CO2 ) Mass concentration of sulfur
1)
JIS K2301
1) 1)
JIS K2301 JIS K2301 JIS K2301 JIS K2301 JIS K2301 JIS K2301 JIS K2301 JIS K2301
mg/m3
Wobbe index and Combustion speed index shall be calculated based on the gas composition.
13
N/A
Property Volume fraction of C3 components Volume fraction of C4 components Volume fraction of inerts, < C3, > C4 Volume fraction of olefins Evaporation residue Water at 0C Total sulfur content Hydrogen sulfide Copper strip corrosion Odour Engine octane number
Test method ISO 7941 ISO 7941 ISO 7941 ISO 7941 ISO 13757 visual inspection
Fuel A 50 2 Balance max. 2,0 max.12 max. 50 free max. 50/10 none Class 1 characteristic
Fuel B 85 2 Balance max. 2,0 max.14 max. 50 free max. 50/10 none Class 1 characteristic min. 92,5
mg/kg
Rating
ISO 6251
EN 589 Annex B
min. 92,5
14
N/A
Table 6 Liquefied petroleum gas USA certification test fuel [Source: Title 40, Code of Federal Regulations, 1065.720]
Property
Unit
ASTM D 2163 ASTM D 2163 ASTM D 2163 ASTM D 2163 ASTM D 2163 ASTM D 1267 ASTM D 1837 ASTM D 2158 ASTM D 1838 ASTM D 2784 ASTM D 2713
85 Pass
Volume fraction of pentenes and heavier % by volume Volume fraction of propene Vapor pressure at 38C Volatility residue Residual matter Copper strip corrosion Mass concentration of sulfur Moisture content % kPa C ml Rating mg/kg Rating
15
N/A
Table 9 Engine gasolines EU reference fuels [Source: CEC, Reference fuels manual] [Source: EU Directive 2002/80/EC] [Source: EU Directive 2004/26/EC] [Source: ECE Regulation 83]
Property Unit Test method RF-02-99 Unleaded min. Research octane number (RON) Engine octane number (MON) Density at 15 C Reid vapour pressure Vapour pressure (DVPE) Distillation Initial boiling point Evaporated at 100C Evaporated at 150C Final boiling point Residue Hydrocarbon analysis Volume fraction of olefins Volume fraction of aromatics Volume fraction of benzene Volume fraction of saturates Mass fraction of sulfur Oxygen content Lead content Phosphorus content Oxidation stability Induction period Mass of existent gum Copper corrosion at 50 C min mg/ml EN-ISO 7536 EN-ISO 6246 EN-ISO 2160 480 0,04 class 1 480 0,04 class 1 % % % % mg/kg % (by mass) mg/l mg/l ASTM D 1319 ASTM D 1319 pr. EN 12177 ASTM D 1319 pr. EN ISO/DIN 14596 EN 1601 EN 237 ASTM D 3231 28 10 40 1 balance 100 2,3 5 1,3 29 10 35 1 balance 10 1,0 5 1,3 C % v/v % v/v C % 1 1 kg/m kPa kPa EN 25164 EN 25163 ISO 3675 ISO 3007 prEN 13016-1 EN-ISO 3405 24 49 81 190 40 57 87 215 2 24 50 83 190 40 58 89 210 2 95 85 748 56 max. 762 60 RF-02-03 Unleaded min. 95 85 740 56 max. 754 60
16
N/A
Table 10 Engine gasolines USA certification test fuel [Source: Title 40, Code of Federal Regulations, 86.1313-2004] [Source: Title 40, Code of Federal Regulations, 1065.710]
Property Research octane number (RON) Sensitivity (RON/MON) Reid vapour pressure Distillation Initial boiling point 10 % (by volume) 50 % (by volume) 90 % (by volume) Final boiling point Hydrocarbon analysis Volume fraction of olefins Volume fraction of aromatics Volume fraction of saturates Mass fraction of sulfur Mass concentration of lead Mass concentration of phosphorus % % % mg/kg g/l g/l ASTM D3237 ASTM D 3231 C C C C C ASTM D 1319 Remainder 80 0,013 0,0013 10 35 Unit 1 1 kPa Test method min. ASTM D 2699 ASTM D 2699 ASTM D 2700 ASTM D 323 ASTM D 86 24 49 93 149 35 57 110 163 213 93 7,5 60.0 max. 63.4
17
N/A
Table 11 Engine gasolines Japanese certification test fuels [Source: Details of Safety Regulations for Road Vehicles, Attachment 41 and 42]
Property
Unit
Test method
Regular Grade min. max. 92 82 0,77 60 328 (55) 373 (100) 443 (170) 488 (215)
Premium Grade min. 99 86 0,72 56 318 (45) 363 (90) 413 (140) max. 101 88 0,77 60 328 (55) 373 (100) 443 (170) 488 (215)
Research octane number (RON) Engine octane number (MON) Density at 15 C Reid vapour pressure Distillation 10 % (by volume) 50 % (by volume) 90 % (by volume) Final boiling point Hydrocarbon analysis Olefins Aromatics Benzene Oxygen MTBE Methanol Ethanol Kerosine Mass fraction of sulfur Mass concentration of lead Existent gums per 100 ml 1) ND = not detectable.
