1st Year Chemistry

Revision Assignment (Test 1)

Chapter# 1
Encircle the correct answer.
1. Molecular mass of CaCO3 is
(a) 106 amu (b) 102 amu (c) 100 amu (d) 90 amu
2. Large number of isotopes are known for the elements whose masses are multiple of
(a) Two (b) Four (c) Six (d) Eight
3. One mole of SO2 contains oxygen atoms:
(a) 6.02 x1023 (b) 12.04 x1023 (c) 1 mole (d) 3 moles
4. The number of moles of CO2 which contain 8.0 g of oxygen ..
(a) 0.25 mol (b) 0.5 mol (c) 1.0 mol (d) 1.50 mol
5. The mass of one mole of electron is mg.
(a). 1.008 (b). 0.184 (c) 1.673 (d) 0.55
6. Percentage of oxygen in H2O is
(a) 80% (b) 8.8 % (c). 88.8% (d). 9.8%
7. 9.8 grams of aqueous solution of H2SO4 contains moles of H+ ions
(a) 0.1 (b) 0.2 (c) 0.4 (d) 0.01
8. When 100 g of CaCO3 is decomposed, the CO2 produced occupies a volume at STP.
(a) 2.2414 dm3 (b) 224014 dm3 (c) 22.414 dm3 (d) 0.00214 dm3
9. Which of the following compound does not have empirical formula CH 2O?
(a) HCHO (b) C6H12O6 (c) CH3COOH (d) CH3CH2OH
10. One mole of Carbon – 12 has mass
(a) 0.012 g (b) 1 kg (c) 0.0224 g (d) 12 kg
11. What is the maximum mass of chromium, that can be extracted from 76g of cr 2O3 (Relative
atomic masses: Cr = 52, 0=16)
(a) 48g (b) 52g (c) 104g (d) 152g
12. 27 g of Al will react completely with how much of mass of O2 to produce Al2O3
(a) 32 g of oxygen (b) 24 g of oxygen (c) 16 g of oxygen (d) 18 g of oxygen
13. Hemoglobin contains nearly
(a) 10 atoms (b) 100 atoms (c) 1000 atoms (d) 10000 atoms
14. The percentage of nitrogen in (NH4)2SO4 is
(a) 21.12% (b) 26.96% (c) 36.77% (d) 82.35%
15. Volume occupied by 1.4g of N2 gas at STP is?
(a) 22.414dm3 (b) 11.207dm3 (c) 2.2414dm3 (d) 1.1207 dm3
16. The highest electronegative element in the periodic table is
(a) Oxygen (b) Nitrogen (c) Chlorine (d) Fluorine
17. Each molecule of hemoglobin is 68,000 times heavier than one atom of
(a) C (b) H (c) N (d) O
18. Isotopes differs in properties which depends upon
(a) Electrons (b) Atomic number (c) Mass number (d) All of these
19. Which of the following substances use as CO2 to absorber in combustion analysis ?
(a) 50% KOH (b) silica gel (c) Mg(ClO4)2 (d) All of these
20. The number of isotopes of Cd is
(a) 8 (b) 9 (c) 10 (d) 11
21. Gooch Crucible is used to filter the solution of
(a) KOH (b) K2Cr2O7 (c) KMnO4 (d) K2SO4
22. The largest number of molecules are present in
(a) 3.6 g of H2O (b) 4.8g of C2 H5OH (c) 2.8 g of CO (d) 5.4 g of H2O5
23. Which of the following compounds has the highest % age of oxygen by weight:
 1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
(a) CH3- OH (b) C2H5 – OH (c) HCOOH (d) H2O
24. Numbers of atoms of Oxygen in one mole of O2 is
(a) 6.02 x1023 (b) 12.04 x 1023 (c) 3.01 x 1023 (d) 1.204 x 1023
25. Formula mass of MgSO4 in g/mole:
(a) 150 (b) 120 (c) 130 (d) 140
26. Which of the following is not a molecular ion?
(a) CH4+ (b) O2 + (c) NH4 + (d) All of these
27.Tin has isotopes
(a) 7 (b) 9 (c) 11 (d) 5
28.One a.m.u is equal to
(a) 1.661 × 1027 kg (b) 1.661 × 10-27 kg (c) 1.661 × 10-24 kg (d) 1.661 × 10-27g
29- The mass of CO2 containing 8 grams of oxygen (O2) in grams is
(a) 32 (b) 22 (c) 16 (d) 11
30. Positive ions are called
(a) Cations (b) Anions (c) Molecules (d) Hydrated ions
31. A limiting reactant is one which
(a) is taken in lesser quantity in grams as compared to other reactants
(b) is taken in lesser quantity in volume as compared to other reactants
(c) gives maximum amount of product
(d) gives minimum amount of product
32. Calcium has isotopes;
(a) 7 (b) 9 (c)1 (d)6
33. Which of these statement is not true.
(a) Isotopes with even atomic masses are comparatively abundant
(b Isotopes with odd atomic masses are comparatively abundant ..
(c) Isotopes with even atomic masses and even atomic numbers are comparatively abundant
(d) Isotopes with even atomic masses and odd atomic numbers are comparatively abundant
34. During the process of crystallization, the hot saturated solution.
(a) is cooled very slowly to get large sized crystals
(b) is cooled at a moderate rate to get medium sized
(c) is evaporated to get the crystals of the products
(d) is mixed with an immiscible liquid to get the pure crystals of the product.
35. An ordinary microscope can measure size of object up to
(a) 100 nm (b) 200 nm (c) 400 nm (d) 500 nm
36. How many isotopes are present in palladium.
(a) four (b) five (c) six (d) seven
37. In Al2O3 the ratio between ions are
(a) 1 : 2 (b) 2 : 1 (c) 2 : 3 (d) 3 : 2
38. The number of moles of CO2 which contain 16 grams of oxygen.
(a) 0.25 (b) 0.50 (c) 1.0 (d) 1.50
39. Sn has Isotopes.
(a) 7 (b) 9 (c) 11 (d) 5

