13 SPM CH MRSM Trial p1 2 3 Q

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CONFIDENTIAL
4s4ut
Chemistry
Paper 1
September
2013
I 114 hour
SPM TRTAL EXAMINATION 2013
\
MAKTAB RENDAH SAINS MARA
CHEMISTRY
Paper I
:
One hour and fifteen minutes
DO NOT OPEN THE
QUESTION
BOOKLET
UNTIL BEING TOLD TO DO SO.
This question booklet is bilingual
Kertas soalan ini adalah dalam dwibahasa
Candidates are required to read the information at the last page of this question
booklet
Calon dikehendaki membaca maHumat di halaman belakang kertas soalan
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Kertas soalan mp lain terdapat di :
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6g
d\c
Diagram 1 shows an atomic model.
Rajah I menunjukkan suatu model atom.
Electron moves outside
of the nucleus
Eleklron bergerak di luar nukleus
Nucleus that contains protons
Nukleus mengandungi proton
Diagram 1
Rajah I
Who was the scientist that proposed this atomic model?
Siapakah saintis yang mencadangkan model atom infl
J.J Thompson
John Dalton
Ernest Rutherford
James Chadwick
Which of the statements are true for elements belonging to the same group?
Manakah antara pernyataan berikut adalah benar mengenai unsur-unsur yang terletak di dalam
kumpulan yang sama?
I Have similar physical properties
Menunjukkan sifatfizikal yang sama
II Have similar chemical properties
Menunjukkan sifat kimiayang sama
m Have the same number of electrons in the outermost shell
Mempunyai bilangan elektron yang sama di dalam petala terluar
ry Have same number of shells occupied by electrons
Mempunyai bilangan petala berisi elektron yang samct
A
B
C
D
A
B
C
D
I and II
I and IV
II and III
II and IV
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Diagram 2 shows the set-up of apparatus used to prepare hydrogen gas in the
laboratory.
Rajah2 menunjukkan susunan radas bagi penyediaan gas hidrogen di dalam makmal.
Flow of hydrogen gas
Aliran gas hidrogen
Hydrochloric aci
Asid hidroWorik
Solid X
Pepejal X
Diagram2
Rajah 2
Which of the following is solid X?
Manakah antara adalah pepejalX?
Zinc
Zink
Copper(Il) oxide
Kuprum(Il) oksida
Sodium carbonate
Natrium karbonat
Potassium hydroxide
Kalium hidrolcsida
4 A chemical reaction can be represented by the following equation:
Suatu tindak balas kimia boleh diwakili oleh persamaan berikut :
CaCOs + 2HNOr
-+
Ca(NO3)z + HzO + COz
Which of the following are reactants?
Manakah antara berikut adalah bahsn tindak balas?
HzO and COz
HNOg and COz
CaCO3 and HNO3
Ca(I.IO3)z,HzO and COz
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A
B
C
D
A
B
C
D
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5
4
Which of the following is correct about nitrogen dioxide
,
NO2 and
potassium oxide
,
KzO?
Manakah antara berikut benar tentang nitrogen dioksida, NOz dan kalium oksida, K2O?
Nitrogen dioxide
Nitrogen dioksida
Potassium oxide
Kalium oksida
Covalent compound
Sebatian kovalen
Ionic compound
Sebatian ionik
Ionic compound
Sebatian ionik
Covalent compound
Sebatian kovalen
Ionic cornpound
Sebatian ionik
Ionic compound
Sebatian ionik
Covalent compound
Sebatian kovalen
Covalent compound
Sebatian kovalen
Diagram 3 shows how aluminium is extracted by electrolysis process.
Rajah 3 menunjukkan bagaimana aluminium diekstrak menggunakan proses elektrolisis.
Anode (+ve)
Anod(+)
A
C
D
Aluminium oxide
dissolved in cryolite
Aluminium oksida larut
dalam lriolit
Diagram 3
Rajah3
What are the possible substances used as anode and cathode?
Apakah bahan yang mungkin digunakan sebagai anod dan katod?
Anode
Anod
Cathode
Katod
Aluminium Aluminium
Aluminium Carbon
Carbon Aluminium
Carbon Carbon
Cathode(-ve)
Katod(-)
Molten aluminium
Leburan aluminium
A
B
C
D
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Dragram 4
Rajah 4
Diagram 5
Rajah 5
What is substance T?
Apakah bahanT?
A Acid B
Acid
C Water
D
Air
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5
Diagram 4 shows an electrolytic circuit using solid sodium chloride. The butb
in the circuit does not light up.
Raiah 4 menuniuklmn satu litar elektrolisis menggunakan pepejal natrium klorida. Mentol dalam
litar tidak menyala.
Carbon
Karbon
Solid sodium chloride
P ep ej al natrium klor ida
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which of the following changes would cause the bulb to light up?
Manakah antara perubahan berilrut boleh menyebabkan mentol menyala?
A Add more solid sodium chloride into the beaker
Tambahkan lebih banyak pepejal natrium klorida ke dalam bikar
B Add water to the solid sodium chloride
Tambahkan air kepada pepejal natrium klorida
C Add ethanol to the solid sodium chloride
Tambahkan etanol kepada pepejal natrium lclorida
D Replace the carbon electrodes with copper electrodes
Gantikan elektrod karbon dengan elektrod la,prum
Diagram 5 shows how the pH of an industrial waste changes when substance T
is added to it.
Raiah 5 menunjukkan bagaimana pH bahan buangan industri berubah apabila bahan
ditambahkan.
beforeT is added after T is added
sebelwtTditanbah
seldpas Tditanbah
PII
Salt
Garam
Lime
Kapur
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6
Diagram 6 shows the energy level for a chemical reaction.
Rajah 6 menunjukkan aras tenaga bagi satu tindak balas kimia.
Energy
Tenaga
Products
Hqsil tindak balas
Diagram 6
Rajah 6
Which of the following reaction is represented by the energy level diagram?
Manakah antara tindak balas berikut diwakili oleh gambar rajah aras tenqga tersebut?
A Adding water to solid ammonium nitrate
Menambahkan air kepada pepejal ammonium nitrat
B Adding water to solid sodium hydroxide
Menambahkan oir kepada pepejal natrium hidrol<sida
C Dissolving solid potassium hydrogen carbonate in water
Melarutkan pepejal kalium hidrogen karbonat ke dalam air
D Strongly heating solid copper(Il) carbonate
Memanaskan dengan kuat pepejal kuprum(Il) karbonat
Diagram 7 shows a graph of volume of carbon dioxide gas against time.
RajahT menunjukkan graf isi padu gas karbon diolqida melawan masa.
Volume of gas / cm3
Isi padu gas / cm3
tg
Diagram 7
RajahT
The rate of reaction is the highest at
Kadar tindak balas yang tertinggi pada
trs
trs
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B tzs
D tls
A
C
Time / s
Masa / s
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7
Diagram 8 shows apparatus set-up to prepare aqueous copper(Il) sulphate.
Raiah 8 menuniukkan susunan radas untuk menyediakan larutan kuprum(ll) sulfut.
Glass rod
Rod kaca
Solid M
Pepejal M
*\
Aqueous N
I
Filter paper
kertas turas
Excess solid M
pepejal M berlebihan
A
B
C
D
12
B A
D C
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\#
xxx)o(xxxx
flfi
\_/
\%z_Aqueous
Diagram 8
Rajah 8
What are substances M and N?
Apakah bahanM danN?
Substance M
BaltsnM
Substance N
Bolton N
Copper
Kuprum
Iron(II) sulphate
Ferum(ll) sulfat
Copper(Il) chloride
Kuprum(Il) klorida
Potassium sulphate
Kalium suw
Copper(Il) oxide
Kuprum(ll) olcrida
Sulphuric acid
Asid sulfurik
Sulphur
Sulfur
Copper(Il) chloride
Kuprum(Il) klorida
Which of the following represent particles of hydrochloric acid in water?
Manakah antara berikut menunjukkan zarah-zarah.asid hidroklorik dalam air?
copper(Il) sulphate
kupr um(II) s u lfat a ku e s
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A
B
C
D
8
Which of the following is true about ethane?
Manakoh antara berikut benar mengenai etana?
Physical state at
room temperature
KeadaanJizikal
pada
sultu bilik
Reaction with
oxygen
Tindak balas dengan
oksisen
Reaction with
bromine water
Tindak balas dengan
sir bromin
Gas
Gas
Burns
Terbakar
Decolourised bromine
Menyahwarnakan bromin
Gas
Gas
Burns
Terbakar
No reaction
Tiada tindak balas
Liquid
Cecoir
Burns
Terbakar
No reaction
Tiada tindak balas
Liquid
Cecair
Burns
Terbakar
Decolourised bromine
Menyahwarnakan bromin
Diagram 9 shows a blast furnace used to extract iron from iron ore.
Raiah 9 menunjukkan relau bagas yang digunakan untuk mengekstrak besi daripada bijihnya.
iron ore +
coke * limestone
bijihbesi + arangkpk+ batakqnr
waste gases
stsagas
hot air
udaa panas
ruolten irou
besi lebw
t4
fl
snag
sanga
Diagram9
Rajah 9
Why is limestone added to the furnace?
Mengapakah batu kapur ditambahkan ke dalam relau?
A To increase temperature in the furnace
Meningkatkan suhu dalam relau
B To convert impurities in the ore into slag
Menukar bendasing dalam bijih kepada sanga
C To produce oxygen for burning the coke
Menghas ilkan o l<s igen untuk memb akar ko k
D To change the ore into iron
Menukqrkan bijih kepada besi
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15
9
Which of the following pairs is correct?
Manakah antara pasangan berikut adalah benar?
A
B
C
D
)
I
i
c
*
U
Homologous series
Siri Honnlog
General formula
Formula ant
Alkane
Alkana
CnHzn,[:2r3..
Carboxylic acid
Asid karboksilik
CrHzn+tCOOC*Hzm+t
tD
:
0, 1,2... m:l,2..
Alcohol
Alkohol
CnHzn+rOH, tr:1,2,3..
Ester
Ester
C'Hz'+TCOOH
,
r: 0,1,2...
16
Iron screw
Skru besi
Nitro
Nitrogen
Iron screw
Skru besi
17
SULIT
A group of students are given iron screws to conduct experiment on rusting.
In which test tube does the iron screw rust?
Selatmpulan pelajar dibekolkan slru besi untuk menjalankan eksperimen mengenai pengaratan.
Dalam tabung uji manakah slcru besi akan berkarat?
B A
Air
Udara
Iron screw
Skru besi
Iron
Slcru besi
D
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D C
Which picture shows a common use of stainless steel?
Manakah antara gambar berikut menunjukkan kegunaan keluli nirkarat?
ffi*fu
B A
10
18 The following equation shows the reaction between potassium hydroxide solution
and nitric acid.
Persamaan berikut menunjukkan tindak balas antara larutan kalium hidrotrsida dan asid nitrik.