JIS K 2280 JIS K 2280 JIS K 2249 JIS K 2258 JIS K 2254
JIS K 2536-1, -2, -3, -4, -5, -6 % by volume % by volume % by volume % by mass % by volume % by volume % by volume % by volume mg/kg g/l mg JIS K 2541-1, -2, -6, -7 JIS K 2255 JIS K 2261 15 20 25 45 1,0 ND
1)
15 20
25 45 1,0 ND ND ND ND ND 10 ND 5
ND ND ND ND 10 ND 5
18
N/A
Mass fraction of Sulfur Mass concentration of phosphorus Mass concentration of lead Oxidation stability Mass of existent gums per 100 ml Copper strip corrosion at 50 C Oxygenates Elemental analysis2) Mass fraction of carbon Mass fraction of hydrogen Mass fraction of nitrogen Mass fraction of oxygen
1) Indicate the method used. 2) See the ultimate paragraph of clause 5.
% % % % ASTM D 3343
19
N/A
Table 13 Diesel fuels EU reference fuels [Source: CEC, Reference fuels manual] [Source: EU Directive 2005/78/EC] [Source: EU Directive 2004/26/EC]
RF-06-99 min. Cetane number Density at 15 C Distillation 50 % (by volume). 95 % (by volume). Final boiling point Flash point Cold filter plugging point Kinematic viscosity at 40 C Polycyclic Aromatic Hydrocarbons Mass fraction of Sulfur Copper corrosion Mass fraction of Conradson carbon residue (10 % DR) Mass fraction of ash Mass fraction of water Lubricity (HFRR @ 60C) Neutralisation number Oxidation stability C C C C C mm2/s % (by mass) mg/kg % % % m mgKOH/g mg/ml EN-ISO 12205 ISO 2719 EN 116 ISO 3104 EN 12916 EN-ISO 14596 ISO 2160 ISO 10370 EN-ISO 6245 EN-ISO 12937 CEC F-06-A-96 0,02 0,025
to be reported
Property
Unit
Test methods
max. 54 837
1 kg/m
52 833
350 370 -5 3,5 6,0 300 (50) class 1 0,2 0,01 0,05
350 370 -5 3,3 6,0 10 class 1 0,2 0,01 0,02 400 0,02 0,025
55 2,5
370 +5 3,5
1000
0,02 0,025
20
N/A
Table 14 Diesel fuels USA certification tests fuels [Source: Title 40, Code for Federal Regulations, 86.1313-98] [Source: Title 40, Code for Federal Regulations, 86.1313-2007] [Source: Title 40, Code of Federal Regulations, 1065.703] Property
Cetane number Cetane index Density at 15 C Distillation Initial boiling point 10 % (by volume). 50 % (by volume). 90 % (by volume). Final boiling point Flash point Kinematic viscosity at 37,88 C Mass fraction of sulfur C C C C C C mm2/s % ppm % ASTM D 93 ASTM D 445 ASTM D 1266 ASTM D 2622 ASTM D 1319
Unit
1 1 kg/l
Test method
ASTM D 613 ASTM D 976 ASTM D 1298 ASTM D 86
Fuel 2-D min. 40 40 0,840 171 204 243 293 321 54 2 0,03 7 27 (10) max. 50 50 0,865 204 238 282 332 366 3,2 0,05 15
Table 15 Diesel fuels California certification test fuel [Source: California Code of Regulations, Title 13, Division 3]
Property Unit Test method min. Cetane number Cetane index Density at 15 C Distillation Initial boiling point 10 % (by volume). 50 % (by volume). 90 % (by volume). Final boiling point Flash point Kinematic viscosity at 37,88 C Mass fraction of sulfur Volume fraction of aromatics C C C C C C mm2/s % % ASTM D 93 ASTM D 445 ASTM D 1266 ASTM D 2622 ASTM D 1319 1 1 kg/l ASTM D 86 171 204 243 293 321 54 2 0,03 204 238 282 332 366 3,2 0,05 10 ASTM D 613 ASTM D 976 42 42 0,840 Fuel 2-D max. 50 50 0,865
21
N/A
Table 16 Diesel fuels Japanese certification test fuel [Source: Details of Safety Regulations for Road Vehicles, Attachment 41, 42 and 43]
