Rang Academy

Chapter : 9,11 Std 12 : Chemistry Date : 18/12/22

Total marks - 60 Test
Section A
//X
• Choose correct answer from the given options. [Each carries 1 Mark] [60]
1. Which complex ion of the following contains atomic magnet property possesses ?
(A) [Ni(H2O)6]2+ (B) [Ni(Co)4] (C) [Co(NH3)6]3+ (D) [Zn(H2O)4]2+
2. Which complex ion from the following does not have electron in d-orbit of a atom of a central metal ?
(A) [MnO4]– (B) [Co(NH3)6]+3 (C) [Fe(CN)6]–3 (D) [Cr(H2O)6]+3
3. Which complex from the following possesses maximum isomers ?

MY
(A) [Co(NH3)4Cl2] (B) [Ni(en)(NH3)4]2+
(C) [Ni(C2O4)(en)2]2– (D) [Cr(SCN)2(NH3)4]+
4. Which complex possesses facial and meridian isomers ?
(A) [Co(NH3)3Cl3] (B) [Co(NH3)4Cl2]Cl (C) [Co(en)3]Cl3 (D) [Co(NH3)5Cl]Cl2

DE
5. Least coordination number is shown by .........
(A) Co2(CO)8 (B) Mn2(CO)10 (C) [Cr(OH)3(NH3)3 ] (D) [Fe(en)2NH3]
6. One mole aqueous solution of complex compound [Co(NH3)5Cl3] gives 3 moles of ions. So if 1 mole
of same compound reacts with 2 mole of AgNO3 and 2 mole AgCl(s) is obtained then what is the
formula of that complex ?
CA
(A) [Co(NH3)3Cl3]2NH3 (B) [Co(NH3 )4Cl2]Cl · NH3
(C) [Co(NH3 )4Cl]Cl2 · NH3 (D) [Co(NH3)5Cl]Cl2
7. State the types of isomer of complexes [Co(NH3)6] [Cr(CN)6] and [Cr(NH3)6] [Co(CN)6].
(A) Linkage isomers (B) Ionization isomers
A

(C) Co-ordination isomers (D) Geometrical isomers

8. What is the number of geometrical isomers of complex [Pt(Py)(NH3)BrCl] ?
NG

(A) 3 (B) 4 (C) 0 (D) 2

9. Among the following complexes the one which show zero crystal field stabilization energy is...
(A) [Mn(H2O)6]3+ (B) [Fe(H2O)6]3+ (C) [Co(H2O)6]3+ (D) [Co(H2O)6]2+
10. The equation which is balanced and represents the correct product(s) is :
excess NaOH
(A) [Mg (H2O)6]2+ + (EDTA)4–¾¾¾¾¾¾ ® [Mg (EDTA)]2+ + 6H2O
RA

(B) CuSO4 + 4KCN ® K2[Cu (CN)4] + K2SO4

(C) Li2O + 2KCl ® 2LiCl + K2O
(D) [CoCl (NH3)5]+ + 5H+ ® Co2+ + 5NH+4 + Cl–

11. The hybridization involved in complex [Ni(CN)4]2– is (At. No. Ni = 28)

(A) d2sp2 (B) d2sp3 (C) dsp2 (D) sp3

12. Which of these statements about [Co(CN)6]3– is true ?

(A) [Co(CN)6]3– has no unpaired electrons and will be in a low-spin configuration.
(B) [Co(CN)6]3– has four unpaired electrons and will be in a low-spin configuration.
(C) [Co(CN)6]3– has four unpaired electrons and will be in a high-spin configuration.
(D) [Co(CN)6]3– has no unpaired electrons and will be in a high-spin configuration.
13. The correct increasing order of trans- effect of the following specie is ..........
(A) NH3 > –CN > Br– > C6H–5 (B) –CN >Br– > C6H–5 > NH3
(C) –CN > C6H–5 > Br– > NH3 Br– > –CN > NH3 > C6H–5
(D)Best
Wish You - All The
 The correct increasing order of trans- effect of the following specie is ..........
(A) NH3 > –CN > Br– > C6H–5 (B) –CN >Br– > C6H–5 > NH3
(C) –CN > C6H–5 > Br– > NH3 (D) Br– > –CN > NH3 > C6H–5
14. The pair having the same magnetic moment is : [At. No. : Cr = 24, Mn = 25, Fe = 26, Co = 27]
(A) [CoCl4]2– and [Fe(H2O)6]2+ (B) [Cr(H2O)6]2+ and [CoCl4]2–
(C) [Cr(H2O)6]2+ and [Fe(H2O)6]2+ (D) [Mn(H2O)6]2+ and [Cr(H2O)6]2+