KOHlaql+ HNO:(aq)+ KNO312q1 +
HzO1ll AH: -57 kJmol-l
Which of the following statements is true?
Manakah antara pernyataan berikut adalah benar?
A Total energy content of reactants is lower than products
Jumlah kandungan tenaga bahan tindak balas lebih rendah dari hasil tindak balos
B The heat is absorbed from the surroundings
Haba diserap dari persekitaran
C The temperature of the mixture rises
Suhu campur an meningkat
D The reaction is endothermic
Tindak balos ini adalah endotermik
19 Why does the excessive use of aspirin can cause stomach ulcer ?
Mengapa penggunaan aspirin secara berlebihan menyebabkan ulser perut ?
A Aspirin can react with food to produce poisonous products
Aspirin boleh bertindak balas dengan makanan untuk menghasilkan produk beracun
B Aspirin can react with gastric juice
to produce acid
Aspirin boleh bertindak balas dengan jus gastrik untuk menghasilkan asid
C Aspirin contains poisonous substances
Aspirin mengandungi bahan beracun
D Aspirin contains acid
Aspir in mengandungi as id
20 The following shows examples of food additive.
Berikut adalah contoh-contoh bahan tambah maksnan.
.
Sodium beruoate
Natrium benzoat
o
Vinegar
Cuka
.
Sodium nitrite
Natrium nitrit
Which type of food additive do the substances belon g to?
Apakah jenis
bahan tambah makanan bagi bahan di atas?
A
y;:tr::*,
B Preservatives
Pengawet
c
XlXyo""n*
D stabilizer
Penstabil
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2t
11
Diagram l0 shows a process involving the molecules in the exhaust gas of a car.
Raiah l0 menunjukkan proses melibatkan molekul-molekul gas dalam ekzos sebuah kereta.
molecules in air
molehd dalanudoa
/
\\
N=
/.""\\
@j..ql""""
->
molecules io exhaust gas
moleladdalatt gas ebos
Diagram 10
Rajah l0
Which statement describes the process?
Manakah antaro pernyataan berikut menerangkan proses itu?
A The molecules condense to the ground
Molekul-molekul terkondensasi ke tanah
B The molecules grouped as they cool
Mo lekul-molekul terkumpul apabila menyejuk
C The molecules spread further into the air
Molekul-molekul tersebar ke udara
D The molecules stay where they are
Molekul-molekul kekal di tempat asal
Diagram 1 I shows the standard representation of P
, Q
and R.
Rajah ll menunjukkan perwakilan piawai bagiP
, Q
dank
Diagram 11
Rajah 11
What can be deduced from the proton number and the nucleon number of
P,QandR?
Apakahyang dapat dirumuskan daripada nombor proton dan nombor nukleon P,
Q
danR?
oo
to
u'
.ooo
o!0to
.
I
to'o
too
i
.o +
E
o
q
L
(I)
=
.C,
o
o
o
.C
o
@
E
;
=
=
E
o
q
c
o)
L
=
o
o
o
c)
a
E
t
=
=
22
A R has more neutrons than
Q
R mempunyai lebih banyak neutron berbanding
Q
B P has more protons than
Q
P mempunyai lebih banyak proton berbandingQ
C P and R are the same element
P danR adalah unsur yang qama
D P and
Q
are the same element
P dan
Q
adalah unsur yang sama
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24
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T2
An element melts at 1455
oC
and forms a green chloride compound.
Which of the following shows the position of this element in ihe Periodic Table?
Suatu unsur melebur pada 1455
oC
dan membentuk sebatian klorida berwarna hijau.
Manakahyang berikut menunjukkan kedudukan unsur ini dalam Jadual Berkala?
Diagram 12 shows the energy profile diagram for the decomposition reaction of
potassium chlorate(V).
Rajah 12 menunjukkan gambar rajah profil tenaga bagi tindak balas penguraian
kalium klorat (Y).
Energy
Tenaga
Diagram 12
Rajah 12
which of the following is true about curve R and curve s?
Manakah antara berilrut benar mengenai lenglamgR dan tengkung s?
A Curve R occurs at a higher temperafure than curve S
LenglatngR berlalru pada suhu yang lebih tinggi berbanding lengtamg S
B Curve S is produced when less pressure is applied to potassium
chlorate(V)
Lenglamg S dihasilkan opabila tekanan yang lebih rendah dikenakan ke atas kalium
klorat(Y)
C Curve R is produced by using a larger amount of potassium chlorate(V)
LenglamgR dihasilkan dengan menggunakan kalium klorat(Y) yang lebih banyak
D Curve S is produced
by adding manganese(IV) oxide
Lenglamg s dihasilkan dengan menambahkan mangaz(IV) otrsida
2KClOg
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25
26
Metal K
Logam K
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13
ElementY forms ion Y-. The electron arrangement of ion Y- is 2.8.
Where is the position of element Y in the Periodic Table?
Unsur Y membentuk ionY-. Susunan elektron bagi ion Y'ialah2.8.
Manakah kedudukan unsur Y dalam Jadual Berkala?
A Group 1
B Group 2
C Group 17
D Group 18
Diagram l3 shows the apparatus set-up of a simple voltaic cell.
Rajah 13 menunjukkan susunan radas bagi satu sel kimio ringkas.
Metal L
Logam L
Sulphuric acid
Asid sulfurik
Diagram 13
Rajah 13
Which metals could be used as K and L to produce the highest voltmeter reading?
Logam manakahyang boleh digunakan sebagaiK dan L untik menghasilkan bacaanvoltmeter
tertinggi?
I Zinc
Zink
II Iron
Ferum
m Copper
Kuprum
IV Aluminium
Aluminium
I and II
I and III
II and III
III and IV
A
B
C
D
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l4
Diagram 14 shows the electron zurangement of a carbon dioxide molecule.
Rajah 14 menunjukkan susunon elektron bagi molekul karbon dioluida.
Diagram 14
Rajah 14
Which of the following is true?
Manakah antara berikut adolah benar?
A Each oxygen atom contributes one electron for sharing
Setiap atom ol<sigen menyumbang satu elektron untuk dikongsi
B One carbon atom contributes four electrons to be shared by two oxygen
atoms
Satu atom karbon menyumbang empat elektron untuk dikongsi dengan dua atom olcigen
C Four double covalent bonds are formed in a carbon dioxide molecule
Empat ikatan kovalen ganda dua terbentuk dalam molekul karbon dioksida
D One carbon atom requires two electrons to achieve the octet electron
arrangement
Satu atom karbon memerlukan dua elelctron untuk mencapai susunan elektron oktet
The following equation represents the reaction between magnesium and
oxide.
Persamaan berikut mewakili tindak balas antara mognesium dan zink oksida.
Mg +
ZnO MgO + Zn
Which of the following statements is true about the reaction?
Manakah antara pernyataan berikut benar mengenai tindak balas tersebut?
A Magnesium is reduced
Magnesium diturunkan
B Zinc is an oxidizing agent
Zink adalah agen pengol<sidaan
C Oxidation number of zinc decreases from +2
to 0
Nombor pengoksidaan zink berkurang dari +2 ke 0
D Magnesium atom gain electron
Atom magnesium menerima elektron
28
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ZffIC
0
0 0
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30
15
Diagram l5 shows an apparatus set-up to identify the cations present in
mixture X.
Raiah 15 menuniukkan susunan radas untuk mengenal pasti kation yang hadir dalam campuranX.
Red litmus pape
Kertos litmus merah
X +
NaOH
L
t
Heat
Panaskan
Diagram 15
Rajah 15
When mixture X is heated with sodium hydroxide solutior
,
& green precipitate is
formed and red litmus paper turns blue.
Which cations are present in X?
Apabila campuranX dipanaskan bersama larutan natrium hidrol<sida, mendakan hijau terbentuk
dan kertas litmus merah bertukar ke biru.
Apakah kation yang hadir dalamX?
A NHa* and Fe2+
C Na* and Cu2*
Table I shows theproton number of four elements, R, S, T and U.
Jadual I menunjukkan nombor proton bagi empat unsur,
&
S, T danll.
Element
Unsur
Proton number
Nombor oroton
R 10
S t2
T t4
U 20
Table I
Jadual I
Which of the following is the correct ascending order for the atomic size of
elements R, S, T and U?
Manakah antara berikut susunan secara menaik yang betul bagi saiz atom unsur R, S, T danU?
A U,T,S,R
C R,T,S,U
B NH4* and Fe3*
D Pb2* and Cu2*
B R,S,T,U
D U,S,T,R
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t6
Table 2 shows the information about the reactants used in Experiment I and II.
JadualZ menunjukkan maklumat mengenai bahan tindak balas yang digunakan di dalqm
El<sperimenl danII.
Experiment
Eksperimen
Reactants
Balton tindak balas
I
25 cm3 of 0.5 mol dm-3 sulphuric acid and excess
zinc powder
25 cm3 asid sulfurik 0.5 mol dm-3 dan serbuk zink berlebihan
II
25 cm3 of 0.5 mol dm-3 hydrochloric aci,C and
excess zinc powder
25 cm3 asid hidroklorik0.5 mol dm'3 dan serbuk zink
berlebihan
Table 2
Jadual2
Which of the following graphs represents the reaction in Experiment I and II?
Manakah antara graf berikut menunjukkan tindak balas dalam Eksperimenl danll?
Volume of
H2 gas /cm3
Time/s
Volume of
Hz
Bas
lcm3
Time/s
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A
B Volume of
H2 gas /cm3
Volume of
H2 gas /cm3
D C
Time/s
Time/s
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t7
32 Diagram 16 shows the process of producing compound M.
Rajah 16 menunjukkan proses penghosilan sebatianM.
Ethanol
,
CzHsOH
Etonol
Acidified KMnOa
KMnO4 berasid
Diagram 16
Rajah 16
V/hich of the following is the structural formula of compound M?
Manakah antara berikut merupakanformula struktur bagi sebatianM?
o
A
cH3 [- oH
B
CHz
:
CHz
o
cll
cHs- c- o'- cHs
D cHs- cHz- cH2- oH
33 Which of the following can be converted to polymer through polymerisation?
Manakah antara berikut boleh ditukarkan kepada polimer melalui tindak balas pempolimeran?
o,
il
H-G-O-CHl
cH2: C-CH
I
H
-CHl
A IandII
B II and III
C II and IV
D III and IV
3 Hak Cipta Majlis Arnanatr
II
ry m
(},
II
EN_C_OH
CH^- C
-
CH"
'Lr'
cHr
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34
Iron(II) nitrate
Ferum(II) nitrat
35
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18
Diagram 17 shows the apparatus set-up to investigate the reaction between
iron(Il) nitrate and liquid bromine.
Rajah 17 menunjukkan susunan radas untuk mengkaji tindak balas antara larutanferum(Il) nitrat
dan air bromin.
