Section A single choice question (+4, -1)

Q.1 For the reaction in equilibrium: 2NOBr (g) 2NO(g)+Br(g) if PBr2(g) is P/9 at equilibrium and P is
total pressure then k p/P will be
1 8 1 9
(A) 9
(B) 9
(C) 18
(D) 8

Q.2 When Sulphur is in form of S8 it is heated at 900 k, the initial pressure of 1 atm falls by 29% at
equilibrium due to conversion of S8 to S2 find kp

(A) 2.55 atm3 (B) 1.81 atm3 (C) 1.34 atm3 (D) 5.25 atm3

Q.3 How many moles of NH4Cl must be added to one litre of 1 M NH4OH to make a buffer of pH=9
given p kb = 4.74 ?

(A) 1.8 mole (B) 2.3 mole (C) 1.3 mole (D) 3 mole

Q.4 What is correct order of decreasing strength of bases:

(A) CH3C H2– > NH2– > HC Ξ C – > OH– (B) HC Ξ C – > C2H5– > NH2– > OH–

(C) OH– > NH2– > HC Ξ C – > CH3C H2– (D) NH2– > HC Ξ C – > OH– > CH3CH–2

Q.5 The volume of water needed to dissolve 1 g of BaSO 4 (kSp=1.1×10-10) at 25oC is

(A) 820 litre (B) 410 litre (C) 205 litre (D) 100 litre

Q.6 pH of which salt is independent of its concentration:

(A) (CH3COO). C2H5N (B) NaH2PO4 (C) Na2HPO4 (D) NH4CN

Q.7 Which are/is incorrect expression for solubility product (k SP), solubility (S g/litre) of sparingly
soluble salt A3B2 (mol. Wt= M) in water at 25 oC
3 2
[ B 3- ] 1 M 4 é 3S ù é 2S ù
(A) KSP = 108 S 5
(B) 2+ 3
KSP = [3A ] [2B ] 3- 2
(C) = (D) k SP = ê ú ê ú
K Sp 54 S 4 ëM û ëM û

Q.8 In degree of dissociation of phCOOH is influenced by

(A) NH4OH (B) NaOH (C) HCl (D) ph COONa

Q.9 Highest solubility of a salt of weak acid and strong base is shown in

(1) Acidic buffer (2) Basic buffer (3) Water (4) All are same

Passage

A 10-2M solution of PuO2 (NO3)2 was found to have a pH of 3.8 [antilog -3.8 = 1.6×10-4]

Q.10 What is Hydrolysis constant for PuO22+ ion?

(A) 2.6×10-6 (B) 3.2×10-8 (C) 5.2×10-4 (D) 2.6×10-8

Q.11 What is kb for PuO2.OH+ ion?

(A) 10-6 (B) 3.8×10-8 (C) 3.8×10-9 (D) 3.8×10-11

Q.12 Equilibrium Effect

(A) Bismuth(S) Bi(l) P) Eq. shifts RHS on increasing pressure.

(B) H2O(s) H2O(l) Q) Eq. shifts LHS on increasing pressure.

(C) 2HI H2 + I2 R) Eq. shifts RHS on increasing P & T.

(D) Zr(l) Zr(S) S) No effect of addition of inert gas on equilibrium

Q.13 A vessel contain A(g) and B(g) at 2 atm and 4 atm respectively at T(k), the mixture is allowed to
attain equilibrium at T k, according to the reaction –

8 B(g) 8A(g) + C(S)

æn ö æn ö
at equilibrium çç A ÷÷ = çç B ÷÷ initial find value of y if kc = 2y
è nB ø eq è n A ø
Q.14 The self ionization constant of a pure monobasic acid HA K = [H 2A+][A-] has been estimated as
10-6 at room temperature. If the percentage acid molecules which converts to A - ion is x × 10−y then
the value of x is : (density of HA is 1.22 g/cc) molecular mass of acid 46

Q.15 Calculate the percentage error in hydronium ion concentration made by neglecting the
ionization of water in 1×10-6M NaOH.
 05/07/2020 CODE-A

Regd. Office: Aakash Tower, 8, Pusa Road, New Delhi-110005, Ph.011-47623456

MM : TEST SERIES for JEE-2021 Time :

Test - 7
Topics covered:
Mathematics : Trigonometric Ratio & Equations

Instructions :
(i) Use blue/black ballpoint pen only to darken the appropriate circle.
(ii) Mark should be dark and should completely fill the circle.
(iii) Dark only one circle for each entry.
(iv) Dark the circle in the space provided only.
(v) Rough work must not be done on the Answer sheet and do not use white-fluid or any other rubbing
material on Answer sheet.
(vi) Each question carries 4 marks. For every wrong response 1 mark shall be deducted from total score.

