Chart of Thermodynamic & Transport Properties of CO2 - Manual

THERMODYNAMIC AND TRANSPORT PROPERTIES OF CARBON DIOXIDE
Carbon Dioxide: Pressure - Enthalpy Diagram

1,000
240 oC
180
280
200
220
260
120
160
t = 0 oC
100
140
80
40
60
-20
-40
20
0 3
90 00
00
0 r= r=8 kg/m 0
700 r = 60
12
0
10 = 0
50
sity r= 50
r=
50 r= Den
11
00
10 0
r=
r = 40
11
r=
r=
0
r = 30
3
0 kg/m
0
r = 20
-2.00
-1.70
kJ/kg, oC
--1.6
0
-1.90
0
-1.80
s = -2.20
-.9
0
0
. 30
-1.5
0
0
.0
r = 150
-2.10
-1.4
-.8
1
-1
-1.
0
-1
2
-1.
100
0
r = 100
30
- .7
Entropy = -2.
r = 75
Pressure, Bar
0
-.6
r = 50
-.50
r = 35
0
-.4 r = 25
3
= 20 kg/m
Melting Line
0 Density
-.3
r =15
0 r = 10
10 -.2
CHEMICALOGIC
0
-.1 r=8
0
240
=
r=6
s
220
Triple Point (5.18 bar, -56.558 oC)
160
200
180
120
100
140
-40 oC
40
60
20
80
-20
0
Sublimation Line
Copyright © 1999
Drawn with CO2TabTM ChemicaLogic Corporation
A Spreadsheet Add-in for the Thermodynamic and www.chemicalogic.com
Transport Properties of Carbon Dioxide Enthalpy, kJ/kg
1
-500 -400 -300 -200 -100 0 100 200
ChemicaLogic Corporation, 8 Cedar Street, Suite 56, Woburn MA, 01801 USA
Tel: 781.938.1151 Fax: 781.938.7722
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INTRODUCTION TO CO2TAB .............................................................................. 1
OVERVIEW AND FEATURES ....................................................................................... 1
TECHNICAL SUPPORT AND CONTACT INFORMATION ................................................. 3
GETTING STARTED............................................................................................... 5
MINIMUM SYSTEM REQUIREMENTS .......................................................................... 5
INSTALLATION .......................................................................................................... 5
Quick Installation of CO2Tab................................................................................ 6
Manual Installation of CO2Tab for Excel 97/2000 ............................................... 6
USING CO2TAB ......................................................................................................... 7
Where is CO2Tab?................................................................................................. 7
Setting CO2Tab Property Options......................................................................... 9
Using the Saturated Properties Dialog Box........................................................ 10
Using the Superheated/Subcooled Properties Dialog Box.................................. 11
Using the Constant Properties Dialog Box ......................................................... 13
Using the Melting/Sublimation Dialog Box ........................................................ 14
Using the Solubility in Water Dialog Box ........................................................... 15
FUNCTION REFERENCE .................................................................................... 17
OVERVIEW .............................................................................................................. 17
FUNCTIONS FOR SATURATED PROPERTIES .............................................................. 21
CDPSAT .............................................................................................................. 21
CDTSAT .............................................................................................................. 22
FUNCTIONS FOR SUPERHEATED OR SUBCOOLED PROPERTIES ................................. 22
General Description............................................................................................ 23
FUNCTIONS FOR CONSTANT PROPERTIES ................................................................ 24
MELTING AND SUBLIMATION LINE FUNCTIONS ...................................................... 25
General Description............................................................................................ 25
FUNCTIONS FOR SOLUBILITY IN WATER.................................................................. 26
Range .................................................................................................................. 26
CDSOLU ............................................................................................................. 26
CDSOLUPP ........................................................................................................ 27
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7$%/( LIST OF FILES IN CO2TAB FOR EXCEL 97/2000 DISK ................................. 6
7$%/( OVERVIEW OF CO2TAB FUNCTIONS ......................................................... 18
7$%/( PROPERTY CODES FOR THERMODYNAMIC AND TRANSPORT PROPERTIES 20
7$%/( SOLUBILITY PROPERTY CODES................................................................. 26
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Saturated Vapor, Liquid, and Two-Phase Functions
CDPSAT pressure (P) CDPSAT(pressure, quality, code, units)
CDTSAT temperature (T) CDTSAT(temperature, quality, code, units)
Superheated or Subcooled Functions
CDTP temperature and pressure (T-P) CDTP(temperature, pressure, code, units)
CDTV temperature and volume (T-V) CDTV(temperature, volume, code, units)
CDTH temperature and enthalpy (T-H) CDTH(temperature, enthalpy, code, units)
CDTS temperature and entropy (T-S) CDTS(temperature, entropy, code, units)
CDTU temperature and internal energy (T-U) CDTU(temperature, internal, code, units)
CDPV pressure and volume (P-V) CDPV(pressure, volume, code, units)
CDPH pressure and enthalpy (P-H) CDPH(pressure, enthalpy, code, units)
CDPS pressure and entropy (P-S) CDPS(pressure, entropy, code, units)
CDPU pressure and internal energy (P-U) CDPU(pressure, internal, code, units)
Melting and Sublimation Functions
CDPMELT pressure at specified temperature (T) CDPMELT(temperature, units)
CDTMELT temperature at specified pressure (P) CDTMELT(pressure, units)
CDPSUBL pressure at specified temperature (T) CDPSUBL(temperature, units)
CDTSUBL temperature at specified pressure (P) CDTSUBL(pressure, units)
Solubility in Water Functions
CDSOLU temperature and total pressure CDSOLU(temperature, pressure, code, units)
CDSOLUPP temperature and CO2 partial pressure CDSOLUPP(temperature, pressure, code, units)
Constant Properties Functions
CDWM Molecular weight CDMW(units)
CDTC Critical temperature CDTC(units)
CDPC Critical pressure CDPC(units)
CDVC Critical specific volume CDVC(units)
CDRC Critical specific density CDRC(units)
CDZC Critical compressibility factor CDZC(units)
CDTPT Triple point temperature CDTPT(units)
CDTPP Triple point pressure CDTPP(units)
CDTMIN Minimum temperature range CDTMIN(units)
CDTMAX Maximum temperature range CDTMAX(units)
CDPMIN Minimum pressure range CDPMIN(units)
CDPMAX Maximum pressure range CDPMAX(units)
Quality (vapor mass fraction) Units

