Bottom of Pyramid - Test # 30 - d & f Block

Contact Number: 9667591930 / 8527521718

1.
(b) Cl-,Br-
H2 S↑ Excess

CuSO4 (aq.)−−→M↓−−−−→N+O
of   KCN (c) CN-
Then final products N and O are respectively. (d) Cl-,F-
(a) [Cu(CN)4]3-,(CN)2 6.

(b) CuCn,(CN)2 The iron salt used in blue prints is:

(a) FeC2O4
(c) [Cu(CN)4]2-,(CN)2
(b) Fe2(C2O4)3
(d) Cu(CN)2,K2S
(c) K4Fe(CN)6
2.
(d) FeSO4
CrO42- (yellow) changes to Cr2O72- (orange) in pH =x
and vice versa in pH=y. Hence, x and y are: 7.
(a) 6,8 Which has highest melting point?
(b) 6,5 1. Cr
(c) 8,6 2. Fe
(d) 7,7 3. Cu
3. 4. Mo
When steam is passed over red hot iron , the substances 8.
formed are:
The colour of KMnO4 is due to
(a) Fe2O3 +H2
1. d-d transition
(b) Fe3O4 +H2
2. Charge transfer spectra
(c) FeO +H2 3. Polarisation of ion
(d) FeO+ H2 +O2 4. p-d transition

4. 9.

Which of the following solid salt on heating with Which of the following element does not show the
K2Cr2O7 and Conc. H2SO4 orange,red vapours are variable oxidation state?
evolved which turn aquous NaOH solution yellow? 1. Fe
(a) NaBr 2. Mn
(b)NaCl 3. Cu
(c) NaNO3 4. Zn
(d) NaI 10.
5. With F highest stable oxidation state of Mn is
Consider the following transformation: 1. +6
room   temperature 2. +4
2CuX2−−−−−−−−−−→2CuX+X2↑
3. +7
Then X- can be :
4. +3
(a) F-,Br- 11.
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 Bottom of Pyramid - Test # 30 - d & f Block
Contact Number: 9667591930 / 8527521718

H
+
4. 24
Cr2O72-+X→Cr3++H2O + oxidized product of X, X in
the above reaction cannot be 16.
Magnetic moment of K3[Fe(CN)5(H2O)] is
1. C2O42-
1. 0
2. Fe2+
2. 4.92
3. SO42-
3. 3.87
4. S2- 4. 2.83
12. 17.
The pair having similar magnetic moment is HgCl2 and I2 both when dissolved in water containing I-
1. Ti3+,V3+ ions the pair of species formed is

2. Cr3+,Mn2+ (a) HgI2, I                               (b) HgI2, I-

−

3. Mn2+,Fe3+ (c) HgI 2−

4
,  I
−

3
                             (d) Hg2I2, I-

4. Fe2+,Mn2+ 18.
13. Which one of the following statements related to
lanthanons is incorrect?
The main reason for a larger number of oxidation states
exhibited by the actinoids than the corresponding (a) Europium shows +2 oxidation state
lanthanoids is
(b) The basicity decreases as the ionic radius decreases
1. The lesser energy difference between 5f and 6d from Pr to Lu
orbitals than 4f and 5d orbitals
(c) All the lanthanons are much more reactive than
2. Larger atomic size of actinoids than the lanthanoids aluminium
3. More energy difference between 5f and 6d orbitals (d) Ce (+4) solutuion are widely used as oxidising agent
than between 4f and 5d orbitals in volumetric analysis
4. Greater reactive nature of the actinoids than the 19.
lanthanoids
Gadolinium belongs to 4f series. It's atomic number is
14. 64. Which of the following is the correct electronic
configuration of gadolinium?
In the dichromate ion Cr2O72-,
(a) [Xe]4f86d2                    (b) [Xe]4f95s1
1. 4 Cr-O bonds are equivalent
(c) [Xe]4f75d16s2                   (d) [Xe]4f65d26s2
2. 6 Cr-O bonds are equivalent
3. All Cr-O bonds are equivalent 20.

4. None of Cr-O bonds are equivalent Assuming complete ionisation, same moles of which of
the following compounds will require the least amount of
  acidified KMnO4 for complete oxidation?
15. (a) FeSO4
Electronic configuration of a transition element X in +3 (b) FeSO3
Oxidation state is [Ar]3d5. What is its atomic number? (c) FeC2O4
1. 25 (d) Fe(NO2)2

2. 26 21.
3. 27 Reason of lanthanoid contraction is
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 Bottom of Pyramid - Test # 30 - d & f Block
Contact Number: 9667591930 / 8527521718
27.
(a) negligible screening effect of 'f orbitals
(b) increasing nuclear charge Which of the following order of CFSE is incorrect?
(c) decreasing nuclear charge 3+  3+ 3+

(d) decreasing screening effect (a) [Co(en) ]

3
> [Co(NH3 ) ]
6
> [Co(H2 O) ]
6

22. (b) [PtCl 4]
2−
> [PdCl4 ]
2−
> [NiCl4 ]
2−

Which of the following lanthanoid ions is diamagnetic? 2+

(At. nos. Ce=58, Sm=62, Eu=63, Yb = 70) (c) [Ni(DMHH) 2

] < [Ni(en) ]
2

(a) Ce2+
3− 3+
(d) [Co(ox) 3
] < [Co(en) ]
3

(c) Eu2+
28.
(b) Sm2+
4−

(d) Yb2+ The CFSE for  [(Cocl)   complex is 18000  cm . −1

]
6
2−

23. The Δ for [(Cocl) 4
]  will be:

KMnO4 can be prepared from K2MnO4 as per reaction (a) 18000 cm                     (b) 16000 cm
−1 −1

3 MnO
2−
  +  2H2 O ⇌ 2 MnO
−
  +   MnO2   +  4 OH
− (c) 8000 cm                        (d) 2000 cm
−1 −1

4 4

29.
The reaction can go to completion by removing OH- ions
by adding Which of the following is called Wilkinson's catalyst?
(a) HCl (a) [RhCl(PPh 3
)3 ]              (b) TiCl 4
+ (C2 H5 )3 Al

(b) KOH (c) (C 2 H 5 )4 Pb                   (d) [PtCl 2 (NH3 )2 ]

(c) CO2 30.