Certification Fuel 1 1) min. Cetane index Density at 15 C Distillation 50 % (by volume). 90 % (by volume). Final boiling point Hydrocarbon analysis Total aromatics Polycyclic aromatics Flash point Kinetic viscosity at 30 C Mass fraction of sulfur Triglyceride Fatty acid methyl esters
1) 2) 3)
Property
Unit
Test method
Certification Fuel 2 2) min. 53 0,815 528 (255) 573 (300) max. 60 0,840 568 (295) 618 (345) 643 (370)
JPI-5S-49-97 3) JPI-5S-49-97 JIS K2283 JIS K2541-1,-2,-6,-7 Measurement method specified by METI4) bulletin
3)
25 5,0 4,5 10 ND ND
5) 5)
JIS K2265-3
4) 5)
Test fuel for on road vechcle specified in Details of Safety Regulations for Road Vehicles, Attachment 41and 42 Test fuel for on road special vechcle specified in Details of Safety Regulations for Road Vehicles, Attachment 43 Japan Petroleum Institute Standard Ministry of Economy, Trade and Industry ND = not detectable
22
N/A
Test method 1) ISO 5165 ISO 4264 ISO 3675 ISO 3405
Result of measurements
ISO 2719 EN 116 ISO 3016 ISO 3104 ISO 4260 ASTM D 1319 2) ASTM D 5186 ISO 6615 ISO 6245 ISO 3733 ASTM D 974 ASTM D 525 ASTM D 381 ASTM D 3343
23
N/A
Table 18 Distillate fuel oils ISO class F test fuel oils [Source: ISO 8217:2010]
Property Cetane index Density at 15 C Flash point Pour point Winter quality Summer quality Kinematic viscosity at 40 C Mass fraction of sulfur Mass fraction of carbon residue, Ramsbottom on 10 % residue Mass fraction of carbon residue, Ramsbottom Mass fraction of ash Volume fraction of water Mass fraction of sediment Mass fraction of hydrogen sulfide Acid number Cloud point Lubricity, corrected wear scar diameter (wsd 1.4) at 60 C2) Visual inspection Property Cetane index Density at 15 C Flash point Cloud point Pour point Winter quality Summer quality Kinematic viscosity at 40 C Mass fraction of sulfur Mass fraction of carbon residue, Ramsbottom on 10 % residue Mass fraction of carbon residue, Ramsbottom Mass fraction of ash Volume fraction of water Mass fraction of sediment Mass fraction of hydrogen sulfide Acid number Cloud point Lubricity, corrected wear scar diameter (wsd 1.4) at 60 C2) Vanadium Aluminium+silicon Visual inspection Unit Test Method kg/m C C C mm/s % % % % % % mg/kg mgKOH/g C ISO 4264 ISO 3675 ISO 2719 ISO 3016 Fuel ISO-F-DMA min. 40 60 1,50 2,00 max. 890,0 Fuel ISO-F-DMB min. 35 60 2,00
(1
max. 900,0
ISO 3104 ISO 8754 ISO 10370 ISO 10370 ISO 6245 ISO 3733 ISO 10307-1 IP 570 ASTM D664 ISO 3015 ISO 12156-1 ISO 8217 Test Method ISO 4264 ISO 3675 ISO 2719 ISO 3015 ISO 3016
m
Unit
520 clear and bright Fuel ISO-F-DMX min. max. 45 43 - 16 2,00 -16 5,50 1,00 0,30 0,01 2,00 0,5
Fuel ISO-F-DMZ min. max. 40 890,0 60 3,00 -6 0 6,00 1,50 0,30 2,50 0,01 0,3 0,0 2,00 0,5
ISO 3104 ISO 8754 ISO 10370 ISO 10370 ISO 6245 ISO 3733 ISO 10307-1 IP 570 ASTM D664 ISO 3015 ISO 12156-1 ISO 14597 ISO 10478 ISO 8217
m mg/kg mg/kg
1) See ISO 8217:2010, subclause 7.6 2) This requirement is applicable to the fuels with a sufhur content below 500 mg/kg (0,05 mass%)
24
N/A
Test method ISO 5165 ISO 3675 ISO 2719 ISO 3016 ISO 3015 ISO 3104 ISO 8754 ISO 10370
Result of measurements
% % % % mg/kg mgKOH/g C
ISO 10370 ISO 6245 ISO 3733 ISO 3735 10307-1 IP 570 ASTM D664 ISO 3015 ISO 12156-1 ISO 8217
m
% % % % %
ASTM D 3343
25
N/A
Table 20 Residual fuel oils ISO class F test fuel oils [Source: ISO/8217:2010]
