Class - XIII CHEMISTRY PAPER - 1

Q.26 Titrating of strong acid (HCl) with strong base (NaOH) gives the following curve

Which indicator is suitable to find out end point of this titration?

(A) indicator (A) (PH range 3 to 4.5) (B) Indicator (B) (PH range 8 to 10)
(C*) Both indicator A and B (D) none of these

HCl
Q.27 


total No. of Markwonikoff 's products in above reaction is

(A) 1 (B) 3 (C*) 2 (D) 4
[Sol. H2 addtion is syn addition

 +

Total 2 stereoisomers. Ans. (C)]

Q.28 20 ml of 0.1 M (pka = 5) reacts with 20 ml 0.025 M Ca(OH)2 solution, what

will be pH of final solution
(A) 4.7 (B) 7 (C*) 5 (D) none of these
[Sol: pH = pKa = 5 (buffer solution) (C) ]

Q.29 The E0 of the following half cell reaction at 298 K

Ag (NH3)2 Ag + 2NH3
Ag+ + e Ag E 0Ag  / Ag = 0.80 V
Ag(NH3)2 Ag+ + 2NH3 K = 6 × 10–8
(A*) 0.373 V (B) 0.866 V (C) 0.591 V (D) none of these
[Sol: (1) Ag   e  Ag E oAg  / Ag  0.8V ; ( G o )1   F(0.8) J
(2) Ag( NH 3 ) 2  Ag   2 NH 3 K = 6 x 10–8 ( G o ) 2   RT n K
Now (2) + (1)
Ag(NH3)+2 + e Ag + 2NH3 G o  ( G o )1  ( G o ) 2
= (-0.8F) - 2.303RT log (K)
  -Eo(F) = -0.8F - 2.303 RT log (6 x 10–8)
( 2.303)(8.314)( 298)
 Eo = 0.8  (8  log 6)
96500
= (0.8 - 0.427) V
= 0.373 V (A) ]

Q.30 Arrange in order of decreasing reactivity in electrophilic addition

(I) Ph CH = CH COOH (II) p–NO2–C6H4–CH=CH COOH
(III) p–MeO C6H4CH = CH COOH (IV) p–ClC6H4CH = CHCOOH
(A) II >I > IV > III (B) III > IV > I > II (C*) III > I > IV > II (D) II > IV > I > III

Q.31 The structure of B3N3H6 is as follows

How many derivative structures of B3N3H4X2 can be derived from the basic structure, by the replacement
of two hydrogen atoms?
(A) 2 (B) 3 (C*) 4 (D) 5

Q.32 The pH of 0.5 M solution of NaHCO3 (for H2CO3; k1 = 2.0 × 10–7 and k2 = 4.0 × 10–11 ) is almost
equal to
(A) 10.52 (B) 9.8 (C*) 8.55 (D) none of these
pKa 1  pKa 2
[Sol: pH  = 8.55 (C) ]
2

Q.33 Correct order of rate of hydrolysis for following compounds is

[I] [II] [III] [IV]

(A*) III > II > IV > I (B) I > II > III > IV (C) III > I > II > IV (D) III > II > I > IV
[Sol. 1–bromotriptycine is 1023 times less reactive than Ph3C–Br which is 1011 times less reactive than tropylium
bromide ]

Q.34 50 mL of a weak acid, HA required 30 mL 0.2 M NaOH for the end point. During titration, the pH of
acid solution is found to be 5.8 upon addition of 20 mL of the above alkali. The pKa of the weak acid is
(A) 6.3 (B*) 5.5 (C) 6.1 (D) none of these
[Sol: 50N = 30 x 0.2 = 6
6 3
N 
50 25
50 ml HA + 20 ml NaOH  HA / NaA
6 meq 4 meq 2 meq 4 meq
 4
pH = pKa + log
2
5.8 = pKa + log 2
pKa = 5.8 - log 2
= 5.8 - 0.3 = 5.5 (B) ]

Q.35 Equilibrium constant for the given reaction is K = 1020 at temperature 300 K
A(s) + 2B (aq) 2C (s) + D (aq) K = 1020
The equilibrium conc. of B starting with 1 mole of A and 1/3 mole/litre of B is
(A*) ~ 4 ×10–11 M (B) ~ 2 ×10–10 (C) ~ 2 ×10–11 (D) none of these
[Sol: A(s) + 2B (aq) 2C (s) + D (aq) K = 1020
1
[ D]
K  6  10 20
[B]2 [B]2
[B] = 4 x 10–11 M (A) ]

Q.36 A compound having molecular formula C8H4O2Cl2 can give following set of reactions

Compound B & D are

(A) + (B*) +
 (C) + (D) +

[Sol:

e.g. of Anionotropy.


