Top of Pyramid - Test #52- Chemical Kinetics

Contact Number: 9667591930 / 8527521718

1.
In a reaction, the rate expression is, rate = K[A]
Hydrogenation of vegetable ghee at 250C  reduces [B]2/3[C]0 , the order of reaction is:
pressure of H2 from 2 atom to 1.2 atom in 50 minute. The
1. 1
rate of reaction in terms of molarity per second is:
2. 2
(a)1.09 x 10-6
3. 5/3
(b)1.09 x 10-5
4. zero
(c)1.09 x 10-7 6.
(d)1.09 x 10-8 The rate of a reaction get doubles when the temperature
changes from 7°C to 17°C. By what factor will it change
  for the temperature change from 17°C to 27°C?
2. (a) 1.81
Following mechanism has been proposed for a reaction, (b) 1.71
2A+B →D+E (c) 1.91
A+B→ C+D    ...(Slow) (d) 1.76
A+ C→ E         ...(Fast) 7.
The rate law expression for the reaction is: For the elementary step,
(a) r = K[A]2[B] (CH3)3.CBr(aq) → (CH3)3C+ (aq) + Br- (aq) the
(b) r=K[A][B] molecularity is:

(c) r= K[A]2 (a) zero

(d) r= K[A][C] (b) 1

3. (c) 2

For the reaction N2 + 3H2 → 2NH3, the rate d[NH3]/dt = (d) cannot ascertained
2x10-4 Ms-1 .Therefore, the rate -d[N2]/dt is given as: 8.
When ethyl acetate was hydrolysed in pressure of 0.1 N
(a) 10-4 Ms-1
HCl, the rate constant was found to be 5.40 x 10-5 sec-1 .
(b) 104 Ms-1 But when 0.1 N H2SO4 was used for hydrolysis, the rate
constant was found to be 6.25 X10-5sec-1.  Thus, it may
(c) 10-2 sM-1
be concluded that:
(d) 10-4 sM-1 (a) H2SO4 is stronger than HCI
4.
(b) H2SO4 is weaker than HCl
If 'a' is the initial concentration of a substance which
reacts according to zero order kinetics and K is rate (c) H2SO4 and HCl both have the same strength
constant, the time for the reaction to go to completion is:
(d) the data are not sufficient to compare the strength of
(a) a/K H2SO4 and HCI
(b) 2/Ka 9.
(c) K/a The half time of a second order reaction is:
(d) 2K/a (a) inversely proportional to the square of the
5. initial concentration of the reactants
(b) inversely proportional to the initial concentration of 
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 Top of Pyramid - Test #52- Chemical Kinetics
Contact Number: 9667591930 / 8527521718

the reactants (a) 8.665 x 103 minute

(c) proportional to the initial concentration of reactants
(b) 8 x 10-5 minute
(d) independent of the initial concentration of reactants
(c) 1.25 x 104 minute
10.
(d) 4x10-5 minute
The half-life period of a first order chemical reaction is
6.93 minutes. The time required for the completion of 15.
99% of the chemical reaction will be (log 2 = 0.301):
The time for half-life of a first order reaction is 1 hr.
(a) 23.03 minutes What is the time taken for 87.5% completion of the
reaction?
(b) 46.06 minutes
(a) 1 hour
(c) 460.6 minutes
(b) 2 hour
(d) 230.3 minutes
(c) 3 hour
11.
(d) 4 hour
A zero order reaction is one:
16.
(a) in which reactants do not react
Which order of reaction obeys the relation t1/2 = 1/Ka?
(b) in which one of the reactants is in large excess
(c) whose rate does not change with time (a) First

(d) whose rate increases with time (b) Second

12. (c) Third

(d) Zero
For A+B →C+D, ΔH = -20 kJmol-1 the activation
energy of the forward reaction is 85 kJ mol-1. The 17.
activation energy for backward reaction is...... kJ mol-1 The chemical reaction, 2O3 →3O2 proceeds as follows;
(b) 105 O3 ⇌O2 + O .....(Fast)
(c) 85
O+O3 → 2O2 ....(Slow)
(d) 40
The rate law expression should be:
(a) 65
(a) r = K[O3]2
13.
For the elementary reaction M  → N, the rate of (b) r = K[O3]2[O2]-1
disappearance of M increases by a factor of 8 upon
doubling the concentration of M. The order of the (c) r = K[O3][O2]
reaction with respect to M is:
(d) unpredictable
(a) 4
18.
(b) 3
The rate of reaction becomes 2 times for every 10°C rise
(c) 2 in temperature. How the rate of reaction will increase
when temperature is increased from 30°C to 80°C?
(d) 1
(a) 16
14.
(b) 32
The rate constant for a second order reaction is 8x10-5 M-
1  min-1 . How long will it take a 1M solution to be (c) 64
reduced to 0.5M? (d) 128

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 Top of Pyramid - Test #52- Chemical Kinetics
Contact Number: 9667591930 / 8527521718
19.
What fraction of a reactant showing first order remains
after 40 minute if t1/2 is 20 minute?

