Data diketahui :

Hf,298 CH4 = -74,520 kJ/mol

Hf,298 CO2 = -393,509 kJ/mol
Hf,298 CO = -110,525 kJ/mol
Hf,298 H2O (g) = -241,818 kJ/mol
Hf,298 H2 = 0
Cpi CH4 = 4,217 x R = 4,217 x 8,314 J/mol.K = 35,060 J/mol.K
Cpi CO2 = 4,467 x R = 4,467 x 8,314 J/mol.K = 37,139 J/mol.K
Cpi CO = 3,507 x R = 3,507 x 8,314 J/mol.K = 29,157 J/mol.K
Cpi H2O (g) = 4,038 x R = 4,038 x 8,314 J/mol.K = 33,572 J/mol.K
Cpi H2 = 3,468 x R = 3,468 x 8,314 J/mol.K = 23,833 J/mol.K

Perhitungan HR pada T = 298 K (HR,298) reaksi 1 :

HR,298

= (3 Hf,298 H2 + Hf,298 CO) (Hf,298 CH4 + Hf,298 H2O)

= (3 x 0 + -110,525 kJ/mol) (-74,520 kJ/mol + (-241,818 kJ/mol))

HR,298

= + 205,813 kJ/mol

Perhitungan HR pada T = 500 K ( HR,500) reaksi 1 :

HR,500 = [3 x (Hf,298 H2 + Cpi H2 . (T 298)) + (Hf,298 CO + Cpi CO . (T-298))]
[(Hf,298 CH4 + Cpi CH4 . (T-298)) + (Hf,298 H2O + Cpi . H2O (T-298))]
= [3 x (0 + 33,572.(500-298)/1000) + (-110,525 + 29,157.(500-298)/1000]kJ/mol
[(-74,520 +35,060.(500-298)/1000) + (-241,818 + 33,572.(500-298)/1000)]kJ/mol
= (20,345 -104,635) kJ/mol (-67,438 235,036) kJ/mol
= 218,184 kJ/mol
HR,298= + 205,813 kJ/mol