0 Saturated Liquid 0 or none Metric/SI
1 Saturated Vapor 1 English
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Code Carbon Dioxide Property Metric/SI Units English Units

0 T Temperature, T °C °F
1 P Pressure, P bar psia
3
2 V Volume, V m /kg ft3/lb
3 D Density, ρ kg/m3 lb/ft3
4 Z Compressibility factor, Z dimensionless dimensionless
5 A Helmoltz free energy, A kJ/kg Btu/lb
6 S Entropy, S kJ/(kg·°C) Btu/(lb·°F)
7 U Internal energy, U kJ/kg Btu/lb
8 H Enthalpy, H kJ/kg Btu/lb
9 G Gibbs free energy, G kJ/kg Btu/lb
10 CV kJ/(kg·°C) Btu/(lb·°F)
Heat capacity at constant volume, C v
11 CP kJ/(kg·°C) Btu/(lb·°F)
Heat capacity at constant pressure, C p
12 W Speed of sound, v m/s ft/s
13 ALPHA
Coefficient of thermal expansion, α = ρ (∂V ∂T )P 1/°C 1/°F
14 KAPPA
Isothermal compressibility, κ = − ρ (∂V ∂P )T 1/bar 1/psia
15 DPDT
dpdt, (∂P ∂T )V bar/°C psia/°F
16 DVDT
dvdt, (∂V ∂T )P m3/(kg·°C) ft3/(lb·°F)
17 DVDP
dvdp, (∂V ∂P )T m3/(kg·bar) ft3/(lb·psi)
18 MU Viscosity (dynamic), µ µPa·s lb/(ft·hr)

19 KT Thermal conductivity, K W/(m·°C) Btu/(hr·ft·°F)
20 ST Surface tension, σ N/m N/m
21 PR dimensionless dimensionless
Prandtl number, N Pr
22 DC Static dielectric constant dimensionless dimensionless
23 IJT Isothermal Joule-Thomson coefficient kJ/(kg·bar) Btu/(lb·psia)
24 JT Joule-Thomson coefficient °C/bar °F/psia
25 Q Quality (vapor mass fraction) dimensionless dimensionless
Code Solubility in Water Property Metric/SI Units English Units
0 XCO2 Liquid mole fraction of CO2 (molar solubility) dimensionless dimensionless
1 YCO2 Vapor mole fraction of CO2 dimensionless dimensionless
2 XWCO2 Liquid mass fraction of CO2 (mass solubility) dimensionless dimensionless
3 YWCO2 Vapor mass fraction of CO2 dimensionless dimensionless
CHEMICALOGIC

Chart of Thermodynamic &amp; Transport Properties of CO2 - Manual

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THERMODYNAMIC AND TRANSPORT PROPERTIES OF CARBON DIOXIDE

Carbon Dioxide: Pressure - Enthalpy Diagram

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Quality (vapor mass fraction) Units

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Code Carbon Dioxide Property Metric/SI Units English Units

18 MU Viscosity (dynamic), µ µPa·s lb/(ft·hr)

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Chart of Thermodynamic & Transport Properties of CO2 - Manual

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