Property Unit Test method Limit RMA 10 Density at 15 C Kinematic viscosity at 50 C Flash point Pour point (upper) Winter quality Summer quality CCAI Mass fraction of sulfur Mass fraction of carbon residue: micro method Mass fraction of ash Volume fraction of water Mass fraction of sediment Mass fraction of Aluminium + silicon Mass fraction of Vanadium kg/m mm/s C C ISO 3675 ISO 3104 ISO 2719 ISO 3016 max. max. 0 6 850 0 6 860 30 30 860 30 30 860 30 30 870 Statutory requirements 2,50 0,040 0,30 0.10 25 50 2.00 2.5 10,00 0,070 0,50 0.10 49 150 2.00 2.5 14,00 0,070 0,50 0.10 49 150 2.00 2.5 15,00 0,070 0,50 0.10 50 150 2.00 2.5 18,00 0.100 0,50 0.10 60 350 2.00 2.5
2)
Category: RMB 30 960,0 30,00 60,0 RMD 80 975,0 80,00 60,0 RME 180 991,0 180,00 60,0
ISO-FRMG RMK
180
380
500
700
30 30 870
% % % % % mg/kg mg/kg
ISO 10307-2 max. ISO 10478 ISO 14597 IP 570 max. max. max. 2.5
Mass fraction of hydrogen mg/kg sulfide Acid number Used lubricating oils (ULO): Calcium and zinc; or Calcium and phosphorus
The fuel shall be free from ULO. A fuel shall be considered to contain ULO when another one of the following conditions is met: Calcium >30 and zinc >15; or Calcium >30 and phosphorus >15
1) See ISO 8217:2010, Clause 6.3 a) and Annex F 2) See ISO 8217:2010, Clause 7.2 and Annex C
26
N/A
Test method1) ISO 3675 ISO 2719 ISO 3016 ISO 3104 ISO 8754 ISO 4260 ISO 6615 ISO 10370 ISO 6245 ISO 3733 ISO 3735 10307-2 ISO 10478 ISO 8691 IP 570 ASTM D 664
Result of measurements
ASTM D 3343
Test method 1) ISO 3675 ISO 3104 ISO 3105 ISO 8754 ISO 3016 ISO 3007 ISO 3733
Result of measurements
27
N/A
cw = k w cd
The dry to wet correction factor kwr is used for converting dry measured concentrations to the wet reference condition. kwr is further the quotient between dry and wet exhaust volume flow:
k wr =
cgasw cgasd
qved qvew
= 1
qvH2O qvew
k wr1
qmf p 1,2442 H a + 111,19 wALF 773,4 r qmad pb = 1 qmf 773,4 + 1,2442 H a + f fw 1000 qmad
The fuel specific constants ffw [m volume change from combustion air to wet exhaust/kg fuel] is calculated, as follows:
fw
The fuel specific constants ffd [m volume change from combustion air to dry exhaust/kg fuel] is calculated, as follows:
28
N/A
Table A.1 Values of fuel specific factors for some selected fuels Copied from ISO 8178-1:2006 (table E.1); As ISO 8178-1:2006 is currently under revision, table A.1 needs to be updated accordingly before publication.
Composition Fuel % mass Molar ratio EAF independent fuel specific parameters EAF kg/m3 wet 1,295 5 1,294 8 1,294 3 1,293 8 1,293 6 1,293 5 1,296 8 1,295 9 1,295 0 1,294 3 1,294 0 1,293 8 1,234 6 1,247 7 1,261 0 1,271 0 1,276 2 1,279 4 1,260 6 1,268 2 1,275 7 1,281 2 1,284 1 1,285 8 1,242 1 1,254 3 1,266 1 1,274 8 1,279 2 1,281 9 1,268 9 1,274 8 1,280 5 1,284 5 1,286 6 1,287 9
Values for dry intake air Exhaust density kg/m3 dry 1,365 7 1,345 9 1,328 1 1,316 1 1,310 3 1,306 8 1,369 2 1,348 5 1,329 9 1,317 4 1,311 2 1,307 5 1,364 0 1,344 6 1,327 2 1,315 5 1,309 8 1,306 4 1,363 7 1,344 3 1,327 1 1,315 4 1,309 7 1,306 3 1,341 0 1,327 7 1,315 9 1,308 0 1,304 2 1,301 9 1,354 4 1,337 4 1,322 3 1,312 3 1,307 4 1,304 4 kwr Mrew g/mol ffh
Diesel
H C S N O