Carbon
Karbon
Liquid bromine
Air bromin
Nitric acid
Asid nitrik
Diagrarn 17
Rajah 17
What is the colour change for both of the solutions?
Ap akah perub ahan w arna b agi kedua-dua larut an?
Iron(I) nitrate solution
Larutan ferum(Ill nitrot
Liquid bromine
Air bromin
Brown to green
Perans kepada hiiau
Colourless to brown
Tanp a w arna kepada Deranp
Green to brown
Hiiau kepada Derans
Brown to colourless
P erang kepada tanpa warna
Brown to green
Perans kepadahiiau
Remains brown
Kekal Deranp
Green to brown
Hiiau kepada Derans
Remains colourless
Kekal tanpawarna
Element
Q
is below bromine in Group 17 of the Periodic Table.
Which pair correctly describe the reaction between
Q
and sodium?
Unsur
Q
berada di bawah bromin dalam Kumpulan 77 Jadual Berkala.
Manakah antara pasangan berikut benar mengenai tindakbalas antaro
Q
dan natrium?
A
B
C
D
A
B
C
D
Formula of the compound
Formula sebatian
Reactivity compared to bromine
Kereaktifan b erb andfug dengan bromin
NaQ
less reactive
kurang reahif
NA2Q
less reactive
kurangreaWif
NuQ,
more reactive
lebih reaWif
NaQ
more reactive
lebih reaWif
[Lihat
halaman sebelah
19
36 Temperature of water rises by 30.0'C when 0.929 propanol is used to heat
200 cm3 of water.
What is the heat released in the reaction?
[specific
heat capacity
:4.2J
g-'oc-', density of solution
-
1.0 g cm-3
]
Suhu air meningkat sebanyak 30
oC
apabila 0.92 g propanol digunakan untuk memanaskan
200 cm3 air.
Berapakah nilai haba yang dibebaskan di dalam tindak balas tersebut?
LKapasiti
haba spestfik:4.21*-l
og-1,
ketumpaton larutan: 1.0 g cm-3]
A 1t5.92 l
B 5796 I
c 25200 l
D 1260000 J
37 Which of the following has the smallest volume of gas at room condition?
[Molecular
mass /g mol-l : NH3
:
lTiHzO
:
18, CO
:28i
NOz
:46,
1 mol of any gas occupies 24 dm3 at room condition]
Manakah antara berikut mempunyai isi padu gas terkecil pada keadaan bilin
[Jisim
molar/ g mol-r; HzO
:18,
CO=28; NHr
:
17;NO,
:46,
I mol sebarang gas menempati 24 dm3 pada keadaan bilikl
A 42.0 g of carbon monoxide
42.0 g karbon monol<sida
B 23.0 g of nitrogen dioxide
23.0 g nitrogen diolcsida
C 17 .0 g of ammonia
17.0 g ammonia
D 12.0 g of steam
12.0 gwap air
38 3.2 gof sulphur is burnt in oxygento form 8.0 g oxide of sulphur.
What is the empirical formula of the compound?
[Relative
atomic mass: S
-32;
O
:16]
3.2 g sulfur terbakar dalam oksigen membentu& 8.0 g ol<sida sulfur.
Ap a ka h
fo
r mul a emp ir ik b a g i s eb at i an t er s ebut?
[Jisim
atom relatif : S =32; O
:16]
A SOz
B SzO
C SOr
D SzOr
454t/l @2013 Hak Cipta Majlis Alnanah Rakyat, MARA
[Lihat
halaman sebelah
SULIT
20
39 Which of the following chemical compound is the best fertilizer for growth of
plants?
[Relative
atomic mass : N
:
14
,
Relative molecular mass: CaOIOg)2: 164,
NI{4NOr: 80, (NH+)zSO+
:
132, (NH+):PO+: l49l
Manakah antara bohan kimia berilan merupakan baja paling baik digunakan untuk tumbesaran
tumbuhan?
lJisim
atom relatif. N = 14
,
Jisim molekul relatif : Ca(NO3)
2:
164, NH4NO3: 80,
CNIH4)2SO a:
132,
OIH4)3PO a:
l49l
A Calcium nitrate, CaQ.{O3)2
Kalsium nitrat
B Ammonium phosphate,
CNH+):PO+
Ammonium
fosfat
C Ammonium sulphate, (NH+)zSO+
Ammonium sulfat
D Ammonium nitrate, NF{+NOg
Ammonium nitrat
4A Label on bottles of glucose, sodium chloride and sodium hydroxide were
accidentally removed. A student tested a sample from each bottle and results are
shown in Table 3.
Label botol bagi glukosa
,
natrium Horida dan natrium hidrol<sida telah tertanggal. Seorang
pelajar telah menguji setiap sampel daripada botol-botol tersebut dan keputwan ditunjukkan dalam
Jaduol 3.
Bottle
Botol
Addition of water
Penambahan dengan air
Electrical conductivity of solution
Kekonduksian elektrik larutan
I Forms an alkaline solution
Memb entuk I arut an alkali
Conducts electricity
Mengalirkan elektrik
2
Forms a neutral solution
Memb entuk larut an neutr al
Conducts electricity
Mengalirkan elektrik
3
Forms a neutral solution
Memb entuk I arut an neutr al
Does not conduct electricity
Tidak mengalirkan elektrik
Table 3
Jadual 3
What are the correct labels for each bottle?
Apakah label yang betul bagi setiap botol?
Bottle I
Botoll
Bottle 2
Botol2
Bottle 3
Botol3
Sodium hydroxide
Natrium hidrol<sida
Sodium chloride
Natrium klorida
Glucose
Glukosa
Sodium hydroxide
Natrium hidrol<sida
Glucose
Glukosa
Sodium chloride
Natrium Horida
Sodium chloride
Natrium Horida
Glucose
Glul<osa
Sodium hydroxide
Natrium hidrol<^sida
Glucose
Glukosa
Sodium hydroxide
Natrium hidrolsida
Sodium chloride
Natrium Horida
454lll 02013 Hak Cipta Majlis Amanah Rakyat, MARA
[Lihat
halaman sebelah
SULIT
A
C
D
4t
42
4541/L
SULIT
2t
Diagram 18 shows the apparatus set-up for electrolysis of 1.0 mol dm-3 copper(Il)
nitrate solution using copper electrodes.
Rajah 18 menunjukkan susunan radas bagi elektrolisis larutan kuprum(Il) nitrat 1.0 mol dm-3
m enggunqkan el ektr o d kuprum.
Copper
Kuprum
Copper(Il) nitrate solution
Kuprum(Il) nitrat
Diagram 18
Rajah 18
Which of the following arc observation at the anode and cathode?
Manakah antara berikut merupakan pemerhatian di anod dan katod?
At the anode
Di anod
At the cathode
Di katod
Electrode become thinner
Elektrod menjadi nipis
Brown solid deposited
Pepejal perang terenap
Electrode become thinner
Elektrod menjadi nipis
Colourless gas released
Gas tidak berwarna terbebas
Greenish yellow gas released
Gas kuning kehijauan terbebas
Brown solid deposited
Pepejal perang terenap
Table 4 shows information about three chemical cells.
Jadual4 menunjukkan makluntat bagi tiga sel kimia.
Table 4
Jadual 4
Arrange the metals from the most electropositive to the least electropositive.
Susun logam tersebut daripada yang paling elektropositif kepada yang paling latrang
elektropositif,
A
C
D
B
D
A
C
H,G,F,E
F,G,H,E
E,G,H,F
E,H,G,F
Chemical cell
Sel kimia
Pair of metal electrodes
Posangan elektrod lo gam
Voltage / V
Voltan /Y
Positive terminal
Terminal positif
I E,F 2.7 F
II E,G 1.5 G
m G,H 0.6 G
@2013 Hak Cipta Majlis AmaaahRakyat,,MARA
[Lihat
halaman sebelah
4,4
43
454t/t
SULIT
10 cm3
20 cm3
50 cm3
90 cm3
22
What is the concentration of hydroxide ions when 8.55 g solid barium hydroxide
is dissolved in water to produce2l} cm3 of solution?
[Molar
mass of Ba(OH)r: l7t gmol-r]
Apakah kepekatan ion hidroksida apabila 8.55 g pepejal barium hidroksida dilarutkan dalam oir
untuk menghasilkan250 cm3 larutan ?
lJisim
molar Ba(OH)z
:
17 | g molrl
A 0.40 mol dm-3
B O.2O mol dm-3
C 0.05 mol dm-3
D 0.01 mol dm-
Diagram 19 shows two volumetric flasks containing2.0 mol dm-3 of hydrochloric
acid and0.2mol dm-3 hydrochloric acid.
Rojah 19 menunjukkan dua kelalang volumetri yang mengandungi asid hidroWorik 2.0 mol drn-3
dan asid hidroklorik 0.2 mol dm-3.
qF
2.0 motdm-3
E A
too cm3 of o.2mot dm-3
hug;2htoncacid
- Efl l{i:T,Y:;i;::f,,,,r
2.0 mol dm-3 0.2 mol dm-3
Diagram 19
Rajah 19
What is the volume of water needed to be added to prepare 100 cm3 of
0.2 mol dm-3 hydrochloric acid from 2.0 mol dm-3 hydiochloric acid?
Berapaknh isi padu air perlu ditambah untuk menyediakan 100 cm3 asid hidroHorik0.2 mol dm'3
daripada asid hidroklorik2.0 mol dm'3?
A
B
C
D
@2013 Hak Cipta Majlis Amanah Rakyat, MARA
[Lihat
halaman sebelah
45
46
23
Diagram 20 shows a series of reaction involving salt V.
Rajah20 menunjukkan siri tindak balas melibatkan garamy.
+
Barium chloride solution
Larutan barium Horida
White precipitate W
Mendakan putihW
A
B
C
D
*
Excess aqueous afitmonia,NH3
Amm onia akues b erl eb ihan,Ntl3
White precipitate,
dissolves in excess NH3
Mendakan putih,
I arut di dalam Nt\ berlebihan
Diagram 20
Rajah 20
Which of the following pairs represent solid V and precipitate W?
Manakah antaro yang berikut mewakili pepejalY dan mendakanW?
Salt V
GarumY
Precipitate W
Mendakan W
Lead(II) nitrate
Plumbum(Il) nitrat
Zinc chloride
Zink Horida
Zinc sulphate
Zink sulfat
Barium sulphate
Barium sulfat
Zinc nitrate
Zink nitrat
Barium chloride
Barium klorida
Aluminium sulphate
Aluminium sulfat
Aluminium nitrate
Aluminium nitrat
Table 5 shows the total volume of gas collected for every 30 second in areaction.
Jadual 5 menunjukkan jumloh
isi padu gas terkumpul setiop 30 saat dalam satu tindak balas.
Time / s
Masa / s
0 30 60 90 120
Volume of gas/ cm3
Isi padu gas/ cm3
0 w x Y Z
Table 5
Jadual 5
\Ie$ is the avtrago rate of reaction in the second minute?