NH
3  RMgX
H
3O
  


H 3O
CH3NH2 + 

Q.37 SO32– + S* boil

 SS*O32–
SS*O32– + 2H+  H2SO3 + S*
The above reaction sequence proves
(A*) Two sulphur atoms of thiosulphate are not equivalent
(B) Both are equivalent
(C) Both of the above are correct
(D) None of these

O
|| NaNO2
Q.38 R  C  NH 2   A
HCl
final product A is:
O O O O
|| || || ||

(A*) R  C  OH (B) R  C  Cl (C) R  C  NO 2 (D) R  C  N
2 Cl
[Sol. NaNO2 + HCl converts NH2 into OH ]
Q.39 A mixture contains Cu2+, Al3+ and Ni2+. Following steps have been adopted for separation but written in
disorder:
(I) Filter, boil off H2S gas and NH4Cl, heat and add NH4OH
(II) Filter, add NH4OH and pass H2S gas
(III) Pass H2S gas into acidified solution of mixture
steps will be used in the following order
(A) I, II, III (B*) III, I, II (C) III, II, I (D) I, III, II

Q.40 Compound A and B both having molecular weight 104

[A]  [C] C & D having molecular wt. 172

B  D (C shows geometrical isomerism but D cannot. What is the structure of A & B)


(A*) (B) is , (A) is

(B) (B) is , (C) is

(C) (B) is , (A) is

(D) None of these

[Sol:  hydroxy acid





 + + trans



Ans: (A) ]

Q.41 The oxide of a metal (R) can be reduced by the metal (P) and metal (R) can reduce the oxide of metal
(Q). Then the decreasing order of the reactivity of metal (P), (Q) and (R) with oxygen is
(A) P > Q > R (B*) P > R > Q (C) R > P > Q (D) Q > P > R
 
Q.42 The product(s) of the reaction H
 is:


(I) (II) (III) (IV)

(A) II, III and IV (B) II and IV (C) only I (D*) only IV

[Sol. Ring
 expansion
  ]

Q.43 20 ml of 0.1 M CH3COOH (pKa = 4.7) reacts with 20 ml 0.025 M Ca(OH)2 solution, what will be pH
of final solution
(A*) 4.7 (B) 7 (C) 5 (D) 5.3
[Sol: pH = pKa = 4.7 (buffer solution) (A) ]

( i ) NaOI
Q.44 A   B 
(ii ) H  
Starting compound A responds to

(A) (B)

(C*) (D)

[Sol: (
i ) NaOI

 
 + CO2
(ii ) H

Ans: (C) ]
Q.45 The pH of a saturated solution of Ca(OH)2 in water at 150C is 12.67. What is the concentration of OH–
in the saturated solution, in moles of OH– per litre
(A) 10–14/12.67 (B) 10–14 × 10–12.67 (C*) 10–14/10–12.67 (D) none of these
[Sol: pH = 12.67 +
=> [H ] = 10 -12.67

Kw 10 14
[OH–] = => 12.67 (C) ]
[H  ] 10

Q.46 How many moles of benzene would be produced when 2.28 gm of phenyl magnesium iodide is treated
with 112 cc of ethyne at STP.
(A) 0.112 lt. (B) 0.228 lt (C) 0.224 lt. (D*) none of these

[Sol: 2C6H5MgI + HC  CH  2C6H6 +

2.28 112
 0.01  0.005
228 22400
- LR
=> n C 6 H 6  0.005 x 2  0.01 (D) ]

Q.47 In the reaction

AB2(l) + X2(g) AX2(g) + BX2(g)
H = –270 Kcal/mol of AB2(l)
The enthalpy of formation of
AX2(g) & BX2 (g) are in ration 4 : 3 & having opposite sign. The value of Hf0 (AB2(l)) = +30 K cal /
ml then
(A) Hf0 (AX2) = –96 K cal/mol
(B) Hf0 (BX2) = +480 Kcal/mol
(C*) Kp = Kc & Hf0 (AX2) = +480 K cal/mol ; Hf0 (BX2) = –360 K cal/mol
(D) none of these
[Sol: AB2(l) + 3X2(g) AX2(g) + 2BX2(g)
H = ( H AX 2  H BX 2 )  ( H AB 2  H X 2 )
– 270 = (4a + 2(-3a) - (30 + 0)
– 270 = –2a – 30
2a = 270 - 30  2a = 240  a = 120
 AX 2 = 4a = 4 x 120 = + 480
 BX 2 = -3a = -3 x 120 = -360
& Kp = Kc (RT)ng  K = Kc ( n g  0 ) (C) ]

i ) I 2  Ca ( OH ) 2
(
i ) CH 3MgBr
  B (    C. C is
Q.48 P
2O 5
 A ( ii ) H 3O  (ii ) 

(A) (B)

(C*) (D)
[Sol: P2O5 is dehydrating reagent.

Ans (C) ]

Q.49 Four test tubes containing dil. HCl, BaCl2, CdCl2 and KNO3 solution. Which of the following will
identify BaCl2?
(A) dil. H2SO4 (B*) K2CrO4 (C) FeSO4/H2SO4 (D) AgNO3

Q.50 Arrange in order of enolic content

(a) (b)

(c) (d)

(A*) c > d > b > a (B) d > c > a > b (C) a > c> d > b (D) b > c > a > d