0,882 5 0,913 5 0,943 2 0,964 3 0,975 1 0,981 6 0,879 3 0,910 9 0,941 3 0,963 0 0,974 0 0,980 7 0,775 6 0,827 7 0,880 7 0,920 4 0,941 2 0,954 0 0,822 9 0,866 4 0,909 4 0,940 8 0,957 0 0,966 9 0,823 1 0,867 1 0,910 4 0,941 7 0,957 8 0,967 6 0,852 2 0,890 2 0,927 0 0,953 2 0,966 6 0,974 8
29,023 29,009 28,996 28,987 28,982 28,979 29,053 29,032 29,012 28,997 28,990 28,985 27,661 27,954 28,252 28,475 28,592 28,664 28,243 28,413 28,581 28,704 28,768 28,806 27,829 28,100 28,366 28,559 28,658 28,718 28,429 28,560 28,687 28,778 28,824 28,852
1,818 4 1,848 3 1,877 0 1,897 4 1,907 8 1,914 1 1,601 1 1,631 3 1,660 4 1,681 1 1,691 6 1,698 0 1,483 9 1,553 9 1,625 1 1,678 3 1,706 3 1,723 5 1,651 0 1,705 3 1,759 0 1,798 2 1,818 5 1,830 9 2,479 9 2,549 8 2,618 2 2,667 9 2,693 4 2,708 9 2,425 3 2,475 1 2,523 2 2,557 6 2,575 1 2,585 8
RME
H C S N O
Methanol
H C S N O
Ethanol
H C S N O
Natural Gas
H C S N O
Propane
H C S N O
29
N/A
Butane
H C S N O
0,858 1 0,894 8 0,930 1 0,955 4 0,968 3 0,976 1 0,889 3 0,918 7 0,946 8 0,966 8 0,976 9 0,983 0 0,659 3 0,737 6 0,817 1 0,876 6 0,907 8 0,927 0
28,545 28,648 28,748 28,819 28,855 28,877 29,173 29,122 29,073 29,038 29,021 29,010 24,639 25,610 26,598 27,336 27,723 27,962
2,300 0 2,345 4 2,389 2 2,420 5 2,436 5 2,446 1 1,647 1 1,673 3 1,698 3 1,716 1 1,725 2 1,730 6 11,872 8 12,432 5 13,001 6 13,427 1 13,650 5 13,788 2
Gasoline
H C S N O
Hydrogen
H C S N O
30
N/A
wALF = 26 15 f
wBET =100 wALF
where is the density at 288 K (15 C) in grams per cubic centimetre
A.2.2 Method 2 The method has been published in the Book of ASTM Standards (June 1968) with the original title: Proposed method for estimation of net and gross heat of combustion of burner and diesel fuels. In this formula, the sulfur content is known.
Z=
wALF =
It is also possible to estimate the net heat of combustion value, NHCV in megajoules per kilogram:
31
N/A
wALF = (26 15 ) [1 0,01 (wGAM +wDEL) ] wBET = 100 (wALF +wGAM +wDEL)
where is the density at 288 K (15 C), in grams per cubic centimetre.
where T is the temperature in degrees Kelvin; is the kinematic viscosity, in square millimetres per second at temperature T; is the density at 15 C in kilograms per cubic metre.
32
N/A
Key A B C D a b kinematic viscosity, square millimetres per second density at 15 C, in kilograms per cubic metre CII CCAI At 50 C At 100 C
Figure A.1 Nomogram for deriving the Calculated Ignition Index (CII) and the Calculated Carbon Aromaticity Index (CCAI)
33
N/A
NOTE
The standard given in this annex are not completely equivalent but should be considered comparable.
34
N/A
ISO test method ASTM test method CEN test method ISO 5165 ISO 3675 ISO 3405 ISO 2719 ISO 3015 ISO 3016 ISO 3104 ISO 3105 ISO 4260 ISO 8754 ISO 2160 ISO 6245 ISO 3733 ISO 6296 ASTM D 613 ASTM D 1298 ASTM D 86 ASTM D 93 ASTM D 2500 ASTM D 97 ASTM D 445 ASTM D 1266 ASTM D 2622 ASTM D 130 ASTM D 482 ASTM D 95 ASTM D 1744 EN 41 ISO 6245
JIS test method JIS K 2280 JIS K 2249 JIS K 2254 JIS K 2265 JIS K 2269 JIS K 2283 JIS K 2283 JIS K 2541 JIS K 2513 JIS K 2272 JIS K 2275 JIS K 2275
Table B.5 Methods for the determination of ignition quality (calculated cetane index)
Number of variables 4 2
1) Institute of Petroleum, U.K.
35
N/A
NOTE Since the specifications of commercial fuels are subject to changes, the particular specification should be checked prior to commencing the test.