B.er4palrah kad* ptrata ttndak balas pada minit kedua?
cm3 s'l A*
Z-X t
-r
G;60m-8'
Z-Y ?
-r
cm-s'
120-90
Z?-r
cm-s'
120
B
D c
24
47 Diagram 21 shows the structural formula of compound G which formed from the
reaction between compould E and F.
Raiah2l menunjukkanformula struhur bagi sebatian G yang terbentuk daripada tindak balas
ontara sebatianE donF.
Compound E
SebatianE
Compound F
SebatianF
+
I
+
o
ll
cHr- cHz
-
C
-O -
CHe
-CHe-
CHz
-
CHr
Compound G
Sebatian G
Diagrarn 2l
Rajah2l
What is compound E and F?
Apakah sebatianE danF?
Compound E
Sebatian E
Compound F
SebatianF
Butanoic acid
Asid butanoik
Propanol
Propanol
Propanoic acid
Asid propanoik
Butanol
Butanol
Ethanoic acid
Asid etanoik
Propanol
Propanol
Ethanoic acid
Asid etanoik
Butanol
Butanol
48 Which of the following has the same number of atoms as in one mole of water,
HzO?
Manakah antara berikut mempunyai bilangan atom yang sama dengan satu mol air, H2O ?
A I mol chlorine gas, Cl2
I mol gas klorin, Cl2
B
T;:IffiIJ"1;Y,
c
'(;#r',il#i:;x'o'
'D % mol sulphur dioxide, SOz
% mol sulfur diolaida, SO2
4541/r Cipta Majlis Amar
SULIT
A
C
D
25
49 Table 6 shows the method used to extract metal J, K and L from their ores.
Jadual6 menuniukkan kaedah pengelcstrakan logam l,K danL daripada bijih masing-masing.
MetaI
Logam
Method
Ifuedalt
J
Reduction using carbon
P enurunan menggunakan kar bon
K
Electrolysis
Elektrolisis
L
Reduction by hydrogen
P enurunan ol eh hi dr o gen
Tab1e 6
Jadual 6
What is the correct arangement of the reactivity of metals in the ascending order?
Apakah susunan yang betul bogi kereaktifan logam mengikut tertib menaik?
A L,J,K
B J,L,K
C K,L,J
D K,J,L
=
g
50 When 100 cm3 of 1.0 mol dm-3 hy,Cro"hloric acid reacts with 100 cm3 of
a
1.0 mol dm-3 potassium hydrogen carbonate solution, the temperature decreased
3
by OoC.
o-
What is the decrease in temperature for the reaction when 50 cm3 P
c)
of 1.0 mol dm-3 hydrochloric acid reacts with 50 cm3of 1.0 mol dm-3 potassium
3
hydrogen carbonate solution?
Apabila 100 cm3 asid hidroktorik 1.0 mol dm3 bertindak balas dengan 100 cm3 larutan kalium
hidrogen karbonat 1.0 mol dm-', suhu berlatrang sebanyakO
oC.
Berapakah penurunan suhu bagi tindak balas apabila 50 cm3 asid hidroklorik 1.0 mol dm'3
bertindak balas dengan 50 cm3 larutan kalium hidrogen karbonat 1.0 mol dm-3?
A 0.1e
oc
B 0.5e
oc
C EOC
D }EOC
END OF
QUESTION
PAPER
KERTAS SOAI-AN TAMAT
454112
Chemistry
Paper 2
September
20L3
2%how
Namg I ............. o........... o.... o.
'." "
t
"
t'
Indgx Number! .............. o. t....... t. r..t.. t.
I
(
D
a
a
rd
h{
rrl
U
SIJIL PELAJARAN MALAYSIA
TRTAL EXAMINATION
2013
1.
CIIEMISTRY
Paper 2
Two hours and thirty minutes
DO NOT OPEN THE
QUESTION
BOOKLET
UNTIL BEING TOLD TO DO SO
Write your name and index number in the
space provided.
Tuliskan nama dan angka giliran anda pada ruang
yang disediakan.
The question booklet is bilingual.
Kertas soalan ini adalah dalam dwibahaso.
Candidate is required to read the information
on page 28.
Calon dikehendaki membaca maklumat di halamanZS-
www. myschoolchildren.com
2.
3.
Untuk ke gunaan p emerilcs a
Section
Question
Full
mark
Marks
A
I 9
2 9
3 t0
4 10
5 1l
6 11
B
7 20
8 20
C
9 20
10 20
TOTAL
CONFIDENTIAL
This booklet contains 28 printed pages.
454112 @ 2013 Copyright Reserved MARA
454U2
(a)
Section A
Bahagian A
[60
marl<s)
[60
markahl
Answer all questions in this section.
Jawab semua soalan dalam bahagian ini.
Diagram 1.1 shows the uses of lemon grass in daily life.
Rajah l.l menunjukkan kegunaan serat dalam kehidupan seharian.
Tomyam soup
Sup Tomyam
Lemon grass
Serai
Lemon grcss balm
Balsam serai
Diagram 1.1
Rajah l.l
(i) state the type and function of lemon grass as food additive.
Nyatakan jenis
danfungsi serai sebagai bahan tambah makanan.
Type:
...................
Jenis
Function:. . .
Fungsi
[2
marlcs]
[2
markah)
State the uses of lemon grass balm.
Nyatakan kegunaan balsam serai.
ll
mark)
U
marlcahl
For
Examiner
Use
1(a)(i)
(ii)
[Soo
next page
CONTIDENTIAL
1(aXii)
For
ixaminer's
Use
1(axi)
1(6Xii)
t_l
1(bxiii)
454112
(D) Diagram 1.2 shows a flow chart to produce fertilizer Z.
Rajah 1.2 menunjukkan carta alir untukmenghasilkan bajaZ.
(i)
Haber Process
Proses Haber
lfl
s,
Ammonia
Ammonia
Diagram 1.2
Rajah 1.2
Name industrial Process X.
Namalran Pros es in&tstri X.
I
markl
[1
markah]
State two raw materials needed for industrial Process X.
Nyatakan dua bahan mentahyang diperlukan dalam Proses industriX.
I
2
[2
marla)
[2
markah]
with ammonia to produce fertilizer Z.
balas dengon ammonia untuk menghasilkan baja Z.
(ii)
(iii) Sulphuric acid reacts
Name ferfilizer Z .
Asid sulfurik bertindak
Namakan baja Z.
fl
markl
ll
markahl
[See
next page
CONFIDENTIAL
Industrial Process X
Proses Industri X
$
Sulphuric Acid
Asid Sulfurik
4541/2
(iv) Detergent is also a product
cleansing agent in hard water.
Explain why.
Detergen
juga
adalah produk asid
berkesan dalam air liat.
Terangkan mengapa.
of sulphuric acid and effective
sulfurik dan merupakan bahan penctrci
ll
markl
ll
narkahl
(v) During the manufacture of sulphuric acid, excess sulphur dioxide
gas is released to the environment .
How does sulphur dioxide gas cause pollution ?
Semasa pembuatan asid sulfurik, gas sulfur diol<sida berlebihan terbebas lce
persekitaran.
Bagaimanakah gas sulfur dioksida menyebabkan pencemaran?
I
markl
ll
markahl
[See
next page
CONFIDENTIAL
4
For
Examiner ''s
Use
1(bXiv)
1(DXv)
For
Examiner's
Use
2(b)
2(a)
n
2(c)(i)
2(c)(ii)
454U2
Diagram 2 shows part of the
periodic
Table of Elements.
Rajahz menunjukkan sebahagian daripada Jadual Berkala
(Jnsur.
Diagram2
Rajah 2
Based on DiagramZ:
Berdasarkan Rajah2:
(a)
What is the physicat state of chlorine at room temperature?
Apakah keadaanfizikunsur
Horin pada suhu bitik?
ll
marlcl
11
markahj
(b)
choose one element that can form an amphoteric oxide?
Pilih satu unsur yang boleh membentuk oksida amfoterik?
ll
markl
ll
markah)
(c) (i)
(ii)
Write the electron arrangement for argon atom.
Tulis susunan elektron bagi atom argon.
ll
markl
ll
markahl
Explain why argon exists as monoatomic gases.
Terangkan mengqpa argonwujud sebagai gas monoatom.
ll
markl
fi
markahl
[See
next page
CONFIDENTIAL
4541D @ 2013 Copyright Reserved MARA
454112
For
Examiner's.
(d) Carbon bums in excess oxygen to form carbon dioxide gas.
Karbon terbakar dalam oluigen berlebihan untuk menghasilkan gas karbon diolsida.
(i) Explain why carbon dioxide gas has low boiling point.
Terangkan mengapa gas karbon diol<sida mempunyai takat didih rendah.
[2
marks)
p
markahl
(ii) Write a balanced chemical equation for the formation of carbon
dioxide.
Tulis persamaan kimia yang seimbang untuk pembentukan lcarbon dioksida.
(iii) Draw the electron arrangement of the carbon dioxide molecule.
Lukis susunon elelrtron bogi molekul karbon dioksida.
I
mark)
ll
marluhl
{2.
metrksl
{2
mar,lcahl
[See
nextpage
ffiNFIDENTIAL
Use
2(dKi)
z(A$i)
t_l
2(dxiii)
TOTAL A2
9
4541t2 @ 2Ol3 Copyright Reserved MARA 6
For
Examiner's
Use
3(a)(i)
3(aXiv)
4541/2
Diagram 3.1 shows the apparatus set-up of a voltaic cell
Raj ah 3 .l menunjukkan susunan radas bagi suatu sel voltan
p
.
Magnesi
P.
Copper
Kuprum Magnesium
Magnesium nitrate
solution
Larut an m agnes ium nitr at
Based on Diagram 3.1,
Berdasarkan Rajah 3.1,
(i)
Porous pot
Pasu berliang
Copper(Il) sulphate
solution
L arut an lary rum(l[) s ulfat
Cell P
SelP
Diagram 3.1
Rajah3.l
(a)
What is the function of porous pot?
Apakah
fungsi
pasu berliang)
11,
markl
I
markah)
(ii)
(iv)
State the negative terminal of the voltaic cell.
Nyatakan terminal negatif bagi sel voltan.
I
marlcl
fl
markahl
(iii) Explain your answer in (a)(ii).
Terangkan jautapan
anda dalam (aXii).
[1
mark)
I
markahJ
Name the type of reaction that occurred at copper electrode.
Namakan jenis
tindak balas yang berlalru di elektrod kuprum.
fl
mark)
l1
markahJ
[See
next page
CONFIDENTIAL
l:]::
I
-::
t;::
I
-r
\tr
;::l
i=l
::J
\:J
-l
il
i]
4541f2 @ 2013 Copyright Reserved MARA
(b) Diagram 3.2 shows an incomplete ceIl
Q
to electroplate an iron ring with
silver.
