PINNAACLE CLASSES

26. Which of the following pairs represents linkage isomers ?

(a) [Pd(PPh3)2 (NCS)2] and [Pd(PPh3)2 (SCN)2]
(b) [Co(NH3)5 NO3] SO4 and [Co (NH3)5 (SO4)] NO3
(c) [PtCl2 (NH3)4 Br2 and [Pt Br2 (NH3)4] Cl2 31. Major Product is :
(d) [Cu (NH3)4] [Pt Cl4] and [Pt (NH3)4 [CuCl4]
C H 3– C = C H – C H 3 C H 3– C H – C H = C H 2

27. A solution containing 2.675 g of CoCl3.6 NH3 (molar mass = (a) CH3 (b) CH3
267.5 g mol–1) is passed through a cation exchanger. The OH
chloride ions obtained in solution were treated with excess of
C H 2 = C – C H 2– C H 3 CH 3 –CH–CH–CH 3
AgNO3 to give 4.78 g of AgCl (molar mass = 143.5 g mol–1).
The formula of the complex is (At. mass of Ag = 108 u) (c) CH3 (d) CH 3
(a) [Co(NH3)6 ] Cl3 (b) [CoCl2 (NH3)4] Cl
(c) [CoCl3(NH3)3] (d) [CoCl(NH3)5] Cl2
32. Major product of given reaction is-

28. Which of the following name formula combinations is not O 2 N–CH 2 –CH–CH 3
correct ?
Cl Major product
Formula Name (a) O2N–CH=CH–CH3 (b) O2N–CH2–CH=CH2
(a) K2[Pt(CN)4] Potasium CH2  C  CH3
O 2 N–CH =C–CH 3 |
tetracyanoplatinate (II) NO 2
(c) Cl (d)
(b) [Mn(CN)5]2– Pentacyanomagnate (II)
ion
33. Match List I (Reaction) with List II (Type of reaction) and
(c) K[Cr(NH3)2Cl4] Potassium diammine select the correct answer using the code given below the lists :
tetrachlorochromate (III)
(d) [Co(NH3)4(H2O)l]SO4 Tetraammine aquaiodo List
List I
cobalt (III) sulphate II

(P) (a) SN1

29. [Co2(CO)8] displays :
(a) one Co–Co bond, four terminal CO and four bridging
CO
(b) one Co–Co bond, six terminal CO and two
bridging CO
(Q) (b) SN2
(c) no Co–Co bond, four terminal CO and four
bridging CO
(d) no Co–Co bond, six terminal CO and two
bridging CO
(R) (c) E1
30. The correct order of spin-only magnetic moments among the
following is :

(Atomic number : Mn = 25, Co = 27, Ni = 28, Zn =

30) (S) (d) E2
2– 2– 2– 2–
(a) [ZnCl4] > [NiCl4] > [CoCl4] > [MnCl4]
(b) [CoCl4]2– > [MnCl4]2– > [NiCl4]2– > [ZnCl4]2– Codes
(c) [NiCl4]2– > [CoCl4]2– > [MnCl4]2– > [ZnCl4]2– P Q R S
(d) [MnCl4]2– > [CoCl4]2– > [NiCl4]2– > [ZnCl4]2– (a) 4 2 1 3
(b) 2 4 3 1
(c) 3 1 2 4
(d) 2 1 4 3

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 PINNAACLE CLASSES
34. The relative rate of acid catalysed dehydration of following
alcohols would be :

(a) (b)

(c) (d)

37. The major product of the following reaction is :

(a) CH3CH=C=CH2 (b) CH3CH=CHCH2NH2

CH 3
|
C – Ph
|
OH (c) CH3CH2CCH (d)

IV
(a) III > I > IV > II (b) III >IV > I > II
(c) I > III > IV > II (d) IV > III > I > II

⃗
H 2 / Ni
room temp .
38. Product

35. In the given reaction,

[X]
(a) (b)
[X] as the major product among the elimination
products is :
(d)
(c)

(a) (b) 39. Correct name for the given compound,

CH 3 −CH 2 CH −CH 2 −CH −CH 2 −CH 3 is
||
CH 2 CH 3 CH 3
(c) (d)
(a) 3 – Ethyl -5 – Methylheptane
(b) 5 – Ethyl, – 3 – Methylheptane
36. The major product of the following reaction is
(c) 1,1 – Diethyl, – 3 – Methylpentane
(d) 3 – Methyl , – 5,5 – Diethylpentane.

40. How much sulphur is present in organic compound if on

analysis 0.53 gm of this compound gives 1.158 gm of
BaSO 4
(a) 10% (b) 15%

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 PINNAACLE CLASSES

(c) 20% (d) 30% 48. If [Cu(H2O)4]2+ absorbs a light of wavelength 600
nm for d-d transition, then the value of octahedral
crystal field splitting energy for [Cu(H 2O)6]2+ will
be___________x 1021J. (Nearest Integer)(Given : h =
116 mg of a compound on vaporisation in a Victor Meyer’s 6.63 x 10-34Js and c = 3.08 x 108ms-1)
41.

apparatus displaces
44 .8 mlof air measured at S.T.P. The 49. How many of the following is correctly matched complex ?
molecular weight of the compounds is
(a) 116 (b) 232 Complex Oxidation Electronic
(c) 58 (d) 44.8 no. on central configuration
metal
42. If 0.228 g of silver salt of dibasic acid gave a residue of
(a) K3[Co(C2O4)3] +3
0.162g of silver on ignition then molecular weight of the acid (b) (NH4)2 [CoF4] +2
is
(a) 70 (b) 80 (c) Cis - +3
(c) 90 (d) 100 [Cr(en)2Cl2]Cl
(d) [Mn(H2O)6]SO4 +2

43.
0.0833 mol of carbohydrate of empirical formula
CH 2 O

contain 1 g of hydrogen. The molecular formula of the 50. For the octahedral complexes of Fe3+ in SCN– (thiocyanato-S)
carbohydrate is
and in CN– ligand environments, the difference between the
C 5 H 10 O5 C 3 H 4 O3 spin-only magnetic moments in Bohr magnetons (when
(a) (b)
C H O C H O approximated to the nearest integer) is : [Atomic number of
(c) 12 22 11 (d) 6 12 6 Fe = 26]

44. A gas mixture contains 50% helium and 50% methane by

volume. What is the percent by weight of methane in the
mixture
(a) 19.97% (b) 20.05%
(c) 50% (d) 80.03%

45. 0.5 g of hydrocarbon gave 0.9 g water on combustion. The

percentage of carbon in hydrocarbon is
(a) 75.8 (b) 80.0
(c) 56.6 (d) 28.6

46. Among the compounds, Benzene, Carbon

tetrachloride, Naphthalene, Benzole acid,
Isooctane and Anthracene, how many can be
purified by sublimation.

47. Find the value of for given structure

p = degree of unsturation (DU)

q = number of 2° carbon

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