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Table Of Contents

Transition metals
Transition metal oxidation states
Transition metal complexes
An example of a complex
Coordination numbers
Stereochemistry
Example geometries
Ligands
Example chelating ligands
Ligandsand oxidation state
Isomerism in metal complexes
Geometrical isomers
Chirality
Chiralmolecules
Properties of chiralmolecules
Optical rotation
Symmetry criteria for chirality
Examples of optical isomerism
Naming enantiomers
∆and Λ
Linkage isomerism
Isolation of isomers
Berry Pseudorotation
Naming of complexes
18 electron rule
Bonding in coordination complexes
d-orbitals
Crystal Field Theory
Octahedral complexes
Colors
Ligandfield splitting
Ligandfield splitting parameters
Tetrahedral complexes
d-orbitalsin tetrahedral complexes
MO theory
Octahedral sigma bonded complex
Orbital energy level diagram for a sigma bonded complex
Ligandsthat can form πbonds
π-donor ligands
π-acceptor ligands
Carbonyl complexes
High spin and low spin complexes
Factors effecting spin state
High spin-low spin equilibria
Experimental methods for determining the spin state
Measuring magnetic properties
Spin only magnetic moments
Magnetic properties
Electronic spectra
complexes
Charge transfer transitions
Ligandfield stabilization energies
Hydration energies
Ionic radii for 3d metals
Lattice energies of 3d oxides MO
Degree of inversion in Spinels
Jahn-Teller effect
Jahn-Teller effect 2
Reactions of complexes
Coordination equilibria
Trends in formation constants
Statistical treatment of successive Kn
Effect of successive reactions
Chelateeffect
Macrocyclicligands
Size selectivity of binding
Rates of reaction
Water exchange rates
Reaction mechanisms
Mechanism of substitution reactions
Associative reactions
The trans effect
Mechanism of the trans effect
Dissociativereactions
Catalysts
Example homogeneous catalysts
A catalytic cycle
Example heterogeneous catalyst
Vitamin B12
Oxygen transport
Oxygen binding in myoglobin
Nitrogen fixation
Anticancer drugs
Anti arthritis drugs
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TRANSITION METAL COMPLEXES

TRANSITION METAL COMPLEXES

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TRANSITION METALS
TRANSITION METALS

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Published by: idownloadbooksforstu on Jul 04, 2013
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12/28/2013

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