MATHEMATICS
Choose the correct answer: 3. The value of  for which
Single Option Correct Type (Q. No. 1 to Q. No. 5) tan150 tan 250 tan350  tan , where
1. Sum of all possible values of x satisfying the 
  0, 900 
system of equations tan x  tan y  tan x.tan y  5 0
(A) 5 (B) 450
 
and sin  x  y   4 cos x.cos y , where x   0,  (C) 75 0 (D) 65 0
 2
is: cos sin a b
4. If  , then  is
7 5 a b sec 2 cos ec 2
(A) (B)
12 12 (A) b (B) a
 3 (C) a+b (D) a
(C) (D) b
2 4
1  sin  2   cos  2 
2. Number of solution of equation: 5. If f    , then the value of
2 cos  2 

      3    
 
cos2  sinx  2cos2 x   tan2 x  tan2x  1, x  2, 2 f  . f   is:
4   4   28   7 
is: (A) 1 (B) 1
3 4
(A) 4 (B) 2
(C) 6 (D) 0 (C) 3 (D) 1
4 2

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Test-7 (Code-A) T est Series for J EE-2020

More than One Option Correct Question Paragraph (For Q. No. 10 to Q No. 11)
(From Q. No. 6 to Q. No. 9) '  ' is a root of the equation

6. If tan  2      x and tan   2   y then, the  2 sin x  cos x 1  cos x   sin2 x ,
values of tan  3      .tan     are '  ' is a root of the equation 3 cos 2 x  10 cos x  3  0
and
x2  y 2 xy  x  y  '  ' is a root of the equation
(A) (B)
1 x 2y 2 1  xy  x  y  1  sin 2 x  cos x  sin x; o   ,  ,    2
 y  y 10. cos   cos   cos  can be equal to:

xy x 2  y 2 1  xy  1  x  1  x 
(C) (D)    
2 3  1 2
1  x 2
y2 x  y  1  1
 x  y  x  y 
 (A)
   2 2

7. Let, 3 2
2
(B)
1 tanx  tan2 x   cosx cos3x  sin3x sinx  2
p x  cot2 x 
2    ,
 2 sin2x cos2x 6 3
 1 cot x  cot x    (C)
then which of the following are correct: 2
3 2
 
(A) p 180  p 720  2   (D)  1
2 2
(B) p 180   p  270   3 11.      can be equal to:
2

 4   7   5
(C) p  (A) (B)
  p 6   3 6 12
 3   
11 7
   3  (C) (D)
(D) p    p  3 12 12
5
   10 
Matrix Match
8. If a cos x  cot x  1  cos ecx then possible value 12. Column –I Column-II
of 'x' and 'a' can be: (A) The number of solution of the (P) 0
(A) x  2 n  , a  R, n  I equation
tan2 x  sin x, x  o,   (Q) 2

(B) x   4n  1 , a  R, n  I
2 (B) The value of

(C) a    , 1  12,      

4 tan    4 tan3  
 16   16 
    
(D) x   2n  1 , a  R, n  I, 6 tan2    tan4    1
2 16
   16 
y 3 (C) The number of solution of the (R) 4
9. If  sin2 x  2cos x  1 then y may belong
2y  5 equation
to:
cos3  sin3 
  1  cos  ,
(A)   , 10 3    58 ,   1  sin  1  cos 
  0, 2 
(B)   , 3    1,   (D) The number of integral solution (S) 3
 11  9  of the equation:
(C)   ,  , 
 3   5  tan3 x  3  3 tan x  tan2 x , in
   
2  x , 

(D)  , 1    ,  
3  3   2 2

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Test Series for JEE-2020 Test-7 (Code-A)
Numeric Answer Type Question (From Q. No. 13 to 1
 1  sin x  2
Q. No. 15) 15. If sum of the series: 1  x.log 1sin x  
cox 
cos x 
13. Number of solutions of the equation:
sin3 x  1  sin3 x   1  cos6 x  ; where x 0, 2 
1 1

and . is greater integer function; is....  1 sin x  4  1 sin x  8

x2 log1sin x  3
  x log1sin x  cos x   .......
cox  cos x  cox  
14. Number of ordered triplet  x, y , z  satisfying the
2 2 2
equation: tan x  cot x  2cos y and
k 1  x 
(Wherever defined) is equal to , then ' k '
2 2   13  2 x
cos y  sin z  1 ; xyz   , , is....
 3 6  is equal to....




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