JEE (Main + Adv.

) Division

Daily Practice Problems

Chemistry

IUPAC

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 IUPAC
DPP – 1
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

1. An unsaturated compound has:
(A) Carbon-carbon double bond (B) Carbon-carbon triple bond
(C) Carbon-carbon double or triple bond (D)Carbon-oxygen double bond
2. The total number of secondary H-atoms in the structure given below are:
CH3 CH CH2 CH3
CH3
(A) 1 (B) 4 (C) 3 (D) 2
CH3 CH3

3. ; and
CH3
Number of secondary carbon atoms present in the above compounds respectively are:
(A) 6, 4, 5 (B) 4, 5, 6 (C) 5, 4, 6 (D) 6, 2, 1
4. Which of the following have only 2º H-atom

(a) (b)

CH3
CH2
(c) (d)

Correct code is :
(A) a andb (B) a, b and d (C) a, c and d (D) a, b, c and d
5. The number of olefinic bonds in the given compound is/are
CH2 CH C CH CH C N
O
(A) 2 (B) 3 (C) 1 (D) 4
6. The number of acetylinilic bonds in the given compound is/are
HC C C CH CH C N
O
(A) 2 (B) 3 (C) 1 (D) 4
7. The geometry of the compound is :-
CH2 CH CH CH2
(A) Tetrahedral (B) Linear (C) Planar (D) Pyramidal

8. The hybrid state of C-atoms which are attached to single bond with each other in the following
structure are:
CH2 CH C CH
(A) sp2, sp (B) sp3, sp (C) sp2, sp2 (D) sp2, sp3

9. In compound HC C CH2 CH CH CH3 , the C2—C3 bond is the type of:-

(A) sp – sp2 (B) sp3 – sp3 (C) sp – sp3 (D) sp2 – sp2

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10. The IUPAC name of this compound is :
F Cl
CH3 C CH2 C CH3
C2H5 C2H5
(A) 2–Fluoro–4–chloro–2,4–diethyl pentane
(B) 3–Fluoro–5–chloro–3–methyl–5–ethyl hexane
(C) 3–chloro–5–fluoro-3,5–dimethyl heptane
(D) 3,5-Dimethyl–5–fluoro–3–chloro heptane
11. Number of 1°, 2° and 3° hydrogen in isooctane is :
(A) 9,8,1 (B) 12,5,1 (C) 15,2,1 (D) None of these
12. Identify total number of 2° amines in given compound?
Me
N H
O
N

NH
N
H O
(A) 1 (B) 2 (C) 3 (D) 4
13. Total number of 3° hydrogens present in given compound are ?

(A) 4 (B) 5 (C) 7 (D) 8

OH
HO OH

14. Number of 2o alcoholic group present in structure

OH

HO OH OH

(A) 3 (B) 2 (C) 4 (D) 5

15. Which compound has same unmber of 1°, 2°, 3° carbon atoms?

(A) (B)

(C) (D)

Answer Key
1. C 2. D 3. A 4. B 5. A 6. C 7. C
8. A 9. C 10. C 11. C 12. B 13. A 14. C
15. D
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 IUPAC
DPP – 2
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

1. No. of hetero atoms present in the following heterocyclic compound is :

O

N H

O
(A) 3 (B) 2 (C) 1 (D) zero

2. Alicyclic compound is
(A) Aromatic compound (B) Aliphatic compound
(C) Hetero cyclic compound (D) Cyclic compound but not aromatic

OH CH2CH2OH
3. (A) and(B)

True statement for the above compounds is :

(A) (A) is phenol while (B) is alcohol
(B) Both (A) and (B) are primary alcohol
(C) (A) is primary and (B) is secondary aclohol
(D) (A) is secondary and (B) is primary alcohol

4. The simplest tertiary amine has :-

(A) 2 carbons (B) 3 carbons (C) 4 carbons (D) 5 carbons

5. Which of the following is the triad of a homologous series :

(A) (CH3)2NH, CH3NHCH2CH3, H5C2NHC2H5 (B) C2H5OH,(CH3)2CHOH, (CH3)3COH
(C) CH2=CH2, CH3–CH=CH2, C2H5–CH=CH2 (D) All the above

6. The higher homologue of dimethylamine (CH3—NH—CH3) has the structure :-

(A) CH3 N CH3 (B) CH3 CH2 CH2 NH2
CH3
(C) CH3 NH CH2 CH3 (D) CH3 CH CH3
NH2

7. What is not true about homologous series :

(A)All the members have similar chemical properties
(B) They have identical physical properties
(C) They can be represented by a general formula
(D) Adjacent members differ in molecular mass by 14

8. Number of hetero atoms in the compound is:

CO CH2
HN O
CO CH2
(A) 1 (B) 2 (C) zero (D) 3

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9. Which of the following are homologues.
OH
(A) CH3CH2 NH2 and CH3CH2NH CH3 (B) CH3 OH and CH3CH2CH2CH2CH2
OH CH2OH

(C) and (D) CH3COOH and CH3 COOCH3

10. Which of the following is a Heterocyclic compound.

H 3C N

(A) HOOC OH NO2 (B)