40. 18.02 g of H2O sample has


(a) 1 mole of hydrogen atom
(c) 6.022  1023 moles of H2O
41. The percentage of nitrogen in NH3 is
1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
(b) ½ mole of oxygen atom
(d) 6.022  1023 molecules of H2O

(a)  100 (b)  100 (c)  100 (d)  100

42. One mole of SO2 conta ins:

(a) 4.0 gram atoms of SO2 (b) 6.02  1023 atoms of sulphur
(c) 18.1  1023 molecules of SO2 (d) 6.02  1023 atoms of oxygen
43. Isotopes are sister atoms of same element with similar chemical properties but different
(a) atomic number (b) atomic volume (c) atomic weight (d) atomic structure
44. NH3 burns in O2 according to the following reaction: 4NH3 + 3O2  2N2 + 6H2O
(a) It shows that 1 mole of NH3 will produce ½ mole of N2.
(b) 1 mole of NH3 will produce 6 moles of N2.
(c) For the complete reaction, 2 moles of NH 3 and 20g of O2 are required.
(d) For the complete reaction, 2 moles of NH 3 and 40g of O2 are required.
45. Silver has Isotopes ..
(a) 9 (b) 16 (c) 17 (d) 18
46. The number of molecules in one gram molecule of CO 2 is
(a) 6.02 × 1023 (b) 6.02 × 1022 (c) 6.27 ×1027 (d) 6.02 ×1024

