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IIT – JEE: 2021 CRASH COURSE (MAIN) DATE: 23/11/19

TIME: 1 Hr. TOPIC: CHEMICAL & IONIC EQUILIBRIUM MARKS: 120

SINGLE CORRECT ANSWER TYPE

This section contains20 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. Following equilibria are established starting from reactants only in three separate containers and total
pressure set up in each at equilibrium are equal to 1 atm.
(I) CaCO3s   CaO s   CO2 g  ; K p  K1
(II) NH 4 HSs   NH3 g   H 2S g  ; K p  K 2
(III) NH 2CO 2 NH 4 s   2NH3 g   CO2g  ; K p  K 3
Hence,
(A) K1  K 2  K3 (B) K3  K 2  K1 (C) K1  K 2  K3 (D) K1  K 2  K3

1
2. If Kp value for reaction H 2 g   S2 g   H 2S g  is 0.8. The value of Kp for
2
2H 2 g   S2 g   2H 2S g  will be:
(A) 1.6 (B) 6.4 (C) 0.64 (D) 0.8

3. The figure shows the change in concentrations of species A and B as a function of time. If n is an
integer then the equilibrium constant K c for the reaction: A  g   nB g  is:

(A) 1.6 (B) 16/30 (C) 1 (D) data insufficient

4. If solubility of AgCl in pure water is 10-5 M at a temperature then solubility of AgCl in 10-5 M NaCl
solution will be: (Take √5 = 2.24, if required)
(A) 10–5 M (B) 1.4  10-4 M (C) 0.62  10–5 M (D) 10–6 M

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5. At a particular temperature, ionic product Kw for water is 10–10. The CORRECT statement about a
solution with pH = 7 at this particular temperature is
(A) Solution is acidic in nature (B) [H+] = [OH-]
(C) Solution can be a basic buffer (D) Temperature < 250 C

6. CaCO3 and CaO solids and gaseous CO2 are placed in a vessel and allowed to reach equilibrium as
per the following reaction.
CaO s   CO 2 g   CaCO3s  H  180 kJ mol 1
The quantity of CaO in the vessel could not be increased by
(A) adding more of solid CaCO3 (B) removing some of CO2
(C) increasing the temperature (D) increasing the volume of vessel

7. In which of the following reactions, Kp < Kc at 298K?

(A) CO(g) + Cl2(g)  COCl2(g) (B) CO2(g) + C(s)  2CO(g)
(C) 2BrCl(g)  Br2(g) + Cl2(g) (D) I2(g)  2I(g)

8. An endothermic gas phase reaction is represented by the graph

lnKp lnKp lnKp lnKp

1/T 1/T 1/T 1/T

(A) (B) (C) (D)

9. 2CO 2(g)  2CO(g)  O2(g) H o  514KJ

Adding O2(g) to the reaction container (with reactants and products in equilibrium) will
(A) decrease the partial pressure of CO2(g) at equilibrium
(B) decrease the value of equilibrium constant
(C) increase the partial pressure of CO2(g) at equilibrium
(D) increase the partial pressure of CO(g) at equilibrium

10. Which one of the following equilibria is not affected by change in volume of the flask at constant
temperature?
(A) PCl5 g   PCl3g   Cl2g  (B) N 2 g   3H 2 g   2NH3 g 
(C) N 2 g   O2 g   2NO g  (D) SO2Cl 2 g   SO 2 g   Cl2 g 

11. The exothermic gaseous reaction A g   B g   2C g   D g  is most favoured at

(A) Low temperature and high pressure (B) High temperature and high pressure
(C) High temperature and low pressure (D) Low temperature and low pressure

12. The solubility product of Ag2CrO4 is 3.2  10–11. The concentration of Ag+ ion in its saturated
solution in mol/litre is
(A) 2  10–4 (B) 4  10–4 (C) 4  10–6 (D) 8  10–6

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13. A 0.1 M solution of CH3COOH (Ka = 2  10–5) is being titrated by a standard 0.025 M NaOH
solution. pH at equivalence point is
(A) 5.5 (B) 8.5 (C) 2.91 (D) 7

14. 0.1 M aqueous solution of which oxychloride has maximum pH?

(A) NaClO (B) NaClO2 (C) NaClO3 (D) NaClO4

15. When equal number of gram-equivalents of a strong acid and weak base are mixed at 25 oC, the
resulting solution undergoes
(A) Cationic hydrolysis resulting pH > 7 (B) Cationic hydrolysis resulting pH <7
(C) Anionic hydrolysis resulting pH > 7 (D) Anionic hydrolysis resulting pH< 7

16. Ionic product of water at 25oC is 10–14. Its value at a temperature higher than 25oC can be:
(A) 1  10–14 (B) 1  10–12 (C) 1  10–20 (D) 1  10–16

17. pH of 0.1 M aqueous solution of H2S (Ka1 = 10–7 and Ka2 = 10–14) will be
(A) 4 (B) 5.5 (C) 7 (D) 11

18. Degree of hydrolysis of salt of a weak acid (Ka = 2  10–7) and a weak base (Kb = 2  10–7) in
aqueous solution at 25oC is
(A) 1/2 (B) 1/3 (C) 1/4 (D) 1/5

19. At 25°C, the dissociation constants of CH3COOH and NH4OH in aqueous solution are almost the
same i.e., 10–5. If pH of some acetic acid solution is 3, the pH of NH4OH solution of same
concentration at the same temperature would be
(A) 3.0 (B) 4.0 (C) 10.0 (D) 11.0

20. Which of the following is NOT true for acidic solution at room temperature?
(A)  H    OH   (B)  H    10 7 M (C)  H    107 M (D)  OH    10 7 M

NUMERICAL VALUE TYPE

This section contains 05 questions. Each question is numerical value type. For each question,
enter the correct numerical value (in decimal notation, truncated/rounded-off to second
decimal place. (e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.

21. C s   CO 2 g   2CO g 
C s  and CO2 g  are present initially in the container and 50% of moles of CO2 reacts to reach at
equilibrium. If the equilibrium pressure is 6 atm, then what will be the value of K p ?

22. 10 ml of an aqueous solution of H2SO4 having pH 5 is diluted to 10 litres by adding water. What will
be the pH of diluted solution? Report the nearest integral value.

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23. 2O 3(g )  3O 2(g) K c  16
At equilibrium, the concentration of O2 is 4 mol/L. Report the molarity of O3 at this equilibrium
stage.

24. The pKb value of ammonium hydroxide is 4.75. An aqueous solution of ammonium hydroxide is
titrated with HCl. Report the pH of the solution at the point where half of ammonium hydroxide has
been neutralized.

25. The solubility product expression for Ca3(PO4)2 in terms of its solubility in pure water ‘s’ mol/litre is A  sB.
A and B are positive integers. Report (A/B).

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