OH

(C) (D) N

OH

11. In the trivial system which prefix will be used for the following compound ?
CH3
CH3 C
CH3
(A) Neo (B) Tertiary (C) Secondary (D) Iso
12. The group of heterocyclic compounds is ;
(A) Phenol, Furane (B) Furane, Thiophene
(C) Thiophene, Phenol (D) Furane, Aniline

13. Which of the following is a heterocyclic compound

HC CH HC COOH HC CH HC CH
(A) S (B) (C) CH2 (D) C O
HC CH HC COOH HC CH HC CH

14. How many carbons are in simplest alkyne having two side chains?
(A) 5 (B) 6 (C) 7 (D) 8
15. How many secondary carbon atoms does methyl cyclopropane have?
(A) None (B) One (C) Two (D)Three

Answer Key
1. C 2. D 3. D 4. B 5. D 6. C 7. B
8. B 9. B 10. B 11. B 12. B 13. A 14. B
15. C

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 IUPAC
DPP – 3
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

Me
Me

1. IUPAC name of this compound is:

(A) 1,2-dimethyl cyclohex-2-ene (B) 1,2-dimethyl cyclohex-1-ene

(C) 2,3-dimethyl cyclohex-1-ene (D) 1,6-dimethyl cyclohex-1-ene

2. IUPAC Name of is

(A) 5-ethenylcyclopenta-1,3-diene (B) 3-ethenylcyclopenta-1,4-diene

(C) 1-ethenylcyclopenta-2,4-diene (D) 2-ethenylcyclopenta-1,3-diene
Cl

3. name of the compound is

(A) 5-chloro-2-ethyl-1-methyl–cyclohexane
(B) 1-chloro-4-ethyl -3-methyl cyclohexane
(C) 1-ethyl-2-methyl-4-chloro cyclohexane
(D) 4-chloro-1-ethyl-2-methyl cyclohexane
4. CH3 C C CH CH CH CH C C CH3
CH3 CH CH CH CH CH3
(A) Parent Carbon Chain contains three double bonds.
(B) Parent Carbon Chain contains one double bond and two triple bonds.
(C) Parent Carbon Chain contains two double bonds and one triple bond.
(D) Parent Carbon Chain contains two double bonds and two triple bonds.
5. What is the correct IUPAC name of the following compound.
H2C CH CH2 C CH
(A) Pent-1-ene-4-yne (B) Pent-4-ene-1-yne
(C) Pent-1-yne-4-ene (D) 1-Ethenyl-prop-1-yne
6. Which of the following is the correct IUPAC name for the following compound?

(A) 2-(1, 1-dimethyl ethyl)-5-(1-methyl ethyl) heptane

(B) 2-(1, 2-dimethyl ethyl)-5-ethyl-6-methyl heptane
(C) 3-ethyl-2, 6, 7, 7-tetramethyl octane
(D) 6-ethyl-2, 2, 3, 7-tetramethyl octane

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7. Give IUPAC name

(A) 3,3-Diethenyl pent-1-ene (B) 3,3-Diethenyl pent-4-ene

(C) 3-Ethenyl-3-ethyl penta-1,4-diene (D) 3,3,3 Triethenyl propane
Cl
8.

Br
IUPAC name of given compound is -
(A) 3-Bromo 4-chlorohept-1-en-6-yne (B) 5-Bromo 4-chlorohept-1-en-6-yne
(C) 3-Bromo 4-chlorohept-6-en-1-yne (D) 5-Bromo 4-chlorohept-6-en-1-yne
9. Give IUPAC name of following compound

(A) 5-Ethylidene -7-methylene oct-1-yne (B) 5-Ethylidene -7-methyl oct-7-en-1-yne

(C) 4-Ethylidene-2-methyl oct-1-en-7-yne (D) 4-Ethenyl -2-methyl oct-1-en-7-yne
10. Correct IUPAC name of compound is :
Br

Br

(A) 4,4-dibromo cyclohexene (B) 5,5-dibromo cyclohexene

(C) 1,1-dibromo cyclohex-3-ene (D) 1,1-dibromo cyclohex-4-ene
11. Write correct IUPAC name of 2,3 dichloro 2,4 dibromo hept-4-ene.
(A) 2,4-dibromo-2,3-dichloro hept-4-ene (B) 4,6-dibromo-5,6-dichloro hept-3-ene
(C) 4,6-dibromo-5,6-dichloro hept-4-ene (D) 5,6-dichloro-4,6-dibromo hept-3-ene

Cl

12.
Br
IUPAC name of given structure:
(A) 8-bromo-5-chloro cyclooct-3-en-1-yne
(B) 5-bromo-8-chloro cyclooct-1-en-3-yne
(C) 1-bromo-6-chloro cyclo oct-4-en-2-yne
(D) 1-bromo-4-chloro oct-5-en-7-yne
13. The IUPAC name of the compound Br(Cl)CH·CF3 is :
(A) Haloethane
(B) 1,1,1–Trifluoro–2–bromo–2–chloroethane
(C) 2–Bromo–2–chloro–1,1,1–trifluoroethane
(D) 1–Bromo–1–chloro–2,2,2–trifloro ethane

