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Chemical Processing
Chemical Processing
• Objectives
• To remove natural fat, wax and oil material
containing in the fabric without damaging
the fiber.
• To accelerate wet processing.
• To improve the handle of textiles.
Bleaching agent
• OXIDATIVE REDUCTIVE
• H2O2 SO2
• NAOCL( Sod. Hypochlorite) CL2
• NAOCL2 NA2SO4
• Sodium Perborate
• KMNO4
• Paracetate acid
• Calcium Hypochlorite
Bleaching agent for cellulosic
• Bleaching with sodium hypochlorite
• Bleaching with hydrogen peroxide
• Bleaching with sodium chlorate
Optical brightener
• Certain organic compounds have the property of fluorescence i.e. they can absorb light of
short wavelengths and re-emit it at the longer ones. Many of such compounds absorb ultra
rays and re-emit as visible light in the range of 4,000 to 7,000 A0.
• Textile fibers containing a fluorescent compound reflect more light than an untreated one
and thus increase its brightness and whiteness.
• The fluorescent brightening agents called ‘optical brightening agents, increase the apparent
whiteness or brightness of materials, and are used in textiles, detergent, paper, paints, etc.
•
MERCERIZATION
• it is the action of the alkali ( caustic soda) on a fabric.
• It was a revolutionary development discovered in 1853
by John Mercer , a calico printer.
• It is used mainly on cotton and sometimes on linen for
many different reasons.
• It increases luster and softness
• It gives greater strength.
• It improves the affinity for dyes and water borne finishes.
• Cotton is mercerized for luster in both yarn and fabrics.
• Objectives
• 1. To make the goods more luster because raw cotton fib
ers are ribbon-like. After this process, the fibers change
to cylindrical shape resulting more evenness reflected lig
ht from the goods.
• Mercerising can be carried out on yarn in hanks, woven
and knitted fabric through one of the following different
treatments:
• mercerization with tension (stretch mercerization)
• Mercerization without tension ( slack mercerization)
• Ammoniating
•
• Mercerization with tension ( cold mercerization)
• Caustic soda mercerizing is the most commonly applied mercerising
technique (it is not applied to flax). Cotton is treated under tension in
a solution of concentrated caustic soda (270 - 300g NaOH/l, which
means also 170 - 350 g NaOH/kg) for approximately
40 - 50 seconds.
• During mercerising the temperature is adjusted at low values
(5 - 18 °C) when the lustre is the priority and at slightly higher levels
when the improvement of the other characteristics is preferred.
Because the reaction between caustic soda and cellulose is
exothermic, cooling systems are applied to keep down the
temperature of the bath.
• Mercerization with tension (Hot
mercerization)
• The hot mercerization process can double strength of
the cotton fabric and contribute resistance to shrinkage
in washing.
• Beside the conventional cold treatment, a hot
mercerising process is also now increasingly applied (for
hanks and fabric). The material is soaked in a solution of
caustic soda close to boiling point. After hot stretching,
the fabric is cooled down to ambient temperature and
washed under tension.
•
• Slack mercerization
• The technique is applied to yarn as well as
woven and knitted fabrics.
• It is also used in producing woven fabric with
stretch in the filling direction.
• Ammoniating
BIOPOLISHING
• Define
• History
• Purpose
• Properties