15. The [Co(H2O)6]2+ ion has three unpaired electrons. The hybridization of Co in [Co(H2O)6]2+ is ......
(A) sp3 (B) dsp2 (C) sp3d2 (D) d2sp3
16. Which of the following complex ions is not diamagnetic ?
(A) [Ti(en)2(NH3)2]4+ (B) [Cr(NH3)6]3+
(C) [Zn(NH3)6]2+ (D) [Sc(H2O)3(NH3)3]3+
17. In Wilkinson’s catalyst, the hybridisation of central metal ion and its shape are respectively
(A) dsp2, square planar (B) sp3d, trigonal bipyramidal

MY
(C) sp3, tetrahedral (D) d2sp3, octahedral

18. The total number of possible isomers for square planar [Pt(Cl)(NO2)(NO3)(SCN)]2– is ............
(A) 16 (B) 8 (C) 24 (D) 12
19. The geometry and magnetic behaviour of the complex [Ni(CO)4] are....

20.
(A) tetrahedral geometry and paramagnetic.
(C) square planar geometry and paramagnetic.

(A) Linkage isomerism

DE (B) square planar geometry and diamagnetic.
(D) tetrahedral geometry and diamagnetic.
The type of isomerism shown by the complex [CoCl2(en)2]+ is
(B) Geometrical isomerism
CA
(C) Ionization isomerism (D) Coordination isomerism
21. Consider the following reaction and statements :
[Co(NH3)4Br2]+ + Br– ® [Co(NH3)3Br3] + NH3
(I) Two isomers are produced if the reactant complex ion is a cis-isomer.
A

(II) Two isomers are produced if the reactant complex ion is a trans-isomer.
(III) Only one isomer is produced if the reactant complex ion is a tran-isomer.
(IV) Only one isomer is produced if the reactant complex ion is a cis-isomer.
NG

The correct statements are :

(A) (I) and (II) (B) (I) and (III) (C) (III) and (IV) (D) (II) and (IV)
22. ) The coordination number of Th in K4[Th(C2O4)4(OH2)] is .......
(A) 10 (B) 6 (C) 8 (D) 14
23. A reaction of cobalt(III) chloride and ethylene diamine in a 1 : 2 mole ratio generates two isomeric
RA

products (A) (violet coloured) and (B) (green coloured). (A) can show optical activity where as (B) is
optically inactive. What type of isomers does (A) and (B) represent ?
(A) Geometrical isomers (B) Ionization isomers (C) Coordination isomers (D) Linkage isomers
24. The oxidation states of Cr in [Cr(H2O)6]Cl3, [Cr(C6H6)2] and K2[Cr(CN)2(O)2(O)2(NH3)] respectively
are :
(A) +3, +4 and +6 (B) +3, +2 and +4 (C) +3, 0 and +6 (D) +3, 0 and +4
25. Pick out the correct statement w.r.t. [Mn(CN)6]3–.
(A) It is sp3d2 hybridised and octahedral. (B) It is dsp2 hybridised and square planar.
(C) It is d2sp3 hybridised and octahedral. (D) It is sp3d2 hybridised and tetrahedral.
26. Number of possible isomers for the complex [Co(en)2Cl2] Cl will be : (en = ethylenediamine)
(A) 3 (B) 4 (C) 2 (D) 1
27. Which of the following has longest C – O bond length ? [Free C – O bond length in CO is
1.128 A°]
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(A) [Fe(CO)4]2– (B) [Mn(CO)6]+ (C) Ni(CO)4 (D) [Co(CO)4] –
 Which of the following has longest C – O bond length ? [Free C – O bond length in CO is
1.128 A°]
(A) [Fe(CO)4]2– (B) [Mn(CO)6]+ (C) Ni(CO)4 (D) [Co(CO)4] –
28. Cobalt(III) chloride forms several octahedral complexes with ammonia. Which of the following will not
give test for chloride ions with silver nitrate at 25°C ?
(A) CoCl3 · 3NH3 (B) CoCl3 · 4NH3 (C) CoCl3 · 5NH3 (D) CoCl3 · 6NH3

29. The name of complex ion, [Fe(CN)6]3– is :

(A) Tricyanoferrate (III) ion (B) Hexacyanidoferrate (III) ion
(C) Hexacyanoiron (III) ion (D) Hexacyanitoferrate (III) ion
30. Which of the following complex species is not expected to exhibit optical isomerism ?
(A) [Co(en)3]3+ (B) [Co(en)2Cl2]+
(C) [Co(NH3)3Cl3 ] (D) [Co(en)(NH3)2Cl2]+