14. The IUPAC name of is :

(A) 4–Ethyl–3–methyl hexane (B) 3–Ethyl–4–methyl hexane

(C) 3–Methyl–4–ethyl hexane (D) All of these

Answer Key
1. D 2. A 3. D 4. A 5. A 6. D 7. C
8. B 9. C 10. A 11. B 12. B 13. C 14. B
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 IUPAC
DPP – 4
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

1. The IUPAC name of given compound is :
CH3CH C CH2CH3
COOH
(A) 3–Carboxy–2–pentene (B) 2–Ethylidene butanoic acid
(C) 2–Ethyl–2–butenoic acid (D) 3–Ethyl–2–buten–4–oic acid

2. IUPAC name of compound is :

CH3 CH CH2 CH CH3
CH2CH3 OH
(A) 4–Methyl–3–hexanol (B) Heptanol
(C) 4–Methyl–2–hexanol (D) 4–Ethylpentan–2–ol

3. The correct IUPAC name of :

CH3 CH2 CH CH2COCl
CH3
(A) 3–Methyl pentanoyl chloride (B) 3–Methyl butanoyl chloride
(C) 1–Chloro–3–ethyl butanone (D) 1–Chloro–3–methyl pentanone

4. The IUPAC name for CH3 C NH2 andCH3 C Cl are :

O O
(A) 1–Amino–1–oxo ethane,1–chloro ethanal
(B) 1–Amino ethanal, acetoyl chloride
(C) 1–Oxoethanamine, ethanoyl chloride
(D) Ethanamide, Ethanoyl chloride
OH

5. The IUPAC name of is :

OH
(A) But–2–ene–2,3–diol (B) Pent–2–ene–2,3–diol
(C) 2–methylbut–2–ene–2,3–diol (D) Pent–3, 4–diol

6. The number of carbon atoms in the principle chain of the given compound are :-
CH3 CH2 CH2 C COOH 
NC C CH2 CH3
(A) 7 (B) 5 (C) 4 (D) 6

7. The IUPAC name of BrCH2 CH CO CH2 CH2CH3 is :

CONH2
(A) 2–(Bromo methyl)–3–oxo hexanamide
(B) 1–Bromo–2–amido–3–oxo hexane
(C) 1–Bromo–2–amido–n–propyl ketone
(D) 3–Bromo–2–butanoyl propanamide
8. The IUPAC name of N C CH2 CH2 OH is :
(A) 1–Hydroxy ethanenitrile (B) 3–Hydroxy propanenitrile
(C) 2–Hydroxy ethyl cyanide (D) 1–Hydroxy–2–cyanoethane

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 O

O
9. Correct IUPAC name is :

(A) 2-methyl-2-pentyl propanoate

(B) 1-ethoxy-2-ethyl-3-methyl-but-2-en-1-al
(C) ethyl-2-ethyl-3-methylpent-2-en-1-oate
(D) ethyl-2,3-diethylbut-2-en-oate

10. In IUPAC nomenclature of compounds

O O O O
(I) C NH2 (II) C OH (III) C Cl (IV) C H
(V) C N
Correct priority order of group is :
(A) I > II > III > IV > V (B) II > III > I > V > IV
(C) II > I > III > IV > V (D) I > III > II > V > IV

11. IUPAC name of following compound is :

COOH

COOH
COOH
(A) 3,5-dicarboxy-2-methyl hexanoic acid
(B) hexane-2,4,5-tricarboxylic acid
(C) hexane-2,3,5-tricarboxylic acid
(D) 2-(1-hydroxy carbonyl)-4-methylhexane-1,6-dionic acid

12. Give the IUPAC name of compound.

NH2 O
C OC2H5
O
(A) 5-Amino-3-oxo-ethylhexanoate
(B) Ethyl-5-amino-3-oxohexanoate
(C) 1-Ethoxy carbonyl-4-amino pentan-2-one
(D) 5-Amino-1-ethoxy-hexane-1,3-dione

13. CHO

Correct IUPAC name of this compound is

(A) Tetracyclopropanal
(B) 1,2,3-tricyclopropylcyclopropanal
(C) 1,2,3-tricyclopropylcyclopropanecarbaldehyde
(D) 1-formyl-1,2,3-tricyclopropylcyclopropane

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 COOH
HO Br

14. IUPAC name of the following compound is :

NO2
(A) 2-bromo-6-hydroxy-4-nitro cyclohexanoic acid
(B) 2-bromo-6-hydroxy-4-nitro cyclohexane carboxylic acid
(C) 6-bromo-2-hydroxy-4-nitro cyclohexane carboxylic acid
(D) 2-hydroxy-6-bromo-4-nitro cyclohexane carboxylic acid

CH3

15. IUPAC name of the compound is

Br

(A) 3-(2-bromo cyclopentyl)-6-methyl-cyclohex-1-ene

(B) 3-methyl-6-(2-bromo cyclopentyl)-cyclohex-1-ene
(C) 1-methyl,4-(2-bromo cyclopentyl)-cyclohex-2-ene
(D) 4-methyl-1-(2-bromo cyclopentyl)-cyclohex-2-ene
OH

16. IUPAC name of the compound is

(A) 3-ethyl-5-methyl phenol

(B) 5-methyl-3-ethyl phenol
(C) 5-methyl-3-ethyl cyclohexanol
(D) 3-ethyl-5-methyl cyclohexanol

