Deodhar Classes

Chemical Kinetics
Time : 30 Min. Total Marks :- 60

1. For the reaction N2O5 (g) → 4NO2 (g) + O2 (g) the concentration of NO2
increases by 2.4 x 10-2 mol L-1 in 6 seconds. Calculate the rate of
appearance of NO2 and the rate of disappearance of N2 O5

a) 4 x 10-3 mol L-1 sec-1, 2 x 10-3 mol L-1 sec-1

b) 2 x 10-3 mol L-1 sec-1, 4 x 10-3 mol L-1 sec-1
c) 3 x 10-3 mol L-1 sec-1 , 3 x 10-3 mol L-1 sec-1
d) None of these

2. According to the Arrhenius equation, a straight line is to be obtained

by plotting the logarithm of the rate constant of chemical reaction (log
K) against

a) (T)
b) Log T

c)

d)

3. An exothermic reaction A → B has an activation energy of 17

KJ/mol. The heat of the reaction is 40 KJ. Calculate the activation
energy for the reserve reaction B → A ?

a) 60 KJ
b) 57 KJ
c) 75 KJ
d) 90 KJ

4. A gaseous reaction, 2A(g) + B(g) → 2C(g) , shows decrease n pressure

from 120 mm to 100 mm in 10 minutes. Th rate of appearance of C is
a) 2 mm/min
b) 4 mm/min
c) 10 mm/min
d) 12mm/min

5. For a hypothetical reaction; A + B → C the following data was

obtained in three different experiments:
[A] [B] Rate or reaction
(mol L )
-1
(mol L )
-1
(mol L-1 min-1)
0.01 0.01 1.0 x 10-4
0.01 0.03 9.0 x 10-4
0.03 0.03 2.70 x 10-3
Suggest Rate of Law
a) r = K[A]2 [B]
b) r = K[A] [B]2
c) r = K[A] [B]
d) None of these

6. The rate of a chemical reaction doubles for every 10◦ C rise in

temperature. If the temperature is increased by 60◦ C, the rate of
reaction increases by about

a) 20 times
b) 32 times
c) 64 times
d) 128 times

7. If the first order reaction involves gaseous reactants and gaseous

products the units of its rate are

a) atm
b) atm sec.
c) atm sec-1
d) atm2 sec2
8. Arrhenius equation may be written as:

a)

b)
 c)

d)

9. A first order reaction takes 69.3 minute for 50% completion. How
much time will be needed for 89% completion?

a) 160.97 minutes
b) 170.97 minutes
c) 130.97 minutes
d) 10.703 minutes

10 . A chemical reaction involves two reacting species. The rate of reaction

is directly proportional to the conc of one of them and inversely
proportional to the concentration of the other. The order of reaction is

a) 1
b) 2
c) Zero
d) Unpredictable

11. Time required to complete a half fraction of a reaction varies inversely to

the concentration of reactant then the order of reaction is

a) 0
b) 1
c) 2
d) 3

12. The acid hydrolysis of ester is

a) First order reaction

 b) Bimolecular reaction
c) Pseudo unimolecular reaction
d) All of the above

13. For a first order reaction which of the following relation is

not correct ?

a) K = K1 + K2

b)

c)

d)

14. For gaseous reaction, rate = K[A] [B]. If volume of container is reduced

to of initial, the rate of the reaction will be ____ times of initial.

1
a) 8
b) 8
1
c) 16
d) 16

15. Chemical reaction occurs as a result of collision between reacting

molecules. Therefore, the reaction rate is given by

a) Total number of collisions occurring in a unit volume per second

b) Fraction of molecules which possess energy less than the threshold
energy.
c) Total number of effective collisions
 d) None of the above

Question Answer
1 A
2 C
3 B
4 B
5 B
6 C
7 C
8 C
9 A
10 C
11 C
12 D
13 D
14 D
15 C