MY
31. Low spin complex of d6 – cation in an octahedral field will have the following energy :
-12
(A) Do + P
5
-12
(B) Do + 3P
5
-2

32.
(C)

(D)
5
-2
5
Do + P

DE
Do + 2P[Do : Crystal field splitting energy in an octahedral field, P = electron pairing energy]

NiCl2{P(C2H5)2(C6H5)}2 exhibits temperature dependent magnetic behaviour. The coordination

CA
geometries of Ni2+ in paramagnetic and diamagnetic behaviour are respectively ...........
(A) Tetrahedral and Tetrahedral. (B) Square planar and Square planar.
(C) Tetrahedral and Square planar. (D) Square planar and Tetrahedral.
33. Which is optical isomer from the following ?
A

(A) [Co(H2O)4(en)]3+ (B) [Zn(en)2]2+ (C) [Zn(en)(NH3)2]2+ (D) [Co(en)3]3+

34. Which one of the following shows optical isomerism ?
(A) [Zn(en)2]2+ (B) [Zn(en)(NH3)2]2+ (C) [Co(en)3]3+ (D) [Co(H2 O)4(en)]3+
NG

35. What is the magnetic moment of Cr(CO)6 in BM unit ?

(A) 0 (B) 2.84 (C) 4.90 (D) 5.92
36. What is co-ordination numbers of E in [E(en)2(C2O4)]NO2 complex and what is its oxidation state ?
(A) 6 and 3 (B) 6 and 2 (C) 4 and 2 (D) 4 and 3
RA

37. Which complex of the following possesses square planar structure ?

(A) [FeCl4]2– (B) [NiCl4]2– (C) [PtCl4]2– (D) [CoCl4]2–
38. Which type Fe – CO bond is possessed in [Fe(CO)5] complex ?
(A) s-type (B) p-type (C) (A) and (B) both (D) Ionic type
39. What is the oxidation no. of [Cr(NH3)4Cl2]+ ?
(A) +3 (B) +2 (C) +1 (D) 0
40. How many EDTA molecules are needed to make octahedral complex with Ca2+ ion ?
(A) 3 (B) 1 (C) 2 (D) 6
41. Oxidation product 1, 2-cyclopentanediol with HIO4 gives
O
(A) H C – CH2 – CH 2 – CH 2 – C – H (B)
|| ||
O O O

(C) O = C – CH2 – CH2 – CH2 – C =Wish

O You - All The
(D)Best
none of these
| |
OH OH
 (A) H C – CH2 – CH 2 – CH 2 – C – H (B)
|| ||
O O O

(C) O = C – CH2 – CH2 – CH2 – C = O (D) none of these

| |
OH OH
42. A : Ethers can be dried by using sodium wire.
R : Ethers do not react with sodium.
(A) Assertion and reason both are correct statements and reason explains the assertion.
(B) Both assertion and reason are wrong statements.
(C) Assertion is correct statement and reason is wrong statement.
(D) Assertion is wrong statement and reason is correct statement.
43. Arrange the following compounds in order of decreasing acidity :
OH OH OH OH

MY
; ; ;
Cl CH3 NO2 OCH3
(I) (II) (III) (IV)
(A) II > IV > I > III (B) I > II > III > IV (C) III > I > II > IV (D) IV > III > I > II
44. Compound (A), C8H9Br, gives a white precipitate when warmed with alcoholic AgNO3. Oxidation of

(A)
CH3
CH2Br

(B)
C2 H5

Br
DE
(A) gives an acid (B), C8H6O4 (B) easily forms anhydride on heating. Identify the compound (A).

(C)
CH2Br

CH3
(D)
CH2Br

CH3
CA
45. Among the following ethers, which one will produce methyl alcohol on treatment with hot concentrated
HI ?

(A) CH 3 – CH – CH2 – O – CH 3 (B) CH3 – CH2 – CH2 – CH2 – O – CH3

A

|
CH 3
CH3
|
NG

(C) CH 3 – CH2 – CH – O – CH 3 (D) CH 3 – C – O – CH3

| |
CH3 CH 3

46. Sodium phenoxide when heated with CO 2 under pressure at 125oC yields a product which on
acetylation produces C.
RA

ONa H+
+ CO2 5125º
Atm
B AC C
2O
The major product C would be :
OH
OH O COCH3 O COCH3
COCH3
(A) COOCH3 (B) (C) COOH (D)
COOH
COCH3
47. The most suitable reagent for the conversion of R – CH2 – OH ® R – CHO is :
(A) CrO3 (B) PCC(Pyridinium Chlorochromate)
(C) KMnO4 (D) K2Cr2O7

