PINNAACLE CLASSES

31. (b) Reversible reaction always attains equilibrium which proceeds

both sides and never go for completion.

32. (c) In a reversible reaction some amount of the reactants remains

unconverted into products.

33. (a)

34. (d)

35. (c) When rate of forward reaction is equal to the rate of backward
reaction then equilibrium is supposed to be established.

36. (b) Equilibrium can be achieved only in closed vessel.

37. (a)

38. (c) When rate of forward reaction is equal to rate of backward reaction the reaction
is said to be in equilibrium.
39. (b)

40. (d) At equilibrium rate of forward reaction is equal to the rate of

backward reaction.

41. (c) According to Le-chatelier principle when concentration of

reactant increases, the equilibrium shift in favour of forward reaction.

42. (b) According to law of mass-action, “at a given temperature, the rate
of a reaction at a particular instant is proportional to the product of the active masses
of the reactants at that instant raised to powers which are numerically equal to the
numbers of their respective molecules in the stoichiometric equation describing the
reaction”.

43. (a)

64 gm
[ HI ]= =0. 25
44. (d) 128×2 litre
Active mass is the concentration in moles/litre.

45. (c)

46. (a)
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 PINNAACLE CLASSES

47. (d)

48. (a)

49. (d) Equilibrium constant for the reaction , 3A + 2B ⇌ C is

[C ]
= 3 2
K [ A] [B] .

50. (d)Suppose 1 mole of A and B each taken then 0.8 mole/litre of C and D each formed
remaining concentration of A and B will be (1 – 0.8) = 0.2 mole/litre each.
[C ] [ D ] 0 . 8×0 . 8
Kc= = =16 . 0
[ A ] [ B ] 0 . 2×0 . 2

51. (a) H 2 + I 2 ⇌ 2HI; [HI] = 0.80, [ H 2 ]=0 . 10 , [ I 2 ]=0 .10

[ HI ]2 0 . 80×0 . 80
Kc= = =64
[ H 2 ] [ I 2 ] 0 . 10×0 . 10

52. (a)Those reaction which have more value of K proceeds towards completion.

53. (a) K p is constant and does not change with pressure.

54. (a)For reaction A + 2B ⇌ C

[C] 0. 216
K= = =250
[ A ] [ B ] 2 0. 06×0 .12×0 .12 .

55. (c)

56. (d) Δn = 1 for this change

So the equilibrium constant depends on the unit of concentration.

Δn
57. (d)Unit of K p =(atm)
Δn
Unit of K c =(mole /litre )
=[ mole/litre ]0=0

[ ]
2
10 −3
2×
[ NO 2 ]2 2 10−6
K= = = =10−5

58. (c)
[ N2O4]
[ ] .2
2
10−1
.

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 PINNAACLE CLASSES

59. (b)For A + B ⇌ C + D
[C ] [ D ] 0 . 4×1
K= = =1
[ A ] [ B ] 0 .5×0 .8 .

60. (c) A+ B ⇌C+ D

Initial 1 1 0 0
remaining at equilibrium 0.4 0.4 0.6 0.6
[C ] [ D ] 0 . 6×0 .6 36
K= = = =2 .25
[ A ] [ B ] 0 . 4×0 . 4 16 .

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