Co-ordinating European Council for the Development of Performance Tests for Transportation Fuels, Lubricants and Other Fluids (CEC) Interlynk Administrative Services Ltd PO Box 6475 Earl Shilton Leicester LE9 9ZB, UK The European Liquefied Petroleum Gas Association (AEGPL) 165 bd du Souverain 1160 Brussles, Belgium European Natural Gas Vehicle Association (ENGVA) Kruisweg 813-A 2132 NG Hoofdorp, The Netherlands American Petroleum Institute (API) 1220 L Street, Northwest Washington, DC 20005, USA American Gas Association (AGA) 400 North Capitol Street, NW Suite 450 Washington, DC 20001, USA Petroleum Association of Japan Keidanren Bldg. No. 9-4, 1-Chome Ohtemachi Chiyoda-ku Tokyo 100-0004, Japan The Japan LP-Gas Association 1-14-1, Toranomon, Minato-ku Tokyo 105-0001, Japan The Japan Gas Association 1-15-12 Toranomon, Minato-ku, Tokyo 105-0001, Japan
36
N/A
Bibliography
[1] ISO 1998-1:1998, Petroleum industry Terminology Part 1: Raw materials and products [2] ISO 1998-2:1998, Petroleum industry Terminology Part 2: Properties and tests [3] ISO 1998-3:1998, Petroleum industry Terminology Part 3: Exploration and production [4] ISO 1998-4:1998, Petroleum industry Terminology Part 4: Refining [5] ISO 1998-5:1998, Petroleum industry Terminology Part 5: Transport, storage, distribution [6] ISO 1998-6:2000, Petroleum industry Terminology Part 6: Measurement [7] ISO 1998-7:1998, Petroleum industry Terminology Part 7: Miscellaneous terms [8] ISO 1998-99:2000, Petroleum industry Terminology Part 99: General and index [9] ISO 4259:2006, Petroleum products Determination and application of precision data in relation to methods of test [10] ISO 6251:1996, Liquefied petroleum gases Corrosiveness to copper Copper strip test [11] ISO 6296:2000, Petroleum products Determination of water Potentiometric Karl Fischer titration method [12] ISO 8178-4:2007, Reciprocating internal combustion engines Exhaust emission measurement Part 4: Steady-state test cycles for different engine applications [13] ISO 8178-11:2006, Reciprocating internal combustion engines Exhaust emission measurement Part 11: Test-bed measurement of gaseous and particulate exhaust emissions from engines used innonroad mobile machinery under transient test conditions [14] ISO 8819:1993, Liquefied petroleum gases Detection of hydrogen sulfide Lead acetate method [15] ISO 12156-1:2006, Diesel fuel Assessment of lubricity using the high-frequency reciprocating rig (HFRR) Part : Test method [16] ISO 12205:1995, Petroleum products Determination of the oxidation stability of middle-distillate fuels [17] ISO 12937:2000, Petroleum products Determination of water Coulometric Karl Fischer titration method [18] ISO 14596:2007, Petroleum products Determination of sulfur content Wavelength-dispersive X-ray fluorescence spectrometry [19] ISO 22854, Liquid petroleum products Determination of hydrocarbon types and oxygenates in automotive-engine gasoline Multidimensional gas chromatography method [20] ASTM D 86-07b, Standard Test Method for Distillation of Petroleum Products at Atmospheric Pressure [21] ASTM D 93-07, Standard Test Methods for Flash Point by Pensky-Martens Closed Cup Tester [22] ASTM D 95-05e1, Standard Test Method for Water in Petroleum Products and Bituminous Materials by Distillation [23] ASTM D 97-07, Standard Test Method for Pour Point of Petroleum Products
37
N/A
[24] ASTM D 130-04e1, Standard Test Method for Corrosiveness to Copper from Petroleum Products by Copper Strip Test [25] ASTM D 189-06, Standard Test Method for Conradson Carbon Residue of Petroleum Products [26] ASTM D 323-06, Standard Test Method for Vapor Pressure of Petroleum Products (Reid Method) [27] ASTM D 381-04e1, Standard Test Method for Gum Content in Fuels by Jet Evaporation [28] ASTM D 445-06, Standard Test Method for Kinematic Viscosity of Transparent and Opaque Liquids (and Calculation of Dynamic Viscosity) [29] ASTM D 482-07, Standard Test Method for Ash from Petroleum Products [30] ASTM D 525-05, Standard Test Method for Oxidation Stability of Gasoline (Induction Period Method) [31] ASTM D 613-05, Standard Test Method for Cetane Number of Diesel Fuel Oil [32] ASTM D 974-07, Standard Test Method for Acid and Base Number by Color-Indicator Titration [33] ASTM D 976-06, Standard Test Method for Calculated Cetane Index of Distillate Fuels [34] ASTM D 1266-07, Standard Test Method for Sulfur in Petroleum Products (Lamp Method) [35] ASTM D 1267-02(2007), Standard Test Method