CAREER POINT

Fresher Course for IIT JEE (Main & Advanced)–2017

DAILY PRACTICE PROBLEM SHEET
Course : Fresher(XL) Batch Subject : Chemistry DPPS-3
Topic : Chemical Kinetics
Q.1 Consider a reaction A + B  C, in which both reactants are in the same phase may be
(A) unimolecular elementary reaction (B) Exothermic
(C) Heterogeneous (D) Photochemical

Q.2 In the following gaseous phase first order reaction

A(g)  2B(g) + C(g)
initial pressure was found to be 400 mm of Hg and it changed to 1000 mm of Hg after 20 min. Then
(A) Half life for A is 10 min
(B) Rate constant is 0.0693 min–1
(C) Partial pressure of C at 30 min is 350 mm of Hg
(D) Total pressure after 30 min is 1150 mm of Hg

Q.3 Identify the true statement(s)

(A) A catalyst is chemically unchanged at the end of a reaction
(B) A catalyst may appear in the kinetic rate equation of the reaction
(C) A catalyst will not affect the composition of an equilibrium mixture
(D) A catalyst cannot cause a non-spontaneous (G > 0) reaction to proceed

k1sec–1
Q.4 For the reaction A B following graph is given,
k2sec–1
k1 = 4 × 10–2 sec–1. Which is/are correct statement (s) (n 2 = 0.7, n 8/7 = 0.14)

2.0
1.6 B
Conc.
(M)
0.4 A
time (in sec) 
(A) Equilibrium constant is 4.0
(B) Time taken for the completion of 50% of equilibrium conc. of B is 14 sec.
(C) Time taken for the completion of 10% of initial conc. of A is 2.8 sec.
(D) Rate constant of backward reaction is 10–2 sec–1

Q.5 Following is the plot between concentration of A versus time for the reaction 2A  B. Calculate rate of
reaction at 10s.
[A]

135º
t
10s
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Q.6 Following is the plost between concentration of B versus time for the reaction 3A 2B. Calculate rate of
reaction at 5s.
[B]

45º

t
5s
Q.7 The inversion of sucrose proceeds with constant half life of 600 minute at pH = 5 for any concentration of
sucrose. However, if pH = 6, the half life changes to 60 minute. Derive the rate law for inversion of sucrose.

Q.8 The acid catalysed hydrolysis of an organic compound A at 303 K has time for half change of 100 minute when
carried out in a buffer solution at pH = 5 and 10 minute when carried out at pH = 4. Both time of half change are
d[ A]
independent of the initial concentration of A. if the rate constant k is given by  k[ A ]x [ H ]y , what are the
dt
values of x and y ?

Q.9 Show that for a first-order reaction R  P the concentration of product can be represented as a function of
time by-
[P] = a + bt – ct2 + ………
And express a, b and c in terms of [R]0 and k.
[ R ]0 K 2
(A) a = 0 (B) b = [R]0 K (C) c  (D) a = [R]0 K
2

Q.10 The high temperature ( 1200K) decomposition of CH3 COOH(g) occurs as follows as per simultaneous 1st
order reactions
k1
CH 3 COOH  CH 4  CO 2
k2
CH 3COOH  CH 2 CO  H 2 O
What would be the % of CH 4 by mole in the product mixture (excluding CH3COOH) ?
50k1 100k1 200k1
(A) (B) (C) (D) it depends on time
(k1  k 2 ) (k1  k 2 ) (k1  k 2 )

ANSWERS
1 1
1. (B,C,D) 2. (A,B,C,D) 3. (A,B,C,D) 4. (A,B,C,D) 5. M/s 6.  M / s
2  2

7. Rate = K[Sucrose]1[H+]º 8. x = 1, y = 1 9. (A, B, C) 10. (A)

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