(d) SO2 heat

(X) + K2 CO3 + Air −→ (Y)

24.
(Y) + Cl2 → (Z) Pink
Identify the alloy containing a non-metal as a constituent
in it.
Which of the following is correct?
(a) lnvar
(b) Steel (a) X= black, MnO ,Y=Blue, K 2 2 CrO4 , Z = KMnO 4

(c) Bell metal (b) X= green,  Cr2 O3 , Y=Yellow ,K CrO4 , Z = 

(d) Bronze K2 Cr2 O7
2

25.
(c) X= black, MnO , Y = green, K 2 2 MnO4 , z = KMnO 4

Which of the following ions will exhibit colour in

(d) x = black,  Bi O , Y = Colourless,  KBiO , z = 
aqueous solutions ? 2 3 2

KBiO
(a) La3+ (Z=57)
3

(b) Ti3+ (Z=22) 31.

(c) Lu3+ (Z=71) Acidified permanganate solution does not oxidize:
3+
(d) Sc (Z=21) (a) C O (aq)                    (b) NO (aq)
2
2−

4
−

26.
(c) S (aq)                         (d) F (aq)
2− −

In which of the following pairs are both the ions coloured

in aqueous solution? 32.
Which of the following solid salt on heating with solid 
(a) Ni2+, Ti3+              (b) Sc3+, Ti3+
K Cr O   and 
2 2 conc.H SO   orange red vapours are
7 2 4

(c) Sc3+, Co2+            (d) Ni2+, Cu+ evolved which turn aqueous NaOH solution yellow?

(At. no : Sc =21, Ti = 22, Ni = 28, Cu = 29, Co = 27) (a)NaBr               (b) NaCl

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 Bottom of Pyramid - Test # 30 - d & f Block
Contact Number: 9667591930 / 8527521718

(c) NaNO            (d) NaI

3 (B) Decomposes into Fe   and   Cl 2.

33. (B) Sublimes go give liquid FeCl                           3

Which of the following is true for the species  3d

4
(D) Sublimes to give gaseous dimmer (FeCl 3
) .
2

 configuration ?
38.
(A) Cr  is reducing in nature                               
2+

Anhydrous ferric chloride is prepared by

(B) Mn  is oxidising in nature.
3+

(A) Heating hydrated ferric chloride at a high

(C) Both (A) and (B)                                              temperature in a stream of air.
(D) None of these (B) Heating metallic iron in a stream of dry chlorine gas.
34. (C) Reaction of ferric oxide with HCl (aq).
In which compound does vanadium have an oxidation (D) Reaction of metallic iron with HCl (aq).
number of +4?
39.
(A) NH VO2                  
4
Select the correct statement :
(B) K 4 [V(CN) ]
6
(A) PH  reduces AgNO  to metallic Ag.
3 3

(C) VSO                                      
4
(B) Organic tissues turn  AgNO  black by reducing it to 3

(D) VOSO 4
Ag.
35. (C) AgCN  is soluble in KCN.
Arrange the following species in the increasing order of (D) All are correct statements.
their magnetic properties.
40.
VCl3     VOSO     Na VO4        [V(H 2 O) ]SO4 . H2 O
4 3
6
Which of the following products are formed when
  I              II                  III                      IV potassium bromide reacts with potassium permanganate
in alkaline pH?
 
‐
1. BrO ,   MnO2                    
(A) III<II<I<IV                                         
3

‐
(B) III<IV<II<I 2. BrO 4
2+
,   Mn

(C) II<III<I<IV                                          3. Br 2,   MnO2                      

‐
(D) IV<I<II<III 4. B2O‐ ,  MnO 4
2

36. 41.
Which of the following increasing order of oxidising Which of the following pairs of compounds are more
power is correct for the following species? stable
           VO + − 2− 2−

2
,  MnO4 ,   Cr2 O7 (A) K 2 [N iCl6 ], [P t(CN ) ]
4

(A) VO 2
+
< Cr2 O7
2−
< MnO4
−
               (B) NiCl4, PtCl4
(B) VO +
< MnO4
−
< Cr2 O7
2−
2−
2
(C) [N i(CN ) 4
] ,  K2 [P t(Cl6 )]

(C) Cr 2
O7
2−
< VO2
+
< MnO4
−
,               
(D) PtCl2, NiCl2
(D) Cr 2 O7
2−
< MnO4
−
< VO2
+

42.
37.
Which of the following has maximum number of
At 300°C,   FeCl 3   : unpaired electrons?
(A) Decomposes into FeCl 2   and   Cl2 .          (A) Fe2+
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 Bottom of Pyramid - Test # 30 - d & f Block
Contact Number: 9667591930 / 8527521718

(B) Fe3+

(C) Co3+

(D) Co2+
43.
Heating of Ag with dil. HNO3 give

(A) NO
(B) NO2

(C) N2O

(D) N2O3

44.
When excess of SnCl2 is added to HgCl2, the substance
formed is
(A) Hg2Cl2

(B) Sn
(C) Hg
(D)Cl2

45.
Which of the following elements form stable dinuclear
ions
(A) Zn
(B) Cd
(C)Hg
(D)Fe

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