for Gage Vapor Pressure of Liquefied Petroleum (LP) Gases (LP-Gas Method) [36] ASTM D 1298-99(2005), Standard Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method [37] ASTM D 1319-03e1, Standard Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption [38] ASTM D 1657-02(2007), Standard Test Method for Density or Relative Density of Light Hydrocarbons by Pressure Hydrometer [39] ASTM D 1837-02a(2007), Standard Test Method for Volatility of Liquefied Petroleum (LP) Gases [40] ASTM D 1838-07, Standard Test Method for Copper Strip Corrosion by Liquefied Petroleum (LP) Gases [41] ASTM D 1945-03, Standard Test Method for Analysis of Natural Gas by Gas Chromatography [42] ASTM D 2158-05, Standard Test Method for Residues in Liquefied Petroleum (LP) Gases [43] ASTM D 2163-912) Test Method for Analysis for Liquefied Petroleum (LP) Gases and Propane concentrates by Gas Chromatography [44] ASTM D 2274-03a, Standard Test Method for Oxidation Stability of Distillate Fuel Oil (Accelerated Method) [45] ASTM D 2500-05, Standard Test Method for Cloud Point of Petroleum Products [46] ASTM D 259802(2007), Standard Practice for Calculation of Certain Physical Properties of Liquefied Petroleum (LP) Gases from Compositional Analysis
2) This standard was withdrawn in 2005, but as of February 2008, was still the test method referred to in the Code of Federal Regulations, Title 40, Table 1 of 1065.720 Test Fuel Specifications for Liquefied Petroleum Gas.
38
N/A
[47] ASTM D 2622-08, Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive Xray Fluorescence Spectrometry [48] ASTM D 2699-08, Standard Test Method for Research Octane Number of Spark-Ignition Engine Fuel [49] ASTM D 2700-08, Standard Test Method for Engine Octane Number of Spark-Ignition Engine Fuel [50] ASTM D 2713-07, Standard Test Method for Dryness of Propane (Valve Freeze Method) [51] ASTM D 2784-06, Standard Test Method for Sulfur in Liquefied Petroleum Gases (Oxy-Hydrogen Burner or Lamp) [52] ASTM D 3231-07, Standard Test Method for Phosphorus in Gasoline [53] ASTM D 3237-06e1, Standard Test Method for Lead in Gasoline by Atomic Absorption Spectroscopy [54] ASTM D 3244-07a, Standard Practice for Utilization of Test Data to Determine Conformance with Specifications [55] ASTM D 3341-05, Standard Test Method for Lead in Gasoline-Iodine Monochloride Method [56] ASTM D 3343-05, Standard Test Method for Estimation of Hydrogen Content of Aviation Fuels [57] ASTM D 3606-07, Standard Test Method for Determination of Benzene and Toluene in Finished Engine and Aviation Gasoline by Gas Chromatography [58] ASTM D 4530-07, Standard Test Method for Determination of Carbon Residue (Micro Method) [59] ASTM D 4737-04, Standard Test Method for Calculated Cetane Index by Four Variable Equation [60] ASTM D 5186-03, Standard Test Method for Determination of Aromatic Content and Polynuclear Aromatic Content of Diesel Fuels and Aviation Turbine Fuels by Supercritical Fluid Chromatography [61] ASTM D 5191-07, Standard Test Method for Vapor Pressure of Petroleum Products (Mini Method) [62] ASTM D 5580-02 (2007), Standard Test Method for Determination of Benzene, Toluene, Ethylbenzene, p/m-Xylene, o-Xylene, C9 and Heavier Aromatics, and Total Aromatics in Finished Gasoline by Gas Chromatography [63] California Code of Regulations, Title 13, Division 3 [64] CEC, Reference fuels manual [65] CEC F-06-A-96, Measurement of Diesel Fuel Lubricity Approved Test Method, HFRR Fuel Lubricity Test [66] Code for Federal Regulations,Title 40, 86.113-94 [67] Code for Federal Regulations,Title 40, 86.1313-98 [68] Code for Federal Regulations,Title 40, 86.1313-2007 [69] Code of Federal Regulations, Title 40, Part 1065 Engine Testing Procedures [70] EN 228:2004, Automotive fuels Unleaded petrol Requirements and test methods [71] EN 237:2004, Liquid petroleum products Petrol Determination of low lead concentrations by atomic absorption spectrometry [72] EN 589:2004, Automotive fuels LPG Requirements and test methods
39
N/A