Rajah 3.2 menunjukkan Sel
Q
yang tidak lengkap untuk menyadurkan cincin besi
dengan argentum.
Magnesi
Magnesium
ilver nitrate
solution
Larutan
argentum nitrat
Magnesium nitrate
solution
Larutan magnesium
nitrate
Diagram 3.2
Rajah3.2
Complete the diagram of Cell
Q
in the space provided.
Lengkapkan rajah bagi Sel
Q
dalam ruangyang disediakan.
State one observation in CeII
Q
after 30 minutes.
Nyatakan satu pemerhatian dalam Sel
Q
selepas 30 minit.
Kuprum Copper(Il) sulphate
Kuprum(Il) sulfut
454v2
12
marksl
12
markahl
For
Examiner's
I
1,,,,,,,
t:
t:
lr::
llr"r"-
I[r
(i)
(ii)
ll
markl
ll
markahl
(iii) Write the half equation for the reaction occurred at the iron ring
Tulis setengah persamaan bagi tindak balas yang berlalcu pada cincin besi.
(iv) What happens to the concentration of silver ions in Cell
Q.
Explain your answer.
Apakahyang berlaku pada kepekatan ion argentum dalam.Sel
Q.
Ter angkan
j
au ap an anda.
ll
markl
ll
markahl
12
marksl
p
markahl
[See
next page
CONFIDENTIAL
For
Exqminer',
Use
{
t/
F
a
hl
FT
a
rd
F(
U
4s4t/2
4 Three experiments, I
,
II and III are cuuried out at room condition to investigate
factors affecting the rate of reaction between nitric acid and zinc metal.
Tab1e 4 shows the reactants and conditions of the reaction.
Tiga eksperimen, I
,II
dan III dijalankan untuk mengkaji
faWor
yqng mempengaruhi kadar tindak
balas antara asid nitrik dengan logam zink.
Jodual4 di bawah menunjulckan bahan-bahan dan keadaan tindak balas yang terlibat.
Experiment
Eksperimen
Reactant mixture in the experiment
Campuron bahan dalom eksperimen
Time
Masa
(s)
Volume of gas
Isi padu gas
(cm3)
4.0 g zinc granules
4.0 g ketulan zink
20.0 cm3 nitric acid 1.0 mol dm-3
20.0 cm3 asid nitrik I.0 mol dm-3
60 50
II
4.0 g zinc powder
4.0 g serbuk zink
20.0 6m3 nitric acid 1.0 mol dm-3
20.0 cm3 asid nitrik 1.0 mol dm-3
45 50
m
20.0 cm3 nitric acid 1.0 mol drn-3 +
copper(Il) sulphate solution
20.0 cm3 asid nitrik 1.0 mol dm'3 +
larutan kuprum(Il) suW
4.0 gzincpowder
4.0 g serbuk zink
25 50
Table 4
Jadual 4
[See
next page
CONFIDENTIAL
4541n @ 2013 Copyright Reserved MARA 9
454U2
State the meaning of th e rate of reaction.
Nyatakan maksud kadar tindak balas.
$
mark)
I
markahl
State the factor that differentiate the rate of reaction between
Experiment I and II.
Nyatakanfaktor yang membezakan kadar tindqk balas antara
El<sperimenl danII.
ll
mark)
l1
markahl
For
Examiner's
Use
(a) (i)
(b) Write the ionic equation for the reaction in Experiment IIL
Tuliskan persamqan ion bagi tindak balas dalam EksperimenIII.
(ii)
I
a(aXi)
lr:
I
|
+("Xii)
lr:
I
lft
a(cXi)
[]
(i)
12
marlrsl
12
markahl
(c) The result for Experiment II is represented by Graph 4.
Keputusan bagi eksperimenll diwakili oleh Graf 4.
Volume of
hydrogen gas I cm3
Isi padu gas hidrogen /cmj
Graph 4
Graf 4
Time / s
Masa/s
Based on Graph 4, sketch the graph of the volume of
hydrogen gas collected against time for Experiment I and
Experiment III on the same axis.
Berdasarkan Graf 4, lakar graf isi padu gas hidrogen yang terkumpul melawan
masa bagi Eksperimenl dan Elcsperimenlll pada pal<si yang sama.
12
marksl
12
markahl
[See
next page
CONFIDENTIAL
4541/2 @ 2013 Copyright Reserved MARA I 0
For
Examiner's
(/se
a@)(ii)
4(A
[]
(ii)
454U2
Calculate the average rate of reaction for Experiment I for the first
minute .
Hitung kadar tindak balas purata bagi tindak balas dalam El<sperimenl dalam
minit pertama.
fi
markl
ll
markahf
Based on the Collision Theory, explain why the time taken for Experiment
III is shorter than Experiment II?
Berdasarkan Teori Perlanggaran, terangkan mengapq masa yang diambil bagi
El<sp er im en III I e b ih s ingkat dar ip ad a Elcsp er im en II?
13
marksl
[3
markah]
@
11
[See
next page
CONFIDENTIAL
454U2
For
Examiner's
Use A student carried out an experiment to determine the value of heat of
neutralisation as shown in Diagram 5.
Seorang pelajar menjalankan eksperimen untuk menentukan nilai haba peneutralot
seperti ditunjukkan dalam Rajah 5.
Thermometer
Termometer
50 cm3 2.0 mol dm-3 hydrochloric acid
50 cm3 asid hidroHorik2.0 mol dm3
+
50 cm3 2.0 mol dm-3 potassium
hydroxide solution
50 cm3 larutan kalium hidrol<sida2.0 mol dm-3
Polystyrene cup
Cawan polistirena
(a)
Diagram 5
Rajah 5
Table 5 shows the results of the experiment.
Jadual 5 merut{ ulikan kepufis an eksp erim en.
EI
8l
cI
(l)l
LI
EI
EI
C)l
ol
ot
ct
()l
utl
>l
el
=l 3t
=l
Table 5
Jadual 5
What is the meaning of heat of neutralisation?
Apakah malcsud haba peneutralan?
-_t
FJ
Initial temperature of hydrochloric acid
Suhu awal asid hidroklorik
29.0
0c
Initial temperature of potassium hydroxide solution
Suhu
qwal
larutan kalium hidroksida
29.0
0c
Highest temperature of the mixture
Suhu tertinggi campuran
41.5
0C
(b)
ll
markl
ll
markahl
Calculate:
Hitung:
(i) heat released during the experiment.
[Specific
heat capacity of solution is 4.2 J g-1
oc-t
,
density of
solution is 1.0 g cm-3]
haba yang dibebaskan semasa elcsperimen.
lMuatan
haba tentu larutan ialah 4.2 I g-l
oc'l
,
ketumpatan larutan ialah
1.0 g crn-31
s(a)
[]
5('XD
[]
12
marlcl
p,
markahl
[See
next page
CONFIDENTIAL
4541D O 2013 Copyright Reserved MARA t2
454t/2
fl
mark)
fi
markah)
f2
marlcs)
f2
markahl
f2
marksl
12
markahl
[See
next page
CONFIDENTIAL
(ii) the number of moles of hydrochloric acid.
bilangan mol asid hidroklorik.
(iii) the heat of neutralisation.
haba peneutralan.
Draw an energy level diagram for this reaction.
Lukis rajah aras tenaga bagi tindak balas ini.
(c)
For
=l
I
{
<
c
F(
U
13 4541D @ 2013 Copynght Reserved MARA
@
4s4t/2
The experiment is repeated using 25 cm3 of 1.0 mol dm-3 of ammonia
solution to replace potassium hydroxide.
The heat of neutralisation using ammonia solution is less than heat of
neutralisation using potas sium hydroxide solution.
Explain the difference in the heat of neutralisation.
drn-3 bagl
daripada
For
Exominer's
Use
s(e)
El<sperimen diulang dengan menggunakan 25 crrf larutan ammonia 1.0 mol
menggant ilwn I arut an kal ium hidro ks i da.
Haba peneutralan menggunakan larutan ammonia adalah lcarang
m enggunakan I arutan kal ium hi droks ida.
Teranglwn perbezaan bagi haba peneutralan ini.
{e)
[2
marksl
{2
markahl
Suggest another material that can replace a polystyrene cup in the
experiment.
Cadangkan bahan lain yang boleh menggantikan cctwon polistirena dalam eksperimen
ini.
$
marlQ
fl
markahl
4541,12 @ 2013, Copy,right Reserved MARA L4
[Seenextpage
CGNFIDENTIAL
For
Examiner's
Use
4541/2
Table 6.1 shows the result from Experiment I and II to investigate the acidic
properties of hydrogen chloride gas.
Jadual 6.1 menuniul:kan keputusan daripada Elaperimen I dan Il yang dijalankan untuk mengkaji
sifot asid gas hidrogen klorida.
(a)
Table 6.1
Jadual6.l
Based on Table 6.1
,
Berdasarkan Jodual 6.7,
,(i) Narrre the ion whioh,change moist blue litmus paper to
,r.ed.
Namakan ,ion yangmenukarkan kertas litmus biru lembap,ke merah.
11
rnarkl
f7
markahl
,[See
next page
CONFIDENTIAL
Experiment
Eksoerimen
Apparatus set-up
Susunon radas
Observation
Pemerhatian
HClret
.+/
\
Blue litmus
paper
Kertas litmus
biru
Calcium carbonate
Kalsium karbonat
Colourless
gas bubbles
Gelembung gas
tidak berwarna
Moist blue
litmus paper
tur-ns to red
Kertas litmus
biru lembap
bertukar ke
merah
u
HCIGI-+
ry
No gas
bubbles
Tiada gelernbung
gas
Moist blue
litmus paper
remains
unchanged
Kertas litmus
biru lembap
tidak berubah
6da)G)
W
.@
2913'Copyr,ight Rpserved MA,RA l5
4s4U2
(ii) Explain why there are no gas bubbles and the moist blue litmus
paper remains unchanged in Experiment II.
Terangkan mengapa tiada gelembung gas dan kertas litmus biru
lembap tidak berubah dalam Eluperimenll.
For
Examiner's
Use
6(6)(ii)
L]
(i)
(ii)
i
E
FU
).9
laJ
F
(b) Table 6.2 shows the molarity and pH value
acid L. Both are monoprotic acid.
Jaduol 6.2 menunjukkan kemolaran dan nilai pH bagi
Kedua-duanya adqlah asid monoprotik
12
marksl
p
markah)
of hydrochloric acid and
asid hidroklorik dan asid L.
Table 6.2
Jadual6.2
Based on the information in Table 6.2, suggest acid L.
Berdasarkan makJumat dalam Jadual6.2, cadangkan asidL.
[1
mark]
ll
markahl
Explain why the pH value of hydrochloric acid is lower than acid
L?