Answer Key
1. C 2. C 3. A 4. D 5. B 6. B 7. A
8. B 9. C 10. B 11. C 12. B 13. C 14. B
15. A 16. D

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 IUPAC
DPP – 5
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

1. Correct IUPAC name of following compound is

O NH2
HC CH CH COOH
COOH
(A) 2-amino-3-formylbutan-1,4-dioic acid
(B) 2-formyl-3-amino butan-1,4-dioic acid
(C) 3-amino-2-formylbutan-1,4-dioic acid
(D) 2-amino-3-carboxy-4-oxobutanoic acid

2. The correct IUPAC name of the following compound is:

O C CH2 CH CHO
OH H C O
(A) 3,3-diformyl propanoic acid (B) 3-formyl-4-oxo-butanoic acid
(C) 3,3-dioxo propanoic acid (D) 3,3-dicarbaldehyde propanoic acid

3. Correct IUPAC name of following compound is

O
OHC
O

H2N
O
(A) 3-Amino-2-formyl butane-1,4-dioic anhydride
(B) 2-Amino-3-formyl-1,2-epoxy butane-1,4-dione
(C) 2-Amino-3-formyl butane-1,4-dioic anhydride
(D) 3-Amino-2-formyl-1,2 epoxy butane -1,4 - dione

4. Select the correct IUPAC name of the following compound.

CN

COCl
(A) 4-chloro Carbonyl Benzonitrile
(B) 4-Cyano Benzoyl Chloride
(C) 4-Chloro Carbonyl Benzene Carbonitrile
(D) 4-Carbylamino Benzene Carbonyl Chloride

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5. Which of the following compound is not named correctly?

(A) 3-ethenyl-2,4-heptanedione

O O
Cl
(B) 4,4-dichloro-2,5-cyclohexadien-1-one
O

Cl
O
(C) 3,3-dimethyl-1-phenyl-1-butanone

(D) 5-methylene-hepta-1, 4-dione

O
O

6. IUPAC of following is :
O

OH

Cl
O

(A) 2-Chloro-3-methoxy cyclohex-5-ene carboxylic acid

(B) 6-Chloro-5-methoxy cyclohex-2-ene carboxylic acid
(C) 6-Chloro-5-methoxy cyclohex-2-enoic acid
(D) 2-Chloro-3-methoxy cyclohex-5-enoic acid
O
C O Et

7. IUPAC name of following compound is:

Cl C
O
(A) 4-ethoxycarbonyl benzoyl chloride
(B) Ethyl 4-chlorocarbonyl benzene carbonate
(C) Ethyl 4-chloroformyl phenyl methanoate
(D) Ethyl 4-chlorocarbonyl benzoate

8. Write the correct IUPAC name of 2-amino-1, 3, 7-trihydroxy hept-4-ene-1, 7-dione?

(A) 6-Amino-5-hydroxy hept-3-ene-1, 7-dioicacid
(B) 2-Amino-3-hydroxy hept-4-ene-1, 7-dioicacid
(C) 6-Amino-5-hydroxy hept-4-ene-1, 7-dicarboxylic acid
(D) 6-Amino-5-hydroxy hept-3-ene-1, 7-dicarboxylic acid

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 COOH

9. H2N CHO IUPAC name of the compound is

(A) 3-amino-2- formyl cyclopropane carboxylic acid
(B) 2-amino-3- formyl cyclopropane carboxylic acid
(C) 3-amino-2- formyl cyclopropanoic acid
(D) 2-amino-3- formyl cyclopropanoic acid

10. CH3 CH2 CH2 CH COOH

CH2
C O
OH
Number of carbon in selected principal carbon chain for IUPAC nomenclature will be
(A) 3 (B) 4 (C) 5 (D) 6

11. What will be the correct IUPAC name of the following compound?
COOH

O
Cl O C CH3
(A) 3- Ethanoyl oxy-4-Chloro Cyclopentanoic acid
(B) 3- Chloro-4-Ethanoyloxy Cyclopentanoic acid
(C) 3- Chloro-4-Ethanoyloxy Cyclopentane Carboxylic acid
(D) 3- Ethanoyl oxy-4-Chloro Cyclopentane Carboxylic acid

H3C CH2 CH3

12. Give correct IUPAC name of
CH3
C OCH CH2
O
(A) Ethyl-2-ethyl-5,5 dimethyl cyclopentane carboxylate
(B) Ethenyl-2-ethyl-5,5-dimethyl cyclopentane carboxylate.
(C) Ethenyl-5-ethyl-2,2-dimethyl cyclopentanoate.
(D) Ethenyl-5-ethyl-2,2-dimethyl cyclopentane carboxylate

Answer Key
1. A 2. B 3. C 4. B 5. D 6. B 7. D
8. A 9. B 10. B 11. C 12. D

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 IUPAC
DPP – 6
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

COOH

1.