(a) 1/4
(b) 1/2
(c) 1/8
(d) 1/6
20.
For the reaction 2NO2 + F2 → 2NO2F, following

mechanism has been provided, 23.

slow

 NO2 + F2   −→  NO2F+F A reactant with initial concentration 1.386 mol litre-1
showing first order change takes 40 minute to become
f ast half. If it shows zero order change taking 20 minute to
NO2 + F   −→ NO2F becomes half under the similar conditions, the ratio,
K1/K0 for first order and zero order kinetics will be:
Thus, rate expression of the above
reaction can be written as: (a) 0.5 mol-1 litre

(a) r = K[NO2]2[F2] (b) 1.0 mol/litre

(c) 1.5 mol/litre
(b) r = K[NO2 ][F2]
(d) 2.0 mol-1 litre
(c) r = K[NO2]
 
(d) r = K[F2]
24.
21.
In a first order reaction, the concentration of the reactant
For the reaction: is decreased from 1.0 M to 0.25M in 20 minute. The rate
constant of the reaction would be:
[Cu(NH3)4]2+ + H2O⇌[Cu(NH3)3H2O]2+ + NH3
(a) 10min-1
the net rate of reaction at any time is given by, net rate =
(b) 6.931 min-1
20x10-4 [Cu(NH3)4]2+[H2O] - 3.0x105 [Cu(NH3 )3
(c) 0.6931 min-1
H20]2+[NH3]
(d) 0.06931 min-1
Then correct statement is/are :
25.
(a) rate constant for forward reaction = 2 x 10-4
The rate constant of a first order reaction is 4x10-3 sec-1.
(b) rate constant for backward reaction = 3 x 105 At a reactant concentration of 0.02 M, the rate of reaction
would be:
(c) equilibrium constant for the reaction = 6.6 x 10-10
(d) all of the above (a) 8 x 10-5 Msec-1

22. (b) 4 x 10-3 Msec-1

(c) 2 x 10-1 Msec-1

(d) 4 x 10-1 Msec-1

26.
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 Top of Pyramid - Test #52- Chemical Kinetics
Contact Number: 9667591930 / 8527521718

If concentration of reactants is increased by 'X', the rate Cl2 + HS- → 2Cl- + H+ + S (slow)
constant K becomes:
(a) A only
(a) eK/X
(b) B only
(b) K/X
(c) Both A and B
(c) K
(d) Neither A nor B
(d) X/K
30.
27.
The activation energies of the forward and backward
A graph plotted between log (t) 50% vs. log (a) reactions in the case of a chemical reaction are 30.5 and
concentration is a straight line. What conclusion can you 45.4 KJ/mol respectively. The reaction is
draw from the given graph?
1. Exothermic
2. Endothermic
3. Neither exothermic nor endothermic
4. Independent of temperature
31.
The t0.5 for the first order reaction.
(a) n=1, t1/2 = 1/K.a PCl5(g) →PCl3(g) + Cl2(g) is 20 min. The time in which
(b) n=2, t1/2 = 1/a the conc. of  PCl5  reduces to 25% of the initial conc. is
close to 
(c) n=1, t1/2 = 0.693/K
1. 22 min
(d) None of the above 2. 40 min
28. 3. 90 min
The rate of a chemical reaction doubles for every 10°C 4. 50 min
rise of temperature. If the temperature is raised by 50°C,
the rate of the reaction increases by about : 32.
(a) 10 times The activation energy of a reaction is zero. The rate
constant of the reaction is :
(b) 24 times
(1) increases with increase in temperature
(c) 32 times
(2) decreases with decrease in temperature
(d) 64 times
(3) decreases with increase in temperature
29.
(4) is nearly independent of temperature
Consider the reaction:
33.
Cl2(aq) + H2S(aq) → S(s) +2H+(aq) +2Cl-(aq)
When initial concentration of a reactant is doubled in a
The rate equation for this reaction is rate = k[Cl2][H2S] reaction, its half-life period is not affected. The order of
Which of these mechanisms is/are consistent with the reaction is
this rate equation? (a) zero
A. Cl2 + H2S → H+ + Cl- +Cl+ + HS- (slow) (b) first
(c) second
cl+ + HS- → H+ +Cl- + S (fast)
(d) more than zero but less than first
B. H2S ⇔ H+ + HS- (fast equilibrium)
34.
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 Top of Pyramid - Test #52- Chemical Kinetics
Contact Number: 9667591930 / 8527521718

