IONIC EQUILIBRIUM

QUIZ FIITJEE

O
1.
O C CH3 (Asprin) is a pain reliever with pKa = 2

COOH
Two tablets each containing 0.09 gm of aspirin are dissolved in 100 mL solution pH will be:
(A) 0.5 (B) 1.0 (C) 0.0 (D) 2.0

2. 1M NH4OH and 1M HCl are mixed to make total volume of 300 mL. If pH of the mixture is 9.26 and
 
pKa N H 4  = 9.26 then volume ratio of NH4OH and HCl will be:
 
(A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) 3 : 1

3. A mono acid base is 10% ionised at 1M. Hence Kb is

(A) 1.0 × 10-2 (B) 1.1 × 10-2 (C) 1.0 × 102 (D) 1.0 × 10-4

4. A certain buffer solution contains equal concentration of X – and HX. the Kb for X – is 10-10. The pH of
the buffer is:
(A) 4 (B) 7 (C) 10 (D) 14

5. pH of a saturated solution of Ba(OH)2 is 12. Hence, Ksp of Ba(OH)2 is (in M3)

(A) 5 × 10-7 (B) 5 × 10-4 (C) 1 × 10-6 (D) 4 × 10-6

6. Ksp of CaSO4 is 4 × 10-12 CaSO4 is precipitated on mixing equal volume of the following solutions:
(A) 3 × 10-6 M CaCl2 & 3 × 10-6 M (NH4)2 SO4
(B) 4 × 10-6 M CaCl2 & 3 × 10-6 M (NH4) 2 SO4
(C) 6 × 10-6 M CaCl2 & 3 × 10-6 M (NH4) 2 SO4
(D) in all cases.

7. IF Ka for HCN is 4 × 10-10 and Kb for NH3 is 1.8 × 10-5. Then which of the following is correct
   
(A) pKa  N H 4  > pKa (HCN) (B) pKa  N H 4  < pKa (HCN)
   
  
(C) pKa  N H 4  = pKa (HCN) (D) can’t predict.
 

8. What is the pH of a solution prepared by mixing 2 gm of NaOH in 100mL of 1M CH3COOH pKa for
CH3COOH = 4.74
(A) 4.74 (B) 5.74 (C) 3.74 (D) none.

9. pKa of lactic acid is 5. pH of 0005M sodium lactate solution is:

(A) 10.5 (B) 8.5 (C) 5.0 (D) 9.7

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10. Which of the hydrated species can exist:
(I) H3O+, (II) H5O2+, (III) H9O4+
(A) I only (B) I, II only (C) I, II & III (D) II only.

11. If P, Q,R and S are solubilities of AgCl in water, 0.01M CaCl2, 0.01M NaCl and 0.05M AgNO3 solutions
respectively, then
(A) P > Q > R > S (B) P > R > Q > S (C) P > R > S > Q (D) Q > R > S > P

12. The solubility of AgI in 0.1M NaI compared to water will be

(A) Less (B) More (C) Remains same (D) Can’t say

13. A certain weak acid HA has dissociation constant of 10-4. The equilibrium constant for its reaction
with strong base in aqueous medium, is
(A) 10-4 (B) 10-10 (C) 1010 (D) 104

14. pKa of CH3COOH is 4.74.X mol of lead acetate and 0.1 mol acetic acid in 1L solution make a solution
of pH = 5.04. Hence X is
(A) 0.2 (B) 0.05 (C) 0.1 (D) 0.02

15. A certain buffer solution contain equal concentration of BOH and BCl. If Kb for BOH is 10-4, then pH of
solution will be
(A ) 4 (B) 10 (C) 6 (D) 8

16. N2O4(g) 2NO2(g) ;

In the given equilibrium , NO2 is 50 % of the total volume at a given temperature . Hence vapour
density of the equilibrium mixture is
(A) 34.5 (B) 25.0 (C) 23.0 (D) 20.0

17. If inert gas is added at constant volume to the following equilibrium

A(g) + 2B(g)  C(g)
(A) More C will form (B) More B will form (C) More A will form (D) No change

18. Sulphide ion (S 2-) react with solid sulpher forming S22- and S32- with formation constants 12 and 132
respectively. Formation constant of S32 from sulphur and S22- is:
(A) 12 (B) 132 (C) 11 (D) 1584

19. CO(g) + H2O(g) CO2(g) + H2(g) ; Kp = 9

1 mole each are placed in 1 Ltr. flask at 25o C, the mole of CO2 present at equilibrium:
(A) 0.5 (B) 1.5 (C) 0.25 (D) 3.0 mol

Kp
20. for the reaction CO(g) + ½ O2(g) CO2(g) will be:
Kc
1
(A) 1 (B) RT (C) (D) RT
RT

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