(A) 3,5-dimethyl Bicyclo [2, 2, 1] hept-2-ene-7-carboxylic acid

(B) 3,7-dimethyl Bicyclo [2, 2, 1] hept-3-ene-1-carboxylic acid
(C) 2,6-dimethyl Bicyclo [2, 2, 1] hept-2-ene-7-carboxylic acid
(D) 3,7-dimethyl Bicyclo [2, 2, 1] hept-6-ene-1-carboxylic acid
Br Cl
Br
2. Give IUPAC name
Cl
Cl Br

(A) 3, 6, 8 - Bromo - 2, 5, 7 - tribromo bicyclo [2 · 2 · 2] octane

(B) 2, 5, 7 - Chloro - 3, 6, 8 - trichloro bicyclo [2 · 2 · 2] octane
(C) 3, 6, 8 - Chloro - 2, 5, 7 - trichloro bicyclo [2 · 2 · 2] octane
(D) 2, 5, 7 - Chloro - 3, 6, 8 - trichloro bicyclo [2 · 2 · 2] octane
3. What will be the correct IUPAC name for the following compound.

OH

Cl
(A) 7-Chloro-2-methyl bicyclo [3,2,1] octan-1-ol
(B) 7-Chloro-2-methyl bicyclo [3,2,1] octan-8-ol
(C) 2-Chloro-7-methyl bicyclo [3,2,1] octan-8-ol
(D) 2-Chloro-7-methyl bicyclo [3,2,1] octane-1-ol
4. Which of the following is/are a bicyclo compound(s):

(I) (II)

(III) (IV)

(A) III only (B) III and IV only (C) II, III and IV (D) I, II, III and IV

5. is
O
(A) Camphor (B) Trimethyl bicyclo[2.2.1]-2-heptanon
(C) 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one (D) Both (A) and (C)
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 I Cl
OH

6. IUPAC name of compound

Br
(A) 2-Chloro-2-bromo-6-iodospiro [4.5]-5-decanol
(B) 2-Bromo-1-Chloro-6 iodospiro [4.5]-5 decanol
(C) 10-Bromo-1-Chloro-6 iodospiro [4.5]-7 decanol
(D) None of these

7. The correct IUPAC name of the spiro compound

O
(A) 1-Oxaspiro[4.3]octane (B) 5-Oxaspiro[3.4]octane
(C) 1-Oxospiro[3.4]octane (D) 5-Oxospiro[4.3]octane

CH3

8. The IUPAC name of the spiro compound,

(A) 8-Methylspiro[4.5]deca-1,7-diene (B) 3-Methylspiro[5.4]deca-3,7-diene

(C) 2-Methylspiro[5.4]deca-1,6-diene (D) 2-Methylspiro[4.5]deca-1,6-diene

9. Consider the following compound :

CN

Its IUPAC name is

(A) Bicyclo[2.2.2]oct-2-en-5-nitrile (B) Bicyclo[2.2.2]oct-5-en-2-carbonitrile
(C) 3-Cyanobicyclo[2.2.2]oct-5-ene (D) 2-Cyanobicyclo[2.2.2]oct-5-ene

10. The IUPAC name of the compound.

COOH
(A) 2-Carboxy bicyclo[2.2.2]oct-5-ene
(B) Bicyclo[2.2.2]oct-2-en-5-oicacid
(C) Bicyclo[2.2.2]oct-5-en-2-carboxylic acid
(D) 3-Carboxy bicyclo[2.2.2]oct-5-ene

C2H5
11. The IUPAC name of the spiro compound

(A) 8-Ethyl spiro[4.5]deca-1,7-diene (B) 2-Ethyl spiro[5.4]deca-1,6-diene

(C) 3-Ethyl spiro[5.4]deca-3,7-diene (D) 2-Ethyl spiro[4.5]deca-2,6-diene
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12. The IUPAC name of the compound is :

Cl
(A) 5-Chloro oct-2-ene (B) 7-Chloro bicyclo[2.2.2]oct-2-ene
(C) 5-Chloro bicyclo[2.2.2]oct-2-ene (D) None of these

13. The systematic name of the compound is :

O O

(A) Bicyclo[2.2.0]octan-2,6-dione (B) Bicyclo[2.2.2]octan-2,6-dione

(C) Bicyclo[1.1.1]octanone (D) None of these

OH

14. The IUPAC name of the compound

(A) Bicyclo[2.2.2]octane-3-ol (B) Bicyclo[4.2.0]octane-6-ol

(C) Bicyclo[4.2.0]octane-3-ol (D) Bicyclo[2.4.0]octane-3-ol

Answer Key
1. C 2. B 3. B 4. B 5. D 6. C 7. B
8. D 9. B 10. C 11. D 12. C 13. B 14. C

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 IUPAC
DPP – 7
JEE [MAIN + ADV.] DIVISION
SINGLE CORRECT QUESTIONS

1. Ethyl methyl vinyl amine has the structure :

(A) CH3CH2 N CH2CH CH2 (B) CH3CH2 N CH CH2
CH3 CH3
(C) CH2 CH N CH CH2 (D) CH3 N CH CH2
CH3 CH3

2. Which of the following are correctly matched :

(a) Trimethyl amine (CH3)3CNH2 (b) Isobutyronitrile (CH3)2CHCH2CN
(c) Secondary butyl alcohol C2H5 CHOH (d) Acetoisonitrile CH3 N C
CH3
(A) a and b (B) b and c (C) c and d (D) a and d

3. The IUPAC name of the following compound is :

CHO

Br OH
(A) 5-Bromo-3-hydroxybenzenecarbaldehyde
(B) 3-Bromo-5-formylphenol
(C) 3-Bromo-5-hydroxybenzenecarbaldehyde
(D) 1-Bromo-3-formyl-5-hydroxybenzene

O
4. IUPAC name of Cl C O 

 (A) 4-Chlorophenyl benzoate. (B) Phenyl-4-chlorobenzenecarboxylate.

