Coordination Compounds

(Average Marks: 3)
For: KCET
c) optical isomerism
1. The Co-ordination number of Fe and Co in d) hydrate isomerism (2018)
the complex ions, [𝐹𝑒(𝐶2 𝑂4 )3 ]3− and 9. The coordination number and the oxidation
[𝐶𝑜(𝑆𝐶𝑁)4 ]2− are respectively: (2020) state of the element ‘M’ in the complex
a) 3 and 4 b) 6 and 8 [M(en)2(C2O4)]NO2 (where, en is ethane -
c) 4 and 6 d) 6 and 4 1,2-diamine) are respectively (2017)
2. Number of stereoisomers exhibited by
a) 6 and 2 b) 4 and 2
[𝐶𝑜(𝑒𝑛)2 𝐶𝑙2 ]+ is (2020)
c) 6 and 3 d) 4 and 3
a) 4 b) 2 c) 5 d) 3
3. Give the IUPAC name of [Pt(NH3)4][PtCl4] 10. Square planar complex of the type MAXBL
is (2020) (where A, B, X and L are unidentate ligands)
a) Tetra ammine platinum (o) tetra chlorido shows following set of isomers
platinum (IV) a) two cis and one trans
b) Tetra ammine palatinate (II) tetra chlorido b) two trans and one cis
platinum (II) c) two cis and two trans
c) Tetra ammine palatinate (o) tetra chlorido d) three cis and one trans (2017)
platinum (IV) 11. According to crystal field theory, the M – L
d) Tetra ammine platinum (II) tetra chlorido bond in a complex is (2017)
palatinate (II) a) purely ionic b) purely coordinate
4. Addition of excess of AgNO3 to an aqueous c) purely covalent d) partially covalent
solution of 1 mole of PdCl2.4NH3 gives 2 12. The number of isomers possible octahedral
moles of AgCl. The conductivity of this complex [CoCl2(en)(NH3)2]+ is (2017)
solution corresponds to (2019) a) Two b) Three
a) 1 : 1 electrolyte b) 1 :3 electrolyte c) No isomer d) Four isomers
c) 1 : 2 electrolyte d) 1 : 4 electrolyte 13. CO is a stronger ligand than Cl-, because
5. The formula of a) CO is a neutral molecule
pentaaquanitratochromium(III)nitrate is b) CO has πbonds
a) [Cr(H2O)6](NO3)3 c) CO is poisonous
b) [Cr(H2O)6](NO2)2 d) CO is more reactive (2016)
c) [Cr(H2O)5NO3](NO3)2 14. Which of the following sequence is correct
d) [Cr(H2O)5NO2]NO3 (2019) regarding field strength of ligands as per
6. Which among the following is the strongest spectrochemical series?
ligand? a) SCN- < F- < CN- < O
a) CN- b) NH3 b) F- < SCN- < CN < CO
c) CO d) en (2019) c) CN- < F- < CO- < SCN-
7. The IUPAC name of [Co(NH3)4Cl(NO2)]Cl d) SCN- < CO < F- < CN- (2016)
a) tetraaminechloridonitrito-N- 15. As per IUPAC names, the name of the
cobalt(III)chloride complex [Co(en)2(ONO)Cl]Cl is
b) tetraaminechloridonitriocobalt(II) a) Chlorodobis(ethane-1,2-diamine)nitro-O-
chloride cobalt(III) chloride
c) tetraaminechloridonitriocobalt(I) chloride b) Chlorobis(ethylenedamie)nitro-O-
d) tetraaminechloridonitriocobalt(III) cobalt(III) chloride
chloride (2018)
8. [Fe(NO2)3Cl3] and [Fe(O – NO)3Cl3] shows
a) linkage isomerism c) Chloridodi(ethylene
b) geometrical isomerism
 Coordination Compounds
(Average Marks: 3)
For: KCET
diamine)nitrocobalt(III)chloride
d) Chloroethylenediaminenitro-O-cobalt(III)
chloride (2016)
16. The complex ion having minimum
magnitude of ∆0(CFSE) is
a) [Co(NH3)6]3+ b) [Cr(H2O)6]3+
c) [Cr(CN)6]3- d) [CoCl6]3- (2015)
17. Which of the following will be able to show
geometrical isomerism?
a) MA2B2 – Tetrahedral
b) MABCD-Tetrahedral
c) MA3B – Square planar
d) MABCD – Square planar (2015)
18. How many ions per molecule are produced in
the solution when Mohr salt is dissolved in
excess of water?
a) 5 b) 10
c) 4 d) 6 (2015)