[73] EN 590:2004, Automotive fuels Diesel Requirements and test methods [74] EN 1601:1997, Liquid petroleum products Unleaded petrol Determination of organic oxygenate compounds and total organically bound oxygen content by gas chromatography (O-FID) [75] EN 12177:2000, Liquid petroleum products Unleaded petroleum Determination of benzene content by gas chromatography [76] EN 12916:2006, Petroleum products Determination of aromatic hydrocarbon types in middle distillates High performance liquid chromatography method with refractive index detection [77] EN 13016-1:2007, Liquid petroleum products Vapour pressure Part 1: Determination of air saturated vapour pressure (ASVP) and calculated dry vapour pressure equivalent (DVPE) [78] EN 14214:2003, Automotive fuels Fatty acid methyl esters (FAME) for diesel engines Requirements and test methods [79] EN 24260:1994, Methods of test for petroleum and its products Petroleum products and hydrocarbons Determination of sulfur content Wickbold combustion method [80] IP 364/84, Petroleum and its products Part 364: Calculated cetane index of diesel fuels (range below 55) [81] IP 380/98, Petroleum and its products Part 380: Calculation of the cetane index of middle distillate fuels by the four-variable equation [82] JIS K 2202:2007, Engine gasoline [83] JIS K 2204:2007, Diesel fuel [84] JIS K 2240:2007, Liquefied petroleum gases [85] JIS K 2249:1995, Crude petroleum and petroleum products Determination of density and petroleum measurement tables based on a reference temperature (15 centigrade degrees) [86] JIS K 2254:1998, Petroleum products Determination of distillation characteristics [87] JIS K 2255:1995, Petroleum products Gasoline Determination of lead content [88] JIS K 2258:1998, Crude oil and petroleum products Determination of vapour pressure Reid method [89] JIS K 2261:2000, Petroleum products Engine gasoline and aviation fuels Determination of existent gum Jet evaporation method [90] JIS K 2265-1:2007, Determination of flash point Part 1: Tag closed cup method [91] JIS K 2265-2:2007, Determination of flash point Part 2: Rapid equilibrium closed cup method [92] JIS K 2265-3:2007, Determination of flash point Part 3: Pensky-Martens closed cup method [93] JIS K 2265-4:2007, Determination of flash points Part 4: Cleveland open cup method [94] JIS K 2269:1987, Testing methods for pour point and cloud point of crude oil and petroleum products [95] JIS K 2270:2000, Crude petroleum and petroleum products Determination of carbon residue [96] JIS K 2272:1998, Crude oil and petroleum products Determination of ash and sulfated ash [97] JIS K 2275:1996, Crude oil and petroleum products Determination of water content
40
N/A
[98] JIS K 2280:1996, Petroleum products Fuels Determination of octane number, cetane number and calculation of cetane index [99] JIS K 2283:2000, Crude petroleum and petroleum products Determination of kinematic viscosity and calculation of viscosity index from kinematic viscosity [100] JIS K 2287:1998, Gasoline Determination of oxidation stability Induction period method [101] JIS K 2288:2000, Petroleum products Diesel fuel Determination of cold filter plugging point [102] JIS K 2513:2000, Petroleum products Corrosiveness to copper Copper strip test [103] JIS K 2536-1:2003, Liquid petroleum products Testing method of components Part 1: Fluorescent indicator adsorption method [104] JIS K 2536-2:2003, Liquid petroleum products Testing method of components Part 2: Determination of total components by gas chromatography [105] JIS K 2536-3:2003, Liquid petroleum products Testing method of components Part 3: Determination of aromatic components by gas chromatography [106] JIS K 2536-4:2003, Liquid petroleum products Testing method of components Part 4: Determination of components by tandem type gas chromatography [107] JIS K 2536-5:2003, Liquid petroleum products Testing method of components Part 5: Determination of oxygenate compounds by gas chromatography [108] JIS K 2536-6:2003, Liquid petroleum products Testing method of components Part 6: Determination of oxygen content and oxygenate compounds by gas chromatography and oxygen selective detection [109] JIS K 2541-1:2003, Crude oil and petroleum products Determination of sulfur content Part 1: Wickbold combustion method [110] JIS K 2541-2:2003, Crude oil and petroleum products Determination of sulfur content Part 2: Oxidative microcoulometry [111] JIS K 2541-6:2003, Crude oil and petroleum products Determination of sulfur content Part 6: Ultraviolet fluorescence method [112] JIS K 2541-7:2003, Crude oil and petroleum products Determination of sulfur content Part 7: Wavelength-dispersive X-ray fluorescence method [113] JIS K 2301:1992, Fuel gases and natural gas Methods for chemical analysis and testing [114] JPI-5S-49-97, Japan Petroleum Institute Standard, Hydrocarbon Type Testing Method for Petroleum Products using High Performance Liquid Chromatography
41