SHORT QUESTIONS
1. Calculate the mass of 10 moles of MgSO4?
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2. Define Avogadro ’s number?
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3. How many molecules of water are their in 12g of ice?
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4. Calculate the gram atoms in 0.4g of potassium?
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5. Define isotopes.
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6. If 4 moles of hydrogen react with 2 moles of oxygen then how many moles of water will be produced?
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7. Differentiate between qualitative and quantitative analysis?
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 1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
8. How many moles of CO3-2 CO 3-2 in 60 g of CO3-2 ion?
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9. How much potential difference is applied between the plates to accelerate the positive ions in mass
spectrometer?
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10. What is spectrometry?
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11. The atomic masses may be in fractions. Why?
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12. How does a limiting reactant control the amounts of products formed?
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13. How many molecules of water are in 24 g of ice?
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14. Define quantitative analysis.
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15. A sample of Bromine contains 35Br79 and 35Br81 in percentage 50.54% and 49.49% respectively.
Calculate fraction atomic mass of Bromine.
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16. Concept of limiting reactant is not applicable to the reversible reactions. Explain it.
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17. Molecular formula is multiple of empirical formula. Give an example.
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18. Define Avogadro’s number. How does it relate to the masses of chemical substances?
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19. How can the efficiency of a chemical reaction be expressed?
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20. Why isotopes have the same chemical properties?
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21. The atomic masses may be in fraction. Why?

 1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
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22. Why the experimental yield is mostly less than the theoretical yield?
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23. What is the function of electrometer in mass spectrometer?
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24. Just that N2 and CO have same number of electrons, protons and neutrons.
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25. Define gram molecule and gram formula.
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26. Which laws are to be considered during stoichiometry calculations?
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27. Explain molar volume with two examples.
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28. Why 100 ions of and have unequal number of atoms?
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29. Give two assumptions of stoichiometry?
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30. Why the experiment yield is mostly less than the theoretical yield?
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31. Distinguish between actual and theoretical yield.
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32. What is a limiting reactant? Write steps for its identification.
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33. What is the justification of two strong peaks in mass spectrum of bromide?
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34. Calculate the number of molecules present in 4.40 grams of carbon dioxide.
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35. Define molecule and gram molecule.
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 1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
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36. One mole of H2SO4 should completely react with two moles of NaOH. How does Avogadro’s number
help to explain it?
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37. Justify the statement: 23 g of sodium and 238 g of uranium have equal no. of atoms in them.
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38. Give reasons that law of conservation of mass has to be obeyed during stoichiometric calculations.
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39. Define yield. How do you calculate the percentage yield of a chemical reaction?
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40. No individual neon atom in the sample of the element, has a mass 20.18 a.m.u. justify it.
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41. The total volume of the solution by mixing 100 cm3 of water with 100 cm3 of alcohol may not be equal to
200 cm3. Justify it.
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42. Define the following terms (a) Relative atomic mass (b) Mole
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43. Write down the reason for low value of actual yield than the theoretical yield.
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44. Calculate mass in grams of 10-3 moles of H2O.
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45. Why the isotopes have same chemical properties?
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46. Many chemical reactions taking place around us involve the limiting reactions. Explain.
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47. One mole of N2, CO2 and H2 contain equal number of molecules. Why?
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48. Define the following terms:- (a) Isotope (b) Atomic mass unit
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49. 11 g of carbon is reacted with 32 g of O2 to give CO2? Which is the limiting reactant?
 1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
C + O2 CO2
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50. Give two assumptions of stoichiometry?
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51. What is Avogadro’s number? Give is numerical value?
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52. Formation of uni-negative ion is an exothermic process. Justify.
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53. How many carbon atoms are in 18g of carbon?
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54. What is Avogadro’s number? Establish a relationship between mass and Avogadro’s number of
elements ?
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55. Prove that CO and N2 contain equal number of fundamental particles ?.
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56. why actual yield is always less than theoretical yield?.
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57. Why atomic masses of elements are always in fractions?.
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58. Differentiate between ions and molecular ions?
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59. A compound have same empirical and molecular formula justify?
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60. Write down the assumptions of stoichiometery?
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61. What is mass spectrum?
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62. Two grams of H2, 16 g of CH4 and 44 g of CO2 occupy separately the volumes of 22.414 dm3, although
the sizes and masses of molecules of three gases are very different from each other.
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63. Calculate the number of water molecules in 10 g of ice.
 1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
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64. One mg of K2CrO4 has thrice the number of ions than the number of formula units when ionized in
water.
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65. Why oxygen cannot be determined directly in combustion analysis?
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71. Define limiting reactant, give an example.
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72. Explain mathematical relationship for m/e of an ion in mass spectrometry.
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73. Mg atom is twice heavier than that of carbon atom. Comment.
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74. Sea water has 5.65 × 10-3g of dissolved oxygen in one kg of water. Calculate the concentration of oxygen
in sea water in parts per million.
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75. Define atomic mass unit. Give its value in grams.
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LONG QUESTIONS
1. Define molecules and its properties?
2. What is relative atomic mass?
3. What are Isotopes, relative abundance of Isotopes and how their relative atomic masses are
determined?
4. 8.657 g of a compound were decomposed into its into its elements and gave 5.271 g of carbon,
0.962 g of hydrogen 2.478g of oxygen. Calculated the percentage composition of the compound under
study
5. The combustion analysis if an organic compound shows it to contain 65.44 % carbon, 5.50% hydrogen and
29.06% oxygen. what is the empirical formula of the compound? If the molecular mass of this
compound is 110.15. Calculate the molecular formula of the compound.
6. What is Mole, gram mole, formula mass and Avogadro’s number?
7. Calculate the amount of NH3 formed by heating together NH4Cl and Ca(OH)2 when a mixture containing
100 g of each is heated. The reaction is as follows.
2NH4Cl(S) + Ca(OH)(S) CaCl2(S) +2H2O(S) + 2NH3(S)