 (C) Benzyl-4-chlorobenzenecarboxylate. (D) 4-Chloro diphenylcarboxylate.

5. The correct IUPAC name of the compound.

NH CHO

Cl
(A) N–Formyl-4-chlorobenzenamine (B) N–Formyl-4-chloroaniline
(C) N–(4-chlorophenyl)methanamide (D) N–(Parachlorophenyl)–N–formylaniline

COOC2H5

6. IUPAC name of the compound is

COCl
(A) 2-Chlorocarbonyl ethylbenzenecarboxylate
(B) 2-Carboxyethylbenzoyl chloride
(C) Ethyl 2-(chlorocarbonyl)benzenecarboxylate
(D) Ethyl 1-(chlorocarbonyl)benzenecarboxylate

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 O
7. Common name of compound CH3 CH2 C NH2 is -
(A) acetamide (B) Propionamide (C) Butyramide (D) Acetic amide

8. The structure of 2-butenyl radical is :

(A) CH3 CH C2H5 (B) CH3 CH CH CH2
(C) CH3 CH2 C CH3 (D) CH2 CH2 C CH3

9. Which one is structure of Maleic acid

O
H C C OH
(A) (B) OH CH COOH
OH C C H
CH2 COOH
O
O
OH CH COOH H C C OH
(C) (D)
OH CH COOH H C C OH
O
10. Common name of the strucutreCH3 C O CH CH2 is ?
O

(A) vinyl acetate (B) acryle acetate (C) methyl acrylate (D) Vinyl ethanoate

11. Common name of compound C6H5CHO

(A) Anisole (B) Benzaldehyde (C) Salicylaldehyde (D) None of these

Answer Key
1. B 2. C 3. C 4. B 5. C 6. C 7. B
8. B 9. D 10. A 11. B
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 IUPAC
DPP – 8
JEE [MAIN + ADV.] DIVISION
SINGLE CORRECT QUESTIONS
1. Which of the following is not a neo strucutre:-
C C C C
(A) C C C (B) C C C C C (C) C C (D) C C C C
C C C C
2. Acryl aldehyde is -
(A) A saturated aldehyde (B) An alkene
(C) A polymer (D) An unsaturated aldehyde

3. The common name of the compound CH2 CH C CH CH2 is -

O
(A) Divinyl ketone (B) Diallyl ketone
(C) Both A and B (D) None

4. Common name of CH2 CH CN is :

(a) acrylonitrile (b) vinyl cyanide (c) allyl cyanide (d) allyl nitrile
(A) a, b and d (B) a, and b (C) only b (D) a, b and c

5. The number of possible alkyl groups of iso octane are-

(A) 1 (B) 3 (C) 5 (D) 6

6. Which of the following are secondary redicals:

(a) CH3 C C2H3 (b) CH2 C CH3 (c) CH2 CH (d) (CH3)2 CH
(A) a, b, c (B) a, d, c (C) b, c, d (D) a, b, d

CH2 OH
7. Common name of the structure
CH2 OH
(A) Ethylene Glycol (B) Ethene dialcohol
(C) Glycerol (D) Ethyl
O
8. Common name of the compound CH3 CH2 C NH2
(A) Acetamide (B) Propionamide (C) Butyramide (D) Acetic amide

9. The number of gem dihalides possible with the molecular formula C2H4X2 and C3H6X2 is given by
the set :
(A)1, 2 (B) 2, 1 (C) 2, 2 (D) 1, 1

10. Common name of the structure is CH3 CH2 CH CH2 NH CH2 CH CH2 CH3
CH3 CH3
(A) Di Active amyle amine (B) Active amyl amine
(C)amyle amine (D) none of these

11. Drived name of the following strucuture

H
CH3 CH2 C OH
CH3
(A) methyl ethyl carbinol (B) Ethyl methyl carbinol
(C) Carbinol propyl (D) None of these

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12. The structure of the following compound ethyl di methyl methane
CH3 H
(A) CH3 C CH3 (B) CH3 CH2 C CH3
CH3 CH3
H
(C) CH3 C CH2 CH2 CH3 (D) None of these
H

13. Common name of the compound is Di isopentyl keton

(A) CH3 CH CH2 CH2 C CH2 CH2 CH CH3
CH3 O CH3
(B) CH3 CH C CH2 CH2 CH2 CH CH3
CH3 O CH3
CH3
(C) CH3 C CH2 C CH2 CH CH3
CH3 O CH3
(d) none of these

14. Which of the following compound has sp-hybridised carbon atom :-

(A) CH3COOH (B) CH3COCH3 (C) CH3CH2CN (D) CH2 CH CH CH2

15. The IUPAC name of the compound is

O
Cl is
O
(A)(2-Chloro-1-methylethyl)-2-methylpropanoate
(B) 2-Chloropropyl-2-methylpropanoate
(C) Chloroisopropyl isobutyrate
(D) 1, 2-Dimethyl-2-chloroethylpropanoate