Terangkan mengapa nilai pH asid hidroHorik lebih rendah daripada asidL?
l2
marlcsl
fZ
markahl
[See
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CONFIDENTIAL
Substance
Bahon
Hydrochloric acid
Asid hidroklorik
Acid L
AsidL
Molarity
Kemolaran
0.1 mol dm-3 0.1 mol dm-3
pH value
Nilai pH
I 4
454112 @ 2013 Copyright Reserved MARA 16
For
Examiner's
Use
6(cXi)
6(c)(iD
4541,/2
(c) 1.0 g of calcium carbonate reacts completely with excess hydrochloric
acid.
1.0 g kalsium karbonat bertindak balas lengkap dengan asid hidroklorik berlebihan.
(i) Write a balanced chemical equation for the reaction.
Tulis persamaon seimbang bagi tindak balas ini.
lZmarks)
f2
markah)
Calculate the volume of carbon dioxide released in the reaction.
[Relative
atomic mass: C
:
12; O
:
16; Ca: 40; I mol of any gas
occupies 24 dm3 at room conditions]
Hitung isi padu karbon diolrsidayang dibebaskan dalam tindakbalas ini.
lJisim
atom relatif: C: 12; O
:
16; Ca: 40; I mol sebarang gas menempati 24
dm3 pada keadaan bitikl
13
marksl
[3
markah]
(ii)
[See
next page
CONFIDENTIAL
4541n @ 2013 Copyright Reserved MARA L7
4s4U2
Table 7
Jadual 7
(i) What is the physical state of W at room condition?
Explain your answer.
12
marlcsl
Apakah keadaanfizik bahanW pada keadaan bilik?
Terangkan jawapan
ando.
t2
markah)
(ii) Sketch a graph of temperature against time for the heating of
substance W from 90
oC
to 140
oC.
Show the melting point of substance W on your graph.
13
marlcsJ
Lakarkan graf suhu melawan masq bogi pemanasan bahanW daripada 900C
hingga 140
oC.
Tunjukkan takat lebur bahanW pada grafanda.
13
markahl
[See
next page
CONFIDENTIAL
Section B
BaltagianB
120
marlcsl
f20
markahl
Answer any one question from this section.
Ja\yqb mana-mana satu soalan daripada bahagian ini.
7 (") Table 7 shows the melting point and boiling point of substance W.
Jadual T menunjukkan takat lebur dan takat didih bagi bahanW.
Melting point
C
Cl
Takut lebur (
C)
Boiling point
CCI
Takat didih
(
C)
119 444
4541/2 @ 2013 Copyright Reserved MARA l8
4s4t/2
(b) Diagram 7.1 shows the atomic structure of isotopes for carbon atoms.
RajahT.l menunjukkan struktur atom bagi isotop-isotop atom karbon.
Carbon -12
Korbon-12
Carbon-14
Karbon-14
6 protons
6 neutrons
6 protons
8 neutrons
Diagram 7.1
RajahT.l
Based on DiagramT.l :
Berdasarkan Rajah7.l :
(i) State the meaning of isotoPes.
Nyatakan maksud isotop.
(ii) State one usage for isotope of carbon-14.
Berikan satu kegunaan isotop karbon-| .
(iii) Compare the number of subatomic particles that are present in the
isotopes.
Bandingkan bilangan zarah-zaralt sub atom dalam isotop-isotop tersebut.
[5
marlcs]
15
markall
(c) Diagram 7.2 shows an apparatus set-up for the reaction between carbon
and copper(Il) oxide powder.
Rajah7.2 menunjukkan susunan radas bagi tindak balas antara karbon dan serbuk
latprum(ll) oksida.
Crucible
Mangkuk piar
Mixture of carbon
and copper(Il) oxide
Campuran karbon dan
kuprum(Il) ol<sida
Heat
Panaskan
Diagrar,r.7.2
Rajah 7 .2
(i)
(ii)
45*ln @ a0J3,
qgp.yught
Reserved MARA
Write a balanced chemical equation for the reaction.
[2
marks)
Tulis persamaan kimia seimbang bagi tindak balas itu.
f2
markahf
Calculate the mass of copper produced when 4 g of copper(Il)
oxide is heated with excess carbon.
[Relative
atomic mass
;
O
:
16
,
Cu
:647
13
marlcs]
Hitung
jisim htprum yang terhasil apabila 4 g kuprum(ll) ol<sida dipanaskan
bersama karbon berlebihan.
fJisiln
atom relatif
;
O
:
16, Cu
:
64]
13
markah)
[See
next page
CONFIDENTIAL
t9
@
454t/2
Diagram7.3 shows the apparatus set up of two experiments to study the
rate of diffrrsion in water at different temperatures.
Raiahl.3 menunjukkan susunan radas bagi dua eksperimen untuk mengkaji kadar
resapan di dalam air pada suhu yang berbeza.
Diagram 7.3
Rajah7.3
State the type of particles present in the solution when purple colour is
observed after one hour.
Explain the observation based on the kinetic theory of matter.
15
marksl
Nyatakanienis zarah apabila larutan yang berwarna ungu diperhatikan selepas satu
jam.
T er an gkan p em er h at i an b er das ar kan t e or i kinet ik j
ir im.
[5
markah]
[See
next page
CONFIDENTIAL
I
l
,,
I
ts
a
Experiment
Eksoerimen
Apparatus set-up
Susunan radas
Observation
Pemerhatian
I
At 30
0C
Pada suhu
30
0c
After t hour
Selepas I
jum
Water
Potas s ium manganate(VlD
crystals
H ab lur kal ium m anganat(Yll)
Purple colour of
potassium
manganate(VID
crystal spread
only at the
bottom of water
Warna ungt kalium
manganat(YII)
merebak hanya di
bahagian bawah oir
II
At 80
0C
Pada suhu
g0
0c
After I hour
Selepas I
jam
---=-+
Water
Potassium manganate(Vll)
crystals
H ab lur kalium manganat(Y Il)
Purple colour of
potassium
manganate(VII)
crystal spread
throughout
water
Warna ungu kalium
manganat(YII)
merebak ke seluruh
air
4s4u2 @ erved MARA 2A
454t/2
8 Diagram 8 shows two organic compounds
S and T.
www.myschoolchildren...qorn
RajahS menunjukkan dua sebatian organiks danT.
Diagram 8
Rajah 8
(a) Based on Diagram 8, for each compound s and r state the :
(i) general
formula
(ii) functional group
(iii) homologous series
16
martrsJ
Berdasarkan Rajah 8, untuk setiap sebatian s danT nyatakan :
(i)
formula
am
(ii) kumpulan berfungsi
(ii, siri homolog
[6
markah)
(b) When 1 mole of compound T undergoes combustion reaction in excess
oxygen, it produces carbon dioxide, water and releases 2676 kJ of heat.
Calculate the volume of carbon dioxide gas produce d it 669 kJ of heat is
released in the reaction.
[1
mol of any gas occupies24 dm3 mol-l at room condition]
15
marl*l
Apabila I mol sebatianT terbakar dalam oksigen berlebihan, ia akan menghasilkan
karbon diol<sida dan air serta\676 kJ haba dibebaskan.
Hitung isi padu gas karbon diolcsida yqng terhasil jika
669 kI haba terbebas dalam
tindak balas tersebut.
[l
mol sebaranggas adalah menempati24 dm3 molt pada keadaan bilik!
15
markahf
[See
next page
CONFIDENTIAL
H
I
H-C
-C:C-C-H
IIII
H
H
I
HHH
HHHH
IIII
H-Cr,CreC*C*H
IIIX
OHH
H
H
T
S
4541n @ 2013 Copyright Reserved IvIARA 2l
4541/2
Natural rubber is obtained from latex which is a white fluid secreted by
rubber tree.
Thble 8 shows the results of experiments when latex is exposed to air and
when ammonia solution is added to it.
Getah asli diperoleh daripada latelcs yang merupakan bendalir putih didapati dari pokok
getah.
Jadual S menunjul*an keputusan eksperimen apabila lateks didedahkan ke udara dan
apabila larutan ammonia dimasukkan ke dalamnya.
Table 8
Jadual 8
Explain why there is a difference in the results of the experiments.
[6
marks]
Terangkan mengapa terdapat perbezaan bagi keputusan eksperimen ini.
16
markahJ
Explain how vulcanization can increase the elasticity of natural
rubber.
[3
marks]
Ter angkon bagoim an a pr os es p emvulkanan b o I eh m eningkatkan
kekenyalon getah asli.
[3
markah]
,[See
next page
CONFIDENTTAL
(c)
(i)
(ii)
Experiment
Eksperimen
Apparatus set-up
Susunan radas
Latex exposed to air
Latelrs didedahkan ke udara
White lump
Gumpalan putih
II
Latex * ammonia solution
Latelcs + larutan ammonia
White fluid remains
Bendalir putih kekal
4541n @ 2013 Copyright Reserved IvIARA 22
9 (a)
4541D
Section C
Bahagian C
,
120
marksl
p0
marlcah)
Answer any one question from this section.
Jm,ab mana-mana satu soalan daripada bahagian ini.
Rajah9 menunjul*an senarai larutan-larutan garam di dalam malqnal.
Diagram 9
Rajah 9
Name the solutions from the list that will react with sodium
hydroxide solution to form white precipitate and dissolve in excess
of sodium hydroxide solution.
f3
marlul
Namakan larutan daripada senarai yang akan bertindak balas dengan larutan
natrium hidroksida membentuk mendakan putih yang larut dolam larutan
natriwn hidroks ida b erl ebihan.
13
markahl
(ii) Based on your answer in 9(a)(i), name one of the white precipitate
formed and write an ionic equation for the formation of the white
precipitate.
p
marksl
(i)
(iii)
Berdasarkan jawapan anda dalam 9(aXr), namakan satu mendakan putih yang
terbentuk dan tuliskan satu persamaan ion bagi pembentulcan mendakan putih
12
markahJ itu.
Choose two solutions from the list in Diagram 9 that can react
to form an insoluble salt.
Describe how this insoluble salt can be prepared in the laboratory.
Your answer should include the following:
I
Frocedure of the experiment
.
Chernical equation involved.
{8
ruarksl
Pilth daalarutan daripada senarai dalam Rqjah9 yangboleh bertindakbalos
metnb*t* .saatu gar etm t ak terlarutkafl .
I{urailcan bagaitnana garam tak terlarutkan ini disedialwn di dalam malsnal.
Jawqan anda perlu mengandungi perkara berilcut:
.
Prosedur elaperimen
.
Persatnaan kimiayang terlibat
[8
markah]
,[See
nextpage
,COI.{FIDENTIAL
Aluminium nitate
Aluminium nitrat
Lead(II) nitrate
Plumbum(Il) nitrat
Calcium nitrate
Kalsium nitrat
Zinc nitrate
Zinknitrat
Magnesium sulphate
Magnesium sulfat
Sodium carbonate
Natrium kctrbonat
$ffiBdT{ARA
23
454t/2
(D) The label on two reagent bottles are removed. One of the bottle
contains zinc chloride solution and another one contains zinc sulphate
solution.