8. 10.0g of H3PO4 have been dissolved in excess of water to dissociate it completely into ions.
 1st Year Chemistry
Revision Assignment (Test 1)
Chapter# 1
Calculate:
a) Number of molecules in 10.0g of H3PO4
b) Number of positive and negative ions in case of complete dissociation in water
c) Mass of individuals ions.
d) Number of positive and negative charges dispersed in the solution.
9. Glucose C6H12O6 is the most important nutrient in the cell for generating chemical potential energy.
Calculate the mass % of each element in glucose and determine the number C, H and O atoms in 10.5g of the
sample.
10. Ethylene glycol is used in automobile antifreeze. It has 38.7% carbon, 9.7% hydrogen and 51.6%
oxygen. It molar mass is 62.1g mol . Determine its empirical formula.
-1

11. Calculate the number of gram of Al2S3, which can be prepared by the reaction by 20.00g of Al and 30.00g of
sulphur. How much non limiting reactants in excess?
12. Silicon carbide (SiC) is an important ceramic material. It is produced by allowing sand (SiO 2) to react with
carbon at high temperature SiO2+ 3C SiC + 2CO, when 100 kg sand is reacted with excess of
carbon 51.4 g of SiC is produced. What is percentage yield of SiC?
13. What is mass spectrometer? How is it used to determine the relative atomic masses of isotopes?
14. Calculate the mass of 1 dm of NH3 gas at 30 C and 1000 mm. Hg pressure considering that NH3s behaving
3 o

ideally.
15. Write down the steps required to find the empirical formula of a compound?
16. Ascorbic acid (vitamin C) contains 40.97 % carbon, 4.58% hydrogen and 54.5 5 oxygen by mass. What is the
empirical formula of the ascorbic acid?
17. Calculate the number of molecules and the number of atoms in 20 cm 3 of CH4 at 0 oC and pressure of 700 mm
of mercury.
18. What are isotopes? How do you deduce the fractional atomic masses of elements from the relative isotopic
abundance? Give one example in support of your answer.
19. NH3 gas is prepared by reacting nitrogen with hydrogen. If we have a mixture of 50 g of each gas, calculate
the number of grams of NH3.
20. Calculate the number of grams of K2SO4 and water produced when 14 g of KOH are reacted with excess of
H2SO4. Also calculate the number of molecules of water produced
2KOH (aq) + H2SO4 (aq) K2SO4(aq) + 2H2O(l)
(At. Mass K = 39 , S = 32, O = 16)
21. What is combustion analysis? How it can be helpful to find empirical formula of organic compounds?