Answer Key
1. C 2. D 3. A 4. B 5. B 6. D 7. A
8. B 9. A 10. A 11. B 12. B 13. A 14. C
15. D

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 IUPAC
DPP – 9
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

1. The IUPAC name of C CH CH3 is

H5C2
(A) 3-Cyclopropyl-3-ethyl-2-propene (B) 1-Cyclopropyl-1-ethylpropene
(C) 3-Cyclopropyl-2-pentene (D) (1-Ethyl-1-propenyl) cylcopropane
O

2. The IUPAC name of is :

O OH
(A) 5-Hydroxy-3, 4-hexanedione (B) 3, 4-Dioxo-2-hexanol
(C) 2-Hydroxy-3, 4-hexanedione (D) 2-Hydroxy-3, 4-diketohexane
OH
OH

3. The IUPAC name of is :

(A) 2-Hydroxybenzenol (B) 1, 2-Dihydroxybenzene

(C) Benzene-1, 2-diol (D) 2-Hydroxyphenol

4. Choose the correct IUPAC name of the compound:

Me
H3C N C Et
Me CH2CH3
(A) N, N-Dimethyl-1-methyl-1-ethyl propane
(B) 3-Methyl-3-(N, N-dimethyl amine) pentane
(C) N-Dimethyl amino-3-methyl pentane
(D) N, N, 3-Tri methyl pentan-3-amine
COOH

5. The IUPAC name of

COOH
(A) 6-Carboxy-2, 3-dimethyl-4-heptenoic acid
(B) 2, 3, 6-Trimethyl-1-heptene-1, 7-dioic acid
(C) 2, 5, 6-Trimethyl-3-heptene-1, 7-dioic acid
(D) 6-Carboxy-2, 5-dimethyl-3-heptenoic acid

6. The IUPAC name of the given compound

O
(CH3)2CH(CH2)2 C N(CH3)2
(A) N, N, 4-Trimethylpentanamide
(B) Dimethylamino-4-methylpentanone
(C) N, N-Dimethylamino-4-methylpentanamide
(D) 2-Methyl-5-oxodimethylpentanamine
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7. Which of the following is not correctly matched :-
CH2 CH2
(A) Ethylene chloride
Cl Cl
(B) Acetonitrile CH2 CH C N
O
(C) Pyruvic acidHO C C CH3
O
(D) Neopentane(CH3)4C

8. The IUPAC name of the structure is :-

Me

Me Me
Me Me

(A) 2,4,5–Triethyl–3–nonene (B) 5,6–Diethyl–2–methyl–4–decene

(C) 2,4,5–Triethyl–3–octene (D) 3–Ethyl–5–methyl–3–heptene

9. Names of some compounds are given. Which one is not in IUPAC system :-
CH3
(A) CH3 CH2 CH2 CH CH CH2 CH3 3–Methyl–4–ethyl heptane
CH2CH3
(B) CH3 CH CH CH3 3–Methyl–2–butanol
OH CH3
(C) CH3 CH2 C CH CH3 2–Ethyl–3–methyl–but–1–ene
CH2 CH3
(D) CH3 C C CH CH3 4–Methyl–2–pentyne
CH3

10. The correct IUPAC name of the compound

is :-
(A) 4-Ethyl-3-propyl hex-1-ene (B) 3-Ethyl-4-ethenyl heptane
(C) 3-Ethyl-4-propyl hex-5-ene (D) 3-(1-ethyl propyl) hex-1-ene

CHO

11. Give IUPAC name of CN :

CH3
(A) 2–cyano–5–methyl hept–3–enal
(B) 2–formyl–5–methyl hept–3–enenitrile
(C) 2–oxo–5–methyl hept–3–ene–1–nitrile
(D) 1–cyano–1–formyl–4–methyl hex–2–ene

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12. The IUPAC name of CH3 is

(A) 3-Cyclobutylcyclopropane (B) 1-Cyclopropyl–3–methylcyclobutane

(C) 1,3-Cyclopropylmethylcyclobutane (D) 2-Methylbicyclo [4.3.0] heptane

13. The IUPAC name of the given compound is

CHO CONH2
CH3 CH CH CH CH COOH
Br COCl
(A) 2-Bromo-4-carbamoyl-5-chloroformyl-3-formylhexanoic acid
(B) 5-Bromo-3-carbamoyl-2-chloroformyl-4-formylhexanoic acid
(C) 4-Formyl-2-chloroformyl-5-carbamoyl-5-bromohexanoic acid
(D) 2-Chloroformyl-3-carbamoyl-4-formyl-5-bromohexanoic acid

14. The IUPAC name of the compound is :-

H C (CH2)2 CH (CH2)2 C H
O H C O O
(A) 1,4,7–Triheptanal (B) 1,3,5–Triformyl pentane
(C) 3–Formyl heptane dial (D) 1,3,5–Pentane tricarbaldehyde

15. The IUPAC name of the given compound is :–

OH CH2 CH2OH
HO CH2 CH CH CH2OH
(A) 3–(Hydroxymethyl) pentane–1,4,5–triol
(B) 3–(Hydroxyethyl) butane–1,2,4–triol
(C) 4–(Hydroxyethyl)–1,2,4–trihydroxy butane
(D) 3–(Hydroxymethyl) pentane–1,2,5–triol