48. Among the following sets of reaction which one produces anisole ?
(A) CH3CHO, RMgX (B) C6H5OH, NaOH, CH3I
(C) C6H5OH, neutral FeCl3 (D) C6H5CH3, CH3COCl, AlCl3

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49. ) 2-Chloro-2-methylpentane on reaction with sodium methoxide in methanal yields :
CH3
(a) C2H5CH2C OCH3 (b) C2H5CH2C CH2 (c) C2H5CH C CH3

CH3 CH3 CH3

(A) (a) and (b) (B) All of these (C) (a) and (c) (D) (c) only

– NaH – + Me–1
OH O Na

103)
50.
Me
O

MY
Can be classified as :
(A) Alcohol formation reaction (B) Dehydration reaction
(C) Williamson alcohol synthesis reaction (D) Williamson ether synthesis reaction
51. ) The major product obtained in the following reaction is ......
O
O

COOH
DIBAL - H
¾¾¾¾¾¾ ® DE
CA
OH OH

(A) CHO (B) CHO (C) CHO (D) CHO

COOH CHO COOH CHO

A

52. ) An organic compound (X) showing the following solubility profile :

Water Insoluble
‘X’ 5% HCl
NG

Insoluble
10% NaOH
Soluble
10% NaHCO3
Insoluble
The compound (X) is ............
(A) m-cresol (B) Oleic acid (C) o-Toludiene (D) Benzamide
RA

53. ) Anisole on cleavage with HI gives :

OH I OH I
(A) +C2H5I (B) +C2H5OH (C) +CH3I (D) +CH3OH

CH3
|
CH 3 – C – CH2OH
119)
54. |
CH3
How this compound respond the Lucas test ?
(A) No reaction (B) Coloured layer formed
(C) Oily droplets appear (D) Mixture becomes milky white
55. ) Which of the following compound is more acidic ?
CH3 · CH · CH3
(A) CH3 · OH (B) |
Wish You - All The Best OH
CH 3
|
CH · C – CH
 ) Which of the following compound is more acidic ?
CH3 · CH · CH3
(A) CH3 · OH (B) |
OH
CH 3
|
(C) CH3 · CH2 · CH2 · OH (D) CH 3 · C – CH 3
|
OH
56. ) Following options contain the pairs of the name of reaction and the name of final product, which pair
is incorrect ?
(A) Kolbe-Smitt reaction ® 2-Hydroxy benzoic acid
(B) Cumene Process ® Phenol and acetone
(C) Reimer-Tiemann reaction ® 2-Hydroxy benzaldehyde
(D) Fries rearrangement ® Methoxy benzoic acid
57. ) Which products are otained when phenyl ethanoate reacts in presence of Anh.AICl3 ?

MY
(A) o – Hydroxy acetophenone and
p – Hydroxy acetophenone
(B) o – Methoxy acetophenone and
p – Methoxy acetophenone
(C) o – Methyl acetophenone and
p – Methyl acetophenone
(D) o – Ethoxy acetophenone and
p – Ethoxy acetophenone
DE
58. ) How many gm. of ethanol is required in the reaction with Na metal in order to give 560 ml. dihydrogen gas
CA
at STP ? [mole. mass of ethanol = 46 gm mol–1]
(A) 1.15 (B) 2.3 (C) 4.6 (D) 11.5
59. ) The IUPAC name of the product obtained by the oxidation of phenol with the help of chromic acid
is ........... .
A

(A) Cyclo hexa – 2,4 – diene – 1,4 – dione (B) Cyclo hexa – 2,5 – diene – 1,4 – dione
(C) Cyclo hexa – 2,5 – diene – 1,4 – diol (D) Cyclo hexa – 2,4 – diene – 1,4 – diol
60. ) Which is the final product obtained by the reaction of a Grignard reagent ethyl Magnesium bromide
NG

with propanone ?
(A) Pentane-1-ol (B) 2-Methylbutane-2-ol
(C) Pentane-2-ol (D) 3-Methylbutane-2-ol
RA

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 Rang Academy
Chapter : 9,11 Std 12 : Chemistry Date : 18/12/22
Total marks - 60 Test