In a zero order reaction for every 10° rise of temperature, (log 4=0.60, log 5=0.69)
the rate is doubled. If the temperature is increased from
10°C to 100°C, the rate of the reaction will become 39.

(a) 256 times Consider the reaction

(b) 512 times N2(g) +3H2(g) →2NH3(g)
(c) 64 times
(d) 128 times The equality relationship between d[NH3]/dt and -
35. d[H2]/dt is:

Which one of the following statements for the order of a (a) d[NH3]/dt = -1/3.d[H2]/dt
reaction is incorrect?
(b) +d[NH3]/dt = -2/3.d[H2]/dt
(a) Order is not influenced by stiochiometric coefficient
of the reactants (c) +d[NH3]/dt = -3/2.d[H2]/dt
(b) Order of reaction is sum of power to the (d) d[NH3]/dt = -d[H2]/dt
concentration terms of reactants to express the rate of
reaction 40.
(c) Order of reaction is always whole number Which of the following rate laws has an over all order of
0.5 for the reaction A+B+C→product-
(d) Order can be determined only experimentally
(A) R = k[A]. [B]. [C]                                         
 
0.5 0.5 0.5

36. (B) R = k[A] [B] [C]  

Half-life period of a first order reaction is 1386s. The

1.5 −1 0
(C) R = k[A] [B] [C]                    
specific rate constant of the reaction is
0 0.5
(D) R = k[A] [B] [C]
(a) 5.0 x 10-3s-1
41.
(b) 0.5 x 10-2s-1
For a reaction of the type 2A+B  →2C, the rate of the
(c) 0.5 x 10-3s-1 reaction is given by  k[A] [B]. When the volume of the
2

reaction vessel is reduced to 1/4 th of the original

(d) 5.0 x 10-2s-1 volume, the rate of reaction changes by a factor of
37. (A) 0.25                                                          
For the reaction, N2 + 3H2 →2NH3, if d[NH2]/dt = 2x10- (B) 16
4 mol L-1s-1, the value of -d[H ]/dt would be 
2 (C) 64                                                             

(a) 3x10-4 mol L-1s-1 (D) 4

42.
(b) 4x10-4 mol L-1s-1
The rate constant of a first order reaction is generally
(c) 6x10-4 mol L-1s-1 determined from a plot of 
(d) 1x10-4 mol L-1s-1 (A) Concentration of reactant vs time t
38. (B) log (concentration of reactant) vs time t
If 60% of a first order reaction was completed in 60 min, (C)  1
vs time t
50% of the same reaction would be completed in
concentration of  reac tan t

approximately.
(D) Concentration of reactant vs log time t
(a) 50 min
43.
(b) 45 min
(c) 60 min The plot of log k versus 1
is linear with a slope of
(d) 40 min T

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 Top of Pyramid - Test #52- Chemical Kinetics
Contact Number: 9667591930 / 8527521718
Ea
(A)  R
                          
−Ea
(B)  R

Ea
(C)  2.303R
                                            
−Ea
(D)  2.303R

44.
The rate constant , the activation energy and the
Arrhenius parameter of a chemical reaction at 25°C are 
3. 0  × 10  s
−4 −1
, 104. 4 kJ  mol and  6. 0  × 10 s–1−4 14

respectively the value of the rate constant as T→ ∞ is :

(A) 2. 0 ×  10 18
 s
−1
                                                  
(B) 6. 0 ×  10 −14
s
−1

(C) ∞                                                                   
(D) 3. 6 ×  10 30
 s
−1

 
45.
87.5% of a radioactive substance disintegrates in 40
minutes. What is the half life of the substance ?
(A) 13.58 min                                                   
(B) 135.8 min
(C) 1358 min                                                    
(D) None of these

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