Answer Key
1. C 2. C 3. C 4. D 5. C 6. A 7. B
8. B 9. A 10. A 11. B 12. B 13. B 14. D
15. D

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 IUPAC
DPP – 10
JEE [MAIN + ADV.] DIVISION

SINGLE CORRECT QUESTIONS

1. What is the sum of positions assigned to bromine while numbering the Parent Chain in the
below compounds.
Br Br Br
Br

I. II. III. IV.

(A) 13 (B) 14 (C) 15 (D) 16

2. The IUPAC name for the compound :

O

H2C CH CH3
(A) Propylene oxide (B) 1, 2-Oxo propane
(C) 1, 2-Epoxy propane (D) Methyloxirane
O
3. The IUPAC name of Ph Ph is
O
(A) Benzyl benzoate (B) 2-Phenylethyl phenylacetate
(C) 2, 2-Diphenyl ethylethanoate (D) (2-Phenylethyl)–2–phenylethanoate

OH

4. has the IUPAC name :-

(A) 3,4–Dimethyl–1–penten–3–ol (B) Isopropyl–3–methyl vinyl carbinol

(C) 2,3–Dimethyl–4–penten–3–ol (D) 1-Vinyl-1,2-dimethyl propanol

5. The IUPAC name of given compound is :

O
CH3 CH C CH OCH2 CH3
OCH3 CH3
(A) 2-Ethoxy-4-methoxy pentan-3-one
(B) 1-Ethoxy-3-methoxy-1-methyl butan-2-one
(C) 1-Ethoxy-3-methoxy-1, 3- dimethyl propanone
(D) none of these

6. The IUPAC name of the compound is

OHC CH CH CH CH CH2
CH2 CH2 CH2 CH3
(A) 4-Butyl-2, 5-hexadien-1-al (B) 5-Vinyloct-3-en-1-al
(C) 5-Vinyloct-5-en-8-al (D) 3-Butyl-1, 4-hexadien-6-al

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7. Structure of the compound whose IUPAC name is 3–Ethyl–2–hydroxy–4–methylhex–3–en–5–
ynoic acid is :

OH

COOH
COOH
(A) (B)
OH
OH OH

COOH COOH
(C) (D)

8. Which nomenclature is not according to IUPAC system?

(A) CH3 CH CH CH2CH3 (B) CH3 C CH2 CH2 CH2COOH
CH3 O
5-Oxohexanoic acid

2-Methyl-3-phenylpentane
CH3
(C) Br CH2 CH CH2 (D) CH3 CH2 CH CH2 CHCH3
1-Bromo-prop-2-ene Br CH3
4-Bromo,2,4-di-methylhexane

9. The IUPAC name of following polyfunctional compound is

O
OHC COOH

H H
(A) 2, 4-Dioxo cyclohexanoic acid
(B) 2, 4-Dioxo cycloheptanoic acid
(C) 4-Formyl-2-oxocyclohexane-1-carboxylic acid
(D) 2, 4-Dioxo cyclohexane-1-carboxylic acid

10. The IUPAC name of the compound is

CH3 O
CH O C CH3

(A) 1-Phenyl-1-acetyloxy ethane (B) 1-Acetoxyethyl benzene

(C) 1-Phenylethyl ethanoate (D) 1-Methylbenzyl acetate

11. The IUPAC name of is :

N

(A) N-Ethyl-N, 2-dimethyl-4-hexanamine

(B) N, 4-Diethyl-N, 2-dimethyl-4-butanamine
(C) N-Ethyl-N, 5-dimethyl-3-hexanamine
(D) 3-(Ethylmethylamino)-5-methylhexane

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12. IUPAC name of the compound is
CH3
CH3 C COOC2H5

NO2
(A) Ethyl-2-methyl-2-(m-nitro phenyl) propanoate
(B) Ethyl-2-methyl-2-(o-nitro phenyl) propanoate
(C) Ethyl-2-methyl-2-(3-nitro phenyl) propanoate
(D) Ethyl-2-methyl-2-(3-nitrophenyl) propanoic acid
13. Which of the following has wrong IUPAC name
Me Et

(A) 5-Ethyl-1-methylcyclohexene

(B) 5-Bromo-6-chloro-1-cyclohexen-3-yne
Cl
Br
Cl
Cl

(C) 1, 6-Dichlorocyclohexene

OH

(D) 2–Methylcyclopent–4–en–1–ol

CH3
14. The correct IUPAC name of
O
CH2CH2COCH3

(A) 4-(2-Oxobutyl) cyclohexane-1-one

(B) 2-(3-Oxobutyl) cycloxane-1-one
(C) 1-(2-Oxocyclohexyl) cyclohexane-3-one
(C) 4-(2-Oxocyclohexyl) butan-2-one
15. IUPAC name of the following compound :
O
C
O
C
O
(A) Cyclohexane-1, 2-dicarboxylic acid (B) Cyclohexane-1, 2-dicarboxylic anhydride
(C) Cyclohexane ethanoic anhydride (D) Cyclohexane butanoic anhydride

Answer Key
1. C 2. C 3. D 4. A 5. A 6. A 7. C
8. C 9. C 10. C 11. C 12. C 13. D 14. B
15. B

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