Section [ A ] : 1 Mark MCQ

No Ans Chap Sec Que Universal_QueId

1. A Chap 9 S6 1 QP22P11B1212_P1C9S6Q1
2. A Chap 9 S6 4 QP22P11B1212_P1C9S6Q4
3. D Chap 9 S6 7 QP22P11B1212_P1C9S6Q7
4. A Chap 9 S6 21 QP22P11B1212_P1C9S6Q21
5. A Chap 9 S6 30 QP22P11B1212_P1C9S6Q30
6. D Chap 9 S6 39 QP22P11B1212_P1C9S6Q39
7. C Chap 9 S6 53 QP22P11B1212_P1C9S6Q53
8. A Chap 9 S6 54 QP22P11B1212_P1C9S6Q54
9. B Chap 9 S6 64 QP22P11B1212_P1C9S6Q64
10. D Chap 9 S6 65 QP22P11B1212_P1C9S6Q65
11. C Chap 9 S6 73 QP22P11B1212_P1C9S6Q73
12. A Chap 9 S6 72 QP22P11B1212_P1C9S6Q72
13. C Chap 9 S6 81 QP22P11B1212_P1C9S6Q81
14. C Chap 9 S6 80 QP22P11B1212_P1C9S6Q80
15. C Chap 9 S6 89 QP22P11B1212_P1C9S6Q89
16. B Chap 9 S6 88 QP22P11B1212_P1C9S6Q88
17. A Chap 9 S6 91 QP22P11B1212_P1C9S6Q91
18. C Chap 9 S6 92 QP22P11B1212_P1C9S6Q92
19. D Chap 9 S6 95 QP22P11B1212_P1C9S6Q95
20. B Chap 9 S6 96 QP22P11B1212_P1C9S6Q96
21. B Chap 9 S6 97 QP22P11B1212_P1C9S6Q97
22. A Chap 9 S6 100 QP22P11B1212_P1C9S6Q100
23. A Chap 9 S6 98 QP22P11B1212_P1C9S6Q98
24. D Chap 9 S6 93 QP22P11B1212_P1C9S6Q93
25. C Chap 9 S6 83 QP22P11B1212_P1C9S6Q83
26. A Chap 9 S6 75 QP22P11B1212_P1C9S6Q75
27. A Chap 9 S6 76 QP22P11B1212_P1C9S6Q76
28. A Chap 9 S6 70 QP22P11B1212_P1C9S6Q70
29. B Chap 9 S6 71 QP22P11B1212_P1C9S6Q71
30. C Chap 9 S6 62 QP22P11B1212_P1C9S6Q62
31. B Chap 9 S6 59 QP22P11B1212_P1C9S6Q59
32. C Chap 9 S6 58 QP22P11B1212_P1C9S6Q58

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33. D Chap 9 S6 49 QP22P11B1212_P1C9S6Q49
34. C Chap 9 S6 50 QP22P11B1212_P1C9S6Q50
35. A Chap 9 S6 48 QP22P11B1212_P1C9S6Q48
36. A Chap 9 S6 47 QP22P11B1212_P1C9S6Q47
37. C Chap 9 S6 46 QP22P11B1212_P1C9S6Q46
38. A Chap 9 S6 44 QP22P11B1212_P1C9S6Q44
39. A Chap 9 S6 41 QP22P11B1212_P1C9S6Q41
40. B Chap 9 S6 43 QP22P11B1212_P1C9S6Q43
41. A Chap 11 S6 86 QP22P11B1212_P2C11S6Q86
42. A Chap 11 S6 88 QP22P11B1212_P2C11S6Q88
43. C Chap 11 S6 90 QP22P11B1212_P2C11S6Q90
44. D Chap 11 S6 91 QP22P11B1212_P2C11S6Q91
45. D Chap 11 S6 92 QP22P11B1212_P2C11S6Q92
46. C Chap 11 S6 93 QP22P11B1212_P2C11S6Q93
47. B Chap 11 S6 94 QP22P11B1212_P2C11S6Q94
48. B Chap 11 S6 95 QP22P11B1212_P2C11S6Q95
49. B Chap 11 S6 102 QP22P11B1212_P2C11S6Q102
50. D Chap 11 S6 103 QP22P11B1212_P2C11S6Q103
51. B Chap 11 S6 104 QP22P11B1212_P2C11S6Q104
52. A Chap 11 S6 107 QP22P11B1212_P2C11S6Q107
53. C Chap 11 S6 113 QP22P11B1212_P2C11S6Q113
54. A Chap 11 S6 119 QP22P11B1212_P2C11S6Q119
55. A Chap 11 S6 122 QP22P11B1212_P2C11S6Q122
56. D Chap 11 S6 123 QP22P11B1212_P2C11S6Q123
57. A Chap 11 S6 132 QP22P11B1212_P2C11S6Q132
58. B Chap 11 S6 133 QP22P11B1212_P2C11S6Q133
59. B Chap 11 S6 134 QP22P11B1212_P2C11S6Q134
60. B Chap 11 S6 135 QP22P11B1212_P2C11S6Q135

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