Describe chemical tests that can be used to identiff the cation and anions
in each solution.
t7
marksf
Label pada dua botol reagen kimia telah tertanggal . Salah satu daripada botol itu
mengandungi larutan zink Horida dan satu lagi mengandungi larutan zink sulfat.
Huraikan ujian-ujian kimia yang boleh digunakan untuk mengenal pasti kation dan
anion di dalam setiap larutan.
[7
markah]
4541t2 @ 2013 Copyright Reserved MARA 24
10 (a)
454U2
Diagram 10.1 shows an apparatus set-up to investigate the displacement of
halogen from its halide solution by halogen X .
Rajah l0.l menunjuklan susunan radas untuk mengkaji penyesaran halogen daripada
larutan halidanya oleh halogenX.
Diagram 10.1
Rajah l0.l
(i) Suggest a name for halogen X
Cadangkan satu nama bagi halogenX
ll
marlc)
fl
markahl
(ii) Write a half equation for the oxidation or reduction process that has
occurred.
[2
marla]
Tulis persamaan setengah pengoksidaan atau penurunan bagi proses yang
berlaku.
[2
markahl
(iii) Describe a chemical test to veriff the halogen formed in this
reaction.
13
marlal
Huraikan ujian kimia untuk mengesahkan halogen yang terbentuk dalam tindak
balas ini.
13
markahl
[See
next page
CONFIDENTIAL
n
x
--#
U
r
0
r shake
I I soncans
Potassium iodide solution
-l*-l
L
Larutan kalium iodida
-El
*,-
I, 1, 1 -trichloroethane
---+7
l,l,l-triHoroetana
Purple
Urgu
Chemical equation :
Persamaan kimia :
2 Kkuq)
+
X2*q) --+ 2KX1u4 *
Iz(.q)
Reserved IvfARA 25
(b)
4541/2
Diagram 10.2 shows an apparatus set up to investigate the effect of two
different metals M and N on the rusting of iron.
Rajah 10.2 menunjuklcan susunan radas bagi mengkaji kesan dua logam berbeza
M dan N ke atas pengaratan besi.
Test tube I
Tabung uji I
Test tube II
Tabung uji lI
Iron nail
Paku besi
Metal M
LogamM
Metal N
LogamN
Jelly solution * potassium hexacyanoferrate(Il! solution
Larutan gel + larutan kalium heksasianoferattlll)
Diagram 10.2
Rojah 10.2
The result of this experiment after a few days is shown in Table 10.
Keputusan eksperimen selepas beberapa hari adalah seperti dolam Jadual 10.
Pair of metals
Pasangan logam
Observation
Pemerhatian
1",
M
Blue spots
Tompok biru
Fe,N
No change
Tiada perubahan
Table 10
Jadual l0
Based on Table 10, suggest the names of metal M and N.
Explain why there is a difference in the observations in both test tubes.
l8
morks)
Berdasarkan Jadual 10, cadangkan nama logamM danN.
Terangkan mengapa terdapat perbezaan pemerhatian dalam kedua-dua tabung uji
tersebut.
l8
markahl
Iron is a metal that rusts easily when exposed to air and humidity.
With a labeled diagram, explain how the rusting of iron occurred.
16
marksl
Besi adalah logam yang mudah berkarat apabila terdedah kepada udara
dan kelembapan.
Dengan gambar rajah berlabel
,
huraikan bagaimana pengaratan besi berlaht.
l!
ma!.ah)
END OF'QUESTION PAPER
KERTAS SOAL/IN TAMAT
=
=3
a
C)
o
o
d
-) :
o-
a
=
b
o
3
(c)
4541D @ 2013 Copyright Reserved MARA 26
Periodic Table of Elements
454tn
18
1
H
Hydrogeu
1 2
13 14 15 16 17
2
He
Helium
4
3
Li
Lithium
7
4
Be
Berylllum
9
Key:
hoton Number
SymboI
Name of element
Relative Atomic Mass
3 10 11 12
5
B
Boron
11
6
C
Carbou
L2
7
N
Nltrogen
L4
8
o
Oxygen
16
I
F
Eluortne
19
10
Ne
Neon
20
11
Na
Sodium
23
L2
Mg
Magneslum.
24
13
AI
Aluminum
27
L4
Si
Silicon
?B
15
P
Phosphorus
31
16
S
Srilfru
32
L7
CI
Cblorine
3s.5
18
Ar
fugon
40
19
K
Potasslum
40
2A
Ca
Calcium
40
21
Sc
Scmdlu
45
22
Ti
Iltoium
4B
23
v
Vanadiun
51
24
Cr
Cbroulum
52
25
Mn
Manganese
55
26
Fe
Iron
56
27
Co
Cobalt
s9
28
Ni
Ntckel
59
29
Cu
Copper
64
30
Zn
Zlnc
65
31
Ga
Galllum
70
32
Ge
Germanlum
73
33
As
Arsenic
7S
34
Se
Selenium
79
35
Br
Bromine
BO
36
Kr
Krlpton
84
37
Rb
Rubtdlum
B6
38
Sr
Strontium
88
39
Y
Yttrium
89
40
Zr
Zhcmtum
91
4L
Nb
Mobfim.
93
42
Mo
Itlolybdenum
96
43
m
ltc
Technetlum
9B
44
Ru
Ruthenium
101
45
Rh
Rhodium
103
46
Pd
PaIIadium
106
47
Ag
Silver
108
48
Cd
Cadmlum
Lt2
49
In
Indlum
115
50
Sn
Tin
119
51
Sb
Antimony
L22
52
Te
Tdlurtum
128
s3
I
Iodlne
L27
s4
Xe
Xenon
131
55
Cs
Cesium
133
56
Ba
Barfum
L37
57
La
Lanthailrm
139
72
Hf
Hafoium
L79
73
Ta
Tantalun
181
74
w
Tun$tlr
184
75
Re
Rhentum
186
76
Os
Osmium
190
77
Ir
Iridium
L92
78
Pt
Plattraum
19s
79
Au
Gold
r97
80
Hg
Mercury
20L
81
TI
Thallium
204
82
Pb
Lead
207
83
Bi
Btsmuth
209
84
Po
Polonlum
209
B5
At
AstatiJoe
2LO
86
Rn
Radon
222
87
Fr
Franclum
223
88
Ra
Radlum
226
89
Ac
Acttrftm
227
454112 @ 2AI3 Copyright Reserved I\1[ARA
27
[See
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CONFIDENTIAL
4s4112
INFORMATION FOR CANDIDATES
MAKLUMAT ANTAK CALON
l. This question paper consists of three sections: Section A, Section B and
Section C.
Kertas soalan ini mengandungi tiga bahagian: Bahagian A, BahagianB dan Bahogian C.
2. Answer all questions in Section A. Write your answers for Section A in the
spaces provided in the question paper.
Joyab semua soalan dalam Bahagian A. Tuliskan
jawapon bagi Bahagian A dalam ruang yang
disediakan dalam kertas soalan.
3. Answer one question from Section B and one question from Section C. Write
your answers for Section B and Section C on the answer sheets provided. Answer
questions in Section B and Section C in detail. You may use equations, diagrams,
tables, graphs and other suitable methods to explain your answer.
Jawab satu soalan daripada Bahagian B dan satu soalan daripada Bahagian C. Tuliskan
jawapan bagi Bahagian B dan Bahagian C pada kertas
jawapan yang dibekalkan. Jawab
Bahagian B dan Bahagian C dengan terperinci. Anda boleh menggunakan persamaan, gambar
rajah, jadual, graf dan cara lainyang sesuai untuk menjelaskan
janapan anda.
4. The diagrams in the questions are not drawn to scale unless stated.
Rajah yang mengiringi soalan tidak dilukiskan mengikut skala keanli dinyatakan.
5. Marks allocated for each question or part question are shown in brackets.
Markah yang diperuntulckan bagi setiap soalan atau ceraian soalan ditunjukkan dalam
kurungan.
6. Show your working, it may help you to get marks.
Tunjukkan kerja mengiro, ini membantu anda mendapatkan markah.
7 . If you wish to cancel any answer, neatly cross out the answer.
Sekiranya anda hendak membatalkan sesuatu jawapan,
buat garisan di atas jawapan
itu.
8. The Periodic Table of Elements is provided onpage27.
Jadual Berkala Unsur disediakan di halaman2T.
9. You may use a scientific calculator.
Anda dib enar kan m en ggunakan kalkul ato r s aint ifik.
10. The time suggested to complete Section A is 90 minutes, Section B is 30 minutes
and Section C is 30 minutes
Masa yang dicadangkan untuk menjawab Bahagian A ialah 90 minit, Bahagian B ialah 30 minit
dan Bahagian C ialah 30 minit.
11. Hand in all your answer sheets at the end of the examination.
Serahkan semua kertas jawapan
anda di akhir peperiksaan.
r.t
ta,
F
b.)
4541D @ 2013 Copyright Reserved MARA
28
CONFIDENTTAL
I
)
z
H
l+l
t.i
U
454u3
Name :
Class : ... .
COI\'FIDENTIAL
4s41t3
Chemistry
Paper 3
September
20t3
1% hours
SIJIL PELAJARAN MALAYSIA
TRTAL EXAMINATION
2013
CHENIISTRY
Paper 3
One hour and thirty minutes
DO NOT OPEN Trrrs
QUESTTON
BOOKLET UNTIL BErNG TOLD TO DO SO
1.
z.
3.
Write down your name and class in
the space provided
Tuliskan nama dan kelas anda pada ruang
yang disediakan.
The question booklet is bitingual.
Buku soalan ini adalah dalam dwibahasa.
Candidates are required to answer
all questions,
Calon dikehendaki menjawab semua
soalan
For Examiner's Use
Question
Full
Mark
Mark
1 18
2 15
3 17
Total 50
www, myschoolchildren.com
This question booklet has 10 printed pages arrd2 unprinted pages
[See
next page
CONFIDENTIAL
For
Examiner's
Use
4s4U3
Answer all
Questions
Jawab semua soalan
Diagram 1.1 shows the apparatus set-up for an experiment to study the hardness of
pure copper by using 1.0 kg weight.
Rajah 1.1 menunjukkan susunan radas bagi elrsperimen untuk mengkaji kekerasan laqrum tulen
dengan menggunakan pemberal I.0 kg.
Meter rule
Pembaris meter
Thread
Benang
Weight
Pemberat
Retort stand
Kaki retoi,t
Step I
Langkah I
Step 2
Langkah2
Step 3
Langkah3
Step 4
Langkah 4
Step 5
Langkah 5
Step 6
Langkah 6
Steel ball bearing
Bebola keluli
Cellophane tape
Pita pelekat
Copper block
Blok kuprum
Diagram 1.1
Rajah l.l
The experiment was carried out according to the following steps:
Ela p er i m e n t e I a h dij a I a nka n s ep er t i I an gka h- I a n gka h b er i kut :
A steel ball bearing is taped onto a copper block.
Bebola keluli dilekatkan di atas blok kuprum.
A 1 kg weight is hung at a height of 50 cm above the copper block as
shown in Diagram 1.1.
I kg pemberat digantung pada ketinggian 50 cm di atas blok kuprum seperti ditunjukkan
di dalam Rajah l.l
The weight is allowed to drop onto the steel ball bearing.
Pemberat dijatuhkan ke atas bebola keluli
The diameter of the dent made on the copper block is measured.
Diameter lekuk yan g t er bentuk di at as b lok kuprum diular.
Steps 1 to 4 are repeated on two other parts of the copper block in order to
obtain an average value for the diameter of dents formed.
Langkah I hingga 4 diulangi di atas dua bahagian lain di permukaan blok fuprum untuk
memperoleh nilai purata bagi diameter lekukan yang terhasil.
Steps I to 5 are repeated by replacing the copper block with bronze block.
Langkah I hingga 5 diulangi dengan menggantikan blok kuprum dengan blok gangsa.
[See
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CONFIDENTIAL
Type of block
Jenis blok
Diameter of dents / mm
Diameter lelatk / mm
Average diameter of dent / mm
Purata diameter lekuk / mm
I II m
Copper
Kuprum
3.60 3.50 3.70 3.50
Bronze
Gangsa
2.s0 2.45 2.55 2.50
4541/3
(a)
Table I . 2 shows the recorded diameter of dents formed on the blocks.
Jadual 1.2 menunjukkan rekod bacaan diameter lekuk yang terhasil di atas kedua-dua blok.
Table 1.2
Jadual1.2
Complete Table 1.3 based on the experiment.
Lengkaplcan Jadual 1.3 berdasarkan eksperimen ini.
Table 1. 3
Jadual 1.3
State the hypothesis for this experiment.
Nyatakan hipotesis untuk eksperimen ini.
[6
marks]
For
Exantiner's
Use
L(a)
1(b)
(b)
Type of variables
Jenis
pemboleh
ubah
Action to be taken
Tindakan untuk diambil
(i) Manipulatedvariable :
P em b oleh ubah dimanipul as ikan :
(ii) Method to manipulate variable :
C ar a mem anipul as ikan p emb o le h ub ah:
(iii) Responding variable :
Pemboleh ubah bergerak balas:
(iv) What to observe in the responding
variable :
Apa yang diperhatikan bagi pemboleh ubah
bergerak balas
(v) Controlled variable :
Pemboleh ubah yang dimalarkan:
(vi) Method to maintain the controlled
variable :
Cara menetapkan pemboleh ubah yang
dimalarkan:
454N13 @ 2013 Copyright Reserved MARA
Jl, i
13
marlcsJ
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CONFIDENTIAL
For
Examiner's
Use
1(c)
\a
1(e)
4s4
c) Based on the datain Table 1.2, state the inference of the experiment.
Berdasarkan data dalam Jadual 1.2, nyatakan inferens bagi el<sperimen tersebut .
13
marksl
d) Based on the experiment, state the operational definition for alloy.
Berdasarkan eksperimen, nyatakan definisi secara operasi bagi aloi.
[3
marla)
Diagram I.4 shows a few materials.
Rajah 1.4 menuniukkan beberapa bahan.
.
Duralumin
o
Magnesium
Duralumin
Magnesium
o
Tin
.
Cupronickel
Timah
Kupronikel
o
Brass
o
Mercury
Loyang
Merkuri
Diagram 1.4
Rajah 1.4
Classiff ttre materials into metals and alloys by completing the Table 1.5.
Kelaskan bahan-bahan itu kepada logam dan aloi dengan melengkapltan Jadual1.5
Metals
Logant
Alloys
Aloi
Table 1.5
Jadual1.5
[See
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CONFIDENTIAL
e)
{3
marksJ
4
Total
Diagram 2.1 shows the apparatus set-up to construct the Electrochemical Series.
The voltage produced when copper and magnesium electrodes are dipped into the
copper(Il) sulphate solution is measured. The experiment is repeated by replacing
magnesium with aluminium and zinc.
Raiah2.l menunjukkan susunan radas yang digunakan untuk membina Siri Elektrokimia.
Voltan yang dihasilkan apabila elektrod latprum dan magnesium dicelup ke dalam larutan kuprum(Il)
sulfat diulatr. Eksperimen ini diulangi dengan menggantikan magnesium dengan aluminium dan zink.
Magnesium
Magnesium
Copper and Magnesium
Kuprum dan magnesium
Copper
Kuprum
Copper and zinc
Kuprum dan zink
4s4u3
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CONFIDENTIAL
Copper(Il) sulphate solution
La r ut a n kup r u tn(ll) s u lfa t
Diagram 2.1
Rajah2.l
(a) Diagram 2.2 shows the readings of three voltmeters each using different metals
paired with copper.
Rai ah 2.2 menunjukkan t iga bacaan vo ltmet er yang menggun akan lo gam b erlainan
berpas angan dengan kuprum.
Copper and aluminium
Kuprum dan aluminium
Diagram 2.2
Rajah2.2
@ 2013 Copyright Reserved MARA
For
Examiner's
Use
For
Examiner's
Use
2(a)
2(b)
(6)
454t/3
Based on Diagram?.Z, record the voltmeter readings in Table2.3
Berdasorkan kepada Rajah2.2, rekodkan bacaan voltmeter dalam Jadual2.3
Pair of metals
Pasangon logant
Negative Terminal
Terminol nesatif
Voltage/ V
Voltan tV
Cu and Mg Magnesium
Cu andZn Zinc
Cu and AI Aluminium
Table23
Jadual2.3
13
marksl
Based on Table 2.3
,
state the relationship between the voltage and the position
of the metals in the Electrochemical Series.
Berdasarkan Jadual2.3
,
nyatakan hubungan antara bacaanvoltan dan lredudukan logam-
logam dalam Siri Elektrokimia.
2(c)
13
marks)
(c) Based on the voltmeter readings, arrange aluminium, copper, magnesium and
zinc in ascending order of tendency to release electrons.
Berdasarkan bacaan voltmeter, susunkan aluminium, kuprurn, magnesium dan zink mengikut
kecenderungan menderma elektron dalarn turutan menaik
Tendency to release electron increases
Kecenderungan menderma el ektron b ertamb ah
13
marksl
The experiment is repeated using the pair ofmetals; magnesium and zinc, Predict
the voltmeter reading.
El<sperimen ini diulangi dengan menggunakan pasangan logam; magnesium dan zinlc
Ram a I kan b a ca an v o lt tn eter.
13
marlcrl
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CONFIDENTIA
(d)
2(d)
454113 @ 2013 Copyright Reserved MARI\
4s4U3
(e) The experiment is repeated using two copper electrodes dipped in
copper(Il) sulphate solution. The voltmeter does not show any reading.
Explain why.
El<sperimen diulangi menggunakan duo elektrod laryrum yang dicelup ke dalam
larutan kuprum(Il) sulfat. Voltmeter tidak menunjukkan sebarang bacaan.
Terangkan mengapa.
For
Examiner's
Use
2(e)
13
marlcsl
[See
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CONFIDENTIAL
dARA
Total
4s4U3
Diagram 3.1 shows a conversation between two students about the solubility of
an ionic compound in water and organic solvents.
Rajah3.l menunjukkan perbualan di antara dua orang pelajar mengenai keterlarutan sebatian ion di
dqlam air dan pelarut organik
Diagram 3.1
Rajah3.l
I tested the solubility of a white solid in water.
I observed that the white solid disappeared. A colourless
solution was formed
Saya telah menguji keterlarutan pepejal putih di dalam air.
Saya dapati pepejal putih tidak kelihatan lagi. Satu larutan tanpa
warna terhasil.
I tested the solubility of the white solid in
cyclohexane. I didn't see any change. The
white solid still remained.
Scya telah menguji keterlarutan pepejal putih itu di
dalam siklohelcsana. Saya mendapati tiada perubahan.
Pepeial
putih
masih kelihatan.
4s4l13
Based on the situation, plan a laboratory experiment to study the solubility of an ionic
compound in water and organic solvent.
Berdasarkan situasi tersebut, rincangkan satu el<sperimen makmal untuk mengkaji keterlarutan
sebatian ionik dalam air dan pelarut organik.
Your planning should include the following aspects:
Perancangan anda hendaHah mengandungi aspek-aspek berikut i
(a) Problem statement
Penyataan masalah
(b) A11 the variables.
Semua pembolehubah.
(c) Statement of the hypothesis
Pernyataan hipotesis
(d) Lists of materials and apparatus
Senarai bahan dan radas
(e) Procedure for the experiment
Prosedur elcsperimen
A
Tabulation of data
Penjadualan data
ll7
marksl
www. myschoolch
ildren.com
END Or
QUESTION
PAPER
KERTAS SOALAN TAMAT
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CONFIDENTIAL
454113 @ 2013 Copyright Reserved I{ARA
454113
INFORMATION FOR CANDIDATES
MAKLUMAT ANTAK CALON
l. This question paper consists of three questions. Answer all questions.
Kertas soalqn ini mengandungi tiga soalan. Jawab semua soalan.
2. Write your answers for
Question
1 and
Question
2 in the spaces provided in this
question paper.
Tulis jau,apan
anda bagi Soalan I dan Soalan 2 pada ruang yang disediakan dalam kertas soalan
ini.
3. Write your answers for
Question
3 on the answer sheet provided.
Tuliskan jawapan
bagi Soalan 3 pada kertas
jawapan yang dibekallcan.
4. Show your working, it may help you to get marks.
Tunjukkan kerja mengira, ini membantu anda mendapatkan markeh.
5. The diagrams in the questions are not drawn to scale unless stated.
Rajahyang mengiringi soalan tidak dilukis mengikut skala kecaali dinyatakan.
6. The marks allocated for each question or sub-part of a question are shown in brackets.
Markah yang diperuntukkan bagi setiap soalan otau ceraian soalan ditunjul:lcan dalam htrungan.
7. If you wish to change your answer, cross out the answer that you have done. Then
write down the new answer.
Jika anda hendak menukar jnlapan,
batalkan
jau,apan yang telah dibuat. Kernudian tulis
jawapan
yang baru.
8. You may use a scientific calculator.
A n da di b en ar kan menggun a kan kal kul at o r s a i nt ifi k.
9, You are advised to spend t hour to answer
Question
1 and
Question
2 and
30 minutes for
Question
3.
Anda dinasihati supcya mengambil masa I
jam
untuk menjawab Soalan I dan Soalan 7 dan 30 minit
untuk Soalan 3.
10. Hand in all your answer sheets at the end of the examination.
Serahkan semua kertas
jawapan
anda di akhir peperiksaan.
[See
next page
CONFIDENTIAL
fr
r-
E
E
f'U
ta:
F

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